CN105951471B - A kind of manufacturing method of the conductive touch screen material of environment-friendly type gloves - Google Patents

A kind of manufacturing method of the conductive touch screen material of environment-friendly type gloves Download PDF

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CN105951471B
CN105951471B CN201610473517.1A CN201610473517A CN105951471B CN 105951471 B CN105951471 B CN 105951471B CN 201610473517 A CN201610473517 A CN 201610473517A CN 105951471 B CN105951471 B CN 105951471B
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conductive
touch screen
parts
layer
foaming
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CN105951471A (en
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傅非
傅一非
张哲�
何玲芳
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Kehua (Changzhou) new material technology Co.,Ltd.
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Wan Hua (changzhou) New Mstar Technology Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/52—Electrically conductive inks
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24—Electrically-conducting paints
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
    • D06N3/0047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers obtained by incorporating air, i.e. froth
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
    • D06N3/005—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers obtained by blowing or swelling agent
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0806—Silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0862—Nickel
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/04—Properties of the materials having electrical or magnetic properties
    • D06N2209/041—Conductive
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D06N2211/28—Artificial leather

Abstract

The present invention relates to a kind of environment-friendly type gloves manufacturing methods of conductive touch screen material, conductive touch screen material is successively including being base cloth layer, foaming layer and superficial layer, foaming layer is to coat the aqueous mechanical foaming slurry containing conductive material in base fabric layer surface, and the water-soluble polyurethane leather beth being made of foaming layer and base cloth layer is obtained after drying；Ink containing conductive material is directly printed on to the surface of water-soluble polyurethane leather beth by inkjet printing technology, superficial layer is formed, processing is embossed to superficial layer by synthetic leather embossing technique, obtains the conductive touch screen material of waterborne polyurethane synthetic leather.The beneficial effects of the invention are as follows：It enough solves the problems, such as conventional oil-based Synthetic Leather processing pollution, while the more excellent functional conductive synthesis leather goods of the feature of environmental protection can be obtained.

Description

A kind of manufacturing method of the conductive touch screen material of environment-friendly type gloves
Technical field
The present invention relates to a kind of environment-friendly type gloves manufacturing methods of conductive touch screen material.
Background technology
Today of information age, many mobile devices, computer instrument are all simpler in pursuit and directly manipulate, and touch Formula electronic control screen will more be applied in our lives.However, the generation of new things is also necessarily adjoint first to close mating production The birth and upgrading of product, the glove material poorly conductive of daily wearing are substantially all and cannot be satisfied people's manipulation electronic curtain Without barrier property, therefore, the just very valuable and meaning of the glove material with conductive effect is developed.
Since the glove material of artificial leather leather-like has good imitation leather, durability feature is current glove material In first choice.But traditional artificial leather synthetic leather processing process usually can all be produced using solvent borne polyurethane as primary raw material There are problem of environmental pollutions for processing, while the harmful substances such as organic solvent can also remain in the product, bring healthy danger Evil, therefore, being badly in need of exploitation has the feature of environmental protection strong, and conductive effect good synthetic leather product meets the needs of market.
Invention content
The technical problem to be solved by the present invention is to：Based on the above issues, it is conductive to provide a kind of environment-friendly type gloves by the present invention The manufacturing method of touch screen material.
The present invention solves a technical solution used by its technical problem：A kind of conductive touch screen material of environment-friendly type gloves The manufacturing method of material, for conductive touch screen material successively including being base cloth layer, foaming layer and superficial layer, foaming layer is in base fabric layer surface The aqueous mechanical foaming slurry containing conductive material is coated, the aqueous polyurethane being made of foaming layer and base cloth layer is obtained after drying Synthetic leather bass；The ink containing conductive material is directly printed on into water-soluble polyurethane leather beth by inkjet printing technology Surface, form superficial layer, processing be embossed to superficial layer by synthetic leather embossing technique, acquisition waterborne polyurethane synthetic leather Conductive touch screen material.
Further, the material of base cloth layer is woven fabric, looped fabric or non-woven fabrics, preferably looped fabric.
Further, foaming layer is obtained by way of aqueous mechanical foaming, and concrete operations are：It is sent out by aqueous machinery Aqueous mechanical foaming slurry is mixed evenly bubble equipment with air, is coated on scrim surfaces, and drying obtains aqueous poly- ammonia Lipase absobed removes from office bass.
Further, aqueous mechanical foaming slurry, by weight, component includes：100 parts of waterborne polyurethane resin, 0~50 part of deionized water, 3 parts of foaming agent, 3 parts of foam stabilizer, 0.2~3 part of thickener, 0~10 part of colorant, conductive material 0.5 ~30 parts.
Further, foaming agent is mono succinate stearamide sodium sulfonate, lauryl sodium sulfate or detergent alkylate sulphur Sour sodium；Foam stabilizer is ammonium stearate emulsion or coconut oil diethanol amine；Thickener is Hydrophobic association property polyurethane thickener or alkali It is swollen acrylic type thickener；Colorant is aqueous pigment cream；Conductive material is graphene, electrically conductive graphite, conductive titanium dioxide, gold Belong to one or more of nickel powder or silver powder.
Further, the ink containing conductive material, by weight, component includes：Waterborne polyurethane resin 100 Part, 0~50 part of deionized water, 1~3 part of dispersant, 0.2~1 part of levelling agent, 0.1~0.5 part of antifoaming agent, thickener 0.2~3 Part, 0~10 part of colorant, 0.5~60 part of conductive material.
Further, dispersant is unsaturated fatty acid salt or macromolecule dispersing agent；Levelling agent is organic silicon modified by polyether； Antifoaming agent is polysiloxanes or mineral oil；Thickener is Hydrophobic association property polyurethane thickener or the swollen acrylic type thickening of alkali soluble Agent；Colorant is aqueous pigment cream；Conductive material is graphene, electrically conductive graphite, conductive titanium dioxide, metal nickel powder or silver powder One or more of.
Further, by weight, component includes conductive material：1~5 part of graphene, 5~15 parts of electrically conductive graphite, Or its component includes：5~15 parts of conductive titanium dioxide, 0.5~2 part of silver powder or its component include：Metal nickel powder 1~5 Part, 1~5 part of silver powder.
The beneficial effects of the invention are as follows：The present invention can solve the problems, such as conventional oil-based Synthetic Leather processing pollution, together When can obtain the more excellent functional conductive synthesis leather goods of the feature of environmental protection.
Specific implementation mode
Presently in connection with specific embodiment, the invention will be further described, following embodiment be intended to illustrate invention rather than Limitation of the invention further.
Embodiment 1
(1) prepare base fabric：Select the 75D32N knittings of knitting cloth base material are special to gather.
(2) aqueous foaming slurry configures：Weigh 100 parts of waterborne polyurethane resin, 20 parts of deionized water, mono succinate 18 3 parts of amidosulfonic acid sodium, 3 parts of ammonium stearate emulsion, 1 part of Hydrophobic association property polyurethane thickener, 5 parts of black water pigment paste mix It closes uniformly, while 5 parts of graphene is added, be ground, made without particle in slurry, grain size is small by the grinding of three rollers or sand mill In 5 μm, 3000~12000CPS of slurry viscosity.
(3) aqueous mechanical foaming：The aqueous foaming slurry configured is stirred by mechanical foaming machine and is foamed, expansion ratio 1.5~2.0 times.
(4) prepared by aqueous bass：Aqueous mechanical foaming slurry, coating weight are coated on the special densely covered surface of 75D32N knittings：300 ~600g/m2, drying mode：Hot blast is dried, drying temperature：Gradient dries 80 DEG C -100 DEG C -120 DEG C -140 DEG C, when drying Between：6min, coating film forming thickness：0.15~0.35mm.
(5) configuration of the ink containing conductive material：Weigh 100 parts of waterborne polyurethane resin, 20 parts of deionized water, insatiable hunger With 2 parts of fatty acid salt, 0.5 part of organic silicon modified by polyether, 0.3 part of polysiloxanes, 1 part of Hydrophobic association property polyurethane thickener, black 5 parts of color aqueous pigment cream is uniformly mixed, and 1 part of graphene, 9 parts of electrically conductive graphite is added, and is carried out by the grinding of three rollers or sand mill Grinding makes to be less than 5 μm, 500~1000CPS of slurry viscosity without particle, grain size in slurry, and slurry is stirred by vacuum defoamation again It is used after filter.
(6) superficial layer is processed：The electrically conductive ink configured is added in ink-cases of printers, is beaten using wide cut Computerized ink-jetting Ink is printed on bass surface by print machine, is then embossed processing to the product after printing using synthetic leather emebosser, The common lozenge embossing of glove material may be selected, the rear gloves that obtain are with conductive touch screen material.
Embodiment 2
(1) prepare base fabric：Select the knitting two-sided unglazed suede of cloth base material 0.65.
(2) aqueous foaming slurry configures：Weigh 100 parts of waterborne polyurethane resin, 30 parts of deionized water, dodecyl sulphate 3 parts of sodium, 3 parts of coconut oil diethanol amine, alkali soluble is swollen 2 parts of acrylic type thickener, 8 parts of blue water-based pigment paste are uniformly mixed, together When 8 parts of electrically conductive graphite is added, be ground, made in slurry without particle by the grinding of three rollers or sand mill, grain size is less than 5 μm, 3000~12000CPS of slurry viscosity.
(3) aqueous mechanical foaming：The aqueous foaming slurry configured is stirred by mechanical foaming machine and is foamed, expansion ratio 1.5~2.0 times.
(4) prepared by aqueous bass：Aqueous mechanical foaming slurry, coating weight are coated on 0.65 two-sided unglazed suede surface：300~ 600g/m2, drying mode：Hot blast is dried, drying temperature：Gradient dries 80 DEG C -100 DEG C -120 DEG C -140 DEG C, drying time： 6min, coating film forming thickness：0.15~0.35mm.
(5) configuration of the ink containing conductive material：Weigh 100 parts of waterborne polyurethane resin, 10 parts of deionized water, high score 1 part of sub- dispersant, 0.2 part of organic silicon modified by polyether, 0.1 part of mineral oil, alkali soluble is swollen 0.2 part of acrylic type thickener, blue water Property 1 part of pigment paste, be uniformly mixed, be added 3 parts of graphene, 5 parts of electrically conductive graphite, by three rollers grinding or sand mill ground Mill makes to be less than 5 μm without particle, grain size in slurry, and 500~800CPS of slurry viscosity, slurry passes through vacuum defoamation agitation and filtration again After use.
(6) superficial layer is processed：The electrically conductive ink configured is added in ink-cases of printers, is beaten using wide cut Computerized ink-jetting Ink is printed on bass surface by print machine, is then embossed processing to the product after printing using synthetic leather emebosser, The common earth line embossing of glove material may be selected, the rear gloves that obtain are with conductive touch screen material.
Embodiment 3
(1) prepare base fabric：Knitting 0.65 single side of cloth base material is selected to imitate napped cotton fabric.
(2) aqueous foaming slurry configures：Weigh 100 parts of waterborne polyurethane resin, 10 parts of deionized water, detergent alkylate sulphur 3 parts of sour sodium, 3 parts of ammonium stearate emulsion, 3 parts of Hydrophobic association property polyurethane thickener, 10 parts of white water-borne pigment paste, mixing are equal It is even, while 0.5 part of conductive titanium dioxide is added, it is ground, is made in slurry without particle, grain size by the grinding of three rollers or sand mill Less than 5 μm, 3000~12000CPS of slurry viscosity.
(3) aqueous mechanical foaming：The aqueous foaming slurry configured is stirred by mechanical foaming machine and is foamed, expansion ratio 1.5~2.0 times.
(4) prepared by aqueous bass：Napped cotton fabric surface, which is imitated, in 0.65 single side coats aqueous mechanical foaming slurry, coating weight：300 ~600g/m2, drying mode：Hot blast is dried, drying temperature：Gradient dries 80 DEG C -100 DEG C -120 DEG C -140 DEG C, when drying Between：6min, coating film forming thickness：0.15~0.35mm.
(5) configuration of the ink containing conductive material：Weigh 100 parts of waterborne polyurethane resin, 50 parts of deionized water, insatiable hunger With 3 parts of fatty acid salt, 1 part of organic silicon modified by polyether, 0.5 part of polysiloxanes, 3 parts of Hydrophobic association property polyurethane thickener, white 10 parts of aqueous pigment cream is uniformly mixed, and 15 parts of conductive titanium dioxide, 2 parts of silver powder is added, and passes through the grinding of three rollers or sand mill It is ground, makes to be less than 5 μm without particle, grain size in slurry, 500~800CPS of slurry viscosity, slurry is stirred by vacuum defoamation again It is used after mixing filtering.
(6) superficial layer is processed：The electrically conductive ink configured is added in ink-cases of printers, is beaten using wide cut Computerized ink-jetting Ink is printed on bass surface by print machine, is then embossed processing to the product after printing using synthetic leather emebosser, The common pin hole line embossing of glove material may be selected, the rear gloves that obtain are with conductive touch screen material.
Embodiment 4
(1) prepare base fabric：Select the 75D32N knittings of knitting cloth base material are special to gather.
(2) aqueous foaming slurry configures：Weigh 100 parts of waterborne polyurethane resin, 35 parts of deionized water, dodecyl sulphate 3 parts of sodium, 3 parts of coconut oil diethanol amine, alkali soluble is swollen 1.5 parts of acrylic type thickener, red 7 parts of aqueous pigment cream, are uniformly mixed, 5 parts of metal nickel powder is added simultaneously, is ground by the grinding of three rollers or sand mill, makes to be less than 5 μ without particle, grain size in slurry M, 3000~12000CPS of slurry viscosity.
(3) aqueous mechanical foaming：The aqueous foaming slurry configured is stirred by mechanical foaming machine and is foamed, expansion ratio 1.5~2.0 times.
(4) prepared by aqueous bass：Aqueous mechanical foaming slurry, coating weight are coated on the special densely covered surface of 75D32N knittings：300 ~600g/m2, drying mode：Hot blast is dried, drying temperature：Gradient dries 80 DEG C -100 DEG C -120 DEG C -140 DEG C, when drying Between：6min, coating film forming thickness：0.15~0.35mm.
(5) configuration of the ink containing conductive material：Weigh 100 parts of waterborne polyurethane resin, 15 parts of deionized water, alkali soluble 2.5 parts of swollen acrylic type thickener, 0.6 part of organic silicon modified by polyether, 0.4 part of mineral oil, alkali soluble is swollen acrylic type thickener 2.1 Part, 4 parts of aqueous pigment cream are uniformly mixed, and 2 parts of metal nickel powder, 4 parts of silver powder is added, and pass through the grinding of three rollers or sand mill It is ground, makes to be less than 5 μm without particle, grain size in slurry, 500~800CPS of slurry viscosity, slurry is stirred by vacuum defoamation again It is used after mixing filtering.
(6) superficial layer is processed：The electrically conductive ink configured is added in ink-cases of printers, is beaten using wide cut Computerized ink-jetting Ink is printed on bass surface by print machine, is then embossed processing to the product after printing using synthetic leather emebosser, The common taper line embossing of glove material may be selected, the rear gloves that obtain are with conductive touch screen material.
Embodiment 5
(1) prepare base fabric：Select the knitting two-sided unglazed suede of cloth base material 0.65.
(2) aqueous foaming slurry configures：Weigh 100 parts of waterborne polyurethane resin, 17 parts of deionized water, detergent alkylate sulphur 3 parts of sour sodium, 3 parts of ammonium stearate emulsion, 2.7 parts of Hydrophobic association property polyurethane thickener are uniformly mixed, while silver powder are added It 19 parts, being ground, is made in slurry without particle by the grinding of three rollers or sand mill, grain size is less than 5 μm, slurry viscosity 3000~ 12000CPS。
(3) aqueous mechanical foaming：The aqueous foaming slurry configured is stirred by mechanical foaming machine and is foamed, expansion ratio 1.5~2.0 times.
(4) prepared by aqueous bass：Aqueous mechanical foaming slurry, coating weight are coated on 0.65 two-sided unglazed suede surface：300~ 600g/m2, drying mode：Hot blast is dried, drying temperature：Gradient dries 80 DEG C -100 DEG C -120 DEG C -140 DEG C, drying time： 6min, coating film forming thickness：0.15~0.35mm.
(5) configuration of the ink containing conductive material：Weigh 100 parts of waterborne polyurethane resin, 27 parts of deionized water, insatiable hunger With 1.9 parts of fatty acid salt, 0.6 part of organic silicon modified by polyether, 0.45 part of polysiloxanes, Hydrophobic association property polyurethane thickener 2.2 Part, it is uniformly mixed, 4 parts of metal nickel powder, 3 parts of silver powder is added, be ground by the grinding of three rollers or sand mill, make slurry Middle no particle, grain size are less than 5 μm, 1000~3000CPS of slurry viscosity, and slurry after vacuum defoamation agitation and filtration again by using.
(6) superficial layer is processed：The electrically conductive ink configured is added in ink-cases of printers, is beaten using wide cut Computerized ink-jetting Ink is printed on bass surface by print machine, is then embossed processing to the product after printing using synthetic leather emebosser, The common stone riprap line embossing of glove material may be selected, the rear gloves that obtain are with conductive touch screen material.
Conductive touch screen material electric conductivity prepared by the application is as follows：
Conductive material is the resistivity of the conductive touch screen material of graphene：103~105Ω；
Conductive material is the resistivity of the conductive touch screen material of electrically conductive graphite：103~105Ω；
Conductive material is the resistivity of the conductive touch screen material of conductive titanium dioxide：105~106Ω；
Conductive material is the resistivity of the conductive touch screen material of metal nickel powder：10~103Ω；
Conductive material is the resistivity of the conductive touch screen material of silver powder：10~103Ω。
It is typically chosen the use of two or more conductive material blending, can both realize the complementation of storeroom, conductive effect Most preferably, while material utilization amount price is also relatively more reasonable.
It is enlightenment with above-mentioned desirable embodiment according to the present invention, through the above description, relevant staff is complete Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention Property range is not limited to the contents of the specification, it is necessary to determine its technical scope according to right.

Claims (6)

1. a kind of environment-friendly type gloves manufacturing method of conductive touch screen material, it is characterized in that：Conductive touch screen material is successively including being Base cloth layer, foaming layer and superficial layer, foaming layer are to coat the aqueous mechanical foaming slurry containing conductive material in base fabric layer surface, The water-soluble polyurethane leather beth being made of foaming layer and base cloth layer is obtained after drying；It will be contained by inkjet printing technology and be led The ink of electric material directly prints on the surface of water-soluble polyurethane leather beth, forms superficial layer, work is embossed by synthetic leather Skill is embossed processing to superficial layer, obtains the conductive touch screen material of waterborne polyurethane synthetic leather,
The ink containing conductive material, by weight, component includes：100 parts of waterborne polyurethane resin, deionization 0~50 part of water, 1~3 part of dispersant, 0.2~1 part of levelling agent, 0.1~0.5 part of antifoaming agent, 0.2~3 part of thickener, colorant 0 ~10 parts, 0.5~60 part of conductive material,
The dispersant is unsaturated fatty acid salt or macromolecule dispersing agent；Levelling agent is organic silicon modified by polyether；Antifoaming agent For polysiloxanes or mineral oil；Thickener is Hydrophobic association property polyurethane thickener or the swollen acrylic type thickener of alkali soluble；Coloring Agent is aqueous pigment cream；Conductive material is one in graphene, electrically conductive graphite, conductive titanium dioxide, metal nickel powder or silver powder Kind is several.
2. a kind of environment-friendly type gloves according to claim 1 manufacturing method of conductive touch screen material, it is characterized in that：It is described Base cloth layer material be woven fabric, looped fabric or non-woven fabrics.
3. a kind of environment-friendly type gloves according to claim 1 manufacturing method of conductive touch screen material, it is characterized in that：It is described Foaming layer be to be obtained by way of aqueous mechanical foaming, concrete operations are：By aqueous mechanical foaming equipment by aqueous machine Tool foamed slurry is mixed evenly with air, is coated on scrim surfaces, and drying obtains water-soluble polyurethane leather beth.
4. a kind of environment-friendly type gloves according to claim 1 manufacturing method of conductive touch screen material, it is characterized in that：It is described Aqueous mechanical foaming slurry, by weight, component includes：100 parts of waterborne polyurethane resin, 0~50 part of deionized water, 3 parts of foaming agent, 3 parts of foam stabilizer, 0.2~3 part of thickener, 0~10 part of colorant, 0.5~30 part of conductive material.
5. a kind of environment-friendly type gloves according to claim 4 manufacturing method of conductive touch screen material, it is characterized in that：It is described Foaming agent be mono succinate stearamide sodium sulfonate, lauryl sodium sulfate or neopelex；Foam stabilizer is hard Resin acid ammonium lotion or coconut oil diethanol amine；Thickener is Hydrophobic association property polyurethane thickener or the swollen acrylic type thickening of alkali soluble Agent；Colorant is aqueous pigment cream.
6. a kind of environment-friendly type gloves according to claim 1 manufacturing method of conductive touch screen material, it is characterized in that：It is described Conductive material by weight, component includes：1~5 part of graphene, 5~15 parts of electrically conductive graphite or its component include： 5~15 parts of conductive titanium dioxide, 0.5~2 part of silver powder or its component include：1~5 part of metal nickel powder, silver powder 1~5 Part.
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