CN106165932A - A kind of have shape memory adhesive lining with temperature adjustment function and preparation method thereof - Google Patents

A kind of have shape memory adhesive lining with temperature adjustment function and preparation method thereof Download PDF

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Publication number
CN106165932A
CN106165932A CN201610584252.2A CN201610584252A CN106165932A CN 106165932 A CN106165932 A CN 106165932A CN 201610584252 A CN201610584252 A CN 201610584252A CN 106165932 A CN106165932 A CN 106165932A
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China
Prior art keywords
shape memory
base fabric
double
adhesive
layer
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Granted
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CN201610584252.2A
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Chinese (zh)
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CN106165932B (en
Inventor
豆鑫帆
豆树华
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CHANGXING SHENFAN TEXTILE Co Ltd
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CHANGXING SHENFAN TEXTILE Co Ltd
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Classifications

    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/02—Layered materials
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D27/00—Details of garments or of their making
    • A41D27/02—Linings
    • A41D27/06—Stiffening-pieces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
    • B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by features of form at particular places, e.g. in edge regions
    • B32B3/08—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/028—Net structure, e.g. spaced apart filaments bonded at the crossing points
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/02—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/047—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of fibres or filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D01F1/103—Agents inhibiting growth of microorganisms
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/18—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
    • D06L1/14—De-sizing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic System
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/59—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
    • D06M11/61—Liquid ammonia
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/12—Processes in which the treating agent is incorporated in microcapsules
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/30—Antimicrobial, e.g. antibacterial
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/02—2 layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/20—All layers being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B32B2262/062—Cellulose fibres, e.g. cotton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/08—Animal fibres, e.g. hair, wool, silk
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Abstract

nullThe invention discloses a kind of adhesive lining with shape memory and temperature adjustment function，Including double-deck level base fabric and adhesive-layer，Described double-deck level base fabric is composited by shape memory layer and anti-bacterial wet-absorbing layer，The homoiothermic microcapsule containing phase change material also it is fixed with in described double-deck level base fabric，Described shape memory layer is made up of the bombax cotton silk with shape memory function，Described anti-bacterial wet-absorbing layer is made up of chitin fiber silk，One side or the dual coating of described double-deck level base fabric have adhesive-layer，The invention also discloses a kind of preparation method with shape memory and the adhesive lining of temperature adjustment function，Use biodegradable fiber，The feature of environmental protection is good，Shape memory layer has non-ironing and stable form effect，Adhesive lining is well-pressed，Shape-retaining ability is good，Anti-bacterial wet-absorbing layer has antibacterial activity and hygroscopicity，The affinity of skin is good，Non-stimulated，Containing homoiothermic microcapsule in adhesive lining，There is the effect of intelligent thermoregulating，Wearing comfort is greatly improved.

Description

A kind of have shape memory adhesive lining with temperature adjustment function and preparation method thereof
[technical field]
The present invention relates to the technical field of adhesive lining, particularly to a kind of adhesive lining with shape memory and temperature adjustment function And preparation method thereof.
[background technology]
Modern clothing stress wear embody in style comfortable, soft, slim and graceful and the most flexible.Adhesive lining is as " clothes The skeleton of dress ", it is the adjuvants that can not suddenly lack of clothing, adhesive lining is a kind of lining scribbling PUR, is that cloth art makes through commonly using One of adjuvant arrived.Adhesive lining is attached to the back side of cloth through pressing of heating, and " stitching with viscous generation " is greatly simplified production technology, and Widely applicable, itself and the reasonable coordination of fabric, the design philosophy of designer can not only be fully demonstrated, and can reach good Good takes effect.
Along with economic develops rapidly, gradually stepping up of people's living standard, people are more and more higher to the requirement of clothing, Do not require nothing more than apparel appearance natural, comfortable and easy to wear, and require that product is not required to safeguard, as having non-ironing, crease-resistant, intelligent thermoregulating etc. Performance, and the macromolecular material of current major part synthetic is difficult to degrade in nature, nondegradable macromolecular material Cause the white pollution to environment, it has also become the polluter that environment is new.In order to improve the environmental-protecting performance of adhesive lining, reduce ring The pollution in border, makes lining cloth have the effect of ironing and anti-crease, intelligent thermoregulating simultaneously, it is necessary to proposes one and has shape memory and tune Adhesive lining of temperature function and preparation method thereof.
[summary of the invention]
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, it is provided that one has shape memory and temperature adjustment function Adhesive lining and preparation method thereof, its aim to solve the problem that adhesive lining in prior art functional the most single, the feature of environmental protection is relatively low Technical problem.
For achieving the above object, the present invention proposes a kind of adhesive lining with shape memory and temperature adjustment function, including double Level base fabric and adhesive-layer, described double-deck level base fabric is composited by shape memory layer and anti-bacterial wet-absorbing layer, described bilayer Also being fixed with the homoiothermic microcapsule containing phase change material in level base fabric, described shape memory layer is by having shape memory function Bombax cotton silk is constituted, and described anti-bacterial wet-absorbing layer is made up of chitin fiber silk, the one side or double of described double-deck level base fabric Topcoating is covered with adhesive-layer.
As preferably, a diameter of 1～3 μm of described homoiothermic microcapsule.
As preferably, described shape memory layer and anti-bacterial wet-absorbing layer are light and thin type network structure.
As preferably, described shape memory layer is (65～70) with the volume ratio of double-deck level base fabric: 100.
A kind of preparation method with shape memory and the adhesive lining of temperature adjustment function, comprises the steps:
A) fiber is prepared: select natural kawo fiber to make bombax cotton silk；With dimethyl acetylamide as solvent, anhydrous chlorine Change lithium is dispersant, after magnetic stirrer mix homogeneously, adds the chitin granule of 35%～85% (w/v), through sealing Stirring, obtains thick transparent colloid spinning solution, obtains chitin fiber silk by wet spinning, standby；
B) fleece is prepared: respectively the bombax cotton silk in step a) and chitin fiber silk (5) are entered on carding machine Row combing, obtains thickness uniform bombax cotton net and chitin fiber net；
C) fleece arranges: the bombax cotton net prepared in step b) is carried out Liquid Ammonia Treatment, abundant water after 35～45min Wash, then carry out being dried after resin finishing, obtain the shape memory layer with shape memory function；
D) base fabric is prepared: overlapped with the shape memory layer in step c) by the chitin fiber net in step b), pass through water Thorn, method hot rolling obtain double-deck level base fabric；
E) spraying homoiothermic microcapsule: the homoiothermic microcapsule containing phase change material is mixed with distilled water, and adds appropriate Dispersant, preliminary stirring is placed on ultrasonic oscillator 3～6min, after being fully mixed to without precipitation, adds appropriate adhesive, then Secondary it is placed in ultrasonic oscillator 2～3min, obtains homoiothermic microcapsule spray coating liquor, then use spraying process to be vertically sprayed at double-deck level In base fabric, dried at a temperature of 24～27 DEG C, bilayer level base fabric is soaped, removes unreacted and the composition of non-set；
F) coating pre-treatment: by step e) process after double-deck level base fabric carry out desizing and refining treatment, go degreaser and Slurry, temperature is 85～95 DEG C, fully washes and is dried, then carry out in HTHP Jet Dyeing Machine after 25～30min Dyeing processes, and carries out heat treatment, made at double-deck level base fabric by vacuum dehydration simultaneously after having dyeed on framing shaping machine In low-down band liquid status, then in padding liquid, pad process post-drying；
G) double-dot coating: using layer based on PA PUR, retardation PES hot melt adhesive is tack coat, double after step f) processes The one side of level base fabric or the two-sided double-dot coating that carries out, then carry out 170～185 DEG C, the time be 5～8min bake melted, And cool down molding；
H) inspection is batched: after inspection, carry out batching packing by up-to-standard adhesive lining product.
As preferably, the time sealing stirring in described step a) is 3～4 days.
As preferably, in described step c), the treatment fluid of Liquid Ammonia Treatment is by 2D resin finishing agent, MgCl2·6H2O、 NH4Cl, softening agent and wetting agent composition, the concentration of 2D resin finishing agent is 92～95g/L, MgCl2·6H2O and NH4Cl's is dense Degree is 12～16g/L, and softening agent is 30～40g/L, and wetting agent is 1～2g/L；The resin liquid of described resin finishing is by 2D tree Fat finishing agent, MgCl2·6H2O、NH4Cl, softening agent and wetting agent composition, the concentration of 2D resin finishing agent is 80～90g/L, MgCl2·6H2O and NH4The concentration of Cl is 8～10g/L, and softening agent is 40～50g/L, and wetting agent is 1～2g/L.
As preferably, MgCl in the treatment fluid of described Liquid Ammonia Treatment and the resin liquid of resin finishing2·6H2O and NH4Cl Concentration than for 15:1, softening agent is silicone softening agent, and wetting agent is TRITONTMHW-1000。
As preferably, in described step e), dispersant is polycaprolactone, and adhesive is polyvinyl alcohol.
Beneficial effects of the present invention: compared with prior art, the one that the present invention provides has shape memory and homoiothermic merit Adhesive lining of energy and preparation method thereof, the manufacture using degradable bombax cotton silk and chitin fiber silk to be double-deck level base fabric Fiber, has environment protection significance；After bombax cotton silk carding, by Liquid Ammonia Treatment and resin finishing, obtain pliability High, resilience is good and has the shape memory layer of shape memory function, has non-ironing and stable form effect；Chitin is fine The anti-bacterial wet-absorbing layer that dimension silk is made has antibacterial activity and hygroscopicity, good to the affinity of skin, non-stimulated, also has prevention The effect of allergy；By spraying process, the homoiothermic microcapsule containing phase change material is bonded in double-deck level base fabric so that adhesive lining There is the effect of intelligent thermoregulating, play the effect of regulation temperature, it is provided that moist heat in comfortable clothing, wearing comfort It is greatly improved.
Inventive feature and advantage will combine accompanying drawing by embodiment and be described in detail.
[accompanying drawing explanation]
Fig. 1 is a kind of schematic cross-section with shape memory and the adhesive lining of temperature adjustment function of the embodiment of the present invention；
Fig. 2 is the partial enlarged drawing in A portion in Fig. 1.
In figure: 1-bilayer level base fabric, 11-shape memory layer, 12-anti-bacterial wet-absorbing layer, 2-adhesive-layer, 3-homoiothermic microcapsule, 4-bombax cotton silk, 5-chitin fiber silk.
[detailed description of the invention]
For making the object, technical solutions and advantages of the present invention of greater clarity, below by accompanying drawing and embodiment, right The present invention is further elaborated.However, it should be understood that specific embodiment described herein is only in order to explain this Bright, it is not limited to the scope of the present invention.Additionally, in the following description, eliminate the description to known features and technology, with Avoid unnecessarily obscuring idea of the invention.
Refering to Fig. 1 and Fig. 2, the embodiment of the present invention provides a kind of adhesive lining with shape memory and temperature adjustment function, including Double-deck level base fabric 1 and adhesive-layer 2, described double-deck level base fabric 1 is composited by shape memory layer 11 and anti-bacterial wet-absorbing layer 12, institute Also being fixed with the homoiothermic microcapsule 3 containing phase change material in the double-deck level base fabric 1 stated, described shape memory layer 11 is by having shape The bombax cotton silk 4 of shape memory function is constituted, and described anti-bacterial wet-absorbing layer 12 is made up of chitin fiber silk 5, described bilayer One side or the dual coating of level base fabric 1 have adhesive-layer 2.
A diameter of 1～3 μm of described homoiothermic microcapsule 3, described shape memory layer 11 and anti-bacterial wet-absorbing layer 12 are Light and thin type network structure, described shape memory layer 11 is (65～70) with the volume ratio of double-deck level base fabric 1: 100.
The present embodiment also provides for a kind of preparation method with shape memory and the adhesive lining of temperature adjustment function, including walking as follows Rapid:
A) fiber is prepared: select natural kawo fiber to make bombax cotton silk 4；With dimethyl acetylamide as solvent, anhydrous Lithium chloride is dispersant, after magnetic stirrer mix homogeneously, adds the chitin granule of 35%～85% (w/v), through overstocked Envelope stirring, obtains thick transparent colloid spinning solution, obtains chitin fiber silk 5 by wet spinning, standby.
Wherein, the time sealing stirring is 3～4 days.
B) fleece is prepared: respectively the bombax cotton silk 4 in step a) and chitin fiber silk 5 are carried out on carding machine Combing, obtains thickness uniform bombax cotton net and chitin fiber net.
C) fleece arranges: the bombax cotton net prepared in step b) is carried out Liquid Ammonia Treatment, abundant water after 35～45min Wash, then carry out being dried after resin finishing, obtain the shape memory layer 11 with shape memory function.
Wherein, the treatment fluid of Liquid Ammonia Treatment is by 2D resin finishing agent, MgCl2·6H2O、NH4Cl, softening agent and wetting agent group Becoming, the concentration of 2D resin finishing agent is 92～95g/L, MgCl2·6H2O and NH4The concentration of Cl is 12～16g/L, and softening agent is 30～40g/L, wetting agent is 1～2g/L；The resin liquid of described resin finishing is by 2D resin finishing agent, MgCl2·6H2O、 NH4Cl, softening agent and wetting agent composition, the concentration of 2D resin finishing agent is 80～90g/L, MgCl2·6H2O and NH4Cl's is dense Degree is 8～10g/L, and softening agent is 40～50g/L, and wetting agent is 1～2g/L.
Further, MgCl in the treatment fluid of Liquid Ammonia Treatment and the resin liquid of resin finishing2·6H2O and NH4The concentration of Cl Ratio is 15:1, and softening agent is silicone softening agent, and wetting agent is TRITONTMHW-1000。
D) base fabric is prepared: overlapped with the shape memory layer 11 in step c) by the chitin fiber net in step b), pass through Spun lacing, method hot rolling obtain double-deck level base fabric 1.
E) spraying homoiothermic microcapsule: the homoiothermic microcapsule 3 containing phase change material is mixed with distilled water, and adds appropriate Dispersant, preliminary stirring is placed on ultrasonic oscillator 3～6min, after being fully mixed to without precipitation, adds appropriate adhesive, then Secondary it is placed in ultrasonic oscillator 2～3min, obtains homoiothermic microcapsule spray coating liquor, then use spraying process to be vertically sprayed at bilayer In level base fabric 1, dried at a temperature of 24～27 DEG C, bilayer level base fabric 1 is soaped, removes unreacted and the one-tenth of non-set Point.
Wherein, dispersant is polycaprolactone, and adhesive is polyvinyl alcohol.
F) coating pre-treatment: by step e) process after double-deck level base fabric 1 carry out desizing and refining treatment, go degreaser and Slurry, temperature is 85～95 DEG C, fully washes and is dried, then carry out in HTHP Jet Dyeing Machine after 25～30min Dyeing processes, and carries out heat treatment, made at double-deck level base fabric 1 by vacuum dehydration simultaneously after having dyeed on framing shaping machine In low-down band liquid status, then in padding liquid, pad process post-drying.
G) double-dot coating: using layer based on PA PUR, retardation PES hot melt adhesive is tack coat, double after step f) processes The one side of level base fabric 1 or the two-sided double-dot coating that carries out, then carry out 170～185 DEG C, the time be 5～8min bake melted, And cool down molding.
H) inspection is batched: after inspection, carry out batching packing by up-to-standard adhesive lining product.
A kind of adhesive lining with shape memory and temperature adjustment function that the present invention provides and preparation method thereof, uses degradable The manufacture fiber that bombax cotton silk and chitin fiber silk are double-deck level base fabric, there is environment protection significance；Through bombax cotton silk After carding, by Liquid Ammonia Treatment and resin finishing, obtain that pliability is high, resilience is good and has shape memory function Shape memory layer 11, has non-ironing and stable form effect；The anti-bacterial wet-absorbing layer 12 that chitin fiber silk is made has antibacterial Activity and hygroscopicity, good to the affinity of skin, non-stimulated, also there is pre-hypo-allergenic effect；Will be containing phase by spraying process The homoiothermic microcapsule 3 becoming material is bonded in double-deck level base fabric so that adhesive lining has the effect of intelligent thermoregulating, plays regulation temperature The effect of degree, it is provided that moist heat in comfortable clothing, wearing comfort is greatly improved.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention Any amendment, equivalent or the improvement etc. made within god and principle, should be included within the scope of the present invention.

Claims (9)

1. there is an adhesive lining for shape memory and temperature adjustment function, including double-deck level base fabric (1) and adhesive-layer (2), its feature It is: described double-deck level base fabric (1) is composited by shape memory layer (11) and anti-bacterial wet-absorbing layer (12), described double-deck level Also being fixed with the homoiothermic microcapsule (3) containing phase change material in base fabric (1), described shape memory layer (11) is by having shape note The bombax cotton silk (4) recalling function is constituted, and described anti-bacterial wet-absorbing layer (12) is made up of chitin fiber silk (5), and described is double The one side of level base fabric (1) or dual coating have adhesive-layer (2).
A kind of adhesive lining with shape memory and temperature adjustment function, it is characterised in that:
A diameter of 1～3 μm of described homoiothermic microcapsule (3).
A kind of adhesive lining with shape memory and temperature adjustment function, it is characterised in that:
Described shape memory layer (11) and anti-bacterial wet-absorbing layer (12) are light and thin type network structure.
A kind of adhesive lining with shape memory and temperature adjustment function, it is characterised in that:
Described shape memory layer (11) is (65～70) with the volume ratio of double-deck level base fabric (1): 100.
5. a preparation method with shape memory and the adhesive lining of temperature adjustment function, it is characterised in that: comprise the steps:
A) fiber is prepared: select natural kawo fiber to make bombax cotton silk (4)；With dimethyl acetylamide as solvent, anhydrous chlorine Change lithium is dispersant, after magnetic stirrer mix homogeneously, adds the chitin granule of 35%～85% (w/v), through sealing Stirring, obtains thick transparent colloid spinning solution, obtains chitin fiber silk (5) by wet spinning, standby；
B) fleece is prepared: respectively the bombax cotton silk (4) in step a) and chitin fiber silk (5) are carried out on carding machine Combing, obtains thickness uniform bombax cotton net and chitin fiber net；
C) fleece arranges: the bombax cotton net prepared in step b) is carried out Liquid Ammonia Treatment, fully washes after 35～45min, It is dried after carrying out resin finishing again, obtains the shape memory layer (11) with shape memory function；
D) base fabric is prepared: overlapped with the shape memory layer (11) in step c) by the chitin fiber net in step b), pass through water Thorn, method hot rolling obtain double-deck level base fabric (1)；
E) spraying homoiothermic microcapsule: the homoiothermic microcapsule (3) containing phase change material is mixed with distilled water, and add appropriate dividing Powder, preliminary stirring is placed on ultrasonic oscillator 3～6min, after being fully mixed to without precipitation, adds appropriate adhesive, again It is placed in ultrasonic oscillator 2～3min, obtains homoiothermic microcapsule spray coating liquor, then use spraying process to be vertically sprayed at double-deck level base On cloth (1), dried at a temperature of 24～27 DEG C, bilayer level base fabric (1) is soaped, removes unreacted and the one-tenth of non-set Point；
F) coating pre-treatment: the double-deck level base fabric (1) after being processed by step e) carries out desizing and refining treatment, removes degreaser and slurry Material, temperature is 85～95 DEG C, fully washes and is dried, then contaminate in HTHP Jet Dyeing Machine after 25～30min Color processes, and carries out heat treatment, make double-deck level base fabric (1) place by vacuum dehydration simultaneously after having dyeed on framing shaping machine In low-down band liquid status, then in padding liquid, pad process post-drying；
G) double-dot coating: using layer based on PA PUR, retardation PES hot melt adhesive is tack coat, the double-deck level after step f) processes The one side of base fabric (1) or the two-sided double-dot coating that carries out, then carry out 170～185 DEG C, the time be 5～8min bake melted, and Cooling molding；
H) inspection is batched: after inspection, carry out batching packing by up-to-standard adhesive lining product.
A kind of preparation method with shape memory and the adhesive lining of temperature adjustment function, its feature exists In: the time sealing stirring in described step a) is 3～4 days.
A kind of preparation method with shape memory and the adhesive lining of temperature adjustment function, its feature exists In: in described step c), the treatment fluid of Liquid Ammonia Treatment is by 2D resin finishing agent, MgCl2·6H2O、NH4Cl, softening agent and moistening Agent forms, and the concentration of 2D resin finishing agent is 92～95g/L, MgCl2·6H2O and NH4The concentration of Cl is 12～16g/L, soft Agent is 30～40g/L, and wetting agent is 1～2g/L；The resin liquid of described resin finishing is by 2D resin finishing agent, MgCl2· 6H2O、NH4Cl, softening agent and wetting agent composition, the concentration of 2D resin finishing agent is 80～90g/L, MgCl2·6H2O and NH4Cl Concentration be 8～10g/L, softening agent is 40～50g/L, and wetting agent is 1～2g/L.
A kind of preparation method with shape memory and the adhesive lining of temperature adjustment function, its feature exists In: MgCl in the treatment fluid of described Liquid Ammonia Treatment and the resin liquid of resin finishing2·6H2O and NH4The concentration of Cl than for 15:1, Softening agent is silicone softening agent, and wetting agent is TRITONTMHW-1000。
A kind of preparation method with shape memory and the adhesive lining of temperature adjustment function, its feature exists In: in described step e), dispersant is polycaprolactone, and adhesive is polyvinyl alcohol.
CN201610584252.2A 2016-07-22 2016-07-22 A kind of adhesive lining with shape memory and temperature adjustment function and preparation method thereof Active CN106165932B (en)

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CN107201664A (en) * 2017-05-24 2017-09-26 东莞易昌塑胶布业有限公司 A kind of production method for the lining cloth that can adjust temperature
CN114921956A (en) * 2022-06-02 2022-08-19 高梵(浙江)信息技术有限公司 Manufacturing method of ultrathin down jacket fabric with waterproof and constant-temperature functions

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CN203188031U (en) * 2013-04-16 2013-09-11 福建百川资源再生科技有限公司 Novel cloth with intelligent temperature regulation effect
CN204690227U (en) * 2015-05-12 2015-10-07 长兴圣帆纺织有限公司 A kind of water-proof environmental protection adhesive interlining substrates
CN204930484U (en) * 2015-08-13 2016-01-06 长兴三马仕纺织品有限公司 A kind of antibacterial, ventilating adhesion lining cloth
CN205902851U (en) * 2016-07-22 2017-01-25 长兴圣帆纺织有限公司 Bonding lining with shape memory and function that adjusts temperature

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CN102499498A (en) * 2011-09-30 2012-06-20 常熟市众望经纬编织造有限公司 Antibacterial memory fabric
CN203188031U (en) * 2013-04-16 2013-09-11 福建百川资源再生科技有限公司 Novel cloth with intelligent temperature regulation effect
CN204690227U (en) * 2015-05-12 2015-10-07 长兴圣帆纺织有限公司 A kind of water-proof environmental protection adhesive interlining substrates
CN204930484U (en) * 2015-08-13 2016-01-06 长兴三马仕纺织品有限公司 A kind of antibacterial, ventilating adhesion lining cloth
CN205902851U (en) * 2016-07-22 2017-01-25 长兴圣帆纺织有限公司 Bonding lining with shape memory and function that adjusts temperature

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Publication number Priority date Publication date Assignee Title
CN107201664A (en) * 2017-05-24 2017-09-26 东莞易昌塑胶布业有限公司 A kind of production method for the lining cloth that can adjust temperature
CN107201664B (en) * 2017-05-24 2019-08-30 东莞易昌塑胶布业有限公司 A kind of production method of the lining cloth of adjustable temperature
CN114921956A (en) * 2022-06-02 2022-08-19 高梵(浙江)信息技术有限公司 Manufacturing method of ultrathin down jacket fabric with waterproof and constant-temperature functions
CN114921956B (en) * 2022-06-02 2023-11-07 高梵(浙江)信息技术有限公司 Manufacturing method of ultrathin down jacket fabric with waterproof constant temperature function

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