CN105948985A - Humic acid containing alkaline liquid fertilizer and preparation method thereof - Google Patents
Humic acid containing alkaline liquid fertilizer and preparation method thereof Download PDFInfo
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- CN105948985A CN105948985A CN201610297509.6A CN201610297509A CN105948985A CN 105948985 A CN105948985 A CN 105948985A CN 201610297509 A CN201610297509 A CN 201610297509A CN 105948985 A CN105948985 A CN 105948985A
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- CN
- China
- Prior art keywords
- humic acids
- potassium
- containing humic
- fermentation
- akaline liquid
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- 239000007788 liquid Substances 0.000 title claims abstract description 56
- 239000004021 humic acid Substances 0.000 title claims abstract description 51
- 239000003337 fertilizer Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims description 10
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 title abstract 5
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 43
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 39
- 238000000855 fermentation Methods 0.000 claims abstract description 36
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000011591 potassium Substances 0.000 claims abstract description 32
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 32
- 230000004151 fermentation Effects 0.000 claims abstract description 31
- 239000002002 slurry Substances 0.000 claims abstract description 27
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910000027 potassium carbonate Inorganic materials 0.000 claims abstract description 21
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims abstract description 20
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims abstract description 20
- 239000001099 ammonium carbonate Substances 0.000 claims abstract description 20
- 239000004202 carbamide Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 11
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910001950 potassium oxide Inorganic materials 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract description 6
- 239000002361 compost Substances 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 20
- 235000013877 carbamide Nutrition 0.000 claims description 19
- 210000003608 fece Anatomy 0.000 claims description 16
- 244000144972 livestock Species 0.000 claims description 16
- 244000144977 poultry Species 0.000 claims description 16
- 239000002738 chelating agent Substances 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 14
- 238000006396 nitration reaction Methods 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 239000002154 agricultural waste Substances 0.000 claims description 8
- 239000000047 product Substances 0.000 claims description 8
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 6
- 239000011707 mineral Substances 0.000 claims description 6
- 239000003895 organic fertilizer Substances 0.000 claims description 6
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 claims description 5
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 claims description 5
- 239000002509 fulvic acid Substances 0.000 claims description 5
- 229940095100 fulvic acid Drugs 0.000 claims description 5
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 2
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 2
- 235000011151 potassium sulphates Nutrition 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 238000009313 farming Methods 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 210000002700 urine Anatomy 0.000 claims 1
- 239000002689 soil Substances 0.000 abstract description 10
- 235000015097 nutrients Nutrition 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 4
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 230000012010 growth Effects 0.000 abstract description 3
- 239000010815 organic waste Substances 0.000 abstract description 3
- 239000008139 complexing agent Substances 0.000 abstract 1
- 238000009264 composting Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 235000007686 potassium Nutrition 0.000 description 26
- 235000011181 potassium carbonates Nutrition 0.000 description 16
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 12
- 201000010099 disease Diseases 0.000 description 11
- 238000003860 storage Methods 0.000 description 6
- 235000010755 mineral Nutrition 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- -1 salt ion Chemical class 0.000 description 4
- 241000193755 Bacillus cereus Species 0.000 description 3
- 244000063299 Bacillus subtilis Species 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 3
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 230000008635 plant growth Effects 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 235000014469 Bacillus subtilis Nutrition 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 241000488583 Panonychus ulmi Species 0.000 description 2
- 238000010564 aerobic fermentation Methods 0.000 description 2
- 238000012271 agricultural production Methods 0.000 description 2
- 210000000481 breast Anatomy 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000009335 monocropping Methods 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 241001124076 Aphididae Species 0.000 description 1
- 241001530056 Athelia rolfsii Species 0.000 description 1
- 229930192334 Auxin Natural products 0.000 description 1
- 241000193738 Bacillus anthracis Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 229930191978 Gibberellin Natural products 0.000 description 1
- 241000255967 Helicoverpa zea Species 0.000 description 1
- 208000032843 Hemorrhage Diseases 0.000 description 1
- 241000233679 Peronosporaceae Species 0.000 description 1
- 241000907661 Pieris rapae Species 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 235000014443 Pyrus communis Nutrition 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 241000256247 Spodoptera exigua Species 0.000 description 1
- 229930003779 Vitamin B12 Natural products 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000000507 anthelmentic effect Effects 0.000 description 1
- 239000003443 antiviral agent Substances 0.000 description 1
- 239000002363 auxin Substances 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 208000034158 bleeding Diseases 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- AGVAZMGAQJOSFJ-WZHZPDAFSA-M cobalt(2+);[(2r,3s,4r,5s)-5-(5,6-dimethylbenzimidazol-1-yl)-4-hydroxy-2-(hydroxymethyl)oxolan-3-yl] [(2r)-1-[3-[(1r,2r,3r,4z,7s,9z,12s,13s,14z,17s,18s,19r)-2,13,18-tris(2-amino-2-oxoethyl)-7,12,17-tris(3-amino-3-oxopropyl)-3,5,8,8,13,15,18,19-octamethyl-2 Chemical compound [Co+2].N#[C-].[N-]([C@@H]1[C@H](CC(N)=O)[C@@]2(C)CCC(=O)NC[C@@H](C)OP(O)(=O)O[C@H]3[C@H]([C@H](O[C@@H]3CO)N3C4=CC(C)=C(C)C=C4N=C3)O)\C2=C(C)/C([C@H](C\2(C)C)CCC(N)=O)=N/C/2=C\C([C@H]([C@@]/2(CC(N)=O)C)CCC(N)=O)=N\C\2=C(C)/C2=N[C@]1(C)[C@@](C)(CC(N)=O)[C@@H]2CCC(N)=O AGVAZMGAQJOSFJ-WZHZPDAFSA-M 0.000 description 1
- 244000038559 crop plants Species 0.000 description 1
- 244000037666 field crops Species 0.000 description 1
- 235000012041 food component Nutrition 0.000 description 1
- 230000007914 freezing tolerance Effects 0.000 description 1
- 239000003448 gibberellin Substances 0.000 description 1
- IXORZMNAPKEEDV-OBDJNFEBSA-N gibberellin A3 Chemical class C([C@@]1(O)C(=C)C[C@@]2(C1)[C@H]1C(O)=O)C[C@H]2[C@]2(C=C[C@@H]3O)[C@H]1[C@]3(C)C(=O)O2 IXORZMNAPKEEDV-OBDJNFEBSA-N 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 208000015380 nutritional deficiency disease Diseases 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 238000009329 organic farming Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 239000002688 soil aggregate Substances 0.000 description 1
- 238000003900 soil pollution Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000019163 vitamin B12 Nutrition 0.000 description 1
- 239000011715 vitamin B12 Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B17/00—Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F3/00—Fertilisers from human or animal excrements, e.g. manure
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/23—Solutions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Soil Sciences (AREA)
- Biochemistry (AREA)
- Biotechnology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Molecular Biology (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a humic acid containing alkaline liquid fertilizer, which comprises the following components by weight percentage: 4%-11% of biogas slurry, 20%-30% of potassium fulvate, 6%-10% of a complexing agent, 14%-20% of ammonium bicarbonate, 4%-6% of potassium carbonate, 20%-25% of urea, 4%-17% of composting fermentation leachate, and 1%-8% of water; and the total of the mass percentage of the components is 100%. The liquid fertilizer provided by the invention of has a nitrogen content of more than 100mg/L, a phosphorus pentoxide content of more than 50mg/L, a potassium oxide content of more than 50mg/L, a humic acid content of more than 100mg/L, a pH value of greater than 11, and comprehensive nutrients, the humic acid can improve the utilization rate of fertilizer elements, stimulate crop growth, enhance crop stress resistance, increase the crop yield and quality, improve acid soil, and enhance soil activity. The humic acid containing alkaline liquid fertilizer provided by the invention can effectively utilize organic waste and reduce pollution, is produced under room temperature and normal pressure, the production energy consumption is low and the equipment is simple.
Description
Technical field:
The invention belongs to technical field of fertilizers, be specifically related to a kind of containing humic acids akaline liquid fertilizer and preparation side thereof
Method.
Background technology:
The growth of crop be unable to do without Organic carbon and nitrogen, phosphorus, the big nutrient of potassium four.Having of a large amount of soil of China
Machine matter content is on the low side, soil acidification, hardens serious, a large amount of use traditional fertilizer and is excessively used pesticide, making
Becoming biological activity of soil low, serious restriction agricultural production is to the ecological agriculture, green agriculture, Organic Farming.
The livestock-raising industry of China is very big at the proportion of agricultural production, breeding disparate development, a large amount of feces of livestock and poultry
Failing efficient resource utilization is put into environment, causes a large amount of water body and soil pollution, the money of agricultural wastes
Source recycles the most less, and annual substantial amounts of burning causes the pollution of air.Utilize feces of livestock and poultry and agriculture
Biotechnology fermentation is passed through, it is possible to obtain biogas slurry, biogas residue and compost aerobic fermentation sepage as garbage, these
It it is all the organic fertilizer resource of high-quality.
The water quality characteristic of biogas slurry and compost aerobic fermentation sepage makes Crop be exceedingly fast, and existing quick-acting is held concurrently again
Tool slow.Often executing biogas slurry, plant growth is healthy and strong, and vane thickness and fruit weight dramatically increase, and quality shows
Write and improve, can improve about yield 15-35%, soluble sugar mean height 36%；To crop nutritional deficiency disease, as little
Leaf disease has specially good effect；Improve Physiological changes simultaneously, improve freezing tolerance, can be rated as " king in fertilizer ".Biogas slurry institute
Containing the butanoic acid in organic acid and the gibberellins in auxin, heteroauxing and vitamin B12 etc.,
Cell membrane and the vivo protein matter of unicellular pathogenic bacteria can be destroyed, effectively control the breeding of harmful levels of pathogens；Biogas slurry
In ammonia, ammonium salt and antibiotic, can suppress and close the respiratory system of the pest and disease damages such as red spider, thus reach
Anthelmintic, parasite killing, the effect of sterilization.Fruit tree putrefaction disease, ring spot, dry rot, root rot, speckle are fallen
Leaf disease, mould cardiopathia, brown spot, powdery mildew, diplostomiasis, red spot disease；Pear scab；Grapevine anthracnose,
White rot, gray mold, downy mildew, anthrax；Fructus Pruni pseudocerasi blade face shothole disease, leaf spot, bleeding disease；Fruit tree
Nearly all fungus, the bacteriosises such as vegetable and land for growing field crops epidemic disease in seedling stage, banded sclerotial blight all have obvious control action.
To aphid, red spider, white Aranea, maggot, heart-eating worm ovum, Pieris rapae, beet armyworm, bollworm etc. several
All pest and disease damages all have notable preventive effect, use the crop of biogas slurry can reduce prevention and control of plant diseases, pest control number of times throughout the year, and
Pollution-free, without residual hazard, without Drug resistance, be otherwise known as " biological pesticide ".
Potassium fulvate is that a kind of pure natural mineral active potassium element is fertile, and the content of organic matter is more than 50%, includes micro-
The multiple nutritional components such as secondary element, rare earth element, plant growth regulator, viral inhibitors, have improvement
Soil aggregate, chesson, improves the water conservation fertilizer-preserving ability of soil.Regulation pH value, reduces in soil
The content of heavy metal, reduces salt ion to seed and the harm of seedling.There is fixed nitrogen, phosphorus decomposing, activation potassium merit
Energy.The particularly potentiation to potash fertilizer is particularly evident, plays extraneous root strong sprout, anti-continuous cropping, disease-resistant, Crop Improvement
The effect of quality.Can the adhesive force of fortification of plants root system and rapid absorption ability, make the more vigorous leaf of crop plant type
Color is more dark green, and lodging tolerance is higher, makes soil activating, reduces continuous cropping disease.
Summary of the invention:
The technical problem to be solved in the present invention is to provide a kind of big rich in Water Soluble Organic Carbon, nitrogen, phosphorus, potassium four
Nutrient, nutrient is comprehensive, and humic acids can improve the utilization rate of fertilizer element, stimulates plant growth, strengthens
Crop anti-adversity ability, improves crop yield and quality, improves acid ground, improves soil activation, effectively profit
With organic waste, reducing and pollute, normal temperature and pressure produces, and energy consumption is low, equipment is simply alkaline containing humic acids
Liquid Fertilizer and preparation method thereof.
The present invention solves above-mentioned technical problem by the following technical programs:
A kind of fertile containing humic acids akaline liquid, by weight percentage, its raw material includes following components:
Biogas slurry: 4%-11%
Potassium fulvate: 20%-30%
Chelating agent: 6%-10%
Ammonium hydrogen carbonate: 14%-20%
Potassium carbonate: 4%-6%
Carbamide: 20%-25%
Compost fermentation sepage: 4%-17%
Water: 1%-8%；
The most each constituent mass percentage ratio summation is 100%.
Described biogas slurry processes feces of livestock and poultry for using self-circulating anaerobic reactor and short distance nitration reactor linkage
And agricultural waste and obtain.
Described potassium fulvate is mineral sources potassium fulvate or biochemical fulvic acid potassium.
Described chelating agent be mass concentration be the liquid polyphosphoric acids of 100% to 125%；Described ammonium hydrogen carbonate is work
Industry or agricultural ammonium bicarbonate；Described potassium carbonate is industrial or agricultural potassium carbonate or potassium sulfate；Described carbamide is work
Industry or agricultural carbamide.
Described compost fermentation sepage disposes biogas residue, feces of livestock and poultry and medium-height grass for using solar energy biofermentation groove
Medicinal residues obtain compost fermentation sepage.
Described Liquid Fertilizer nitrogen content is higher than 100mg/L, is higher than 50mg/L containing phosphorus pentoxide amount, containing potassium oxide
Amount is higher than 50mg/L, is more than 11 containing humic acids higher than 100mg/L, pH value.
Described a kind of preparation method fertile containing humic acids akaline liquid, comprises the following steps:
(1) by feces of livestock and poultry and agricultural waste 3:1-3 Mixed adjustment C/N to 10-25 and TS in proportion extremely
After 10%-30%, put into self-circulating anaerobic reactor and short distance nitration reactor linkage processing system, through 2-7
It anaerobic fermentation, it is thus achieved that described biogas slurry；Biogas residue and feces of livestock and poultry, Chinese herb residues, strain in mass ratio 100:
(500-700): (200-500): after 1 ratio Mixed adjustment C/N to 20-40 and moisture to 50%-65%,
Put into solar energy biofermentation groove to process, through fermentation in 6-12 days, it is thus achieved that described compost fermentation sepage, fermentation
Solid after after-ripening, make organic fertilizer product；
(2) step (1) gained biogas slurry, compost fermentation sepage and water are separately added into by described percentage by weight
In reactor with stirring, open stirring, mixing speed 10-20 rev/min, then press described weight respectively
Percentage ratio is sequentially added into chelating agent and ammonium hydrogen carbonate, stirs 60-120 minute, mixing speed under room temperature, normal pressure
10-20 rev/min, it is sequentially added into potassium carbonate, carbamide, potassium fulvate by described percentage by weight the most respectively,
Stir 60-120 minute under room temperature, normal pressure, mixing speed 10-20 rev/min, obtain containing humic acids alkalescence
Liquid Fertilizer mixed liquor；
(3) by step (2) gained akaline liquid fertilizer mixed liquor solid-liquid separation Han humic acids, gained liquid is
Described fertile containing humic acids akaline liquid.
Beneficial effects of the present invention:
(1) it is higher than higher than 100mg/L, the amount containing phosphorus pentoxide containing humic acids akaline liquid fertilizer nitrogen content
50mg/L, containing potassium oxide amount higher than 50mg/L, containing humic acids higher than 100mg/L, pH value more than 11, for making
The growth of thing provides Water Soluble Organic Carbon, nitrogen, phosphorus, the big nutrient of potassium four, and nutrient is comprehensive, and humic acids can
Improve fertilizer element utilization rate, stimulate plant growth, strengthen crop anti-adversity ability, improve crop yield and
Quality, improves acid ground, improves soil activation.
(2) producing under room temperature, normal pressure, energy consumption is low, equipment is simple, easily realizes Automated condtrol, fall
Low labor intensity.
(3) effectively utilize organic waste to recycle, reduce and pollute.
Accompanying drawing illustrates:
Fig. 1 is the process chart of a kind of preparation method fertile containing humic acids akaline liquid of the present invention.
Detailed description of the invention:
Following example are used for illustrating the present invention, but are not limited to the scope of the claims in the present invention protection.
Embodiment 1
A kind of fertile containing humic acids akaline liquid, by weight percentage, raw material includes following components:
Biogas slurry: 11%
Potassium fulvate: 20%
Chelating agent: 6%
Ammonium hydrogen carbonate: 14%
Potassium carbonate: 4%
Carbamide: 20%
Compost fermentation sepage: 17%
Water: 8%.
Described potassium fulvate is mineral sources potassium fulvate or biochemical fulvic acid potassium.
Described chelating agent be mass concentration be the liquid polyphosphoric acids of 125%；Described ammonium hydrogen carbonate is industry or agriculture
Use ammonium hydrogen carbonate；Described potassium carbonate is industrial or agricultural potassium carbonate；Described carbamide is agricultural carbamide.
As it is shown in figure 1, the above-mentioned preparation method fertile containing humic acids akaline liquid, comprise the following steps:
(1) by after feces of livestock and poultry and agricultural waste 3:1 Mixed adjustment C/N to 15 and TS to 15% in proportion,
Put into self-circulating anaerobic reactor and short distance nitration reactor linkage processing system, through 5 days anaerobic fermentations,
Obtain described biogas slurry and put into biogas slurry storage tank；Biogas residue is with feces of livestock and poultry, Chinese herb residues, strain in mass ratio
100:600:300:1 ratio Mixed adjustment C/N to 30 and moisture, to after 55%, put into solar energy biofermentation
Groove processes, through fermentation in 8 days, it is thus achieved that described compost fermentation sepage puts into sepage storage tank, the solid warp of fermentation
Organic fertilizer product is made after after-ripening；Described agricultural waste can be straw etc., and described strain is bacillus subtilis
Bacterium, colloid bacillus cereus, yeast and lactic acid bacteria 5:3:1:1 in mass ratio mixes.
(2) step (1) gained biogas slurry, compost fermentation sepage and water are separately added into by described percentage by weight
In reactor with stirring, open stirring, mixing speed 20 revs/min, then press described weight hundred respectively
Proportion by subtraction is sequentially added into chelating agent and ammonium hydrogen carbonate, stirs 60 minutes under room temperature, normal pressure, and mixing speed 20 turns/
Minute, it is sequentially added into potassium carbonate, carbamide, potassium fulvate by described percentage by weight the most respectively, room temperature,
Stir 60 minutes under normal pressure, mixing speed 20 revs/min, obtain containing humic acids akaline liquid fertilizer mixed liquor.
(3) step (2) gained is used precipitate and separate containing humic acids akaline liquid fertilizer mixed liquor, or use
Centrifugation or filtration separate, and gained liquid is containing humic acids akaline liquid fertile.
Gained containing humic acids akaline liquid fertilizer product nitrogen content 119.2mg/L, phosphorus pentoxide amount
55.1mg/L, potassium oxide amount 51.2mg/L, humic acids 102.2mg/L, pH value are 11.2.
Embodiment 2
A kind of fertile containing humic acids akaline liquid, by weight percentage, raw material includes following components:
Biogas slurry: 7%
Potassium fulvate: 25%
Chelating agent: 8%
Ammonium hydrogen carbonate: 17%
Potassium carbonate: 5%
Carbamide: 22%
Compost fermentation sepage: 10%
Water: 6%.
Described potassium fulvate is mineral sources potassium fulvate or biochemical fulvic acid potassium.
Described chelating agent be mass concentration be the liquid polyphosphoric acids of 125%；Described ammonium hydrogen carbonate is industry or agriculture
Use ammonium hydrogen carbonate；Described potassium carbonate is industrial or agricultural potassium carbonate；Described carbamide is agricultural carbamide.
As it is shown in figure 1, the above-mentioned preparation method fertile containing humic acids akaline liquid, comprise the following steps:
(1) by after feces of livestock and poultry and agricultural waste 3:2 Mixed adjustment C/N to 20 and TS to 20% in proportion,
Put into self-circulating anaerobic reactor and short distance nitration reactor linkage processing system, through 6 days anaerobic fermentations,
Obtain described biogas slurry and put into biogas slurry storage tank；Biogas residue is with feces of livestock and poultry, Chinese herb residues, strain in mass ratio
100:650:400:1 ratio Mixed adjustment C/N to 35 and moisture, to after 60%, put into solar energy biofermentation
Groove processes, through fermentation in 10 days, it is thus achieved that described compost fermentation sepage puts into sepage storage tank, the solid warp of fermentation
Organic fertilizer product is made after after-ripening；Described strain is bacillus subtilis, colloid bacillus cereus, yeast and breast
Acid bacterium 5:3:1:1 in mass ratio mixing.
(2) step (1) gained biogas slurry, compost fermentation sepage and water are separately added into by described percentage by weight
In reactor with stirring, open stirring, mixing speed 15 revs/min, then press described weight hundred respectively
Proportion by subtraction is sequentially added into chelating agent and ammonium hydrogen carbonate, stirs 100 minutes, mixing speed 15 turns under room temperature, normal pressure
/ minute, it is sequentially added into potassium carbonate, carbamide, potassium fulvate by described percentage by weight the most respectively, room temperature,
Stir 100 minutes under normal pressure, mixing speed 15 revs/min, obtain containing humic acids akaline liquid fertilizer mixed liquor.
(3) step (2) gained is used precipitate and separate containing humic acids akaline liquid fertilizer mixed liquor, or use
Centrifugation or filtration separate, and gained liquid is containing humic acids akaline liquid fertile.
Gained containing humic acids akaline liquid fertilizer product nitrogen content 128.4mg/L, phosphorus pentoxide amount
72.9mg/L, potassium oxide amount 62.4mg/L, humic acids 125.0mg/L, pH value are 11.5.
Embodiment 3
A kind of fertile containing humic acids akaline liquid, by weight percentage, raw material includes following components:
Biogas slurry: 4%
Potassium fulvate: 30%
Chelating agent: 10%
Ammonium hydrogen carbonate: 20%
Potassium carbonate: 6%
Carbamide: 25%
Compost fermentation sepage: 4%
Water: 1%.
Described potassium fulvate is mineral sources potassium fulvate or biochemical fulvic acid potassium.
Described chelating agent be mass concentration be the liquid polyphosphoric acids of 125%；Described ammonium hydrogen carbonate is industry or agriculture
Use ammonium hydrogen carbonate；Described potassium carbonate is industrial or agricultural potassium carbonate；Described carbamide is agricultural carbamide.
As it is shown in figure 1, the above-mentioned preparation method fertile containing humic acids akaline liquid, comprise the following steps:
(1) by after feces of livestock and poultry and agricultural waste 3:3 Mixed adjustment C/N to 25 and TS to 30% in proportion,
Put into self-circulating anaerobic reactor and short distance nitration reactor linkage processing system, through 7 days anaerobic fermentations,
Obtain described biogas slurry and put into biogas slurry storage tank；Biogas residue is with feces of livestock and poultry, Chinese herb residues, strain in mass ratio
100:700:500:1 ratio Mixed adjustment C/N to 40 and moisture, to after 65%, put into solar energy biofermentation
Groove processes, through fermentation in 12 days, it is thus achieved that described compost fermentation sepage puts into sepage storage tank, the solid warp of fermentation
Organic fertilizer product is made after after-ripening；Described strain is bacillus subtilis, colloid bacillus cereus, yeast and breast
Acid bacterium 5:3:1:1 in mass ratio mixing.
(2) step (1) gained biogas slurry, compost fermentation sepage and water are separately added into by described percentage by weight
In reactor with stirring, open stirring (10 revs/min), then add successively by described percentage by weight respectively
Enter chelating agent and ammonium hydrogen carbonate, stir 120 minutes (10 revs/min) under room temperature, normal pressure, the most respectively by institute
State percentage by weight and be sequentially added into potassium carbonate, carbamide, potassium fulvate, stir 120 minutes under room temperature, normal pressure
(10 revs/min), obtain containing humic acids akaline liquid fertilizer mixed liquor.
(3) step (2) gained is used precipitate and separate containing humic acids akaline liquid fertilizer mixed liquor, or use
Centrifugation or filtration separate, and gained liquid is containing humic acids akaline liquid fertile.
Gained containing humic acids akaline liquid fertilizer product nitrogen content 152.0mg/L, phosphorus pentoxide amount
90.7mg/L, potassium oxide amount 74.0mg/L, humic acids 150.0mg/L, pH value are 11.1.
The solar energy biofermentation groove of above three embodiment all uses Chinese patent " solar energy biofermentation groove "
The patented technology of (number of patent application: 201320228529.X)；Self-circulating anaerobic reactor and short distance nitration
Reactor linkage processing system, employing Chinese patent " self-circulating anaerobic reactor " (number of patent application:
201320045332.2 the self-circulating anaerobic reactor in) and Chinese patent " short distance nitration reactor " (patent
Application number: 201320613848.2) in short distance nitration reactors in series composition.
Claims (7)
1. one kind contains humic acids akaline liquid fertilizer, it is characterised in that by weight percentage, its raw material includes
Following components:
Biogas slurry: 4%-11%
Potassium fulvate: 20%-30%
Chelating agent: 6%-10%
Ammonium hydrogen carbonate: 14%-20%
Potassium carbonate: 4%-6%
Carbamide: 20%-25%
Compost fermentation sepage: 4%-17%
Water: 1%-8%；
The most each constituent mass percentage ratio summation is 100%.
One the most according to claim 1 is fertile containing humic acids akaline liquid, it is characterised in that described
Biogas slurry is discarded for using self-circulating anaerobic reactor and short distance nitration reactor linkage process feces of livestock and poultry and farming
Thing and obtain.
One the most according to claim 1 is fertile containing humic acids akaline liquid, it is characterised in that described
Potassium fulvate is mineral sources potassium fulvate or biochemical fulvic acid potassium.
One the most according to claim 1 is fertile containing humic acids akaline liquid, it is characterised in that described network
Mixture be mass concentration be the liquid polyphosphoric acids of 100% to 125%；Described ammonium hydrogen carbonate is industrial or agricultural carbon
Acid hydrogen ammonium；Described potassium carbonate is industrial or agricultural potassium carbonate or potassium sulfate；Described carbamide is industrial or agricultural urine
Element.
One the most according to claim 1 is fertile containing humic acids akaline liquid, it is characterised in that described
Compost fermentation sepage obtains heap for using solar energy biofermentation groove to dispose biogas residue, feces of livestock and poultry and Chinese herb residues
Fertile fermentation sepage.
6. fertile containing humic acids akaline liquid according to the one one of claim 1-5 Suo Shu, it is characterised in that
Described Liquid Fertilizer nitrogen content is higher than 100mg/L, is higher than 50mg/L containing phosphorus pentoxide amount, containing potassium oxide amount height
In 50mg/L, it is more than 11 containing humic acids higher than 100mg/L, pH value.
A kind of preparation method fertile containing humic acids akaline liquid the most according to claim 1, its feature exists
In, comprise the following steps:
(1) by feces of livestock and poultry and agricultural waste 3:1-3 Mixed adjustment C/N to 10-25 and TS in proportion extremely
After 10%-30%, put into self-circulating anaerobic reactor and short distance nitration reactor linkage processing system, through 2-7
It anaerobic fermentation, it is thus achieved that described biogas slurry；Biogas residue and feces of livestock and poultry, Chinese herb residues, strain in mass ratio 100:
(500-700): (200-500): after 1 ratio Mixed adjustment C/N to 20-40 and moisture to 50%-65%,
Put into solar energy biofermentation groove to process, through fermentation in 6-12 days, it is thus achieved that described compost fermentation sepage, fermentation
Solid after after-ripening, make organic fertilizer product；
(2) step (1) gained biogas slurry, compost fermentation sepage and water are separately added into by described percentage by weight
In reactor with stirring, open stirring, mixing speed 10-20 rev/min, then press described weight respectively
Percentage ratio is sequentially added into chelating agent and ammonium hydrogen carbonate, stirs 60-120 minute, mixing speed under room temperature, normal pressure
10-20 rev/min, it is sequentially added into potassium carbonate, carbamide, potassium fulvate by described percentage by weight the most respectively,
Stir 60-120 minute under room temperature, normal pressure, mixing speed 10-20 rev/min, obtain containing humic acids alkalescence
Liquid Fertilizer mixed liquor；
(3) by step (2) gained akaline liquid fertilizer mixed liquor solid-liquid separation Han humic acids, gained liquid is
Described fertile containing humic acids akaline liquid.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106748495A (en) * | 2016-12-28 | 2017-05-31 | 贵州省贵福生态肥业有限公司 | The Liquid Fertilizer that a kind of soil polluted by manganese is repaired |
| CN115448776A (en) * | 2022-07-28 | 2022-12-09 | 萍乡市红土地腐植酸有限公司 | Phosphorus humate and preparation method thereof |
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| CN102531742A (en) * | 2010-12-31 | 2012-07-04 | 郭宗华 | Liquid fertilizer and preparation method thereof |
| CN203200185U (en) * | 2013-04-28 | 2013-09-18 | 广西玉林市大智生物科技有限公司 | Solar biological fermentation tank |
| CN103833185A (en) * | 2014-03-10 | 2014-06-04 | 北京工业大学 | Energy recovery-based landfill leachate autotrophic nitrogen removal method |
| CN105110879A (en) * | 2015-07-23 | 2015-12-02 | 合肥众月健康科技有限公司 | Liquid fertilizer capable of preventing and treating soil-borne diseases and preparation method thereof |
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2016
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102531742A (en) * | 2010-12-31 | 2012-07-04 | 郭宗华 | Liquid fertilizer and preparation method thereof |
| CN203200185U (en) * | 2013-04-28 | 2013-09-18 | 广西玉林市大智生物科技有限公司 | Solar biological fermentation tank |
| CN103833185A (en) * | 2014-03-10 | 2014-06-04 | 北京工业大学 | Energy recovery-based landfill leachate autotrophic nitrogen removal method |
| CN105110879A (en) * | 2015-07-23 | 2015-12-02 | 合肥众月健康科技有限公司 | Liquid fertilizer capable of preventing and treating soil-borne diseases and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106748495A (en) * | 2016-12-28 | 2017-05-31 | 贵州省贵福生态肥业有限公司 | The Liquid Fertilizer that a kind of soil polluted by manganese is repaired |
| CN115448776A (en) * | 2022-07-28 | 2022-12-09 | 萍乡市红土地腐植酸有限公司 | Phosphorus humate and preparation method thereof |
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