CN106085575A - 一种水基型金属切削液及其制备方法 - Google Patents
一种水基型金属切削液及其制备方法 Download PDFInfo
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- CN106085575A CN106085575A CN201610516662.3A CN201610516662A CN106085575A CN 106085575 A CN106085575 A CN 106085575A CN 201610516662 A CN201610516662 A CN 201610516662A CN 106085575 A CN106085575 A CN 106085575A
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Abstract
本发明公开了一种水基型金属切削液及其制备方法,包括以下重量份的原料:基础油15‑30份;乳化剂0.5‑20;防锈剂3‑20份;油酸2‑10份;活性组分0.5‑20份;水40‑50份;杀菌剂0.3‑0.5份;渗透剂1‑1.5份;消泡剂0.02‑0.1份,其制备方法包括:取基础油加热到50~60℃,加入乳化剂,继续加热到80℃,搅拌30min;升温到90℃,继续搅拌20min;加入活性组分,搅拌30min,加入油酸继续搅拌20min,降温到40℃;得到混合物,将混合物加入防锈剂、渗透剂和水的混合液中,并搅拌1h,然后加入杀菌剂、消泡剂,搅拌1~3h,得到水基型金属切削液。本发明的水基金属切削液组合物,由于含有新型活性组分苯并三氮唑衍生物,与乳化剂、润滑剂、消泡剂一同发挥作用,具有突出润滑性和抗硬水稳定性。
Description
技术领域
本发明涉及一种金属加工液,尤其是一种水基型金属切削液及其制备方法。
背景技术
切削液是一种重要的工业用液体,可以用于金属切削及金属加工过程中起到冷却、润滑和防止工件生锈的作用。一个优良品质的金属应该具有润滑、冷却、清洗以及环保、无毒等性能。现阶段新型切削液组分及配方仍然是科研的热点。如专利CN102268318B“水基切削液组合物及其制备方法”公开的切削液含有新合成的磷酸酯胺盐类活性组分,同时与基础油、乳化剂、防锈剂等组分共同作用得到抗硬水能力强的切削液。专利CN1002736324A“一种防锈切削液的制备方法”公开的切削液含有机械油、油酸、烯基丁二酸、表面活性剂、硼酸、混合醇胺等组分,具有成本低、性能佳、环保、低毒的优势。
发明内容
本发明的一个目的是解决至少上述问题和/或缺陷,并提供至少后面将说明的优点。
为了实现根据本发明的这些目的和其它优点,提供了一种水基型金属切削液,其特征在于,包括以下重量份的原料:基础油15-30份;乳化剂0.5-20份;防锈剂3-20份;油酸2-10份;活性组分0.5-20份;水40-50份;杀菌剂0.3-0.5份;渗透剂1-1.5份;消泡剂0.02-0.1份。
优选的是,所述基础油为石蜡基基础油、环烷基基础油、合成基础油中的任意一种;
所述乳化剂为油酸二乙醇酰胺、烷基醇酰胺磷酸酯、C5-C25的脂肪醇聚氧乙烯醚中的任意一种;
所述防锈剂为柠檬酸、硼酸盐、醇胺、苯甲酸钠、钼酸铵、尿素中的一种或几种的组合;
所述油酸为蓖麻醇酸、棕榈油酸、油酸、亚麻油酸、妥尔油酸中的一种或几种的组合;
所述杀菌剂为含均三嗪类、异噻唑啉酮、苯氧醇类、吗啉的化学组分中的一种;
所述渗透剂为丙二醇丁醚、乙二醇丁醚、二乙二醇***中的任意一种;
所述消泡剂为聚醚类消泡剂、乳化硅油、磷酸酯中的任意一种;
所述活性组分为苯并三氮唑衍生物的分子式为:
其中,X为CH3(CH2)16COO(CH2CH2O)n-、CH3(CH2)10COO(CH2CH2O)n-、CH3(CH2)7CH=CH(CH2)7COO(CH2CH2O)n-中的一种,所述n=1-10。
本发明还提供一种上述的水基型金属切削液的制备方法,其特征在于,包括:取基础油加热到50~60℃,加入乳化剂,继续加热到80℃,搅拌30min;升温到90℃,继续搅拌20min;加入活性组分,搅拌30min,加入油酸继续搅拌20min,降温到40℃;得到混合物,将混合物加入防锈剂、渗透剂和水的混合液中,并搅拌1h,然后加入杀菌剂、消泡剂,搅拌1~3h,得到水基型金属切削液;
优选的是,水基型金属切削液的成分还包括:分散剂0.1-0.5份;极压抗磨剂0.05-0.1份;发酵液1~3份;防沉淀剂1~3份;
所述分散剂为1-乙基-3-甲基咪唑乙酸盐、氯化1-丁基-3-甲基咪唑、1-丁基-3-甲基咪唑四氟硼酸盐、1-己基-3-甲基咪唑硝酸盐、溴化1-乙基-3-甲基咪唑中的任意一种。
所述极压抗磨剂为偏硼酸钠、偏硼酸钾和三硼酸钾中的一种;
所述防沉淀剂为十二烷基苯磺酸钠、季铵盐高分子共聚物、阴离子羧酸共聚体、非离子聚氨酯类中的一种。
优选的是,所述防锈剂包括以下重量份的原料:肌醇六磷酸酯40-60份、1-羟基苯并***20~25份、丁基羟基茴香醚6~8份、多元醇5~8份、三聚氰胺1~3份、聚天冬氨酸1~3份、脂肪酸烷醇酰胺5~10份、草酸1~5份、壳聚糖5~10份、水50~80份。
优选的是,所述消泡剂包括以下重量份的原料:聚丙二醇硬脂酸钠20~30份、异丙醇6~8份、环氧氯丙烷5~8份、液体石蜡10~20份、二硬脂酰乙二胺10~15份、氯化钙5~8份、羟甲基纤维素钠3~5份、碘化钾1~3份、卵磷脂1~3份、氯化铁1~3份、水20~30份。
本发明还提供一种上述的水基型金属切削液的制备方法,包括:取基础油加热到50~60℃,加入乳化剂,继续加热到80℃,搅拌30min;升温到90℃,边搅拌边加入防沉淀剂,继续搅拌20min;加入活性组分,搅拌30min,加入油酸继续搅拌20min,降温到40℃;得到混合物,将混合物加入防锈剂、渗透剂、分散剂、发酵液和水的混合液中,并搅拌1h,然后加入杀菌剂、消泡剂、极压抗磨剂,搅拌1~3h,得到水基型金属切削液。
优选的是,所述活性组分为苯并三氮唑衍生物,其分子式为:
其中,X为CH3(CH2)16COO(CH2CH2O)n-、CH3(CH2)10COO(CH2CH2O)n-、CH3(CH2)7CH=CH(CH2)7COO(CH2CH2O)n-中的一种,所述n=1-10;
所述活性组分的制备方法为:按重量份,将15~20份5-羧基苯并三氮唑溶于80~120份溶剂中,边搅拌边加热温度控制在50-60℃,待溶解均匀后,加入40~60份聚合度n=1-10的聚乙二醇单硬脂酸脂、聚乙二醇单油酸酯或聚乙二醇单月桂酸脂中的一种,再加入1.5~2份的对甲苯磺酸,升温至回流,维持反应1~3小时,待分水器中无水生成时,减压蒸馏除去溶剂得到活性组分。
优选的是,所述发酵液的的制备方法为:按重量份,取淀粉30~50份、魔芋粉20~30份、糖蜜5~10份、甘蔗渣5~10份、褐藻多糖3~5份、钼酸铵5~8份、硒酸钠3~5份、水50~80份,加入发酵罐搅拌均匀;然后采用紫外线对发酵罐中的发酵料液进行杀菌处理,紫外杀菌完成后加入发酵剂6~8份,并搅拌均匀,然后进行第一阶段发酵,发酵罐温度保持在22~25℃,第一阶段发酵的过程中每天密闭搅拌10-15min,不开罐放气,持续2~3天,然后进行第二阶段发酵,发酵罐温度保持在26~30℃,第二阶段发酵的过程中每天打开发酵罐进行放气,并同时搅拌5~8min,持续8~10天,完成发酵,然后过滤,去除滤渣,得到发酵液;所述紫外线的波长为180-280nm,紫外杀菌时间为25~30min;
优选的是,所述发酵剂由以下重量份的种子液混合而成:双歧杆菌15~20份、戊糖乳杆菌6~10份、产朊假丝酵母5~10份、白浅色链霉菌10~18份、里氏木霉15~20份、放线菌20~25份。
本发明得到的水基型金属切削液的pH为6.5-8,水基型金属切削液的使用温度为5-50℃。
本发明至少包括以下有益效果:本发明的水基金属切削液组合物,由于含有新型活性组分苯并三氮唑衍生物,与乳化剂、润滑剂、消泡剂一同发挥作用,具有突出润滑性和抗硬水稳定性,同时通过化学合成法将防锈剂与乳化剂的有效基团结合到一个分子中,使一个组分同时兼具乳化和防锈的作用。通过筛选最佳组分,得到性能优良、成本低、环保的水基型切削液,其能够显著提高切削液的稳定性,说明其具有较好的乳化能力,工件锈蚀程度明显减轻,说明有很好的防锈能力,明显减少工件的磨损,说明器具有较好的润滑性。同时该切削液还具有防止工件氧化、对人体危害小、不易变质、降低加工噪音等优点。
本发明的其它优点、目标和特征将部分通过下面的说明体现,部分还将通过对本发明的研究和实践而为本领域的技术人员所理解。
具体实施方式:
下面结合实施例对本发明做进一步的详细说明,以令本领域技术人员参照说明书文字能够据以实施。
应当理解,本文所使用的诸如“具有”、“包含”以及“包括”术语并不配出一个或多个其它元件或其组合的存在或添加。
实施例1:
一种水基型金属切削液,包括以下原料:基础油28g;乳化剂2.5g;防锈剂4g;油酸4.5g;活性组分5g;水54.48g;杀菌剂0.5g;渗透剂1g;消泡剂0.02g;
所述的水基型金属切削液的制备方法,包括:取基础油加热到60℃,加入乳化剂,继续加热到80℃,搅拌30min;升温到90℃,继续搅拌20min;加入活性组分,搅拌30min,加入油酸继续搅拌20min,降温到40℃;得到混合物,将混合物加入防锈剂、渗透剂和水的混合液中,并搅拌1h,然后加入杀菌剂、消泡剂,搅拌1h,得到水基型金属切削液;
所述基础油150SN基础油;所述乳化剂为AEO-30;所述防锈剂为2g的苯甲酸钠和2g的三乙醇胺混合而成;所述油酸为棕榈油酸OL-7519;所述杀菌剂为0.2g的三嗪和0.3g的吗啉混合而成;所述渗透剂为丙二醇丁醚;所述消泡剂为乳化硅油;
所述活性组分的制备方法为:将5-羧基苯并三氮唑16.31g(163.14)溶于100mL甲苯中,边搅拌边加热温度控制在50-60℃,待溶解均匀后,加入52gEGMS(乙二醇单硬脂酸脂),再加入0.01mol对甲苯磺酸,升温至回流,维持反应1小时,待分水器中无水生成时,减压蒸馏除去溶剂得到活性组分。
实施例2:
一种水基型金属切削液,包括以下原料:基础油29g;乳化剂3.2g;防锈剂6g;油酸4.7g;活性组分6g;水49.68g;杀菌剂0.5g;渗透剂1g;消泡剂0.02g;
所述的水基型金属切削液的制备方法,包括:取基础油加热到60℃,加入乳化剂,继续加热到80℃,搅拌30min;升温到90℃,继续搅拌20min;加入活性组分,搅拌30min,加入油酸继续搅拌20min,降温到40℃;得到混合物,将混合物加入防锈剂、渗透剂和水的混合液中,并搅拌1h,然后加入杀菌剂、消泡剂,搅拌1h,得到水基型金属切削液;
所述基础油150SN基础油;所述乳化剂为AEO-30;所述防锈剂为2g的苯甲酸钠和2g的三乙醇胺混合而成;所述油酸为棕榈油酸OL-7519;所述杀菌剂为0.2g的三嗪和0.3g的吗啉混合而成;所述渗透剂为丙二醇丁醚;所述消泡剂为乳化硅油;
所述活性组分的制备方法为:将5-羧基苯并三氮唑16.31g(163.14)溶于100mL甲苯中,边搅拌边加热温度控制在50℃,待溶解均匀后,加入52gDEGMS(二乙二醇单硬脂酸脂),再加入0.01mol对甲苯磺酸,升温至回流,维持反应1小时,待分水器中无水生成时,减压蒸馏除去溶剂得到活性组分。
实施例3:
一种水基型金属切削液,包括以下原料:基础油29g;乳化剂3.2g;防锈剂5g;油酸4.7g;活性组分5g;水51.58g;杀菌剂0.3g;渗透剂1.2g;消泡剂0.02g;
所述的水基型金属切削液的制备方法,包括:取基础油加热到60℃,加入乳化剂,继续加热到80℃,搅拌30min;升温到90℃,继续搅拌20min;加入活性组分,搅拌30min,加入油酸继续搅拌20min,降温到40℃;得到混合物,将混合物加入防锈剂、渗透剂和水的混合液中,并搅拌1h,然后加入杀菌剂、消泡剂,搅拌2h,得到水基型金属切削液;
所述基础油150N基础油;所述乳化剂为OP-4;所述防锈剂为2.5g的尿素和2.5g的硼酸盐混合而成;所述油酸为亚油酸TZSW;所述杀菌剂为0.1g的三嗪和0.2g的吗啉混合而成;所述渗透剂为丙二醇丁醚;所述消泡剂为乳化硅油;
所述活性组分的制备方法为:将5-羧基苯并三氮唑16.31g(163.14)溶于100mL甲苯中,边搅拌边加热温度控制在50℃,待溶解均匀后,加入52gPEG400ML(聚乙二醇400单硬脂酸脂),再加入0.01mol对甲苯磺酸,升温至回流,维持反应1小时,待分水器中无水生成时,减压蒸馏除去溶剂得到活性组分。
其中实施例1~3的活性组分制备的反应通式为:
实施例4:
一种水基型金属切削液,包括以下原料:基础油29g;乳化剂4.3g;防锈剂3.6g;油酸5.2g;活性组分7g;水49.27g;杀菌剂0.4g;渗透剂1.2g;消泡剂0.03g;
所述的水基型金属切削液的制备方法,包括:取基础油加热到60℃,加入乳化剂,继续加热到80℃,搅拌30min;升温到90℃,继续搅拌20min;加入活性组分,搅拌30min,加入油酸继续搅拌20min,降温到40℃;得到混合物,将混合物加入防锈剂、渗透剂和水的混合液中,并搅拌1h,然后加入杀菌剂、消泡剂,搅拌1h,得到水基型金属切削液;
所述基础油150N基础油;所述乳化剂为OP-4;所述防锈剂为1.8g的尿素和1.8g的硼酸盐混合而成;所述油酸为亚油酸TZSW;所述杀菌剂为三嗪;所述渗透剂为二乙二醇***;所述消泡剂为消泡王CX-170;
所述活性组分的制备方法为:将5-羧基苯并三氮唑16.31g(163.14)溶于150mL水,边搅拌边加热温度控制在50℃,待溶解均匀后,加入52gPEG400MO(聚乙二醇400单油酸脂),再加入0.01mol对甲苯磺酸,升温至回流,维持反应1小时,得到活性组分。
其中实施例4的活性组分制备的反应通式为:
实施例5:
一种水基型金属切削液,包括以下原料:基础油30g;乳化剂4.3g;防锈剂6.4g;油酸5.5g;活性组分5g;水47.07g;杀菌剂0.4g;渗透剂1.3g;消泡剂0.03g;
所述的水基型金属切削液的制备方法,包括:取基础油加热到60℃,加入乳化剂,继续加热到80℃,搅拌30min;升温到90℃,继续搅拌20min;加入活性组分,搅拌30min,加入油酸继续搅拌20min,降温到40℃;得到混合物,将混合物加入防锈剂、渗透剂和水的混合液中,并搅拌1h,然后加入杀菌剂、消泡剂,搅拌1h,得到水基型金属切削液;
所述基础油100SN基础油;所述乳化剂为MOA-3;所述防锈剂为3.2g的三乙醇胺和3.2g的硼酸盐混合而成;所述油酸为硬脂酸SN1801;所述杀菌剂为吗啉;所述渗透剂为二乙二醇***;所述消泡剂为消泡王CX-170;
所述活性组分的制备方法为:将5-羧基苯并三氮唑16.31g(163.14)溶于150mL水,边搅拌边加热温度控制在50℃,待溶解均匀后,加入52gPEG400ML(聚乙二醇400单月桂酸脂),再加入0.01mol对甲苯磺酸,升温至回流,维持反应1小时,得到活性组分。
实施例6:
一种水基型金属切削液,包括以下原料:基础油30g;乳化剂5.5g;防锈剂6g;油酸5.5g;活性组分4g;水47.37g;杀菌剂0.5g;渗透剂1.1g;消泡剂0.03g;
所述的水基型金属切削液的制备方法,包括:取基础油加热到60℃,加入乳化剂,继续加热到80℃,搅拌30min;升温到90℃,继续搅拌20min;加入活性组分,搅拌30min,加入油酸继续搅拌20min,降温到40℃;得到混合物,将混合物加入防锈剂、渗透剂和水的混合液中,并搅拌1h,然后加入杀菌剂、消泡剂,搅拌2h,得到水基型金属切削液;
所述基础油150DN基础油;所述乳化剂为MOA-3;所述防锈剂为3g的三乙醇胺和3g的硼酸盐混合而成;所述油酸为硬脂酸SN1801;所述杀菌剂为三嗪;所述渗透剂为二乙二醇***;所述消泡剂为消泡王CX-170;
所述活性组分的制备方法为:将5-羧基苯并三氮唑16.31g(163.14)溶于150mL水,边搅拌边加热温度控制在50℃,待溶解均匀后,加入52gPEG400ML(聚乙二醇400单月桂酸脂),再加入0.01mol对甲苯磺酸,升温至回流,维持反应1小时,得到活性组分。
其中实施例5~6的活性组分制备的反应通式为:
实施例7:
一种水基型金属切削液,包括以下原料:基础油30g;乳化剂2g;防锈剂12.2g;油酸3g;活性组分5g;水47.07g;杀菌剂0.5g;渗透剂1g;消泡剂0.05g;分散剂0.1g;挤压抗磨剂0.1g;发酵液1g;防沉淀剂1g;
所述的水基型金属切削液的制备方法,包括:取基础油加热到60℃,加入乳化剂,继续加热到80℃,搅拌30min;升温到90℃,边搅拌边加入防沉淀剂,继续搅拌20min;加入活性组分,搅拌30min,加入油酸继续搅拌20min,降温到40℃;得到混合物,将混合物加入防锈剂、渗透剂、分散剂、发酵液和水的混合液中,并搅拌1h,然后加入杀菌剂、消泡剂、极压抗磨剂,搅拌1~3h,得到水基型金属切削液。
所述基础油为100SN基础油;所述乳化剂为MOA-3;所述防锈剂为1.5g柠檬酸、8g硼砂、1.7g苯甲酸钠、1g钼酸铵混合而成;所述油酸为硬脂酸SN1801;所述杀菌剂为吗啉;所述渗透剂为二乙二醇***;所述消泡剂包括以下原料组成:聚丙二醇硬脂酸钠30g、异丙醇6g、环氧氯丙烷5g、液体石蜡10g、二硬脂酰乙二胺10g、氯化钙5g、羟甲基纤维素钠3g、碘化钾1g、卵磷脂1g、氯化铁1g、水20g;所述挤压抗磨剂为偏硼酸钠;所述防沉淀剂为十二烷基苯磺酸钠;所述分散剂为1-乙基-3-甲基咪唑乙酸盐。
所述发酵液的制备方法为:取淀粉30g、魔芋粉20g、糖蜜5g、甘蔗渣5g、褐藻多糖3g、钼酸铵5g、硒酸钠5g、水50g,加入发酵罐搅拌均匀;然后采用紫外线对发酵罐中的发酵料液进行杀菌处理,紫外杀菌完成后加入发酵剂6g,并搅拌均匀,然后进行第一阶段发酵,发酵罐温度保持在25℃,第一阶段发酵的过程中每天密闭搅拌10min,不开罐放气,持续2天,然后进行第二阶段发酵,发酵罐温度保持在30℃,第二阶段发酵的过程中每天打开发酵罐进行放气,并同时搅拌5min,持续8天,完成发酵,然后过滤,去除滤渣,得到发酵液;所述紫外线的波长为280nm,紫外杀菌时间为30min;所述发酵剂由以下种子液混合而成:双歧杆菌15g、戊糖乳杆菌6g、产朊假丝酵母5g、白浅色链霉菌10g、里氏木霉15g、放线菌20g。
所述活性组分的制备方法为:将5-羧基苯并三氮唑16.31g(163.14)溶于150mL水,边搅拌边加热温度控制在50℃,待溶解均匀后,加入52gPEG400ML(聚乙二醇200单月桂酸脂),再加入0.01mol对甲苯磺酸,升温至回流,维持反应1小时,得到活性组分。
实施例8:
一种水基型金属切削液,包括以下原料:基础油28g;乳化剂5g;防锈剂5g;油酸3g;活性组分5g;水47.07g;杀菌剂0.5g;渗透剂1g;消泡剂0.05g;分散剂0.4g;挤压抗磨剂0.08g;发酵液2g;防沉淀剂2g;
所述的水基型金属切削液的制备方法,包括:取基础油加热到60℃,加入乳化剂,继续加热到80℃,搅拌30min;升温到90℃,边搅拌边加入防沉淀剂,继续搅拌20min;加入活性组分,搅拌30min,加入油酸继续搅拌20min,降温到40℃;得到混合物,将混合物加入防锈剂、渗透剂、分散剂、发酵液和水的混合液中,并搅拌1h,然后加入杀菌剂、消泡剂、极压抗磨剂,搅拌1~3h,得到水基型金属切削液。
所述基础油为150SN基础油;所述乳化剂为AEO-30;所述防锈剂包括以下原料组成:肌醇六磷酸酯40g、1-羟基苯并***20g、丁基羟基茴香醚6g、多元醇5g、三聚氰胺1g、聚天冬氨酸1g、脂肪酸烷醇酰胺5g、草酸1g、壳聚糖5g、水50g;所述油酸为硬脂酸SN1801;所述杀菌剂为吗啉;所述渗透剂为二乙二醇***;所述消泡剂包括以下原料组成:聚丙二醇硬脂酸钠30g、异丙醇7g、环氧氯丙烷6g、液体石蜡15g、二硬脂酰乙二胺13g、氯化钙6g、羟甲基纤维素钠5g、碘化钾2g、卵磷脂2g、氯化铁2g、水20g;所述挤压抗磨剂为偏硼酸钠;所述防沉淀剂为十二烷基苯磺酸钠;所述分散剂为1-乙基-3-甲基咪唑乙酸盐。
所述发酵液的制备方法为:取淀粉50g、魔芋粉25g、糖蜜8g、甘蔗渣8g、褐藻多糖4g、钼酸铵8g、硒酸钠4g、水60g,加入发酵罐搅拌均匀;然后采用紫外线对发酵罐中的发酵料液进行杀菌处理,紫外杀菌完成后加入发酵剂8g,并搅拌均匀,然后进行第一阶段发酵,发酵罐温度保持在23℃,第一阶段发酵的过程中每天密闭搅拌10min,不开罐放气,持续2天,然后进行第二阶段发酵,发酵罐温度保持在30℃,第二阶段发酵的过程中每天打开发酵罐进行放气,并同时搅拌5min,持续8天,完成发酵,然后过滤,去除滤渣,得到发酵液;所述紫外线的波长为280nm,紫外杀菌时间为30min;所述发酵剂由以下种子液混合而成:双歧杆菌20g、戊糖乳杆菌8g、产朊假丝酵母8g、白浅色链霉菌15g、里氏木霉18g、放线菌22g。在本发明的切削液中加入生物酸,能够显著的提高其切削的润滑性和稳定性。
所述活性组分的制备方法为:将5-羧基苯并三氮唑16.31g(163.14)溶于100mL甲苯中,边搅拌边加热温度控制在50℃,待溶解均匀后,加入52gDEGMS(二乙二醇单硬脂酸脂),再加入0.01mol对甲苯磺酸,升温至回流,维持反应1小时,待分水器中无水生成时,减压蒸馏除去溶剂得到活性组分。
为了说明本发明的效果,发明人提供比较实验如下:
对比例1:
在水基型金属切削液的制备过程中未添加活性组分,其余参数与实施例1中的完全相同,工艺过程也完全相同。
对比例2:
在水基型金属切削液的制备过程中未添加活性组分,其余参数与实施例2中的完全相同,工艺过程也完全相同。
对比例3:
在水基型金属切削液的制备过程中未添加活性组分,其余参数与实施例3中的完全相同,工艺过程也完全相同。
对比例4:
在水基型金属切削液的制备过程中将活性组分用3g十二烷基磺酸钠(SDS)和4g椰子油二乙醇酰胺(LDEA)代替,其余参数与实施例4中的完全相同,工艺过程也完全相同。
对比例5:
在水基型金属切削液的制备过程中将活性组分用2.5g二异丙醇胺和2.5g平平加-3代替,其余参数与实施例5中的完全相同,工艺过程也完全相同。
对实施例1~8和对比例1~5制备得到的水基型金属切削液进行稳定性、防锈性和润滑性测试;
稳定性测试的方法为:取配制的水基型切削液10g用硬度为500、800、1200ppm的水稀释,震荡摇匀,取100mL稀释液于刻度管中,放置24h观察析出皂层的体积。
防锈性能测试的方法为:取配制的水基型切削液100g用硬度为800ppm的水稀释,取打磨过的合金工件浸入稀释液中1min后取出,空气中静置,保持温度为30℃±2℃,湿度为65±2%,观察工件锈蚀情况。
润滑性能测试的方法为:取配制的水基型切削液100g用硬度为800ppm的水稀释,按照国标GB/T3142-1982进行最大无卡咬负荷PB值的测试。
实施例1~5和对比例1~5制备得到的水基型金属切削液的稳定性、防锈性和润滑性测试的结果如表2所示;
其中,表1列出了实施例1~6和对比例1~5的各成分的用量;
表1
表2
从表2中可以看出,实例1~6中由于采用了本发明的活性组分,其制备的水基型切削液的稳定性、防锈性和润滑性显著高于对比例1~5中制备的水基型切削液。采用本发明所得到的水基型金属切削液具有良好的防锈性、润滑性及稳定性,各项指标可以满足工件加工的需求。
尽管本发明的实施方案已公开如上,但其并不仅仅限于说明书和实施方式中所列运用,它完全可以被适用于各种适合本发明的领域,对于熟悉本领域的人员而言,可容易地实现另外的修改,因此在不背离权利要求及等同范围所限定的一般概念下,本发明并不限于特定的细节和这里示出与描述的实例。
Claims (10)
1.一种水基型金属切削液,其特征在于,包括以下重量份的原料:基础油15-30份;乳化剂0.5-20份;防锈剂3-20份;油酸2-10份;活性组分0.5-20份;水40-50份;杀菌剂0.3-0.5份;渗透剂1-1.5份;消泡剂0.02-0.1份。
2.如权利要求1所述的水基型金属切削液,其特征在于,
所述基础油为石蜡基基础油、环烷基基础油、合成基础油中的任意一种;
所述乳化剂为油酸二乙醇酰胺、烷基醇酰胺磷酸酯、C5-C25的脂肪醇聚氧乙烯醚中的任意一种;
所述防锈剂为柠檬酸、硼酸盐、醇胺、苯甲酸钠、钼酸铵、尿素中的一种或几种的组合;
所述油酸为蓖麻醇酸、棕榈油酸、油酸、亚麻油酸、妥尔油酸中的一种或几种的组合;
所述杀菌剂为含均三嗪类、异噻唑啉酮、苯氧醇类、吗啉的化学组分中的一种;
所述渗透剂为丙二醇丁醚、乙二醇丁醚、二乙二醇***中的任意一种;
所述消泡剂为聚醚类消泡剂、乳化硅油、磷酸酯中的任意一种;
所述活性组分为苯并三氮唑衍生物的分子式为:
其中,X为CH3(CH2)16COO(CH2CH2O)n-、CH3(CH2)10COO(CH2CH2O)n-、CH3(CH2)7CH=CH(CH2)7COO(CH2CH2O)n-中的一种,所述n=1-10。
3.一种如权利要求1或2所述的水基型金属切削液的制备方法,其特征在于,包括:取基础油加热到50~60℃,加入乳化剂,继续加热到80℃,搅拌30min;升温到90℃,继续搅拌20min;加入活性组分,搅拌30min,加入油酸继续搅拌20min,降温到40℃;得到混合物,将混合物加入防锈剂、渗透剂和水的混合液中,并搅拌1h,然后加入杀菌剂、消泡剂,搅拌1~3h,得到水基型金属切削液。
4.如权利要求1所述的水基型金属切削液,其特征在于,还包括:分散 剂0.1-0.5份;极压抗磨剂0.05-0.1份;发酵液1~3份;防沉淀剂1~3份;
所述分散剂为1-乙基-3-甲基咪唑乙酸盐、氯化1-丁基-3-甲基咪唑、1-丁基-3-甲基咪唑四氟硼酸盐、1-己基-3-甲基咪唑硝酸盐、溴化1-乙基-3-甲基咪唑中的任意一种。
所述极压抗磨剂为偏硼酸钠、偏硼酸钾和三硼酸钾中的一种;
所述防沉淀剂为十二烷基苯磺酸钠、季铵盐高分子共聚物、阴离子羧酸共聚体、非离子聚氨酯类中的一种。
5.如权利要求1所述的水基型金属切削液,其特征在于,所述防锈剂包括以下重量份的原料:肌醇六磷酸酯40-60份、1-羟基苯并***20~25份、丁基羟基茴香醚6~8份、多元醇5~8份、三聚氰胺1~3份、聚天冬氨酸1~3份、脂肪酸烷醇酰胺5~10份、草酸1~5份、壳聚糖5~10份、水50~80份。
6.如权利要求1所述的水基型金属切削液,其特征在于,所述消泡剂包括以下重量份的原料:聚丙二醇硬脂酸钠20~30份、异丙醇6~8份、环氧氯丙烷5~8份、液体石蜡10~20份、二硬脂酰乙二胺10~15份、氯化钙5~8份、羟甲基纤维素钠3~5份、碘化钾1~3份、卵磷脂1~3份、氯化铁1~3份、水20~30份。
7.一种如权利要求4~6任一项所述的水基型金属切削液的制备方法,其特征在于,包括:取基础油加热到50~60℃,加入乳化剂,继续加热到80℃,搅拌30min;升温到90℃,边搅拌边加入防沉淀剂,继续搅拌20min;加入活性组分,搅拌30min,加入油酸继续搅拌20min,降温到40℃;得到混合物,将混合物加入防锈剂、渗透剂、分散剂、发酵液和水的混合液中,并搅拌1h,然后加入杀菌剂、消泡剂、极压抗磨剂,搅拌1~3h,得到水基型金属切削液。
8.如权利要求7所述的水基型金属切削液的制备方法,其特征在于,所述活性组分为苯并三氮唑衍生物,其分子式为:
其中,X为CH3(CH2)16COO(CH2CH2O)n-、CH3(CH2)10COO(CH2CH2O)n-、CH3(CH2)7CH=CH(CH2)7COO(CH2CH2O)n-中的一种,所述n=1-10;
所述活性组分的制备方法为:按重量份,将15~20份5-羧基苯并三氮唑溶于80~120份溶剂中,边搅拌边加热温度控制在50-60℃,待溶解均匀后,加入40~60份聚合度n=1-10的聚乙二醇单硬脂酸脂、聚乙二醇单油酸酯或聚乙二醇单月桂酸脂中的一种,再加入1.5~2份的对甲苯磺酸,升温至回流,维持反应1~3小时,待分水器中无水生成时,减压蒸馏除去溶剂得到活性组分。
9.如权利要求7所述的水基型金属切削液的制备方法,其特征在于,所述发酵液的的制备方法为:按重量份,取淀粉30~50份、魔芋粉20~30份、糖蜜5~10份、甘蔗渣5~10份、褐藻多糖3~5份、钼酸铵5~8份、硒酸钠3~5份、水50~80份,加入发酵罐搅拌均匀;然后采用紫外线对发酵罐中的发酵料液进行杀菌处理,紫外杀菌完成后加入发酵剂6~8份,并搅拌均匀,然后进行第一阶段发酵,发酵罐温度保持在22~25℃,第一阶段发酵的过程中每天密闭搅拌10-15min,不开罐放气,持续2~3天,然后进行第二阶段发酵,发酵罐温度保持在26~30℃,第二阶段发酵的过程中每天打开发酵罐进行放气,并同时搅拌5~8min,持续8~10天,完成发酵,然后过滤,去除滤渣,得到发酵液;所述紫外线的波长为180-280nm,紫外杀菌时间为25~30min。
10.如权利要求9所述的水基型金属切削液的制备方法,其特征在于,所述发酵剂由以下重量份的种子液混合而成:双歧杆菌15~20份、戊糖乳杆菌6~10份、产朊假丝酵母5~10份、白浅色链霉菌10~18份、里氏木霉15~20份、放线菌20~25份。
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