CN112063237A - Label-free anti-counterfeiting material based on elastic stress luminescence, preparation method and anti-counterfeiting layer - Google Patents
Label-free anti-counterfeiting material based on elastic stress luminescence, preparation method and anti-counterfeiting layer Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/02—Use of particular materials as binders, particle coatings or suspension media therefor
- C09K11/025—Use of particular materials as binders, particle coatings or suspension media therefor non-luminescent particle coatings or suspension media
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/57—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing manganese or rhenium
- C09K11/572—Chalcogenides
- C09K11/576—Chalcogenides with alkaline earth metals
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
- C09K11/7743—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing terbium
- C09K11/7744—Chalcogenides
- C09K11/7746—Chalcogenides with alkaline earth metals
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Abstract
The invention discloses a label-free anti-counterfeiting material based on elastic stress luminescence, a preparation method and an anti-counterfeiting layer, wherein the label-free anti-counterfeiting material comprises the following components: a luminescent material carrier and an elastic stress luminescent material mixed in the luminescent material carrier; wherein the luminescent material carrier is ink or inkpad. The ink or inkpad mixed with the elastic stress luminescent material is applied to commodity outer package arrangement or painting and calligraphy artwork creation as the anti-counterfeiting material, and the outer package shape or the painting and calligraphy artwork of the product is lightly pressed by fingertips during anti-counterfeiting, so that the difficulty of identifying authenticity of a consumer is reduced, the problem that the traditional anti-counterfeiting label and the anti-counterfeiting mark need to be matched with the appearance of the commodity or the artwork is solved, and the elastic stress luminescent material is mixed with the ink or the inkpad easily and easily, so that the anti-counterfeiting ink or the inkpad is expected to be rapidly and widely applied to the commodity package and painting artwork anti-counterfeiting field.
Description
Technical Field
The invention belongs to the technical field of anti-counterfeiting labels, and particularly relates to a label-free anti-counterfeiting material based on elastic stress luminescence, a preparation method and an anti-counterfeiting layer.
Background
At present, counterfeit and inferior goods infringe various fields including currency, certificates, medicines, foods, household appliances, even painting and calligraphy arts and the like, and cause extremely bad social influence. Printing anti-counterfeit labels on goods and using anti-counterfeit labels are important means for resisting and preventing counterfeit products nowadays. However, the above methods all require external light recognition, and with the development of science and technology, the protection capability of many anti-counterfeit labels and tags to goods and consumers gradually deteriorates.
In the current common anti-counterfeiting means, anti-counterfeiting marks such as safety lines, two-dimensional codes and the like are difficult to fit with the appearances of commodities, particularly artworks; the requirement for binding the watermark paper in the paper anti-counterfeiting is high, and different watermark patterns need to be designed with different printing rollers, so that the individuation of the artwork is hindered; the anti-counterfeit label often can shield the details of the commodity or damage the painting and calligraphy artworks.
Accordingly, the prior art is yet to be improved and developed.
Disclosure of Invention
The invention aims to solve the technical problems that the label-free anti-counterfeiting material based on elastic stress luminescence, the preparation method and the anti-counterfeiting layer are provided aiming at overcoming the defects of the prior art, and the problems that the traditional anti-counterfeiting mark is difficult to be matched with the appearance of a commodity or an artwork, the requirement for binding the watermark paper in paper anti-counterfeiting is high, the anti-counterfeiting label can shield the details of the commodity or damage the painting and calligraphy artwork and the like are solved.
The technical scheme adopted by the invention for solving the technical problem is as follows: a label-free anti-counterfeiting material based on elastic stress luminescence, which comprises: a luminescent material carrier and an elastic stress luminescent material mixed in the luminescent material carrier; wherein the luminescent material carrier is ink or inkpad.
The label-free anti-counterfeiting material based on elastic stress luminescence comprises an elastic stress luminescence material matrix and active ions doped in the elastic stress luminescence material matrix.
The label is free from being lighted based on elastic stressThe anti-counterfeiting material comprises ZnS and SrAl as the elastic stress luminescent material matrix2O4、SrMgAl6O11、SrCaMgSi2O7、SrBaMgSi2O7、Sr2MgSi2O7、Ca2MgSi2O7、CaYAl3O7、(Ba，Ca)TiO3、ZnGa2O4、ZnAl2O4、BaAl2Si2O8、Ca2Al2SiO7、ZrO2、LiNbO3Or CaZnOS.
The label-free anti-counterfeiting material based on elastic stress luminescence, wherein the active ion is Mn2+、Cu2+Or rare earth ion RE3+One or more of; wherein RE is one or more of Tb, Eu, Dy, Ho, Er, Sm, Pr, Nd, Tm, Ce, Gd or Yb.
The label-free anti-counterfeiting material based on elastic stress luminescence is characterized in that the doping concentration of active ions in the elastic stress luminescence material is 0.5% -10%.
The label-free anti-counterfeiting material based on elastic stress luminescence is characterized in that the mass ratio of the elastic stress luminescence material to the luminescence material carrier is 0.01: 100-10: 100.
A preparation method of the label-free anti-counterfeiting material based on elastic stress luminescence comprises the following steps:
adding the elastic stress luminescent material into the luminescent material carrier, stirring, and performing ultrasonic dispersion to obtain mixed slurry; wherein the luminescent material carrier is ink;
and mixing the mixed slurry with ethanol to obtain the label-free anti-counterfeiting material based on elastic stress luminescence.
A preparation method of the label-free anti-counterfeiting material based on elastic stress luminescence comprises the following steps:
adding the elastic stress luminescent material into the luminescent material carrier to obtain a mixture; wherein the luminescent material carrier is inkpad;
mixing the mixture with ethanol to obtain a suspension;
and (4) drying the turbid liquid in an oven to obtain the label-free anti-counterfeiting material based on elastic stress luminescence.
A label-free anti-counterfeiting layer based on elastic stress luminescence, comprising: the transparent protective layer is arranged on the substrate layer; the base layer is formed by the label-free anti-counterfeiting material based on elastic stress luminescence.
The label-free anti-counterfeiting layer based on elastic stress luminescence is characterized in that the transparent protective layer is a PVC or PMMA thin film layer, and the thickness of the transparent protective layer is 0.1-0.5 mm.
The invention has the beneficial effects that: the ink or inkpad mixed with the elastic stress luminescent material is applied to commodity outer package design or painting and calligraphy artwork creation as the anti-counterfeiting material, the outer package of the product or the painting and calligraphy artwork is slightly pressed by fingertips during anti-counterfeiting, the difficulty of identifying authenticity of consumers is reduced, the problem that the traditional anti-counterfeiting label and the anti-counterfeiting mark need to be matched with the appearance of the commodity or the artwork is solved, and the elastic stress luminescent material is mixed with the ink or the inkpad easily and easily, so that the anti-counterfeiting ink or the inkpad is expected to be rapidly and widely applied to the fields of commodity packaging and painting and calligraphy artwork anti-counterfeiting.
Drawings
Fig. 1 is a schematic structural diagram of a label-free anti-counterfeit material based on elastic stress luminescence according to an embodiment of the present invention;
fig. 2 is a schematic structural diagram of a label-free anti-counterfeiting layer based on elastic stress luminescence according to an embodiment of the present invention;
FIG. 3 is a graph of an emission spectrum of the label-free anti-counterfeiting layer provided in the first embodiment of the present invention after being subjected to a compressive stress;
FIG. 4 is a diagram of a luminescent material with elastic stress according to a second embodiment of the present invention.
Detailed Description
The invention provides a label-free anti-counterfeiting material based on elastic stress luminescence, a preparation method and an anti-counterfeiting layer, and the invention is further described in detail below in order to make the purpose, technical scheme and advantages of the invention clearer and clearer. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
In recent years, in addition to the functional demand for the goods themselves, the appearance of the packaging has become an important indicator for people to select the goods, so that good packaging design can add to the goods themselves more and more for manufacturers. In addition, as the quality of life of people improves, the artwork collection and investment markets also develop rapidly. However, because of the different discrimination ability of people for artworks and the 'elaborate' counterfeiting of speculators, the counterfeit works across the market of the artworks and the counterfeit works are inundated. This greatly impairs the rights and interests of the creator and the consumer, making the entire artwork market confusing. In the current common anti-counterfeiting means, anti-counterfeiting marks such as safety lines, two-dimensional codes and the like are difficult to fit with the appearances of commodities, particularly artworks; the requirement for binding the watermark paper is high, and different watermark patterns need to be designed with different printing rollers, so that the individuation of the artwork is hindered; the anti-counterfeit label often can shield the details of the commodity or damage the painting and calligraphy artworks.
In order to solve the above problem, in this embodiment, a label-free anti-counterfeit material based on elastic stress luminescence is provided, and a specific structure is shown in fig. 1, where the label-free anti-counterfeit material includes: a luminescent material carrier 11 and an elastic stress luminescent material 12 mixed in the luminescent material carrier 11; wherein, the luminescent material carrier 11 is ink or inkpad. The elastic stress luminescent material 12 not only has the capability of direct force-light conversion, but also can repeatedly and stably emit light under the action of continuous mechanical force, and the luminous intensity is not attenuated. The elastic stress luminescent material 12 is added into ink or ink paste to obtain an anti-counterfeiting material, and the anti-counterfeiting material is hidden in the commodity outer package or the painting and calligraphy artwork creation by the traditional low-cost spin coating, screen printing, stamping and other modes, for example, the ink added with the elastic stress luminescent material is used for printing characters, patterns and the like required by the commodity outer package, and the ink paste added with the elastic stress luminescent material is used for signing in the signing area of the painting and calligraphy artwork. When anti-counterfeiting is carried out, the anti-counterfeiting area can emit obvious visible light when being touched by fingers, the anti-counterfeiting effect can be achieved without the help of external light, the design requirement of a user on the outer package of a product can be met, and the problems that the traditional anti-counterfeiting label and an anti-counterfeiting mark need to be matched with the appearance of a commodity or an artwork, and the commodity details are easily shielded or the painting artwork is damaged are solved.
Specifically, the graphite and the inkpad are various inks and inkpads sold on the market. In a specific embodiment, the graphite is water-based ink, and the inkpad is red inkpad. The water-based ink is mainly prepared by compounding and grinding water-soluble resin, organic pigment, solvent and related auxiliary agents, and is particularly suitable for packaging and printing products with strict requirements on sanitary conditions, such as cigarettes, wines, foods, beverages, medicines, toys for children and the like.
In particular, the elastic stress luminescent material 12 includes an elastic stress luminescent material matrix and active ions doped in the elastic stress luminescent material matrix. Wherein the elastic stress luminescent material matrix is ZnS or SrAl2O4、SrMgAl6O11、SrCaMgSi2O7、SrBaMgSi2O7、Sr2MgSi2O7、Ca2MgSi2O7、CaYAl3O7、(Ba，Ca)TiO3、ZnGa2O4、ZnAl2O4、BaAl2Si2O8、Ca2Al2SiO7、ZrO2、LiNbO3Or CaZnOS. In a specific embodiment, the elastic stress luminescent material matrix is CaZnOS.
Further, the activating ion is Mn2+、Cu2+Or rare earth ion RE3+One or more of; wherein RE is one or more of Tb, Eu, Dy, Ho, Er, Sm, Pr, Nd, Tm, Ce, Gd or Yb. For example, the elastic stress luminescent material is CaZnOS Tb3+、CaZnOS:Mn2+、Ca2Al2SiO7:Ce3+、SrAl2O4:Eu2+、LiNbO3:Pr3+And the like. In one embodiment, the activating ion is a transition metal Mn2+Or rare earth ion Tb3+。
In specific implementation, the luminescent color of the elastic stress luminescent material 12 changes with the doping concentration of the active ions in the elastic stress luminescent material 12. In one embodiment, the doping concentration of the active ions in the elastic stress luminescent material 12 is 0.5% to 10%.
In specific implementation, too much addition of the elastic stress luminescent material 12 in the luminescent material carrier 11 can affect the design beauty of the outer package of the product or damage the painting and calligraphy artworks; the addition amount of the elastic stress luminescent material 12 in the luminescent material carrier 11 is too small to achieve the luminescent anti-counterfeiting effect. In one embodiment, the mass ratio of the elastic stress luminescent material 12 to the luminescent material carrier 11 is 0.01:100 to 10: 100. The label-free anti-counterfeiting material is applied to product outer packaging or painting and calligraphy artworks, can be completely hidden in the appearance of a commodity or the painting and calligraphy artworks, cannot affect the product outer packaging or the painting and calligraphy artworks, and has great practical significance for maintaining the legal rights and interests of consumers and improving the discrimination of the commodity.
In addition, the invention also provides a preparation method of the label-free anti-counterfeiting material based on elastic stress luminescence, which comprises the following steps:
s1, adding the elastic stress luminescent material into the luminescent material carrier, stirring, and performing ultrasonic dispersion to obtain mixed slurry; wherein the luminescent material carrier is ink;
and S2, mixing the mixed slurry with ethanol to obtain the label-free anti-counterfeiting material based on elastic stress luminescence.
In specific implementation, when the luminescent material carrier is ink, in this embodiment, the elastic stress luminescent material is added into the luminescent material carrier, and after being fully stirred, the mixture is ultrasonically dispersed in an ultrasonic machine for 8 to 12 minutes to obtain a mixed slurry of the elastic stress luminescent material and the ink; and then uniformly mixing the mixed slurry and ethanol according to the volume ratio of 0.1: 1-100: 1 to obtain the label-free anti-counterfeiting material based on elastic stress luminescence. The elastic stress luminescent material and the printing ink or the inkpad are simple and easy to mix, and are expected to be widely applied to the fields of commodity packaging and anti-counterfeiting of calligraphy and painting artworks.
Further, before preparing the label-free anti-counterfeiting material based on elastic stress luminescence, an elastic stress luminescent material needs to be prepared, and the preparation method of the elastic stress luminescent material comprises the following steps: placing the mixture in absolute ethyl alcohol, and heating and stirring to obtain solid powder; placing the solid powder in a corundum crucible, placing the corundum crucible in a tubular furnace, and calcining under a preset condition to obtain a calcined product; and fully grinding the calcined product to obtain the elastic stress luminescent material. In a specific embodiment, the elastic stress luminescent material is CaZnOS Tb3+Or CaZnOS: Mn2+The mixture is CaCO3、ZnS、Tb(NO3)3Or Mn (NO)3)2And LiNO3The heating temperature is 50-70 ℃, and the calcining conditions are as follows: calcining for 1-3 h in inert atmosphere at 1000-1100 ℃. The elastic stress luminescent material in the embodiment has the advantages of simple preparation method and short period, and can realize mass production.
In addition, the invention also provides a preparation method of the label-free anti-counterfeiting material based on elastic stress luminescence, which comprises the following steps:
s1, adding the elastic stress luminescent material into the luminescent material carrier to obtain a mixture; wherein the luminescent material carrier is inkpad;
s2, mixing the mixture with ethanol to obtain a suspension;
and S3, drying the turbid liquid in an oven to obtain the label-free anti-counterfeiting material based on elastic stress luminescence.
In specific implementation, when the luminescent material carrier is inkpad, in this embodiment, the elastic stress luminescent material is added to the luminescent material carrier to obtain a mixture; then uniformly mixing the mixture and ethanol according to the volume ratio of 0.1: 1-100: 1 to obtain a suspension; and then, drying the suspension in a drying oven at 40-60 ℃ for 2-4 h to completely volatilize alcohol, thereby obtaining the label-free anti-counterfeiting material based on elastic stress luminescence.
In a specific embodiment, the invention further provides a label-free anti-counterfeiting layer based on elastic stress luminescence, as shown in fig. 2, the label-free anti-counterfeiting layer comprises a substrate layer 21 and a transparent protective layer 22 arranged on the substrate layer 21, and the substrate layer 21 is formed in a product outer package or a painting and calligraphy artwork by using the label-free anti-counterfeiting material based on elastic stress luminescence. The formation mode of the substrate layer 21 includes traditional low-cost spin coating, screen printing, stamping and the like, the anti-counterfeiting material is obtained by mixing the elastic stress luminescent material in ink or inkpad in the embodiment, the anti-counterfeiting material can be hidden in commodity appearance or painting and calligraphy artworks directly in the modes of spin coating, screen printing, stamping and the like, the design requirement of a user on the outer package of a product can be met, the problem that the traditional anti-counterfeiting label and the anti-counterfeiting mark are matched with the commodity or the artworks in appearance needs, and commodity details are easily shielded or the painting and calligraphy artworks are damaged is solved.
Further, the base layer 21 is covered with a protection layer 22 for protecting the base layer 21, the protection layer 22 is transparent to visible light, the protection layer 22 is a PVC or PMMA thin film layer, and the thickness of the transparent protection layer is 0.1-0.5 mm. In this embodiment, the protective layer 22 is covered on the substrate layer 21 to effectively protect the anti-counterfeit ink or the anti-counterfeit inkpad.
The ink or inkpad mixed with the elastic stress luminescent material is applied to commodity outer package design or painting and calligraphy artwork creation as the anti-counterfeiting material, and the outer package shape or the painting and calligraphy artwork of the product is lightly pressed by fingertips during anti-counterfeiting, so that the difficulty of identifying authenticity of a consumer is reduced, the problem that the traditional anti-counterfeiting label and the anti-counterfeiting mark need to be matched with the appearance of the commodity or the artwork is solved, and the elastic stress luminescent material is mixed with the ink or the inkpad easily and easily, so that the anti-counterfeiting ink or the inkpad is expected to be rapidly and widely applied to the commodity package and painting and calligraphy artwork anti-counterfeiting fields.
The invention is further illustrated by the following specific examples.
Example 1
(1) 0.4855g (4.85mmol) CaCO3、0.4873g(5mmol)ZnS、0.069mmol(0.15mmol)Mn(NO3)2And 0.0209g (0.3mmol) of LiNO3Placing the mixture in a beaker filled with 50mL of absolute ethyl alcohol to obtain a mixed solution;
(2) placing the mixed solution on a magnetic stirring table, and continuously stirring at 60 ℃ until the ethanol is completely volatilized to obtain white solid powder;
(3) placing the white powder in a corundum crucible, transferring the corundum crucible to a tubular furnace, calcining the corundum crucible in a nitrogen atmosphere at 1050 ℃ for 2 hours, and fully grinding a calcined product to obtain CaZnOS: Mn2+An elastic stress luminescent material;
(4) 0.1g of CaZnOS: Mn2+Placing in 10g of yellow water-based ink, fully stirring, and ultrasonically dispersing in an ultrasonic machine for 10min to obtain mixed slurry;
(5) uniformly mixing the mixed slurry with 1mL of ethanol to obtain yellow anti-counterfeiting ink, and applying 20 mu L of the anti-counterfeiting ink to printing characters or patterns on the outer package of the commodity to form a substrate layer on the outer package of the commodity;
(6) covering a PVC transparent film protective layer with the thickness of 0.1mm on the substrate layer, and forming a label-free anti-counterfeiting layer on the outer package of the commodity;
(7) the visible light can be emitted by scraping and touching the label-free anti-counterfeiting layer on the outer package of the commodity with fingers, the anti-counterfeiting effect can be achieved without irradiation of an ultraviolet lamp, the use of consumers is facilitated, and the competitiveness of the commodity is improved. Fig. 3 is a light emission spectrum of the label-free anti-counterfeiting layer in this embodiment after being subjected to a compressive stress, and it can be seen from fig. 3 that the label-free anti-counterfeiting layer in this embodiment emits an obvious red light (wavelength range 550nm to 750nm) after being subjected to a compressive stress.
Example 2
(1) 0.4855g (4.85mmol) CaCO3、0.4873g(5mmol)ZnS、0.069mmol(0.15mmol)Tb(NO3)2And 0.0209g (0.3mmol) of LiNO3Placing the mixture in a beaker filled with 50mL of absolute ethyl alcohol to obtain a mixed solution;
(2) placing the mixed solution on a magnetic stirring table, and continuously stirring at 60 ℃ until the ethanol is completely volatilized to obtain white solid powder;
(3) placing white powder in a corundum crucible, transferring the corundum crucible to a tubular furnace, calcining the corundum crucible in a nitrogen atmosphere at 1050 ℃ for 2 hours, and fully grinding a calcined product to obtain CaZnOS (0.05 Tb)3+An elastic stress luminescent material; FIG. 4 shows CaZnOS 0.05Tb prepared in the example of the present invention3+A topography of the elastic stress luminescent material;
(4) 0.1g of CaZnOS:0.05Tb3+Mixing in 1g red inkpad to obtain a mixture;
(5) uniformly mixing the mixture in 10mL of ethanol to obtain a thinner red inkpad suspension;
(6) drying the red inkpad suspension in a 50 ℃ oven for 3h to completely volatilize ethanol to obtain the anti-counterfeiting inkpad;
(7) printing the anti-counterfeiting inkpad to a painting and calligraphy signing area by using a stamp to form a substrate layer on the painting and calligraphy;
(8) covering a PMMA transparent film protective layer with the thickness of 0.1mm on the substrate layer to form a label-free anti-counterfeiting layer on the painting and calligraphy;
(9) the label-free anti-counterfeiting layer on the painting and calligraphy is scraped by fingers to emit obvious green light (with the wavelength ranging from 520nm to 650nm), and the anti-counterfeiting effect can be achieved without the irradiation of an ultraviolet lamp. The anti-counterfeiting inkpad is used for the final seal link of painting and calligraphy creation, so that the design step of an author on anti-counterfeiting imprints is omitted, and the cost of purchasing traditional anti-counterfeiting watermark paper by the author is greatly reduced; and consumers can more easily identify the authenticity of the painting and calligraphy artworks when purchasing the painting and calligraphy artworks, and the design of the anti-counterfeiting inkpad provides important guarantee for ensuring the health and the order of the artworks market.
In summary, the invention discloses a label-free anti-counterfeiting material based on elastic stress luminescence, a preparation method and an anti-counterfeiting layer, wherein the label-free anti-counterfeiting material comprises: a luminescent material carrier and an elastic stress luminescent material mixed in the luminescent material carrier; wherein the luminescent material carrier is ink or inkpad. The ink or inkpad mixed with the elastic stress luminescent material is applied to commodity outer package arrangement or painting and calligraphy artwork creation as the anti-counterfeiting material, and the outer package shape or the painting and calligraphy artwork of the product is lightly pressed by fingertips during anti-counterfeiting, so that the difficulty of identifying authenticity of a consumer is reduced, the problem that the traditional anti-counterfeiting label and the anti-counterfeiting mark need to be matched with the appearance of the commodity or the artwork is solved, and the mixing technology of the elastic stress luminescent material and the ink or the inkpad is simple and easy, and is expected to be rapidly and widely applied to the commodity package and painting artwork anti-counterfeiting field.
It is to be understood that the invention is not limited to the examples described above, but that modifications and variations may be effected thereto by those of ordinary skill in the art in light of the foregoing description, and that all such modifications and variations are intended to be within the scope of the invention as defined by the appended claims.
Claims (10)
1. The utility model provides a exempt from label anti-counterfeiting material based on elasticity stress is luminous which characterized in that includes: a luminescent material carrier and an elastic stress luminescent material mixed in the luminescent material carrier; wherein the luminescent material carrier is ink or inkpad.
2. The elastic stress luminescence-based label-free anti-counterfeiting material according to claim 1, wherein the elastic stress luminescence material comprises an elastic stress luminescence material matrix and active ions doped in the elastic stress luminescence material matrix.
3. The elastic stress luminescence-based label-free anti-counterfeiting material according to claim 2, wherein the elastic stress luminescence material matrix is ZnS or SrAl2O4、SrMgAl6O11、SrCaMgSi2O7、SrBaMgSi2O7、Sr2MgSi2O7、Ca2MgSi2O7、CaYAl3O7、(Ba，Ca)TiO3、ZnGa2O4、ZnAl2O4、BaAl2Si2O8、Ca2Al2SiO7、ZrO2、LiNbO3Or CaZnOS.
4. The elastic stress luminescence-based label-free anti-counterfeiting material according to claim 2, wherein the active ion is Mn2+、Cu2+Or rare earth ion RE3+One or more of; wherein RE is one or more of Tb, Eu, Dy, Ho, Er, Sm, Pr, Nd, Tm, Ce, Gd or Yb.
5. The elastic stress luminescence-based label-free anti-counterfeiting material according to claim 2, wherein the doping concentration of active ions in the elastic stress luminescence material is 0.5-10%.
6. The elastic stress luminescence-based label-free anti-counterfeiting material according to claim 1, wherein the mass ratio of the elastic stress luminescence material to the luminescence material carrier is 0.01: 100-10: 100.
7. The preparation method of the label-free anti-counterfeiting material based on elastic stress luminescence according to any one of claims 1 to 6, which is characterized by comprising the following steps:
adding the elastic stress luminescent material into the luminescent material carrier, stirring, and performing ultrasonic dispersion to obtain mixed slurry; wherein the luminescent material carrier is ink;
and mixing the mixed slurry with ethanol to obtain the label-free anti-counterfeiting material based on elastic stress luminescence.
8. The preparation method of the label-free anti-counterfeiting material based on elastic stress luminescence according to any one of claims 1 to 6, which is characterized by comprising the following steps:
adding the elastic stress luminescent material into the luminescent material carrier to obtain a mixture; wherein the luminescent material carrier is inkpad;
mixing the mixture with ethanol to obtain a suspension;
and (4) drying the turbid liquid in an oven to obtain the label-free anti-counterfeiting material based on elastic stress luminescence.
9. A label-free anti-counterfeiting layer based on elastic stress luminescence is characterized by comprising: the transparent protective layer is arranged on the substrate layer; the base layer is formed by the label-free anti-counterfeiting material based on elastic stress luminescence according to any one of claims 1 to 6.
10. The elastic stress luminescence-based label-free anti-counterfeiting layer according to claim 9, wherein the transparent protective layer is a PVC or PMMA film layer, and the thickness of the transparent protective layer is 0.1-0.5 mm.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010966934.6A CN112063237A (en) | 2020-09-15 | 2020-09-15 | Label-free anti-counterfeiting material based on elastic stress luminescence, preparation method and anti-counterfeiting layer |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112785911A (en) * | 2021-01-22 | 2021-05-11 | 深圳前海蓝莓文化传播有限公司 | Luminous anti-counterfeit label and preparation method thereof |
| CN112898828A (en) * | 2021-01-15 | 2021-06-04 | 深圳劲嘉集团股份有限公司 | Stress luminous anti-counterfeiting ink, preparation method and use method |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006022455A (en) * | 2004-07-09 | 2006-01-26 | National Institute Of Advanced Industrial & Technology | Sheet-like stress-induced light-emitting structure containing stress-induced light-emitting material and its utilization |
| CN1772836A (en) * | 2004-07-26 | 2006-05-17 | 独立行政法人产业技术综合研究所 | Stress-luminescent composition containing anisotropic stress-luminescent material, and method of producing the same |
| JP2010188671A (en) * | 2009-02-19 | 2010-09-02 | Dainippon Printing Co Ltd | Securities |
| WO2015159919A1 (en) * | 2014-04-15 | 2015-10-22 | 大日本印刷株式会社 | Light-emitting paper, counterfeit-preventing medium, and packaging container |
| JP2016204526A (en) * | 2015-04-23 | 2016-12-08 | 共同印刷株式会社 | Stress luminescent material-containing ink and printed matter of the same |
| WO2017109867A1 (en) * | 2015-12-22 | 2017-06-29 | 日本たばこ産業株式会社 | Packaging blank and packaging box |
| CN110240898A (en) * | 2019-07-08 | 2019-09-17 | 上海洞舟实业有限公司 | A kind of preparation and application of flexible extensible stress irradiance device |
-
2020
- 2020-09-15 CN CN202010966934.6A patent/CN112063237A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006022455A (en) * | 2004-07-09 | 2006-01-26 | National Institute Of Advanced Industrial & Technology | Sheet-like stress-induced light-emitting structure containing stress-induced light-emitting material and its utilization |
| CN1772836A (en) * | 2004-07-26 | 2006-05-17 | 独立行政法人产业技术综合研究所 | Stress-luminescent composition containing anisotropic stress-luminescent material, and method of producing the same |
| JP2010188671A (en) * | 2009-02-19 | 2010-09-02 | Dainippon Printing Co Ltd | Securities |
| WO2015159919A1 (en) * | 2014-04-15 | 2015-10-22 | 大日本印刷株式会社 | Light-emitting paper, counterfeit-preventing medium, and packaging container |
| JP2016204526A (en) * | 2015-04-23 | 2016-12-08 | 共同印刷株式会社 | Stress luminescent material-containing ink and printed matter of the same |
| WO2017109867A1 (en) * | 2015-12-22 | 2017-06-29 | 日本たばこ産業株式会社 | Packaging blank and packaging box |
| CN110240898A (en) * | 2019-07-08 | 2019-09-17 | 上海洞舟实业有限公司 | A kind of preparation and application of flexible extensible stress irradiance device |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112898828A (en) * | 2021-01-15 | 2021-06-04 | 深圳劲嘉集团股份有限公司 | Stress luminous anti-counterfeiting ink, preparation method and use method |
| CN112785911A (en) * | 2021-01-22 | 2021-05-11 | 深圳前海蓝莓文化传播有限公司 | Luminous anti-counterfeit label and preparation method thereof |
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