CN103205190A - Ultraviolet-cured anti-dazzle hard film and application thereof - Google Patents
Ultraviolet-cured anti-dazzle hard film and application thereof Download PDFInfo
- Publication number
- CN103205190A CN103205190A CN2012103146487A CN201210314648A CN103205190A CN 103205190 A CN103205190 A CN 103205190A CN 2012103146487 A CN2012103146487 A CN 2012103146487A CN 201210314648 A CN201210314648 A CN 201210314648A CN 103205190 A CN103205190 A CN 103205190A
- Authority
- CN
- China
- Prior art keywords
- weight
- film
- dazzle
- hard coat
- ultraviolet light
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention provides an ultraviolet-cured anti-dazzle hard film and application thereof. The ultraviolet-cured anti-dazzle hard film comprises a transparent supporter and an anti-dazzle hard film coating coated on at least one surface of the transparent supporter. A formula for the coating comprises, by weight, 5 to 90 parts of an ultraviolet-cured resin, 5 to 90 parts of a solvent, 1 to 10 parts of a photoinitiator, 0 to 80 parts of a reactive diluents, 1 to 40 parts of an anti-dazzle particle and 0 to 6 parts of an auxiliary agent. Compared with the prior art, the invention has the following advantages: the ultraviolet-cured resin contains a certain amount of an organic silicon resin, which enables the antifouling property of the surface of the anti-dazzle hard film to be improved; and the selected organic particle has good compatibility with the ultraviolet-cured resin, so transmission loss of light is reduced, which enables clarity of displaying by the anti-dazzle hard film to be improved. The ultraviolet-cured anti-dazzle hard film has good anti-dazzling performance, a good antifouling effect, high hardness, good scratch resistance, excellent flexibility and high resolution.
Description
Technical field
The present invention relates to a kind of as the anti-dazzle hard coat film of ultraviolet light polymerization of protecting kinds of displays and being used as touch-screen.
Background technology
In recent years, various novel flat-plates demonstration (LCD, OLED, EL, PDP) technology and production development are rapid, and the flat pannel display industry has become the important component part of information industry, and flat pannel display industry and market increase just in the world fast.High light or the inner high light that produces are injected human eye around the reflection of various flat-panel monitor outside surfaces, cause easily dazzling fuzzy, can't clear display screen content, this phenomenon becomes dazzle.For solving this class problem, need various display surfaces applyings have been carried out the hard coat film of roughening non-glare treated, reduce dazzle, improve the image quality sharpness.Usually way is to form fine scraggly outside surface on the hard coat film surface, uses refraction or the scattering principle of light, forms the anti-dazzle effect.A kind of is to use physical method to make its surface rough and uneven in surface.Another kind directly adds particulate in the sclerosis coating fluid, coating is solidified, and forms surperficial dimpling concave shape.A kind of mode in back commonly used is produced anti-dazzle hard coat film at present, and this tunic has anti-dazzle and anti-scratch effect simultaneously.
The particulate that adds in the anti-dazzle anti-scratch coating fluid is divided into organic and inorganic two classes, adds and all can play anti-dazzle effect after particulate solidifies.Coating fluid self solidifies back hardness simultaneously needs can reach more than the 3H, plays the anti-scratch effect.Coating mainly is that coating fluid is applied on the plastic film substrate by various wet coating modes, forms through ultraviolet light polymerization.Particle Distribution can not bury fully in coating inside in coating, can't play anti-dazzle effect, can not expose too much, otherwise cause white point, influences transmittance.
UV-light (UV) is coating material solidified to be a kind of environment-friendly and energy-efficient coating of the exploitation sixties in 20th century.The ultraviolet light polymerization system is owing to have higher cross-linking density, coating can be regulated the performance of coating composition needing to obtain as required, inorganic nano metal oxide and organic polymer particulate there is good moisture dispersibility energy, cross-linking density height after UV-irradiation, the light transmission of filming that forms is good, the anti-scratch performance is good, is widely used in the preparation of coating.
Patent CN 101046520A discloses a kind of hard-coated antiglare film, the component of described coating fluid is made up of uv curable oligomer, anti-dazzle particulate, thinner and light trigger, photocuring prepolymer contains polyurethane acrylate resin and (methyl) polyalcohol acrylate resin and (methyl) acid alkyl ester resin, it is characterized in that, coating has outstanding anti-dazzle performance, and coating has good hardness and scratch resistance performance simultaneously.Anti-fouling effect is limited but this is filmed.
Patent CN 101299073A discloses a kind of anti-fouling anti-dazzle film, the component of described coating fluid is made up of uv curable oligomer, inorganic particles, thinner and light trigger, photocuring prepolymer contains polyurethane acrylate resin and organic silicon acrylic ester resin, it is characterized in that, coating has lower surface energy, can reach the good antifouling effect, coating has good flexility and antifouling property simultaneously.But this resistance to marring and scraping and wiping resistance performance are limited, and sharpness is slightly poor.
Summary of the invention
The object of the present invention is to provide a kind of have anti-dazzle can performance and high-res improve the antifouling property of transparent support and the anti-dazzle hard coat film of ultraviolet light polymerization of anti-scratch performance simultaneously.
The present invention also aims to the anti-dazzle hard coat film of above-mentioned ultraviolet light polymerization in the application of the protection of liquid crystal display device and other display devices and touch-screen etc., can improve the demonstration image quality.
In the present invention, except special instruction was arranged, the ratio that adopts among the present invention was weight ratio.
Technical program of the present invention lies in: it comprises a transparent support and is coated in transparent support simultaneously or the anti-dazzle hard coat film coating on the two sides that the prescription of anti-dazzle hard coat film coating and content unit are by weight counted:
UV-cured resin 5-90 weight part
Solvent 5 ~ 90 weight parts
Light trigger 1 ~ 10 weight part
Reactive thinner 0 ~ 80 weight part
Anti-dazzle particle 1 ~ 40 weight part
Auxiliary agent 0 ~ 6 weight part.
The preferred content of the present invention's prescription is:
UV-cured resin 10-70 weight part
Solvent 10 ~ 70 weight parts
Light trigger 2 ~ 7 weight parts
Reactive thinner 5 ~ 60 weight parts
Anti-dazzle particle 5 ~ 20 weight parts
Auxiliary agent 2 ~ 4 weight parts
UV-cured resin contains polyurethane acrylate resin described in the present invention, wherein said UV-cured resin also contains organosilicon-modified acrylate resin and polyester acrylate resin simultaneously, the functionality of described polyurethane acrylate resin is 2～10, viscosity is 60 ℃ of 500～2500cP down, and hardness is 2～8H.
The anti-dazzle hard coat film coating of ultraviolet light polymerization of the present invention in the preferred case, based on the gross weight of described UV-cured resin, the content of described polyurethane acrylate resin is 10 ~ 90 weight %, is preferably 30 ~ 70 weight %; The content of described organosilicon-modified acrylate resin is 5 ~ 60 weight %, is preferably 15 ~ 40 weight %; The content of described polyester acrylate resin is 5 ~ 60 weight %, is preferably 15 ~ 40 weight %.
The described polyurethane acrylate resin of the anti-dazzle hard coat film of ultraviolet light polymerization of the present invention can be in the aliphatic urethane acrylate resin, cycloaliphatic polyurethane acrylate resin and the aromatic urethane acrylate resin that satisfy above-mentioned performance index scope one or more, preferred aliphat polyurethane acrylate resin.Described polyurethane acrylate resin can be commercially available, for example, and 7605,1700,3000 of Japanese synthetic chemistry company; The EB1290 of the special company of cyanogen; The 6145-100 of Changxing, Taiwan company; The UV3600 of middle mountain Chiba Synesis Company; The CN965 of Sartomer company, CN996, CN9006, CN9007, CN9013.
The described organosilicon-modified acrylate resin of the anti-dazzle hard coat film coating of ultraviolet light polymerization of the present invention can be in the organosilicon-modified acrylate resin that satisfies above-mentioned performance index scope one or more.Described organosilicon-modified acrylate resin can be commercially available, for example, and the organosilicon-modified acrylate resin EB350 of Belgian excellent Thebe (UCB) company, six functionality organosilicon-modified acrylate resin EB1360; The polysiloxane aliphatic urethane acrylate resin CN990 of U.S. Sartomer company; The organosilicon modified polyether acrylate resin 6225 of Changxing, Taiwan chemical company.
The described polyester acrylate resin of the anti-dazzle hard coat film coating of ultraviolet light polymerization of the present invention can be in the polyester acrylate resin that satisfies above-mentioned performance index scope one or more.Described polyester acrylate resin can be commercially available, for example, and the CN2281 of Sartomer company, CN2900, CN2295; The OU-740 of Bayer AG; The 6311-100 of Changxing, Taiwan company.
Add anti-dazzle particulate in the anti-dazzle hard coat film coating of ultraviolet light polymerization of the present invention, play anti-dazzle performance.Described anti-dazzle particle is organic fine particles, and is good with organic solvent and resin compatible, and coating is solidified the back coating and had high-res, improves image sharpness.Organic fine particles is the plexiglass particulate, polystyrene resin particulate, vinylformic acid styrene resin particulate, the silicone resin particulate, melamine resin particulate, polyolefin resin particulate, the vibrin particulate, polyimide resin particulate, one or more in the polyamide resin particulate.These organic fine particles can use separately, also can 2 kinds or abovely mix use.Organic anti-dazzle particle provided by the present invention is selected from MBX series, the SSX series that ponding changes into, and combines the products such as MX series that grind chemistry.
Through a large amount of repeatability experimental exploring, used anti-dazzle average particle size is distributed between 0.2 ~ 10 μ m, and the ratio of particulate median size and anti-dazzle hard coat film total coating thickness causes antiglare effect preferably between 0.6 ~ 1.5 the time in anti-dazzle hard coat film.Ratio is lower than 0.6, and particle is imbedded coating, can't play anti-dazzle effect; Ratio is higher than 1.5, and particle is too much exposed, causes white point, influences transmittance.Than the total amount of coating, used anti-dazzle particle content is 1 ~ 40% in the coating formula, can control anti-dazzle hard coat film surface gloss in 90%.Particle content is higher than 40% in the coating formula, system thickness too then, and crawling, and cause that easily particulate reunites; Content is lower than 1%, can't play anti-dazzle effect.
The content of the described UV-cured resin of the anti-dazzle hard coat film coating of ultraviolet light polymerization of the present invention, solvent and light trigger is the content in the conventional ultraviolet-curing paint.In general, gross weight based on described anti-dazzle hard coat film coating formula, the content of described UV-cured resin is 5～90 weight %, preferred 10～70 weight %, and solvent is 5～90 weight %, preferred 10～70 weight %, and photoinitiator levels is 1～10 weight %, be preferably 2～7 weight %.
The anti-dazzle hard coat film of ultraviolet light polymerization of the present invention, described solvent is organic solvent, as known to those skilled in the art, be in hexane, heptane, toluene, dimethylbenzene, ethyl acetate, butylacetate, isobutyl acetate, propyl acetate, methyl alcohol, ethanol, propyl alcohol, Virahol, isopropylcarbinol, propyl carbinol, cyclopentanone, acetone, methylethylketone, butanone, 2 pentanone, pimelinketone, butyl glycol ether, methyl proxitol and the propylene glycol butyl ether one or more.
There is no particular limitation for light trigger kind described in the present invention and consumption, can use various light trigger known in those skilled in the art, for example, st-yrax, the st-yrax methyl ether, the st-yrax dme, the st-yrax ethyl ether, benzoin isobutyl propyl group ether, the st-yrax n-butyl ether, benzoin isobutyl butyl ether, 2-hydroxy-2-methyl-1-phenyl-acetone (Darocur1173), 1-hydroxy-cyclohexyl Propiophenone (Irgacure184), methyl phenyl ketone, the dimethylamino benzoylformaldoxime, 2,2-dimethylamino-2-phenyl methyl phenyl ketone, 2,2-diethoxy-2-phenyl methyl phenyl ketone, 2-methyl isophthalic acid-[4-(methyl sulfo-) phenyl]-2-morpholine-1-acetone (Irgacure907), 2-benzyl-2-dimethylamino-1-(4-morpholine benzyl)-1-butanone, 4-(2-hydroxyl-oxethyl) phenyl-2-(hydroxyl-2-propyl group) ketone, benzophenone, to phenyl benzophenone, 4,4 '-diethylamino benzophenone, benzophenone of dichloro, 2-methylanthraquinone, 2-tertiary butyl anthraquinone, the 2-aminoanthraquinone, isopropyl thioxanthone, 2, in 4, the 6-Three methyl Benzene formyl diphenyl phosphine oxide (TPO) one or more.Described light trigger can be selected from Irgacure651 Irgacure184, Irgacure369, Irgacure754, Irgacure907, Irgacure2022, the Darocur1173 of domestic IHF-PI185, IHT-PI907 and Switzerland vapour Bagong department, among the DarocurMBF one or more.
The anti-dazzle hard coat film of ultraviolet light polymerization of the present invention, in the preferred case, described coating formula also contains reactive thinner, and based on the gross weight of described coating, the content of described reactive thinner is 0～80 weight %.
The anti-dazzle hard coat film of ultraviolet light polymerization of the present invention, adopt described reactive thinner can improve the consistency between the various compositions in the anti-dazzle hard coat film coating formula of ultraviolet light polymerization of the present invention, it is more even that each composition is mixed, also can cooperate several resins in the prescription can better cross-linking and curing reaction, in the process of solidifying, improve the degree of crosslinking of coating, make the formed paint film of coating of the present invention have good hardness and sticking power.Reactive thinner provided by the present invention is selected from one or more among Dipentaerythritol five acrylate DPPA, dipentaerythritol acrylate DPHA, Viscoat 295 TMPTA, pentaerythritol triacrylate PETA, 1,6 hexylene glycol acrylate HDDA, the tripropylene glycol diacrylate TPGDA.
In the anti-dazzle hard coat film of ultraviolet light polymerization of the present invention, also contain auxiliary agent in the preferred case, the content of described auxiliary agent is 0～6 weight %.According to anti-scratch coating formula provided by the invention, described auxiliary agent can be selected for use and well known to a person skilled in the art various auxiliary agents, and this auxiliary agent can be selected one or more in flow agent, defoamer, the dispersion agent for use.
According to the anti-dazzle hard coat film coating formula of ultraviolet light polymerization provided by the invention, the content of described various auxiliary agents is for well known to a person skilled in the art, in the preferred case, gross weight based on prescription, described flow agent content is 0～2 weight %, preferred 0.2～1.5 weight %, the content of described defoamer is 0～2 weight %, preferred 0.2～1.5 weight %, the content of described dispersion agent is 0～2 weight %, preferred 0.2～1.5 weight %, the content of described coupling agent is 0～7 weight %, preferred 1～5 weight %, the content of described tensio-active agent are 0～5 weight %, preferred 1～3 weight %.
The anti-dazzle hard coat film of ultraviolet light polymerization of the present invention, described dispersion agent are the various material that can improve described matrix resin dispersion state in solvent known in those skilled in the art, can select polyurethanes or graft acrylic acid copolymer analog for use.For example, described dispersion agent can be selected CFC-500HP, the CFC-510 of Kerper-602, Kerper-605, the Kerper-630 of the U.S. Kerper company that is purchased, French CFC company, among CFC-637, the CFC-604S one or more for use;
The anti-dazzle hard coat film of ultraviolet light polymerization of the present invention, the kind of described flow agent are as well known to those skilled in the art, and can select fluorine system or silicon for use is flow agent.For example, described flow agent can be selected EFKA-3883, the EFKA3600 of the Dutch Ai Fuka company that is purchased for use, the BYK-353 of BYK company, BYK-361 and BYK-UV3570, the DEGO410 of Germany Di Gao company, the CoatOSil 1211 of organosilicon company of General Electric Toshiba, among the CoatOSil 2400 one or more.
The anti-dazzle hard coat film of ultraviolet light polymerization of the present invention, the kind of described defoamer are known in those skilled in the art, can select silicon class or polyether-modified silicon defoamer for use.For example, described defoamer can be selected EFKA2022, EFKA2527 and the EFKA2040 of the Dutch Ai Fuka company that is purchased for use, the BYK-053 of BYK company, BYK-057, BYK-060 and BYK-066, the CoatOSil 3501 of organosilicon company of General Electric Toshiba, among the CoatOSil 7510 one or more.
The anti-dazzle hard coat film of ultraviolet light polymerization of the present invention, the kind of described dispersion agent are known in those skilled in the art, can select polyurethanes or graft acrylic acid copolymer analog for use.For example, described dispersion agent can be selected CFC-500HP, the CFC-510 of Kerper-602, Kerper-605, the Kerper-630 of the U.S. Kerper company that is purchased, French CFC company, among CFC-637, the CFC-604S one or more for use.
The anti-dazzle hard coat film of ultraviolet light polymerization of the present invention, owing in the coated coating prescription, add organic anti-dazzle particulate, thereby increase the anti-dazzle performance of filming, organic fine particles and solvent and UV-cured resin have good consistency, thereby can improve the coating display resolution.Contain the organic silicon acrylic ester resin in the UV-cured resin, can reduce the surface energy of ultraviolet light polymerization hard coat film of the present invention well, thereby can reach the good antifouling effect.It is 500～2500cP that the present invention has adopted 60 ℃ of following viscosity, and functionality is 2～10, and hardness is the polyurethane acrylate resin of 2～8H, can improve the over-all properties by the formed paint film of coating of the present invention, has rub resistance energy preferably.Owing in matrix resin, also contain the polyester acrylate resin, can well remedy the relatively poor problem of snappiness, sticking power that causes when polyurethane acrylate resin solidifies, particularly be applied to the polyester plastics film surface, can well improve adhesive force of coatings.Organosilicon-modified acrylate resin and polyurethane acrylate resin are used under certain conditions, and make and can reach the good antifouling effect by formed water-fast, oil resistant and the self-cleaning performance preferably of having filmed of gained coating of the present invention.Simultaneously higher hardness is arranged again, have the rub resistance energy thereby make to film.
There is no particular limitation for the transparent support that uses among the present invention, can select to use from the plastics film that uses as existing optics.The transmittance of the preferred visible light of transparent support outstanding (preferred transmittance is more than 90%) and the outstanding material (the preferred film haze value is below 1%) of the transparency.Example as this plastics film comprises: as polyethylene terephthalate, as polybutylene terephthalate and poly (ethylene naphthalate) film, polyethylene film; polypropylene film; glassine paper, diacetyl cellulose film, tri acetyl cellulose film; butyric acid ethanoyl cellulosefilm; polyvinyl chloride film, polyvinylidene chloride film, PVA (PVOH) FILM; the ethylene-vinyl acetate copolymer film; polystyrene film, polycarbonate film, poly-methyl pentene film; polysulphone film; poly (ether ether ketone) film, polyetherimide film, Kapton; fluorine resin film, polyamide layer.
Thickness to transparent support has no particular limits, and can according to circumstances suitably select.Common described thickness is between 10～500 μ m, preferably in the scope of 20～300 μ m, most preferably in the scope of 30～200 μ m.
When needed, can one or two surface of transparent support be handled by handling, in order to strengthen the adhesion of going up each layer with the surface.For example utilize Corona discharge Treatment, plasma treatment is utilized the processing (wet method) of chromic acid, utilizes the processing of flame, utilizes to add the processing of warm air, or utilizes ultraviolet irradiation to handle in the presence of ozone.Surface treatment is carried out appropriate selection according to the kind of transparent support, considers preferred Corona discharge Treatment usually from effect and operability.
The method of producing the anti-dazzle hard coat film of ultraviolet light polymerization provided by the invention is as follows:
Be added in the container according to its mutually deserved weight fraction according to each component in the anti-dazzle hard coat film coating formula of ultraviolet light polymerization provided by the present invention and stir, obtain coating fluid, coating fluid is coated on the transparent support, by ultraviolet light polymerization, obtains the anti-dazzle hard coat film of ultraviolet light polymerization.
The coating process of coating fluid has no particular limits, and can use conventional method, and for example rod is coated with method, the scraper coating method, and rolling method, scraper plate coating method and intaglio plate coating method form coating.
The ultraviolet ray of solidifying as the anti-dazzle hard coat film coating of ultraviolet light polymerization of the present invention medium ultraviolet light-cured resin can obtain from high voltage mercury lamp, usually, is used for the UV-light dosage of irradiation at 100～500mj/cm
2Scope in.
The present invention obtains anti-dazzle hard coat film coating by one or two surface coating uV curable compositions at transparent support, described UV-cured resin composition is the polyester acrylate resin, polyurethane acrylate resin and organic silicon acrylic ester resin reasonable combination.
Medium ultraviolet light-cured resin of the present invention contains a certain amount of silicone resin, thereby improves anti-dazzle hard coat film surface depolluting properties, is embodied in water contact angle greater than 100 °; Select for use organic fine particles and UV-cured resin that good consistency is arranged, can reduce the loss that sees through of light, thereby improve anti-dazzle hard coat film display resolution, 60 ° of glossiness of this anti-dazzle hard coat film are less than 90%.
Compared with prior art, the invention has the advantages that: the anti-dazzle hard coat film coating of ultraviolet light polymerization of the present invention is used for transparent support, make transparent support have outstanding anti-dazzle, anti scuffing and antifouling property, have enough hardness, lower surface energy simultaneously, good sticking power, flexility and properties of transparency.
Adopt the mode of embodiment that the present invention is described in further detail below.Yet, the invention is not restricted to these embodiment.For ease of comparing, the present invention selects polyethylene terephthalate thin film (Korea S SKC product) to experimentize as transparent support, wherein tests treated side and handles through primary coat.
Embodiment
Embodiment 1
20 parts of polyurethane acrylate resins
10 parts of organosilicon-modified acrylate resins
20 parts of polyester acrylate resins
10 parts of plexiglass particulates
184 8 parts of Irgacure
60 parts of toluene: methyl proxitol=1:1
(toluene: methyl proxitol=1:1) add 10 weight part plexiglass particulates (median size 5 μ m, ponding change into company and produce, trade mark MB20X-5) mixes to 60 weight part mixed solvents.To wherein adding 20 weight part polyurethane acrylate resins (U.S.'s Sartomer product, the trade mark is CN9006), 10 weight part organosilicon-modified acrylate resin (U.S.'s Sartomer products, the trade mark is CN990) and 20 weight part polyester acrylate resin (U.S.'s Sartomer products, the trade mark is CN2281), mixing and stirring.In mixed solution, add 8 weight part light triggers (Irgacure 184), 1.5 weight part flow agent (BYK-UV3570, BYK company), 1.5 weight part defoamer (BYK-053, BYK company), 1.5 weight part dispersion agent (Kerper-602, U.S. Kerper company) mixes, and makes coating fluid.
Made coating fluid is applied to the polyethylene terephthalate thin film that transparent support thickness is 100 μ m (Korea S SKC product) handles one side through primary coat, between 60～80 ℃ to after dry 1 minute of the coating that forms, with 300mj/cm
2Ultraviolet irradiating dose the coating of drying is cured, and form the anti-dazzle hard coat film of ultraviolet light polymerization, the thickness of anti-scratch coating is 6 microns.Survey its performance, the results are shown in table 1.
Embodiment 2
20 parts of polyurethane acrylate resins
20 parts of organosilicon-modified acrylate resins
10 parts of polyester acrylate resins
15 parts of polystyrene resin particulates
20 parts of dipentaerythritol acrylate DPHA
12 parts of Darocur1173
40 parts of propyl alcohol.
(toluene: methyl proxitol=1:1) add 15 weight part polystyrene resin particulates (median size 6 μ m, ponding change into company and produce, trade mark SBX-6) mixes to 40 weight part mixed solvents.To wherein adding 20 weight part polyurethane acrylate resins (U.S.'s Sartomer product, the trade mark is CN9013), 20 weight part organosilicon-modified acrylate resin (U.S.'s Sartomer products, the trade mark is CN990) and 10 weight part polyester acrylate resin (U.S.'s Sartomer products, the trade mark is CN2295), mixing and stirring.In mixed solution, add 12 weight part light triggers (Darocur1173), 2 weight part flow agent (EFKA-3883, Holland Ai Fuka company), 1 weight part defoamer (EFKA2022, Holland Ai Fuka company), 1 weight part dispersion agent (Kerper-630, U.S. Kerper company), mix, make coating fluid.
Implementation method is surveyed its performance with embodiment 1, the results are shown in table 1.
Embodiment 3
20 parts of polyurethane acrylate resins
10 parts of organosilicon-modified acrylate resins
10 parts of polyester acrylate resins
20 parts of Viscoat 295 TMPTA
20 parts of plexiglass particulates
10 parts of Irgacure369:Irgacure907=1:1
50 parts of ethyl acetate.
In 50 parts by weight solvent ethyl acetate, add 20 weight part plexiglass particulates (median size 10 μ m, ponding change into company and produce, trade mark MB20X-10), mix.To wherein adding 20 weight part polyurethane acrylate resins (Changxing, Taiwan chemical company, trade mark 6145-100), 10 weight part organosilicon-modified acrylate resin (Changxing, Taiwan chemical companies, the trade mark 6225) and 10 weight part polyester acrylate resin (Changxing, Taiwan chemical companies, trade mark 6311-100), and 20 weight part Viscoat 295 TMPTA, mix.In mixed solution, add 10 weight part light triggers (Irgacure369:Irgacure907=1:1), mix, make coating fluid.
Implementation method is surveyed its performance with embodiment 1, the results are shown in table 1.
Embodiment 4
20 parts of polyurethane acrylate resins
10 parts of organosilicon-modified acrylate resins
20 parts of polyester acrylate resins
Plexiglass particulate: 20 parts of polystyrene resin particulates (1:1)
20 parts of pentaerythritol triacrylate PETA
15 parts of Irgacure2022
40 parts of pimelinketone.
In 40 parts by weight solvent pimelinketone, add plexiglass particulate and polystyrene resin particulate (weight ratio is 1:1, and median size is respectively 2 μ m and 6 μ m, and the trade mark is respectively SSX-102 and SBX-6) respectively, mix.To wherein adding 20 weight part polyurethane acrylate resins (Japanese synthetic chemistry company, the trade mark is 1700), 10 weight part organosilicon-modified acrylate resins (Belgian excellent Thebe (UCB) company, the trade mark is EB350) and 20 weight part polyester acrylate resin (Bayer AG, trade mark OU-740), add 20 weight part pentaerythritol triacrylate PETA, mix.In mixed solution, add 15 weight part light trigger (Irgacure2022, Switzerland vapour Bagong department), 1 weight part flow agent (EFKA-3883, Holland Ai Fuka company), 1 weight part defoamer (EFKA2022, Dutch Ai Fuka company), 1 weight part dispersion agent (U.S. Kerper company, Kerper-630) mix, make coating fluid.
Implementation method is surveyed its performance with embodiment 1, the results are shown in table 1.
Embodiment 5
10 parts of polyurethane acrylate resins
20 parts of organosilicon-modified acrylate resins
10 parts of polyester acrylate resins
20 parts of plexiglass particulates
40 parts of tripropylene glycol diacrylate TPGDA
184 7 parts of Irgacure
30 parts of ethyl acetate
In 30 parts by weight solvent ethyl acetate, add 20 weight part plexiglass particulates (median size 5 μ m, combine and grind chemical company's production, trade mark MX500), stir, add 10 weight part polyurethane acrylate resins (Changxing, Taiwan chemical company, trade mark 6145-100), 20 weight part organosilicon-modified acrylate resin (Changxing, Taiwan chemical companies, the trade mark 6225) and 10 weight part polyester acrylate resin (Changxing, Taiwan chemical companies, trade mark 6311-100), add 40 weight part tripropylene glycol diacrylate TPGDA, mix.In mixed solution, add 7 weight part light triggers (Irgacure 184), the flow agent of 1 weight part (BYK company, BYK-361), the defoamer of 1 weight part (organosilicon company of General Electric Toshiba, CoatOSil 3501), (French CFC company CFC-500HP) mixes 2 weight part dispersion agents, makes coating fluid.
Implementation method is surveyed its performance with embodiment 1, the results are shown in table 1.
Comparative Examples 1
20 parts of polyurethane acrylate resins
20 parts of plexiglass particulates
40 parts of dipentaerythritol acrylate DPHA
184 6 parts of Irgacure
Thinner (toluene: methyl proxitol=1:1) 40 parts.
(toluene: methyl proxitol=1:1) adds 20 weight part plexiglass particulates (median size 5 μ m to 40 weight part mixed solvents, ponding changes into company and produces, trade mark MB20X-5), stir, add 20 weight part polyurethane acrylate resins (U.S.'s Sartomer product, the trade mark is CN9013), add 40 weight part dipentaerythritol acrylate DPHA, mix.In mixed solution, add 6 weight part light triggers (Irgacure 184), 1.5 the flow agent of weight part (BYK company, BYK-UV3570), 1.5 the defoamer of weight part (BYK company, BYK-053), 1.5 (U.S. Kerper company Kerper-602) mixes the weight part dispersion agent, makes coating fluid.
Implementation method is surveyed its performance with embodiment 1, the results are shown in table 1.
Comparative Examples 2
20 parts of organosilicon-modified acrylate resins
40 parts of polyester acrylate resins
5 parts of plexiglass particulates
12 parts of Darocur1173
40 parts of propyl alcohol.
In 40 parts by weight solvent propyl alcohol, add plexiglass particulate (median size 5 μ m, combine and grind chemical company's production, trade mark MX500), stir, add 20 weight part organosilicon-modified acrylate resin (U.S.'s Sartomer products, the trade mark is CN990) and 40 weight part polyester acrylate resin (U.S.'s Sartomer products, the trade mark is CN2281), stir, and add 12 weight part light triggers (Darocur1173, Switzerland vapour Bagong department), 1 weight part flow agent (EFKA-3883, Holland Ai Fuka company), 2 weight part defoamers (EFKA2022, Dutch Ai Fuka company), 1 weight part dispersion agent (U.S. Kerper company, Kerper-630) mix, make coating fluid.
Implementation method is surveyed its performance with embodiment 1, the results are shown in table 1.
Comparative Examples 3
10 parts of organosilicon-modified acrylate resins
20 parts of dipentaerythritol acrylate DPHA
20 parts of plexiglass particulates
10 parts of Irgacure907
40 parts of Virahols.
Add 20 weight part plexiglass particulates (median size 15 μ m to 40 parts by weight solvent Virahols, ponding changes into company and produces, trade mark MBX-12), stir, add 40 weight part organosilicon-modified acrylate resin (U.S.'s Sartomer products, the trade mark is CN990), add 20 weight part dipentaerythritol acrylate DPHA, mix.Add the light trigger (Irgacure907) of 10 weight parts in the mixed solution, mix, make coating fluid.
Implementation method is surveyed its performance with embodiment 1, the results are shown in table 1.
Performance test
The anti-dazzle hard coat film of ultraviolet light polymerization of embodiment 1～5 and Comparative Examples 1～3 gained is tested.Survey its performance, the results are shown in table 1.Every performance in the table adopts following measuring method.
(1) sticking power
According to stipulating among the standard A STMD3359, utilize hundred lattice methods test film adhesive.As being 5B without any delamination, the delamination amount is 4B between 0-5%, is 3B between 5～15%, is 2B between 15～35%, is 1B between 35～65%, is 0B more than 65%.
(2) ratio of thickness and particle diameter
According to stipulating among the standard A STM D374, test the anti-dazzle hard coat film coat-thickness of ultraviolet light polymerization (the Jinan blue streak is produced, model C HY-CA) with the high precision thickness tester.U.S. BECKMAN COULTER LS series laser particle size analyzer utilizes particulate scattered light analytical technology principle, measures diameter of particle with dry method, then the ratio of particle diameter with coat-thickness is calculated.
(3) pencil hardness test
Carry out according to chapter 4 regulation among the standard GB/6739, (Tianjin material-testing machine factory of smart section makes model: the anti-dazzle hard coat film coating hardness of test ultraviolet light polymerization portable pencil hardness meter QHQ-A) to utilize the hardness of film tester of swiping by pencil.
(4) scratch resistance performance
The scratch resistance performance of filming is generally tested with Steel Wool, with steel wool #0000 with 500g power and constant speed (about 100mm/s) the anti-dazzle hard coat film coatingsurface of wiping ultraviolet light polymerization back and forth, and the surface appearance that detects by an unaided eye.When occurring the tangible cut in first road from the teeth outwards, the wiping number of times when record cut occurs at this moment characterizes the scratch resistance performance.General number of times is better greater than 10 scratch resistance performances.
(5) fingerprint antifouling property test
With the anti-dazzle hard coat film of ultraviolet light polymerization back side applying black acrylic panel (20 microns of tackiness agent bed thickness, thickness of slab 2mm), make the experiment slice of no backside reflection.The anti-dazzle hard coat film coating of ultraviolet light polymerization faces up.To point and slowly be pressed in above the anti-dazzle hard coat film coating, whether have fingerprint stay, judge antifouling property if observing.Concrete standard is as follows: A: no fingerprint is residual.B: show slight fingerprint, easily wiping.C: fingerprint is arranged, erasable.D: fingerprint is arranged, be difficult to wiping.
(6) anti-dazzle performance test
With the anti-dazzle hard coat film of ultraviolet light polymerization back side applying black acrylic panel (20 microns of tackiness agent bed thickness, thickness of slab 2mm), make the experiment slice of no backside reflection.The anti-dazzle hard coat film coating of ultraviolet light polymerization faces up, and lies in a horizontal plane under the common working environment, from become 30 ° of angular direction visual observations with level, judges anti-dazzle performance.Concrete standard is as follows:
One white blur: A: there is not white blur substantially, visual good.B: white blur does not slightly influence clarity.C: white blur, slightly influential clarity.D: white blur influences observing effect.
Two image reflections: A: do not have image reflection substantially.B: image reflection is arranged, do not influence observing effect.C: image reflection is arranged, slightly influence observing effect.D has image reflection, influences observing effect.
(7) transmittance/mist degree
According to regulation among the standard A STMD 1003, (exact science instrument company in Shanghai makes, model: WGT-S), measure transmittance and the mist degree of the anti-dazzle hard coat film of ultraviolet light polymerization to utilize transmittance mist degree instrument.
(8) 60 ° of glossiness
According to stipulating among the standard GB/T9754, utilize the intelligent Grossmeters of JFL that the anti-dazzle hard coat film coating of ultraviolet light polymerization is carried out 60 ° of glossiness tests.(the Tianjin gold inspires confidence in Lun Science ﹠ technology Co., Ltd, model: JFL-BZ206084).
(9) contact angle
According to regulation among the standard A STM 7490, use the Data physics OCA of company series contact angle measurement to record the hard anti-dazzle static contact angle that is coated with film coating and water of ultraviolet light polymerization.
Calculate the result.Table 1
By the result shown in the table 1 as can be seen, ultraviolet light polymerization hard coat film provided by the present invention has anti-dazzle performance preferably, has scratch resistance performance and antifouling property and snappiness and high-res preferably simultaneously.
Claims (13)
1. anti-dazzle hard coat film of ultraviolet light polymerization is characterized in that it comprises a transparent support and is coated in anti-dazzle hard coat film coating on the transparent support one side at least, and the prescription of anti-dazzle hard coat film coating and content unit are by weight counted:
UV-cured resin 5-90 weight part
Solvent 5 ~ 90 weight parts
Light trigger 1 ~ 10 weight part
Reactive thinner 0 ~ 80 weight part
Anti-dazzle particle 1 ~ 40 weight part
Auxiliary agent 0 ~ 6 weight part.
2. the anti-dazzle hard coat film of ultraviolet light polymerization according to claim 1, it is characterized in that: the content of described anti-dazzle hard coat film coating formula is:
UV-cured resin 10-70 weight part
Solvent 10 ~ 70 weight parts
Light trigger 2 ~ 7 weight parts
Reactive thinner 5 ~ 60 weight parts
Anti-dazzle particle 5 ~ 20 weight parts
Auxiliary agent 2 ~ 4 weight parts.
3. the anti-dazzle hard coat film of ultraviolet light polymerization according to claim 1 and 2, it is characterized in that: described UV-cured resin contains polyurethane acrylate resin, contains organosilicon-modified acrylate resin and polyester acrylate resin simultaneously.
4. the anti-dazzle hard coat film of ultraviolet light polymerization according to claim 3, it is characterized in that: based on the gross weight of described UV-cured resin, the content of described polyurethane acrylate resin is 10 ~ 90 weight %, is preferably 30 ~ 70 weight %; The content of described organosilicon-modified acrylate resin is 5 ~ 60 weight %, is preferably 15 ~ 40 weight %; The content of described polyester acrylate resin is 5 ~ 60 weight %, is preferably 15 ~ 40 weight %.
5. the anti-dazzle hard coat film of ultraviolet light polymerization according to claim 1 and 2, it is characterized in that: described anti-dazzle particle is one or more in plexiglass particulate, polystyrene resin particulate, vinylformic acid styrene resin particulate, silicone resin particulate, melamine resin particulate, polyolefin resin particulate, vibrin particulate, polyimide resin particulate, the polyamide resin particulate.
6. the anti-dazzle hard coat film of ultraviolet light polymerization according to claim 1 and 2, it is characterized in that: used anti-dazzle average particle size is distributed between 0.2 ~ 10 μ m; And the particulate median size with the ratio of coat-thickness is: 0.6 ~ 1.5.
7. the anti-dazzle hard coat film of ultraviolet light polymerization according to claim 1 and 2, it is characterized in that: described solvent is one or more in hexane, heptane, toluene, dimethylbenzene, ethyl acetate, butylacetate, isobutyl acetate, propyl acetate, methyl alcohol, ethanol, propyl alcohol, Virahol, isopropylcarbinol, propyl carbinol, cyclopentanone, acetone, methylethylketone, 2 pentanone, pimelinketone, butyl glycol ether, methyl proxitol and the propylene glycol butyl ether.
8. the anti-dazzle hard coat film of ultraviolet light polymerization according to claim 1 and 2, it is characterized in that: described light trigger is st-yrax, the st-yrax methyl ether, the st-yrax dme, the st-yrax ethyl ether, benzoin isobutyl propyl group ether, the st-yrax n-butyl ether, benzoin isobutyl butyl ether, 2-hydroxy-2-methyl-1-phenyl-acetone, 1-hydroxy-cyclohexyl Propiophenone, methyl phenyl ketone, the dimethylamino benzoylformaldoxime, 2,2-dimethylamino-2-phenyl methyl phenyl ketone, 2,2-diethoxy-2-phenyl methyl phenyl ketone, 2-methyl isophthalic acid-[4-(methyl sulfo-) phenyl]-2-morpholine-1-acetone, 2-benzyl-2-dimethylamino-1-(4-morpholine benzyl)-1-butanone, 4-(2-hydroxyl-oxethyl) phenyl-2-(hydroxyl-2-propyl group) ketone, benzophenone, to phenyl benzophenone, 4,4 '-diethylamino benzophenone, benzophenone of dichloro, 2-methylanthraquinone, 2-tertiary butyl anthraquinone, the 2-aminoanthraquinone, isopropyl thioxanthone, 2,4, in the 6-Three methyl Benzene formyl diphenyl phosphine oxide (TPO) one or more, or IHF-PI185, IHT-PI907, the Irgacure651 Irgacure184 of Switzerland vapour Bagong department, Irgacure369, Irgacure754, Irgacure907, Irgacure2022, Darocur1173, among the DarocurMBF one or more.
9. the anti-dazzle hard coat film of ultraviolet light polymerization according to claim 1 and 2, it is characterized in that: described reactive thinner is Dipentaerythritol five acrylate, dipentaerythritol acrylate, Viscoat 295, pentaerythritol triacrylate, 1, one or more in 6-hexylene glycol acrylate and the tripropylene glycol diacrylate.
10. the anti-dazzle hard coat film of ultraviolet light polymerization according to claim 1 and 2, it is characterized in that: described auxiliary agent is one or more in flow agent, defoamer, the dispersion agent, and the gross weight based on the anti-dazzle hard coat film coating formula of ultraviolet light polymerization, described flow agent content is 0～2 weight %, preferred 0.2～1.5 weight %; The content of described defoamer is 0～2 weight %, preferred 0.2～1.5 weight %; The content of described dispersion agent is 0～2 weight %, preferred 0.2～1.5 weight %.
11. the anti-dazzle hard coat film of ultraviolet light polymerization according to claim 10, it is characterized in that: described flow agent is that fluorine system or silicon are flow agent, EFKA-3883, EFKA-3886, EFKA3600 for Dutch Ai Fuka company, the BYK-353 of BYK company, BYK-361, BYK-UV3570, the DEGO410 of German Di Gao company, the CoatOSil 1211 of organosilicon company of General Electric Toshiba, among the CoatOSil 2400 one or more; Defoamer is silicon class or polyether-modified silicon defoamer, be EFKA2022, EFKA2527, the EFKA2040 of Dutch Ai Fuka company, the CoatOSil 3501 of the BYK-053 of BYK company, BYK-055, BYK-057, BYK-060, BYK-066, organosilicon company of General Electric Toshiba, among the CoatOSil 7510 one or more; Dispersion agent is polyurethanes or graft acrylic acid copolymer analog, is CFC-500HP, the CFC-510 of Kerper-602, the Kerper-605 of U.S. Kerper company, Kerper-630, French CFC company, among CFC-637, the CFC-604S one or more.
12. the anti-dazzle hard coat film of ultraviolet light polymerization according to claim 1; it is characterized in that: described transparent support is polyethylene terephthalate; polybutylene terephthalate and poly (ethylene naphthalate) film; polyethylene film; polypropylene film; glassine paper; the diacetyl cellulose film, tri acetyl cellulose film, butyric acid ethanoyl cellulosefilm; polyvinyl chloride film; the polyvinylidene chloride film, PVA (PVOH) FILM, ethylene-vinyl acetate copolymer film; polystyrene film; polycarbonate film, poly-methyl pentene film, polysulphone film; poly (ether ether ketone) film; polyetherimide film, Kapton, fluorine resin film or polyamide layer.
13. the anti-dazzle hard coat film of the described ultraviolet light polymerization of arbitrary claim is in the protection of liquid crystal display device and display device and the application of touch-screen in the claim 1 ~ 12.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103146487A CN103205190A (en) | 2012-08-30 | 2012-08-30 | Ultraviolet-cured anti-dazzle hard film and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103146487A CN103205190A (en) | 2012-08-30 | 2012-08-30 | Ultraviolet-cured anti-dazzle hard film and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103205190A true CN103205190A (en) | 2013-07-17 |
Family
ID=48752601
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012103146487A Pending CN103205190A (en) | 2012-08-30 | 2012-08-30 | Ultraviolet-cured anti-dazzle hard film and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103205190A (en) |
Cited By (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103540183A (en) * | 2013-10-27 | 2014-01-29 | 合肥乐凯科技产业有限公司 | Anti-fingerprint transparent hardening film for touch screen |
| CN103792789A (en) * | 2014-01-27 | 2014-05-14 | 京东方科技集团股份有限公司 | Photoresist composition |
| CN104109432A (en) * | 2014-07-28 | 2014-10-22 | 广西梧州龙鱼漆业有限公司 | Ultraviolet curing paint |
| CN104293052A (en) * | 2014-09-26 | 2015-01-21 | 锐展(铜陵)科技有限公司 | Energy-saving waterproof coating for exterior trim of automobile |
| CN105038570A (en) * | 2015-07-14 | 2015-11-11 | 深圳市汇万川塑胶薄膜有限公司 | Highly scratch-resistant anti-dazzle ultraviolet-curable coating and application method therefor |
| CN105315879A (en) * | 2014-07-11 | 2016-02-10 | 湖北航天化学技术研究所 | High definition ultraviolet (UV) cured antidazzle hard film |
| CN105353431A (en) * | 2015-12-02 | 2016-02-24 | 合肥乐凯科技产业有限公司 | Basal membrane of composite brightness enhancement film |
| CN105482683A (en) * | 2016-01-26 | 2016-04-13 | 江苏海田技术有限公司 | Anti-fouling UV cured resin coating for LCD screen |
| CN105505199A (en) * | 2016-01-26 | 2016-04-20 | 江苏海田技术有限公司 | Anti-dazzle UV curing resin coating for LCD display screen |
| CN105524563A (en) * | 2014-09-30 | 2016-04-27 | 湖北航天化学技术研究所 | Blue-light-barrier anti-dazzle optical film and preparation method therefor |
| CN105566963A (en) * | 2015-12-25 | 2016-05-11 | 佛山佛塑科技集团股份有限公司 | Non-glare coating and non-glare membrane |
| CN105647375A (en) * | 2016-01-26 | 2016-06-08 | 江苏海田技术有限公司 | UV curing resin paint for LCD screen |
| CN105860724A (en) * | 2016-05-06 | 2016-08-17 | 安徽和润特种玻璃有限公司 | Transparent stain-resistant ageing-resistant thermal-insulation anti-dazzle glass coating |
| CN105907275A (en) * | 2016-05-06 | 2016-08-31 | 安徽和润特种玻璃有限公司 | High-hardness and high-toughness anti-corrosion non-glare glass film |
| CN106147357A (en) * | 2015-06-02 | 2016-11-23 | 湖北航天化学技术研究所 | A kind of light absorptive anti-glare hard coating film and its preparation method and application |
| CN106932998A (en) * | 2015-12-31 | 2017-07-07 | 深圳超多维光电子有限公司 | A kind of light-splitting device and 3 d display device |
| CN107177301A (en) * | 2016-05-19 | 2017-09-19 | 湖北航天化学技术研究所 | A kind of sustainable slow-release fragrance anti-glare hardened film and its application |
| CN107236426A (en) * | 2017-06-28 | 2017-10-10 | 太仓市美航涂料有限公司 | A kind of high rigidity plated film UV finish paints |
| CN107641454A (en) * | 2017-08-24 | 2018-01-30 | 张家港康得新光电材料有限公司 | Anti- precipitation PET optical thin films and its application |
| CN107641455A (en) * | 2017-09-27 | 2018-01-30 | 芜湖春风新材料有限公司 | A kind of automotive upholstery anti-fingerprint UV coating, preparation method and applications |
| CN108047852A (en) * | 2017-12-14 | 2018-05-18 | 合肥乐凯科技产业有限公司 | A kind of polyester film |
| CN108690209A (en) * | 2017-03-07 | 2018-10-23 | 宁波惠之星新材料科技有限公司 | A kind of anti-dazzle optical coating of UV resistant and its application |
| TWI648154B (en) * | 2014-03-26 | 2019-01-21 | 日商琳得科股份有限公司 | Anti-glare hard coat film |
| CN109385163A (en) * | 2018-09-27 | 2019-02-26 | 合众（佛山）化工有限公司 | A kind of PEEK modified acroleic acid full-shield infrared ray and ultraviolet light water transparent heat insulation paint |
| CN109554009A (en) * | 2018-06-08 | 2019-04-02 | 湖南阳光新材料有限公司 | One kind being convenient for the clean water-repellent paint of carbody shell |
| CN110802796A (en) * | 2019-11-11 | 2020-02-18 | 熊何宇 | Preparation method of high-performance in-mold injection molding panel |
| CN112034685A (en) * | 2020-09-01 | 2020-12-04 | 珠海市能动科技光学产业有限公司 | High-resolution dry film photoresist |
| CN114437616A (en) * | 2022-03-17 | 2022-05-06 | 惠州市日大实业有限公司 | Fingerprint-resistant high-solid low-viscosity wear-resistant ceramic-like photocureable coating and preparation method thereof |
| CN114805896A (en) * | 2022-05-18 | 2022-07-29 | 苏州诺菲纳米科技有限公司 | Anti-glare protective film and preparation method thereof |
| CN115386270A (en) * | 2021-12-23 | 2022-11-25 | 南通恒华粘合材料科技有限公司 | Wear-resistant scratch-resistant anti-glare coating for UV (ultraviolet) type glass and preparation method thereof |
| CN117625035A (en) * | 2024-01-26 | 2024-03-01 | 广州申威新材料科技有限公司 | Anti-dazzle anti-reflection coating, composite film, preparation method and application |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1746702A (en) * | 2005-09-30 | 2006-03-15 | 中国乐凯胶片集团公司 | Anti-dazzle thin-membrane and production thereof |
| CN101046520A (en) * | 2006-03-28 | 2007-10-03 | 日东电工株式会社 | Hard-coated antiglare film, method of manufacturing the same, optical device, polarizing plate, and image display |
| CN101299073A (en) * | 2008-07-02 | 2008-11-05 | 中国乐凯胶片集团公司 | Anti-fouling anti-dazzle film |
| CN101825729A (en) * | 2010-05-11 | 2010-09-08 | 中国乐凯胶片集团公司 | Anti-glare hardened film for in-mold decoration |
| CN102236113A (en) * | 2010-05-01 | 2011-11-09 | 中国航天科技集团公司第四研究院第四十二所 | Ultraviolet-cured hard coating and application thereof |
-
2012
- 2012-08-30 CN CN2012103146487A patent/CN103205190A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1746702A (en) * | 2005-09-30 | 2006-03-15 | 中国乐凯胶片集团公司 | Anti-dazzle thin-membrane and production thereof |
| CN101046520A (en) * | 2006-03-28 | 2007-10-03 | 日东电工株式会社 | Hard-coated antiglare film, method of manufacturing the same, optical device, polarizing plate, and image display |
| CN101299073A (en) * | 2008-07-02 | 2008-11-05 | 中国乐凯胶片集团公司 | Anti-fouling anti-dazzle film |
| CN102236113A (en) * | 2010-05-01 | 2011-11-09 | 中国航天科技集团公司第四研究院第四十二所 | Ultraviolet-cured hard coating and application thereof |
| CN101825729A (en) * | 2010-05-11 | 2010-09-08 | 中国乐凯胶片集团公司 | Anti-glare hardened film for in-mold decoration |
Cited By (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103540183A (en) * | 2013-10-27 | 2014-01-29 | 合肥乐凯科技产业有限公司 | Anti-fingerprint transparent hardening film for touch screen |
| CN103792789A (en) * | 2014-01-27 | 2014-05-14 | 京东方科技集团股份有限公司 | Photoresist composition |
| WO2015109878A1 (en) * | 2014-01-27 | 2015-07-30 | 京东方科技集团股份有限公司 | Photoresist composition |
| CN103792789B (en) * | 2014-01-27 | 2015-11-25 | 京东方科技集团股份有限公司 | A kind of photoetching compositions |
| US9726975B2 (en) | 2014-01-27 | 2017-08-08 | Boe Technology Group Co., Ltd. | Photoresist composition |
| TWI648154B (en) * | 2014-03-26 | 2019-01-21 | 日商琳得科股份有限公司 | Anti-glare hard coat film |
| CN105315879A (en) * | 2014-07-11 | 2016-02-10 | 湖北航天化学技术研究所 | High definition ultraviolet (UV) cured antidazzle hard film |
| CN104109432A (en) * | 2014-07-28 | 2014-10-22 | 广西梧州龙鱼漆业有限公司 | Ultraviolet curing paint |
| CN104293052A (en) * | 2014-09-26 | 2015-01-21 | 锐展(铜陵)科技有限公司 | Energy-saving waterproof coating for exterior trim of automobile |
| CN105524563A (en) * | 2014-09-30 | 2016-04-27 | 湖北航天化学技术研究所 | Blue-light-barrier anti-dazzle optical film and preparation method therefor |
| CN106147357A (en) * | 2015-06-02 | 2016-11-23 | 湖北航天化学技术研究所 | A kind of light absorptive anti-glare hard coating film and its preparation method and application |
| CN105038570A (en) * | 2015-07-14 | 2015-11-11 | 深圳市汇万川塑胶薄膜有限公司 | Highly scratch-resistant anti-dazzle ultraviolet-curable coating and application method therefor |
| CN105353431A (en) * | 2015-12-02 | 2016-02-24 | 合肥乐凯科技产业有限公司 | Basal membrane of composite brightness enhancement film |
| CN105566963A (en) * | 2015-12-25 | 2016-05-11 | 佛山佛塑科技集团股份有限公司 | Non-glare coating and non-glare membrane |
| CN106932998B (en) * | 2015-12-31 | 2019-12-20 | 深圳超多维科技有限公司 | Light splitting device and three-dimensional display device |
| CN106932998A (en) * | 2015-12-31 | 2017-07-07 | 深圳超多维光电子有限公司 | A kind of light-splitting device and 3 d display device |
| CN105505199A (en) * | 2016-01-26 | 2016-04-20 | 江苏海田技术有限公司 | Anti-dazzle UV curing resin coating for LCD display screen |
| CN105647375A (en) * | 2016-01-26 | 2016-06-08 | 江苏海田技术有限公司 | UV curing resin paint for LCD screen |
| CN105482683A (en) * | 2016-01-26 | 2016-04-13 | 江苏海田技术有限公司 | Anti-fouling UV cured resin coating for LCD screen |
| CN105907275A (en) * | 2016-05-06 | 2016-08-31 | 安徽和润特种玻璃有限公司 | High-hardness and high-toughness anti-corrosion non-glare glass film |
| CN105860724A (en) * | 2016-05-06 | 2016-08-17 | 安徽和润特种玻璃有限公司 | Transparent stain-resistant ageing-resistant thermal-insulation anti-dazzle glass coating |
| CN107177301A (en) * | 2016-05-19 | 2017-09-19 | 湖北航天化学技术研究所 | A kind of sustainable slow-release fragrance anti-glare hardened film and its application |
| CN108690209A (en) * | 2017-03-07 | 2018-10-23 | 宁波惠之星新材料科技有限公司 | A kind of anti-dazzle optical coating of UV resistant and its application |
| CN107236426A (en) * | 2017-06-28 | 2017-10-10 | 太仓市美航涂料有限公司 | A kind of high rigidity plated film UV finish paints |
| CN107641454A (en) * | 2017-08-24 | 2018-01-30 | 张家港康得新光电材料有限公司 | Anti- precipitation PET optical thin films and its application |
| CN107641455A (en) * | 2017-09-27 | 2018-01-30 | 芜湖春风新材料有限公司 | A kind of automotive upholstery anti-fingerprint UV coating, preparation method and applications |
| CN107641455B (en) * | 2017-09-27 | 2019-12-24 | 芜湖春风新材料有限公司 | Anti-fingerprint UV coating for automotive interior parts, and preparation method and application thereof |
| CN108047852B (en) * | 2017-12-14 | 2020-06-23 | 合肥乐凯科技产业有限公司 | Polyester film |
| CN108047852A (en) * | 2017-12-14 | 2018-05-18 | 合肥乐凯科技产业有限公司 | A kind of polyester film |
| CN109554009A (en) * | 2018-06-08 | 2019-04-02 | 湖南阳光新材料有限公司 | One kind being convenient for the clean water-repellent paint of carbody shell |
| CN109385163B (en) * | 2018-09-27 | 2020-10-27 | 合众（佛山）化工有限公司 | PEEK modified acrylic acid water-based transparent heat-insulating coating capable of fully shielding infrared rays and ultraviolet rays |
| CN109385163A (en) * | 2018-09-27 | 2019-02-26 | 合众（佛山）化工有限公司 | A kind of PEEK modified acroleic acid full-shield infrared ray and ultraviolet light water transparent heat insulation paint |
| CN110802796A (en) * | 2019-11-11 | 2020-02-18 | 熊何宇 | Preparation method of high-performance in-mold injection molding panel |
| CN112034685A (en) * | 2020-09-01 | 2020-12-04 | 珠海市能动科技光学产业有限公司 | High-resolution dry film photoresist |
| CN112034685B (en) * | 2020-09-01 | 2022-03-18 | 珠海市能动科技光学产业有限公司 | High-resolution dry film photoresist |
| CN115386270A (en) * | 2021-12-23 | 2022-11-25 | 南通恒华粘合材料科技有限公司 | Wear-resistant scratch-resistant anti-glare coating for UV (ultraviolet) type glass and preparation method thereof |
| CN115386270B (en) * | 2021-12-23 | 2023-10-13 | 南通恒华粘合材料科技有限公司 | Wear-resistant scratch-resistant anti-dazzle coating for UV type glass and preparation method thereof |
| CN114437616A (en) * | 2022-03-17 | 2022-05-06 | 惠州市日大实业有限公司 | Fingerprint-resistant high-solid low-viscosity wear-resistant ceramic-like photocureable coating and preparation method thereof |
| CN114805896A (en) * | 2022-05-18 | 2022-07-29 | 苏州诺菲纳米科技有限公司 | Anti-glare protective film and preparation method thereof |
| CN114805896B (en) * | 2022-05-18 | 2023-09-12 | 苏州诺菲纳米科技有限公司 | Anti-dazzle protective film and preparation method thereof |
| CN117625035A (en) * | 2024-01-26 | 2024-03-01 | 广州申威新材料科技有限公司 | Anti-dazzle anti-reflection coating, composite film, preparation method and application |
| CN117625035B (en) * | 2024-01-26 | 2024-04-12 | 广州申威新材料科技有限公司 | Anti-dazzle anti-reflection coating, composite film, preparation method and application |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103205190A (en) | Ultraviolet-cured anti-dazzle hard film and application thereof | |
| CN102236113B (en) | Ultraviolet-cured hard coating and application thereof | |
| CN105315879B (en) | A kind of high-resolution UV-curing anti-glare hard coating film | |
| CN106338783B (en) | A kind of anti-dazzle antireflective optical film and its preparation method and application | |
| CN105899623B (en) | Include the hard coat film of alkoxylated more (methyl) acrylate monomers and surface treated nano-particle | |
| CN101878276B (en) | Coating composition and coating film having enhanced abrasion resistance and fingerprint traces removability | |
| TWI409306B (en) | Hard coating | |
| CN102786875B (en) | Anti-static hardened film | |
| CN103205191A (en) | Low-warp hard film, and making method and application thereof | |
| CN103197363B (en) | A kind of anti-scratch optical diffusion and preparation method thereof | |
| US6723423B1 (en) | Transparent sheet or film | |
| KR101501682B1 (en) | Anti-Glare Coating Composition Having Improved Anti-Fingerprinting and Anti-Glare Coating Film Prepared Therefrom | |
| CN107075320B (en) | Pressure-sensitive adhesive film | |
| JP2013174888A (en) | Anti-glare film composition and anti-glare film prepared using the same | |
| CN106811108A (en) | A kind of anti-flash-point coating of anti-dazzle and preparation method and application | |
| CN103403073A (en) | Hardcoat | |
| CN103620447A (en) | Molding material, coating composition, and method for producing molding material | |
| CN102762644A (en) | Coating layer for an antiglare film, and an antiglare film comprising the same | |
| KR20160140643A (en) | Anti-fingerprint coating composition, products therefrom, method for forming the same, and use thereof | |
| CN103080252A (en) | Curable resin composition and multi-layer laminate manufactured using the same | |
| CN106147357B (en) | A kind of light absorptive anti-glare hard coating film and its preparation method and application | |
| CN106634552A (en) | UV curable coating composition, coating method thereof, and substrates coated thereby | |
| CN107203013A (en) | A kind of antistatic anti-glare antireflective optical film and its preparation method and application | |
| CN106661362A (en) | Metal oxide particle dispersion, composition containing metal oxide particles, coating film, and display device | |
| KR20120075362A (en) | Coating solution for forming transparent film and substrate coated by transparent film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130717 |