CN105968597A - Waterproof coiled material and preparation method thereof - Google Patents
Waterproof coiled material and preparation method thereof Download PDFInfo
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- CN105968597A CN105968597A CN201610336030.9A CN201610336030A CN105968597A CN 105968597 A CN105968597 A CN 105968597A CN 201610336030 A CN201610336030 A CN 201610336030A CN 105968597 A CN105968597 A CN 105968597A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
- C08L23/286—Chlorinated polyethylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a waterproof coiled material and a preparation method thereof. The preparation method comprises the following steps: (1) adding chlorinated polyethylene, high-density polyethylene, styrene-butadiene rubber, chloroprene rubber, rubber powder and carboxymethyl cellulose into a Banbury mixer, and banburying for 10-15 minutes; (2) adding coco fatty acid diethanol amide, N,N'-diphenyl-para-phenylene diamine, N-phenyl-alpha-aniline, zinc oxide, pentaerythritol, tributyl citrate, glyceryl triacetate, tall oil and silicone oil, and continuing banburying for 15-20 minutes; (3) plasticizing at 23-27 DEG C for 15-20 minutes; (4) carrying out rubber filter extrusion by using a rubber filter extruder; and (5) adding into a flat vulcanizing machine, and carrying out pelleting forming, wherein the vulcanizing temperature is 140-160 DEG C, and the vulcanizing time is 15-20 minutes. The waterproof coiled material has the advantages of favorable mechanical properties, favorable elasticity, favorable toughness, excellent waterproofness and favorable waterproof effect.
Description
Technical field
The present invention relates to Material Field, be specifically related to a kind of waterproof roll and preparation method thereof.
Background technology
Along with the fast development of economic science and technology, all trades and professions are increasing for the demand of material, and performance requirement is more and more higher, and the performance of many materials can not meet all trades and professions demand high performance to material.Wherein, waterproof roll is mainly used for construction wall, roofing and tunnel, highway, refuse landfill etc., play the flexible building material product of a kind of rollable one-tenth web-like resisting extraneous rainwater, subsoil water seepage, it is connected as ne-leakage between engineering foundation with building, it is the first barrier of whole engineering waterproofing, whole engineering is played vital effect.Therefore, novel waterproof roll is researched and developed further, it is thus achieved that more superior mechanical property and water resistance, the development for every profession and trade all has great importance, and has wide market prospect.
Summary of the invention
Solve the technical problem that:It is an object of the invention to provide a kind of waterproof roll, there is good mechanical property, elastic good with toughness, the most also there is the water resistance of brilliance, good water-proof effect.
Technical scheme:A kind of waterproof roll, it is prepared from weight portion by following component: chlorinated polyethylene 30-50 part, high density polyethylene (HDPE) 20-40 part, butadiene-styrene rubber 10-20 part, neoprene 10-20 part, rubber powder 10-20 part, carboxymethyl cellulose 5-8 part, lauric acid amide of ethanol 2-5 part, N, N'-diphenyl-para-phenylene diamine's 1-3 part, N-phenyl-α-aniline 1-2 part, zinc oxide 1-3 part, tetramethylolmethane 2-5 part, tributyl citrate 3-6 part, glyceryl triacetate 2-3 part, tall oil 2-4 part, silicone oil 2-4 part.
Further preferred, described a kind of waterproof roll, it is prepared from weight portion by following component: chlorinated polyethylene 35-45 part, high density polyethylene (HDPE) 25-35 part, butadiene-styrene rubber 12-17 part, neoprene 12-18 part, rubber powder 11-17 part, carboxymethyl cellulose 6-7 part, lauric acid amide of ethanol 3-4 part, N, N'-diphenyl-para-phenylene diamine's 1.5-2.5 part, N-phenyl-α-aniline 1.3-1.7 part, zinc oxide 1.5-2.5 part, tetramethylolmethane 3-4 part, tributyl citrate 4-5 part, glyceryl triacetate 2.3-2.8 part, tall oil 2.5-3.5 part, silicone oil 2.5-3.5 part.
The preparation method of above-mentioned waterproof roll comprises the following steps:
(1) chlorinated polyethylene, high density polyethylene (HDPE), butadiene-styrene rubber, neoprene, rubber powder and carboxymethyl cellulose addition banbury will carry out banburying 10-15 minute；
(2) lauric acid amide of ethanol, N are added, N'-diphenyl-para-phenylene diamine, N-phenyl-α-aniline, zinc oxide, tetramethylolmethane, tributyl citrate, glyceryl triacetate, tall oil and silicone oil, continue banburying 15-20 minute；
(3) carry out plasticating 15-20 minute at temperature 23-27 DEG C；
(4) carry out filtering glue extrusion with filter rubber extruding machine；
(5) adding in vulcanizing press and carry out compression molding and get final product, curing temperature is 140-160 DEG C, and cure time is 15-20 minute.
It is further preferred that in step (1) the banburying time be 11-14 minute.
It is further preferred that in step (2) the banburying time be 16-19 minute.
It is further preferred that temperature is 24-26 DEG C in step (3), the time of plasticating is 16-19 minute.
It is further preferred that curing temperature is 145-155 DEG C in step (5), cure time is 16-19 minute.
Beneficial effect:The waterproof roll of the present invention has good mechanical property, and its hot strength reaches as high as 21.7MPa, and elongation at break is 599%, there is good elasticity and toughness, the present invention also has the water resistance of brilliance simultaneously, still ne-leakage, good water-proof effect after 60min under pressure 0.4MPa.
Detailed description of the invention
Embodiment 1
A kind of waterproof roll, it is prepared from weight portion by following component: chlorinated polyethylene 30 parts, high density polyethylene (HDPE) 20 parts, 10 parts of butadiene-styrene rubber, neoprene 10 parts, rubber powder 10 parts, carboxymethyl cellulose 5 parts, lauric acid amide of ethanol 2 parts, N, N'-diphenyl-para-phenylene diamine 1 part, N-phenyl-α-aniline 1 part, zinc oxide 1 part, tetramethylolmethane 2 parts, tributyl citrate 3 parts, glyceryl triacetate 2 parts, tall oil 2 parts, silicone oil 2 parts.
The preparation method of above-mentioned waterproof roll is:
(1) chlorinated polyethylene, high density polyethylene (HDPE), butadiene-styrene rubber, neoprene, rubber powder and carboxymethyl cellulose addition banbury will carry out banburying 10 minutes；
(2) lauric acid amide of ethanol, N are added, N'-diphenyl-para-phenylene diamine, N-phenyl-α-aniline, zinc oxide, tetramethylolmethane, tributyl citrate, glyceryl triacetate, tall oil and silicone oil, continue banburying 15 minutes；
(3) carry out plasticating 15 minutes at temperature 23 DEG C；
(4) carry out filtering glue extrusion with filter rubber extruding machine；
(5) adding in vulcanizing press and carry out compression molding and get final product, curing temperature is 140 DEG C, and cure time is 15 minutes.
Embodiment 2
A kind of waterproof roll, it is prepared from weight portion by following component: chlorinated polyethylene 35 parts, high density polyethylene (HDPE) 25 parts, 12 parts of butadiene-styrene rubber, neoprene 12 parts, rubber powder 11 parts, carboxymethyl cellulose 6 parts, lauric acid amide of ethanol 3 parts, N, N'-diphenyl-para-phenylene diamine 1.5 parts, N-phenyl-α-aniline 1.3 parts, zinc oxide 1.5 parts, tetramethylolmethane 3 parts, tributyl citrate 4 parts, glyceryl triacetate 2.3 parts, tall oil 2.5 parts, silicone oil 2.5 parts.
The preparation method of above-mentioned waterproof roll is:
(1) chlorinated polyethylene, high density polyethylene (HDPE), butadiene-styrene rubber, neoprene, rubber powder and carboxymethyl cellulose addition banbury will carry out banburying 11 minutes；
(2) lauric acid amide of ethanol, N are added, N'-diphenyl-para-phenylene diamine, N-phenyl-α-aniline, zinc oxide, tetramethylolmethane, tributyl citrate, glyceryl triacetate, tall oil and silicone oil, continue banburying 16 minutes；
(3) carry out plasticating 16 minutes at temperature 24 DEG C；
(4) carry out filtering glue extrusion with filter rubber extruding machine；
(5) adding in vulcanizing press and carry out compression molding and get final product, curing temperature is 145 DEG C, and cure time is 16 minutes.
Embodiment 3
A kind of waterproof roll, it is prepared from weight portion by following component: chlorinated polyethylene 40 parts, high density polyethylene (HDPE) 30 parts, 15 parts of butadiene-styrene rubber, neoprene 15 parts, rubber powder 15 parts, carboxymethyl cellulose 6.5 parts, lauric acid amide of ethanol 3.5 parts, N, N'-diphenyl-para-phenylene diamine 2 parts, N-phenyl-α-aniline 1.5 parts, zinc oxide 2 parts, tetramethylolmethane 3.5 parts, tributyl citrate 4.5 parts, glyceryl triacetate 2.5 parts, tall oil 3 parts, silicone oil 3 parts.
The preparation method of above-mentioned waterproof roll is:
(1) chlorinated polyethylene, high density polyethylene (HDPE), butadiene-styrene rubber, neoprene, rubber powder and carboxymethyl cellulose addition banbury will carry out banburying 12 minutes；
(2) lauric acid amide of ethanol, N are added, N'-diphenyl-para-phenylene diamine, N-phenyl-α-aniline, zinc oxide, tetramethylolmethane, tributyl citrate, glyceryl triacetate, tall oil and silicone oil, continue banburying 17 minutes；
(3) carry out plasticating 17 minutes at temperature 25 DEG C；
(4) carry out filtering glue extrusion with filter rubber extruding machine；
(5) adding in vulcanizing press and carry out compression molding and get final product, curing temperature is 150 DEG C, and cure time is 17 minutes.
Embodiment 4
A kind of waterproof roll, it is prepared from weight portion by following component: chlorinated polyethylene 45 parts, high density polyethylene (HDPE) 35 parts, 17 parts of butadiene-styrene rubber, neoprene 18 parts, rubber powder 17 parts, carboxymethyl cellulose 7 parts, lauric acid amide of ethanol 4 parts, N, N'-diphenyl-para-phenylene diamine 2.5 parts, N-phenyl-α-aniline 1.7 parts, zinc oxide 2.5 parts, tetramethylolmethane 4 parts, tributyl citrate 5 parts, glyceryl triacetate 2.8 parts, tall oil 3.5 parts, silicone oil 3.5 parts.
The preparation method of above-mentioned waterproof roll is:
(1) chlorinated polyethylene, high density polyethylene (HDPE), butadiene-styrene rubber, neoprene, rubber powder and carboxymethyl cellulose addition banbury will carry out banburying 14 minutes；
(2) lauric acid amide of ethanol, N are added, N'-diphenyl-para-phenylene diamine, N-phenyl-α-aniline, zinc oxide, tetramethylolmethane, tributyl citrate, glyceryl triacetate, tall oil and silicone oil, continue banburying 19 minutes；
(3) carry out plasticating 19 minutes at temperature 26 DEG C；
(4) carry out filtering glue extrusion with filter rubber extruding machine；
(5) adding in vulcanizing press and carry out compression molding and get final product, curing temperature is 155 DEG C, and cure time is 19 minutes.
Embodiment 5
A kind of waterproof roll, it is prepared from weight portion by following component: chlorinated polyethylene 50 parts, high density polyethylene (HDPE) 40 parts, 20 parts of butadiene-styrene rubber, neoprene 20 parts, rubber powder 20 parts, carboxymethyl cellulose 8 parts, lauric acid amide of ethanol 5 parts, N, N'-diphenyl-para-phenylene diamine 3 parts, N-phenyl-α-aniline 2 parts, zinc oxide 3 parts, tetramethylolmethane 5 parts, tributyl citrate 6 parts, glyceryl triacetate 3 parts, tall oil 4 parts, silicone oil 4 parts.
The preparation method of above-mentioned waterproof roll is:
(1) chlorinated polyethylene, high density polyethylene (HDPE), butadiene-styrene rubber, neoprene, rubber powder and carboxymethyl cellulose addition banbury will carry out banburying 15 minutes；
(2) lauric acid amide of ethanol, N are added, N'-diphenyl-para-phenylene diamine, N-phenyl-α-aniline, zinc oxide, tetramethylolmethane, tributyl citrate, glyceryl triacetate, tall oil and silicone oil, continue banburying 20 minutes；
(3) carry out plasticating 20 minutes at temperature 27 DEG C；
(4) carry out filtering glue extrusion with filter rubber extruding machine；
(5) adding in vulcanizing press and carry out compression molding and get final product, curing temperature is 160 DEG C, and cure time is 20 minutes.
Comparative example 1
The present embodiment is to replace neoprene with butadiene-styrene rubber with the difference of embodiment 5.Specifically:
A kind of waterproof roll, it is prepared from weight portion by following component: chlorinated polyethylene 50 parts, high density polyethylene (HDPE) 40 parts, 40 parts of butadiene-styrene rubber, rubber powder 20 parts, carboxymethyl cellulose 8 parts, lauric acid amide of ethanol 5 parts, N, N'-diphenyl-para-phenylene diamine 3 parts, N-phenyl-α-aniline 2 parts, zinc oxide 3 parts, tetramethylolmethane 5 parts, tributyl citrate 6 parts, glyceryl triacetate 3 parts, tall oil 4 parts, silicone oil 4 parts.
The preparation method of above-mentioned waterproof roll is:
(1) chlorinated polyethylene, high density polyethylene (HDPE), butadiene-styrene rubber, rubber powder and carboxymethyl cellulose addition banbury will carry out banburying 15 minutes；
(2) lauric acid amide of ethanol, N are added, N'-diphenyl-para-phenylene diamine, N-phenyl-α-aniline, zinc oxide, tetramethylolmethane, tributyl citrate, glyceryl triacetate, tall oil and silicone oil, continue banburying 20 minutes；
(3) carry out plasticating 20 minutes at temperature 27 DEG C；
(4) carry out filtering glue extrusion with filter rubber extruding machine；
(5) adding in vulcanizing press and carry out compression molding and get final product, curing temperature is 160 DEG C, and cure time is 20 minutes.
Comparative example 2
The present embodiment is not contain carboxymethyl cellulose with the difference of embodiment 5.Specifically:
A kind of waterproof roll, it is prepared from weight portion by following component: chlorinated polyethylene 50 parts, high density polyethylene (HDPE) 40 parts, 20 parts of butadiene-styrene rubber, neoprene 20 parts, rubber powder 20 parts, lauric acid amide of ethanol 5 parts, N, N'-diphenyl-para-phenylene diamine 3 parts, N-phenyl-α-aniline 2 parts, zinc oxide 3 parts, tetramethylolmethane 5 parts, tributyl citrate 6 parts, glyceryl triacetate 3 parts, tall oil 4 parts, silicone oil 4 parts.
The preparation method of above-mentioned waterproof roll is:
(1) chlorinated polyethylene, high density polyethylene (HDPE), butadiene-styrene rubber, neoprene and rubber powder addition banbury will carry out banburying 15 minutes；
(2) lauric acid amide of ethanol, N are added, N'-diphenyl-para-phenylene diamine, N-phenyl-α-aniline, zinc oxide, tetramethylolmethane, tributyl citrate, glyceryl triacetate, tall oil and silicone oil, continue banburying 20 minutes；
(3) carry out plasticating 20 minutes at temperature 27 DEG C；
(4) carry out filtering glue extrusion with filter rubber extruding machine；
(5) adding in vulcanizing press and carry out compression molding and get final product, curing temperature is 160 DEG C, and cure time is 20 minutes.
Table 1 below is embodiment and the performance indications of comparative example of material of the present invention, it may be seen that, first the present invention has good mechanical property, its hot strength reaches as high as 21.7MPa, elongation at break is 599%, has good elasticity and toughness, and the present invention also has the water resistance of brilliance simultaneously, still ne-leakage, good water-proof effect after 60min under pressure 0.4MPa.
The partial properties index of table 1 waterproof roll
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example 1 | Comparative example 2 | |
| Hot strength (MPa) | 21.3 | 21.4 | 21.5 | 21.7 | 21.6 | 20.6 | 18.5 |
| Elongation at break (%) | 594 | 596 | 597 | 599 | 597 | 593 | 574 |
| Water proofing property (0.4MPa, 60min) | Ne-leakage | Ne-leakage | Ne-leakage | Ne-leakage | Ne-leakage | Slightly seepage | Ne-leakage |
Claims (7)
1. a waterproof roll, it is characterized in that: be prepared from weight portion by following component: chlorinated polyethylene 30-50 part, high density polyethylene (HDPE) 20-40 part, butadiene-styrene rubber 10-20 part, neoprene 10-20 part, rubber powder 10-20 part, carboxymethyl cellulose 5-8 part, lauric acid amide of ethanol 2-5 part, N, N'-diphenyl-para-phenylene diamine's 1-3 part, N-phenyl-α-aniline 1-2 part, zinc oxide 1-3 part, tetramethylolmethane 2-5 part, tributyl citrate 3-6 part, glyceryl triacetate 2-3 part, tall oil 2-4 part, silicone oil 2-4 part.
A kind of waterproof roll the most according to claim 1, it is characterized in that: be prepared from weight portion by following component: chlorinated polyethylene 35-45 part, high density polyethylene (HDPE) 25-35 part, butadiene-styrene rubber 12-17 part, neoprene 12-18 part, rubber powder 11-17 part, carboxymethyl cellulose 6-7 part, lauric acid amide of ethanol 3-4 part, N, N'-diphenyl-para-phenylene diamine's 1.5-2.5 part, N-phenyl-α-aniline 1.3-1.7 part, zinc oxide 1.5-2.5 part, tetramethylolmethane 3-4 part, tributyl citrate 4-5 part, glyceryl triacetate 2.3-2.8 part, tall oil 2.5-3.5 part, silicone oil 2.5-3.5 part.
3. the preparation method of a kind of waterproof roll described in any one of claim 1 to 2, it is characterised in that: comprise the following steps:
(1) chlorinated polyethylene, high density polyethylene (HDPE), butadiene-styrene rubber, neoprene, rubber powder and carboxymethyl cellulose addition banbury will carry out banburying 10-15 minute；
(2) lauric acid amide of ethanol, N are added, N'-diphenyl-para-phenylene diamine, N-phenyl-α-aniline, zinc oxide, tetramethylolmethane, tributyl citrate, glyceryl triacetate, tall oil and silicone oil, continue banburying 15-20 minute；
(3) carry out plasticating 15-20 minute at temperature 23-27 DEG C；
(4) carry out filtering glue extrusion with filter rubber extruding machine；
(5) adding in vulcanizing press and carry out compression molding and get final product, curing temperature is 140-160 DEG C, and cure time is 15-20 minute.
The preparation method of a kind of waterproof roll the most according to claim 3, it is characterised in that: in described step (1), the banburying time is 11-14 minute.
The preparation method of a kind of waterproof roll the most according to claim 3, it is characterised in that: in described step (2), the banburying time is 16-19 minute.
The preparation method of a kind of waterproof roll the most according to claim 3, it is characterised in that: in described step (3), temperature is 24-26 DEG C, and the time of plasticating is 16-19 minute.
The preparation method of a kind of waterproof roll the most according to claim 3, it is characterised in that: in described step (5), curing temperature is 145-155 DEG C, and cure time is 16-19 minute.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610336030.9A CN105968597A (en) | 2016-05-20 | 2016-05-20 | Waterproof coiled material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610336030.9A CN105968597A (en) | 2016-05-20 | 2016-05-20 | Waterproof coiled material and preparation method thereof |
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| CN105968597A true CN105968597A (en) | 2016-09-28 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610336030.9A Pending CN105968597A (en) | 2016-05-20 | 2016-05-20 | Waterproof coiled material and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109627612A (en) * | 2018-11-07 | 2019-04-16 | 固安金盾时代建筑防水材料有限公司 | A kind of energy conservation and environmental protection polymer membranes and preparation method thereof |
| WO2023136130A1 (en) * | 2022-01-17 | 2023-07-20 | 日本製紙株式会社 | Rubber composition and method for producing same |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1986719A (en) * | 2006-12-21 | 2007-06-27 | 绍兴市油毛毡厂 | Chlorinated polyethylene rubber waterproof coiled material and production method thereof |
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2016
- 2016-05-20 CN CN201610336030.9A patent/CN105968597A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1986719A (en) * | 2006-12-21 | 2007-06-27 | 绍兴市油毛毡厂 | Chlorinated polyethylene rubber waterproof coiled material and production method thereof |
Non-Patent Citations (1)
| Title |
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| 赵鹿合: ""氯化聚乙烯/氯丁橡胶/丁苯橡胶难燃防水卷材的研制"", 《橡胶工业》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109627612A (en) * | 2018-11-07 | 2019-04-16 | 固安金盾时代建筑防水材料有限公司 | A kind of energy conservation and environmental protection polymer membranes and preparation method thereof |
| WO2023136130A1 (en) * | 2022-01-17 | 2023-07-20 | 日本製紙株式会社 | Rubber composition and method for producing same |
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Application publication date: 20160928 |