CN106083008A - Preparation method of lightweight cloud stone ceiling board and products thereof - Google Patents

Preparation method of lightweight cloud stone ceiling board and products thereof Download PDF

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Publication number
CN106083008A
CN106083008A CN201610406225.6A CN201610406225A CN106083008A CN 106083008 A CN106083008 A CN 106083008A CN 201610406225 A CN201610406225 A CN 201610406225A CN 106083008 A CN106083008 A CN 106083008A
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parts
base substrate
glaze
glazing
ceiling board
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CN201610406225.6A
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周国华
邵敏
江毅
李永兴
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Zhejiang Ou Fu Technology Co Ltd
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Zhejiang Ou Fu Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/14Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
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    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/20Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
    • C04B2235/3248Zirconates or hafnates, e.g. zircon
    • C04B2235/3249Zirconates or hafnates, e.g. zircon containing also titanium oxide or titanates, e.g. lead zirconate titanate (PZT)
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
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    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/36Glass starting materials for making ceramics, e.g. silica glass
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    • C04B2235/44Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
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    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
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    • C04B2235/52Constituents or additives characterised by their shapes
    • C04B2235/5208Fibers
    • C04B2235/5216Inorganic
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Abstract

The present invention relates to the preparation method of a kind of lightweight cloud stone ceiling board, comprise the following steps: step one, base: after perlite, bentonite, zeolite, Kaolin, travertine, black mud, green pottery silica flour, fluorite tailing, glass fiber powder, lead zirconate titanate nano powder, chopped basalt fibre, the raw material of polypropylene chopped strand are mixed, then broken, wet ball grinding, old uniformly, carry out again being spray-dried, pelletize, powder process, the most compressing biscuit that obtains, then biscuit is carried out drying obtain base substrate;Step 2, enamel frit makeing, glazing: blank raw material, albite, potassium feldspar raw material are carried out ball milling and obtain glaze, with glaze, described base substrate is carried out glazing;Step 3, by the base substrate after glazing through high-temperature firing, form base substrate closed pore and uniformly gather the lightweight cloud stone ceiling board of band glaze.Technical solution of the present invention, have lightweight, be incubated, prevent fires, waterproof, high intensity, the technique effect of ageing-resistant band decorative cover.

Description

Preparation method of lightweight cloud stone ceiling board and products thereof
Technical field
The present invention relates to preparation method of a kind of lightweight cloud stone ceiling board and products thereof.
Background technology
Skin heat-insulation system is part critically important in energy saving building, at home and abroad extensively should in architectural engineering With, existing warming plate mainly has EPS sheet, XPS plate, PU plate, phenolic board, and foam mixes earth plate, rock cotton board etc..Finish coat is With the inorganic board of each type coating, metallic plate, stone plate and ceramic wafer etc..Facing uses polyurethane adhesive or epoxy glue to be directly bonded to On heat-insulation layer material.This kind of material is primarily present following shortcoming:
1. decoration panel is not light material, and unit weight is big, it is impossible to accomplish lightweight.
2. heat-insulation layer uses organic material, there is poor durability and the problem of fire protecting performance difference.The inorganic heat preservation material used It is high to there is water absorption rate in material, and shrinkage factor is big, the problems such as intensity is low, and service life is short.
3. the unit weight between decoration panel with heat-insulation layer material differs ten times, and intensity differs tens times, forms outer weight inner weight, The exterior wall heat-preserving system of strong outside and weak inside.Although generally using viscous anchor to combine, but anchoring piece must being anchored on decoration panel, so its Support system and construction technology are extremely complex.
The problem that the most commonly used heat-insulating mortar exterior wall heat insulation system exists 4 aspects:
1. system durability is short, and external wall outer insulation engineering design service life is 25 years, and can conventional organic insulation material Using 25 years and need test, and mineral-type insulation exists water absorption rate height, shrinkage factor is big, affects actual life.
2. security performance allows people worry, and the most the most frequently used external-wall heat-insulation material remains organic material, its fire protecting performance , during constructing and using, there is fire safety hidden danger in difference.
3. working procedure is complicated, and hidden danger of quality is many, and construction level is required very strict, if to it by External Thermal Insulation Technology for External Construction method, technology requires to be unfamiliar with, or workman's technical operation level is relatively low, and construction management is strict not, easily produces tight The quality problems of weight.
4. system cost is high, and construction of exterior wall external heat-preservation system operation is more, when using thermal insulation mortar as heat-insulation layer, and one Plastering in Ban Fen tri-road (the most), per pass is plastered and need to be carried out after front one coat of plaster hardening again, and heat-insulation layer external demand is set up and put Crack-resistant layer, there is provision of grid cloth or steel wire protective layer, does decorative cover coating the most again.
Summary of the invention
The deficiency existed for prior art, it is an object of the invention to provide a kind of lightweight, be incubated, prevent fires, waterproof, high Intensity, the preparation method of lightweight cloud stone ceiling board and products thereof of ageing-resistant band decorative cover.
For achieving the above object, the technical scheme is that and comprise the following steps: step one, base: will be with The perlite of weight portion meter 35 ~ 55 parts, bentonite 5 ~ 10 parts, 10 ~ 20 parts of zeolite, Kaolin 5 ~ 10 parts, travertine 5 ~ 15 parts, black 10 ~ 20 parts of mud, green pottery silica flour 0.4 ~ 1.0 part, fluorite tailing 10 ~ 20 parts, glass fiber powder 5-10 part, lead zirconate titanate nanometer is micro- After powder 1-4 part, chopped basalt fibre 2 ~ 6 parts, the raw material of polypropylene chopped strand 3 ~ 8 parts mix, then broken, wet method Ball milling, old uniformly, then carry out being spray-dried, pelletize, powder process, the most compressing biscuit that obtains, then biscuit is dried Obtain base substrate;Step 2, enamel frit makeing, glazing: by blank raw material 40 ~ 60 parts in parts by weight, albite 20 ~ 30 parts, potassium feldspar The raw material of 20 ~ 30 parts carries out ball milling and obtains glaze, with glaze, described base substrate is carried out glazing;Step 3, by the base substrate after glazing Through 1100 DEG C ~ 1300 DEG C high-temperature firings, form base substrate closed pore and uniformly gather the microporous foam ceramic thermal insulation decoration of band glaze Plate.
The present invention is arranged further: in described step one, base: by perlite 45 ~ 50 parts in parts by weight, bentonite 6 ~ 8 parts, 12 ~ 18 parts of zeolite, Kaolin 6 ~ 8 parts, travertine 8 ~ 12 parts, black mud 13 ~ 16 parts, green pottery silica flour 0.5 ~ 0.8 part, jade-like stone Stone mine tailing 12 ~ 18 parts, glass fiber powder 6-8 part are lead zirconate titanate nano powder 1.5-3 part, chopped basalt fibre 3 ~ 5 parts, poly- The raw material that propylene chopped strand is 5 ~ 7 parts mixes.
The present invention is arranged further: in described step 2, enamel frit makeing, glazing: by blank raw material 45 ~ 55 in parts by weight Part, albite 22 ~ 26 parts, the raw material of potassium feldspar 22 ~ 26 parts carry out ball milling and obtain glaze.
The present invention is arranged further: in described step 3, by the base substrate after glazing through 1180 DEG C ~ 1200 DEG C high-temperature firings.
The present invention is arranged further: in described step 2, enamel frit makeing, glazing: after described base substrate being carried out glazing with glaze, Stamp is carried out on glaze.
The present invention is arranged further: described stamp uses lamina printing decoration or ink-jet printed mode.
A kind of lightweight cloud stone ceiling board, including base substrate and glaze, described base substrate has the closed pore uniformly gathered, institute State base substrate with glaze in being wholely set.
Compared with prior art, it provides the benefit that the present invention: lightweight cloud stone ceiling board of the present invention makes full use of mine tailing The like waste, makes and has lightweight, and pyroconductivity is low, fire prevention, waterproof, ageing-resistant, good with the cement products compatibility, weatherability, Decorative cover (glaze) and base substrate direct combination when base substrate and glaze use above-mentioned material sintering, the superior functions such as decorative cover is abundant can Being applied to the fields such as building, decoration, environmental protection, it is particularly advantageous in that:
1. decorative cover and base substrate one sinter molding, and bond without binding agent.
2. lightweight.Lightweight is mainly reflected in product compared with stone curtain wall, big specification ceramic plate, in weight significantly Alleviate, be suitable for skyscraper, panel and support system and construction technology will be simplified, be substantially reduced engineering cost, after being also Phase safeguards provides convenient.
3. tensile strength is high." architectural engineering cohesive strength of decorative tile touchstone " (JGJ110-2008) requires ceramic tile Adhesion strength not less than 0.4Mpa.Tensile strength >=the 1.0Mpa of lightweight cloud stone ceiling board.Specialty exterior wall pottery is used to glue Knot agent, is fully able to guarantee tensile bond strength, meets code requirement.
4. heat conductivity≤0.07w/ (m*k).Suitable with inorganic light-weight aggregate thermal insulation mortar, may act as external thermal insulation system Heat-insulating heat-preserving material.
5. fire protecting performance is good.Product forms through 1200 DEG C of high-temperature calcinations, and combustibility is A1 level.
6. water absorption rate is low.Small product size water absorption rate≤0.8%, other insulation volume of comparison expanded perlite thermal-nsulation plate etc. Water absorption rate≤10%, will not reduce heat preservation and insulation because of exterior wall leakage.
The most ageing-resistant.Ceramic material property is stable, and good endurance is the most aging, can realize the life-span same with building, is conventional Organic insulation material unrivaled.
8. the compatibility is good.Close with the linear expansion coefficient such as cement mortar, concrete, the compatibility is good, and bonding is reliable, with high temperature The traditional ceramic building material fired is the same, does not ftractures under expanding with heat and contract with cold, indeformable, does not shrinks.
9. the main chemical compositions of glass fiber powder is SiO2AL2O3.CaO.MgO, and lead zirconate titanate nano powder is to use Pb3O4, ZrO2 and TiO2 use aqueous sol-gel method synthesis;Technical scheme of the present invention uses glass fiber powder With the high-temperature nuclei of lead zirconate titanate nano powder, make, between the two by fiber and basal body interface generation chemical reaction, to improve fibre Dimension and the bond strength of glass ceramics, reduce the not matching that property of binding site performance, thus rely on Stress-induced transformation toughness reinforcing, Crack deflection is toughness reinforcing and microcrack evolution equation, and ZrO2 granule just occurs four directions to the phase in version of monocline, and causes fine fisssure in body Stricture of vagina, it absorbs the energy of cracks can spread, weakens or prevent the extension of crackle, introduces P2O5 in the feed substantially to increase ZrO2 dissolubility in silicate melt, reaches to strengthen and mends tough purpose;AL2O3 composition adds not when high-temperature fusion Carry out the high temperature viscosity of stone crystal, form the skeleton of body;Wherein CaO and MgO volatilizees with the form of CO2 at high temperature, the most also Promote the generation in hole of holding one's breath, therefore technical scheme of the present invention does not interferes with foaming while improving ceramic material toughness yet Agent pyroreaction in body produces bubble, therefore its heat insulating effect is also fine, overcomes tradition foaming thermal-insulating toughness The defects such as low, heat insulating effect is poor.Traditional lightweight cloud stone ceiling board often can because of each position ratio of tangential to radial shrinkage in warming plate not Unanimously cause occurring rupturing (drying shrinkage ruptures), and the present invention is by short by the section shape being cut into after continuous fiber material surface treated Cut fiber to mix, and inside lightweight cloud stone ceiling board, played the function of uniform drying shrinkage stress by chopped strand, make drying shrinkage Stress tends to being applied to inside whole warming plate uniformly, greatly reduces the drying shrinkage destructive rate of lightweight cloud stone ceiling board.Short Cutting basalt fibre and played potentiation, polypropylene chopped strand is playing toughness reinforcing effect.
Detailed description of the invention
Embodiment one,
Step one, base: by perlite 35 parts in parts by weight, bentonite 5 parts, 10 parts of zeolite, Kaolin 5 parts, travertine 5 Part, black mud 10 parts, green pottery silica flour 0.4 part, fluorite tailing 10 parts, glass fiber powder 5 parts, lead zirconate titanate nano powder 1 part, short Cut basalt fibre 2 parts, after the raw material of polypropylene chopped strand 3 parts mixes, then broken, wet ball grinding, old uniformly, Carry out again being spray-dried, pelletize, powder process, the most compressing biscuit that obtains, then biscuit is carried out drying obtain base substrate;Step Two, enamel frit makeing, glazing: blank raw material 40 parts in parts by weight, albite 20 parts, the raw material of potassium feldspar 20 parts are milled to 350 mesh glaze, excessively sift out ball and store to glaze bucket, with glaze, described base substrate is carried out glazing;Step 3, by the base substrate warp after glazing 1100 DEG C of high temperature continuous way roller kiln burning systems, form base substrate closed pore and uniformly gather the lightweight cloud stone ceiling board of band glaze.
Embodiment two,
Step one, base: by perlite 55 parts in parts by weight, bentonite 10 parts, 20 parts of zeolite, Kaolin 10 parts, solidifying ash 15 parts of stone, black mud 20 parts, green pottery silica flour 1.0 parts, fluorite tailing 20 parts, glass fiber powder 10 parts, lead zirconate titanate nano powder 4 After part, chopped basalt fibre 6 parts, the raw material of polypropylene chopped strand 8 parts mix, then broken, wet ball grinding, old Uniformly, then carry out being spray-dried, pelletize, powder process, the most compressing biscuit that obtains, then biscuit is dried at drying kiln To base substrate;Step 2, enamel frit makeing, glazing: by blank raw material 60 parts in parts by weight, albite 30 parts, potassium feldspar 230 parts former Material carries out being milled to 350 mesh glaze, excessively sifts out ball and stores to glaze bucket, carries out drenching glaze mode glazing to described base substrate with glaze; Step 3, by the base substrate after glazing through 1300 DEG C of high temperature continuous way roller kiln burning systems, form base substrate closed pore and uniformly gather band The lightweight cloud stone ceiling board of glaze.
Embodiment three, step one, base: by perlite 45 parts in parts by weight, bentonite 6 parts, 12 parts of zeolite, kaolinite 6 parts of soil, travertine 8 parts, black mud 13 parts, green pottery silica flour 0.5 part, fluorite tailing 12 parts, glass fiber powder 6 parts, lead zirconate titanate After nano powder 1.5 parts, chopped basalt fibre 3 parts, the raw material of polypropylene chopped strand 5 parts mix, then broken, wet Method ball milling, old uniformly, then carry out being spray-dried, pelletize, powder process, the most compressing biscuit that obtains, then biscuit is being dried Kiln carries out drying and obtains base substrate;Step 2, enamel frit makeing, glazing: by blank raw material 45 parts in parts by weight, albite 22 parts, potassium The raw material that Anhydrite is 22 parts carries out being milled to 350 mesh glaze, excessively sifts out ball and stores to glaze bucket, with glaze to described base substrate to drench glaze side Formula carries out glazing;Step 3, by the base substrate after glazing through 1180 DEG C of high temperature continuous way roller kiln burning systems, form base substrate closed pore The lightweight cloud stone ceiling board of the most densely covered band glaze.
Embodiment four, step one, base: by perlite 50 parts in parts by weight, bentonite 8 parts, 18 parts of zeolite, kaolinite 8 parts of soil, travertine 12 parts, black mud 16 parts, green pottery silica flour 0.8 part, fluorite tailing 18 parts, glass fiber powder 8 parts, lead zirconate titanate After nano powder 3 parts, chopped basalt fibre 5 parts, the raw material of polypropylene chopped strand 7 parts mix, then broken, wet method Ball milling, old uniformly, then carry out being spray-dried, pelletize, powder process, the most compressing biscuit that obtains, then to biscuit at drying kiln Carry out drying and obtain base substrate;Step 2, enamel frit makeing, glazing: by long to blank raw material 55 parts in parts by weight, albite 26 parts, potassium The raw material that stone is 26 parts carries out being milled to 350 mesh glaze, excessively sifts out ball and stores to glaze bucket, with glaze to described base substrate to drench glaze mode Carry out glazing;Step 3, by the base substrate after glazing through 1200 DEG C of high temperature continuous way roller kiln burning systems, form base substrate closed pore equal The lightweight cloud stone ceiling board of even densely covered band glaze.
Embodiment five, step one, base: by perlite 48 parts in parts by weight, bentonite 7 parts, 15 parts of zeolite, kaolinite 7 parts of soil, travertine 10 parts, black mud 14 parts, green pottery silica flour 0.7 part, fluorite tailing 15 parts, glass fiber powder 7 parts, lead zirconate titanate After nano powder 2 parts, chopped basalt fibre 4 parts, the raw material of polypropylene chopped strand 6 parts mix, then broken, wet method Ball milling, old uniformly, then carry out being spray-dried, pelletize, powder process, the most compressing biscuit that obtains, then to biscuit at drying kiln Carry out drying and obtain base substrate;Step 2, enamel frit makeing, glazing: by long to blank raw material 50 parts in parts by weight, albite 23 parts, potassium The raw material that stone is 24 parts carries out being milled to 350 mesh glaze, excessively sifts out ball and stores to glaze bucket, with glaze to described base substrate to drench glaze mode Carry out glazing;Step 3, by the base substrate after glazing through 1190 DEG C of high temperature continuous way roller kiln burning systems, form base substrate closed pore equal The lightweight cloud stone ceiling board of even densely covered band glaze.
The present embodiment 1-5 lightweight cloud stone ceiling board, after testing, its performance indications are following with reference to form:
Embodiment 1 Embodiment 2 Embodiment 4 Embodiment 5 Embodiment 5
Unit weight ≤160kg/m2 ≤160kg/m2 ≤350kg/m2 ≤320kg/m2 ≤300kg/m2
Tensile strength ≥2.3MPA ≥2.3MPA ≥2.3MPA ≥1.2MPA ≥1.2MPA
Heat conductivity ≤0.085w/(m*k) ≤0.085w/(m*k) ≤0.08W/(m*k) ≤0.07w/(m*k) ≤0.07w/(m*k)
Fire protecting performance A1 level A1 level A1 level A1 level A1 level
Water absorption rate ≤0.8% ≤0.8% ≤0.8% ≤0.8% ≤0.8%
Ageing-resistant Ageing-resistant Ageing-resistant Ageing-resistant Ageing-resistant Ageing-resistant
The compatibility Compatible Compatible Compatible Compatible Compatible
Comprcssive strength ≥6.5MPa ≥6.2MPa ≥5.4MPa ≥4.3MPa ≥3.8MPa

Claims (7)

1. the preparation method of a lightweight cloud stone ceiling board, it is characterised in that: comprise the following steps: step one, base: will be with The perlite of weight portion meter 35 ~ 55 parts, bentonite 5 ~ 10 parts, 10 ~ 20 parts of zeolite, Kaolin 5 ~ 10 parts, travertine 5 ~ 15 parts, black 10 ~ 20 parts of mud, green pottery silica flour 0.4 ~ 1.0 part, fluorite tailing 10 ~ 20 parts, glass fiber powder 5-10 part, lead zirconate titanate nanometer are micro- After powder 1-4 part, chopped basalt fibre 2 ~ 6 parts, the raw material of polypropylene chopped strand 3 ~ 8 parts mix, then broken, wet method Ball milling, old uniformly, then carry out being spray-dried, pelletize, powder process, the most compressing biscuit that obtains, then biscuit is dried Obtain base substrate;Step 2, enamel frit makeing, glazing: by blank raw material 40 ~ 60 parts in parts by weight, albite 20 ~ 30 parts, potassium feldspar The raw material of 20 ~ 30 parts carries out ball milling and obtains glaze, with glaze, described base substrate is carried out glazing;Step 3, by the base substrate after glazing Through 1100 DEG C ~ 1300 DEG C high-temperature firings, form base substrate closed pore and uniformly gather the lightweight cloud stone ceiling board of band glaze.
The preparation method of lightweight cloud stone ceiling board the most according to claim 1, it is characterised in that: described step one, system In base: by perlite 45 ~ 50 parts in parts by weight, bentonite 6 ~ 8 parts, 12 ~ 18 parts of zeolite, Kaolin 6 ~ 8 parts, travertine 8 ~ 12 parts, black mud 13 ~ 16 parts, green pottery silica flour 0.5 ~ 0.8 part, fluorite tailing 12 ~ 18 parts, glass fiber powder 6-8 part, lead zirconate titanate Nano powder 1.5-3 part, chopped basalt fibre 3 ~ 5 parts, the raw material of polypropylene chopped strand 5 ~ 7 parts mix.
The preparation method of lightweight cloud stone ceiling board the most according to claim 1, it is characterised in that: described step 2, system In glaze, glazing: blank raw material 45 ~ 55 parts in parts by weight, albite 22 ~ 26 parts, the raw material of potassium feldspar 22 ~ 26 parts are carried out Ball milling obtains glaze.
The preparation method of lightweight cloud stone ceiling board the most according to claim 1, it is characterised in that: in described step 3, By the base substrate after glazing through 1180 DEG C ~ 1200 DEG C high-temperature firings.
5. according to the preparation method of the lightweight cloud stone ceiling board described in claim 1 or 2 or 3 or 4, it is characterised in that: described In step 2, enamel frit makeing, glazing: after described base substrate being carried out glazing with glaze, glaze carries out stamp.
The preparation method of lightweight cloud stone ceiling board the most according to claim 5, it is characterised in that: described stamp uses net Plate stamp or ink-jet printed mode.
7. the lightweight cloud stone prepared according to the preparation method of the lightweight cloud stone ceiling board described in any one of claim 1-5 hangs Top board, it is characterised in that: include that base substrate and glaze, described base substrate have the closed pore uniformly gathered, described base substrate and glaze In being wholely set.
CN201610406225.6A 2016-06-12 2016-06-12 Preparation method of lightweight cloud stone ceiling board and products thereof Withdrawn CN106083008A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113121128A (en) * 2021-06-04 2021-07-16 嘉华特种水泥股份有限公司 High-strength toughened cementing material and preparation method and application thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102898178A (en) * 2012-09-28 2013-01-30 江苏金久科技新材料有限公司 High-strength foamed thermal-insulation ceramic material and preparation method thereof
CN103243826A (en) * 2013-05-15 2013-08-14 江苏鑫石器玄武岩纤维有限公司 Inorganic foaming micro-pore heat preservation composite board
CN103693993A (en) * 2013-12-23 2014-04-02 宾阳县明翔新材料科技有限公司 Ceramic tile with heat-preservation and heat-insulation functions and production method of same
CN104098304A (en) * 2014-06-18 2014-10-15 池州市新科建材有限公司 Fluorite tailings/steel slag powder composite lightweight partition board and manufacturing method thereof
CN105399437A (en) * 2015-11-20 2016-03-16 信阳科美新型材料有限公司 Thermal-insulating and decorative porcelain plate quickly fired at ultralow temperature and production method of thermal-insulating and decorative porcelain plate

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102898178A (en) * 2012-09-28 2013-01-30 江苏金久科技新材料有限公司 High-strength foamed thermal-insulation ceramic material and preparation method thereof
CN103243826A (en) * 2013-05-15 2013-08-14 江苏鑫石器玄武岩纤维有限公司 Inorganic foaming micro-pore heat preservation composite board
CN103693993A (en) * 2013-12-23 2014-04-02 宾阳县明翔新材料科技有限公司 Ceramic tile with heat-preservation and heat-insulation functions and production method of same
CN104098304A (en) * 2014-06-18 2014-10-15 池州市新科建材有限公司 Fluorite tailings/steel slag powder composite lightweight partition board and manufacturing method thereof
CN105399437A (en) * 2015-11-20 2016-03-16 信阳科美新型材料有限公司 Thermal-insulating and decorative porcelain plate quickly fired at ultralow temperature and production method of thermal-insulating and decorative porcelain plate

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
刘培生: "《多孔材料引论》", 30 September 2004, 清华大学出版社 *
周文英: "《导热高分子材料》", 30 April 2014, 国防工业出版社 *
白世贞: "《工业品商品学》", 30 June 2014, 中国财富出版社 *
自贡市轻工业管理局、工业合作联社: "《自贡市轻工业志》", 31 August 1993, 四川大学出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113121128A (en) * 2021-06-04 2021-07-16 嘉华特种水泥股份有限公司 High-strength toughened cementing material and preparation method and application thereof

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