CN105887489A - Anti-pilling agent for knitting, and preparation method and application thereof - Google Patents

Anti-pilling agent for knitting, and preparation method and application thereof Download PDF

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Publication number
CN105887489A
CN105887489A CN201610286059.0A CN201610286059A CN105887489A CN 105887489 A CN105887489 A CN 105887489A CN 201610286059 A CN201610286059 A CN 201610286059A CN 105887489 A CN105887489 A CN 105887489A
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CN
China
Prior art keywords
parts
fluffing
globule
knitting
polyethylene glycol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610286059.0A
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Chinese (zh)
Inventor
纪新荣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Suyang Service Cap Co Ltd
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Jiangsu Suyang Service Cap Co Ltd
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Filing date
Publication date
Application filed by Jiangsu Suyang Service Cap Co Ltd filed Critical Jiangsu Suyang Service Cap Co Ltd
Priority to CN201610286059.0A priority Critical patent/CN105887489A/en
Publication of CN105887489A publication Critical patent/CN105887489A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/64Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
    • D06M11/65Salts of oxyacids of nitrogen
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144Alcohols; Metal alcoholates
    • D06M13/148Polyalcohols, e.g. glycerol or glucose
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188Monocarboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/17Natural resins, resinous alcohols, resinous acids, or derivatives thereof

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses an anti-pilling agent for knitting, and a preparation method and application thereof. The anti-pilling agent for the knitting is prepared from the following raw components in parts by mass: 15 to 20 parts of dehydrated sorbitan fatty acid ester polyoxyethylene ether, 8 to 10 parts of stearic acid, 35 to 40 parts of rosin ethyl ester, 10 to 15 parts of hydrogenated rosin methaester, 15 to 20 parts of methyl laurate, 10 to 20 parts of polyethylene glycol, 3 to 5 parts of dicarbonate, 3 to 5 parts of zinc nitrate, 2 to 3 parts of potassium bicarbonate, 10 to 12 parts of glycerinum, and 180 to 190 parts of water. The raw components of the anti-pilling agent for the knitting disclosed by the invention have a very good synergistic effect; the obtained treatment agent has very high stability; a knitted fabric which is treated by the anti-pilling agent is durable and wear-resistant and does not pill.

Description

A kind of for knitting anti-fluffing globule, its preparation method and application thereof
Technical field
The present invention relates to a kind of for knitting anti-fluffing globule, its preparation method and application thereof, belong to knitting field.
Background technology
Knitted fabric is various in style, the most all kinds of looped fabrics, sweater, woollen sweater etc., and these knitted fabrics are in actual dress With in washing process, due to constantly by either large or small friction so that the fiber of knitted surfaces exposes the surface of fabric, At fabric face, young pilose antler occurs, and these young pilose antlers can form many spherical granules by tied up in knots mutually in the course of time, be commonly called as Ball, these highlight the ball top in fabric exterior, the attractive in appearance of knitted fabric and wearability are had serious impact, along with life The raising that running water is flat, people are more and more higher to the requirement of appearance of fabrics and wearability, therefore, fabric carried out anti-fluffing Balling-up arranges, and improves wearing comfort and the quality of fabric, is increasingly subject to the attention of domestic and international dyeing and finishing worker.
Summary of the invention
In order to solve the defect such as easy balling-up of knitted fabric in prior art, the present invention provide a kind of for knitting anti-fluffing globule, Its preparation method and application thereof.
For solving above-mentioned technical problem, the technical solution adopted in the present invention is as follows:
A kind of for knitting anti-fluffing globule, its raw material components includes: sorbitan fatty acid ester polyoxyethylene ether 15-20 Part, stearic acid 8-10 part, Rosin Ethyl 35-40 part, hercolyn D 10-15 part, methyl laurate 15-20 part, poly- Ethylene glycol 10-20 part, sodium bicarbonate 3-5 part, zinc nitrate 3-5 part, potassium bicarbonate 2-3 part, glycerol 10-12 part and water 180-190 Part, described number is mass fraction.
In order to improve anti-pilling effect further, it is preferable that Polyethylene Glycol is polyethylene glycol 1500 0.
As a kind of preferred version of the application, the raw material components for knitting anti-fluffing globule includes: Sorbitan alcohol ester Fat acid ester polyoxyethylene ether 18 parts, stearic acid 9 parts, Rosin Ethyl 38 parts, hercolyn D 12 parts, methyl laurate 18 Part, Polyethylene Glycol 15 parts, sodium bicarbonate 4 parts, zinc nitrate 4 parts, potassium bicarbonate 3 parts, glycerol 11 parts and 185 parts of water, described Number is mass fraction.
In order to improve anti-pilling effect further, it is preferable that the raw material components for knitting anti-fluffing globule also includes benzoic acid Ethyl ester 6-9 part, described number is mass fraction.
In order to improve the stability of products obtained therefrom further, it is preferable that the raw material components for knitting anti-fluffing globule also includes Lauric acid 5-8 part, described number is mass fraction.
The above-mentioned preparation method for knitting anti-fluffing globule, the following steps including connected in order:
A, Rosin Ethyl and hercolyn D heated and stirred are melted;
B, sorbitan fatty acid ester polyoxyethylene ether and stearic acid are mixed with water, be then heated to 90 DEG C;
C, by step B gained material in instill the step A gained material being in stirring with the speed of 40/min, turn After success, remaining step B gained material is poured in step A gained material together mutually;
D, Polyethylene Glycol, sodium bicarbonate, zinc nitrate and potassium bicarbonate are mixed, add in step C gained material;
E, methyl laurate and glycerol mixing, add in step D gained material, and be 60-65 DEG C, mixing speed in temperature Under conditions of 1300r/min, continue stirring 10-15 minute, to obtain final product.
Further preferably, the mixing speed in step C is 2000-2100r/min.
If raw material components also includes ethyl benzoate and lauric acid, then ethyl benzoate in step with Rosin Ethyl and hydrogenation Abalyn heated and stirred together melts;Lauric acid in stepb with sorbitan fatty acid ester polyoxyethylene ether and tristearin Acid mixes with water together.
The above-mentioned application for knitting anti-fluffing globule, the consumption for knitting anti-fluffing globule is every gram of knitted fabric 0.02-0.03 gram.
The NM technology of the present invention is all with reference to prior art.
The present invention has good cooperative effect, gained inorganic agent between each raw material components of knitting anti-fluffing globule There is good stability, with prolonged endurable, the not balling-up of its knitted fabric processed.
Detailed description of the invention
In order to be more fully understood that the present invention, it is further elucidated with present disclosure below in conjunction with embodiment, but present disclosure It is not limited solely to the following examples.
Embodiment 1
Raw material components for knitting anti-fluffing globule includes: sorbitan fatty acid ester polyoxyethylene ether (Tween 80 Hundred million auxiliary reagent factories of Xingtai City stile) 18 parts, stearic acid 9 parts, Rosin Ethyl 38 parts, hercolyn D 12 parts, lauric acid first Ester 18 parts, Polyethylene Glycol 15 parts, sodium bicarbonate 4 parts, zinc nitrate 4 parts, potassium bicarbonate 3 parts, glycerol 11 parts, benzoic acid second Ester 7 parts, lauric acid 6 parts and 185 parts of water, described number is mass fraction.
The above-mentioned preparation method for knitting anti-fluffing globule, the following steps including connected in order:
A, Rosin Ethyl, ethyl benzoate and hercolyn D heated and stirred are melted;
B, sorbitan fatty acid ester polyoxyethylene ether, lauric acid and stearic acid and water are mixed, be then heated to 90 DEG C;
C, step B gained material is being instilled step A being in stirring (2100r/min) with the speed of 40/min In gained material, after phase inversion success, remaining step B gained material is poured in step A gained material together;
D, Polyethylene Glycol, sodium bicarbonate, zinc nitrate and potassium bicarbonate are mixed, add in step C gained material;
E, methyl laurate and glycerol mixing, add in step D gained material, and temperature be 60 DEG C, mixing speed be Under conditions of 1300r/min, continue stirring 15 minutes, to obtain final product.
Embodiment 2
Substantially the same manner as Example 1, except that: the raw material components for knitting anti-fluffing globule includes: dehydration mountain Pears alcohol fatty acid ester polyoxyethylene ether (hundred million auxiliary reagent factories of Tween 80 Xingtai City stile) 15 parts, stearic acid 8 parts, Rosin Ethyl 35 parts, hercolyn D 10 parts, methyl laurate 15 parts, polyethylene glycol 1500 0 10 parts, sodium bicarbonate 3 parts, Zinc nitrate 3 parts, potassium bicarbonate 2 parts, glycerol 10 parts, ethyl benzoate 6 parts, lauric acid 5 parts and 180 parts of water, institute Stating number is mass fraction.
Embodiment 3
Substantially the same manner as Example 1, except that: the raw material components for knitting anti-fluffing globule includes: dehydration mountain Pears alcohol fatty acid ester polyoxyethylene ether (hundred million auxiliary reagent factories of Tween 80 Xingtai City stile) 20 parts, stearic acid 10 parts, Colophonium second Ester 40 parts, hercolyn D 15 parts, methyl laurate 20 parts, polyethylene glycol 1500 0 20 parts, sodium bicarbonate 5 Part, zinc nitrate 5 parts, potassium bicarbonate 3 parts, glycerol 12 parts, ethyl benzoate 9 parts, lauric acid 8 parts and 190 parts of water, Described number is mass fraction.
Being impregnated with the knitting anti-fluffing globule that is used for of the various embodiments described above gained respectively by plain, consumption is every gram of knitted fabric 0.02 gram of inorganic agent, then dries, and gained knitted fabric No. 60 sand paper bi-directional frictions 20 times, without any pilling effect;By institute Obtaining knitted fabric and be made as medicated clothing, washing machine washing is once every other day, without any pilling effect after persistently wearing 2 months.

Claims (9)

1. one kind is used for knitting anti-fluffing globule, it is characterised in that: its raw material components includes: sorbitan fatty acid Ester polyoxyethylene ether 15-20 part, stearic acid 8-10 part, Rosin Ethyl 35-40 part, hercolyn D 10-15 part, Laurel Acid methyl ester 15-20 part, Polyethylene Glycol 10-20 part, sodium bicarbonate 3-5 part, zinc nitrate 3-5 part, potassium bicarbonate 2-3 part, sweet Oil 10-12 part and water 180-190 part, described number is mass fraction.
2. as claimed in claim 1 for knitting anti-fluffing globule, it is characterised in that: Polyethylene Glycol is Polyethylene Glycol 15000。
3. as claimed in claim 1 or 2 for knitting anti-fluffing globule, it is characterised in that: its raw material components includes: Sorbitan fatty acid ester polyoxyethylene ether 18 parts, stearic acid 9 parts, Rosin Ethyl 38 parts, hercolyn D 12 parts, Methyl laurate 18 parts, Polyethylene Glycol 15 parts, sodium bicarbonate 4 parts, zinc nitrate 4 parts, potassium bicarbonate 3 parts, glycerol 11 parts and 185 parts of water, described number is mass fraction.
4. as claimed in claim 1 or 2 for knitting anti-fluffing globule, it is characterised in that: its raw material components also includes Ethyl benzoate 6-9 part, described number is mass fraction.
5. as claimed in claim 1 or 2 for knitting anti-fluffing globule, it is characterised in that: its raw material components also includes Lauric acid 5-8 part, described number is mass fraction.
6. the preparation method for knitting anti-fluffing globule described in claim 1-5 any one, it is characterised in that: bag Include following steps connected in order:
A, Rosin Ethyl and hercolyn D heated and stirred are melted;
B, sorbitan fatty acid ester polyoxyethylene ether and stearic acid are mixed with water, be then heated to 90 DEG C;
C, by step B gained material in instill the step A gained material being in stirring with the speed of 40/min, turn After success, remaining step B gained material is poured in step A gained material together mutually;
D, Polyethylene Glycol, sodium bicarbonate, zinc nitrate and potassium bicarbonate are mixed, add in step C gained material;
E, methyl laurate and glycerol mixing, add in step D gained material, and be 60-65 DEG C, mixing speed in temperature Under conditions of 1300r/min, continue stirring 10-15 minute, to obtain final product.
7. preparation method as claimed in claim 6, it is characterised in that: the mixing speed in step C is 2000-2100r/min.
Preparation method the most as claimed in claims 6 or 7, it is characterised in that: if raw material components also include ethyl benzoate and Lauric acid, then ethyl benzoate in step together with Rosin Ethyl and hercolyn D heated and stirred melt;Lauric acid Mix with water together with sorbitan fatty acid ester polyoxyethylene ether and stearic acid in stepb.
9. the application for knitting anti-fluffing globule described in claim 1-5 any one, it is characterised in that: for pin The consumption of the anti-fluffing globule knitted is every gram of knitted fabric 0.02-0.03 gram.
CN201610286059.0A 2016-04-29 2016-04-29 Anti-pilling agent for knitting, and preparation method and application thereof Pending CN105887489A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106381712A (en) * 2016-08-30 2017-02-08 威莱(广州)日用品有限公司 Textile processing agent for removing pilling and preparation method thereof
CN107904955A (en) * 2017-11-14 2018-04-13 广州先盈生物科技有限公司 A kind of compound crease-resistant anti-fluffing treating agent and preparation method thereof
CN116084162A (en) * 2023-01-04 2023-05-09 江苏新瑞贝科技股份有限公司 Bio-based anti-pilling finishing agent and preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103422351A (en) * 2013-08-02 2013-12-04 吴江市七都镇庙港雅迪针织制衣厂 Woolen sweater treating liquid containing abietic acid polyoxyethylene ester
CN104256963A (en) * 2014-09-09 2015-01-07 江苏阳光股份有限公司 Multifunctional wool spinning fabric
CN104264460A (en) * 2014-08-27 2015-01-07 无锡市奇盛针织手套厂 Anti-pilling antistatic wool fabric conditioning agent and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103422351A (en) * 2013-08-02 2013-12-04 吴江市七都镇庙港雅迪针织制衣厂 Woolen sweater treating liquid containing abietic acid polyoxyethylene ester
CN104264460A (en) * 2014-08-27 2015-01-07 无锡市奇盛针织手套厂 Anti-pilling antistatic wool fabric conditioning agent and preparation method thereof
CN104256963A (en) * 2014-09-09 2015-01-07 江苏阳光股份有限公司 Multifunctional wool spinning fabric

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106381712A (en) * 2016-08-30 2017-02-08 威莱(广州)日用品有限公司 Textile processing agent for removing pilling and preparation method thereof
CN106381712B (en) * 2016-08-30 2017-06-06 威莱(广州)日用品有限公司 One kind removes ball top fabric-treating agent and preparation method thereof
CN107904955A (en) * 2017-11-14 2018-04-13 广州先盈生物科技有限公司 A kind of compound crease-resistant anti-fluffing treating agent and preparation method thereof
CN107904955B (en) * 2017-11-14 2019-01-25 广州先盈生物科技有限公司 Compound crease-resistant anti-fluffing treating agent of one kind and preparation method thereof
CN116084162A (en) * 2023-01-04 2023-05-09 江苏新瑞贝科技股份有限公司 Bio-based anti-pilling finishing agent and preparation method and application thereof

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Application publication date: 20160824