CN107266999A - A kind of watersoluble plumbago alkene anticorrosive paint and preparation method thereof - Google Patents
A kind of watersoluble plumbago alkene anticorrosive paint and preparation method thereof Download PDFInfo
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- CN107266999A CN107266999A CN201710349191.6A CN201710349191A CN107266999A CN 107266999 A CN107266999 A CN 107266999A CN 201710349191 A CN201710349191 A CN 201710349191A CN 107266999 A CN107266999 A CN 107266999A
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- anticorrosive paint
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/06—Polyurethanes from polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention belongs to chemistry painting industry field, more particularly to a kind of watersoluble plumbago alkene anticorrosive paint and preparation method thereof, according to parts by weight, it is made up of following component：Aqueous polymer resin, wetting dispersing agent, defoamer, PH conditioning agents, graphene extender paste, graining paste, levelling agent, thickener, deionized water, curing agent, adhesion promoter.Watersoluble plumbago alkene anticorrosive paint provided by the present invention, without organic solvent, has no irritating odor using water as diluent, free from environmental pollution, harmless.And the addition of graphene improves the wearability, hardness and Corrosion Protection of whole lacquer painting.
Description
Technical field
The invention belongs to chemistry painting industry field, more particularly to a kind of watersoluble plumbago alkene anticorrosive paint and preparation method thereof.
Background technology
As coatings industry and coating process develop to low stainization, water paint increasingly rises.Water paint
Using pollution of the organic solvent to environment is reduced, ensure that operating personnel's is healthy, its safe and environment-friendly production and fortune
Transmission method receives extensive favor.But presently commercially available water-based anticorrosive paint its on Corrosion Protection be difficult with solvent-borne type apply
Material contends with, poor water resistance, the half of salt-fog resistant time deficiency solvent based coating, and this just greatly limit the development of water paint.
The content of the invention
The problem of present invention is directed to above-mentioned, proposes a kind of watersoluble plumbago alkene anticorrosive paint.
In order to achieve the above object, the technical solution adopted by the present invention is that the present invention provides a kind of watersoluble plumbago alkene anti-corrosion
Coating according to parts by weight characterized in that, include following component：
The parts by weight ratio of the component A and B component is A：B=(4-6)：1.
Preferably, the aqueous polymer resin is aqueous polyethylene acetate resin, acrylic modified waterborne resin, water
Any one in property alkyd resin, waterborne polyurethane resin, aqueous polyester resin or two kinds.
Preferably, the wetting dispersing agent is polyoxyethylene fatty acid esters, polyethylene glycol oxide alkyl phenyl ether, polyoxy
Change any one material in ethene succinate.
Disappear preferably, the defoamer is mineral hydrocarbon defoamer and/or non-ionic alkyl copolymer
Infusion.
Preferably, the PH conditioning agents are one in dimethylethanolamine, ammoniacal liquor, 2-amino-2-methyl-1-propanol
Kind.
Preferably, the graphene extender paste is titanium dioxide, powdered whiting, kaolin, talcum powder, ultra-fine calcite
At least one of powder, barium sulfate, mica powder, aluminium triphosphate, trbasic zinc phosphate material adds flake graphite alkene powder and wetting point
Dissipate and wait auxiliary agent and the slurry like material of the scattered stirring of deionized water.
Preferably, the graining paste is answered for the one or more in iron oxide red, iron oxide yellow, iron oxide black, red lead, zinc yellow, carbon black etc.
Match somebody with somebody, add the auxiliary agents such as wetting and dispersing and the slurry like material of the scattered stirring of deionized water.
Preferably, the levelling agent is any in type siloxane, azo polyether polyeste class, modified acroleic acid esters
It is a kind of.
Preferably, the thickener is one kind in alkali swollen thickener, polyurethane thickener.
Preferably, described curing agent is water-based isocyanate curing agent.
Preferably, the adhesion promoter be vinyl silanes, amino silane, epoxy radicals silicone hydride, hydrosulphonyl silane and
The silane coupling agents such as methacryloxypropyl silane.
The present invention also provides a kind of preparation method of watersoluble plumbago alkene anticorrosive paint, it is characterised in that comprise the following steps：
(1) aqueous polymer resin, graphene extender paste, graining paste are added and stirred in mixing kettle to well mixed, obtained
To mixture a；
(2) wetting dispersing agent, defoamer, levelling agent are added in mixture a successively into step (1), continues to stir extremely
It is well mixed, obtain mixture b；
(3) deionized water, PH conditioning agents and thickener are added in the slow mixture b into step (2), and stirs equal
Even, 120 mesh silk screen filters obtain watersoluble plumbago alkene anticorrosive paint coating component A finished product c；
(4) curing agent and adhesion promoter are added and stirred in mixing kettle to being well mixed, 120 mesh silk screen filters are obtained
To watersoluble plumbago alkene anticorrosive paint coating B component d.
Preferably, in (1) step, mixing time is 40-50min, speed of agitator is that 600-800 turns/min.
Preferably, in (2) step, mixing time is 20-30min, speed of agitator is that 600-800 turns/min.
Preferably, in (3) step, mixing time is 30-40min, speed of agitator is that 600-800 turns/min, pH
Control is between 7.5-8.5.
Compared with prior art, advantages and positive effects of the present invention are,
The present invention selects different aqueous polymer resins to be compounded according to demand, can improve the wear-resisting, resistance to of paint film
The performances such as impact, water-fast, salt spray resistance.Designed using two-component, improve the crosslinking degree of resin, add the solidification effect of paint film
Really.Meanwhile, graphene has excellent heat, electricity, mechanical property, and shielding properties, its two-dimentional laminated structure and big ratio
Surface area, can be arranged in film parallel to metallic substrates, can effectively prevent to add in the infiltration of corrosion factor, paint vehicle
Graphene composition improve the impact property and Corrosion Protection of paint film.In addition, the anticorrosive paint is water paint, Ke Yizhi
Connect and be watered construction, it is to avoid the use of carbon containing organic solvent, not only reduce the pollution to environment, and substantial amounts of saved money
Source.
Embodiment
In order to be more clearly understood that the above objects, features and advantages of the present invention, with reference to embodiment to this hair
It is bright to be described further.It should be noted that in the case where not conflicting, the feature in embodiments herein and embodiment can
To be mutually combined.
Many details are elaborated in the following description to facilitate a thorough understanding of the present invention, still, the present invention may be used also
To be implemented using other modes described here are different from, therefore, the present invention is not limited to the specific of specification described below
The limitation of embodiment.
Embodiment 1, a kind of watersoluble plumbago alkene anticorrosive paint, in parts by weight including following material：Component A：Aqueous acrylamide
40 parts of acid resin, 5 parts of aqueous polyester resin, 0.2 part of polyethylene glycol oxide alkyl phenyl ether (wetting dispersing agent), DREWPLUSL-
1311 0.2 part of (defoamer), 0.3 part of AMP-95# (PH conditioning agents), 30 parts of graphene extender paste, 8 parts of graining paste, dimethyl-silicon
0.3 part of oxygen alkane (levelling agent), 0.5 part of polyurethane thickener, 15.5 parts of deionized water；B component：Toluene di-isocyanate(TDI) (solidification
Agent) 70 parts, 30 parts of silane coupler S-401 (adhesion promoter).Wherein, A:B=6:1.
Preparation process is：(1) aqueous polymer resin, graphene extender paste, graining paste are added in mixing kettle 700
Rev/min mixing speed under stir 45 minutes, obtain mixture after thing to be mixed is well mixed；Then add successively into mixture
Enter wetting dispersing agent, defoamer, levelling agent, then adjust rotating speed to 800 revs/min, stir 20 minutes.Uniformly mixed
Thing；After all substances are well mixed, deionized water, PH conditioning agents and thickener are sequentially added in mixing kettle, 600 turns/
Stirring is suitably adjusted for 35 minutes to uniform with PH conditioning agents to the PH of mixture under the mixing speed divided, and controls mixture
PH, with 120 mesh silk screen filters, finally gives watersoluble plumbago alkene anticorrosive paint component A finished product between 7.5-8.5.(2) will solidification
Agent and adhesion promoter are added in mixing kettle and stirred 40 minutes under 700 revs/min of mixing speed, with 120 mesh silk screen filters,
Finally give watersoluble plumbago alkene anticorrosive paint B component finished product.
Embodiment 2
A kind of watersoluble plumbago alkene anticorrosive paint, in parts by weight including following material：Component A：30 parts of aqueous alkide resin,
20 parts of waterborne polyurethane resin, 0.2 part of polyethylene glycol oxide succinate (wetting dispersing agent), DREWPLUS L-1311 (froth breakings
Agent) 0.2 part, 0.2 part of ammoniacal liquor (PH conditioning agents), 40 parts of graphene extender paste, 5 parts of graining paste, alkyl-modified organosiloxane (stream
Flat agent) 0.5 part, 0.3 part of polyurethane thickener, 3.6 parts of deionized water；B component：60 parts of toluene di-isocyanate(TDI) (curing agent),
40 parts of vinyl silicane coupling agent (adhesion promoter).Wherein, A:B=5:1.
Preparation process is：(1) aqueous polymer resin, graphene extender paste, graining paste are added in mixing kettle 600
Rev/min mixing speed under stir 40 minutes, obtain mixture after thing to be mixed is well mixed；Then add successively into mixture
Enter wetting dispersing agent, defoamer, levelling agent, then adjust rotating speed to 700 revs/min, stir 30 minutes.Uniformly mixed
Thing；After all substances are well mixed, deionized water, PH conditioning agents and thickener are sequentially added into mixing kettle, 600 turns/
Stirring is suitably adjusted for 35 minutes to well mixed with PH conditioning agents to the PH of mixture under the mixing speed divided, and control is mixed
Compound pH, with 120 mesh silk screen filters, finally gives watersoluble plumbago alkene anticorrosive paint component A finished product between 7.5-8.5.(2) will
Curing agent and adhesion promoter are added in mixing kettle to be stirred 30 minutes under 600 revs/min of mixing speed, with 120 mesh silk screens
Filtering, finally gives watersoluble plumbago alkene anticorrosive paint B component finished product.
Embodiment 3
A kind of watersoluble plumbago alkene anticorrosive paint, in parts by weight including following material：Component A：45 parts of aqueous polyester resin,
0.3 part of polyoxyethylene fatty acid esters (wetting dispersing agent), 0.2 part of mineral oil defoaming agent, 0.3 part of DMAE (PH conditioning agents),
40 parts of graphene extender paste, 10 parts of graining paste, 0.5 part of modified acroleic acid esters levelling agent, alkali soluble rises 0.3 part of thickener, go from
Sub- 3.4 parts of water；B component：80 parts of toluene di-isocyanate(TDI) (curing agent), 20 parts of silane coupler S-401 (adhesion promoter).
Wherein, A:B=4:1.
Preparation process is：(1) aqueous polymer resin, graphene extender paste, graining paste are added in mixing kettle 600
Rev/min mixing speed under stir 50 minutes, obtain mixture after thing to be mixed is well mixed；Then add successively into mixture
Enter wetting dispersing agent, defoamer, levelling agent, then adjust rotating speed to 700 revs/min, stir 30 minutes.Uniformly mixed
Thing；After all substances are well mixed, deionized water, PH conditioning agents and thickener are sequentially added, with 800 in mixing kettle
Rev/min mixing speed under stirring 35 minutes and to uniform, the PH of mixture is suitably adjusted with PH conditioning agents, control is mixed
Compound pH, with 120 mesh silk screen filters, finally gives watersoluble plumbago alkene anticorrosive paint component A finished product between 7.5-8.5.(2) will
Curing agent and adhesion promoter are added in mixing kettle to be stirred 30 minutes under 700 revs/min of mixing speed, with 120 mesh silk screens
Filtering, finally gives watersoluble plumbago alkene anticorrosive paint B component finished product.
The traditional solvent-borne anticorrosive paint of table 1, common water borne anticorrosive paint and watersoluble plumbago alkene anticorrosive paint performance detection：
Pass through the traditional solvent-borne anticorrosive paint of table 1, common water borne anticorrosive paint and watersoluble plumbago alkene anticorrosive paint performance
Testing result, which compares, to be understood, the graphene composition that can effectively disperse is added in water-based anticorrosive paint, can make paint film
The physical property such as abrasive resistance and hardness is obviously improved, while promoting the adhesive force of paint film.In terms of chemical property, water
Property graphene anticorrosive paint effectively slow down the corrosion rate of paint film due to the shielding action of graphene.Meanwhile, each performance refers to
Mark can compare favourably with traditional solvent-borne coating completely.
The above described is only a preferred embodiment of the present invention, being not the limitation for making other forms to the present invention, appoint
What those skilled in the art changed or be modified as possibly also with the technology contents of the disclosure above equivalent variations etc.
Imitate embodiment and be applied to other fields, but every without departing from technical solution of the present invention content, the technical spirit according to the present invention
Any simple modification, equivalent variations and the remodeling made to above example, still fall within the protection domain of technical solution of the present invention.
Claims (6)
1. a kind of watersoluble plumbago alkene anticorrosive paint, it is characterised in that include following component according to parts by weight：
Component A：
B component：
60-80 parts of curing agent,
20-40 parts of adhesion promoter；
The parts by weight ratio of the component A and B component is A：B=(4-6)：1.
2. a kind of watersoluble plumbago alkene anticorrosive paint according to claim 1, it is characterised in that：The aqueous polymer resin is
Aqueous polyethylene acetate resin, acrylic modified waterborne resin, aqueous alkide resin, waterborne polyurethane resin, waterborne polyester tree
Any one in fat or two kinds；The wetting dispersing agent be polyoxyethylene fatty acid esters, polyethylene glycol oxide alkyl phenyl ether,
Any one material in polyethylene glycol oxide succinate；The defoamer is mineral hydrocarbon defoamer and/or non-
Ionic alkyl copolymer defoamer；The PH conditioning agents is in dimethylethanolamine, ammoniacal liquor, 2-amino-2-methyl-1-propanols
One kind；The graphene extender paste be titanium dioxide, powdered whiting, kaolin, talcum powder, ultra-fine calcite in powder, barium sulfate,
At least one of mica powder, aluminium triphosphate, trbasic zinc phosphate material add the auxiliary agent such as flake graphite alkene powder and wetting and dispersing with
The slurry like material of the scattered stirring of deionized water；The graining paste is in iron oxide red, iron oxide yellow, iron oxide black, red lead, zinc yellow, carbon black etc.
One or more of compoundings, add the auxiliary agents such as wetting and dispersing and the slurry like material of the scattered stirring of deionized water；The levelling
Agent is any one in type siloxane, azo polyether polyeste class, modified acroleic acid esters；The thickener, which is that alkali soluble is swollen, to be increased
Thick dose, one kind in polyurethane thickener；Described curing agent is water-based isocyanate curing agent；The adhesion promoter is
The silane coupling agents such as vinyl silanes, amino silane, epoxy radicals silicone hydride, hydrosulphonyl silane and methacryloxypropyl silane.
3. a kind of preparation method of watersoluble plumbago alkene anticorrosive paint, it is characterised in that comprise the following steps：
(1) aqueous polymer resin, graphene extender paste, graining paste are added and stirred in mixing kettle to well mixed, mixed
Compound a；
(2) wetting dispersing agent, defoamer, levelling agent are added in mixture a successively into step (1), continues to stir to mixing
Uniformly, mixture b is obtained；
(3) deionized water, PH conditioning agents and thickener are added in the slow mixture b into step (2), and is stirred, 120
Mesh silk screen filter, obtains watersoluble plumbago alkene anticorrosive paint coating component A finished product c；
(4) curing agent and adhesion promoter are added and stirred in mixing kettle to being well mixed, 120 mesh silk screen filters obtain water
Property graphene anticorrosive paint coating B component d.
4. a kind of preparation method of watersoluble plumbago alkene anticorrosive paint according to claim 4, it is characterised in that：(1) step
In rapid, mixing time is 40-50min, and speed of agitator is that 600-800 turns/min.
5. a kind of preparation method of watersoluble plumbago alkene anticorrosive paint according to claim 4, it is characterised in that：(2) step
In rapid, mixing time is 20-30min, and speed of agitator is that 600-800 turns/min.
6. a kind of preparation method of watersoluble plumbago alkene anticorrosive paint according to claim 4, it is characterised in that：(3) step
In rapid, mixing time is 30-40min, and speed of agitator is that 600-800 turns/min, and pH is controlled between 7.5-8.5.
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| CN201710349191.6A CN107266999A (en) | 2017-05-17 | 2017-05-17 | A kind of watersoluble plumbago alkene anticorrosive paint and preparation method thereof |
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| CN201710349191.6A CN107266999A (en) | 2017-05-17 | 2017-05-17 | A kind of watersoluble plumbago alkene anticorrosive paint and preparation method thereof |
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Application publication date: 20171020 |