CN103772763A - Rubber composite and preparation process thereof - Google Patents
Rubber composite and preparation process thereof Download PDFInfo
- Publication number
- CN103772763A CN103772763A CN201310721252.9A CN201310721252A CN103772763A CN 103772763 A CN103772763 A CN 103772763A CN 201310721252 A CN201310721252 A CN 201310721252A CN 103772763 A CN103772763 A CN 103772763A
- Authority
- CN
- China
- Prior art keywords
- agent
- rubber
- mixing
- rubber composite
- promotor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses a rubber composite and a preparation process thereof. The rubber composite is composed of a rubber raw material, a white smoke activating agent, a plasticizer, an activating agent, an anti-aging agent, a coupling agent, an accelerant and sulfur, wherein the rubber raw material is prepared by mixing acrylonitrile-butadiene rubber, butadiene rubber and standard rubber. By using the rubber composite, the strength and abrasion performance of a rubber-plastic blending material are improved, and thus, the obtained rubber composite not only is kept soft, elastic and antiskid, but also has favorable abrasion performance.
Description
?
Technical field
The present invention relates to a kind of matrix material, be especially specifically designed to the rubber composite of the assemblies such as footwear material, sports goods, leather.
?
Background technology
Existing EVA adopts the material modified making method of POE mostly, material modified applicable injection moulding and compression molding, can be widely used in footwear outer bottom, sports goods and other light industry product, it is prepared burden by 50-95% EVA, 5-40% POE (polyolefin elastomer), 5-20% talcum powder or CaC0., metal oxide foretells 2%, lubricant 0. foretells 1%, superoxide (bridging agent) 0.4 one 1%, azo foaming agent foretell 4% and appropriate pigment mix through Banbury mixer, auxiliary mixed, the pelletizing of mill, injection moulding or compression molding.Its finished product of EVA composition of existing employing POE (polyethylene hydrocarbon elastomerics) modification is light, moulding is also easier, but the flexibility of its material and elasticity are not good enough, even if part flexibility reaches requirement, its intensity is still poor, and particularly abrasion performance is undesirable.
Summary of the invention
In order to overcome above shortcomings part in prior art, the object of the present invention is to provide a kind of rubber composite that there is high strength and high abrasion resistance energy, retained again the resilient flexible of rubber simultaneously.
In order to reach above-mentioned object, the present invention adopts following concrete technical scheme: rubber composite, formed by rubber raw materials, white smoke active agent, softening agent, promoting agent, anti-aging agent, coupling agent, promotor and Sulfur, the weight proportion of above-mentioned each component is: 100% compounded rubber, 2-10% white smoke active agent, 5-15% softening agent, 0.5-10 promoting agent, 0.5-5% anti-aging agent, 1-10% coupling agent, 0.5-5% promotor, 0.5-5% Sulfur
Concrete composition and the proportioning of the each component of wherein said rubber raw materials are as follows:
Paracril 60-90%
Cis-1,4-polybutadiene rubber 5-20%
Mark glue 5-20%.
Further, softening agent of the present invention adopts phthalic ester.
Further, promoting agent of the present invention adopts mixing of stearic acid and zinc carbonate, and its proportioning is 1:12.
Further, anti-aging agent of the present invention adopts Microcrystalline Wax.
Further, coupling agent of the present invention adopts silane coupling agent.
Further, promotor of the present invention adopts triethylene diamine promotor.
The manufacture craft of above-mentioned rubber composite comprises following steps:
1) by above-mentioned rubber raw materials, white smoke active agent, softening agent, promoting agent, anti-aging agent, coupling agent, promotor by said ratio in Banbury mixer fully mixing evenly;
2) by mixing the mixing material obtaining through above-mentioned steps 1 to set the temperature of Celsius 105 ℃ one 120 ℃, after mixing 8 minutes, add and Sulfur;
3) mixing material obtaining through above-mentioned steps 2 is continued after mixing 2 minutes to discharge after temperature reaches Celsius 110 ℃ one 160 ℃;
4) mixing material that meets discharge condition is further mixed after 3 minutes through mill (Celsius 70 ℃ one 80 ℃ of roller temperature), manufacture granular composition, can obtain described rubber composite.
The present invention's advantage is compared with prior art: the present invention has improved intensity and the abrasion resistance of rubber plastic blend body material, and the rubber composite that makes to obtain had both kept softness, elasticity, anti-skidding and good abrasion resistance.
?
Embodiment
Can further understand basis by the embodiment of the present invention given below bright, but protection of the present invention is not limited to this.
Embodiment 1:
Rubber composite, is made up of rubber raw materials, white smoke active agent, softening agent, promoting agent, anti-aging agent, coupling agent, promotor and Sulfur, and the weight proportion of above-mentioned each component is:
Compounded rubber: 100kg, its proportioning is 90kg paracril, 5kg cis-1,4-polybutadiene rubber, 5kg marks glue;
White smoke active agent is 8kg;
Softening agent: the phthalic ester that adopts 13kg;
Promoting agent: adopt mixing of the stearic acid of 1kg and the zinc carbonate of 12kg;
Anti-aging agent: the Microcrystalline Wax that adopts 1kg;
Coupling agent: the silane coupling agent that adopts 5kg;
Promotor: the triethylene diamine promotor that adopts 4kg;
Sulfur is 4kg;
Its manufacture craft is as follows:
1) by above-mentioned 100kg rubber raw materials, 8kg white smoke active agent, 13kg softening agent, 13kg promoting agent, 1 anti-aging agent, 5kg coupling agent, 4kg promotor by said ratio in Banbury mixer fully mixing evenly;
2) by mixing the mixing material obtaining through above-mentioned steps 1 to set the temperature of Celsius 105 ℃ one 120 ℃, after mixing 8 minutes, add the Sulfur with 4kg;
3) mixing material obtaining through above-mentioned steps 2 is continued after mixing 2 minutes to discharge after temperature reaches Celsius 110 ℃ one 160 ℃;
4) mixing material that meets discharge condition is further mixed after 3 minutes through mill (Celsius 70 ℃ one 80 ℃ of roller temperature), manufacture granular composition, can obtain described rubber composite.
Embodiment 2:
Rubber composite, is made up of rubber raw materials, white smoke active agent, softening agent, promoting agent, anti-aging agent, coupling agent, promotor and Sulfur, and the weight proportion of above-mentioned each component is:
Compounded rubber: 100kg, its proportioning is 80kg paracril, 10kg cis-1,4-polybutadiene rubber, 10kg marks glue;
White smoke active agent is 5kg;
Softening agent: the phthalic ester that adopts 10kg;
Promoting agent: adopt mixing of the stearic acid of 0.5kg and the zinc carbonate of 6kg;
Anti-aging agent: the Microcrystalline Wax that adopts 0.5kg;
Coupling agent: the silane coupling agent that adopts 3kg;
Promotor: the triethylene diamine promotor that adopts 2kg;
Sulfur is 2kg;
Its manufacture craft is as follows:
1) by above-mentioned 100kg rubber raw materials, 5kg white smoke active agent, 10kg softening agent, 6.5kg promoting agent, 0.5 anti-aging agent, 3kg coupling agent, 2kg promotor by said ratio in Banbury mixer fully mixing evenly;
2) by mixing the mixing material obtaining through above-mentioned steps 1 to set the temperature of Celsius 105 ℃ one 120 ℃, after mixing 8 minutes, add the Sulfur with 2kg;
3) mixing material obtaining through above-mentioned steps 2 is continued after mixing 2 minutes to discharge after temperature reaches Celsius 110 ℃ one 160 ℃;
4) mixing material that meets discharge condition is further mixed after 3 minutes through mill (Celsius 70 ℃ one 80 ℃ of roller temperature), manufacture granular composition, can obtain described rubber composite.
Above are only a specific embodiment of the present invention, but design concept of the present invention is not limited to this, allly utilizes this design to carry out the change of unsubstantiality to the present invention, all should belong to the behavior of invading protection domain of the present invention.
Claims (7)
1. rubber composite, it is characterized in that: formed by rubber raw materials, white smoke active agent, softening agent, promoting agent, anti-aging agent, coupling agent, promotor and Sulfur, the weight proportion of above-mentioned each component is: 100% compounded rubber, 2-10% white smoke active agent, 5-15% softening agent, 0.5-10 promoting agent, 0.5-5% anti-aging agent, 1-10% coupling agent, 0.5-5% promotor, 0.5-5% Sulfur, and concrete composition and the proportioning of the each component of wherein said rubber raw materials are as follows:
Paracril 60-90%
Cis-1,4-polybutadiene rubber 5-20%
Mark glue 5-20%.
2. rubber composite as claimed in claim 1, is characterized in that: described softening agent adopts phthalic ester.
3. rubber composite as claimed in claim 1, is characterized in that: described promoting agent adopts mixing of stearic acid and zinc carbonate, and its proportioning is 1:12.
4. rubber composite as claimed in claim 1, is characterized in that: described anti-aging agent adopts Microcrystalline Wax.
5. rubber composite as claimed in claim 1, is characterized in that: described coupling agent adopts silane coupling agent.
6. rubber composite as claimed in claim 1, is characterized in that: described promotor adopts triethylene diamine promotor.
7. the manufacture craft of a kind of rubber composite as claimed in claim 1, is characterized in that comprising following steps:
1) by above-mentioned rubber raw materials, white smoke active agent, softening agent, promoting agent, anti-aging agent, coupling agent, promotor by said ratio in Banbury mixer fully mixing evenly;
2) by mixing the mixing material obtaining through above-mentioned steps 1 to set the temperature of Celsius 105 ℃ one 120 ℃, after mixing 8 minutes, add and Sulfur;
3) mixing material obtaining through above-mentioned steps 2 is continued after mixing 2 minutes to discharge after temperature reaches Celsius 110 ℃ one 160 ℃;
4) mixing material that meets discharge condition is further mixed after 3 minutes through mill (Celsius 70 ℃ one 80 ℃ of roller temperature), manufacture granular composition, can obtain described rubber composite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310721252.9A CN103772763A (en) | 2013-12-25 | 2013-12-25 | Rubber composite and preparation process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310721252.9A CN103772763A (en) | 2013-12-25 | 2013-12-25 | Rubber composite and preparation process thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103772763A true CN103772763A (en) | 2014-05-07 |
Family
ID=50565564
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310721252.9A Pending CN103772763A (en) | 2013-12-25 | 2013-12-25 | Rubber composite and preparation process thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103772763A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194096A (en) * | 2014-09-22 | 2014-12-10 | 安徽电气集团股份有限公司 | High-strength modified butadiene-acrylonitrile rubber and preparation method thereof |
| CN104774348A (en) * | 2015-03-18 | 2015-07-15 | 南京东亚橡塑制品有限公司 | Rubber material added with heat stabilizer (HS-80) and preparation method thereof |
| CN105440464A (en) * | 2015-12-08 | 2016-03-30 | 宁国市开源橡塑汽车零部件有限公司 | Damping rubber material |
| CN106397870A (en) * | 2016-09-07 | 2017-02-15 | 刘丽霞 | Ultralight shoe sole material and preparation method thereof |
| CN111071013A (en) * | 2018-12-07 | 2020-04-28 | 宁波帅特龙集团有限公司 | Automobile sun-shading curtain handle plate and preparation process thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735495A (en) * | 2009-12-21 | 2010-06-16 | 泰亚鞋业股份有限公司 | Formula of sole of high oil resistant rubber sneakers and manufacturing method of soles |
| CN102181083A (en) * | 2011-05-05 | 2011-09-14 | 茂泰(福建)鞋材有限公司 | Oil-resistant anti-slip rubber for soles and preparation method thereof |
| CN102796292A (en) * | 2012-08-09 | 2012-11-28 | 际华三五三七制鞋有限责任公司 | High-elongation wear-resistant oil-resistant rubber sole and preparation method thereof |
| CN102871291A (en) * | 2012-10-15 | 2013-01-16 | 广州市邦尔福鞋材有限公司 | Anti-skid sole and preparation method thereof |
| JP2013102829A (en) * | 2011-11-10 | 2013-05-30 | Kohshin Rubber Co Ltd | Oil-proof and anti-slip sole |
-
2013
- 2013-12-25 CN CN201310721252.9A patent/CN103772763A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735495A (en) * | 2009-12-21 | 2010-06-16 | 泰亚鞋业股份有限公司 | Formula of sole of high oil resistant rubber sneakers and manufacturing method of soles |
| CN102181083A (en) * | 2011-05-05 | 2011-09-14 | 茂泰(福建)鞋材有限公司 | Oil-resistant anti-slip rubber for soles and preparation method thereof |
| JP2013102829A (en) * | 2011-11-10 | 2013-05-30 | Kohshin Rubber Co Ltd | Oil-proof and anti-slip sole |
| CN102796292A (en) * | 2012-08-09 | 2012-11-28 | 际华三五三七制鞋有限责任公司 | High-elongation wear-resistant oil-resistant rubber sole and preparation method thereof |
| CN102871291A (en) * | 2012-10-15 | 2013-01-16 | 广州市邦尔福鞋材有限公司 | Anti-skid sole and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194096A (en) * | 2014-09-22 | 2014-12-10 | 安徽电气集团股份有限公司 | High-strength modified butadiene-acrylonitrile rubber and preparation method thereof |
| CN104774348A (en) * | 2015-03-18 | 2015-07-15 | 南京东亚橡塑制品有限公司 | Rubber material added with heat stabilizer (HS-80) and preparation method thereof |
| CN105440464A (en) * | 2015-12-08 | 2016-03-30 | 宁国市开源橡塑汽车零部件有限公司 | Damping rubber material |
| CN106397870A (en) * | 2016-09-07 | 2017-02-15 | 刘丽霞 | Ultralight shoe sole material and preparation method thereof |
| CN111071013A (en) * | 2018-12-07 | 2020-04-28 | 宁波帅特龙集团有限公司 | Automobile sun-shading curtain handle plate and preparation process thereof |
| CN111071013B (en) * | 2018-12-07 | 2021-08-17 | 宁波帅特龙集团有限公司 | Automobile sun-shading curtain handle plate and preparation process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102040762B (en) | Abrasion-resistant rubber and plastic composite material | |
| CN102532677A (en) | High-elasticity wear-resistant composite material | |
| CA3043354C (en) | A method for preparing high shrinkage stability styrene butadiene rubber-based nanocomposite foams | |
| CN103772763A (en) | Rubber composite and preparation process thereof | |
| CN102504362B (en) | Sizing material for rubber shoe sole and preparation method thereof | |
| CN102061017B (en) | Rubber for sneaker sole and preparation method thereof | |
| CN102964671A (en) | Polymer rubber composite material | |
| CN110423408A (en) | Short vulcanization ethylene propylene diene rubber and preparation method thereof | |
| CN101418085A (en) | Natural rubber sole and preparation method thereof | |
| CN105037902A (en) | High-elastic wear-resistant EVA, preparation method and application thereof | |
| CN104231372A (en) | Motorcycle tire side rubber composition for prolonging mold washing period and preparation method thereof | |
| CN105482193B (en) | A kind of sole elastomeric material and preparation method thereof | |
| CN109836630A (en) | A kind of high-weatherability white rubber sole and preparation method thereof | |
| CN102731857A (en) | Abrasion resistance sole and production method thereof | |
| CN114350036B (en) | High-weather-resistance anti-slip foaming sole and preparation method thereof | |
| CN111607185A (en) | EVA (ethylene-vinyl acetate copolymer) foamed shoe material and preparation method thereof | |
| CN107057204A (en) | A kind of composite assistant for producing rubber | |
| CN108976523B (en) | Cold-resistant cellular-structure sponge rubber and preparation method thereof | |
| CN102558661A (en) | Ultra-light composite material | |
| CN112795065B (en) | Sole rubber composition and preparation method thereof | |
| CN104974458A (en) | Novel high-wear-resistance painting-free shoe sole material and preparation method thereof | |
| CN103509206A (en) | Aging-resistant flame-retardant modified calcium carbonate used for auto tyres, and preparation method thereof | |
| CN105602014A (en) | Rubber outsole material and processing method thereof | |
| CN106543566A (en) | It is a kind of to take turns acid and alkali-resistance elastomeric material peculiar to vessel and preparation method thereof | |
| CN102492159B (en) | Method for preparing aluminum sulfate coordination cross-linking nitrile elastic body |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140507 |