CN106009908A - Luminous printing ink and preparation method thereof - Google Patents
Luminous printing ink and preparation method thereof Download PDFInfo
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- CN106009908A CN106009908A CN201610604407.4A CN201610604407A CN106009908A CN 106009908 A CN106009908 A CN 106009908A CN 201610604407 A CN201610604407 A CN 201610604407A CN 106009908 A CN106009908 A CN 106009908A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses luminous printing ink. The luminous printing ink is prepared from the following raw materials in parts by weight: 25 to 45 parts of water-soluble acrylic modified resin, 15 to 30 parts of fluorescent powder, 15 to 30 parts of deionized water, 5 to 10 parts of ethyl alcohol, 5 to 10 parts of pigment, 1 to 2 parts of antioxygen, 0.5 to 0.8 part of dispersing agent, 0.5 to 1 part of preservative, 0.5 to 1 part of pH (Potential of Hydrogen) value stabilizer, 0.5 to 1 part of defoaming agent, 0.5 to 1.5 parts of magnetite and 0.5 to 1.5 parts of hydrotalcite. After the luminous printing ink prepared by the invention is printed on a light-colored substrate, the luminous power of the luminous printing ink is greatly enhanced, the luminous effect at night is obvious, the luminous time of the luminous printing ink is prolonged, and the luminous printing ink has a better artistic appreciation effect and better reminding ability and is suitable for being promoted and applied. Materials used by the luminous printing ink are non-benzene materials, so that the environmental protection performance is good, the health of a printing worker cannot be damaged, and extremely good color contrast property and extremely good market prospect are obtained after the luminous printing ink is used for printing; the prepared luminous printing ink has faster drying speed, good adhesion force and excellent heat resistance.
Description
Technical field
The present invention relates to printing technology, specifically a kind of Noctilucence printing ink and preparation method thereof.
Background technology
In recent years, the fluorescent ink that more and more can be used for fine screen-printing constantly occurs.The main term of fluorescent ink
Printing window display, decal paper, bumper guard, industrial insurance instrument, ads. on vehicle, letter raft, pictorial poster (poster),
24 inches of posters, notepad, signal flag, journal surface, invitation card, outdoor advertising, cloth marks etc..Due to fluorescent ink with
Huge difference between common ink color so that fluorescent ink act as weight in the open air and house ads of silk screen printing
Want role.
Fluorescent ink is luminescent material, is the material that can launch light.This material absorbs solar radiation under irradiation by sunlight
Energy storage get up, show the most in the form of heat, or photochemical reaction occur, or energy is with visible ray
Form comes out.The radiation absorbed can be than the energy wave length distributed.People, the light of absorption different colours, then distribute
Phenomenon out is referred to as fluorescence.Phenomenon luminous in dark surrounds after absorbing light is called phosphorescence.The two be not both phosphorus
Light absorbs nature light or artificial light, luminous in the dark surrounds after light is removed, and fluorescence must be at light after absorbing light
In the presence of just can be luminous.Fluorescent ink can also be luminous in the presence of " noctilucence " or purple light.But in dark
In the case of unglazed the most luminous.Fluorescent ink is not only able to show the color that he is own, and has absorbing light and change
The ability of light intensity so that the color that it shows has higher light intensity, but form and aspect (or color) are constant.
Common ink or dyestuff carry out Show Color by reflection light, and the wavelength of every kind of ink colors and output energy are the most not
With, such as reflection to red light is red, absorbs other colors.And fluorescent red not only has partially reflective redness, and it
His color (green, blue and purple) is converted into red wavelength and comes out as redness, and therefore this color seems from object
As portion radiates.The attribute of the most this luminescence makes this ink be referred to as fluorescent ink.Printer uses fluorescent ink to enter
Row printing can obtain brightness and the observability of 4 times of common inks.Fluorescent ink under dim light, such as dusk
At the crack of dawn, it appears the brightest.
The reflectance signature of common ink color and fluorescent ink color is different, and its units of measurement is angstrom.Fluorescent ink is short
Wavelength light is converted into long wavelength light and superposition produces fluorescence, by conversion and superposition, formed a kind of there is special brightness in and
The fluorescence color of observability.
Summary of the invention
It is an object of the invention to provide a kind of Noctilucence printing ink and preparation method thereof.
For achieving the above object, the present invention provides following technical scheme:
A kind of Noctilucence printing ink, is made up of the raw material of following weight parts:
Water-soluble acrylic modification resin 25～45 parts, fluorescent material 15～30 parts, deionized water 15～30 parts, ethanol 5～
10 parts, pigment 5～10 parts, antioxidant 1～2 parts, dispersant 0.5～0.8 part, preservative 0.5～1 part, pH value is steady
Determine agent 0.5～1 part, defoamer 0.5～1 part, Magnetitum 0.5～1.5 parts, brucite 0.5～1.5 parts.
Preferably, a kind of Noctilucence printing ink, it is made up of the raw material of following weight parts:
Water-soluble acrylic modification resin 25 parts, 15 parts of fluorescent material, deionized water 15 parts, ethanol 5 parts, pigment 5 parts,
1 part of antioxidant, dispersant 0.5 part, preservative 0.5 part, pH stable agent 0.5 part, defoamer 0.5 part, Magnetitum
0.5 part, brucite 0.5 part.
A kind of Noctilucence printing ink, is made up of the raw material of following weight parts:
Water-soluble acrylic modification resin 45 parts, 30 parts of fluorescent material, deionized water 30 parts, ethanol 10 parts, pigment 10
Part, 2 parts of antioxidant, dispersant 0.8 part, preservative 1 part, pH stable agent 1 part, defoamer 1 part, Magnetitum 1.5
Part, brucite 1.5 parts.
Preferably, a kind of Noctilucence printing ink, it is made up of the raw material of following weight parts:
Water-soluble acrylic modification resin 33 parts, 24 parts of fluorescent material, deionized water 22 parts, ethanol 8 parts, pigment 8 parts,
1.5 parts of antioxidant, dispersant 0.7 part, preservative 0.8 part, pH stable agent 0.8 part, defoamer 0.7 part, Magnetitum
1 part, brucite 1.2 parts.
Preferably, described fluorescent material by tricalcium orthophosphate, zinc silicate, Potassium monosulfide., barium nitrate, silver nitrate according to 1:1～3:1～
The mass ratio of 5:1～2:1～3 mixes.
Preferably, described fluorescent material by tricalcium orthophosphate, zinc silicate, Potassium monosulfide., barium nitrate, silver nitrate according to 1:2:3:1:
The mass ratio of 2 mixes.
Described pigment is the one in white carbon black, phthalocyanine color, iron oxide red, AZOpigments, quinacridone pigment.
Described Magnetitum, the particle diameter of brucite are 4～8 microns.
The preparation method of described Noctilucence printing ink, comprises the following steps:
S1, the raw water soluble acrylic modification resin of above-mentioned weight portion, fluorescent material, Magnetitum, brucite are used at a high speed
Dispersion machine carries out premixing, and its high speed dispersion time is 30～60 minutes, described high speed dispersor rotating speed be 1000～
1200r/min；
S2, by the mixture after step S1 high speed dispersion and ionized water, ethanol, pigment, antioxidant, dispersant, anticorrosion
Agent, pH stable agent, defoamer mixing, be reduced to 500～600r/min by the rotating speed of high speed dispersor, continue stirring 40～
80 minutes；
S3, the solidliquid mixture obtained by S2 are put in a container, and are sealed by container, and putting into temperature is 150～160 DEG C
Calorstat in, be immediately placed in after shelving 40～60 minutes in the refrigerator-freezer that temperature is-10 DEG C～-5 DEG C, shelve 40～60
It is immediately placed in after minute in the calorstat that temperature is 100～120 DEG C, is immediately placed in temperature after shelving 60～90 minutes and is-5 DEG C
In the refrigerator-freezer of-0 DEG C, shelve 60～90 minutes；
S3, taking out this container, the mixture using defecator to obtain step S3 carries out filtration and is allowed to purify；
S4, finally by above-mentioned finished product printing-ink filling and sealing.
Preferably, the preparation method of described Noctilucence printing ink, comprise the following steps:
S1, the raw water soluble acrylic modification resin of above-mentioned weight portion, fluorescent material, Magnetitum, brucite are used at a high speed
Dispersion machine carries out premixing, and its high speed dispersion time is 40 minutes, and described high speed dispersor rotating speed is 1100r/min；
S2, by the mixture after step S1 high speed dispersion and ionized water, ethanol, pigment, antioxidant, dispersant, anticorrosion
Agent, pH stable agent, defoamer mixing, be reduced to the rotating speed of high speed dispersor 550r/min, continue stirring 60 minutes；
S3, the solidliquid mixture obtained by S2 are put in a container, and are sealed by container, put into the perseverance that temperature is 155 DEG C
In incubator, being immediately placed in the refrigerator-freezer that temperature is-8 DEG C after shelving 50 minutes, being immediately placed in temperature after shelving 50 minutes is
In the calorstat of 110 DEG C, it is immediately placed in after shelving 80 minutes in the refrigerator-freezer that temperature is-4 DEG C, shelves 70 minutes；
S3, taking out this container, the mixture using defecator to obtain step S3 carries out filtration and is allowed to purify；
S4, finally by above-mentioned finished product printing-ink filling and sealing.
Compared with prior art, the invention has the beneficial effects as follows:
The present invention prepares the Noctilucence printing ink of gained, and after being printed on light color base material, its luminous power is greatly enhanced,
Obvious in noctilucence effect, extend its fluorescent lifetime, there is preferable effect of art appreciation and prompting ability, be suitable for pushing away
Wide application.Material used herein is without benzene series material, and the feature of environmental protection is good, without compromising on the health of printing worker, uses this
After invention printing, there is splendid color developing, market prospect.The Noctilucence printing ink that the present invention obtains have faster rate of drying,
Good adhesive force and excellent thermostability, and solvent-free volatilization, particularly filler Magnetitum and brucite, the ink obtained
Characteristic be much better than pearl filler ink.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further illustrated.
Embodiment 1
A kind of Noctilucence printing ink, is made up of the raw material of following weight parts:
Water-soluble acrylic modification resin 25 parts, 15 parts of fluorescent material, deionized water 15 parts, ethanol 5 parts, pigment 5 parts,
1 part of antioxidant, dispersant 0.5 part, preservative 0.5 part, pH stable agent 0.5 part, defoamer 0.5 part, Magnetitum
0.5 part, brucite 0.5 part.
Further, described fluorescent material by tricalcium orthophosphate, zinc silicate, Potassium monosulfide., barium nitrate, silver nitrate according to 1:1:1:1:
The mass ratio of 1 mixes.
Described pigment is the one in white carbon black, phthalocyanine color, iron oxide red, AZOpigments, quinacridone pigment.
Described Magnetitum, the particle diameter of brucite are 4～8 microns.
The preparation method of described Noctilucence printing ink, comprises the following steps:
S1, the raw water soluble acrylic modification resin of above-mentioned weight portion, fluorescent material, Magnetitum, brucite are used at a high speed
Dispersion machine carries out premixing, and its high speed dispersion time is 30 minutes, and described high speed dispersor rotating speed is 1200r/min；
S2, by the mixture after step S1 high speed dispersion and ionized water, ethanol, pigment, antioxidant, dispersant, anticorrosion
Agent, pH stable agent, defoamer mixing, be reduced to the rotating speed of high speed dispersor 500r/min, continue stirring 80 minutes；
S3, the solidliquid mixture obtained by S2 are put in a container, and are sealed by container, put into the perseverance that temperature is 150 DEG C
In incubator, being immediately placed in the refrigerator-freezer that temperature is-10 DEG C after shelving 60 minutes, being immediately placed in temperature after shelving 60 minutes is
In the calorstat of 100 DEG C, it is immediately placed in after shelving 90 minutes in the refrigerator-freezer that temperature is-5 DEG C, shelves 90 minutes；
S3, taking out this container, the mixture using defecator to obtain step S3 carries out filtration and is allowed to purify；
S4, finally by above-mentioned finished product printing-ink filling and sealing.
Embodiment 2
A kind of Noctilucence printing ink, is made up of the raw material of following weight parts:
Water-soluble acrylic modification resin 45 parts, 30 parts of fluorescent material, deionized water 30 parts, ethanol 10 parts, pigment 10
Part, 2 parts of antioxidant, dispersant 0.8 part, preservative 1 part, pH stable agent 1 part, defoamer 1 part, Magnetitum 1.5
Part, brucite 1.5 parts.
Further, described fluorescent material by tricalcium orthophosphate, zinc silicate, Potassium monosulfide., barium nitrate, silver nitrate according to 1:3:5:2:
The mass ratio of 3 mixes.
Described pigment is the one in white carbon black, phthalocyanine color, iron oxide red, AZOpigments, quinacridone pigment.
Described Magnetitum, the particle diameter of brucite are 4～8 microns.
The preparation method of described Noctilucence printing ink, comprises the following steps:
S1, the raw water soluble acrylic modification resin of above-mentioned weight portion, fluorescent material, Magnetitum, brucite are used at a high speed
Dispersion machine carries out premixing, and its high speed dispersion time is 60 minutes, and described high speed dispersor rotating speed is 1000r/min；
S2, by the mixture after step S1 high speed dispersion and ionized water, ethanol, pigment, antioxidant, dispersant, anticorrosion
Agent, pH stable agent, defoamer mixing, be reduced to the rotating speed of high speed dispersor 600r/min, continue stirring 40 minutes；
S3, the solidliquid mixture obtained by S2 are put in a container, and are sealed by container, put into the perseverance that temperature is 160 DEG C
In incubator, it is immediately placed in after shelving 40 minutes in the refrigerator-freezer that temperature is-5 DEG C, after shelving 40 minutes, is immediately placed in temperature
It is in the calorstat of 120 DEG C, is immediately placed in after shelving 60 minutes in the refrigerator-freezer that temperature is 0 DEG C, shelves 60 minutes；
S3, taking out this container, the mixture using defecator to obtain step S3 carries out filtration and is allowed to purify；
S4, finally by above-mentioned finished product printing-ink filling and sealing.
Embodiment 3
A kind of Noctilucence printing ink, is made up of the raw material of following weight parts:
Water-soluble acrylic modification resin 33 parts, 24 parts of fluorescent material, deionized water 22 parts, ethanol 8 parts, pigment 8 parts,
1.5 parts of antioxidant, dispersant 0.7 part, preservative 0.8 part, pH stable agent 0.8 part, defoamer 0.7 part, Magnetitum
1 part, brucite 1.2 parts.
Further, described fluorescent material by tricalcium orthophosphate, zinc silicate, Potassium monosulfide., barium nitrate, silver nitrate according to 1:2:3:1:
The mass ratio of 2 mixes.
Described pigment is the one in white carbon black, phthalocyanine color, iron oxide red, AZOpigments, quinacridone pigment.
Described Magnetitum, the particle diameter of brucite are 4～8 microns.
The preparation method of described Noctilucence printing ink, comprises the following steps:
S1, the raw water soluble acrylic modification resin of above-mentioned weight portion, fluorescent material, Magnetitum, brucite are used at a high speed
Dispersion machine carries out premixing, and its high speed dispersion time is 40 minutes, and described high speed dispersor rotating speed is 1100r/min；
S2, by the mixture after step S1 high speed dispersion and ionized water, ethanol, pigment, antioxidant, dispersant, anticorrosion
Agent, pH stable agent, defoamer mixing, be reduced to the rotating speed of high speed dispersor 550r/min, continue stirring 60 minutes；
S3, the solidliquid mixture obtained by S2 are put in a container, and are sealed by container, put into the perseverance that temperature is 155 DEG C
In incubator, being immediately placed in the refrigerator-freezer that temperature is-8 DEG C after shelving 50 minutes, being immediately placed in temperature after shelving 50 minutes is
In the calorstat of 110 DEG C, it is immediately placed in after shelving 80 minutes in the refrigerator-freezer that temperature is-4 DEG C, shelves 70 minutes；
S3, taking out this container, the mixture using defecator to obtain step S3 carries out filtration and is allowed to purify；
S4, finally by above-mentioned finished product printing-ink filling and sealing.
Claims (9)
1. a Noctilucence printing ink, it is characterised in that be made up of the raw material of following weight parts:
Water-soluble acrylic modification resin 25～45 parts, fluorescent material 15～30 parts, deionized water 15～30 parts, ethanol 5～
10 parts, pigment 5～10 parts, antioxidant 1～2 parts, dispersant 0.5～0.8 part, preservative 0.5～1 part, pH value is steady
Determine agent 0.5～1 part, defoamer 0.5～1 part, Magnetitum 0.5～1.5 parts, brucite 0.5～1.5 parts.
A kind of Noctilucence printing ink the most according to claim 1, it is characterised in that by the raw material system of following weight parts
Become:
Water-soluble acrylic modification resin 25 parts, 15 parts of fluorescent material, deionized water 15 parts, ethanol 5 parts, pigment 5 parts,
1 part of antioxidant, dispersant 0.5 part, preservative 0.5 part, pH stable agent 0.5 part, defoamer 0.5 part, Magnetitum
0.5 part, brucite 0.5 part.
A kind of Noctilucence printing ink the most according to claim 1, it is characterised in that by the raw material system of following weight parts
Become:
Water-soluble acrylic modification resin 45 parts, 30 parts of fluorescent material, deionized water 30 parts, ethanol 10 parts, pigment 10
Part, 2 parts of antioxidant, dispersant 0.8 part, preservative 1 part, pH stable agent 1 part, defoamer 1 part, Magnetitum 1.5
Part, brucite 1.5 parts.
A kind of Noctilucence printing ink the most according to claim 1, it is characterised in that by the raw material system of following weight parts
Become:
Water-soluble acrylic modification resin 33 parts, 24 parts of fluorescent material, deionized water 22 parts, ethanol 8 parts, pigment 8 parts,
1.5 parts of antioxidant, dispersant 0.7 part, preservative 0.8 part, pH stable agent 0.8 part, defoamer 0.7 part, Magnetitum
1 part, brucite 1.2 parts.
A kind of Noctilucence printing ink the most according to claim 1, it is characterised in that described fluorescent material by tricalcium orthophosphate,
Zinc silicate, Potassium monosulfide., barium nitrate, silver nitrate mix according to the mass ratio of 1:1～3:1～5:1～2:1～3.
A kind of Noctilucence printing ink the most according to claim 5, it is characterised in that described fluorescent material by tricalcium orthophosphate,
Zinc silicate, Potassium monosulfide., barium nitrate, silver nitrate mix according to the mass ratio of 1:2:3:1:2.
A kind of Noctilucence printing ink the most according to claim 1, it is characterised in that described pigment is white carbon black, phthalocyanine face
One in material, iron oxide red, AZOpigments, quinacridone pigment.
A kind of Noctilucence printing ink the most according to claim 1, it is characterised in that described Magnetitum, the grain of brucite
Footpath is 4～8 microns.
9. the preparation method of the Noctilucence printing ink as described in claim 1-8 any one, it is characterised in that include with
Lower step:
S1, the raw water soluble acrylic modification resin of above-mentioned weight portion, fluorescent material, Magnetitum, brucite are used at a high speed
Dispersion machine carries out premixing, and its high speed dispersion time is 30～60 minutes, described high speed dispersor rotating speed be 1000～
1200r/min；
S2, by the mixture after step S1 high speed dispersion and ionized water, ethanol, pigment, antioxidant, dispersant, anticorrosion
Agent, pH stable agent, defoamer mixing, be reduced to 500～600r/min by the rotating speed of high speed dispersor, continue stirring 40～
80 minutes；
S3, the solidliquid mixture obtained by S2 are put in a container, and are sealed by container, and putting into temperature is 150～160 DEG C
Calorstat in, be immediately placed in after shelving 40～60 minutes in the refrigerator-freezer that temperature is-10 DEG C～-5 DEG C, shelve 40～60
It is immediately placed in after minute in the calorstat that temperature is 100～120 DEG C, is immediately placed in temperature after shelving 60～90 minutes and is-5 DEG C
In the refrigerator-freezer of-0 DEG C, shelve 60～90 minutes；
S3, taking out this container, the mixture using defecator to obtain step S3 carries out filtration and is allowed to purify；
S4, finally by above-mentioned finished product printing-ink filling and sealing.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610604407.4A CN106009908A (en) | 2016-07-28 | 2016-07-28 | Luminous printing ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610604407.4A CN106009908A (en) | 2016-07-28 | 2016-07-28 | Luminous printing ink and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108334921A (en) * | 2018-02-28 | 2018-07-27 | 华南理工大学 | It is a kind of can dark positive identification luminous Quick Response Code and preparation method thereof |
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| CN108334921A (en) * | 2018-02-28 | 2018-07-27 | 华南理工大学 | It is a kind of can dark positive identification luminous Quick Response Code and preparation method thereof |
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Application publication date: 20161012 |