CN105874357A - Anti-glare hard coat film - Google Patents
Anti-glare hard coat film Download PDFInfo
- Publication number
- CN105874357A CN105874357A CN201480071029.7A CN201480071029A CN105874357A CN 105874357 A CN105874357 A CN 105874357A CN 201480071029 A CN201480071029 A CN 201480071029A CN 105874357 A CN105874357 A CN 105874357A
- Authority
- CN
- China
- Prior art keywords
- composition
- value
- film coating
- dazzle
- hardness film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 claims abstract description 161
- 239000002245 particle Substances 0.000 claims abstract description 134
- 229920005989 resin Polymers 0.000 claims abstract description 109
- 239000011347 resin Substances 0.000 claims abstract description 109
- 239000002270 dispersing agent Substances 0.000 claims abstract description 32
- 229920003023 plastic Polymers 0.000 claims abstract description 20
- 239000004033 plastic Substances 0.000 claims abstract description 18
- 150000001875 compounds Chemical class 0.000 claims abstract description 6
- 239000007888 film coating Substances 0.000 claims description 83
- 238000009501 film coating Methods 0.000 claims description 83
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 66
- 230000015572 biosynthetic process Effects 0.000 claims description 38
- 235000012239 silicon dioxide Nutrition 0.000 claims description 31
- 239000000377 silicon dioxide Substances 0.000 claims description 29
- 239000004531 microgranule Substances 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 26
- -1 sulfonic group Chemical group 0.000 claims description 26
- 239000011859 microparticle Substances 0.000 claims description 22
- 239000002585 base Substances 0.000 claims description 21
- 239000012748 slip agent Substances 0.000 claims description 17
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 7
- 239000003513 alkali Substances 0.000 claims description 7
- 229920006026 co-polymeric resin Polymers 0.000 claims description 7
- 239000002952 polymeric resin Substances 0.000 claims description 7
- 125000003368 amide group Chemical group 0.000 claims description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 4
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 4
- 229920002545 silicone oil Polymers 0.000 claims description 4
- 229920003002 synthetic resin Polymers 0.000 claims description 4
- 125000001302 tertiary amino group Chemical group 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 claims 1
- 229920002050 silicone resin Polymers 0.000 claims 1
- 230000004313 glare Effects 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract 2
- 239000003999 initiator Substances 0.000 abstract 1
- 239000010408 film Substances 0.000 description 22
- 230000033228 biological regulation Effects 0.000 description 16
- 238000000576 coating method Methods 0.000 description 16
- 238000000034 method Methods 0.000 description 15
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 14
- 239000011248 coating agent Substances 0.000 description 14
- CERQOIWHTDAKMF-UHFFFAOYSA-N alpha-methacrylic acid Natural products CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 13
- 238000009826 distribution Methods 0.000 description 11
- 208000002173 dizziness Diseases 0.000 description 11
- 238000011156 evaluation Methods 0.000 description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 10
- 239000010410 layer Substances 0.000 description 9
- 238000002834 transmittance Methods 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- 230000008859 change Effects 0.000 description 7
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical class OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 7
- 230000004048 modification Effects 0.000 description 7
- 238000012986 modification Methods 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 229920002284 Cellulose triacetate Polymers 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 238000004062 sedimentation Methods 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 4
- 239000011247 coating layer Substances 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 4
- 150000003141 primary amines Chemical class 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical group CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000005543 nano-size silicon particle Substances 0.000 description 3
- 230000010287 polarization Effects 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 150000003335 secondary amines Chemical class 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- 230000001629 suppression Effects 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 2
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical class CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 2
- SZNYYWIUQFZLLT-UHFFFAOYSA-N 2-methyl-1-(2-methylpropoxy)propane Chemical compound CC(C)COCC(C)C SZNYYWIUQFZLLT-UHFFFAOYSA-N 0.000 description 2
- NJWGQARXZDRHCD-UHFFFAOYSA-N 2-methylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(C)=CC=C3C(=O)C2=C1 NJWGQARXZDRHCD-UHFFFAOYSA-N 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 241000521257 Hydrops Species 0.000 description 2
- 239000005041 Mylar™ Substances 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 206010030113 Oedema Diseases 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 2
- 229960005222 phenazone Drugs 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 235000019260 propionic acid Nutrition 0.000 description 2
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 2
- RLUFBDIRFJGKLY-UHFFFAOYSA-N (2,3-dichlorophenyl)-phenylmethanone Chemical compound ClC1=CC=CC(C(=O)C=2C=CC=CC=2)=C1Cl RLUFBDIRFJGKLY-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical class CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- MSAHTMIQULFMRG-UHFFFAOYSA-N 1,2-diphenyl-2-propan-2-yloxyethanone Chemical compound C=1C=CC=CC=1C(OC(C)C)C(=O)C1=CC=CC=C1 MSAHTMIQULFMRG-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- GIMQKKFOOYOQGB-UHFFFAOYSA-N 2,2-diethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)(OCC)C(=O)C1=CC=CC=C1 GIMQKKFOOYOQGB-UHFFFAOYSA-N 0.000 description 1
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 1
- CZZVAVMGKRNEAT-UHFFFAOYSA-N 2,2-dimethylpropane-1,3-diol;3-hydroxy-2,2-dimethylpropanoic acid Chemical compound OCC(C)(C)CO.OCC(C)(C)C(O)=O CZZVAVMGKRNEAT-UHFFFAOYSA-N 0.000 description 1
- LCHAFMWSFCONOO-UHFFFAOYSA-N 2,4-dimethylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(C)=CC(C)=C3SC2=C1 LCHAFMWSFCONOO-UHFFFAOYSA-N 0.000 description 1
- XOGPDSATLSAZEK-UHFFFAOYSA-N 2-Aminoanthraquinone Chemical class C1=CC=C2C(=O)C3=CC(N)=CC=C3C(=O)C2=C1 XOGPDSATLSAZEK-UHFFFAOYSA-N 0.000 description 1
- GTACSIONMHMRPD-UHFFFAOYSA-N 2-[4-[2-(benzenesulfonamido)ethylsulfanyl]-2,6-difluorophenoxy]acetamide Chemical compound C1=C(F)C(OCC(=O)N)=C(F)C=C1SCCNS(=O)(=O)C1=CC=CC=C1 GTACSIONMHMRPD-UHFFFAOYSA-N 0.000 description 1
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 description 1
- SJEBAWHUJDUKQK-UHFFFAOYSA-N 2-ethylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC=C3C(=O)C2=C1 SJEBAWHUJDUKQK-UHFFFAOYSA-N 0.000 description 1
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 description 1
- MYISVPVWAQRUTL-UHFFFAOYSA-N 2-methylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(C)=CC=C3SC2=C1 MYISVPVWAQRUTL-UHFFFAOYSA-N 0.000 description 1
- GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 description 1
- 101710130081 Aspergillopepsin-1 Proteins 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- XDSYCAFBAHBYSN-UHFFFAOYSA-N C(C=C)(=O)O.C(C(=C)C)(=O)OCCN=C=O Chemical compound C(C=C)(=O)O.C(C(=C)C)(=O)OCCN=C=O XDSYCAFBAHBYSN-UHFFFAOYSA-N 0.000 description 1
- URSREKBNYBPWFA-UHFFFAOYSA-N C(C=C)(=O)OC.P(=O)(OCC(CCCC)CC)(OCC(CCCC)CC)O Chemical class C(C=C)(=O)OC.P(=O)(OCC(CCCC)CC)(OCC(CCCC)CC)O URSREKBNYBPWFA-UHFFFAOYSA-N 0.000 description 1
- QYGNWDWNZBZHMD-UHFFFAOYSA-N CN(C)C(=NO)C(C1=CC=CC=C1)=O Chemical compound CN(C)C(=NO)C(C1=CC=CC=C1)=O QYGNWDWNZBZHMD-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 102100031007 Cytosolic non-specific dipeptidase Human genes 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920005372 Plexiglas® Polymers 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000004697 Polyetherimide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 1
- SSOONFBDIYMPEU-UHFFFAOYSA-N [3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propyl] prop-2-enoate Chemical compound OCC(CO)(CO)COCC(CO)(CO)COC(=O)C=C SSOONFBDIYMPEU-UHFFFAOYSA-N 0.000 description 1
- RMKZLFMHXZAGTM-UHFFFAOYSA-N [dimethoxy(propyl)silyl]oxymethyl prop-2-enoate Chemical compound CCC[Si](OC)(OC)OCOC(=O)C=C RMKZLFMHXZAGTM-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229940081735 acetylcellulose Drugs 0.000 description 1
- HFBMWMNUJJDEQZ-UHFFFAOYSA-N acryloyl chloride Chemical compound ClC(=O)C=C HFBMWMNUJJDEQZ-UHFFFAOYSA-N 0.000 description 1
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 238000005937 allylation reaction Methods 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- QDVNNDYBCWZVTI-UHFFFAOYSA-N bis[4-(ethylamino)phenyl]methanone Chemical compound C1=CC(NCC)=CC=C1C(=O)C1=CC=C(NCC)C=C1 QDVNNDYBCWZVTI-UHFFFAOYSA-N 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- VYVRIXWNTVOIRD-LRHBOZQDSA-N ciguatoxin CTX1B Chemical compound C([C@@]12[C@@H](C)[C@@H]([C@@H]3[C@H]([C@H]([C@H](C)[C@H]4O[C@H]5C[C@@H](C)C[C@H]6O[C@@]7(C)[C@H](O)C[C@H]8O[C@H]9C=C[C@H]%10O[C@H]%11C[C@@H]%12[C@H]([C@@H]([C@H]%13O[C@H](C=CC[C@@H]%13O%12)\C=C\[C@H](O)CO)O)O[C@@H]%11C=C[C@@H]%10O[C@@H]9C\C=C/C[C@@H]8O[C@@H]7C[C@@H]6O[C@@H]5C[C@@H]4O3)O)O2)C)[C@H](O)CO1 VYVRIXWNTVOIRD-LRHBOZQDSA-N 0.000 description 1
- 229940075614 colloidal silicon dioxide Drugs 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 210000002858 crystal cell Anatomy 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical group O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000002433 cyclopentenyl group Chemical group C1(=CCCC1)* 0.000 description 1
- MAWOHFOSAIXURX-UHFFFAOYSA-N cyclopentylcyclopentane Chemical group C1CCCC1C1CCCC1 MAWOHFOSAIXURX-UHFFFAOYSA-N 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 229920005994 diacetyl cellulose Polymers 0.000 description 1
- 238000007607 die coating method Methods 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- VLNBQUAHERCLKT-UHFFFAOYSA-N dimethylamino benzoate Chemical compound CN(C)OC(=O)C1=CC=CC=C1 VLNBQUAHERCLKT-UHFFFAOYSA-N 0.000 description 1
- 230000009429 distress Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Natural products OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- DUWWHGPELOTTOE-UHFFFAOYSA-N n-(5-chloro-2,4-dimethoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC(OC)=C(NC(=O)CC(C)=O)C=C1Cl DUWWHGPELOTTOE-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 150000002924 oxiranes Chemical group 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- ZBVQEUUTPTVMHY-UHFFFAOYSA-N phenyl-(2-phenylphenyl)methanone Chemical compound C=1C=CC=C(C=2C=CC=CC=2)C=1C(=O)C1=CC=CC=C1 ZBVQEUUTPTVMHY-UHFFFAOYSA-N 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- HXHCOXPZCUFAJI-UHFFFAOYSA-N prop-2-enoic acid;styrene Chemical compound OC(=O)C=C.C=CC1=CC=CC=C1 HXHCOXPZCUFAJI-UHFFFAOYSA-N 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 231100000241 scar Toxicity 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 150000004819 silanols Chemical class 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000012800 visualization Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/106—Esters of polycondensation macromers
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/11—Anti-reflection coatings
- G02B1/111—Anti-reflection coatings using layers comprising organic materials
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/02—Diffusing elements; Afocal elements
- G02B5/0205—Diffusing elements; Afocal elements characterised by the diffusing properties
- G02B5/0236—Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place within the volume of the element
- G02B5/0242—Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place within the volume of the element by means of dispersed particles
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Optics & Photonics (AREA)
- General Physics & Mathematics (AREA)
- Dispersion Chemistry (AREA)
- Laminated Bodies (AREA)
- Optical Elements Other Than Lenses (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Provided is an anti-glare hard coat film which has excellent anti-glare properties and is capable of effectively suppressing the occurrence of glare even in cases where the anti-glare hard coat film is applied to a high-definition display. An anti-glare hard coat film which comprises an anti-glare hard coat layer on the surface of a plastic base. The anti-glare hard coat layer is formed of a cured product of a composition for forming an anti-glare hard coat layer, said composition containing an active energy ray-curable resin (component (A)), fine resin particles (component (B)), a dispersant (component (C)) and a photopolymerization initiator (component (D)). The volume average particle diameter of the fine resin particles (component (B)) is set to be within the range of 1-2.5 [mu]m. The blending amount of the fine resin particles (component (B)) is set to be within a specific range. The dispersant (component (C)) is a compound having a specific polar group. The blending amount of the dispersant (component (C)) is set to be within a specific range.
Description
Technical field
The present invention relates to a kind of anti-dazzle hardness film coating.
Even if particularly relating to a kind of anti-glare with excellence and also can in the case of being applicable to High Resolution Display
Enough effectively suppression produce the anti-dazzle hardness film coating of dazzle.
Background technology
In the past, Braun tube (CRT) or the display of liquid crystal display (LCD), plasma display (PDP) etc., screen
Can reflect from outside incident illumination (hereinafter sometimes referred to " outer light "), and find to have the problem being difficult to identification display image.
The most in recent years, along with the maximization of display, the problem that these problems increasingly become important is solved.
Accordingly, as means of this external light reflection problem of solution, implement to use the structure with antiglare hardcoat
The technology of part.
The forming method of this antiglare hardcoat can substantially divide into three kinds: (1) formed hard conating time, by physics side
Method, the method making the rough surface of hard conating；(2) method being mixed into filler in the hard varnish that hard conating is formed；(3) exist
The hard varnish that hard conating is formed is mixed into immiscible two kind composition, utilizes its method being separated.
Any one in these methods all by forming micro concavo-convex on the surface of hard conating, and the minute surface suppressing outer light is anti-
Penetrate, prevent the reflection of the outer light of fluorescent lamp etc., and especially with (2) be mixed in hard conating the method for filler as main flow (reference example
Such as patent documentation 1～2).
That is, patent document 1 discloses that a kind of anti-dazzle hardness film coating, it is characterized by have on the surface of transparent plastic film
Hard conating, described hard conating is contained (a) multi-functional (methyl) acrylic ester monomer and/or (methyl) propylene by containing (A)
Esters of gallic acid prepolymer and the active energy beam induction type compositions of (b) reactive silicon dioxide microgranule, (B) spherical organic are micro-
Grain and (C) intramolecular have the hard conating formation material of the dispersant of at least one polar group and are formed, and the thickness of this hard conating
Degree is more than the mean diameter of (B) spherical organic microgranule.
It addition, document being thought, the mean diameter of (B) spherical organic microgranule is preferably the value in the range of 6～10 μm.
It addition, patent document 2 discloses that a kind of anti-dazzle hardness film coating, it is characterized by, have on the surface of transparent plastic film
Having hard conating, described hard conating is hard by use containing (A) active energy beam induction type compositions and (B) spherical organic microgranule
Coating forms material and is formed, and total haze value of this hard conating is set to less than 20%, " total haze value-internal haze value "
Value is set to the scope of-10～+1%.
It addition, document being thought, the mean diameter of (B) spherical organic microgranule is preferably the value in the range of 1～10 μm.
Prior art literature
Patent documentation
Patent documentation 1: No. 5149052 publications of Japanese Patent No. (claim of patent)
Patent documentation 2: Japanese Unexamined Patent Publication 2011-175081 publication (claim of patent)
Summary of the invention
The technical problem to be solved in the present invention
Although however it has been found that the anti-glare of the available defined of anti-dazzle hardness film coating disclosed in patent documentation 1, but
The mean diameter of spherical organic microgranule causes greatly and is susceptible to the problem that screen has dazzle sense (hereinafter sometimes referred to " dazzle ").
It is found that especially in the case of being applicable to high-resolution High Resolution Display, it is difficult to sending out of suppression dazzle
Raw, that when there is recognition screen, comfortableness reduces problem.
It has further been found that the anti-dazzle hardness film coating disclosed in patent documentation 2 does not the most take into full account spherical organic microgranule
The numerical range of mean diameter, and in hard conating forms material also and be not added with dispersant, therefore exist and be difficult to fully
The problem controlling the Deposition Situation of spherical organic microgranule.
It was found that be not only difficult to stably obtain the anti-glare of regulation, it is being obtained in that regulation anti-glare the most at last
In the case of, spherical organic microgranule also easily excessively comes off from hard coating surface, and cannot obtain sufficient marresistance, the most anti-
Dizzy property is also easily reduced.
Therefore, the present inventor waits situation in view of the above to concentrate on studies, it was found that by for forming anti-glare
The antiglare hardcoat formation compositions of hard conating adds with regulation ratio to have the resin of prescribed volume mean diameter micro-
Grain, adds the dispersant of regulation simultaneously with regulation ratio, can maintain excellent anti-glare, and can effectively suppress sending out of dazzle
Raw, and then complete the present invention.
That is, it is an object of the invention to provide a kind of anti-dazzle hardness film coating, it has the anti-glare of excellence, even and if
It also is able to effectively suppress the generation of dazzle in the case of being applicable to High Resolution Display.
Solve the technological means of technical problem
According to the present invention, it is possible to provide a kind of anti-dazzle hardness film coating, it is to possess Antidazzle hard coating on the surface of plastic basis material
The anti-dazzle hardness film coating of layer, is characterized by, antiglare hardcoat is by containing the active energy ray curable as (A) composition
Resin, the resin particle as (B) composition, the dispersant as (C) composition are anti-with the Photoepolymerizationinitiater initiater as (D) composition
The solidfied material of dizzy property hard conating formation compositions is constituted, and makes the volume average particle of resin particle as (B) composition
Footpath is the value in the range of 1～2.5 μm, and the addition making the resin particle as (B) composition is relative to as (A) composition
Active energy ray curable resin 100 weight portion is the value in the range of 0.1～20 weight portions, and dividing as (C) composition
Powder is the compound that intramolecular has at least one polar group, and polar group is for selecting free carboxyl group, hydroxyl, sulfonic group, primary amine
In the group that base, secondary amine, tertiary amine groups, amide groups, quaternary ammonium salt base, pyridine alkali, sulfonium salt base and alkali are constituted at least
One, the addition making the dispersant as (C) composition is relative to the active energy ray curable resin as (A) composition
100 weight portions are the value in the range of 0～2 weight portions (but except 0 weight portion), thus can solve the problems referred to above.
That is, if the anti-dazzle hardness film coating of the present invention, then it is being used for being formed the antiglare hardcoat of antiglare hardcoat
Formation compositions is added with the resin particle with smaller size smaller mean diameter with regulation ratio, even if being therefore applicable to
In the case of High Resolution Display, it is also possible to effectively suppress the generation of dazzle.
Further, since add regulation dispersant with regulation ratio, coat plastic basis material table therefore, it is possible to efficiently control
The sedimentation situation of the resin particle in the film of the antiglare hardcoat formation compositions in face, can not only be stably formed anti-
The micro concavo-convex of dizzy property hard coating surface, is limited to the volume average particle size of resin particle less scope, but also can obtain
To excellent anti-glare.
Therefore, as long as the anti-dazzle hardness film coating of the present invention, then there is the anti-glare of excellence, even and if being applicable to height
In the case of definition display, it is also possible to effectively suppress the generation of dazzle.
It addition, constitute the present invention anti-dazzle hardness film coating time, as the resin particle of (B) composition, be preferably selected from by
Acrylate copolymer resin particle, acrylic-styrene copolymer resin particle, styrenic polymer resins microgranule and poly-silica
At least one in the group that alkane resin particle is constituted.
By constituting by this way, it is possible to more stably form micro concavo-convex on the surface of antiglare hardcoat.
It addition, when constituting the anti-dazzle hardness film coating of the present invention, antiglare hardcoat formation compositions preferably contains
As the silicon dioxide microparticle of (E) composition, and preferably make the volume average particle size of the silicon dioxide microparticle as (E) composition
It is the value in the range of 2～500nm, and makes the addition of silicon dioxide microparticle as (E) composition for relative to as (A)
Active energy ray curable resin 100 weight portion of composition is the value in the range of 10～200 weight portions.
By constituting by this way, when antiglare hardcoat formation compositions is coated plastic basis material surface,
Can more effectively control in film the sedimentation situation of resin particle as (B) composition, on the surface of antiglare hardcoat more
It is stably formed micro concavo-convex.
It addition, when constituting the anti-dazzle hardness film coating of the present invention, antiglare hardcoat formation compositions preferably contains
As the slip agent of (F) composition, and preferably make the addition of the slip agent as (F) composition for becoming relative to as (A)
Active energy ray curable resin 100 weight portion divided is the value in the range of 0.05～20 weight portions.
By constituting by this way, the marresistance of anti-dazzle hardness film coating can be improved.
It addition, when constituting the anti-dazzle hardness film coating of the present invention, the slip agent as (F) composition is preferably silicone oil and modification
Silicone oil or either of which kind.
By constituting by this way, can further improve the marresistance of anti-dazzle hardness film coating.
It addition, when constituting the anti-dazzle hardness film coating of the present invention, the thickness preferably making antiglare hardcoat is 0.5～6 μ
Value in the range of m.
By constituting by this way, it is possible to obtain actually used needed hardness, and can inhibitory activity energy-ray
The curling that the cure shrinkage of gel-type resin causes, and the Antidazzle hard coating caused when bending anti-dazzle hardness film coating can be suppressed
The be full of cracks of layer.
Accompanying drawing explanation
Fig. 1 (a)～(b) are by for illustrating the figure that the anti-dazzle hardness film coating of the present invention is provided.
Fig. 2 is between dazzle and the anti-glare of volume average particle size and anti-dazzle hardness film coating that resin particle is described
The figure that relation is provided.
The figure that Fig. 3 (a)～(e) are provided by the evaluation methodology of the dazzle for anti-dazzle hardness film coating is described.
Fig. 4 (a)～(b) are by for illustrating the figure that the particle size distribution figure of the resin particle in embodiment 1～2 is provided.
Fig. 5 is by for illustrating the figure that the particle size distribution figure of the resin particle in comparative example 1 is provided.
Detailed description of the invention
Embodiments of the present invention, as shown in Fig. 1 (a), it is anti-dazzle hardness film coating 14, and it is the table at plastic basis material 12
Face possesses the anti-dazzle hardness film coating 14 of antiglare hardcoat 13, it is characterized by, antiglare hardcoat 13 is to be become by containing as (A)
Active energy ray curable resin, the resin particle as (B) composition, the dispersant as (C) composition and the conduct (D) divided
The solidfied material of the antiglare hardcoat formation compositions of the Photoepolymerizationinitiater initiater of composition is constituted, and makes as (B) composition
The volume average particle size of resin particle be the value in the range of 1～2.5 μm, make the interpolation of resin particle as (B) composition
Amount is for being in the range of 0.1～20 weight portions relative to active energy ray curable resin 100 weight portion as (A) composition
Value, and the dispersant as (C) composition is the compound that intramolecular has at least one polar group, and polar group is for choosing freely
Carboxyl, hydroxyl, sulfonic group, primary amine groups, secondary amine, tertiary amine groups, amide groups, quaternary ammonium salt base, pyridine alkali, sulfonium salt base and salt
At least one in the group that base is constituted, the addition making the dispersant as (C) composition is relative to the work as (A) composition
Property energy ray-curable resin 100 weight portion is the value in the range of 0～2 weight portions (but except 0 weight portion).
Hereinafter suitably referring to the drawings embodiments of the present invention are illustrated.
1. antiglare hardcoat
(1) antiglare hardcoat formation compositions
The antiglare hardcoat of the anti-dazzle hardness film coating of the present invention, is by containing the active energy beam as (A) composition
Gel-type resin, the resin particle as (B) composition, the dispersant as (C) composition and the photopolymerization as (D) composition cause
The solidfied material of the antiglare hardcoat formation compositions of agent is constituted.
Hereinafter each composition contained by antiglare hardcoat formation compositions is illustrated.
(1)-1 (A) composition: active energy ray curable resin
The active energy beam as (A) composition contained by antiglare hardcoat formation compositions in the present invention is solid
The kind of change type resin is not particularly restricted, and can be selected by known material, can enumerate energy ray-curable
Monomer, oligomer, resin or their mixture.
More specifically, it is preferable to use multi-functional (methyl) acrylic monomer or (methyl) esters of acrylic acid pre-polymerization
Thing.
It addition, as multi-functional (methyl) acrylic monomer, such as BDO two (methyl) propylene can be enumerated
Acid esters, 1,6-HD two (methyl) acrylate, neopentyl glycol two (methyl) acrylate, Polyethylene Glycol two (methyl) propylene
Acid esters, 3-hydroxypivalic acid neopentyl glycol two (methyl) acrylate, bicyclopentyl two (methyl) acrylate, caprolactone modification two
Cyclopentenyl two (methyl) acrylate, ethylene-oxide-modified di(2-ethylhexyl)phosphate (methyl) acrylate, allylation cyclohexyl two (first
Base) acrylate, isocyanuric acid ester two (methyl) acrylate, trimethylolpropane tris (methyl) acrylate, two seasons penta 4
Alcohol three (methyl) acrylate, propanoic acid modification dipentaerythritol three (methyl) acrylate, tetramethylolmethane three (methyl) acrylic acid
Ester, epoxy pronane modification trimethylolpropane tris (methyl) acrylate, three (acryloyl-oxyethyl) isocyanuric acid ester, propanoic acid
Modified dipentaerythritol five (methyl) acrylate, dipentaerythritol six (methyl) acrylate, caprolactone modification two season penta 4
Multi-functional (methyl) acrylate of alcohol six (methyl) acrylate etc..
It addition, these monomers can use one or be used in combination of two or more.
It addition, as (methyl) esters of acrylic acid prepolymer, such as polyester acrylic esters, epoxy acrylate can be enumerated
Class, urethane acrylate class, polyalcohol acrylate class etc..
Wherein, as polyester acrylic esters prepolymer, can be by such as making to utilize polybasic carboxylic acid with (methyl) acrylic acid
There is the hydroxy esterification of the polyester oligomers of hydroxyl with two ends obtained by the condensation of polyhydric alcohol, or with (methyl) acrylic acid
The hydroxy esterification of the end to the oligomer obtained by polybasic carboxylic acid addition alkylene oxide is made to obtain.
It addition, Epoxy Acrylates prepolymer, can be by such as making bisphenol-type epoxy resin or the phenol of lower molecular weight
The epoxide ring of aldehyde type epoxy resin and (methyl) acrylic acid react and make it be esterified and obtain.
It addition, urethane acrylate class prepolymer, can be by such as making to utilize polyethers many with (methyl) acrylic acid
Polyurethane oligomer obtained by unit's alcohol or PEPA and the reaction of polyisocyanate is esterified and obtains.
Additionally, polyalcohol acrylate class prepolymer, can be by making the hydroxy ester of polyether polyol with (methyl) acrylic acid
Change and obtain.These prepolymers can be used alone one or be used in combination of two or more, the most also can be with above-mentioned multi-functional (first
Base) acrylic ester monomer using.
(1)-2 (B) composition: resin particle
(i) kind
The kind of the resin particle as (B) composition contained by antiglare hardcoat formation compositions in the present invention,
Such as polyorganosiloxane resin microgranule, modified polysiloxane resin microgranule, melmac microgranule, acrylate copolymer can be enumerated
Resin particle (such as plexiglass microgranule etc. can be enumerated), acrylic-styrene copolymer resin particle, poly-
Carbonate resin microgranule, polyvinyl resin microgranule, styrenic polymer resins microgranule, benzoguanamine resin microgranule etc..
Wherein it is preferably selected from by acrylate copolymer resin particle, acrylic-styrene copolymer resin particle, benzene second
At least one in the group that alkene polymer resin particle and polyorganosiloxane resin microgranule are constituted.
Reason is, if using these resin particles, then can the surface-stable of antiglare hardcoat formed fine
Concavo-convex.
Additionally, from making scattering of light state homogenize, and come from the viewpoint of making anti-glare stabilisation, preferably make resin
Being shaped as of microgranule is spherical.
(ii) volume average particle size
It addition, inventive feature is that to make the volume average particle size of resin particle be the value in the range of 1～2.5 μm.
Reason is, is the value in the range of this by the volume average particle size making resin particle, it is possible to maintain excellent preventing
Dizzy property, and also can effectively suppress the generation of dazzle.
That is, if the volume average particle size of resin particle is less than 1 μm, then the situation being difficult to maintain sufficient anti-glare is had.
On the other hand, if the volume average particle size of resin particle is more than 2.5 μm, the most especially it is being applicable to the situation of High Resolution Display
Under, have the situation being difficult to effectively suppress dazzle to occur.
It is therefore preferable that be the value in the range of 1.2～2.3 μm for making the volume average particle size of resin particle, more preferably
Value in the range of 1.3～2 μm.
Additionally, the volume average particle size of resin particle can use laser diffraction and scattering formula particle size distribution device to survey
Fixed.
Then, use Fig. 2 illustrate the volume average particle size of resin particle and the dazzle of anti-dazzle hardness film coating and anti-glare it
Between relation.
That is, Fig. 2 represents the volume average particle size (μm) that transverse axis is resin particle, and the left longitudinal axis is the dazzle of anti-dazzle hardness film coating
(ppi) characteristic curve A and the characteristic curve B of 60 ° of mirror surface lusters (%) that the right longitudinal axis is anti-dazzle hardness film coating.
It addition, about the dazzle (ppi) of anti-dazzle hardness film coating and the concrete assay method of 60 ° of mirror surface lusters (%),
It is recorded in embodiment.
Additionally, the value of dazzle (ppi) is the biggest, represent the generation that more can effectively suppress dazzle.
First, from characteristic curve A, the value of dazzle has along with the volume average particle size change of resin particle reduces greatly
Tendency.
Confirm, in the case of being applicable to the actual High Resolution Display of more than 280ppi, in order to stable herein
The generation of ground suppression dazzle, as long as making the value of the dazzle in characteristic curve A is the value more than 80ppi.
It will therefore be appreciated that be the value more than 80ppi to make the value of dazzle, effectively suppress dazzle, it should make resin micro-
The volume average particle size of grain is 2.5 μm value below.
Secondly, from characteristic curve B, 60 ° of mirror surface lusters also have along with the volume average particle size of resin particle becomes
The tendency reduced greatly.
Herein, in the case of the display being applicable to reality, in order to stably obtain the anti-glare of regulation, need to make
60 ° of mirror surface lusters are 120% value below.
It will therefore be appreciated that be 120% value below to make 60 ° of mirror surface lusters, stably obtain the anti-dazzle of regulation
Property, it should make the value that volume average particle size is more than 1 μm of resin particle.
As previously discussed, from characteristic curve A and B, in order to effectively suppress the generation of dazzle and anti-in order to obtain regulation
Dizzy property, it should the volume average particle size making resin particle is the value in the range of 1～2.5 μm.
Additionally, it is preferred that be 50% value below for making the Cv value of resin particle.
Reason is, if this Cv value is the value more than 50%, then particle diameter is more than or less than the granule of volume average particle size
Amount increases, and in the case of the amount of big particle diameter increases, has the situation being difficult to suppress the generation of dazzle, in small particle
Amount increase in the case of, have the situation being difficult to obtain desired anti-glare.
Therefore, the Cv value more preferably making resin particle is 40% value below, more preferably 30% value below.
Additionally, Cv value refers to the coefficient of variation of the particle diameter distribution shown in following formula (1).
Cv value (%)=(standard deviation particle diameter/volume average particle size) × 100 (1)
It addition, this Cv value can use laser diffraction and scattering formula particle size distribution device to measure.
(iii) addition
It addition, feature of present invention is, the addition making resin particle is relative to the active energy beam as (A) composition
Gel-type resin 100 weight portion is the value in the range of 0.1～20 weight portions.
Reason is, in order to make the surface of antiglare hardcoat form micro concavo-convex, and obtains the anti-glare of excellence.
Be i.e. due to, if the addition of resin particle is the value less than 0.1 weight portion, then cannot be at antiglare hardcoat
Surface is sufficiently formed micro concavo-convex, has the situation being difficult to obtain desired anti-glare.On the other hand be due to, if resin particle
Addition be the value more than 20 weight portions, then have haze value excessive, display display image identification reduce feelings
Condition.
Therefore, the addition more preferably making resin particle is relative to the active energy ray-curable as (A) composition
Type resin 100 weight portion is the value in the range of 1～15 weight portions, more preferably the value in the range of 3～12 weight portions.
(1)-3 (C) composition: dispersant
Antiglare hardcoat formation compositions in the present invention, is characterized by containing the dispersant as (C) composition.
Reason is, by containing dispersant, not only antiglare hardcoat formation compositions is being coated plastics base
During material surface, it is possible to efficiently control in film the sedimentation situation of resin particle as (B) composition, be stably formed anti-glare
The micro concavo-convex of hard coating surface, is limited to the volume average particle size of resin particle less scope, but also can obtain
Excellent anti-glare.
That is, resin particle is made to be non-uniformly distributed in antiglare hardcoat face side in suitable scope, it is possible to stablize landform
Become the micro concavo-convex on antiglare hardcoat surface, even available excellent anti-glare.
(i) kind
The dispersant as (C) composition contained by antiglare hardcoat formation compositions in the present invention, is characterized by
Intramolecular has the compound of at least one polar group, and polar group is carboxyl, hydroxyl, sulfonic group, primary amine groups, secondary amine, uncle
Amido, amide groups, quaternary ammonium salt base, pyridine alkali, sulfonium salt base and alkali.
Reason is, if having the dispersant of these polar groups, then can effectively control to coat plastic basis material table
The sedimentation situation of the resin particle of the film of the antiglare hardcoat formation compositions in face.
The mechanism of action of this dispersant is not yet explained clearly, but speculates that the polar group being because in dispersant is coordinated in
The surface of resin particle, its result, the surface polarity of resin particle changes, and resin particle is present in the probability near film coated surface
Uprise.
It addition, among above-mentioned polar group, particularly preferably carboxyl, sulfonic group, primary amine groups～tertiary amine groups.
Reason is, if these polar groups, then dispersant can be made more effectively to be coordinated in the surface of resin particle.
It addition, one can be imported in intramolecular or import multiple above-mentioned polar group.
It addition, in the case of intramolecular has multiple polar group, need to make to have each polar group organic compound that
The basic framework of this bonding, and this basic framework is preferably by ester chain, vinyl chain, acrylic acid chain, ether chain and carbamic acid
Ester chain etc. is constituted.
It addition, the hydrogen atom of a part can replace through halogen atom in these molecules.
It addition, among these, preferably acrylic resin, carbamate resins, polyester resin and alkyd resin, especially
It is preferably acrylic resin, carbamate resins, polyester resin.
It addition, above-mentioned polar group can completely random configure in molecular resin, but preferably by block structure or grafting
Structure makes polar group be configured at the end section of molecule.
Reason is, by configuring polar group at end section, uprises the absorption property of resin particle.
It addition, the molecular weight of dispersant is not particularly limited, can select from the wide scope of 100～900,000.
The one additionally, dispersant can be used alone, or two or more use be can be combined.
(ii) addition
It addition, feature of present invention is, the addition making dispersant is solid relative to the active energy beam as (A) composition
Change type resin 100 weight portion is the value in the range of 0～2 weight portions (but except 0 weight portion).
Reason is, thus enables that resin particle is non-uniformly distributed in antiglare hardcoat surface in suitable scope.
That is, if the addition of dispersant is 0 weight portion, then resin particle cannot be made to be non-uniformly distributed in suitable scope
Antiglare hardcoat surface, has the situation being difficult to obtain desired anti-glare.On the other hand, if the addition of dispersant is
More than the value of 2 weight portions, then have the situation that marresistance reduces.
Therefore, the addition more preferably making dispersant is relative to the active energy ray curable as (A) composition
Resin 100 weight portion is the value in the range of 0.01～1 weight portion, more preferably in the range of 0.03～0.5 weight portion
Value.
(1)-4 (E) composition: silicon dioxide microparticle
Antiglare hardcoat formation compositions in the present invention is preferably containing the silicon dioxide as (E) composition micro-
Grain.
Reason is, it is possible to when antiglare hardcoat formation compositions is coated plastic basis material surface, more
Efficiently control in film the sedimentation situation of resin particle as (B) composition, it is possible to more steady on the surface of antiglare hardcoat
Surely micro concavo-convex is formed.
That is, the difference in specific gravity with resin particle is utilized, it is possible to make resin particle be non-uniformly distributed in anti-with appropriate scope
Dizzy property hard coating surface side, and can more stably form the micro concavo-convex on antiglare hardcoat surface, and then available excellence
Anti-glare.
(i) kind
It addition, as the kind of silicon dioxide microparticle, be preferably and use colloidal silicon dioxide microgranule or there is surface official
The silicon dioxide microparticle of energy base.
It addition, as having the silicon dioxide microparticle of surface functionalities, can enumerate and such as have containing (methyl) acryloyl group
Group as the silicon dioxide microparticle (hereinafter sometimes referred to reactive silicon dioxide microgranule) of surface functionalities.
This reactive silicon dioxide microgranule, can be by such as making the silanol base on the surface of silicon dioxide microparticle and have can be with
The Organic substance containing polymerism unsaturated group of the functional group of this silanol base reaction reacts and obtains.
It addition, polymerism unsaturated group can enumerate the most free-radical polymerised (methyl) acryloyl group etc..
It addition, as having the organic compound containing polymerism unsaturated group of the functional group that can react with silanol base, suitable
Conjunction uses such as acrylic acid, acryloyl chloride, acrylic acid 2-isocyanatoethyl methacrylate, glycidyl acrylate, acrylic acid 2,3-Asia
Corresponding to amino propyl ester, acrylic acid 2-hydroxyl ethyl ester, acryloxypropyl trimethoxy silane etc. and these acrylic acid derivatives
Methacrylic acid derivative.
Additionally, these acrylic acid derivatives or methacrylic acid derivative can be used alone one or combine two or more come
Use.
(ii) volume average particle size
Additionally, it is preferred that be the value in the range of 2～500nm for making the volume average particle size of silicon dioxide microparticle.
Reason is, if the volume average particle size of silicon dioxide microparticle is the value less than 2nm, then has silicon dioxide microparticle
Dispersion stabilization reduce situation.On the other hand be due to, if the volume average particle size of silicon dioxide microparticle is for more than 500nm
Value, then have the situation that silicon dioxide microparticle causes haze value excessively to increase.
Therefore, the volume average particle size more preferably making silicon dioxide microparticle is the value in the range of 4～300nm, enters one
Step is preferably the value in the range of 6～50nm.
Additionally, the volume average particle size of silicon dioxide microparticle can use laser diffraction and scattering formula particle size distribution device to enter
Row measures.
(iii) addition
Additionally, it is preferred that be solid relative to the active energy beam as (A) composition for making the addition of silicon dioxide microparticle
Change type resin 100 weight portion is the value in the range of 10～200 weight portions.
Reason is, if the addition of silicon dioxide microparticle is the value less than 10 weight portions, then has and is difficult to make resin micro-
Grain is non-uniformly distributed in the situation on antiglare hardcoat surface in suitable scope.On the other hand be due to, if silicon dioxide is micro-
The addition of grain is the value more than 200 weight portions, then reduce due to the adding proportion of active energy ray curable resin, have
The situation that marresistance reduces.
Therefore, the addition more preferably making silicon dioxide microparticle is relative to the active energy beam as (A) composition
Gel-type resin 100 weight portion is the value in the range of 12～175 weight portions, more preferably the model of 15～150 weight portions
Enclose interior value.
(1)-5 (D) composition: Photoepolymerizationinitiater initiater
(i) kind
The Photoepolymerizationinitiater initiater as (D) composition contained by antiglare hardcoat formation compositions in the present invention
Kind, can enumerate such as Benzoinum, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, Benzoinum n-butyl ether, Benzoinum
Diisobutyl ether, 1-Phenylethanone., dimethylamino benzoylformaldoxime, 2,2-dimethoxy-2-phenyl acetophenone, 2,2-diethoxy-2-phenyl
1-Phenylethanone., 2-hydroxy-2-methyl-1-phenyl-propane-1-ketone, 1-hydroxycyclohexyl phenyl ketone, 2-methyl isophthalic acid-[4-(methyl mercapto) benzene
Base]-2-morpholinyl-propane-1-ketone, 4-(2-hydroxyl-oxethyl) phenyl-2 (hydroxyl-2-propyl group) ketone, benzophenone, to phenyl
Benzophenone, 4,4'-diethylamino benzophenone, dichloro benzophenone, 2-methylanthraquinone, 2-ethyl-anthraquinone, the 2-tert-butyl group
Anthraquinone, 2-amino anthraquinones, 2-methyl thiaxanthone, 2-ethyl thiaxanthone, CTX, 2,4-dimethyl thioxanthone, 2,4-bis-
Ethyl thiaxanthone, benzyl dimethyl ketal, 1-Phenylethanone. dimethyl ketal, to dimethylamino benzoate etc..
The one or be used in combination of two or more additionally, these can be used alone.
(ii) addition
Additionally, it is preferred that be solid relative to the active energy beam as (A) composition for making the addition of Photoepolymerizationinitiater initiater
Change type resin 100 weight portion is the value in the range of 0.2～10 weight portions.
Reason is, if the addition of Photoepolymerizationinitiater initiater is the value less than 0.2 weight portion, then has and is difficult to obtain fully
The situation of curable.On the other hand, if the addition of Photoepolymerizationinitiater initiater is the value more than 10 weight portions, then scratch resistance is had
Property reduce situation.
Therefore, the addition more preferably making Photoepolymerizationinitiater initiater is relative to the active energy beam as (A) composition
Gel-type resin 100 weight portion is the value in the range of 0.5～7 weight portions, more preferably in the range of 1～5 weight portions
Value.
(1)-6 (F) composition: slip agent
It addition, the antiglare hardcoat formation in the present invention is preferably containing the slip agent as (F) composition by compositions.
Reason is, by containing slip agent, improving the marresistance of anti-dazzle hardness film coating.
I.e., in the present invention, owing to the volume average particle size of the resin particle as (B) composition is limited to less model
Enclose, therefore have and be non-uniformly distributed in the situation that the resin particle on antiglare hardcoat surface easily comes off because of friction etc..
In this respect, by utilizing slip agent to improve antiglare hardcoat smoothness of the surface, not only resin particle
Volume average particle size is defined to less scope, also can obtain the marresistance of regulation.
(i) kind
It addition, the kind of slip agent, preferably silicone oil and modified silicon oil or either of which kind.
Reason is, if such slip agent, then with other compositions in antiglare hardcoat formation compositions
Intermiscibility excellent, also can further improve the marresistance of anti-dazzle hardness film coating.
More specifically, polysiloxane-modified urethane acrylate and urethane acrylate can be enumerated
Mixture, polydimethylsiloxane, modified dimethyl polysiloxane etc..
(ii) addition
Additionally, it is preferred that be relative to the active energy ray curable tree as (A) composition for making the addition of slip agent
Fat 100 weight portion is the value in the range of 0.05～20 weight portions.
Reason is, if the addition of slip agent is the value less than 0.05 weight portion, then has and cannot obtain sufficient light
Slip, is even difficult to obtain the situation of sufficient marresistance.On the other hand, if the addition of slip agent is for more than 20 weight portions
Value, then have active energy ray curable resin adding proportion reduce, therefore marresistance reduce situation.
Therefore, the addition more preferably making slip agent is relative to the active energy ray curable as (A) composition
Resin 100 weight portion is the value in the range of 0.5～15 weight portions, more preferably the value in the range of 1～10 weight portions.
The preparation of (1)-7 antiglare hardcoat formation compositions
Antiglare hardcoat formation compositions used in the present invention, can as required in suitable solvent add on
State (A) as neccessary composition～(D) composition and (E)～(F) composition as any composition so that it is dissolve or disperse and make
Standby.
Now, in addition to (A)～(F) composition, also can add such as antioxidant, UV absorbent, silanes occasionally
Connection agent, light stabilizer, levelling agent, defoamer etc..
It addition, the solvent used can enumerate the fragrance of the aliphatic hydrocarbon of such as hexane, heptane etc., toluene, dimethylbenzene etc.
The alcohols of the halogenated hydrocarbons of race's hydrocarbon, dichloromethane, dichloroethanes etc., methanol, ethanol, propanol, butanol etc., acetone, methyl ethyl ketone,
The cellosolve class of the esters of the ketone of 2 pentanone, different Buddhist ketone, Ketohexamethylene etc., ethyl acetate, butyl acetate etc., ethyl cellosolve etc.
Solvent etc..
Additionally, the concentration of antiglare hardcoat formation compositions prepared by this way and viscosity, as long as
The numerical range on plastic basis material surface can be coated, can the most suitably select.
(2) thickness
Additionally, it is preferred that be the value in the range of 0.5～6 μm for making the thickness of antiglare hardcoat.
Reason is, if the thickness of antiglare hardcoat is the value less than 0.5 μm, then has and is difficult to obtain actually used institute
The situation of the pencil hardness of palpus.On the other hand be due to, if the thickness of antiglare hardcoat is the value more than 6 μm, then can be in distress
The curling caused with the cure shrinkage of inhibitory activity energy ray-curable resin, and be difficult to suppress anti-dazzle hardness film coating bending
The situation of Shi Zaocheng antiglare hardcoat be full of cracks.
Therefore, the thickness more preferably making antiglare hardcoat is the value in the range of 1～6 μm, more preferably 2～
Value in the range of 5 μm.
2. plastic basis material
The kind of the plastic basis material in the present invention, can be from the past as the known plastic basis material of optics hard coat film base material
In properly select use, such as polyethylene terephthalate, polybutylene terephthalate (PBT), poly-naphthalene diformazan can be enumerated
The mylar of acid glycol ester etc., polyethylene film, polypropylene film, cellophane, diacetyl cellulose, triacetyl are fine
Dimension element, acetylcellulose butyrate, polrvinyl chloride, polyvinylidene chloride, polyvinyl alcohol, ethylene-vinyl acetate copolymer,
Polystyrene, Merlon, polymethylpentene, polysulfones, polyether-ether-ketone, polyether sulfone, Polyetherimide, polyimides, fluororesin,
Polyamide, acrylic resin, norbornene resin, cyclic olefin resins etc..
Furthermore it is preferred that be the value in the range of 15～300 μm for making the thickness of plastic basis material, more preferably 30～200 μm
In the range of value.
It addition, shown in such as Fig. 1 (b), it is possible to the anti-dazzle hardness film coating of the present invention is fitted on polaroid and makes partially
Vibration plate 20.
That is, use that tri acetyl cellulose (TAC) thin film is this does not have optically anisotropic thin film 12a as plastics
Base material, forms antiglare hardcoat 13 in its one side, and makes anti-dazzle hardness film coating 14.
It follows that make the TAC film 12a being formed with antiglare hardcoat 13 by adhering agent layer 15a lamination at polyethylene
The one side of alcohols polaroid 11, and make the TAC film 12b not forming antiglare hardcoat 13 by adhering agent layer 15b lamination
Opposing face at polyvinyl alcohol polaroid.
Thus, though can obtain having excellence anti-glare and in the case of being applicable to High Resolution Display also
Can effectively suppress the polarization plates 20 that dazzle occurs.
Additionally, may also set up in polarization plates 20 adhering agent layer 16 of the optics for fitting in liquid crystal cell etc.,
Stripping film 17.
3. the characteristic of anti-dazzle hardness film coating
(1) 60 ° of mirror surface luster
Additionally, it is preferred that be 130% for making 60 ° of mirror surface lusters according to the anti-dazzle hardness film coating measured by JIS Z8741
Value below.
Reason is, if 60 ° of mirror surface lusters are the value more than 130%, then have and is difficult to obtain excellent anti-glare
Situation.
Therefore, more preferably make according to 60 ° of mirror surface lusters of anti-dazzle hardness film coating measured by JIS Z8741 be
120% value below, more preferably 115% value below.
(2) dazzle
It is provided with transmittance section it addition, use and becomes the lattice of regulation ppi (pixel/inch) as shown in Fig. 3 (a)～(e)
Sub-shape figure, the result preferably making the appraisal of glare implemented the most as be described hereinafter is more than the value in the range of 80ppi.
Reason is, if the evaluation result of this dazzle is 80ppi value below, is then being applicable to the reality of more than 280ppi
High Resolution Display in the case of, have the situation being susceptible to dazzle.
Therefore, more preferably make the value that result is more than 90ppi of the appraisal of glare implemented the most as be described hereinafter, enter
One step is preferably the value of more than 100ppi.
Additionally, the ppi of lattice-like pattern is the biggest, in other words, display gets over fine definition, is more susceptible to Antidazzle hard coating
The dazzle that film causes.
Therefore, the numerical value of above-mentioned ppi is the biggest, illustrates more can effectively suppress the generation of dazzle.
(3) haze value
Additionally, it is preferred that for making the scope that haze value is 3～40% according to the anti-dazzle hardness film coating measured by JIS K7136
Interior value.
Reason is, if haze value is the value less than 3%, then has the situation being difficult to obtain the anti-glare of excellence.Another
Aspect be due to, if haze value is the value more than 40%, then have display display image identification reduce situation.
Therefore, more preferably making the haze value according to the anti-dazzle hardness film coating measured by JIS K7136 is 3.5～35%
In the range of value, the more preferably value in the range of 4～30%.
(4) total light transmittance
Additionally, it is preferred that be more than 85% for making the total light transmittance according to the anti-dazzle hardness film coating measured by JIS K7361
Value.
Reason is, if total light transmittance is the value less than 85%, then the identification of the display image having display reduces
Situation.
Therefore, more preferably making the total light transmittance according to the anti-dazzle hardness film coating measured by JIS K7361 is more than 88%
Value, the more preferably value of more than 90%.
(5) hardness
It addition, anti-dazzle hardness film coating is preferably does not has cosmetic variation in the marresistance evaluation using steel wool.
Reason is, in the evaluation of this marresistance, in the case of observing cosmetic variation, has and is difficult to be made
Situation for the sufficient marresistance needed for hard coat film.
Additionally, the evaluation details of this marresistance is as be described hereinafter.
4. the manufacture method of anti-dazzle hardness film coating
As the manufacture method of the anti-dazzle hardness film coating of the present invention, first, known method, such as bar type is used to be coated with
Cloth method, scraper for coating method, print roll coating method, scraper plate rubbing method, die coating methods, gravure coating process etc., by antiglare hardcoat
Formation compositions is coated on plastic basis material surface, and forms film.
It follows that make dried coating film, then irradiate active energy beam and make curing of coating, and film is made Antidazzle hard
Coating, thus can get anti-dazzle hardness film coating.
It addition, active energy beam when making curing of coating can enumerate ultraviolet, this ultraviolet can pass through high voltage mercury lamp, nothing
Electrod lamp, metal halide lamp, xenon lamp etc. irradiate.
Additionally, it is preferred that be usual 100～500mJ/cm for making ultraviolet irradiation amount2In the range of value.
Embodiment
Referring to embodiment, the anti-dazzle hardness film coating of the present invention is further described.
[embodiment 1]
1. the manufacture of anti-dazzle hardness film coating
(1) preparation process of antiglare hardcoat formation compositions
Such as table 1 and shown below, will be as the active energy ray curable resin of (A) composition, as the tree of (B) composition
Fat microgranule, the dispersant as (C) composition, the Photoepolymerizationinitiater initiater as (D) composition, micro-as the silicon dioxide of (E) composition
Grain and the slip agent as (F) composition mix, and dilute with propylene glycol monomethyl ether, and prepare solid constituent 30 weight %
Antiglare hardcoat formation compositions.
Additionally, in table 1 and following addition be represent with solid constituent convert obtained by value.
(A) composition: polyfunctional acrylate: 100 weight portions
(B) composition: crosslinked acrylic acid polymer resin particle: 10 weight portions
(hydrops finished industrial (strain) is made, Techpolymer XX-27LA, volume average particle size: 1.5 μm, Cv value:
23%)
(C) composition: carboxylic polymer modification thing: 0.1 weight portion
(common prosperity society chemistry (strain) system, Flowlen G700)
(D) composition: 1-hydroxy-cyclohexyl-phenyl-one: 5 weight portions
(BSF (strain) makes, Irgacure 184)
(E) composition；The nano silicon dioxide sol of importing acryloyl group: 150 weight portions
(volume average particle size: 50nm)
(F) composition: polysiloxane-modified urethane acrylate/urethane acrylate: 7 weight portions
(Japan's synthetic chemical industry (strain) system, purple light UV-AF100)
It addition, the Cv value of (B) composition refers to the coefficient of variation of the particle diameter distribution shown in following formula (1).
Cv value (%)=(standard deviation particle diameter/volume average particle size) × 100 (1)
It addition, the volume average particle size of (B) composition and Cv value use laser diffraction and scattering formula particle size distribution device (hole
Field makes institute's (strain) system, LA-920) measure.
Now, dispersion solvent uses methyl ethyl ketone.
Additionally, the particle size distribution of (B) composition used in embodiment 1 is illustrated in Fig. 4 (a).
(2) application step
It follows that use bar #14, obtained antiglare hardcoat formation compositions is coated as plastics base
Material and with on the easy adhesion coating of the mylar (east beautiful (strain) system, Lumirror U48, thickness: 100 μm) of easy adhesion coating,
Making the thickness after solidification is 5 μm, and forms coating layer.
(3) drying steps
It follows that use hot-air drying device, obtained coating layer is made to be dried with the condition of 70 DEG C, 1 minute.
(4) curing schedule
It follows that use ultraviolet lamp (GS Yuasa Corporation (strain) makes, light source: high voltage mercury lamp),
According to following condition to dried coating layer irradiation ultraviolet radiation, make coating layer solidify, make antiglare hardcoat, and obtain
Whole anti-dazzle hardness film coating.
Illumination: 100mW/cm2
Light quantity: 240mJ/cm2
2. evaluate
(1) evaluation 1 of anti-glare
Anti-glare for obtained anti-dazzle hardness film coating is evaluated.
That is, obtained anti-dazzle hardness film coating is placed on the plank of black, makes antiglare hardcoat upward.
It follows that light three wavelength fluorescent lamps above anti-dazzle hardness film coating, make it reflect with anti-dazzle hardness film coating, depend on
It is evaluated according to following standard.Obtained result is shown in table 2.
Zero: the fluorescent lamp soft edge recognized by the reflection of anti-dazzle hardness film coating
×: the fluorescent lamp profile recognized by the reflection of anti-dazzle hardness film coating does not obscures
(2) evaluation 2 of anti-glare
Anti-glare for obtained anti-dazzle hardness film coating is evaluated by mirror surface luster (%).
That is, use gloss meter (Japanese electricity color industry (strain) system, VG2000), according to JIS Z8741, obtained is prevented
60 ° of mirror surface lusters (%) of dizzy property hard coat film are measured.Obtained result is shown in table 2.
(3) evaluation of dazzle
Generation for the dazzle of obtained anti-dazzle hardness film coating is evaluated.
That is, prepare as shown in Fig. 3 (a), to arrange transmittance section and form the lattice-like pattern of 60ppi (pixel/inch).
This lattice-like pattern is by arranging metal vapor deposition layer on a glass, then metal vapor deposition layer is implemented resist
Process, be etched, remove resist further and make.
It follows that the lattice-like pattern prepared to be placed on backlight (King (strain) makes, BRIGHTBOX 5000).
It follows that be placed on lattice-like pattern by obtained anti-dazzle hardness film coating, and make antiglare hardcoat upward,
Observe and occur at dazzle.
It follows that make anti-dazzle hardness film coating move in direction in parallel on lattice-like pattern, observe in advance
In the case of dazzle point is moved together with anti-dazzle hardness film coating, it is judged that be by anti-dazzle hardness film coating institute for this dazzle
Cause.
It addition, in the case of not observing that in the lattice-like pattern of 60ppi anti-dazzle hardness film coating causes dazzle to occur,
Sequentially use the lattice-like pattern increasing ppi with every 10ppi, repeat same operation dizzy to observing that anti-dazzle hardness film coating causes
Till light occurs.
To not observe that the maximum lattice-like pattern (ppi) that anti-dazzle hardness film coating causes dazzle to occur is shown in table 2.
Additionally, the ppi of lattice-like pattern is the biggest, in other words, display gets over fine definition, and it is dizzy that anti-dazzle hardness film coating causes
Light can more be susceptible to.
Therefore, the value of the ppi shown in table 2 is the biggest, represents the generation that more can effectively suppress dazzle.
It addition, Fig. 3 (b) represents the photo of the lattice-like pattern of 80ppi, Fig. 3 (c) represents the lattice-like pattern of 100ppi
Photo, Fig. 3 (d) represents the photo of the lattice-like pattern of 140ppi, and Fig. 3 (e) represents the photo of the lattice-like pattern of 180ppi.
(4) evaluation of haze value
Haze value (%) for obtained anti-dazzle hardness film coating is evaluated.
That is, use haze meter (Japanese electricity color industry (strain) system, NDH5000), according to JIS K7136, obtained is prevented
The haze value (%) of dizzy property hard coat film is measured.Obtained result is shown in table 2.
(5) evaluation of total light transmittance
Total light transmittance (%) for obtained anti-dazzle hardness film coating is evaluated.
That is, use haze meter (Japanese electricity color industry (strain) system, NDH5000), according to JIS K7361, obtained is prevented
The total light transmittance (%) of dizzy property hard coat film is measured.Obtained result is shown in table 2.
(6) evaluation of marresistance
Marresistance for obtained anti-dazzle hardness film coating is evaluated.
That is, the steel wool of #0000 is used, with 250g/cm2Loading, the sliding distance of 10cm, for obtained anti-dazzle
Property hard coat film antiglare hardcoat implement 10 times come and go friction test.
It follows that with visualization antiglare hardcoat with or without scar under three wavelength fluorescent lamps, enter according to following standard
Row is evaluated.Obtained result is shown in table 2.
Zero: do not observe the cosmetic variation of antiglare hardcoat
×: observe the cosmetic variation of antiglare hardcoat
[embodiment 2]
In example 2, by (A)～(B) and (E) composition in antiglare hardcoat formation compositions as described below
Change, in addition, produce anti-dazzle hardness film coating similarly to Example 1, and be evaluated.Obtained result is shown
In table 2.
It addition, the particle size distribution of (B) composition embodiment 2 used is illustrated in Fig. 4 (b).
(A1) composition: urethane acrylate class prepolymer: 70 weight portions
(A2) composition: polyfunctional acrylate: 30 weight portions
(B) composition: cross-linked acrylic acid-styrene copolymerisation resin particle: 5 weight portions
(hydrops finished industrial (strain) is made, Techpolymer XX16LA, volume average particle size: 2.5 μm, Cv value:
28%)
(E) composition: nano silicon dioxide sol: 45 weight portions
(Nissan Chemical (strain) is made, MIBK-ST, volume average particle size: 10nm)
[embodiment 3]
In embodiment 3, (A)～(E) composition in antiglare hardcoat formation compositions is changed as described below, removes
Outside this, produce anti-dazzle hardness film coating similarly to Example 1, and be evaluated.Obtained result is shown in table 2.
(A) composition: polyfunctional acrylate's (dipentaerythritol acrylate): 100 weight portions
(Xin Zhong village industry (strain) system, NK Ester A-DPH)
(B) composition: polyorganosiloxane resin microgranule: 5 weight portions
(Momentive (strain) makes, Tospearl 120, volume average particle size: 2 μm, Cv value: 20%)
(C) composition: carboxylic polymer modification thing: 0.05 weight portion
(common prosperity society chemistry (strain) system, Flowlen G700)
(D) composition: 1-hydroxy-cyclohexyl-phenyl-one: 3 weight portions
(BSF (strain) makes, Irgacure 184)
(E) composition: reacting nano silicon dioxide gel: 18 weight portions
(Nissan Chemical (strain) is made, MIBK-SD, volume average particle size: 10nm)
[embodiment 4]
In example 4, among antiglare hardcoat formation compositions and be not added with (F) composition, in addition, with
Embodiment 1 similarly produces anti-dazzle hardness film coating, and is evaluated.Obtained result is shown in table 2.
[comparative example 1]
In comparative example 1, (B) composition in antiglare hardcoat formation compositions is changed, as described below except this
Outside, produce anti-dazzle hardness film coating similarly to Example 1, and be evaluated.Obtained result is shown in table 2.
It addition, the particle size distribution figure of (B) composition used by comparative example 1 is shown in Fig. 5.
(B) composition: crosslinked acrylic acid polymer resin particle: 10 weight portions
(combine and grind chemistry (strain) system, MX-80H3wt, volume average particle size: 0.8 μm, Cv value=10%)
[comparative example 2]
In comparative example 2, (B) composition in antiglare hardcoat formation compositions is changed, as described below except this
Outside, produce anti-dazzle hardness film coating similarly to Example 1, and be evaluated.Obtained result is shown in table 2.
(B) composition: crosslinked acrylic acid polymer resin particle: 10 weight portions
(combine and grind chemistry (strain) system, Mx-300, volume average particle size: 3 μm, Cv value: 10%)
[table 2]
Industrial applicibility
Such as above detailed narration, the foundation present invention, by the antiglare hardcoat for forming antiglare hardcoat
Formation compositions is added with regulation ratio the resin particle with prescribed volume mean diameter, and adds with regulation ratio
Regulation dispersant, can maintain excellent anti-glare, the most also can effectively suppress the generation of dazzle.
As a result, according to the available a kind of anti-dazzle hardness film coating of the present invention, it has the anti-glare of excellence, even and if suitable
In the case of High Resolution Display, it is also possible to effectively suppress the generation of dazzle.
Therefore, can expect that the anti-dazzle hardness film coating of the present invention contributes to significantly improving the identification of High Resolution Display.
Description of reference numerals
12: plastic basis material；12a, 12b:TAC thin film；13: antiglare hardcoat；14: anti-dazzle hardness film coating；15a, 15b:
Adhering agent layer；16: adhering agent layer；17: stripping film；20: polarization plates.
Claims (6)
1. an anti-dazzle hardness film coating, it is the anti-dazzle hardness film coating possessing antiglare hardcoat on the surface of plastic basis material, its
It is characterised by,
Described antiglare hardcoat is by containing as the active energy ray curable resin of (A) composition, as (B) composition
The antiglare hardcoat formation group of resin particle, the dispersant as (C) composition and the Photoepolymerizationinitiater initiater as (D) composition
The solidfied material of compound is constituted, and
Making the described volume average particle size as the resin particle of (B) composition is the value in the range of 1～2.5 μm, makes described work
Addition for the resin particle of (B) composition is relative to the described active energy ray curable resin 100 as (A) composition
Weight portion is the value in the range of 0.1～20 weight portions, and
The described dispersant as (C) composition is the compound that intramolecular has at least one polar group, and described polar group is
Select free carboxyl group, hydroxyl, sulfonic group, primary amine groups, secondary amine, tertiary amine groups, amide groups, quaternary ammonium salt base, pyridine alkali, sulfonium salt base
And at least one in the group that constituted of alkali, make the addition of the described dispersant as (C) composition for relative to described
The model that active energy ray curable resin 100 weight portion is 0～2 weight portions (but except 0 weight portion) as (A) composition
Enclose interior value.
2. anti-dazzle hardness film coating as claimed in claim 1, it is characterised in that the described resin particle as (B) composition is choosing
Free acrylate copolymer resin particle, acrylic-styrene copolymer resin particle, styrenic polymer resins microgranule and poly-
At least one in the group that silicone resin microgranule is constituted.
3. anti-dazzle hardness film coating as claimed in claim 1 or 2, it is characterised in that described antiglare hardcoat formation is combined
Thing contains the silicon dioxide microparticle as (E) composition, and makes the volume average particle of the described silicon dioxide microparticle as (E) composition
Footpath is the value in the range of 2～500nm, and makes the addition of the described silicon dioxide microparticle as (E) composition for relative to institute
Stating active energy ray curable resin 100 weight portion as (A) composition is the value in the range of 10～200 weight portions.
4. the anti-dazzle hardness film coating as described in any one in claim 1-3, it is characterised in that described antiglare hardcoat shape
One-tenth compositions contains the slip agent as (F) composition, and make the addition of the described slip agent as (F) composition for relative to
Described active energy ray curable resin 100 weight portion as (A) composition is the value in the range of 0.05～20 weight portions.
5. anti-dazzle hardness film coating as claimed in claim 4, it is characterised in that the described slip agent as (F) composition is silicone oil
And modified silicon oil or either of which kind.
6. the anti-dazzle hardness film coating as described in any one in claim 1-5, it is characterised in that make described antiglare hardcoat
Thickness be the value in the range of 0.5～6 μm.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2014/058552 WO2015145618A1 (en) | 2014-03-26 | 2014-03-26 | Anti-glare hard coat film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105874357A true CN105874357A (en) | 2016-08-17 |
| CN105874357B CN105874357B (en) | 2018-08-21 |
Family
ID=54194216
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480071029.7A Active CN105874357B (en) | 2014-03-26 | 2014-03-26 | Anti-dazzle hardness film coating |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP6603652B2 (en) |
| KR (1) | KR102116291B1 (en) |
| CN (1) | CN105874357B (en) |
| TW (1) | TWI648154B (en) |
| WO (1) | WO2015145618A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107868266A (en) * | 2017-11-28 | 2018-04-03 | 上海道助电子科技有限公司 | A kind of low quick-fried surface treatment method and UV film forming materials |
| CN108070101A (en) * | 2016-11-16 | 2018-05-25 | 琳得科株式会社 | Writing sense improves film |
| CN110720058A (en) * | 2017-08-04 | 2020-01-21 | 株式会社大赛璐 | Anti-dazzle film |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI764944B (en) | 2016-10-07 | 2022-05-21 | 日商日塗汽車塗料股份有限公司 | Optical laminated member and method of manufacturing the optical laminated member |
| CN110036315A (en) * | 2016-12-06 | 2019-07-19 | 凸版印刷株式会社 | Optical film and its optics barrier film, color conversion film and back light unit are used |
| KR101988549B1 (en) * | 2016-12-12 | 2019-06-12 | 주식회사 엘지화학 | Optical film and display device comprising the same |
| WO2019026471A1 (en) | 2017-08-04 | 2019-02-07 | 株式会社ダイセル | Anti-glare film |
| CN110832360B (en) | 2017-08-04 | 2021-12-31 | 株式会社大赛璐 | Anti-dazzle film |
| JPWO2019221000A1 (en) * | 2018-05-15 | 2021-07-08 | 日本化薬株式会社 | Photosensitive resin composition and antiglare film |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1498927A (en) * | 2002-10-29 | 2004-05-26 | �յÿ���ʽ���� | Hard coat film |
| CN1636711A (en) * | 2003-12-26 | 2005-07-13 | 琳得科株式会社 | Hard coat film |
| JP2009244305A (en) * | 2008-03-28 | 2009-10-22 | Lintec Corp | Anti-glare hardcoat film and polarizing plate using the same |
| JP2012048099A (en) * | 2010-08-30 | 2012-03-08 | Lintec Corp | Antiglare-antistatic hard coat film and polarizer |
| JP2013083914A (en) * | 2011-09-27 | 2013-05-09 | Nippon Paper Industries Co Ltd | Anti-glare hard coat film |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5149052B1 (en) | 1970-10-05 | 1976-12-24 | ||
| JP4361754B2 (en) * | 2003-04-24 | 2009-11-11 | 日本製紙株式会社 | Anti-glare film |
| JP2005156642A (en) * | 2003-11-20 | 2005-06-16 | Fuji Photo Film Co Ltd | Antireflection film, polarizing plate, and image display device using the same |
| JP2005164890A (en) * | 2003-12-02 | 2005-06-23 | Konica Minolta Opto Inc | Long-sized antiglare film, antiglare and antireflection film, polarizing plate, display device using those, and antiglare processing method |
| JP2008096781A (en) * | 2006-10-13 | 2008-04-24 | Nof Corp | Surface material for high definition display and high definition display and high definition touch panel having the same |
| JP5071005B2 (en) * | 2007-09-05 | 2012-11-14 | 横浜ゴム株式会社 | Pneumatic tire |
| JP2009061686A (en) * | 2007-09-06 | 2009-03-26 | Teijin Dupont Films Japan Ltd | Antiglare laminate |
| JP5290046B2 (en) * | 2009-05-14 | 2013-09-18 | リンテック株式会社 | Anti-glare hard coat film and polarizing plate using the same |
| JP5690491B2 (en) | 2010-02-24 | 2015-03-25 | リンテック株式会社 | Anti-glare hard coat film and polarizing plate using the same |
| JP2013075955A (en) * | 2011-09-29 | 2013-04-25 | Tomoegawa Paper Co Ltd | Hard coat film |
| JP2013083194A (en) * | 2011-10-07 | 2013-05-09 | Honda Motor Co Ltd | Lubricating oil supply device of internal combustion engine |
| US9079384B2 (en) * | 2011-11-11 | 2015-07-14 | Apple Inc. | Touch sensor panel having an index matching passivation layer |
| JP2013195606A (en) * | 2012-03-19 | 2013-09-30 | Nippon Paper Industries Co Ltd | Antiglare hard coat film |
| CN103205190A (en) * | 2012-08-30 | 2013-07-17 | 湖北航天化学技术研究所 | Ultraviolet-cured anti-dazzle hard film and application thereof |
-
2014
- 2014-03-26 KR KR1020167016985A patent/KR102116291B1/en active IP Right Grant
- 2014-03-26 WO PCT/JP2014/058552 patent/WO2015145618A1/en active Application Filing
- 2014-03-26 JP JP2016509711A patent/JP6603652B2/en active Active
- 2014-03-26 CN CN201480071029.7A patent/CN105874357B/en active Active
-
2015
- 2015-03-12 TW TW104107911A patent/TWI648154B/en active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1498927A (en) * | 2002-10-29 | 2004-05-26 | �յÿ���ʽ���� | Hard coat film |
| CN1636711A (en) * | 2003-12-26 | 2005-07-13 | 琳得科株式会社 | Hard coat film |
| JP2009244305A (en) * | 2008-03-28 | 2009-10-22 | Lintec Corp | Anti-glare hardcoat film and polarizing plate using the same |
| JP2012048099A (en) * | 2010-08-30 | 2012-03-08 | Lintec Corp | Antiglare-antistatic hard coat film and polarizer |
| JP2013083914A (en) * | 2011-09-27 | 2013-05-09 | Nippon Paper Industries Co Ltd | Anti-glare hard coat film |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108070101A (en) * | 2016-11-16 | 2018-05-25 | 琳得科株式会社 | Writing sense improves film |
| CN108070101B (en) * | 2016-11-16 | 2022-08-16 | 琳得科株式会社 | Writing feeling improving film |
| CN110720058A (en) * | 2017-08-04 | 2020-01-21 | 株式会社大赛璐 | Anti-dazzle film |
| CN107868266A (en) * | 2017-11-28 | 2018-04-03 | 上海道助电子科技有限公司 | A kind of low quick-fried surface treatment method and UV film forming materials |
Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2015145618A1 (en) | 2017-04-13 |
| TW201601904A (en) | 2016-01-16 |
| CN105874357B (en) | 2018-08-21 |
| JP6603652B2 (en) | 2019-11-06 |
| KR102116291B1 (en) | 2020-05-29 |
| TWI648154B (en) | 2019-01-21 |
| KR20160137508A (en) | 2016-11-30 |
| WO2015145618A1 (en) | 2015-10-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105874357A (en) | Anti-glare hard coat film | |
| JP6896378B2 (en) | Laminated film and image display device including it | |
| CN109337106B (en) | Hard coating optical film, polarizing plate and image display device | |
| CN103975258B (en) | Device used for image display antiglare sheet | |
| KR101189198B1 (en) | Method for manufacturing anti-reflective coating film | |
| US10338276B2 (en) | Antireflective film, polarizing plate, cover glass, image display device, and method of manufacturing antireflective film | |
| KR101151503B1 (en) | Anti-glare hardcoat film and polarizing plate using the same | |
| TWI491907B (en) | Optical film | |
| KR101719819B1 (en) | An anti-glare hard coat film and a polarizing plate using the same | |
| CN101204697A (en) | Production method of hard coating thin film, hard coating thin film, polarizing disc and image display apparatus | |
| CN107849389A (en) | Coating composition for flexible plastic film | |
| CN102162863B (en) | Anti-dazzle hardness film coating and use the polaroid of this hard coat film | |
| JP2010266658A (en) | Antireflective film and polarizing plate using the same | |
| CN103797385A (en) | Antiglare sheet for image display device, manufacturing method thereof, method of improving black tint and image sharpness of an image display device using said antiglare sheet and suited for use with both moving images and still images | |
| CN106574991B (en) | Antiglare film and image display device | |
| JP5899663B2 (en) | Hard coat layer composition, hard coat film, polarizing plate and image display device | |
| JP5365297B2 (en) | Method for producing hard coat film, hard coat film, polarizing plate and liquid crystal display device | |
| EP3950342A1 (en) | Layered film for molding | |
| TW201413295A (en) | Anti-glare film, polarizing plate and display device | |
| JP2004098303A (en) | Coating composition and hard coat film | |
| KR20060051602A (en) | Optical laminate | |
| JP2013025310A (en) | Anti-glare hard coating film, polarizer having the same, and display device | |
| CN104769460B (en) | Antiglare layer formation composition, antiglare film, Polarizer and display device | |
| KR20080054806A (en) | Anti-glare hard coating sheet and method for manufacturing the same | |
| JPH1020105A (en) | Non-glare sheet |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |