CN105860701A - Anion-aqueous interior-wall paint and preparing method - Google Patents

Anion-aqueous interior-wall paint and preparing method Download PDF

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Publication number
CN105860701A
CN105860701A CN201610240223.4A CN201610240223A CN105860701A CN 105860701 A CN105860701 A CN 105860701A CN 201610240223 A CN201610240223 A CN 201610240223A CN 105860701 A CN105860701 A CN 105860701A
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parts
wall paint
anion
aqueous interior
interior wall
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孙小力
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses anion-aqueous interior-wall paint and a preparing method, and belongs to the field of building wall-face decorative materials. The anion-aqueous interior-wall paint comprises, by weight, 100-120 parts of waterborne emulsion, 300-360 parts of deionized water, 1-4 parts of cellulose, 1-3 parts of multifunctional assistant, 6-10 parts of wetting agent, 8-10 parts of dispersing agent, 1-3 parts of antifoaming agent, 15-20 parts of film forming assistant, 10-20 parts of thickening agent, 20-50 parts of anion powder and 400-500 parts of filler. The preparing method includes the steps that deionized water is added into a reaction tank, cellulose and multifunctional assistant are added, and the mixture is stirred at 500 r/min till the mixture is completely dissolved; wetting agent, dispersing agent, antifoaming agent and film forming assistant are sequentially added, and the mixture is stirred for 30 min; then filler and anion powder are added, the mixture is stirred for 1 h at the high speed, and a discharging material is obtained and ground through a grinding machine; after the fineness meets the requirement, the ground discharging material is added into a stirring tank, waterborne emulsion and a proper quantity of thickening agent are added, the viscosity is adjusted to 3,000 mpa.S, discharging is carried out, and the anion-aqueous interior-wall paint can be obtained.

Description

A kind of anion aqueous interior wall paint and preparation method
Technical field
A kind of anion aqueous interior wall paint and preparation method, belong to decorative material for wall surface of building technical field.
Background technology
Indoor environment is that people contact most frequent, the closest place, according to statistics, it has been found that indoor air pollutants have kind more than 300, negative aeroion is that the neutral molecule in air combines electronics and the gas ion with negative charge that formed.When negative ion concentration is higher in air, the breeding of multiple pathogenic bacteria can be suppressed, reduce blood pressure and allaying tiredness, promote growth in humans and growth, thus negative aeroion is likened to " vitamin in air " by people.
When people walk in forest, waterfall or seabeach when, may feel that with fresh air, happy, this is because these place negative ion concentrations are bigger, through people's years of researches, sum up the negative ion concentration relation with health, as shown in the table:
By upper table it is apparent that develop a kind of novel produce and the new indoor ornament materials of releasing negative oxygen ion has the biggest practicality and necessity.
Summary of the invention
In order to overcome the deficiencies in the prior art, the present invention provides a kind of anion aqueous interior wall paint and preparation method.
It is an object of the invention to the living environment for improving people in larger scope, allow people stay indoor just simultaneously and can experience the sensation in the Nature, improve the physical condition of people, it is provided that a kind of anion aqueous interior wall paint.
One utilizes anion aqueous interior wall paint, and its formula proportioning includes:
Water-based emulsion 100-120 part,
Deionized water 300-360 part,
Cellulose 1-4 part,
Multifunctional assistant 1-3 part,
Wetting agent 6-10 part,
Dispersant 8-10 part,
Defoamer 1-3 part,
Coalescents 15-20 part,
Thickening agent 10-20 part,
Anion powder 20-50 part,
Filler 400-500 part.
Described water-based emulsion is the one in aqueous acrylic emulsion, aqueous polyurethane emulsion, aqueous polyvinyl acetate emulsion or aqueous epoxy resin emulsion etc..
Described cellulose is one or more mixture of hydroxyethyl cellulose (HEC), hydroxypropyl methyl cellulose (HPMC), hydroxymethyl cellulose (CMC) and/or ethylhydroxyethylcellulose (EHEC), and mixed proportion can adjust the most in good time.
Multifunctional assistant is the moisture content-2-amino-2-methyl-1-propanol containing 5%.
Wetting agent is one or both mixing in the ethylene oxide adduct of alkylphenol polyoxyethylene, high-carbon fatty alcohol polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid methyl ester ethoxylate and/or polypropylene glycol.
Dispersant is one or more in sulfonated oil (turkey red oil, soil ear base oil), alkyl or long chain base benzene sulfonic acid sodium salt, alkyl polyoxyethylene ether, sodium lignin sulfonate, naphthalene sulfonic acid-formaldehyde condensation product and/or oleoyl polyamine group hydroxy acid salt etc..
Defoamer be emulsified silicone oil, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene tetramethylolmethane ether, polyoxyethylene polyoxy propanol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether and/or polydimethylsiloxane etc. one or more.
Filler be triple superphosphate, fine particle calcium carbonate, bentonite, Kaolin, Pulvis Talci and/or titanium dioxide etc. one or more.
Described coalescents is that propylene glycol, propandiol butyl ether, propylene glycol methyl ether acetate, one or more during alcohol ester ten is second-class mix.
Described thickening agent is the one in water miscible polyacrylate, propylene soda acid swollen thickener, polyurethanes thickening agent.
Described anion powder is based on nanometer vermiculite powder and tourmaline, one or more of the incorporation rare earth element such as attapulgite and cerium oxide, Dineodymium trioxide, terbia. Diterbium trioxide, lanthana are blended and form, wherein mixed proportion is: nanometer vermiculite powder: tourmaline: attapulgite: rare earth element=30-40:30-40:10-20:10-20, it is desirable to mixing anion powder average particle size distribution < 63 μm.
A kind of anion aqueous interior wall paint preparation method, it is characterised in that comprise the following steps: get the raw materials ready according to formulation weight ratio:
Water-based emulsion 100-120 part,
Deionized water 300-360 part,
HEC 1-4 part,
Multifunctional assistant 1-3 part,
Wetting agent 6-10 part,
Dispersant 8-10 part,
Defoamer 1-3 part,
Coalescents 15-20 part,
Thickening agent 10-20 part,
Anion powder 20-50 part,
Filler 400-500 part.
First deionized water is added in retort, be subsequently adding cellulose, multifunctional assistant is stirred to being completely dissolved with 500r/min, then wetting agent, dispersant, defoamer, coalescents stirring 30min are sequentially added, rear addition filler and anion powder high-speed stirred 1h discharging, then by grinder, discharging is ground, after fineness reaches requirement, rejoin in agitator tank, add water-based emulsion and appropriate thickening agent, regulation viscosity to 3000mpa S, discharging anion aqueous interior wall paint.
Present invention have the advantage that
1. lacquer painting Artline is fine and smooth soft and smooth;
2. covering power is good, scrubbing resistance, and mildew-resistant is fungi-proofing;
3. sustained release anion, without formaldehyde, VOC content is low;
4. eliminate abnormal flavour, stink in air, organic chemistry material etc.;
5. purify air, the health environment-friendly scope of application.
The interior wall paint VOC content of the present invention is low, be far below like product without formaldehyde, content of beary metal, the most healthy more environmentally friendly, there is again good negative ion releasing function simultaneously, can allow people in the case of not going out door, fully meet people shower the Nature breath is thirsted for, to improving existing domestic environment, have and well develop meaning.
Detailed description of the invention
Obviously, the many modifications and variations that those skilled in the art are done based on spirit of the invention belong to protection scope of the present invention.
Those skilled in the art of the present technique are appreciated that unless otherwise defined, all terms used herein (including technical term and scientific terminology) have with the those of ordinary skill in art of the present invention be commonly understood by identical meaning.Should also be understood that those terms defined in such as general dictionary should be understood that have the meaning consistent with the meaning in the context of prior art, and unless defined as here, will not explain by idealization or the most formal implication.
Embodiment 1: a kind of anion aqueous interior wall paint, formula proportioning includes forming:
Water-based emulsion 100 parts,
Deionized water 300 parts,
Cellulose 1 part,
Multifunctional assistant 1 part,
Wetting agent 6 parts,
Dispersant 8 parts,
Defoamer 1 part,
Coalescents 15 parts,
Thickening agent 10 parts,
Anion powder 20 parts,
Filler 400 parts.
Described water-based emulsion is the one in aqueous acrylic emulsion, aqueous polyvinyl acetate emulsion or aqueous epoxy resin emulsion etc..
Described cellulose is one or more mixture of hydroxypropyl methyl cellulose (HPMC), hydroxymethyl cellulose (CMC) and/or ethylhydroxyethylcellulose (EHEC), and mixed proportion can adjust the most in good time.
Multifunctional assistant is the moisture content-2-amino-2-methyl-1-propanol containing 5%.
Wetting agent is one or both mixing in the ethylene oxide adduct of high-carbon fatty alcohol polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid methyl ester ethoxylate and/or polypropylene glycol.
Dispersant is one or more in alkyl or long chain base benzene sulfonic acid sodium salt, alkyl polyoxyethylene ether, sodium lignin sulfonate, naphthalene sulfonic acid-formaldehyde condensation product and/or oleoyl polyamine group hydroxy acid salt etc..
Defoamer be the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene tetramethylolmethane ether, polyoxyethylene polyoxy propanol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether and/or polydimethylsiloxane etc. one or more.
Filler be fine particle calcium carbonate, bentonite, Kaolin, Pulvis Talci and/or titanium dioxide etc. one or more.
Described coalescents is that propandiol butyl ether, propylene glycol methyl ether acetate, one or more during alcohol ester ten is second-class mix.
Described thickening agent is the one in water miscible propylene soda acid swollen thickener, polyurethanes thickening agent.
Described anion powder is based on nanometer vermiculite powder and tourmaline, one or more of the rare earth elements such as incorporation Dineodymium trioxide, terbia. Diterbium trioxide, lanthana are blended and form, wherein mixed proportion is: nanometer vermiculite powder: tourmaline: attapulgite: rare earth element=30:30:10:10, it is desirable to mixing anion powder average particle size distribution < 63 μm.
A kind of anion aqueous interior wall paint preparation method, comprises the following steps: get the raw materials ready according to formulation weight ratio:
Water-based emulsion 100 parts,
Deionized water 300 parts,
Cellulose 1 part,
Multifunctional assistant 1 part,
Wetting agent 6 parts,
Dispersant 8 parts,
Defoamer 1 part,
Coalescents 15 parts,
Thickening agent 10 parts,
Anion powder 20 parts,
Filler 400 parts.
First deionized water is added in retort, be subsequently adding cellulose, multifunctional assistant is stirred to being completely dissolved with 500r/min, then wetting agent, dispersant, defoamer, coalescents stirring 30min are sequentially added, rear addition filler and anion powder high-speed stirred 1h discharging, then by grinder, discharging is ground, after fineness reaches requirement, rejoin in agitator tank, add water-based emulsion and appropriate thickening agent, regulation viscosity to 3000mpa S, discharging anion aqueous interior wall paint.
Embodiment 2: a kind of anion aqueous interior wall paint, according to formulation weight than composition:
Styrene-acrylic emulsion 120 parts,
Deionized water 320 parts,
Cellulose 4 parts,
Multifunctional assistant 2 parts,
Wetting agent 10 parts,
Dispersant 10 parts,
Defoamer 3 parts,
Coalescents 20 parts,
Thickening agent 20 parts,
Anion powder 50 parts,
Filler 500 parts.
Described water-based emulsion is the one in aqueous polyurethane emulsion, aqueous polyvinyl acetate emulsion or aqueous epoxy resin emulsion etc..
Described cellulose is one or more mixture of hydroxyethyl cellulose (HEC), hydroxymethyl cellulose (CMC) and/or ethylhydroxyethylcellulose (EHEC), and mixed proportion can adjust the most in good time.
Multifunctional assistant is the moisture content-2-amino-2-methyl-1-propanol containing 5%.
Wetting agent is one or both mixing in the ethylene oxide adduct of alkylphenol polyoxyethylene, polyoxyethylene carboxylate, fatty acid methyl ester ethoxylate and/or polypropylene glycol.
Dispersant is one or more in sulfonated oil (turkey red oil, soil ear base oil), alkyl polyoxyethylene ether, sodium lignin sulfonate, naphthalene sulfonic acid-formaldehyde condensation product and/or oleoyl polyamine group hydroxy acid salt etc..
Defoamer be emulsified silicone oil, polyoxyethylene polyoxypropylene tetramethylolmethane ether, polyoxyethylene polyoxy propanol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether and/or polydimethylsiloxane etc. one or more.
Filler be triple superphosphate, Kaolin, Pulvis Talci and/or titanium dioxide etc. one or more.
Described coalescents is that propylene glycol, propylene glycol methyl ether acetate, one or more during alcohol ester ten is second-class mix.
Described thickening agent is the one in water miscible propylene soda acid swollen thickener, polyurethanes thickening agent.
Described anion powder is based on nanometer vermiculite powder and tourmaline, one or more of the incorporation rare earth element such as attapulgite and cerium oxide, terbia. Diterbium trioxide, lanthana are blended and form, wherein mixed proportion is: nanometer vermiculite powder: tourmaline: attapulgite: rare earth element=40:40:20:20, it is desirable to mixing anion powder average particle size distribution < 63 μm.
A kind of anion aqueous interior wall paint preparation method, comprises the following steps:
Get the raw materials ready according to following formulation weight ratio:
Styrene-acrylic emulsion 120 parts,
Deionized water 320 parts,
Cellulose 4 parts,
Multifunctional assistant 2 parts,
Wetting agent 10 parts,
Dispersant 10 parts,
Defoamer 3 parts,
Coalescents 20 parts,
Thickening agent 20 parts,
Anion powder 50 parts,
Filler 500 parts.
First deionized water is added in retort, be subsequently adding cellulose, multifunctional assistant is stirred to being completely dissolved with 500r/min, then wetting agent, dispersant, defoamer, coalescents stirring 30min are sequentially added, rear addition filler and anion powder high-speed stirred 1h discharging, then by grinder, discharging is ground, after fineness reaches requirement, rejoin in agitator tank, add water-based emulsion and appropriate thickening agent, regulation viscosity to 3000mPa S, discharging anion aqueous interior wall paint.
Embodiment 3: a kind of anion aqueous interior wall paint, according to formulation weight ratio,
Water-based emulsion 110 parts,
Deionized water 360 parts,
Cellulose 2 parts,
Multifunctional assistant 3 parts,
Wetting agent 8 parts,
Dispersant 9 parts,
Defoamer 2 parts,
Coalescents 18 parts,
Thickening agent 18 parts,
Anion powder 40 parts,
Filler 420 parts.
Described water-based emulsion is the one in aqueous polyvinyl acetate emulsion or aqueous epoxy resin emulsion etc..
Described cellulose is one or more mixture of hydroxymethyl cellulose (CMC) and/or ethylhydroxyethylcellulose (EHEC), and mixed proportion can adjust the most in good time.
Multifunctional assistant is the moisture content-2-amino-2-methyl-1-propanol containing 5%.
Wetting agent is one or both mixing in the ethylene oxide adduct of polyoxyethylene carboxylate, fatty acid methyl ester ethoxylate and/or polypropylene glycol.
Dispersant is one or more in alkyl polyoxyethylene ether, sodium lignin sulfonate, naphthalene sulfonic acid-formaldehyde condensation product and/or oleoyl polyamine group hydroxy acid salt etc..
Defoamer be polyoxyethylene polyoxypropylene tetramethylolmethane ether, polyoxyethylene polyoxy propanol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether and/or polydimethylsiloxane etc. one or more.
Filler be bentonite, Kaolin, Pulvis Talci and/or titanium dioxide etc. one or more.
One or more during described coalescents is propylene glycol methyl ether acetate, alcohol ester ten is second-class mix.
Described thickening agent is water miscible polyurethanes thickening agent.
Described anion powder is based on nanometer vermiculite powder and tourmaline, one or more of the incorporation rare earth element such as terbia. Diterbium trioxide, lanthana are blended and form, wherein mixed proportion is: nanometer vermiculite powder: tourmaline: attapulgite: rare earth element=35:38:16:12, it is desirable to mixing anion powder average particle size distribution < 63 μm.
A kind of anion aqueous interior wall paint preparation method, comprises the following steps:
Water-based emulsion 110 parts,
Deionized water 360 parts,
Cellulose 2 parts,
Multifunctional assistant 3 parts,
Wetting agent 8 parts,
Dispersant 9 parts,
Defoamer 2 parts,
Coalescents 18 parts,
Thickening agent 18 parts,
Anion powder 40 parts,
Filler 420 parts.
Get the raw materials ready according to said components;
First deionized water is added in retort, be subsequently adding cellulose, multifunctional assistant is stirred to being completely dissolved with 500r/min, then wetting agent, dispersant, defoamer, coalescents stirring 30min are sequentially added, rear addition filler and anion powder high-speed stirred 1h discharging, then by grinder, discharging is ground, after fineness reaches requirement, rejoin in agitator tank, add water-based emulsion and appropriate thickening agent, regulation viscosity to 3000mpa S, discharging anion aqueous interior wall paint.
As it has been described above, explained embodiments of the invention, but as long as can have a lot of deformation essentially without the inventive point and effect departing from the present invention, this will be readily apparent to persons skilled in the art.Therefore, within such variation is also integrally incorporated in protection scope of the present invention.

Claims (10)

1. one kind utilizes anion aqueous interior wall paint, it is characterised in that formula proportioning includes:
One the most according to claim 1 utilizes anion aqueous interior wall paint, it is characterised in that Described water-based emulsion is aqueous acrylic emulsion, aqueous polyurethane emulsion, aqueous polyvinyl acetate emulsion Or the one in aqueous epoxy resin emulsion.
One the most according to claim 1 utilizes anion aqueous interior wall paint, it is characterised in that Described cellulose is hydroxyethyl cellulose (HEC), hydroxypropyl methyl cellulose (HPMC), hydroxyl first One or more mixture of base cellulose (CMC) and/or ethylhydroxyethylcellulose (EHEC), Mixed proportion can adjust the most in good time;Multifunctional assistant is the moisture content-2-amino-2-containing 5% Methyl isophthalic acid-propanol.
One the most according to claim 1 utilizes anion aqueous interior wall paint, it is characterised in that Wetting agent be alkylphenol polyoxyethylene, high-carbon fatty alcohol polyoxyethylene ether, polyoxyethylene carboxylate, One or both in the ethylene oxide adduct of fatty acid methyl ester ethoxylate and/or polypropylene glycol Mixing.
One the most according to claim 1 utilizes anion aqueous interior wall paint, it is characterised in that Dispersant is sulfonated oil (turkey red oil, soil ear base oil), alkyl or long chain base benzene sulfonic acid sodium salt, alkane Base polyoxyethylene ether, sodium lignin sulfonate, naphthalene sulfonic acid-formaldehyde condensation product and/or oleoyl polyamine group hydroxyl One or more in hydrochlorate.
One the most according to claim 1 utilizes anion aqueous interior wall paint, it is characterised in that Defoamer is emulsified silicone oil, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene tetramethylolmethane Ether, polyoxyethylene polyoxy propanol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether And/or one or more of polydimethylsiloxane;Filler be triple superphosphate, fine particle calcium carbonate, bentonite, Kaolin, One or more of Pulvis Talci and/or titanium dioxide.
One the most according to claim 1 utilizes anion aqueous interior wall paint, it is characterised in that Described coalescents is in propylene glycol, propandiol butyl ether, propylene glycol methyl ether acetate, alcohol ester 12 One or more mix.
One the most according to claim 1 utilizes anion aqueous interior wall paint, it is characterised in that Described thickening agent is water miscible polyacrylate, propylene soda acid swollen thickener, polyurethanes thickening One in agent.
One the most according to claim 1 utilizes anion aqueous interior wall paint, it is characterised in that Described anion powder, based on nanometer vermiculite powder and tourmaline, mixes attapulgite and cerium oxide, oxidation One or more of the rare earth elements such as neodymium, terbia. Diterbium trioxide, lanthana are blended and form, and wherein mixed proportion is: Nanometer vermiculite powder: tourmaline: attapulgite: rare earth element=30-40:30-40:10-20:10-20, Require mixing anion powder average particle size distribution < 63 μm.
10. an anion aqueous interior wall paint preparation method, it is characterised in that comprise the following steps: press Get the raw materials ready according to formulation weight portion rate:
First deionized water is added in retort, be subsequently adding cellulose, multifunctional assistant with 500r/min is stirred to being completely dissolved, and then sequentially adds wetting agent, dispersant, froth breaking Agent, coalescents stirring 30min, rear addition filler and anion powder high-speed stirred 1h discharging, so By grinder, discharging is ground afterwards, after fineness reaches requirement, rejoins in agitator tank, Add water-based emulsion and appropriate thickening agent, regulation viscosity to 3000mpa S, discharging bear from Sub-water-based inner wall paint.
CN201610240223.4A 2016-04-18 2016-04-18 Anion-aqueous interior-wall paint and preparing method Pending CN105860701A (en)

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CN106497205A (en) * 2016-12-05 2017-03-15 钦州市钦南区生产力促进中心 A kind of powder of lacquer putty for use on and preparation method thereof
CN106590253A (en) * 2016-12-16 2017-04-26 重庆浩申实业有限公司 Magnesium seal prism home space negative ion spray and preparation method and application thereof
CN106703355A (en) * 2017-02-24 2017-05-24 四川金路高新材料有限公司 Production method of wall surface decoration materials capable of generating negative oxygen ions
CN107022282A (en) * 2017-06-12 2017-08-08 合肥欧仕嘉机电设备有限公司 A kind of liquid wall paper paint for building and preparation method thereof
CN107163751A (en) * 2017-06-01 2017-09-15 侯宇振 A kind of anion imitates net taste except aldehyde environment friendly emulsion paint and preparation method thereof entirely
CN107641397A (en) * 2017-09-26 2018-01-30 湖南湘讯企业管理有限公司 A kind of fade-proof coating and preparation method thereof
CN107746642A (en) * 2017-11-16 2018-03-02 福建省闽候县建腾工艺品有限公司 A kind of negative ion paint for handicraft
CN107892828A (en) * 2018-01-01 2018-04-10 南京市雨花台区绿宝工业设计服务中心 A kind of preparation method of dope for inner wall of architecture
CN108441099A (en) * 2018-03-30 2018-08-24 天长市巨龙车船涂料有限公司 A kind of negative ion antibiotic aqueous polyurethane coating
CN108485386A (en) * 2018-04-19 2018-09-04 吉林建筑大学 A kind of green inner wall suitable for Condom adsorbs coating
CN108912992A (en) * 2018-06-13 2018-11-30 重庆文理学院 A kind of anion air purifying wall finiss and its production technology
CN109206960A (en) * 2018-04-21 2019-01-15 泉州市德丽佳环保制品有限公司 A kind of conch meal interior wall air cleaning sealing wax
CN109439099A (en) * 2017-08-28 2019-03-08 白晓松 A kind of dumb light texture exterior coating
CN109735152A (en) * 2019-01-18 2019-05-10 佛山市合呈量子科技有限公司 A kind of health environment-friendly coating and its manufacture craft
CN109988475A (en) * 2019-04-04 2019-07-09 李萌 A kind of skin texture wall film and preparation method thereof
CN110591454A (en) * 2019-09-17 2019-12-20 湖州市南浔联谊喷涂厂 Indoor antibacterial coating for high-humidity environment
CN112457727A (en) * 2020-12-11 2021-03-09 北京氧道纳米科技有限公司 Nano negative ion latex paint and preparation method thereof
CN112680061A (en) * 2020-12-22 2021-04-20 南京长三角绿色发展研究院有限公司 Environment-friendly coating for controlling indoor air pollution risk and preparation method thereof
CN112760021A (en) * 2020-12-31 2021-05-07 湖州白洋装饰材料有限公司 Water-based decorative coating and preparation method thereof
CN113045957A (en) * 2021-04-07 2021-06-29 鹏旺科技开发(苏州)有限公司 Efficient and energy-saving production process of environment-friendly negative ion coating
CN113105812A (en) * 2021-04-13 2021-07-13 江苏旌翔建材科技有限公司 Negative ion environment-friendly coating and preparation method thereof
CN113216808A (en) * 2021-05-12 2021-08-06 广东福临门世家智能家居有限公司 Anion glass door and window with sterilization and formaldehyde removal functions and preparation method thereof
CN113462240A (en) * 2021-07-27 2021-10-01 梁作霖 Preparation process and use method of negative ion releasing coating

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CN103923536A (en) * 2013-01-15 2014-07-16 佛山市康威涂料实业有限公司 Preparation method for ecological air-purifying humidity-regulating antibacterial interior wall paint
CN105152617A (en) * 2015-09-06 2015-12-16 孙小力 Gypsum plaster board produced by utilizing negative ion powder and preparation method

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Publication number Priority date Publication date Assignee Title
CN1861710A (en) * 2005-05-13 2006-11-15 大连罗雅尔化学有限公司 Compounding water emulsion paint for internal wall and its tech.
CN103923536A (en) * 2013-01-15 2014-07-16 佛山市康威涂料实业有限公司 Preparation method for ecological air-purifying humidity-regulating antibacterial interior wall paint
CN105152617A (en) * 2015-09-06 2015-12-16 孙小力 Gypsum plaster board produced by utilizing negative ion powder and preparation method

Cited By (27)

* Cited by examiner, † Cited by third party
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CN106217571A (en) * 2016-08-28 2016-12-14 桐乡市美意家具有限公司 A kind of negative ionization processing method of wood furniture
CN106497205A (en) * 2016-12-05 2017-03-15 钦州市钦南区生产力促进中心 A kind of powder of lacquer putty for use on and preparation method thereof
CN106590253A (en) * 2016-12-16 2017-04-26 重庆浩申实业有限公司 Magnesium seal prism home space negative ion spray and preparation method and application thereof
CN106703355A (en) * 2017-02-24 2017-05-24 四川金路高新材料有限公司 Production method of wall surface decoration materials capable of generating negative oxygen ions
CN106703355B (en) * 2017-02-24 2020-04-14 四川金路高新材料有限公司 Method for producing negative oxygen ion wall decoration material
CN107163751A (en) * 2017-06-01 2017-09-15 侯宇振 A kind of anion imitates net taste except aldehyde environment friendly emulsion paint and preparation method thereof entirely
CN107022282A (en) * 2017-06-12 2017-08-08 合肥欧仕嘉机电设备有限公司 A kind of liquid wall paper paint for building and preparation method thereof
CN109439099A (en) * 2017-08-28 2019-03-08 白晓松 A kind of dumb light texture exterior coating
CN107641397A (en) * 2017-09-26 2018-01-30 湖南湘讯企业管理有限公司 A kind of fade-proof coating and preparation method thereof
CN107746642A (en) * 2017-11-16 2018-03-02 福建省闽候县建腾工艺品有限公司 A kind of negative ion paint for handicraft
CN107892828A (en) * 2018-01-01 2018-04-10 南京市雨花台区绿宝工业设计服务中心 A kind of preparation method of dope for inner wall of architecture
CN108441099A (en) * 2018-03-30 2018-08-24 天长市巨龙车船涂料有限公司 A kind of negative ion antibiotic aqueous polyurethane coating
CN108485386B (en) * 2018-04-19 2020-06-02 吉林建筑大学 Interior wall environment-friendly adsorption coating suitable for leisure places
CN108485386A (en) * 2018-04-19 2018-09-04 吉林建筑大学 A kind of green inner wall suitable for Condom adsorbs coating
CN109206960A (en) * 2018-04-21 2019-01-15 泉州市德丽佳环保制品有限公司 A kind of conch meal interior wall air cleaning sealing wax
CN108912992A (en) * 2018-06-13 2018-11-30 重庆文理学院 A kind of anion air purifying wall finiss and its production technology
CN109735152A (en) * 2019-01-18 2019-05-10 佛山市合呈量子科技有限公司 A kind of health environment-friendly coating and its manufacture craft
CN109988475A (en) * 2019-04-04 2019-07-09 李萌 A kind of skin texture wall film and preparation method thereof
CN110591454A (en) * 2019-09-17 2019-12-20 湖州市南浔联谊喷涂厂 Indoor antibacterial coating for high-humidity environment
CN112457727A (en) * 2020-12-11 2021-03-09 北京氧道纳米科技有限公司 Nano negative ion latex paint and preparation method thereof
CN112680061A (en) * 2020-12-22 2021-04-20 南京长三角绿色发展研究院有限公司 Environment-friendly coating for controlling indoor air pollution risk and preparation method thereof
CN112760021A (en) * 2020-12-31 2021-05-07 湖州白洋装饰材料有限公司 Water-based decorative coating and preparation method thereof
CN113045957A (en) * 2021-04-07 2021-06-29 鹏旺科技开发(苏州)有限公司 Efficient and energy-saving production process of environment-friendly negative ion coating
CN113105812A (en) * 2021-04-13 2021-07-13 江苏旌翔建材科技有限公司 Negative ion environment-friendly coating and preparation method thereof
CN113216808A (en) * 2021-05-12 2021-08-06 广东福临门世家智能家居有限公司 Anion glass door and window with sterilization and formaldehyde removal functions and preparation method thereof
CN113216808B (en) * 2021-05-12 2022-01-18 广东福临门世家智能家居有限公司 Anion glass door and window with sterilization and formaldehyde removal functions and preparation method thereof
CN113462240A (en) * 2021-07-27 2021-10-01 梁作霖 Preparation process and use method of negative ion releasing coating

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