CN105899357A - 用于室内和室外的层状建筑板 - Google Patents
用于室内和室外的层状建筑板 Download PDFInfo
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- CN105899357A CN105899357A CN201480073119.XA CN201480073119A CN105899357A CN 105899357 A CN105899357 A CN 105899357A CN 201480073119 A CN201480073119 A CN 201480073119A CN 105899357 A CN105899357 A CN 105899357A
- Authority
- CN
- China
- Prior art keywords
- layer
- acrylate
- building panel
- stratiform
- plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000010410 layer Substances 0.000 claims abstract description 97
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 27
- 239000004814 polyurethane Substances 0.000 claims abstract description 12
- 229920002635 polyurethane Polymers 0.000 claims abstract description 12
- 239000012790 adhesive layer Substances 0.000 claims description 44
- -1 n-octyl Chemical group 0.000 claims description 33
- 239000012948 isocyanate Substances 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 30
- 150000002513 isocyanates Chemical class 0.000 claims description 28
- 239000005056 polyisocyanate Substances 0.000 claims description 28
- 229920001228 polyisocyanate Polymers 0.000 claims description 28
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 26
- 239000000463 material Substances 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 25
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 125000005442 diisocyanate group Chemical group 0.000 claims description 14
- 239000000049 pigment Substances 0.000 claims description 14
- 150000002148 esters Chemical class 0.000 claims description 13
- 125000001931 aliphatic group Chemical group 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 10
- 238000005034 decoration Methods 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 238000007598 dipping method Methods 0.000 claims description 7
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical group NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims description 5
- 125000000468 ketone group Chemical group 0.000 claims description 5
- SEEPANYCNGTZFQ-UHFFFAOYSA-N sulfadiazine Chemical compound C1=CC(N)=CC=C1S(=O)(=O)NC1=NC=CC=N1 SEEPANYCNGTZFQ-UHFFFAOYSA-N 0.000 claims description 5
- 229920003180 amino resin Polymers 0.000 claims description 4
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 4
- 125000005396 acrylic acid ester group Chemical group 0.000 claims description 3
- 125000002723 alicyclic group Chemical group 0.000 claims description 3
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 claims description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 2
- JGCUIOIXGKBHJU-UHFFFAOYSA-N N=C=O.N=C=O.NC(N)=O Chemical class N=C=O.N=C=O.NC(N)=O JGCUIOIXGKBHJU-UHFFFAOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 claims description 2
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims description 2
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- GYDSPAVLTMAXHT-UHFFFAOYSA-N pentyl 2-methylprop-2-enoate Chemical compound CCCCCOC(=O)C(C)=C GYDSPAVLTMAXHT-UHFFFAOYSA-N 0.000 claims description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical class N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 claims 1
- 125000004185 ester group Chemical group 0.000 claims 1
- 238000003475 lamination Methods 0.000 claims 1
- MYSWGNHLJGOCPT-UHFFFAOYSA-N methyl prop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C=C MYSWGNHLJGOCPT-UHFFFAOYSA-N 0.000 claims 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 claims 1
- 239000012792 core layer Substances 0.000 abstract description 2
- 239000000123 paper Substances 0.000 description 20
- 239000011888 foil Substances 0.000 description 17
- 229920005989 resin Polymers 0.000 description 17
- 239000011347 resin Substances 0.000 description 17
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 13
- 230000005855 radiation Effects 0.000 description 10
- 229920000877 Melamine resin Polymers 0.000 description 9
- 239000004640 Melamine resin Substances 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- 239000000654 additive Substances 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 8
- 229920001187 thermosetting polymer Polymers 0.000 description 8
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 7
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 7
- 239000012965 benzophenone Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Natural products OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 6
- 150000002576 ketones Chemical class 0.000 description 6
- 238000007639 printing Methods 0.000 description 6
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 5
- 239000004202 carbamide Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- 238000007711 solidification Methods 0.000 description 5
- 230000008023 solidification Effects 0.000 description 5
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 4
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 4
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 4
- 229920001568 phenolic resin Polymers 0.000 description 4
- 239000005011 phenolic resin Substances 0.000 description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 4
- 239000004926 polymethyl methacrylate Substances 0.000 description 4
- 238000007790 scraping Methods 0.000 description 4
- WXPWZZHELZEVPO-UHFFFAOYSA-N (4-methylphenyl)-phenylmethanone Chemical compound C1=CC(C)=CC=C1C(=O)C1=CC=CC=C1 WXPWZZHELZEVPO-UHFFFAOYSA-N 0.000 description 3
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- NJWGQARXZDRHCD-UHFFFAOYSA-N 2-methylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(C)=CC=C3C(=O)C2=C1 NJWGQARXZDRHCD-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000005058 Isophorone diisocyanate Substances 0.000 description 3
- 235000015511 Liquidambar orientalis Nutrition 0.000 description 3
- 239000004870 Styrax Substances 0.000 description 3
- 244000028419 Styrax benzoin Species 0.000 description 3
- 235000000126 Styrax benzoin Nutrition 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 210000003195 fascia Anatomy 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- HPAFOABSQZMTHE-UHFFFAOYSA-N phenyl-(2,4,6-trimethylphenyl)methanone Chemical class CC1=CC(C)=CC(C)=C1C(=O)C1=CC=CC=C1 HPAFOABSQZMTHE-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- PWCBSPFFLHCDKT-UHFFFAOYSA-N (2,6-dimethoxyphenyl)-(2,4,4-trimethylpentylphosphonoyl)methanone Chemical group COC1=CC=CC(OC)=C1C(=O)P(=O)CC(C)CC(C)(C)C PWCBSPFFLHCDKT-UHFFFAOYSA-N 0.000 description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- VUIMBZIZZFSQEE-UHFFFAOYSA-N 1-(1h-indol-3-yl)ethanone Chemical compound C1=CC=C2C(C(=O)C)=CNC2=C1 VUIMBZIZZFSQEE-UHFFFAOYSA-N 0.000 description 2
- XHLHPRDBBAGVEG-UHFFFAOYSA-N 1-tetralone Chemical compound C1=CC=C2C(=O)CCCC2=C1 XHLHPRDBBAGVEG-UHFFFAOYSA-N 0.000 description 2
- PIZHFBODNLEQBL-UHFFFAOYSA-N 2,2-diethoxy-1-phenylethanone Chemical compound CCOC(OCC)C(=O)C1=CC=CC=C1 PIZHFBODNLEQBL-UHFFFAOYSA-N 0.000 description 2
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NTPLXRHDUXRPNE-UHFFFAOYSA-N 4-methoxyacetophenone Chemical compound COC1=CC=C(C(C)=O)C=C1 NTPLXRHDUXRPNE-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 150000004056 anthraquinones Chemical class 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 125000005605 benzo group Chemical group 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical group CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011518 fibre cement Substances 0.000 description 2
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000000976 ink Substances 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 239000002655 kraft paper Substances 0.000 description 2
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- OJUGVDODNPJEEC-UHFFFAOYSA-N phenylglyoxal Chemical compound O=CC(=O)C1=CC=CC=C1 OJUGVDODNPJEEC-UHFFFAOYSA-N 0.000 description 2
- FAQJJMHZNSSFSM-UHFFFAOYSA-N phenylglyoxylic acid Chemical compound OC(=O)C(=O)C1=CC=CC=C1 FAQJJMHZNSSFSM-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 230000004224 protection Effects 0.000 description 2
- 238000003847 radiation curing Methods 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 1
- UYSQHMXRROFKRN-UHFFFAOYSA-N (2,4-dimethylphenyl)-phenylmethanone Chemical compound CC1=CC(C)=CC=C1C(=O)C1=CC=CC=C1 UYSQHMXRROFKRN-UHFFFAOYSA-N 0.000 description 1
- VMHYWKBKHMYRNF-UHFFFAOYSA-N (2-chlorophenyl)-phenylmethanone Chemical compound ClC1=CC=CC=C1C(=O)C1=CC=CC=C1 VMHYWKBKHMYRNF-UHFFFAOYSA-N 0.000 description 1
- CSUUDNFYSFENAE-UHFFFAOYSA-N (2-methoxyphenyl)-phenylmethanone Chemical compound COC1=CC=CC=C1C(=O)C1=CC=CC=C1 CSUUDNFYSFENAE-UHFFFAOYSA-N 0.000 description 1
- RBKHNGHPZZZJCI-UHFFFAOYSA-N (4-aminophenyl)-phenylmethanone Chemical compound C1=CC(N)=CC=C1C(=O)C1=CC=CC=C1 RBKHNGHPZZZJCI-UHFFFAOYSA-N 0.000 description 1
- KTDVNFPRWNZHMH-UHFFFAOYSA-N (4-butoxyphenyl)-phenylmethanone Chemical compound C1=CC(OCCCC)=CC=C1C(=O)C1=CC=CC=C1 KTDVNFPRWNZHMH-UHFFFAOYSA-N 0.000 description 1
- XKSUVRWJZCEYQQ-UHFFFAOYSA-N 1,1-dimethoxyethylbenzene Chemical compound COC(C)(OC)C1=CC=CC=C1 XKSUVRWJZCEYQQ-UHFFFAOYSA-N 0.000 description 1
- VNMOIBZLSJDQEO-UHFFFAOYSA-N 1,10-diisocyanatodecane Chemical compound O=C=NCCCCCCCCCCN=C=O VNMOIBZLSJDQEO-UHFFFAOYSA-N 0.000 description 1
- ZTNJGMFHJYGMDR-UHFFFAOYSA-N 1,2-diisocyanatoethane Chemical class O=C=NCCN=C=O ZTNJGMFHJYGMDR-UHFFFAOYSA-N 0.000 description 1
- OTEKOJQFKOIXMU-UHFFFAOYSA-N 1,4-bis(trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=C(C(Cl)(Cl)Cl)C=C1 OTEKOJQFKOIXMU-UHFFFAOYSA-N 0.000 description 1
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 1
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 description 1
- DHCIAVVQOMVUPC-UHFFFAOYSA-N 1-(3,4-diacetylphenyl)ethanone Chemical compound CC(=O)C1=CC=C(C(C)=O)C(C(C)=O)=C1 DHCIAVVQOMVUPC-UHFFFAOYSA-N 0.000 description 1
- SKBBQSLSGRSQAJ-UHFFFAOYSA-N 1-(4-acetylphenyl)ethanone Chemical compound CC(=O)C1=CC=C(C(C)=O)C=C1 SKBBQSLSGRSQAJ-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- BOCJQSFSGAZAPQ-UHFFFAOYSA-N 1-chloroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2Cl BOCJQSFSGAZAPQ-UHFFFAOYSA-N 0.000 description 1
- MKZPMOFOBNHBSL-UHFFFAOYSA-N 1-isocyanato-1-methylcyclohexane Chemical compound O=C=NC1(C)CCCCC1 MKZPMOFOBNHBSL-UHFFFAOYSA-N 0.000 description 1
- SQAINHDHICKHLX-UHFFFAOYSA-N 1-naphthaldehyde Chemical compound C1=CC=C2C(C=O)=CC=CC2=C1 SQAINHDHICKHLX-UHFFFAOYSA-N 0.000 description 1
- QQLIGMASAVJVON-UHFFFAOYSA-N 1-naphthalen-1-ylethanone Chemical compound C1=CC=C2C(C(=O)C)=CC=CC2=C1 QQLIGMASAVJVON-UHFFFAOYSA-N 0.000 description 1
- CERJZAHSUZVMCH-UHFFFAOYSA-N 2,2-dichloro-1-phenylethanone Chemical compound ClC(Cl)C(=O)C1=CC=CC=C1 CERJZAHSUZVMCH-UHFFFAOYSA-N 0.000 description 1
- GIMQKKFOOYOQGB-UHFFFAOYSA-N 2,2-diethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)(OCC)C(=O)C1=CC=CC=C1 GIMQKKFOOYOQGB-UHFFFAOYSA-N 0.000 description 1
- BTJPUDCSZVCXFQ-UHFFFAOYSA-N 2,4-diethylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC(CC)=C3SC2=C1 BTJPUDCSZVCXFQ-UHFFFAOYSA-N 0.000 description 1
- LCHAFMWSFCONOO-UHFFFAOYSA-N 2,4-dimethylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(C)=CC(C)=C3SC2=C1 LCHAFMWSFCONOO-UHFFFAOYSA-N 0.000 description 1
- LQPXWLZWRGJJNQ-UHFFFAOYSA-N 2-(9-oxothioxanthen-1-yl)oxyacetic acid Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2OCC(=O)O LQPXWLZWRGJJNQ-UHFFFAOYSA-N 0.000 description 1
- MOMFXATYAINJML-UHFFFAOYSA-N 2-Acetylthiazole Chemical group CC(=O)C1=NC=CS1 MOMFXATYAINJML-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- OLCHHNMEPSVOAH-UHFFFAOYSA-N 2-butylidenenonanoic acid Chemical compound CCCCCCCC(C(O)=O)=CCCC OLCHHNMEPSVOAH-UHFFFAOYSA-N 0.000 description 1
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Abstract
本发明涉及用于室内和室外的层状建筑板,其包括芯层(20)和布置在其上的密胺树脂浸渍纸(21)。为了提高其它层的粘合,包括聚氨酯和丙烯酸酯的粘合层(30)设置在纸上。
Description
技术领域
本发明涉及用于室内和室外的层状建筑板、用于制造该建筑板的板材、以及用于制造该建筑板的方法。
背景技术
如建筑板应当从本发明中得以改进的,它们具有用于建筑物的室内结构和室外结构的若干应用。例如,它们用作用于建筑物外墙的光学涂层的外墙板,以出于美观和/或用于保护建筑群免受大气的影响。
采用纤维水泥作为外墙板非常普遍。纤维水泥是由水泥和抗拉力纤维张力纤维构成的复合材料的总称,这是由于它们例如分布在商标名Eternit下。此外,基于浸渍有酚醛树脂的多层牛皮纸的芯板的层压板被广泛地使用(也可作为高压板(HPL)。装饰纸施加在通常浸渍有密胺树脂的所述芯板的前侧和后侧。以增高的温度和70至100巴之间的特定压制压力,在高压印刷机中压制芯板层和装饰层。然而,大量所使用的装饰没有足够的大气保护。因此,由于太阳的UV辐射,特别是由对颜料色素的腐蚀所引起的,颜料随时间发生变化。为了实现足够的颜色稳定性并且因此外墙板的长寿命,已经建立了不同的解决方案。已知的方法包括将特定的聚甲基丙烯酸甲酯箔片额外地施加在装饰纸上并压制装饰纸。该PMMA箔片包括UV过滤片,通过该过滤片高达99%的UV辐射可被吸收。该PMMA箔片例如已知在商标名Korad下。所述箔片的缺点在于它们必须被特定的硅离型纸压制。这导致相对较高光泽的表面,这在光学上是不期望的。此外,PMMA箔片相对较软,使得这种板材的耐擦刮性不足。此外,表面难以清洁,特别地涂鸦难以去除。
为了避免这些缺点,已经研发出某些方法。在一种方法中,在第一步,装饰层例如浸渍有蜜胺树脂并被干燥。在第二步,这些浸渍的装饰通过漆通道,在此,特定的热固性丙烯酸树脂施加在一侧,其已经包含了UV过滤***。接着,压制发生,如上所述。在又一个方法中,酚醛树脂的芯板与用于电子束的涂漆装饰箔片相结合。
适于制造地板的建筑板例如从WO 2007/042258 A1中已知。在此,描述了用于直接涂布木基材料板的方法,其中,相对较厚的塑料材料的保护层在单个涂布步骤中被施加的板材的表面上。所使用的塑料材料为通过聚合固化的可聚合丙烯酸酯***。聚合由此通过辐射被触发,使得在施加层的厚度上发生完全转化。
在同一申请人的WO2008/061791 A1中,描述了已知的现有技术的进一步发展。该公开的改进的精髓在于至少两个液体聚合物层以湿湿混合的方式施加在板材表面上,使得涂层材料的表面发生部分混合。这两种湿湿混合的施加层继而固化在一起,在此,由于部分混合,固化产生的涂层具有硬度梯度,其中,涂层的硬度随着深度的增大而减小,如从产生的涂层的表面所见。
因此,本发明的任务是改进已知的现有技术并且特别提供用于室内和室外的层状建筑板,其中层具有非常良好的粘合性,并且其中装饰打印优选在没有纸载体的情况下直接被引入到中间层中。此外,期望表面具有改进的特性,像特别为改进的防刮擦性和防耐磨性并且同时易于清洗。在现有技术中陈述的缺点可以通过根据本发明的特定化学结构特性消除。阅读以下描述期间被提及的或者本领域的技术人员可以想到的这些和其它的任务将会通过根据权利要求1所述的层状建筑板、根据权利要求10的层状板以及根据权利要求22的方法来解决。
发明内容
根据本发明,提供了一种适用于室内和室外的层状建筑板。板材包括其上布置浸渍有热固性树脂、特别是氨基树脂的(至少)一种纸的芯板。这种纸在树脂固化后具有优异的机械特性,然而,由于大多数已确认的材料并且特别是丙烯酸酯仅不良地粘合在这些热固性树脂表面上(尤其是当它们基于密胺树脂时),所以表面被涂布得较差。对于该问题的解决方案,本发明提供了特定的粘合层,其中,该层基于异氰酸酯和(甲基)丙烯酸酯(甲基丙烯酸酯、丙烯酸酯以及这两种连接基团的混合物在本文中理解为(甲基)丙烯酸酯)的混合物,并且如需要,则基于催化剂和/或引发剂,以及特定的漆添加剂。该混合物施加(例如轧制、喷射或铸造)在固化板表面上,并且优选借助于高能辐射部分固化。该粘合层可以在一个加工步骤中施加,然而,也可以接连施加相同或相似的混合物的多个薄层,其中,中间层借助于高能辐射、优选UV辐射胶凝。在下文中,该层一般命名为粘合层。优选地,厚度优选大于20μm、更优选大于30μm并且最优选大于40μm的另一个(甲基)丙烯酸酯层在部分固化后直接布置在所述粘合层上。
粘合层和优选进一步施加的(甲基)丙烯酸酯层随后在又一个步骤中例如借助于UV辐射固化在一起。在发生的显著较慢的平行反应中,异氰酸酯尤其在形成尿烷键的情况下转化成丙烯酸酯的羟基。该反应在约10天之后完成,使得粘合层在该阶段之后包括聚氨酯和丙烯酸酯。异氰酸酯随后被完全转化并且不能在产品中检测到。已经表明,(甲基)丙烯酸酯层借助于该粘合层非常良好地粘合在建筑板的蜜胺树脂表面上,使得例如完全满足所生产的这种建筑板的室外应用的EN438的要求。
粘合层优选施加的厚度为10至100μm、更优选为10至80μm、甚至更优选为15至70μm并且最优选为20至60μm。在异氰酸酯与粘结剂基质的反应基(特别是(甲基)丙烯酸酯的羟基)完全反应之后,粘合层优选主要由聚氨酯和聚(甲基)丙烯酸酯的聚合物混合物组成。由于异氰酸酯的可能尚未转化的基团与空气水分发生反应,所以确保异氰酸酯完全反应。因为(甲基)丙烯酸酯组分已被聚合并且从而形成异氰酸酯被结合并缓慢转化为聚氨酯的支撑框架,所以即使聚氨酯反应在制造过程之后未直接完成,处理也可以立即进行。
因此,本发明涉及粘合层中的异氰酸酯完全转化为聚氨酯的建筑板,并且还涉及多层板,该多层板适用于制造粘合层(还)包括异氰酸酯和(甲基)丙烯酸酯的混合物的建筑板。可以说,这种板是根据权利要求1的层状建筑板的前体。
在优选的实施例中,装饰层施加在粘合层与优选施加在其上的(甲基)丙烯酸酯层之间。装饰层优选借助于在部分固化的粘合层上直接印刷而被印刷并且包括装饰颜料本身。换句话说,由于装饰纸通常是用于可商购的层压板的实例,所以装饰层优选不由装饰纸形成,而优选借助于在部分固化的粘合层上进行数字印刷而被直接印刷。
特别优选可聚合的装饰颜料被用作装饰颜料。该可聚合的装饰颜料增强层状板的机械特性。假设由于装饰层至少在边界区域中的聚合反应,故与粘合层的(甲基)丙烯酸酯化合物以及随后施加在其上的(甲基)丙烯酸酯层发生化学反应,这是不同层的粘合性增强的原因。
粘结层优选包括至少一种(甲基)丙烯酸酯、至少一种三聚多异氰酸酯、至少一种光引发剂和用于增强施加特性的一种或多种添加剂(像诸如助剂添加剂或缩合树脂)(若需要)的组合。
(甲基)丙烯酸酯组分通常优选玻璃化温度不大于0℃的单官能(甲基)丙烯酸烷基酯。羟基(甲基)丙烯酸酯优选为包括2至12个碳原子的链烷醇的(甲基)丙烯酸酯。特别优选羟基(甲基)丙烯酸酯在常压下的沸点至少为140℃、最优选至少为200℃。这导致了羟基(甲基)丙烯酸酯的低逸度。最优选地,组分选自由下列各项组成的群组:丙烯酸乙酯、丙烯酸丙酯、丙烯酸正丁酯、丙烯酸正己酯、丙烯酸正辛酯、丙烯酸2-乙基己酯、丙烯酸3-丙基庚酯、丙烯酸正癸酯、丙烯酸月桂酯、甲基丙烯酸正戊酯、甲基丙烯酸正辛酯、甲基丙烯酸正癸酯和甲基丙烯酸月桂酯、(甲基)丙烯酸丁酯、丙烯酸2-乙基己酯或丙烯酸3-丙基庚酯。
多异氰酸酯化合物通常优选包括脂族或脂环族化合物,其简称为脂(环)族。优选NCO官能度至少为1.8、更优选为1.8至5、特别优选为2至4的二异氰酸酯和多异氰酸酯,及其异氰脲酸酯、缩二脲、氨基甲酸酯和脲二酮,其可以通过低聚反应从这些低聚单体形式的基本二异氰酸酯中获得。异氰酸酯基的含量(按NCO=42g/mol计算)通常为低聚多异氰酸酯的5至25wt%。
二异氰酸酯优选为具有4至20个碳原子的异氰酸酯。常见的二异氰酸酯的示例为:脂族二异氰酸酯,像四亚甲基二异氰酸酯、1,6-六亚甲基二异氰酸酯(1,6-二异氰酸己烷)、八亚甲基二异氰酸酯、十亚甲基二异氰酸酯、十二亚甲基二异氰酸酯、十四亚甲基二异氰酸酯,四甲基二甲苯二异氰酸酯、三甲基己烷二异氰酸酯或四甲基己烷二异氰酸酯、赖氨酸二异氰酸酯的衍生物;脂环族二异氰酸酯,像1,4-二异氰酸基环己烷、1,3-二异氰酸基环己烷或1,2-二异氰酸基环己烷、4,4’-二(异氰酸基环己基)甲烷或2,4’-二(异氰酸基环己基)甲烷、1-异氰酸基-3,3,5-三甲基-5-(异氰酸基甲基)环己烷(异佛尔酮二异氰酸酯)、1,3-双(异氰酸基甲基)环己烷或1,4-双(异氰酸基甲基)环己烷或者2,4-二异氰酸基-1-甲基环己烷或2-6-二异氰酸基-1-甲基环己烷。此外,还可以有所提到的二异氰酸酯的混合物。优选为六亚甲基二异氰酸酯、1,3-二(异氰酸基甲基)环己烷、异佛尔酮-异氰酸酯和二(异氰酸基环己基)甲烷,更优选为六亚甲基异氰酸酯。
作为多异氰酸酯,多异氰酸酯可以考虑包括:异氰脲酸酯基的多异氰酸酯、脲二酮二异氰酸酯、包括缩二脲基的多异氰酸酯、包括尿烷基或氨基甲酸酯基的多异氰酸酯、包括噁二嗪三酮基的多异氰酸酯、具有总共6至20个碳原子的脂族二异氰酸酯的脲酮亚胺改性的多异氰酸酯、和/或具有总共6至20个碳原子的脂环族二异氰酸酯。
可***的二异氰酸酯和多异氰酸酯相对于二异氰酸酯和多异氰酸酯(混合物)优选具有10至60wt%、优选15至60wt%并且最优选为20至55wt%的异氰酸酯基(按NCO计算,分子量=42)含量。优选脂族环二或多异氰酸酯,例如前面提到的脂族或脂环族二异氰酸酯或其混合物。
此外,通常优选:
1)具有异氰脲酸酯基的脂族二异氰酸酯和/或脂环族二异氰酸酯。这里特别优选相应的脂族或脂环族异氰酸基异氰脲酸酯,并且特别基于六亚甲基二异氰酸酯和异佛尔酮二异氰酸酯的那些。现在的异氰脲酸酯从而特别为三异氰酸基烷基异氰脲酸酯或者三异氰酸基环烷基异氰脲酸酯(其代表二异氰酸酯的环状三聚物),或者是含有其高级同系物的混合物,其具有一个异氰酸酯环。异氰酸基-异氰脲酸酯的NCO含量一般为10至30wt%、特别为15至25wt%并且平均NCO官能度为3至4.5。
2)脲二酮二异氰酸酯,其具有脂族和/或脂环族键合的异氰酸酯基,优选脂族或脂环族键合的,并且特别是衍生自六亚甲基二异氰酸酯或异佛尔酮二异氰酸酯的那些。脲二酮二异氰酸酯是二异氰酸酯的环状二聚产品。脲二酮二异氰酸酯在制备中可用作唯一组分或用作含有其它的多异氰酸酯的混合物,特别是于1)中所提及的那些。
3)多异氰酸酯,其具有缩二脲基与脂环族或脂族键合的异氰酸酯基,特别是三(6-异氰酸基己基)缩二脲或包含其高级同系物的混合物。具有缩二脲基的这些多异氰酸酯的NCO含量为18至25wt%并且NCO官能度为3至4.5。
4)含有尿烷基和/或氨基甲酸酯基以及脂族或脂环键合的异氰酸酯基的多异氰酸酯,像它们可以例如通过富余量的六亚甲基二异氰酸酯或异佛尔酮二异氰酸酯转化成多元醇、或者优选转化成至少一种化合物(C2)(优选2-羟乙基(甲基)丙烯酸酯)而获得,该多元醇像例如三羟甲基丙烷、新戊二醇、季戊四醇、1,4-丁二醇、1,6-己二醇、1,3-丙二醇、乙二醇、二甘醇、甘油、1,2-二羟基丙烷或其混合物。具有尿烷基和/或氨基甲酸酯基的这些多异氰酸酯的NCO含量通常为12至20wt%并且平均NCO官能度至少为2,优选至少为2.1,特别优选为在2.5至3之间。
5)多异氰酸酯,其具有噁二嗪三酮基,其优选衍生自六亚甲基二异氰酸酯或异佛尔酮二异氰酸酯。含有噁二嗪三酮基的这种多异氰酸酯由二异氰酸酯和二氧化碳产生。然而,在适当情况下,上述提到的噁二嗪三酮基的含量也要被考虑。
6)脲酮亚胺改性的异氰酸酯。
在适当的情况下,1)到6)的多异氰酸酯也可以用作含有二异氰酸酯的混合物。
能够使用本领域的技术人员已知的光引发剂作为光引发剂,例如在“Advances inPolymer Science”,第14卷,施普林格,柏林,1974年或者K.K Dietliker,Chemistry andTechnology of UV-and EB-Formulation for Coatings,Inks and Paints,第3卷;Photoinitiators for Free Radical and Cationic Polymerization,PKT Oldring(EDS),升达(SITA)科技有限公司,伦敦中所提及的。例如可以考虑氧化膦、二苯甲酮、α-羟基烷基芳基酮、噻吨酮、蒽醌、乙酰苯、安息香和安息香醚、缩酮、咪唑类或苯酰甲酸。也考虑如WO 2006/005491 A1,第21页第18行至第22页第2行中所述的光引发剂。
对于单个类,下列化合物被示例性地提及:
单酰基氧化膦或双酰基氧化膦,例如819(双(2,4,6-三甲基苯甲酰基)苯基氧化膦,像诸如它们在EP-A 7 508、EP-A 57 474、DE-A 196 18 720、EP-A 495 751或EP-A 615 980中被描述,例如2,4,6-三甲基苯甲酰基二苯基氧化膦乙基-2,4,6-三甲基苯甲酰基二苯基亚膦酸酯、二(2,6-二甲基苯甲酰基)-2,4,4-三甲基烷基氧化膦,
二苯甲酮、4-氨基二苯甲酮、4,4’-二(二甲基氨基)二苯甲酮、4-苯基二苯甲酮、4-氯二苯甲酮、米蚩酮、邻-甲氧基二苯甲酮、2,4,6-三甲基二苯甲酮、4-甲基二苯甲酮、2,4-二甲基二苯甲酮、4-异丙基二苯甲酮、2-氯二苯甲酮、2,2’-二氯二苯甲酮、4-甲氧基二苯甲酮、4-丙氧基二苯甲酮或4-丁氧基二苯甲酮
1-苯甲酰基环己烷-1-醇(1-羟基-环己基-苯基甲酮)、2-羟基-2,2-二二甲基乙酰基-苯基甲酮(2-羟基-2-甲基-1-苯基-丙烷-1-酮)、1-羟基苯乙酮、1-[4-(2-羟基-乙氧基)-苯基]-2-羟基-2-甲基-1-丙烷-1-酮、聚合物、其包含聚合的2-羟基-2-甲基-1-(4-异丙烯-2-基-苯基)-丙烷-1-酮(KIP 150)
10-噻吨酮、噻吨-9-酮、占吨-9-酮、2,4-二甲基噻吨酮、2,4-二乙基噻吨酮、2,4-二-异-丙基噻吨酮、2,4-二氯噻吨酮、氯噻吨酮,
β-甲基蒽醌、叔丁基蒽醌、蒽醌羰酸酯、苯并[de]蒽-7-酮、苯并[a]蒽-7,12-二酮、2-甲基蒽醌、2-乙基蒽醌、2-叔丁基蒽醌、1-氯蒽醌、2-戊基蒽醌
苯乙酮、苯乙酮醌、苯戊酮、己烷酮、α-苯基丁酸酮、对-吗啉基苯丙酮、二苯并环庚酮、4-吗啉苯甲酮、对-二乙酰基苯、4’-甲氧基苯乙酮、α四氢萘酮、9-乙酰基菲、2-乙酰基菲、3-乙酰基菲、3-乙酰基吲哚、9-芴酮、1-茚满酮、1,3,4-三乙酰基苯,1-萘乙酮、2-萘乙酮、2,2-二甲氧基-2-苯基苯乙酮、2,2-二乙氧基-2-苯基苯乙酮、1,1-二氯苯乙酮、1-羟基苯乙酮、2,2-二乙氧基苯乙酮、2-甲基-1-[4-(甲硫基)苯基]-2-吗啉基丙基-1-酮、2,2-二甲氧基-1,2-二苯基乙基-2-酮、2-苄基-2-二甲基氨基-1-(4-吗啉代苯基)-丁-1-酮
4-吗啉基脱氧安息香、安息香、安息香-异-丁基醚、安息香-四氢吡喃基醚、安息香-甲基醚、安息香-乙基醚、安息香丁基醚、安息香-异-丙基醚、7-H-安息香-甲基醚,
乙酰苯二甲基缩酮、2,2-二乙氧基苯乙酮、苯偶酰缩酮(像苯偶酰二甲基缩酮,
如在DE-A 198 26 712、DE-A 199 13 353或WO 98/33761中所述的苯基乙醛酸,例如摩尔质量为62至500g/mol的聚乙二醇的苯基乙二醛酸单酯和二酯。
苯甲醛、甲基乙基酮、1-萘甲醛、三苯基膦、三-邻-甲苯基膦、2,3-丁二酮
提及的混合物特别是2-羟基-2-甲基-1-苯基-丙基-2-酮和1-羟基-环己基-苯基酮,
双(2,6-二甲氧基苯甲酰)-2,4,4-三甲基戊基氧化膦和2-羟基-2-甲基-1-苯基-丙基-1-酮
苯甲酮和1-羟基-环己基-苯基酮,
双(2,6-二甲氧基苯甲酰)-2,4,4-三甲基戊基氧化膦和1-羟基-环己基-苯基酮,
2,4,6-三甲基苯甲酰基二苯基氧化膦和2-羟基-2-甲基-1-苯基-丙基-1-酮,
2,4,6-三甲基苯甲酮和4-甲基苯甲酮,
2,4,6-三甲基苯甲酮和4-甲基苯甲酮以及2,4,6-三甲基苯甲酰基二苯基氧化膦,
可能的光引发剂也是聚合的光引发剂,像诸如具有不同的分子量(优选200至250g/mol(CAS 515136-48-8))的羧基甲氧基苯甲酮和聚四亚甲基二醇的二元酸酯,以及CAS 1246194-73-9、CAS 813452-37-8、CAS 71512-90-8、CAS 886463-10-1或二苯甲酮的进一步聚合的衍生物,如它们例如可以根据荷兰瓦尔韦克的IGM Resins B.V.公司的商品名BP或者瑞士的Rahn AG公司的商品名BP1商购。此外也可考虑聚合的噻吨酮,例如具有不同分子量的羧基甲氧基噻吨酮和聚四亚甲基二醇的二元酸酯,像它们诸如可以根据荷兰瓦尔韦克的IGM Resins B.V.公司的商品名TX商购。此外也可以考虑是聚合的α-氨基-酮,例如具有不同分子量的羧基乙氧基噻吨酮和聚乙二醇的二元酸酯,像它们例如可以根据荷兰瓦尔韦克的IGM Resins B.V.公司的商品名为910商购。
为了改善粘合以及施加性,例如可以施加由尿素或尿素的衍生物产生的缩合树脂以及选自C-H酸性醛或酮或者其与甲醛的混合物的酮或醛。作为制剂添加剂,可以使用常规的漆制剂添加剂,像诸如消泡剂、除氧剂、分散剂、流动改进添加剂等。
芯板优选为厚度为2至50mm、优选为3至50mm、最优选为4至50mm的相对刚性的板材。作为芯板的起点,例如可以选择层压板,即,包括浸渍有酚醛树脂(也命名为高压层压板-HPL)的多个纸层的板材。进一步优选的材料是中密度纤维板(MDF)或高密度纤维板(HDF),也优选为木基材料板或PVC板。在完全形成的粘合层(其中,异氰酸酯完全反应)中,聚氨酯的重量百分比优选大于5%、更优选大于20%,并且最优选大于40%。
为了增大以这种方式制造的建筑板的抗UV性能,可以加入额外的添加剂,例如作为用于室外应用的大气保护的清除剂和UV吸收剂或者用于提高抗擦刮性和抗微擦刮性的纳米颗粒改性的组分。这些添加剂优选添加到布置在粘合层上的(甲基)丙烯酸酯层。
本发明将在下列示例中得以详细说明:
建筑板的制造:
包括150g/m2的克重的碱性牛皮纸浸渍有适用于压缩板的可商购的酚醛树脂。该浸渍物在浸渍后具有220g/m2的每单位面积的质量。具有95g/m2的克重的白色装饰纸浸渍有可商购的密胺树脂;该浸渍装饰纸的每单位面积的质量为214g/m2。在铺设工位,浸渍基料的以下结合发生:装饰片/75层酚醛树脂浸渍物/装饰片(从底部到顶部)。如此结合的层被传送到多层板压机并进行如下压制:a)压力累积到8MPa的特定的压制压力,b)8分钟内加热至高达140℃,c)使温度在140℃下保持20分钟,d)在8分钟内冷却至室温,e)在室温下调节5分钟以及f)将压力降至常压并从压制机上脱模。
示例A:在辊涂机中,以15g/m2的在涂覆质量,使以这种方式制造的建筑板设置有根据本发明的粘合层。粘合层包括35重量份的LaromerLR9085、10重量份的丙基庚基丙烯酸酯、2.5重量份的丙烯酸月桂酯、0.5重量份的EFKA3777、0.2份的TegoRad2011、1.8重量份的Irgacure MBF以及50份的Basonate HI 100。本领域的技术人员已知的可商购的原料隐藏在这些名称后面。粘合层借助于UV辐射胶凝。在又一个方法步骤中,额外的丙烯酸酯层借助于辊涂机以35g/m2的涂覆质量被施加为顶层。顶层包括以下部分:60.3重量份的LaromerLR 8987、22.2重量份的Laromer HDDA、2重量份的Tinuvin 400、1重量份的Tinuvin 292、10重量的乙基己基丙烯酸酯、2重量份的Irgacure TPO-L、2重量份的Irgacure 184以及0.2重量份的TegoRad 2010。所施加的顶层借助于UV辐射固化。
示例B:建筑板借助于辊涂机以10g/m2的量涂布有来自示例A的粘合层,并且所施加的粘合底漆借助于UV辐射胶凝。在该层之上,装饰层(在该情况下,仿橡木)借助于工业数字打印机生产。由此,施加4.5g/m2的数字印刷油墨,其被分离为黄色、品红、青色和黑色的颜料。这些颜料是可聚合的并且借助于UV辐射胶凝。在下一个工作步骤中,来自示例A的顶漆借助于辊涂机以30g/m2的量施加。该层在“湿状态”下被传送至箔片压延机。第二层顶漆辊涂在结构化箔片上,在这种情况下,橡木结构的再生,即为25g/m2。两个“湿”层在箔片压延机中合并。整个层借助于UV辐射通过箔片被照射,并且从而缓慢地固化。当抽出箔片后,得到装饰性紧凑板材,在这种情况下,具有适当的孔隙结构的仿橡木。
在示例A和B中制造的建筑板在存储10天后进行实验室试验。按照EN 438所需的所有参数从而稳定地获得。此外,根据EN 16094,该板满足了耐微擦刮性的最高水平的要求。
附图说明
下面,将参照附图对本发明进行更详细地描述。这里示出:
图1示出具有芯板和由缩聚热固性树脂纸组成的外层的层状建筑板的示意性结构;
图2示出层状板,其中,粘合层尚未完全转化;
图3示出根据本发明的层状建筑板;
图4示出根据本发明的层状建筑板的另一个实施例;并且
图5示出用于制造根据本发明的板材以及用于实施根据本发明的方法的示例性的、示意性绘示的设备。
具体实施方式
在图1中,示出芯板20的示意性结构。芯板20具有前侧和后侧,其中,布置浸渍有热固性树脂(像诸如密胺树脂)的纸21,并在后表面布置也浸渍有热固性树脂的纸22。芯板20可以例如为MDF板或HDF板。
特别优选芯板20包括较大数量的浸渍有酚醛树脂的牛皮纸,像约20至90层纸。图1所示的结构在热量和压力的影响下在压制机中被压制成一个部件。芯板和覆盖层中的不同树脂固化在其中。在图2中,示例性示出根据本发明的层状板的示意性结构。图2的板材包括芯板20和图1的实施例的装饰浸渍物22和21。优选在粘合层(粘合底漆)30施加在纸21上之前,将这些层压在一起。粘合层30包括异氰酸酯和(甲基)丙烯酸酯的混合物。另外的丙烯酸酯层布置在该粘合层上。粘合层的厚度(高度)一般优选为10至100μm、更优选为10至80μm、甚至更优选为15至70μm并且最优选为20至60μm。这些厚度的示值适用于固化后的粘合层。其上布置的额外的丙烯酸酯层40的厚度(高度)通常还优选大于20μm、更优选大于30μm并且最优选大于40μm(固化后)。优选丙烯酸酯层40的厚度不应大于100μm。图2中示例性示出的层状板可以已被处理。然而,单层的充分粘附仅在粘合层30的异氰酸酯与(甲基)丙烯酸酯基发生完全反应形成聚氨酯之后才能达到。异氰酸酯的近乎完全转化在约10天之后才能达到。
在图3中,示出异氰酸酯被完全转化之后的图2的层状板。为了图示性的目的,在附图中,层30’的图案与层30不同。层30’主要包括(甲基)丙烯酸酯和聚氨酯,如上所述。
图4以示意图示出优选实施例。在图4的实施例中,装饰层50布置在浸渍有热固性树脂(例如蜜胺树脂)的纸21上并且布置在粘合层30或30’的下方。由于所使用的两层30和40的(甲基)丙烯酸酯优选为透明,因此可以提供具有任何期望的装饰的建筑板。
在所示的实施例中,这些层的各者均只位于芯层20的前侧。然而,本领域的技术人员应该了解相同或相似的层构成还可以额外地或替代地设置在芯板的后侧。
在图5中,示意性地示出装置,以图示出根据本发明的方法。方法的起点为具有浸渍有热固性树脂(像诸如密胺树脂)的纸21的芯板,其中,纸的密胺树脂例如已经通过相应的上游压制过程(未示出)被固化。这些前体借助于皮带输送***510被引导通过不同的工位。在工位530处,施加异氰酸酯和丙烯酸酯的液体混合物。该混合物(粘合层30)在工位531处被凝胶,即,该混合物所包含的(甲基)丙烯酸酯仅部分聚合。在附图中,工位550图示出数字印刷设备,期望的装饰可以通过该设备压印到纸21或者粘合层30上。然而,纸21本身也可以包含任意装饰,使得550处的印刷步骤并非绝对必要。由于由板材的直接印刷所提供的灵活性,因此优选借助于印刷工位550直接印刷。在工位550处施加的印刷颜料在551处预干燥。另一个(甲基)丙烯酸酯层继而在工位540处被施加到部分固化的层上,并且层30和40两者均在工位541处完全固化。在工位541之后,板材准备用于进一步加工。然而,进一步加工应当优选等待约10天,直到异氰酸酯完全转化。在图5中,另一个工位560跟随工位541。工位560用于将结构设置到最上面的(甲基)丙烯酸酯层40。如果期望这样的结构,工位541不会投入使用,即,在工位540处施加的丙烯酸酯层40不会在工位541处固化。与此相反,固化工位564设置在工位560中。结构箔片用附图标记561表示,该箔片在导辊562的上方被引导并与板材的前侧相接触。结构箔片561包括待施加的负突起的结构,并且将所述结构压入至尚湿的丙烯酸酯层40中。固化工位564例如通过UV辐射来工作,并且照射通过结构箔片561,为此,该结构箔片对于UV辐射是可渗透的。在工位560的端部,将结构箔片561从现已完全固化的板材的表面上去除,使得结构(像诸如三维木结构)设置在板材的表面。
Claims (31)
1.一种用于室内或室外的层状建筑板,其包括:
具有前侧和后侧的芯板(20),以及
布置在其上的氨基树脂浸渍纸(21),
其特征在于,包括聚氨酯和丙烯酸酯的粘合层(30’)布置在所述纸上。
2.根据权利要求1所述的层状建筑板,其特征在于,额外的丙烯酸酯层(40)布置在所述粘合层(30’)上,所述丙烯酸酯层的厚度优选大于20μm、更优选大于30μm并且最优选大于40μm。
3.根据权利要求1或2所述的层状建筑板,其特征在于,所述粘合层(30’)的厚度为10至100μm、更优选为10至80μm、甚至更优选为15至70μm并且最优选为20至60μm。
4.根据前述任一项权利要求所述的层状建筑板,其特征在于,所述粘合层(30’)主要由聚氨酯和丙烯酸酯组成。
5.根据前述任一项权利要求所述的层状建筑板,其特征在于,包括装饰颜料的装饰层布置在所述粘合层(30’)和所述丙烯酸酯层(40)之间。
6.根据权利要求5所述的层状建筑板,其特征在于,所述装饰颜料基于可聚合的装饰颜料。
7.根据前述任一项权利要求所述的层状建筑板,其特征在于,所述芯板(20)的厚度为2至80mm、优选为3至50mm并且最优选为4至50mm。
8.根据前述任一项权利要求所述的层状建筑板,其特征在于,所述芯板(20)为层压板;MDF板;HDF板;木基材料板或PVC板。
9.根据前述任一项权利要求所述的层状建筑板,其特征在于,所述粘合层(30’)主要由聚氨酯和丙烯酸酯组成,并且其中所述聚氨酯的重量百分比大于5%、更优选大于20%并且最优选大于40%。
10.一种特别用于制造根据权利要求1至9中任一项所述的建筑板的层状板,所述层状板包括:
具有前侧和后侧的芯板(20),以及
布置在其上的氨基树脂浸渍纸(21),其特征在于
异氰酸酯和(甲基)丙烯酸酯的混合物的粘合层(30)布置在所述纸(21)上;并且
丙烯酸酯层(40)布置在其上。
11.根据权利要求10所述的层状板,其特征在于,布置在所述粘合层(30)上的所述丙烯酸酯层(40)的厚度大于20μm、优选大于30μm并且最优选大于40μm。
12.根据权利要求10或11所述的层状板,其特征在于,所述粘合层(30)的厚度为10至100μm、更优选为10至80μm、甚至更优选为15至70μm并且最优选为20至60μm。
13.根据权利要求10至12中任一项所述的层状板,其特征在于,所述粘合层(30)主要由异氰酸酯和(甲基)丙烯酸酯组成。
14.根据权利要求10至13中任一项所述的层状板,其特征在于,包括装饰颜料的装饰层(50)设置在所述粘合层(30)与所述丙烯酸酯层(40)之间。
15.根据权利要求14所述的层状板,其特征在于,所述装饰层基于可聚合的装饰颜料。
16.根据权利要求11至15中任一项所述的层状板,其特征在于,所述粘合层(30)的(甲基)丙烯酸酯基于包括2至12个碳原子的烷醇的(甲基)丙烯酸酯。
17.根据权利要求10至16中任一项所述的层状板,其特征在于,所述粘合层(30)的所述(甲基)丙烯酸酯选自由下列各项组成的群组:丙烯酸乙酯、丙烯酸丙酯、丙烯酸正丁酯、丙烯酸正己酯、丙烯酸正辛酯、丙烯酸2-乙基己酯、丙烯酸3-丙基庚酯、丙烯酸正癸酯、丙烯酸月桂酯、甲基丙烯酸正戊酯、甲基丙烯酸正辛酯、甲基丙烯酸正癸酯和甲基丙烯酸月桂酯、(甲基)丙烯酸丁酯、丙烯酸2-乙基己酯或丙烯酸3-丙基庚酯。
18.根据权利要求10至17中任一项所述的层状板,其特征在于,所述异氰酸酯基于具有至少1.8、更优选1.8至5并且最优选2至4的NCO官能的二异氰酸酯和/或多异氰酸酯。
19.根据权利要求18所述的层状板,其特征在于,所述二异氰酸酯是具有4至20个碳原子的异氰酸酯。
20.根据权利要求18或19所述的层状板,其特征在于,所述多异氰酸酯是包括异氰酸酯基的多异氰酸酯、脲二酮二异氰酸酯、包括缩二脲基的多异氰酸酯、包括尿烷基或氨基甲酸酯基的多异氰酸酯、包括噁二嗪三酮基的多异氰酸酯、具有总共6至20个碳原子的脂族二异氰酸酯的脲酮亚胺改性的多异氰酸酯、和/或具有总共6至20个碳原子的脂环族二异氰酸酯。
21.根据权利要求11至18中任一项所述的层状板,其特征在于,所述芯层(20)为层压板;MDF板;HDF板;木基材料板或PVC板。
22.一种制造用于室内和室外的层状建筑板的方法,所述方法包括以下步骤:
a.提供具有前侧和后侧的芯板,以及
b.在所述前侧和/或所述后侧上提供氨基树脂浸渍纸;其特征在于
c.随后在所述纸上提供异氰酸酯和(甲基)丙烯酸酯的混合物;
d.在步骤c后施加丙烯酸酯层;以及
e.在步骤c和d中施加的所述层一起固化。
23.根据权利要求22所述的用于制造层状建筑板的方法,其特征在于,所述异氰酸酯和(甲基)丙烯酸酯的混合物在步骤c之后并在步骤d之前被部分固化。
24.根据权利要求23所述的用于制造层状建筑板的方法,其特征在于,在所述部分固化步骤之后并在步骤d之前,装饰层直接印刷在包括所述异氰酸酯和(甲基)丙烯酸酯的所述混合物的层上。
25.根据前述任一项权利要求所述的用于制造层状建筑板的方法,其特征在于,所述异氰酸酯和(甲基)丙烯酸酯的混合物由施加辊施加。
26.根据前述任一项权利要求所述的用于制造层状建筑板的方法,其特征在于,所述施加的丙烯酸酯层在步骤d之后并在步骤e之前设置有一结构。
27.根据前述任一项权利要求所述的用于制造层状建筑板的方法,其特征在于,在步骤d中所施加的所述丙烯酸酯层的厚度大于20μm、更优选大于30μm并且最优选大于40μm。
28.根据前述任一项权利要求所述的用于制造层状建筑板的方法,其特征在于,所述粘合层的厚度为10至100μm、更优选为10至80μm、甚至更优选15至70μm并且最优选为20至60μm。
29.根据权利要求24所述的用于制造层状建筑板的方法,其特征在于,用于所述装饰层的装饰颜料基于可聚合的装饰颜料。
30.根据前述任一项权利要求所述的用于制造层状建筑板的方法,其特征在于,所述芯板的厚度为2至50mm、优选为3至50mm、最优选为4至50mm。
31.根据前述任一项权利要求所述的用于制造层状建筑板的方法,其特征在于,所述芯板为层压板;MDF板;HDF板;木基材料板或PVC板。
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KR20120079061A (ko) * | 2009-09-30 | 2012-07-11 | 아이카고교 가부시키가이샤 | 활성 에너지선 경화형 수지 조성물, 전사 시트, 화장판 및 화장판의 제조방법 |
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- 2014-01-14 CN CN201480073119.XA patent/CN105899357A/zh active Pending
- 2014-01-14 CA CA2928890A patent/CA2928890C/en active Active
- 2014-01-14 WO PCT/EP2014/000073 patent/WO2015106771A1/de active Application Filing
- 2014-01-14 LT LTEP14700959.1T patent/LT3094493T/lt unknown
- 2014-01-14 UA UAA201607764A patent/UA117159C2/uk unknown
- 2014-01-14 PT PT147009591T patent/PT3094493T/pt unknown
- 2014-01-14 CN CN202111273373.2A patent/CN114030259A/zh active Pending
- 2014-01-14 US US15/109,491 patent/US20160326744A1/en not_active Abandoned
- 2014-01-14 PL PL14700959T patent/PL3094493T3/pl unknown
- 2014-01-14 EP EP14700959.1A patent/EP3094493B1/de active Active
- 2014-01-14 RU RU2016129203A patent/RU2655364C2/ru active
- 2014-01-14 ES ES14700959.1T patent/ES2656120T3/es active Active
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Also Published As
Publication number | Publication date |
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CA2928890A1 (en) | 2015-07-23 |
EP3094493A1 (de) | 2016-11-23 |
WO2015106771A1 (de) | 2015-07-23 |
PT3094493T (pt) | 2018-01-10 |
UA117159C2 (uk) | 2018-06-25 |
CN114030259A (zh) | 2022-02-11 |
PL3094493T3 (pl) | 2018-03-30 |
ES2656120T3 (es) | 2018-02-23 |
US20160326744A1 (en) | 2016-11-10 |
RU2016129203A (ru) | 2018-02-20 |
CA2928890C (en) | 2021-05-25 |
RU2655364C2 (ru) | 2018-05-25 |
LT3094493T (lt) | 2017-11-10 |
EP3094493B1 (de) | 2017-10-11 |
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