CN106009990A - Micromolecular anionic waterborne glaze and preparation method thereof - Google Patents
Micromolecular anionic waterborne glaze and preparation method thereof Download PDFInfo
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- CN106009990A CN106009990A CN201610406200.6A CN201610406200A CN106009990A CN 106009990 A CN106009990 A CN 106009990A CN 201610406200 A CN201610406200 A CN 201610406200A CN 106009990 A CN106009990 A CN 106009990A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention relates to a micromolecular anionic waterborne glaze and a preparation method thereof. The micromolecular anionic waterborne glaze is prepared from 40%-50% of micromolecular waterborne acrylic emulsion, 5%-10% of micromolecular waterborne epoxy resin, 5%-8% of totally-methylated amino resin, 3%-5% of partly-methylated amino resin, 0.3%-0.5% of a defoaming agent, 0.2%-0.4% of a flatting agent, 0.3-0.8% of a wetting agent, 0.6%-1% of an anti-sagging aid, 0.6%-0.8% of an anti-doodling aid, 1%-1.5% of wax liquid, 3%-15% of anionic powder, 0.1-0.5% of a PH value regulator and the balance micromolecular water. As micromolecular water has high activity and small groups, air in a construction and spray site environment can be effectively purified; in the waterborne glaze spray process, the surface expansion force is small, and thus a surface glaze film is smoother; the micromolecular water in the glaze is regular in molecular structure arrangement and high in density, does not carry free charges, and can permeate into every part of a base material or parts with spray difficulty in the spray use process due to large seepage force and activation force; besides, sagging is not likely to occur, and the surface of the waterborne glaze is smoother and more saturated than that of glaze produced with deionized water or tap water on the market.
Description
Technical field
The present invention relates to coating.
Background technology
With developing rapidly of China's industry, the surface of the high-end metal products such as magnesium alloy, aluminium alloy, magnalium, rustless steel processes demand and day by day increases, especially automotive substrates, automotive hub, the high-end metal of metallic door industry auxiliary products demand bigger, the finish materials used on existing market is mainly oil paint, oil paint is inflammable and explosive, producing, transport, the aspect such as use has the biggest potential safety hazard, and containing organic solvents such as a large amount of benzene, ketone, alcohol ethers in painting, bigger to harm.Aqueous glaze, without organic solvents such as benzene, ketone, alcohol ethers, with water as solvent, brings safety and environmental protection, is increasingly received by the market.But existing aqueous glaze needs higher baking temperature and surface drying time long, and its permeability and moistening spreadability are relatively low, therefore there is necessity of improvement simultaneously.
Summary of the invention
The technical problem to be solved in the present invention is, it is provided that the aqueous glaze of a kind of improvement.
The technical solution adopted for the present invention to solve the technical problems is: scintilla anion aqueous glaze, by weight percentage, including following component: scintilla aqueous acrylic emulsion 40% ~ 50%, scintilla aqueous epoxy resins 5% ~ 10%, full methyl-etherified amino resins 5% ~ 8%, part methyl-etherified amino resins 3% ~ 5%, defoamer 0.3% ~ 0.5%, levelling agent 0.2% ~ 0.4%, wetting agent 0.3% ~ 0.8%, resist sagging auxiliary agent 0.6% ~ 1%, anti-graffiti auxiliary agent 0.6% ~ 0.8%, wax liquid 1% ~ 1.5%, anion powder 3% ~ 15%, pH value regulator 0.1% ~ 0.5%, surplus are scintilla water.
Foregoing scintilla anion aqueous glaze, also includes organic pigment 3% ~ 6%.
Foregoing scintilla anion aqueous glaze, also includes aluminum paste or aluminum argentum powder 6% ~ 12%.
Foregoing scintilla anion aqueous glaze, also includes pearl essence 6% ~ 12%.
Foregoing scintilla anion aqueous glaze, the accounting of described scintilla water is 40% ~ 50%.
Foregoing scintilla anion aqueous glaze, in described scintilla water, each water clusters is made up of 36 hydrones.
Foregoing scintilla anion aqueous glaze, described scintilla aqueous acrylic emulsion is that acrylic emulsion is dispersed in homopolymerization or copolymerization acquisition in scintilla water；Described scintilla aqueous epoxy resins is epoxy resin is scattered in emulsion, aqueous dispersion or the aqueous solution formed in scintilla water with microgranule, drop or colloidal form.
The preparation method of foregoing scintilla anion aqueous glaze, comprises the following steps:
S1, take by weight percentage scintilla aqueous acrylic emulsion, scintilla aqueous epoxy resins, full methyl-etherified amino resins, part methyl-etherified amino resins stir 5-10 minute, rotating speed 800-1000 rev/min；
S2, take by weight percentage scintilla water, defoamer, levelling agent, wetting agent, resist sagging auxiliary agent stir 5-10 minute, rotating speed 800-1000 rev/min；
S3, take by weight percentage anti-graffiti auxiliary agent, wax liquid, anion powder stir 5-10 minute, rotating speed 800-1000 rev/min；
S4, takes pH value regulator by weight percentage and stirs 5-10 minute, rotating speed 500-800 rev/min, and product synthesizes.
Foregoing preparation method, adds organic pigment 3% ~ 6% in step sl.
Foregoing preparation method, adds aluminum paste 6% ~ 12% and/or pearl essence 6% ~ 12% in step s 4.
Implement technical scheme, there is following beneficial effect: because scintilla water activity is the biggest, dumpling is the least, can effectively purify the air of construction spraying site environment, in using aqueous glaze (or water paint) spraying process, surface expansive force is the least, so that surface glaze glaze film is more smooth.The molecular structure marshalling of scintilla water in glaze, high density, without free charge, there is stronger penetration and activation power, during spraying uses, can penetrate each position of ground or be difficult to the position of spraying, and being difficult to sagging, coating surface ratio market using deionized water and tap water produce is more smooth and saturated.
Detailed description of the invention
In order to the technical characteristic of the present invention, purpose and effect are more clearly understood from, now describe the detailed description of the invention of the present invention in detail.
Scintilla anion aqueous glaze, by weight percentage, including following component: scintilla aqueous acrylic emulsion 40% ~ 50%, scintilla aqueous epoxy resins 5% ~ 10%, full methyl-etherified amino resins 5% ~ 8%, part methyl-etherified amino resins 3% ~ 5%, defoamer 0.3% ~ 0.5%, levelling agent 0.2% ~ 0.4%, wetting agent 0.3% ~ 0.8%, resist sagging auxiliary agent 0.6% ~ 1%, anti-graffiti auxiliary agent 0.6% ~ 0.8%, wax liquid 1% ~ 1.5%, anion powder 3% ~ 15%, pH value regulator 0.1% ~ 0.5%, surplus are scintilla water.
Preparation method is: take the most by weight percentage scintilla aqueous acrylic emulsion, scintilla aqueous epoxy resins, full methyl-etherified amino resins, part methyl-etherified amino resins stir 5-10 minute, rotating speed 800-1000 rev/min；Take the most by weight percentage scintilla water, defoamer, levelling agent, wetting agent, resist sagging auxiliary agent stir 5-10 minute, rotating speed 800-1000 rev/min；Take the most by weight percentage anti-graffiti auxiliary agent, wax liquid, anion powder stir 5-10 minute, rotating speed 800-1000 rev/min；The last pH value regulator that takes by weight percentage stirs 5-10 minute, rotating speed 500-800 rev/min, and product synthesizes.
The present invention utilizes the spatial structure of micro hydropower submanifold and adding and with collaborative of intermolecular various weak interaction (such as hydrogen bond, Van der Waals force etc.), directivity and the selectivity of intermolecular interaction determine molecular recognition, molecule assembles and defines unique three dimensional structure with polymer, maintain a dynamic level, through magnetization technology compactness, arrangement property, hardness, anti-soil, the feature all reaching glaze wear-resisting, aging and physical property.Scintilla aqueous automobile wheel hub glaze have low VOC, pollution-free, to operator's nonhazardous, glaze layer adhesive force is strong, pliability good and hardness height, anti-stain, has mirror effect, scintilla aqueous automobile wheel hub glaze also has that wearability, resistance to water, salt spray resistance and the resistance to ag(e)ing of excellence be strong, strong alkali-acid resistance, construction are simple, stable storing safety.
Above-mentioned scintilla aqueous acrylic emulsion and scintilla aqueous epoxy resins are aqueous acrylic emulsion and aqueous epoxy resins in industry slang, the aqueous acrylic emulsion used in industry and aqueous epoxy resins synthesis contained humidity are tap water or deionized water, as a example by aqueous acrylic emulsion, it is by the way of emulsion is polymerized, emulsion by various polymerizable acrylic monomers, and the aqueous acrylic emulsion used in the present invention and aqueous epoxy resins have used scintilla water to substitute the tap water in original composition or deionized water, so being scintilla aqueous acrylic emulsion and scintilla aqueous epoxy resins.Scintilla aqueous acrylic emulsion is that acrylic emulsion is dispersed in (being in the past with tap water or deionized water) the inner homopolymerization of scintilla water or copolymerization obtains；Scintilla aqueous epoxy resins is epoxy resin is scattered in emulsion, aqueous dispersion or the aqueous solution formed in scintilla water (being in the past with tap water or deionized water) with microgranule, drop or colloidal form.
The preferred scope of percentage ratio shared in whole glaze of scintilla water be 40%---50% be preferred scope.Hydrone is H2O, both two hydrogen atoms and an oxygen atom, scientists application nuclear magnetic resonance technique observes the structure in water between hydrone, normal water is to be made up of 13 15 hydrones at 140 150 hertz of each water clusters, it is referred to as macromolecular mass water, World Health Organization (WHO) specifies, within entering 100 hertz, each water clusters is made up of 57 hydrones, referred to as small-micelle water.The preferred scope of scintilla water is 3-6 molecule or unimolecule, and on market use aqueous glaze in deionized water and tap water in each water clusters be made up of 13 15 hydrones.
The membrane formation mechanism of scintilla anion aqueous glaze: nano level aqueous polymer dispersions is different from the membrane formation mechanism of general polymer emulsion colloidal flocculate and break emulsion, use the film forming mechanism of molecular level, along with evaporation of water, there is physicochemical gathering in the specific functional groups in adjacent polymer, water-based microemulsion polymeric system is made to produce the crosslinking of physical property, the critical solid content of this physical crosslinking, more much lower than the critical solid content that emulsion particle is assembled, that is this crosslinking phenomena just can occur when water content is higher, the result that the reinforced effects bringing system is assembled than common micelle to shift to an earlier date, the i.e. surface drying time of system is faster than general aqueous acrylic emulsion, after nano-resin film forming, the microfacies Han nanometer in membrane structure, make the hardness of film, glossiness and pliability are all improved than common water borne polymer emulsion.
Amino resins is polymerization high methylol group type part methyl-etherified melmac, containing alkoxy methyl and methylol, the most minimal amount of imino group.Owing to alkoxy methyl is mainly the group of cross-linking reaction, need higher temperature just can crosslink reaction, and the reactivity of methylol is more than alkoxy methyl, the increase of methylol group content in amino resins, curing reaction speed can be improved and reduce baking temperature, it contains minimal amount of imino group simultaneously, it is possible to reduce self-polymeric reaction；The film formed after the solidification of low methyl-etherified amino resins has alcohol resistance, hardness and the gloss of excellence.
Hydroxy resin can improve the gloss of paint film, hardness, resistance to alcohol repellency and resistance to water；Hydroxy resin containing more hydrophilic group has preferable peptizaiton to pigment, has preferable Stabilization to emulsion, can fill the space between emulsion particle, thus improve the compactness of film, planarization and resistance to water during film forming.Hydroxy resin contains more crosslinked group-COOH and-OH, is on the one hand conducive to the adhesive force to ground, is on the other hand conducive to crosslinking curing, thus the vitrification point of glaze film is the highest, and hardness is the biggest；Hydroxy resin molecular weight is little, the good dispersion in water, and the compatibility with amino resins is good, is conducive to crosslinking.
Deionized water, distilled water, nature water not presented in single hydrone (H2O), but condensed together by the strong effect of hydrogen by some hydrones, form water cluster, it is commonly called as water clusters, and the size of this molecular cluster cannot be estimated, typically being made up of 8-15 hydrone, and be dynamic, its average diameter is 2.6～6nm；And prepared by differential submanifold hydromining special process, its micel is 3-6 hydrone composition, and its average diameter is 0.6nm, has extremely strong permeability and moistening spreadability, can penetrate in polymer molecule space.In a word, after the microstructure of water changes, its many physicochemical properties such as electrical conductivity, density, pH value etc. all have change in various degree.
The structure of scintilla water is completed by hydrogen bond self-organizing with function, and its active function is the space structure characteristic by water cluster and hydrogen bond is had an effect, and can affect the structure of polymer molecule, character and function.Water is good polar solvent, and many polar molecules can be dissolved in water, and its reason is the interaction between hydrone and polar molecule, there is amphion NH in scintilla glaze system+ 3-CH(-R)-COO-
Deng many polar groups, scintilla water electrode easily forms stable state by hydrogen bonded, and the adding and determine molecular recognition with collaborative, the directivity of intermolecular interaction and selectivity of intermolecular various weak interactions (such as hydrogen bond, Van der Waals force etc.), molecule assemble and form the three dimensional structure of uniqueness with polymer and maintain a dynamic level.Scintilla water is not only medium, but also is the direct participant of some important reactions.Additionally, scintilla water has extremely strong permeability and wettability, in the film forming procedure of scintilla glaze, scintilla water electrode easily escapes out by the micropore of film, does not destroy the microstructure of glaze film, thus improves the compactness of glaze film, gloss and third dimension.
For meeting user's use demand to shades of colour scintilla anion aqueous glaze, the aqueous organic pigment of shades of colour (black and white reddish yellow is blue) can be added in above-mentioned formula, aqueous organic pigment preferred scope of proportion in scintilla anion aqueous glaze is 3%-6%, and organic pigment is added in first step of preparation method.
For meeting user's requirement to metal-like in using scintilla anion aqueous glaze, aluminum paste or aluminum argentum powder can be added in above-mentioned formula, make surface of bottom material more have metal-like.Aluminum paste or the aluminum argentum powder preferred scope of proportion in scintilla anion aqueous glaze is 6%-12%, and aluminum paste or aluminum argentum powder are added in last step of preparation method.
For meeting user in using scintilla anion aqueous glaze to flicker effect, the covering power of background color, the requirement of the soft degree of gloss, can add the pearl essence of different-grain diameter in above-mentioned formula, pearl essence preferred scope of proportion in scintilla anion aqueous glaze is 6%-12%；Pearl essence is added in last step of preparation method.
Anion powder, is the principle of human use's nature generation anion, synthetic or a kind of complex mineral of proportioning, typically all tourmaline powder, lanthanide series or rare earth element.Benefit produced by anion powder application in aqueous glaze: for good and all discharge the anion to human body/environmental beneficial, its emissivities >=55000/more than cm under passive states, it will be apparent that dispelling abnormal flavor, purification air effect；Dropping to the following effect of GB after 2 days higher than harmful gass such as the formaldehyde of concentration of national standard 10 times, ammonia, stupid, fat, purifying rate, more than 90%, has obvious useful improvement to respiratory system；Strengthen product to anti-scratch performance boost more than 50%；Anti-flaming function；Weatherability promotes, and antiacid to conformance with standard (PH4.7) alkali (PH8.8) strengthens 55%.
Water paint defoamer is organic polyether ester, mineral oil, the compound product of alcohol, refine through special process and form, there is the performances such as self emulsifying, easily dispersion, highly versatile, froth breaking is good, suds is lasting, surface defect will not be produced or affect film property, aqueous glaze system is had special result.
Levelling agent is a kind of conventional glaze auxiliary agent, and it can promote glaze to form a film smooth, smooth, uniform during drying and forming-film, can effectively reduce covering with paint liquid surface tension, improve a class material of its levelability and uniformity.It can improve the permeability covering with paint, lacquer, colour wash, etc. liquid, produces speckle and the probability of spot, increase spreadability when can reduce spraying, makes film forming uniform, natural, mainly surfactant, organic solvent etc..Levelling agent kind is a lot, and different levelling agent kinds used by coating are also not quite similar, and available high boiling solvent or butyl cellulose in solvent-borne type finishing agent, then with surfactant or polyacrylic acid, carboxymethyl cellulose etc. in aqueous type finishing agent.
Wetting agent can make solid material be more easy to the material being soaked in water.By reducing its surface tension or interfacial tension, allow the water to be deployed on solid material surface or penetrate its surface, and solid material moistening.
Resist sagging auxiliary agent refers to improve the viscosity of glaze, can stop a compounds of sagging in glaze solidification or work progress.
The principle of anti-graffiti auxiliary agent divides two kinds, a kind of is that the filling by nano material realizes, another kind is then to use organosilicon, the low surface tension materials such as fluorine realize, that more conventional is the latter, is easier to add in common coating, easily constructs, but also the organosilicon auxiliary agent of reactive pattern directly participates in the solidification of film forming matter, thus obtain permanent antigraffiti effect.
Wax emulsion is used for aqueous glaze, can play the raising adhesion strength of film, hydrophobic properties of the surface and the effect of anti-stick antifouling property, make film more smooth.
The partial materialization performance parameter of scintilla anion aqueous glaze is as follows:
Adhesive force: 0 grade；Resistance to water: boiling water 3 hours is without the demoulding；Alkali resistance (0.1%NaOH): 120h；Acid resistance (0.1%HCL): 120h；Resistance to impact: 50cm；RCA is wear-resisting: 300 times.
The present invention is mainly made up of self-crosslinking baking-type, formaldehydeless core-shell copolymerized nanometer water polymeric dispersions, property of water-bearing hydroxy resin, amine resin, Magnetic reagent, scintilla water, anion powder；Scintilla anion aqueous glaze has low VOC, pollution-free, to operator's nonhazardous；Glaze layer adhesive force is strong, good hand touch, reach mirror effect, and pliability is good and hardness height.The wearability of excellence, resistance to water, resistance to alcohol, salt spray resistance, uvioresistant, aging resistance, the contaminated air etc. of environment purification, and it is simple to construct, storage is stable, and glaze film hardness, up to more than 5H, has the scratch resistance of enamel film, anti-soil by force, super abrasive performance.
This product is mainly used on the high-end metals such as magnesium alloy, aluminium alloy, magnalium, rustless steel, the Novel environment-friendlymaterial material invented accordingly for automotive substrates, automotive hub, the high-end metal of metallic door industry.
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, for a person skilled in the art, the present invention can have various change, combines and change.All within the spirit and principles in the present invention, any modification, equivalent substitution and improvement etc. made, within should be included in scope of the presently claimed invention.
Claims (10)
1. scintilla anion aqueous glaze, it is characterized in that: by weight percentage, including following component: scintilla aqueous acrylic emulsion 40% ~ 50%, scintilla aqueous epoxy resins 5% ~ 10%, full methyl-etherified amino resins 5% ~ 8%, part methyl-etherified amino resins 3% ~ 5%, defoamer 0.3% ~ 0.5%, levelling agent 0.2% ~ 0.4%, wetting agent 0.3% ~ 0.8%, resist sagging auxiliary agent 0.6% ~ 1%, anti-graffiti auxiliary agent 0.6% ~ 0.8%, wax liquid 1% ~ 1.5%, anion powder 3% ~ 15%, pH value regulator 0.1% ~ 0.5%, surplus are scintilla water.
2. scintilla anion aqueous glaze as claimed in claim 1, it is characterised in that: also include organic pigment 3% ~ 6%.
3. scintilla anion aqueous glaze as claimed in claim 1, it is characterised in that: also include aluminum paste or aluminum argentum powder 6% ~ 12%.
4. scintilla anion aqueous glaze as claimed in claim 1, it is characterised in that: also include pearl essence 6% ~ 12%.
5. scintilla anion aqueous glaze as claimed in claim 1, it is characterised in that: in described scintilla water, each water clusters is made up of 36 hydrones.
6. scintilla anion aqueous glaze as claimed in claim 1, it is characterised in that: the accounting of described scintilla water is 40% ~ 50%.
7. scintilla anion aqueous glaze as claimed in claim 1, it is characterised in that: described scintilla aqueous acrylic emulsion is that acrylic emulsion is dispersed in homopolymerization or copolymerization acquisition in scintilla water；Described scintilla aqueous epoxy resins is epoxy resin is scattered in emulsion, aqueous dispersion or the aqueous solution formed in scintilla water with microgranule, drop or colloidal form.
8. the preparation method of scintilla anion aqueous glaze as claimed in claim 1, it is characterised in that: comprise the following steps:
S1, take by weight percentage scintilla aqueous acrylic emulsion, scintilla aqueous epoxy resins, full methyl-etherified amino resins, part methyl-etherified amino resins stir 5-10 minute, rotating speed 800-1000 rev/min；
S2, take by weight percentage scintilla water, defoamer, levelling agent, wetting agent, resist sagging auxiliary agent stir 5-10 minute, rotating speed 800-1000 rev/min；
S3, take by weight percentage anti-graffiti auxiliary agent, wax liquid, anion powder stir 5-10 minute, rotating speed 800-1000 rev/min；
S4, takes pH value regulator by weight percentage and stirs 5-10 minute, rotating speed 500-800 rev/min, and product synthesizes.
9. the preparation method of scintilla anion aqueous glaze as claimed in claim 8, it is characterised in that: add organic pigment 3% ~ 6% in step sl.
10. the preparation method of scintilla anion aqueous glaze as claimed in claim 8, it is characterised in that: add aluminum paste 6% ~ 12% and/or pearl essence 6% ~ 12% in step s 4.
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| CN109111809A (en) * | 2018-07-26 | 2019-01-01 | 深圳市莱莉雅环保科技有限公司 | The single-component water-based plastic cement aluminium paint of scintilla, preparation process and spraying method |
| CN109135533A (en) * | 2018-07-26 | 2019-01-04 | 深圳市莱莉雅环保科技有限公司 | Scintilla aqueous automobile interior paint, preparation process and spraying method with graphene |
| CN109135532A (en) * | 2018-07-26 | 2019-01-04 | 深圳市莱莉雅环保科技有限公司 | The double-component aqueous PU plastic paint and its preparation process of scintilla water dispersion |
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| 陈华新 等: "《水疗健康300问》", 31 October 2013 * |
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| CN109111809A (en) * | 2018-07-26 | 2019-01-01 | 深圳市莱莉雅环保科技有限公司 | The single-component water-based plastic cement aluminium paint of scintilla, preparation process and spraying method |
| CN109135533A (en) * | 2018-07-26 | 2019-01-04 | 深圳市莱莉雅环保科技有限公司 | Scintilla aqueous automobile interior paint, preparation process and spraying method with graphene |
| CN109135532A (en) * | 2018-07-26 | 2019-01-04 | 深圳市莱莉雅环保科技有限公司 | The double-component aqueous PU plastic paint and its preparation process of scintilla water dispersion |
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Application publication date: 20161012 |