CN106146146B - Special foliar fertilizer for wheat - Google Patents

Special foliar fertilizer for wheat Download PDF

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Publication number
CN106146146B
CN106146146B CN201610498616.5A CN201610498616A CN106146146B CN 106146146 B CN106146146 B CN 106146146B CN 201610498616 A CN201610498616 A CN 201610498616A CN 106146146 B CN106146146 B CN 106146146B
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fertilizer
wheat
foliar fertilizer
foliar
liter
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CN106146146A (en
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王振林
李勇
尹燕枰
慕熙军
陈金
王元元
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Shandong Agricultural University
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Shandong Agricultural University
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses a foliar fertilizer special for wheat, in particular to a foliar fertilizer product special for wheat suitable for spraying in the jointing stage and the booting stage.

Description

Special foliar fertilizer for wheat
Technical Field
The invention relates to the technical field of agricultural fertilizers, and relates to a special foliar fertilizer for wheat, in particular to a special foliar fertilizer for wheat, which is suitable for spraying in the jointing stage and the booting stage.
Background
Chemical fertilizers are important agricultural production materials, and are 'grains' of grain crops. For years, chemical fertilizers play irreplaceable roles in promoting food yield increase and agricultural development in China, but the problems of excessive application, blind application and the like of the chemical fertilizers exist at present, particularly the traditional soil fertilization mode seriously damages soil and causes great pollution to the environment. At present, the harm of applying the fertilizer to soil for a long time appears, such as soil hardening, the capability of soil for keeping moisture and nutrients is deteriorated, the utilization rate of the fertilizer is reduced, and the root growth of crops is influenced. The excessive use of the fertilizer increases the agricultural production cost and obviously reduces the income.
The absorption of nutrients by plants is mainly through two pathways, namely roots and leaves. The crops mainly supply nutrition in soil or nutrient solution to plants through root absorption for growth and development. Besides the root system, the crop can also absorb nutrients through stems and leaves (especially leaves). The phenomenon that the non-root system absorbs nutrition during the growth period of crops is the nutrition outside the roots of the crops, and the measure of applying the fertilizer to the surface of the nutrient body except the roots of the crops is called as the fertilizer application outside the roots, namely the so-called foliar fertilizer application. Fertilizers for foliar application are referred to as foliar fertilizers. It is divided into material nutrient foliar fertilizer and functional nutrient foliar fertilizer. The material nutrient foliar fertilizer is a foliar fertilizer for providing trace elements and hormones, and the functional nutrient foliar fertilizer is a foliar fertilizer for providing vital nutrients for crops. The phenomenon that the fertilizer is fixed by soil and is difficult to be absorbed by plants can be avoided by applying certain fertilizers such as phosphorus, iron, manganese, copper, zinc and the like to the leaf surfaces. Compare traditional fertilization mode, the foliar fertilization has following advantage: (1) the fertilizer has quick effect, and the nutrients can be quickly absorbed by the leaves of the crops by the foliar fertilization and directly enter the plants from the leaves to participate in the metabolism of the crops; (2) the fertilizer efficiency is high, the foliar fertilization is not limited by soil conditions and the root system conditions of crops, and the fertilizer efficiency is fully exerted; (3) the cost is low, the fertilizer consumption is less, the cost is low, the application is convenient, and the labor cost is reduced; (4) the soil pollution is reduced, and the damage and pollution to the soil caused by long-term use of the fertilizer are reduced. Due to the advantages of the foliar fertilizer, the market of the foliar fertilizer in China develops rapidly in recent years.
Although the market of the foliar fertilizer develops rapidly, the quality of the products sold in the market is different, and the problems that (1) the specificity of the products is not strong, the application range of various products is wide, but the effects of different crops are different, and the products with good effect and strong specificity aiming at specific crops are lacked; (2) the nutrition is not comprehensive, the variety and the quantity of the nutrients provided by foliar fertilization are limited, and the requirements of all crops cannot be met; (3) the fertilizer efficiency is poor, and particularly, the absorption efficiency of trace elements such as boron, manganese, molybdenum, zinc and the like is not ideal; (4) the adhesion force of the leaves is poor, most of leaf fertilizers are easy to drip from the leaves, the retention time on the surfaces of the leaves is short, and partial nutrient loss is caused; (5) the fertilizer efficiency is short, most of the foliar fertilizers have quick effect but the fertilizer efficiency maintenance time is short.
Disclosure of Invention
Aiming at various defects in the prior art, the invention provides a foliar fertilizer special for wheat, in particular to a foliar fertilizer product special for wheat suitable for spraying in the jointing stage and the booting stage.
The technical scheme adopted by the invention is as follows:
the foliar fertilizer special for wheat contains the following main active ingredients per liter:
15-25 g of ammonium molybdate, 15-25 g of boric acid, 30-50 g of fulvic acid chelated zinc, 30-50 g of citric acid chelated manganese, 40-60 g of monopotassium phosphate, 75-125 g of urea, 0-0.2 g of compound sodium nitrophenolate, 0.2-0.6 g of diethyl aminoethyl hexanoate, 10-15 g of polyaspartic acid, 20-30 g of proline and 0-1250 hundred million photosynthetic bacteria;
wherein the photosynthetic bacteria are selected from rhodopseudomonas capsulata or rhodopseudomonas palustris; among them, Rhodopseudomonas capsulata is preferably used;
the components are as follows:
the "zinc fulvate chelate" is also called "zinc fulvate", and in the present invention, "zinc fulvate chelate" and "zinc fulvate" are used interchangeably. The fulvic acid chelated zinc is formed by chelating fulvic acid and divalent zinc element, so that the absorption and utilization of zinc trace elements by plants can be improved, and the utilization rate of nutrients is improved; can also inhibit the growth of harmful bacteria and reduce the occurrence of soil-borne diseases. The fulvic acid chelated zinc is the main component of the trace element functional fertilizer.
The citric acid chelated manganese is a trace element nutrient, is widely used for economic crops of agriculture, forestry and the like, and can be applied to water soluble fertilizers, leaf fertilizers, plant nutrient regulators and chelated compound fertilizers. Characterized in that (1) manganese is related to chloroplast synthesis, has the functions of promoting pollen germination and pollen tube elongation, promoting early seed maturation and improving seed setting rate, is a component of SOD enzyme for detoxifying superoxide radical in mitochondria and is a component of a plurality of enzymes in plants; (2) the citric acid fully chelates metal elements and organic active substances, and the chelating strength is moderate, so that the compatibility problem is effectively solved, the citric acid, metal ions and the organic active substances can be slowly released in crops, the slow release effect is obvious, and the absorption and utilization rate is high; (3) the content (> 16%) of the manganese metal element is higher than that of EDTA manganese, compared with the usage amount, the manganese metal element can be reduced by 25%, has high effective components and low molecular weight, is easier to absorb, and is an ideal substitute product for the EDTA manganese.
The potassium dihydrogen phosphate is used as high efficiency P-K compound fertilizer in agriculture, and is widely suitable for various types of industrial crops, grains, melons, fruits, vegetables and other crops. The monopotassium phosphate has a plurality of excellent effects of remarkably increasing production and income, improving and optimizing quality, resisting lodging, resisting diseases and insect pests, preventing and treating premature senility and the like, and has the effect of overcoming insufficient nutrition caused by the reduction of the aging and absorption capacity of the root system in the later growth stage of crops.
"Urea" is also known as carbamide (carbomide) and is an organic compound consisting of carbon, nitrogen, oxygen and hydrogen, also known as urea. Urea is one of the simplest organic compounds and is also the nitrogen fertilizer with the highest nitrogen content at present. As a neutral fertilizer, urea is suitable for various soils and plants. The urea substance has a softening effect on the cuticle of epidermal cells, and can accelerate the permeation of other nutrient substances, so that the urea becomes one of important components of the foliar fertilizer. Urea can promote cell division and growth, and make branches and leaves grow luxuriantly.
The 'compound sodium nitrophenolate' is a powerful cell activator, can be quickly permeated into a plant body after being contacted with the plant, promotes the protoplasm flow of the cell and improves the cell activity. The compound sodium nitrophenolate is also a broad-spectrum plant growth regulator, and can accelerate the growth and development of plants, promote roots and seedlings, protect flowers and fruits, improve yield, enhance stress resistance and the like. Can be used independently and can be used as a pesticide additive and a fertilizer additive; is used together with fertilizer, pesticide, feed, etc. The compound sodium nitrophenolate has certain limit requirements on temperature in the actual use process. The compound sodium nitrophenolate can only play a role rapidly at the temperature of more than 15 ℃. At higher temperature, the compound sodium nitrophenolate can well maintain the activity. The effect can be obtained within 48 hours at the temperature of more than 25 ℃, and can be obtained within 24 hours at the temperature of more than 30 ℃. Therefore, spraying compound sodium nitrophenolate at a higher temperature is beneficial to the exertion of the drug effect.
The compound sodium nitrophenolate is suitable for all crops, is suitable for all fertilizers (leaf fertilizer, compound fertilizer, flush fertilizer base fertilizer, base fertilizer and the like), and is suitable for any time. The following advantages are also provided: (1) the plants are promoted to absorb various nutrient components at the same time, and the antagonism between fertilizers is relieved; (2) the vitality of the plant is enhanced, the fertilizer requirement and the desire of the plant are promoted, and the decline of the plant is resisted; (3) the pH barrier effect is decomposed, the pH value is changed, the plants are changed into inorganic fertilizers into organic fertilizers under the appropriate acid-base condition, the inorganic fertilizer is overcome, and the plants are favored to absorb the organic fertilizers; (4) the penetration, adhesion and spreading force of the fertilizer are increased, the self limitation of the plant is broken, and the capability of the fertilizer entering the plant body is enhanced; (5) increase the utilization rate of the fertilizer by the plants, stimulate the plants not to put the fertilizer any more.
The chemical name of diethyl aminoethyl hexanoate is diethylaminoethanol caproate, which is a broad-spectrum high-energy plant growth regulator. It can increase the activity of plant peroxidase and nitrate reductase, increase chlorophyll content, accelerate photosynthesis, promote division and elongation of plant cell, promote root growth and regulate nutrient balance in vivo. The diethyl aminoethyl hexanoate is suitable for all plants and the whole growth period, and after the diethyl aminoethyl hexanoate is applied for 2-3 days, leaves obviously grow and thicken, the growth vigor is vigorous, the plants are thick, and the stress resistance of disease and insect pest resistance and the like is greatly improved. The diethyl aminoethyl hexanoate has a slow release effect, can be quickly absorbed and stored by plants, one part of diethyl aminoethyl hexanoate quickly acts, the other part of diethyl aminoethyl hexanoate slowly and continuously acts, and the lasting period of the diethyl aminoethyl hexanoate reaches 30-40 days. The diethyl aminoethyl hexanoate can also improve photosynthesis, increase the absorption of nitrogen dioxide by plants and adjust the C/N ratio of the plants. The diethyl aminoethyl hexanoate can be directly mixed with N, P, K, Zn, B, Cu, Mn, Fe, Mo and the like for use and is very stable.
The polyaspartic acid is a water-soluble polymer of macromolecular amino acids, can effectively promote the absorption of plants on nutrient elements, reduce the agricultural production cost, improve the yield and the quality of crops, and reduce the pollution of surface water and underground water caused by fertilizer and pesticide loss; it can be used with pesticide and fertilizer, and can raise the utilization rate of pesticide and fertilizer and raise fertilizer competitiveness. Research and application effects at home and abroad show that the polyaspartic acid is matched with a fertilizer for use, and the polyaspartic acid has the main characteristics that: (1) the loss of the fertilizer is reduced, nutrient elements are activated, and the utilization rate of the fertilizer is improved, so that the using amount of the fertilizer is reduced by 30 percent, and the yield is increased by 10 to 30 percent; (2) promoting the absorption of crops on trace elements such as iron, zinc, manganese and the like; (3) promoting the crops to be precocious for 7-10 days, and prolonging the harvesting period for 10-15 days; (4) promote root growth and enhance stress resistance.
"proline" is one of the components of plant proteins and can be widely present in plants in the free state. Under the stress conditions of drought, salt and the like, proline in a plurality of plants is accumulated in a large amount. Besides being used as an osmotic adjusting substance in plant cytoplasm, the accumulated proline plays an important role in stabilizing the biomacromolecule structure, reducing the cell acidity, relieving the ammonia toxicity, adjusting the cell redox potential as an energy bank and the like.
"Photosynthetic Bacteria (PSB for short)" are the earliest prokaryotes that appear on earth and are ubiquitous in nature and have an original light energy synthesis system, are a generic name for Bacteria that perform anaerobic photosynthesis under anaerobic conditions, are gram-negative Bacteria that do not have the ability to form spores, and are microorganisms that use light as an energy source and can perform photosynthesis using organic matter, sulfides, ammonia and the like in nature as a hydrogen donor and carbon source under anaerobic illumination or aerobic dark conditions. Photosynthetic bacteria can perform photosynthesis in an environment with illumination and oxygen deficiency, perform photosynthesis by utilizing light energy, assimilate carbon dioxide or other organic matters to decompose organic matters by utilizing light energy, and can fix molecular nitrogen in air to generate ammonia. In the invention, the photosynthetic bacteria are placed in a shade place for storage and use, and the photosynthetic bacteria can be directly added into powder for use.
The special foliar fertilizer for wheat provided by the invention has comprehensive nutrition, and ammonium molybdate, boric acid, fulvic acid chelated zinc and citric acid chelated manganese provide trace elements, wherein chelated zinc and manganese are more stable and easy to absorb. Potassium dihydrogen phosphate and urea provide macroelements, and the urea also has the function of promoting the absorption of the cuticle of the leaf, the compound sodium nitrophenolate and diethyl aminoethyl hexanoate are growth regulators, the polyaspartic acid is a fertilizer synergist, the proline belongs to amino acid nutrient components, and the photosynthetic bacteria can promote photosynthesis.
In particular, the chelated zinc and manganese are used for replacing common zinc sulfate and manganese sulfate, so that the stability of trace elements is improved, the absorption is facilitated, and the antagonism among different components is avoided;
as the foliar fertilizer is sprayed on the leaf surface, the dosage of urea and monopotassium phosphate cannot exceed the specified upper limit value, otherwise, the seedling burning can be caused; the used growth regulator is also strictly controlled according to the concentration, and the blade is damaged due to overlarge concentration; if the concentration is too low, the due effect cannot be achieved; in addition, other components can be randomly adjusted according to specific use conditions;
further, the inventors provide the following optimum ratios:
each liter contains the following components by weight: 20 g of ammonium molybdate, 20 g of boric acid, 40 g of zinc fulvate chelate, 40 g of manganese citrate chelate, 50 g of monopotassium phosphate, 100 g of urea, 0.1 g of compound sodium nitrophenolate, 0.25 g of diethyl aminoethyl hexanoate, 12.5 g of polyaspartic acid, 25 g of proline and 1000 hundred million photosynthetic bacteria;
aiming at the period and the area with the air temperature lower than 20 ℃, the leaf fertilizer provided by the invention has the following formula:
20 g of ammonium molybdate, 20 g of boric acid, 40 g of fulvic acid chelated zinc, 40 g of citric acid chelated manganese, 50 g of monopotassium phosphate, 100 g of urea, 0.5 g of diethyl aminoethyl hexanoate, 12.5 g of polyaspartic acid and 25 g of proline;
the two formulas are provided by the inventor, and the main reason is that the compound sodium nitrophenolate/photosynthetic bacteria have slow effect at low temperature and are difficult to achieve the expected effect, and the amine fresh fat does not affect the effect at low temperature, so the inventor adjusts the formula aiming at the period and the area with the temperature lower than 20 ℃ and increases the dosage of the amine fresh fat, thereby the compound sodium nitrophenolate/photosynthetic bacteria can better play the role of a plant growth promoter/fertilizer synergist.
The invention also provides a preparation method of the special foliar fertilizer for wheat, which comprises the following steps:
the preparation method of the concentrated solution comprises the following steps:
accurately weighing each component according to the formula amount, then adding clear water with the temperature of 45-50 ℃ and the half water consumption, and stirring for 10-20 minutes at 180-200 rpm; adding photosynthetic bacteria after all the components are dissolved, continuously stirring for 5 minutes, and then using normal-temperature clear water to fix the volume to 1 liter.
Besides the concentrated solution, the powder can be prepared by the following specific preparation steps: accurately weighing the components according to the formula and mixing uniformly to obtain the finished product.
The special foliar fertilizer for wheat provided by the invention is suitable for the jointing stage and the booting stage of wheat, and when the foliar fertilizer is used, 50 kilograms of water is added to each liter of special foliar fertilizer for wheat, and one mu of wheat can be sprayed; the spraying is preferably carried out in windless cloudy days or 4 pm in fine days, particularly in the evening, and nutrients can be fully absorbed by the leaves after one night. After the fertilizer is sprayed, if the rain falls, the fertilizer should be sprayed once after sunny days.
The special foliar fertilizer for wheat provided by the invention is scientifically prepared according to the physiological characteristics and nutritional requirements of winter wheat. The formula highlights the nutrient elements which are large in wheat demand but relatively deficient, and other large and medium trace nutrient elements are compounded at the same time, so that the nutrient requirements of winter wheat in different growth periods can be met; the chelated microelements are added into the product, so that the product has high stability, is easy to absorb and does not burn seedlings; photosynthetic bacteria can be added to promote photosynthesis; by using the novel adsorbent and the spreading agent, the retention time of the foliar fertilizer on the surface of the leaf can be prolonged, the nutrient absorption efficiency is improved, the efficient absorption of the effective components of the foliar fertilizer is promoted, and the fertilizer efficiency is ensured; the fertilizer efficiency is more durable by adding the high-efficiency plant growth regulator with the slow release effect.
In conclusion, the special foliar fertilizer for wheat provided by the invention has the characteristics of comprehensive nutrient components, high and lasting fertilizer efficiency, low cost and no residue. In wheat planting, the specific functions of the method are as follows: (1) the foliar fertilizer improves the physiological activity of wheat, enhances photosynthesis, promotes good growth of wheat, improves the ear number per mu, the grain number per ear and the thousand grain weight of the wheat, and obviously improves economic benefits; (2) the utilization rate of the fertilizer is improved, and the using amount of the fertilizer is reduced; contains various nutrient elements and can replace the wheat topdressing; (3) improving the drought resistance and lodging resistance of wheat; (4) improving disease resistance of wheat and reducing pesticide consumption.
Detailed Description
The present invention is further described below in conjunction with examples which will allow those skilled in the art to more fully understand the present invention, but which are not intended to limit the invention in any way.
Example 1:
a foliar fertilizer special for wheat, the formula and preparation method thereof are:
accurately weighing 200 g of ammonium molybdate, 200 g of boric acid, 400 g of fulvic acid chelated zinc, 400 g of citric acid chelated manganese, 500 g of monopotassium phosphate, 1000 g of urea, 1 g of compound sodium nitrophenolate, 2.5 g of diethyl aminoethyl hexanoate, 125 g of polyaspartic acid and 250 g of proline; adding a proper amount of clear water at 45-50 ℃, and stirring at 180-200 rpm for 10-20 minutes; 10000 hundred million photosynthetic bacteria are added and the volume is fixed to 10L.
Effect experiment:
1 liter and 0.5 liter are respectively taken, 50 kilograms of water is added, 1 mu of wheat land is sprayed in windless cloudy days or 5 pm in sunny days in the booting period of wheat, the upper surface and the lower surface of the leaves are uniformly sprayed, the effect can be obviously seen in 2-3 days after spraying, the yield of the wheat can be respectively increased by 11.1-17.2 percent and 5.8-7.6 percent under the condition of comprehensive test, 1 liter and 0.5 liter of the product of the invention are respectively applied to each mu of wheat, and the yield increasing effect is obvious.
Example 2:
a foliar fertilizer special for wheat, the formula and preparation method thereof are:
accurately weighing 200 g of ammonium molybdate, 200 g of boric acid, 400 g of fulvic acid chelated zinc, 400 g of citric acid chelated manganese, 500 g of monopotassium phosphate, 1000 g of urea, 5 g of diethyl aminoethyl hexanoate, 125 g of polyaspartic acid and 250 g of proline; adding a proper amount of clear water at 45-50 ℃, stirring at 180-200 rpm for 10-20 minutes, and fixing the volume to 10L;
effect experiment:
1 liter and 0.5 liter are respectively taken, 50 kilograms of water is added, 1 mu of wheat land is sprayed in windless cloudy days or 5 pm in fine days in the wheat jointing stage, the upper surface and the lower surface of the leaf are uniformly sprayed, the effect can be obviously seen in 2-3 days after spraying, the yield of the wheat can be respectively increased by 10.2-15.1 percent and 4.1-5.6 percent under the condition of comprehensive test, 1 liter and 0.5 liter of the product of the invention are respectively applied to each mu of wheat, and the yield increasing effect is obvious. Especially, the use effect is better than that of adding photosynthetic bacteria in the period and the region with the air temperature lower than 20 ℃.
Example 3:
a foliar fertilizer special for wheat, the formula and preparation method thereof are:
accurately weighing 150 g of ammonium molybdate, 150 g of boric acid, 300 g of fulvic acid chelated zinc, 400 g of citric acid chelated manganese, 600 g of monopotassium phosphate, 1250 g of urea, 2 g of compound sodium nitrophenolate, 2 g of diethyl aminoethyl hexanoate, 150 g of polyaspartic acid and 200 g of proline; adding a proper amount of clear water at 45-50 ℃, and stirring at 180-200 rpm for 10-20 minutes; adding 5000 hundred million photosynthetic bacteria, and fixing the volume to 10L.
Effect experiment:
1 liter and 0.5 liter are respectively taken, 50 kilograms of water is added, 1 mu of wheat land is sprayed in windless cloudy days or 5 pm in sunny days in the booting period of wheat, the upper surface and the lower surface of the leaves are uniformly sprayed, the effect can be obviously seen in 2-3 days after spraying, the yield of the wheat can be respectively improved by 9.7-11.2 percent and 3.3-4.7 percent under the condition of comprehensive test, 1 liter and 0.5 liter of the product of the invention are respectively applied to each mu of wheat, and the yield increasing effect is obvious.
Example 4:
a foliar fertilizer special for wheat, the formula and preparation method thereof are:
accurately weighing 250 g of ammonium molybdate, 250 g of boric acid, 500 g of fulvic acid chelated zinc, 500 g of citric acid chelated manganese, 300 g of monopotassium phosphate, 750 g of urea, 5 g of diethyl aminoethyl hexanoate, 100 g of polyaspartic acid and 200 g of proline; adding a proper amount of clear water at 45-50 ℃, and stirring at 180-200 rpm for 10-20 minutes; 12500 hundred million photosynthetic bacteria were added and the volume was kept to 10L.
Effect experiment:
1 liter and 0.5 liter are respectively taken, 50 kilograms of water is added, 1 mu of wheat land is sprayed in windless cloudy days or 5 pm in fine days in the wheat jointing stage, the upper surface and the lower surface of the leaf are uniformly sprayed, the effect can be obviously seen in 2-3 days after spraying, the yield of the wheat can be respectively improved by 9.6-12.2 percent and 4.8-6.1 percent under the condition of comprehensive test, 1 liter and 0.5 liter of the product of the invention are respectively applied to each mu of wheat, and the yield increasing effect is obvious.

Claims (1)

1. A foliar fertilizer special for wheat is characterized in that: each liter of the composition contains the following main active ingredients: 20 g of ammonium molybdate, 20 g of boric acid, 40 g of zinc fulvate chelate, 40 g of manganese citrate chelate, 50 g of monopotassium phosphate, 100 g of urea, 0.5 g of diethyl aminoethyl hexanoate, 12.5 g of polyaspartic acid and 25 g of proline.
CN201610498616.5A 2016-06-29 2016-06-29 Special foliar fertilizer for wheat Expired - Fee Related CN106146146B (en)

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CN107673839A (en) * 2017-10-20 2018-02-09 刘青亚 A kind of production method of poly-aspartate chelating rare earth foliar fertilizer
CN109836252A (en) * 2017-11-27 2019-06-04 丹阳市陵口镇城墅蔬菜专业合作社 A kind of jerusalem artichoke is dedicated to contain potassium foliage fertilizer
CN109836240A (en) * 2017-11-27 2019-06-04 丹阳市陵口镇城墅蔬菜专业合作社 A kind of dedicated nitrogenous foliar fertilizer of spinach
CN109836242A (en) * 2017-11-27 2019-06-04 丹阳市陵口镇城墅蔬菜专业合作社 A kind of dedicated nitrogenous foliar fertilizer of carrot
CN109836260A (en) * 2017-11-28 2019-06-04 丹阳市陵口镇城墅蔬菜专业合作社 A kind of dedicated phosphorous foliar fertilizer of winter squash
CN109836263A (en) * 2017-11-28 2019-06-04 丹阳市陵口镇城墅蔬菜专业合作社 A kind of dedicated phosphorous foliar fertilizer of asparagus lettuce
CN108083900A (en) * 2017-12-19 2018-05-29 深圳市芭田生态工程股份有限公司 A kind of foliar fertilizer and its method of administration
CN108147903A (en) * 2018-03-15 2018-06-12 辽宁省农业科学院 A kind of full nutrition foliage fertilizer and preparation method thereof
CN109180394A (en) * 2018-11-09 2019-01-11 中国农业科学院农业资源与农业区划研究所 A kind of granular urea preparation method containing alginic acid synergistic carrier suitable for winter wheat top dressing
CN111449078A (en) * 2020-04-10 2020-07-28 郑州博翔科技有限公司 Wheat accurate regulation and control method
CN114586494B (en) * 2021-12-08 2023-02-10 北京市农林科学院 Ecological restoration method for root zone soil of northern mountain orchard
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CN101973820A (en) * 2010-09-26 2011-02-16 王春雨 Foliar fertilizer and production method thereof
CN102992874A (en) * 2012-10-19 2013-03-27 田淦平 Soybean leaf fertilizer
CN105461462A (en) * 2016-01-12 2016-04-06 湖南泰谷生物科技股份有限公司 Wheat foliar fertilizer and application thereof

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