CN103756403B - A kind of Noctilucence printing ink - Google Patents

A kind of Noctilucence printing ink Download PDF

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Publication number
CN103756403B
CN103756403B CN201410031276.6A CN201410031276A CN103756403B CN 103756403 B CN103756403 B CN 103756403B CN 201410031276 A CN201410031276 A CN 201410031276A CN 103756403 B CN103756403 B CN 103756403B
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ink
accounts
luminescent powder
printing ink
organic solvent
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CN201410031276.6A
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CN103756403A (en
Inventor
朱家昆
朱晓珍
刘瑞
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Anhui Wanna Package Technology Co., Ltd.
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Zhu Shi Yin Wu Of Fanchang County LLC
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Abstract

The present invention relates to a kind of Noctilucence printing ink, be made up of luminescent powder, organic resin, organic solvent, dispersion agent, anti-settling agent, above-mentioned each component is respectively by mass percentage: fluorescent material accounts for 25 ~ 50%, organic resin accounts for 10 ~ 40%, organic solvent accounts for 5 ~ 30%, dispersion agent accounts for 0.5 ~ 5%, anti-settling agent accounts for 0.5 ~ 3%.The preparation method of above-mentioned ink is as follows: organic resin, organic solvent are put into container, adds dispersion agent, stir, under whipped state, add anti-settling agent, luminescent powder successively; Improve rotating speed after adding luminescent powder, until luminescent powder is dispersed in ink, filter i.e. obtained Noctilucence printing ink.Utilize the technology of the present invention to prepare the Noctilucence printing ink of gained, after being printed on light base material, its luminous power strengthens greatly, at noctilucence successful, extend its fluorescent lifetime, there is good effect of art appreciation and prompting ability, be applicable to applying.

Description

A kind of Noctilucence printing ink
Technical field
The present invention relates to a kind of Noctilucence printing ink, belong to printing technology.
Background technology
In recent years, the fluorescent ink that more and more can be used for fine screen-printing constantly occurs.Fluorescent ink main term printing window display, decal paper, bumper guard, industrial insurance instrument, ads. on vehicle, letter raft, pictorial poster (placard), 24 inches of placards, notepad, signalling pennant, journal surface, invitation card, outdoor advertising, cloth marks etc.Due to the huge difference between fluorescent ink and common ink color, fluorescent ink is made to act as key player in the open air and house ads of silk screen printing.
Fluorescent ink is luminescent material, is can radiative material.This material absorbs the energy storage of solar radiation under irradiation by sunlight, then shows in the form of heat, or photochemical reaction occurs, or energy comes out with the form of visible ray.The radiating capacity absorbed is than the energy wave length of distributing.People are the light absorbing different colours, and the phenomenon then come out is called fluorescence.Phenomenon luminous in dark surrounds after absorb light is called phosphorescence.The phosphorescence that is not both of the two absorbs natural light or artificial light, luminous in the dark surrounds after light is removed, and fluorescence must in the presence of light just can be luminous after absorb light.Fluorescent ink is deposited at " noctilucence " or purple light in case also can be luminous.But it is not luminous when dark is unglazed.Fluorescent ink not only can show his color own, and has the ability of absorb light and change light intensity, and the color that it is showed has stronger light intensity, but form and aspect (or color) are constant.
Common ink or dyestuff carry out Show Color by reflected light, and the wavelength of often kind of ink colors is also different with output energy, and such as reflection to red light is red, absorbs other colors.And fluorescent red not only has the redness of part reflection, and other colors (green, blue and purple) converted to red wavelength as redness come out, therefore this look seem radiate from interior of articles the same.The attribute of this luminescence makes this ink be called as fluorescent ink just.Printer uses fluorescent ink to carry out printing can obtain 4 times of brightness to common ink and visibility.Fluorescent ink, under dim light, at such as dusk and at the crack of dawn, seems very bright.
The reflectance signature of common ink color and fluorescent ink color is different, and its unit of measure is dust.Fluorescent ink converts long wavelength light to short-wavelength light and superposes generation fluorescence, by changing and superposing, is formed and a kind ofly has special brightness and the fluorescence color of visibility.
Summary of the invention
The object of the present invention is to provide a kind of Noctilucence printing ink, can at noctilucent printing-ink to prepare, strengthening print product can in noctilucent ability.
To achieve these goals, technical scheme of the present invention is as follows.
A kind of Noctilucence printing ink, be made up of luminescent powder, organic resin, organic solvent, dispersion agent, anti-settling agent, above-mentioned each component is respectively by mass percentage: fluorescent material accounts for 25 ~ 50%, organic resin accounts for 10 ~ 40%, organic solvent accounts for 5 ~ 30%, dispersion agent accounts for 0.5 ~ 5%, anti-settling agent accounts for 0.5 ~ 3%.
Further, described luminescent powder is mixed by sulfurated lime, magnesium sulfate, potassium sulphide, nitrate of baryta, indium nitrate, Strontium Sulphate, Silver Nitrate.
Further, described organic resin is one or several in epoxy resin, urethane resin, amino varnish, vibrin, acrylic resin, Hydroxylated acrylic resin, acroleic acid polyurethane varnish, the alkyd varnish of color and luster money, fluoro-resin.
Further, described organic solvent is one or several in ethanol, propylene glycol monomethyl ether, diethylene glycol monobutyl ether, dimethyl ether.
Further, described dispersion agent is one or several in methyl-silicone oil xylene soluble liquid, homopolymer, oxidized homopolymer, ethylene acrylic acid co polymer, ethylene vinyl acetate multipolymer, low molecule ionomer.
Further, described anti-settling agent is one or several in the N-Methyl pyrrolidone solution of aerosil, polyolefin-wax particulate, polyamide wax, modified polyurea.
The preparation method of above-mentioned ink is as follows: organic resin, organic solvent are put into container, adds dispersion agent, stir, under whipped state, add anti-settling agent, luminescent powder successively; Improve rotating speed after adding luminescent powder, until luminescent powder is dispersed in ink, filter i.e. obtained Noctilucence printing ink.
The print request of above-mentioned ink is: (1) adjusts ink viscosity according to print speed thinner.(2) in order to obtain the good printed patterns of illumination effect, select 80 ~ 120 object silk screens to carry out Plate making printing, due to the silk screen printing compared with low mesh number, layer of ink is thicker, can obtain the pattern that illumination effect is ideal.(3) under luminescent coating, use white substrate or be printed directly on white or light base material, brightness and the fluorescent lifetime of institute's impression case can be improved.(4) for obtaining the good goods of illumination effect, luminous printing ink layer thickness should at more than 150um.(5) mode of chromaticity printing is adopted.(6), in the process of printing, whole system keeps dry.(7) luminous printing ink must stir before using, and with rear attention sealing, is stored in shady and cool dry place.
This beneficial effect of the invention is: utilize the technology of the present invention to prepare the Noctilucence printing ink of gained, after being printed on light base material, its luminous power strengthens greatly, at noctilucence successful, extend its fluorescent lifetime, there is good effect of art appreciation and prompting ability, be applicable to applying.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is described, better to understand the present invention.
embodiment 1:
The Noctilucence printing ink of the present embodiment, be made up of luminescent powder, organic resin, organic solvent, dispersion agent, anti-settling agent, above-mentioned each component is respectively by mass percentage: fluorescent material accounts for 25%, organic resin accounts for 40%, organic solvent accounts for 30%, dispersion agent accounts for 2%, anti-settling agent accounts for 3%.Described luminescent powder is mixed by sulfurated lime, magnesium sulfate, potassium sulphide, nitrate of baryta, indium nitrate, Strontium Sulphate, Silver Nitrate.Described organic resin is epoxy resin, urethane resin, amino varnish mixture.Described organic solvent is ethanol, propylene glycol monomethyl ether mixture.Described dispersion agent is methyl-silicone oil xylene soluble liquid.Described anti-settling agent is aerosil.
The preparation method of above-mentioned ink is as follows: organic resin, organic solvent are put into container, adds dispersion agent, stir, under whipped state, add anti-settling agent, luminescent powder successively; Improve rotating speed after adding luminescent powder, until luminescent powder is dispersed in ink, filter i.e. obtained Noctilucence printing ink.
The print request of above-mentioned ink is: (1) adjusts ink viscosity according to print speed thinner.(2) 80 object silk screens are selected to carry out Plate making printing.(3) use white substrate or be printed directly on white or light base material.(4) luminous printing ink layer thickness is 155um.(5) mode of chromaticity printing is adopted.(6), in the process of printing, whole system keeps dry.(7) luminous printing ink must stir before using, and with rear attention sealing, is stored in shady and cool dry place.
embodiment 2:
The Noctilucence printing ink of the present embodiment, be made up of luminescent powder, organic resin, organic solvent, dispersion agent, anti-settling agent, above-mentioned each component is respectively by mass percentage: fluorescent material accounts for 50%, organic resin accounts for 20%, organic solvent accounts for 25%, dispersion agent accounts for 4%, anti-settling agent accounts for 1%.Described luminescent powder is mixed by sulfurated lime, magnesium sulfate, potassium sulphide, nitrate of baryta, indium nitrate, Strontium Sulphate, Silver Nitrate.Described organic resin is amino varnish, vibrin, acrylic resin mixture.Described organic solvent is diethylene glycol monobutyl ether, dimethyl ether mixture.Described dispersion agent is oxidized homopolymer, ethylene acrylic acid co polymer mixture.Described anti-settling agent is the N-Methyl pyrrolidone solution mixture of polyamide wax, modified polyurea.
The preparation method of above-mentioned ink is as follows: organic resin, organic solvent are put into container, adds dispersion agent, stir, under whipped state, add anti-settling agent, luminescent powder successively; Improve rotating speed after adding luminescent powder, until luminescent powder is dispersed in ink, filter i.e. obtained Noctilucence printing ink.
The print request of above-mentioned ink is: (1) adjusts ink viscosity according to print speed thinner.(2) 120 object silk screens are selected to carry out Plate making printing.(3) under luminescent coating, use white substrate or be printed directly on white or light base material.(4) luminous printing ink layer thickness is 170um.(5) mode of chromaticity printing is adopted.(6), in the process of printing, whole system keeps dry.(7) luminous printing ink must stir before using, and with rear attention sealing, is stored in shady and cool dry place.
embodiment 3:
The Noctilucence printing ink of the present embodiment, be made up of luminescent powder, organic resin, organic solvent, dispersion agent, anti-settling agent, above-mentioned each component is respectively by mass percentage: fluorescent material accounts for 40%, organic resin accounts for 30%, organic solvent accounts for 28%, dispersion agent accounts for 1%, anti-settling agent accounts for 1%.Described luminescent powder is mixed by sulfurated lime, magnesium sulfate, potassium sulphide, nitrate of baryta, indium nitrate, Strontium Sulphate, Silver Nitrate.Described organic resin is Hydroxylated acrylic resin, acroleic acid polyurethane varnish, the alkyd varnish of color and luster money, fluoro-resin mixture.Described organic solvent is propylene glycol monomethyl ether, diethylene glycol monobutyl ether, dimethyl ether mixture.Described dispersion agent is ethylene acrylic acid co polymer, ethylene vinyl acetate multipolymer, low molecule ionomer mixture.Described anti-settling agent is the N-Methyl pyrrolidone solution mixture of gas phase polyamide wax, modified polyurea.
The preparation method of above-mentioned ink is as follows: organic resin, organic solvent are put into container, adds dispersion agent, stir, under whipped state, add anti-settling agent, luminescent powder successively; Improve rotating speed after adding luminescent powder, until luminescent powder is dispersed in ink, filter i.e. obtained Noctilucence printing ink.
The print request of above-mentioned ink is: (1) adjusts ink viscosity according to print speed thinner.(2) 100 object silk screens are selected to carry out Plate making printing.(3) under luminescent coating, use white substrate or be printed directly on white or light base material.(4) luminous printing ink layer thickness is 160um.(5) mode of chromaticity printing is adopted.(6), in the process of printing, whole system keeps dry.(7) luminous printing ink must stir before using, and with rear attention sealing, is stored in shady and cool dry place.
The above is the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.

Claims (3)

1. a Noctilucence printing ink, it is characterized in that: be made up of luminescent powder, organic resin, organic solvent, dispersion agent, anti-settling agent, above-mentioned each component is respectively by mass percentage: luminescent powder accounts for 25 ~ 50%, organic resin accounts for 10 ~ 40%, organic solvent accounts for 5 ~ 30%, dispersion agent accounts for 0.5 ~ 5%, anti-settling agent accounts for 0.5 ~ 3%; Described luminescent powder is mixed by sulfurated lime, magnesium sulfate, potassium sulphide, nitrate of baryta, indium nitrate, Strontium Sulphate, Silver Nitrate; Described organic resin is one or several in epoxy resin, urethane resin, amino varnish, vibrin, acrylic resin, Hydroxylated acrylic resin, acroleic acid polyurethane varnish, the alkyd varnish of lighter color, fluoro-resin; Described organic solvent is one or several in ethanol, propylene glycol monomethyl ether, diethylene glycol monobutyl ether, dimethyl ether; Described dispersion agent is one or several in methyl-silicone oil xylene soluble liquid, homopolymer, oxidized homopolymer, ethylene acrylic acid co polymer, ethylene vinyl acetate multipolymer, low molecule ionomer; Described anti-settling agent is one or several in the N-Methyl pyrrolidone solution of aerosil, polyolefin-wax particulate, polyamide wax, modified polyurea.
2. a kind of Noctilucence printing ink according to claim 1, it is characterized in that: the preparation method of above-mentioned ink is as follows: organic resin, organic solvent are put into container, add dispersion agent, stir, under whipped state, add anti-settling agent, luminescent powder successively; Improve rotating speed after adding luminescent powder, until luminescent powder is dispersed in ink, filter i.e. obtained Noctilucence printing ink.
3. a kind of Noctilucence printing ink according to claim 1, is characterized in that: the print request of above-mentioned ink is: (1) adjusts ink viscosity according to print speed thinner; (2) 80 ~ 120 object silk screens are selected to carry out Plate making printing; (3) use white substrate or be printed directly on white or light base material; (4) luminous printing ink layer thickness should more than 150 μm; (5) mode of chromaticity printing is adopted; (6), in the process of printing, whole system keeps dry; (7) luminous printing ink must stir before using, and uses rear sealing, is stored in shady and cool dry place.
CN201410031276.6A 2014-01-23 2014-01-23 A kind of Noctilucence printing ink Expired - Fee Related CN103756403B (en)

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CN105273489A (en) * 2014-07-24 2016-01-27 李俞坤 Noctilucent ink and spray-coating method thereof
CN104263081A (en) * 2014-10-21 2015-01-07 苏州中亚油墨有限公司 Preparation method for environment-friendly long-acting luminous printing ink
CN104774495A (en) * 2015-03-28 2015-07-15 安徽美翔塑业有限公司 Environmentally friendly ink for film printing
CN105348920A (en) * 2015-11-12 2016-02-24 成都普瑞斯特新材料有限公司 Binary fluorescent anti-counterfeiting environmental-protection ink and preparation method thereof
CN105368132A (en) * 2015-12-18 2016-03-02 陈荣芳 Noctilucent printing ink and preparation method thereof
CN105348905A (en) * 2015-12-18 2016-02-24 陈荣芳 Red-light luminous ink and preparation method thereof
CN105419478A (en) * 2015-12-18 2016-03-23 陈荣芳 Luminous printing ink and preparation method thereof
CN105504962A (en) * 2015-12-18 2016-04-20 陈荣芳 Red-light luminous ink and preparation method thereof
CN105368148A (en) * 2015-12-28 2016-03-02 李栋军 Quickly-cured luminous printing ink
CN106183488A (en) * 2016-07-11 2016-12-07 鹏码实业(上海)有限公司 A kind of for false proof magnetic thermal Transfer ribbon and preparation method thereof
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CN106221376A (en) * 2016-08-19 2016-12-14 苏州市博来特油墨有限公司 The wear-resisting printing-ink of environmental protection noctilucence
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CN108299949A (en) * 2018-01-22 2018-07-20 中国石油天然气股份有限公司长庆油田分公司技术监测中心 A kind of field pressure dial plate luminous printing ink making and printing process
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CN112181156A (en) * 2020-09-10 2021-01-05 深圳市蓝晨科技股份有限公司 Fluorescent keyboard, printing method thereof and fluorescent UV gloss oil applied to fluorescent keyboard
CN112694788A (en) * 2021-01-21 2021-04-23 江阴市永乐印务有限公司 Noctilucent printing ink and preparation method thereof
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Address after: 241206 Anhui city of Wuhu province Fanchang County Sun Village Industrial Park East

Patentee after: Anhui Wanna Package Technology Co., Ltd.

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