CN105533828B - A kind of seamless synthetism T-shirt - Google Patents

A kind of seamless synthetism T-shirt Download PDF

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Publication number
CN105533828B
CN105533828B CN201610050637.0A CN201610050637A CN105533828B CN 105533828 B CN105533828 B CN 105533828B CN 201610050637 A CN201610050637 A CN 201610050637A CN 105533828 B CN105533828 B CN 105533828B
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CN
China
Prior art keywords
shirt
parts
synthetism
seamless
toughness
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CN201610050637.0A
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CN105533828A (en
Inventor
黄福开
金华
黄忠诚
罗锐
张基鸿
翁创杰
翁宏果
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HONGJI UNDERWEAR INDUSTRY CO., LTD.
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GUANGDONG HONGJIE UNDERWEAR INDUSTRY Co Ltd
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Classifications

    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D1/00Garments
    • A41D1/04Vests, jerseys, sweaters or the like
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D27/00Details of garments or of their making
    • A41D27/10Sleeves; Armholes
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D27/00Details of garments or of their making
    • A41D27/24Hems; Seams
    • A41D27/245Hems; Seams made by welding or gluing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203Polyhydroxy compounds
    • C08G18/3206Polyhydroxy compounds aliphatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225Polyamines
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes

Abstract

The present invention relates to T-shirt preparing technical field, and in particular to a kind of seamless synthetism T-shirt, including T-shirt main body and sleeve, the sleeve splice in the first half both sides of the T-shirt main body, it is characterised in that:The sleeve and the splicing mouthful of the T-shirt main body are end to end, and glue is spliced in the surface of the splicing mouth provided with ultra-toughness, and T-shirt main body of the invention is not present any overall weight for sewing up bone, reducing T-shirt, substantially increases the snugness of fit of T-shirt.

Description

A kind of seamless synthetism T-shirt
Technical field
The present invention relates to T-shirt preparing technical field, and in particular to a kind of seamless synthetism T-shirt.
Background technology
T-shirt is one of favorite clothes of spring and summer people, and particularly The sun is shining fiercely, heat hard to bear midsummer, T-shirt It is natural, comfortable, graceful and do not lose the advantage of serious sense and progressively substitute that men wear part vest in the past or undershirt is additional with its The pattern of one shirt with short sleeves or aloha shirt appears in social life, and the seasonal clothes of dress are happy to as people.At present into The fashionable dress of dress is liked for global men and women, old and young.It is said that whole world annual turnover is up to billions of, constituted with jeans The whole world is most popular, wear the most clothes of number.
T-shirt it is raw materials used very extensively, typically have cotton, fiber crops, hair, silk, chemical fibre and its blend fabric, especially with pure cotton, fiber crops or Cotton and Hemp blending is preferred, and has the advantages that ventilative, soft, comfortable, nice and cool, absorbing sweat, radiating.T-shirt is often knitwear, but due to disappearing The demand of expense person is constantly changing, and designs and produces and also increasingly renovates, therefore, the T-shirt made with woven fabric also numerous and confused face City, as the newcomer in T-shirt family.This T-shirt is led or rib sleeve, rib-loop surple frequently with rib-loop, so that structure is more Plus compacted mass.The most basic cutting structure of T-shirt is to cut out the sleeve of forward and backward and both sides respectively, then utilizes sewing Machine sews up anter, rear piece and sleeve, and it sews up mouth and passed through after flatcar and Xi bones relatively firmly, this side of sewing up Formula T-shirt can all have the mouth that sews up of many projections at the both sides of clothes, shoulder and sleeve, influence the comfortableness of dress.
For this problem, a kind of cartridge type knitting is developed, the technique can obtain main on columnar T-shirt Body, removes the line that sews up of T-shirt both sides, it is only necessary to sew up up in shoulder position and by sleeve.But this mode is still The problem of sewing up bone of shoulder position can not be solved, especially in some close-fitting T-shirts, the Le trace sense for sewing up bone of shoulder position is non- Chang Mingxian, comfort level is not high.
For it is above-mentioned the problem of, people redesign, traditional sleeve part is extended since neckline, anter is instead of With rear must the suture of shoulder position mode, and the position of sewing up of sleeve and anter is moved at both sides clavicle to shirtfront, sleeve Position of sewing up with rear is moved at shoulder blade, eliminates the bone that sews up at shoulder, the T-shirt wearing comfort of this structure Height, be particularly suitable for use in sports T-shirt.But what this structure can not still eliminate shoulder blade and precordial locations sews up bone, for some Close-fitting sweat shirt, this sews up the presence of bone, still can produce friction to human body, comfort level has much room for improvement.
The content of the invention
In order to overcome shortcoming and defect present in prior art, it is an object of the invention to provide a kind of seamless synthetism T Any overall weight for sewing up bone, reducing T-shirt is not present in shirt, its T-shirt main body, substantially increases the dress of T-shirt Comfortableness.
The purpose of the present invention is achieved through the following technical solutions:
A kind of seamless synthetism T-shirt, including T-shirt main body and sleeve, the sleeve splice in the upper of the T-shirt main body Half portion both sides, the sleeve and the splicing mouthful of the T-shirt main body are end to end, and the surface of the splicing mouth is spliced provided with ultra-toughness Glue, the ultra-toughness splicing glue is made up of the raw material of following parts by weight:
30-40 parts of aliphatic dihydroxy alcohol
15-20 parts of aliphatic polyamine class curing agent
4-6 parts of hydrophilic chain extender
25-35 parts of aromatic isocyanate
0.5-1 parts of catalyst
50-55 parts of pentalyn
3-5 parts of lactone compound
1-2 parts of silane coupler
0.2-0.4 parts of antioxidant
2-6 parts of nertralizer.
Ultra-toughness splicing glue prepared by the present invention has pliability high, even if laminating skin, will not also be produced to human skin Raw friction, elastic stretching rate and resilience are good, can adapt to the random variation of T-shirt;Caking property with cloth is good, anti-pull property Can be high.
Wherein, the hydrophilic chain extender is that ethylene oxide glycol is 2 according to weight ratio with amino acid:1 mixture.Can be effective Improve caking property and flexibility that ultra-toughness splices glue.
Wherein, the catalyst is triethylenediamine.Reaction rate is improved, production efficiency is improved.
Wherein, the nertralizer is that trifluoroacetic acid is 1 according to weight ratio with acetic acid:1 mixture.Obtained ultra-toughness splicing Colloidality matter is gentle, will not produce stimulation to human skin.
Wherein, the aromatic isocyanate is 2,4- toluene di-isocyanate(TDI)s, 4,4 ' -- diphenylmethane diisocyanate Ester, hexamethylene diisocyanate are 3 according to weight ratio:5:2 mixture, obtained ultra-toughness splices the caking property and softness of glue Property it is good, the cementability with cloth is good.
Wherein, the lactone compound is butyrolactone.Obtained ultra-toughness splicing glue does not harden after drying, and pliability is good.
Wherein, the antioxidant is antioxidant 245.
Wherein, the preparation method of the ultra-toughness splicing glue is as follows:
(1)By aliphatic dihydroxy alcohol, hydrophilic chain extender, aromatic isocyanate, catalyst, pentalyn, interior Ester compounds are added in reaction vessel, are uniformly mixed, in a nitrogen environment reflux condensation mode reaction 15-20h, and temperature is 60- 70℃;
(2)Toward step(1)Add nertralizer stirring 5-10min;
(3)Silane coupler, antioxidant are added in reaction vessel, 5-7h, temperature control are reacted in a nitrogen environment At 60-65 DEG C, vacuum distillation obtains viscoelastic polyurethane latex solution;
(4)Aliphatic polyamine class curing agent is added in viscoelastic polyurethane latex solution and is well mixed, is coated on base material solid Change is dried to obtain ultra-toughness splicing glue.
The preparation-obtained ultra-toughness splicing glue of the present invention can not only apply the sleeve in T-shirt and the spelling of T-shirt main body Bonding is connect, the crimping that can be applied in neckline and shirt tail is fixed, adhesion firmness is high, water-wash resistance is good.
The processing technology of seamless synthetism T-shirt of the present invention is:T-shirt main body and sleeve part are cut out, then by T-shirt The stitching portion of shirt main body and sleeve fabric is end to end, and ultra-toughness splicing glue is pasted at the back side of the splicing mouthful, and then heating is pressurizeed, Make ultra-toughness splice peptization solution to bond with cloth, the moulding pressure is 35Mpa, and heating-up temperature is 150 DEG C, and the heat time is 30s. To the splicing mouth of seamless synthetism T-shirt can bear at least 2000N pulling force, resistance to 1500 washings not degumming.
Wherein, the base material is purified cotton cloth base material, and the viscoelastic polyurethane latex solution is coated on the purified cotton cloth base material Surface, dried viscoelastic polyurethane latex solution surface prepares one layer of strippable ultra-toughness splicing glue.By viscoelastic polyurethane latex solution It is coated on purified cotton cloth base material, after being bonded with T-shirt main body, its surface contacted with human skin is purified cotton cloth base Material, reduction and the frictionally damage of human skin, comfort are high.
Wherein, the purified cotton cloth base material is formed by the warp and weft braiding of Quality Pure Cotton Yarn Production, and the warp is 3.9tex length Suede cotton, the parallel is 4.2tex long-staple cotton.The Quality Pure Cotton Yarn Production of the purified cotton cloth base material of the present invention uses ultra-fine long-staple cotton, obtains The pliability and degree of drawing of purified cotton cloth base material are high, and the performance for splicing glue with ultra-toughness is approached, and is not susceptible to come off.Quality Pure Cotton Yarn Production and volume Weaving process is all prior art, and no further details to be given herein.
The beneficial effects of the present invention are:A kind of seamless synthetism T-shirt of the present invention, including T-shirt main body and sleeve, institute Sleeve is stated to splice in the first half both sides of the T-shirt main body, the sleeve and the splicing mouthful head and the tail phase of the T-shirt main body Connect, glue is spliced in the surface of the splicing mouth provided with ultra-toughness, splicing glue using ultra-toughness carries out clothes to sew up bonding, is traditional concept In it is impossible because traditional glue caking property and pliability can not all meet clothes degree of deformation height, it is necessary to be subjected to pullling The characteristic washed repeatedly.The present invention researches and develops obtained ultra-toughness splicing glue, can meet the above-mentioned characteristic of clothes, reach pliability Height, caking property is good, the effect of water resistance, and obtained T-shirt of the present invention is lightweight, and seamless synthetism is present, human body snugness of fit It is high.The seamless synthetism T-shirt of invention is pullled with 2000N pulling force, splicing mouth does not rupture, by the washing of 1500 times, splicing Mouth not degumming.
Brief description of the drawings
Fig. 1 is a kind of structural representation of seamless synthetism T-shirt of the present invention;
Reference is:1 --- T-shirt main body 2 --- sleeve 3 --- ultra-toughness splicing glue.
Embodiment
For the ease of the understanding of those skilled in the art, with reference to embodiment and accompanying drawing, 1 couple of present invention makees further Illustrate, the content that embodiment is referred to not limitation of the invention.
Embodiment 1
As shown in figure 1, a kind of seamless synthetism T-shirt, including T-shirt main body 1 and sleeve 2, the sleeve 2 splices in described The first half both sides of T-shirt main body 1, the sleeve 2 and the splicing mouthful of the T-shirt main body 1 are end to end, the splicing mouth Glue 3 is spliced in surface provided with ultra-toughness, and the ultra-toughness splicing glue 3 is made up of the raw material of following parts by weight:
30 parts of aliphatic dihydroxy alcohol
15 parts of aliphatic polyamine class curing agent
4 parts of hydrophilic chain extender
25 parts of aromatic isocyanate
0.5 part of catalyst
50 parts of pentalyn
3 parts of lactone compound
1 part of silane coupler
0.2 part of antioxidant
2 parts of nertralizer.
The hydrophilic chain extender is that ethylene oxide glycol is 2 according to weight ratio with amino acid:1 mixture.
The catalyst is triethylenediamine.
The nertralizer is that trifluoroacetic acid is 1 according to weight ratio with acetic acid:1 mixture.
The aromatic isocyanate is 2,4 toluene diisocyanate, 4,4 ' -- methyl diphenylene diisocyanate, six Methylene diisocyanate is 3 according to weight ratio:5:2 mixture.
The lactone compound is butyrolactone.
The antioxidant is antioxidant 245.
The preparation method of the ultra-toughness splicing glue 3 is as follows:
(1)By aliphatic dihydroxy alcohol, hydrophilic chain extender, aromatic isocyanate, catalyst, pentalyn, interior Ester compounds are added in reaction vessel, are uniformly mixed, in a nitrogen environment reflux condensation mode reaction 15h, and temperature is 60 DEG C;
(2)Toward step(1)Add nertralizer stirring 5min;
(3)Silane coupler, antioxidant are added in reaction vessel, 5h is reacted in a nitrogen environment, temperature control exists 60 DEG C, vacuum distillation obtains viscoelastic polyurethane latex solution;
(4)Aliphatic polyamine class curing agent is added in viscoelastic polyurethane latex solution and is well mixed, is coated on base material solid Change is dried to obtain ultra-toughness splicing glue 3.
The base material is purified cotton cloth base material, and the viscoelastic polyurethane latex solution is coated on the table of the purified cotton cloth base material Face, dried viscoelastic polyurethane latex solution surface prepares one layer of strippable release protective layer.
The purified cotton cloth base material is formed by the warp and weft braiding of Quality Pure Cotton Yarn Production, and the warp is 3.9tex long-staple cotton, The parallel is 4.2tex long-staple cotton.
Embodiment 2
As shown in figure 1, a kind of seamless synthetism T-shirt, including T-shirt main body 1 and sleeve 2, the sleeve 2 splices in described The first half both sides of T-shirt main body 1, the sleeve 2 and the splicing mouthful of the T-shirt main body 1 are end to end, the splicing mouth Glue 3 is spliced in surface provided with ultra-toughness, and the ultra-toughness splicing glue 3 is made up of the raw material of following parts by weight:
40 parts of aliphatic dihydroxy alcohol
20 parts of aliphatic polyamine class curing agent
6 parts of hydrophilic chain extender
35 parts of aromatic isocyanate
1 part of catalyst
55 parts of pentalyn
5 parts of lactone compound
2 parts of silane coupler
0.4 part of antioxidant
6 parts of nertralizer.
The hydrophilic chain extender is that ethylene oxide glycol is 2 according to weight ratio with amino acid:1 mixture.
The catalyst is triethylenediamine.
The nertralizer is that trifluoroacetic acid is 1 according to weight ratio with acetic acid:1 mixture.
The aromatic isocyanate is 2,4 toluene diisocyanate, 4,4 ' -- methyl diphenylene diisocyanate, six Methylene diisocyanate is 3 according to weight ratio:5:2 mixture.
The lactone compound is butyrolactone.
The antioxidant is antioxidant 245.
The preparation method of the ultra-toughness splicing glue 3 is as follows:
(1)By aliphatic dihydroxy alcohol, hydrophilic chain extender, aromatic isocyanate, catalyst, pentalyn, interior Ester compounds are added in reaction vessel, are uniformly mixed, in a nitrogen environment reflux condensation mode reaction 20h, and temperature is 70 DEG C;
(2)Toward step(1)Add nertralizer stirring 10min;
(3)Silane coupler, antioxidant are added in reaction vessel, 7h is reacted in a nitrogen environment, temperature control exists 65 DEG C, vacuum distillation obtains viscoelastic polyurethane latex solution;
(4)Aliphatic polyamine class curing agent is added in viscoelastic polyurethane latex solution and is well mixed, is coated on base material solid Change is dried to obtain ultra-toughness splicing glue 3.
The base material is purified cotton cloth base material, and the viscoelastic polyurethane latex solution is coated on the table of the purified cotton cloth base material Face, dried viscoelastic polyurethane latex solution surface prepares one layer of strippable release protective layer.
The purified cotton cloth base material is formed by the warp and weft braiding of Quality Pure Cotton Yarn Production, and the warp is 3.9tex long-staple cotton, The parallel is 4.2tex long-staple cotton.
Embodiment 3
As shown in figure 1, a kind of seamless synthetism T-shirt, including T-shirt main body 1 and sleeve 2, the sleeve 2 splices in described The first half both sides of T-shirt main body 1, the sleeve 2 and the splicing mouthful of the T-shirt main body 1 are end to end, the splicing mouth Glue 3 is spliced in surface provided with ultra-toughness, and the ultra-toughness splicing glue 3 is made up of the raw material of following parts by weight:
35 parts of aliphatic dihydroxy alcohol
18 parts of aliphatic polyamine class curing agent
5 parts of hydrophilic chain extender
28 parts of aromatic isocyanate
52 parts of pentalyn
4 parts of lactone compound
1.5 parts of silane coupler
0.3 part of antioxidant
4 parts of nertralizer.
The hydrophilic chain extender is that ethylene oxide glycol is 2 according to weight ratio with amino acid:1 mixture.
The catalyst is triethylenediamine.
The nertralizer is that trifluoroacetic acid is 1 according to weight ratio with acetic acid:1 mixture.
The aromatic isocyanate is 2,4 toluene diisocyanate, 4,4 ' -- methyl diphenylene diisocyanate, six Methylene diisocyanate is 3 according to weight ratio:5:2 mixture.
The lactone compound is butyrolactone.
The antioxidant is antioxidant 245.
The preparation method of the ultra-toughness splicing glue 3 is as follows:
(1)By aliphatic dihydroxy alcohol, hydrophilic chain extender, aromatic isocyanate, catalyst, pentalyn, interior Ester compounds are added in reaction vessel, are uniformly mixed, in a nitrogen environment reflux condensation mode reaction 18h, and temperature is 65 DEG C;
(2)Toward step(1)Add nertralizer stirring 8min;
(3)Silane coupler, antioxidant are added in reaction vessel, 6h is reacted in a nitrogen environment, temperature control exists 62 DEG C, vacuum distillation obtains viscoelastic polyurethane latex solution;
(4)Aliphatic polyamine class curing agent is added in viscoelastic polyurethane latex solution and is well mixed, is coated on base material solid Change is dried to obtain ultra-toughness splicing glue 3.
The base material is purified cotton cloth base material, and the viscoelastic polyurethane latex solution is coated on the table of the purified cotton cloth base material Face, dried viscoelastic polyurethane latex solution surface prepares one layer of strippable release protective layer.
The purified cotton cloth base material is formed by the warp and weft braiding of Quality Pure Cotton Yarn Production, and the warp is 3.9tex long-staple cotton, The parallel is 4.2tex long-staple cotton.
Embodiment 4
As shown in figure 1, a kind of seamless synthetism T-shirt, including T-shirt main body 1 and sleeve 2, the sleeve 2 splices in described The first half both sides of T-shirt main body 1, the sleeve 2 and the splicing mouthful of the T-shirt main body 1 are end to end, the splicing mouth Glue 3 is spliced in surface provided with ultra-toughness, and the ultra-toughness splicing glue 3 is made up of the raw material of following parts by weight:
30 parts of aliphatic dihydroxy alcohol
20 parts of aliphatic polyamine class curing agent
4 parts of hydrophilic chain extender
35 parts of aromatic isocyanate
0.5 part of catalyst
55 parts of pentalyn
3 parts of lactone compound
2 parts of silane coupler
0.2 part of antioxidant
6 parts of nertralizer.
The hydrophilic chain extender is that ethylene oxide glycol is 2 according to weight ratio with amino acid:1 mixture.
The catalyst is triethylenediamine.
The nertralizer is that trifluoroacetic acid is 1 according to weight ratio with acetic acid:1 mixture.
The aromatic isocyanate is 2,4 toluene diisocyanate, 4,4 ' -- methyl diphenylene diisocyanate, six Methylene diisocyanate is 3 according to weight ratio:5:2 mixture.
The lactone compound is butyrolactone.
The antioxidant is antioxidant 245.
The preparation method of the ultra-toughness splicing glue 3 is as follows:
(1)By aliphatic dihydroxy alcohol, hydrophilic chain extender, aromatic isocyanate, catalyst, pentalyn, interior Ester compounds are added in reaction vessel, are uniformly mixed, in a nitrogen environment reflux condensation mode reaction 15h, and temperature is 70 DEG C;
(2)Toward step(1)Add nertralizer stirring 5min;
(3)Silane coupler, antioxidant are added in reaction vessel, 7h is reacted in a nitrogen environment, temperature control exists 60 DEG C, vacuum distillation obtains viscoelastic polyurethane latex solution;
(4)Aliphatic polyamine class curing agent is added in viscoelastic polyurethane latex solution and is well mixed, is coated on base material solid Change is dried to obtain ultra-toughness splicing glue 3.
The base material is purified cotton cloth base material, and the viscoelastic polyurethane latex solution is coated on the table of the purified cotton cloth base material Face, dried viscoelastic polyurethane latex solution surface prepares one layer of strippable release protective layer.
The purified cotton cloth base material is formed by the warp and weft braiding of Quality Pure Cotton Yarn Production, and the warp is 3.9tex long-staple cotton, The parallel is 4.2tex long-staple cotton.
Performance test:The seamless synthetism T-shirt of invention is pullled with 2000N pulling force, splicing mouth does not rupture, by 1500 Secondary washing, splices mouth not degumming.
Above-described embodiment is the present invention preferably implementation, and in addition, the present invention can be realized with other manner, Any obvious replacement is within protection scope of the present invention on the premise of not departing from present inventive concept.

Claims (8)

1. a kind of seamless synthetism T-shirt, including T-shirt main body and sleeve, the sleeve splice in the upper half of the T-shirt main body Portion both sides, it is characterised in that:The sleeve and the splicing mouthful of the T-shirt main body are end to end, and the surface of the splicing mouth is set There is ultra-toughness to splice glue, the ultra-toughness splicing glue is made up of the raw material of following parts by weight:
30-40 parts of aliphatic dihydroxy alcohol
15-20 parts of aliphatic polyamine class curing agent
4-6 parts of hydrophilic chain extender
25-35 parts of aromatic isocyanate
0.5-1 parts of catalyst
50-55 parts of pentalyn
3-5 parts of lactone compound
1-2 parts of silane coupler
0.2-0.4 parts of antioxidant
2-6 parts of nertralizer;
The hydrophilic chain extender is that ethylene oxide glycol is 2 according to weight ratio with amino acid:The mixture of 1 mixing, the aromatic series Isocyanates is 2,4 toluene diisocyanate, 4,4 ' -- methyl diphenylene diisocyanate, hexamethylene diisocyanate are pressed It is 3 according to weight ratio:5:The mixture of 2 mixing.
2. a kind of seamless synthetism T-shirt according to claim 1, it is characterised in that:The catalyst is triethylene two Amine.
3. a kind of seamless synthetism T-shirt according to claim 1, it is characterised in that:The nertralizer be trifluoroacetic acid with Acetic acid is 1 according to weight ratio:The mixture of 1 mixing.
4. a kind of seamless synthetism T-shirt according to claim 1, it is characterised in that:The lactone compound is butyrolactone.
5. a kind of seamless synthetism T-shirt according to claim 1, it is characterised in that:The antioxidant is antioxidant 245。
6. a kind of seamless synthetism T-shirt according to claim any one of 1-5, it is characterised in that:The ultra-toughness splices glue Preparation method it is as follows:
(1)By aliphatic dihydroxy alcohol, hydrophilic chain extender, aromatic isocyanate, catalyst, pentalyn, lactonize Compound is added in reaction vessel, is uniformly mixed, in a nitrogen environment reflux condensation mode reaction 15-20h, and temperature is 60-70 DEG C;
(2)Toward step(1)Add nertralizer stirring 5-10min;
(3)Silane coupler, antioxidant are added in reaction vessel, 5-7h is reacted in a nitrogen environment, temperature control is in 60- 65 DEG C, vacuum distillation obtains viscoelastic polyurethane latex solution;
(4)Aliphatic polyamine class curing agent is added in viscoelastic polyurethane latex solution and is well mixed, is coated on to solidify on base material and does It is dry to obtain ultra-toughness splicing glue.
7. a kind of seamless synthetism T-shirt according to claim 6, it is characterised in that:The base material is purified cotton cloth base material, The viscoelastic polyurethane latex solution is coated on the surface of the purified cotton cloth base material, and dried viscoelastic polyurethane latex solution surface is formed One layer of strippable ultra-toughness splicing glue.
8. a kind of seamless synthetism T-shirt according to claim 7, it is characterised in that:The purified cotton cloth base material is by pure cotton The warp and weft braiding of yarn is formed, and the warp is 3.9tex long-staple cotton, and the parallel is 4.2tex long-staple cotton.
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US10669657B2 (en) * 2016-05-31 2020-06-02 Nike, Inc. Knit sleeve ribbing structure

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CN103013418B (en) * 2013-01-10 2014-04-30 中国科学院长春应用化学研究所 Waterborne polyurethane adhesive and preparation method thereof
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Address after: Kawaura Industrial Park C01-2-1 Haojiang District 515098 Guangdong city of Shantou province transfer

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