CN102676009B - Anionic ecological multicolour paint and preparation method thereof - Google Patents
Anionic ecological multicolour paint and preparation method thereof Download PDFInfo
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Abstract
The invention particularly relates to an anionic ecological multicolour paint and a preparation method thereof. The anionic ecological multicolour paint is a composition prepared from the following raw materials in parts by weight: 40-60 parts of nano-acrylic emulsion, 5-15 parts of pearl powder, 5-15 parts of 3% hydroxyethylcellulose, 0.1-0.5 parts of anionic additive, 0.1-1 part of dispersing agent, 0.1-0.5 parts of defoaming agent, 0.1-0.5 parts of surfactant, 0.1-0.5 parts of bactericide, 0.1-0.5 parts of functional additive, 0.1-0.5 parts of mildewcide, 1-5 parts of antifreezing agent, 1-5 parts of film-forming additive, 0.1-0.5 parts of thickening agent, and 20-30 parts of deionized water. The anionic ecological multicolour paint disclosed by the invention has the functions of reducing the contents of VOC (volatile organic compounds) and heavy metals, statically and continuously releasing 3200 anions per cubic metre, removing harmful gases such as formaldehyde, ammonia and benzene, resisting and inhibiting bacteria, and the like; and the anionic ecological multicolour paint is colourful, environmentally-friendly, and low in pollution index.
Description
Technical field
The present invention relates to coating and manufacture field, be specifically related to a kind of anion ecological illusion-colour paint and preparation method thereof.
Background technology
In the mankind's life, the overwhelming majority is spent indoor the time, therefore, the saying of narrow sense, the live and work quality of indoor environment on people and the public's healthy impact is considerably beyond outdoor environment.Current, due to energy shortage, Research on Energy Saving has generally been taked in countries in the world, reduces Air conditioner air exchange number of times, indoor shelter quality is significantly worsened, and the obnoxious flavoures such as formaldehyde that indoor decorating and refurnishing materials and furniture discharge, benzene homologues, ammonia have all had a strong impact on people's health.Negative aeroion is the aerial electronegative minuteness particle that swims, and the content of human habitat negative ion is directly related with HUMAN HEALTH level, ought the judge important indicator of environment and Air quality of negative aeroion.
In recent decades, building coating is widely applied in interior exterior wall, mainly contains the reason of following several respects, and the one, economic aspect, adopts coating more than glass or metal curtain wall, decorative stone, the material of construction such as wallpaper are cheap and convenient; The 2nd, coating wide in variety, has the advantages such as durable, anti-pollution, easy construction, can meet the needs of different building decorations; The 3rd, good decorating effect, with the interior wall rich color of coatings decoration, bright-coloured lucid and lively, and can, according to people's hobby, after use for some time, convert color, the feeling of freshness in holding chamber; The 4th, coating light weight safety, and the mildew-resistant of energy waterproof is compared with other finishing material, has more protectiveness, security.Traditional solvent based coating, owing to containing organic solvent, brings pollution to environment, and infringement people's is healthy, and the environmental friendliness coating of development of new is following paint development trend.
Summary of the invention
For overcoming the defect of prior art, the object of the present invention is to provide a kind of anion ecological illusion-colour paint, have VOC and heavy metal content, the static sustained release negative ion of reduction, dispel the functions such as obnoxious flavour, antibacterial bacteriostatic such as formaldehyde, ammonia, benzene, not only rich color and environmental protection, pollution index are low.
Another object of the present invention is to provide a kind of preparation method of anion ecological illusion-colour paint, simple to operate, can widespread use.
The technical solution adopted in the present invention is as follows for achieving the above object:
A kind of anion ecological illusion-colour paint, it is the composition of making in order to the following component of weight part meter:
In preferred scheme, anion ecological illusion-colour paint of the present invention, below weight part meter
The composition that component is made:
Anionic additive described in the present invention is that granularity is the tourmaline powder of 50-200nm.
Described nanometer ACRYLIC EMULSION is the emulsion that the model of French Arkema production is SNAP720; Dispersion agent is the ammonium polyacrylate salt that model that Japanese Sheng Nuopuke company produces is SN-5027; Defoamer is that the model that Japanese Sheng Nuopuke company produces is SN154 silicon-dioxide defoamer; Tensio-active agent is 2,4,7,9-tetramethyl--5-certain herbaceous plants with big flowers alkynes-4,7-glycol; Sterilant is first chloro plug azoles quinoline ketone; Functional agent is that the model that Dow Chemical is produced is the multi-functional ammonium auxiliary agent of AMP-95; Mould inhibitor is that the model that German Shu Mei company limited produces is the mould inhibitor of Parmetol DF 19 forte; Film coalescence aid is the COASOL film coalescence aid that Dow Chemical produces; Thickening material is the polyurethanes thickening material that model that French Gao Disi company produces is COAPUR2025.
Frostproofer described in the present invention is ethylene glycol.
The selected SNAP720 emulsion of the present invention has nucleocapsid structure, its solid content is 49.0%(mass percent), viscosity < 500cp, pH value is 7.0, minimum film-forming temperature is 0 ℃, particle diameter is 0.08 μ m, latex general volatile VOC is 5.0g/L, therefore adopts the anion ecological illusion-colour paint of this emulsion to have the advantages such as fine and smooth, viscosity is low, and free formaldehyde content is low, and after film forming, there is good gloss, snappiness, resistance to bond and water-repellancy.
SN-5027 ammonium polyacrylate salt of the present invention has lower mill base viscosity, can improve coating stability in storage, increase the features such as gloss and levelling property; The water resistant type dispersion agent dispersion effect that the dispersiveness of dispersion agent 5027 is more general is good, thereby consumption is low, can effectively improve the water tolerance of paint film, is specially adapted to the paint film of high gloss.
SN154 defoamer of the present invention is silicon-dioxide defoamer, has good lasting froth breaking ability, can prevent for a long time that coating from bubbling, and has the good bubble ability that presses down, and is difficult for producing shrinkage cavity; Film is without disadvantage, attractive in appearance, and its impact of toning on coating is little.
COASOL film coalescence aid of the present invention is the mixture of diisobutyl succinate, diisobutyl glutarate and diisobutyl penta adipic acid ester, wherein by massfraction diisobutyl succinate 15-25%, diisobutyl glutarate 55-65%, diisobutyl penta adipic acid ester 10-25%; COASOL film coalescence aid has zero VOC, extremely low smell and good stability to hydrolysis; Therefore, it has more complete hard ionomeric and hydrophobicity with respect to other film coalescence aid, and it can effectively reduce just surface tension in water-based system, and the performance of more excellent reduction MFFT is provided; Make that smell in system is lower, toxicity is lower, and there is low bubble.
COAPUR2025 thickening material of the present invention is solvent-free and does not contain the polyurethane associative thickener of APE.
A preparation method for anion ecological illusion-colour paint, comprises the following steps:
(1) deionized water is joined in the retort with dispersion machine, start dispersion machine;
(2) in stirring, in turn dispersion agent, tensio-active agent, sterilant, functional agent, mould inhibitor, frostproofer, film coalescence aid are joined in retort, stir into the dispersion liquid of homogeneous;
(3) then improve stirring velocity, reacting by heating tank is to 40-60 ℃, then adds in turn defoamer, nanometer ACRYLIC EMULSION, pearl powder, 3% Natvosol, and dispersed with stirring is even;
(4) finally add in turn thickening material, anionic additive, stir 10-20 minute.
In order to stir, in above-mentioned preparation method's step (2), the speed of stirring is turn/min of 400-500, and churning time is 5-10 minute.
In order further to reach the effect of dispersion, prevent that pearl powder from living in emulsion knot grain, the turn/min that in above-mentioned preparation method's step (3), stirring velocity is increased to 1000-1200, churning time is 10-20 minute.
Beneficial effect of the present invention is: anion ecological illusion-colour paint of the present invention has VOC and the heavy metal content of reduction, static sustained release negative ion reaches 3200/m
3, dispel the functions such as obnoxious flavour, antibacterial bacteriostatic such as formaldehyde, ammonia, benzene, not only rich color and environmental protection, pollution index are low.The preparation method of anion ecological illusion-colour paint provided by the invention is simple to operation, can realize widespread use.
Below in conjunction with concrete embodiment, the present invention is described in further detail.
Embodiment
Below specific embodiments of the invention.
The preparation method of anion ecological illusion-colour paint of the present invention, comprises the following steps:
(1) deionized water is joined in the retort with dispersion machine, start dispersion machine;
(2) in stirring, in turn dispersion agent, tensio-active agent, sterilant, functional agent, mould inhibitor, frostproofer, film coalescence aid are joined in retort, stir into the dispersion liquid of homogeneous;
(3) then improve stirring velocity, reacting by heating tank is to 40-60 ℃, then adds in turn defoamer, nanometer ACRYLIC EMULSION, pearl powder, 3% Natvosol, and dispersed with stirring is even;
(4) finally add in turn thickening material, anionic additive, stir 10-20 minute.
In following embodiment, mentioned nanometer ACRYLIC EMULSION is the emulsion that the model of French Arkema production is SNAP720; Dispersion agent is the ammonium polyacrylate salt that model that Japanese Sheng Nuopuke company produces is SN-5027; Defoamer is that the model that Japanese Sheng Nuopuke company produces is SN154 silicon-dioxide defoamer; Tensio-active agent is 2,4,7,9-tetramethyl--5-certain herbaceous plants with big flowers alkynes-4,7-glycol; Sterilant is first chloro plug azoles quinoline ketone; Functional agent is that the model that Dow Chemical is produced is the multi-functional ammonium auxiliary agent of AMP-95; Mould inhibitor is that the model that German Shu Mei company limited produces is the mould inhibitor of Parmetol DF 19 forte; Film coalescence aid is the COASOL film coalescence aid that Dow Chemical produces; Thickening material is the polyurethanes thickening material that model that French Gao Disi company produces is COAPUR2025.
Embodiment 1
A kind of anion ecological illusion-colour paint, is made up of the following component in weight part: 40 parts of nanometer ACRYLIC EMULSION, 5 parts of pearl powders, 3% 5 parts of Mierocrystalline celluloses, 0.1 part of anionic additive, 0.1 part of dispersion agent, 0.1 part of defoamer, 0.1 part, tensio-active agent, 0.1 part, sterilant, 0.1 part of functional agent, 0.1 part of mould inhibitor, 1 part of frostproofer, 1 part of film coalescence aid, 0.1 part of thickening material, 20 parts of deionized waters; And make according to the above-mentioned preparation method of the present invention; Wherein, in step (2), the speed of stirring is 400 turn/min, and churning time is 10 minutes, in step (3), stirring velocity is increased to 1200 turn/min, and churning time is 10 minutes.
Embodiment 2
A kind of anion ecological illusion-colour paint, is made up of the following component in weight part: 50 parts of nanometer ACRYLIC EMULSION, 10 parts of pearl powders, 3% 10 parts of Mierocrystalline celluloses, 0.5 part of anionic additive, 0.6 part of dispersion agent, 0.2 part of defoamer, 0.1 part, tensio-active agent, 0.15 part, sterilant, 0.1 part of functional agent, 0.3 part of mould inhibitor, 2 parts of frostproofers, 2.4 parts of film coalescence aid, 0.3 part of thickening material, 23 parts of deionized waters; And make according to the above-mentioned preparation method of the present invention; Wherein, in step (2), the speed of stirring is 500 turn/min, and churning time is 5 minutes, in step (3), stirring velocity is increased to 1200 turn/min, and churning time is 10 minutes.
Embodiment 3
A kind of anion ecological illusion-colour paint, is made up of the following component in weight part: 60 parts of nanometer ACRYLIC EMULSION, 15 parts of pearl powders, 3% 15 parts of Mierocrystalline celluloses, 0.5 part of anionic additive, 1 part of dispersion agent, 0.5 part of defoamer, 0.5 part, tensio-active agent, 0.5 part, sterilant, 0.5 part of functional agent, 0.5 part of mould inhibitor, 5 parts of frostproofers, 5 parts of film coalescence aid, 0.5 part of thickening material, 30 parts of deionized waters; And make according to the above-mentioned preparation method of the present invention; Wherein, in step (2), the speed of stirring is 400 turn/min, and churning time is 10 minutes, in step (3), stirring velocity is increased to 1000 turn/min, and churning time is 20 minutes.
Performance Detection:
Anion ecological illusion-colour paint prepared by embodiment of the present invention 1-3 is 3200/m through the negative ion that detects its release
3above, and according to the performance of GB/T 9756-2001 standard and GB18582-2001 standard detection anion ecological illusion-colour paint, performance index is in table 1 and table 2:
Table 1: the data that detect according to GB/T 9756-2001
Table 2: the data that detect according to GB18582-2001
Above-mentioned embodiment is only the preferred embodiment of the present invention; can not limit the scope of protection of the invention with this, the variation of any unsubstantiality that those skilled in the art does on basis of the present invention and replacement all belong to the present invention's scope required for protection.
Claims (6)
1.
.a kind of anion ecological illusion-colour paint, is characterized in that it is the composition of making in order to the following component of weight part meter:
Nanometer ACRYLIC EMULSION 40-60 part,
Pearl powder 5-15 part,
3% Natvosol 5-15 part,
Anionic additive 0.1-0.5 part,
Dispersion agent 0.1-1 part,
Defoamer 0.1-0.5 part,
Tensio-active agent 0.1-0.5 part,
Sterilant 0.1-0.5 part,
Functional agent 0.1-0.5 part,
Mould inhibitor 0.1-0.5 part,
Frostproofer 1-5 part,
Film coalescence aid 1-5 part,
Thickening material 0.1-0.5 part,
Deionized water 20-30 part;
Described anionic additive is that granularity is the tourmaline powder of 50-200nm, and described nanometer ACRYLIC EMULSION is the emulsion that the model of French Arkema production is SNAP720; Dispersion agent is the ammonium polyacrylate salt that model that Japanese Sheng Nuopuke company produces is SN-5027; Defoamer is that the model that Japanese Sheng Nuopuke company produces is SN154 silicon-dioxide defoamer; Tensio-active agent is 2,4,7,9-tetramethyl--5-decine-4,7-glycol; Functional agent is that the model that Dow Chemical is produced is AMP-95 multifunctional assistant; Mould inhibitor is that the model that German Shu Mei company limited produces is the mould inhibitor of Parmetol DF 19 forte; Film coalescence aid is the COASOL film coalescence aid that Dow Chemical produces; Thickening material is the polyurethanes thickening material that model that French Gao Disi company produces is COAPUR2025.
2. anion ecological illusion-colour paint according to claim 1, is characterized in that it is to make composition in order to the following component of weight part meter:
50 parts of nanometer ACRYLIC EMULSION,
10 parts of pearl powders,
3% 10 parts of Natvosols,
0.1 part of anionic additive,
0.6 part of dispersion agent,
0.2 part of defoamer,
0.1 part, tensio-active agent,
0.15 part, sterilant,
0.1 part of functional agent,
0.3 part of mould inhibitor,
2 parts of frostproofers,
2.4 parts of film coalescence aid,
0.3 part of thickening material,
23 parts of deionized waters.
3. anion ecological illusion-colour paint according to claim 1, is characterized in that: described frostproofer is ethylene glycol.
4. the preparation method of anion ecological illusion-colour paint as claimed in claim 1 or 2, is characterized in that it comprises the following steps:
(1) deionized water is joined in the retort with dispersion machine, start dispersion machine;
(2) in stirring, in turn dispersion agent, tensio-active agent, sterilant, functional agent, mould inhibitor, frostproofer, film coalescence aid are joined in retort, stir into the dispersion liquid of homogeneous;
(3) then improve stirring velocity, reacting by heating tank is to 40-60 ℃, then adds in turn defoamer, nanometer ACRYLIC EMULSION, pearl powder, 3% Natvosol, and dispersed with stirring is even;
(4) finally add in turn thickening material, anionic additive, stir 10-20 minute.
5. the preparation method of anion ecological illusion-colour paint according to claim 4, is characterized in that: in step (2), the speed of stirring is turn/min of 400-500, and churning time is 5-10 minute.
6. the preparation method of anion ecological illusion-colour paint according to claim 5, is characterized in that: the turn/min that in step (3), stirring velocity is increased to 1000-1200, churning time is 10-20 minute.
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| CN201210197381.8A CN102676009B (en) | 2012-06-14 | 2012-06-14 | Anionic ecological multicolour paint and preparation method thereof |
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| TWI547530B (en) * | 2015-10-28 | 2016-09-01 | Zhang Zhou San De Li Paints Co Ltd | Nano - Anion Functional Interior Interior Latex Paint and Its Preparation |
| CN106634252A (en) * | 2016-11-16 | 2017-05-10 | 常州市坤建筑材料有限公司 | Preparation method of coating with super stain resistance and colorful effect and using method thereof |
| CN106867336A (en) * | 2017-03-29 | 2017-06-20 | 崔玉香 | A kind of negative oxygen glory paint and preparation method thereof |
| CN107629555A (en) * | 2017-11-08 | 2018-01-26 | 重庆市龙凤工艺品有限公司 | A kind of non-toxic unreal colour paint for Wood craft surface treatment |
| CN111151228A (en) * | 2019-12-25 | 2020-05-15 | 天津米一科技有限公司 | Industrial workshop moisture-proof and pollutant adsorbing material and preparation method thereof |
| CN114989684A (en) * | 2022-05-26 | 2022-09-02 | 广西北海隆万科技有限公司 | Ecological pearl coating capable of releasing negative oxygen ions |
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| CN1900187A (en) * | 2006-07-06 | 2007-01-24 | 北京中化科城技术研究所 | Environment friendly emulsion paint |
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Denomination of invention: Anionic ecological multicolour paint and preparation method thereof Effective date of registration: 20150316 Granted publication date: 20140709 Pledgee: Bank of China, Limited by Share Ltd, Guangzhou, Zengcheng branch Pledgor: Guangzhou Futian Chemical Industry Paint Co., Ltd. Registration number: 2015990000195 |
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