CN106590253A - Magnesium seal prism home space negative ion spray and preparation method and application thereof - Google Patents
Magnesium seal prism home space negative ion spray and preparation method and application thereof Download PDFInfo
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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Abstract
The invention discloses a magnesium seal prism home space negative ion spray. The magnesium seal prism home space negative ion spray contains, by weight, 0.05-3 parts of sodium hydroxide, 3-10 parts of negative ion powder, 3-15 parts of paraffin, 45-85 parts of synthetic resin emulsion, 0.1-1.5 parts of a thickening agent, 0.1-1 part of an anti-corrosive agent, 1-3.5 parts of silver ions and 1-5 parts of polyethylene wax. The invention further discloses a preparation method of the magnesium seal prism home space negative ion spray. According to the magnesium seal prism home space negative ion spray, by adding the substances such as sodium hydroxide, polyethylene wax, the synthetic resin emulsion, tourmaline powder, the paraffin and the silver ions, the negative ion spray achieves the properties of releasing negative ions, shielding neutrons and reflecting electromagnetic waves; when the negative ion spray is used on the wall surfaces and the top surface in a home space, the negative ion spray can continuously release the negative ions to the space, and by combining the sterilization function of the negative ions with the sterilization function of the silver ions, the killing capacity of home textiles to space bacteria is greatly improved, and air is purified.
Description
Technical field
The invention belongs to technical field of air purification, and in particular to one kind is used for metope and top surface in home room, and energy
Magnesium imperial or royal seal prismatic crystal home room anion spray of purify air and preparation method thereof.
Background technology
In air purification field, because anion has splendid purifying and dedusting, reduces second hand smoking harm, improves prevention breathing
Tract disease, improve the health care of sleep, antioxidation, it is anti-aging, remove interior free yl and reduce blood viscosity effect, in medical circle
Enjoy laudatory titles such as " tie up his oxygen ", " air vitamin ", " long-lived element " and " air vitamin ".
In physicss, it is known that material is molecular, molecule be it is molecular by original, atom be by
The electronics composition that atomic nucleus and enclosing are rotated about, obtains aobvious elecrtonegativity during electronics, loses aobvious electropositive during electronics, and we are positive and negative
The motion artifacts of electronics are referred to as ionic phenomenon.In its natural state, the polarity of air molecule is in neutrality, i.e. neutral.But
Under the effect such as cosmic ray, ultraviolet, trace element radiation, Lightning strike, air molecule can lose a part around atomic nucleus
The outermost electron of rotation, ionizes air.The electronics of escape atomic nucleus constraint is referred to as free electron, negatively charged.When
After free electron is combined with other neutral gas molecules, negatively charged negative aeroion is just formed, be more than in natural phenomena
The anion of generation.
With the generation and development of artificial anion generation technique.At present the technology of artificially generated anion predominantly passes through
The process of electric discharge manufacture negative oxygen ion is possible to produce ozone etc. in interior side-product, and excessive ozone can accelerate cell old
Change, health is had a negative impact.Current state-of-the-art anion generation technique both at home and abroad, including Japan and the United States, English, method, moral
It is essentially all, using negative high voltage source, carbon fiber to be made into sparking electrode (also having referred to as " discharging antenna ") Deng state, connects high
Carbon fiber electrode one pole is inserted into space after pressure, the peripherad space of electrode injection electronics at a high speed is made.Electronics is fast by air ion
Speed capture, forms negative aeroion, while being sensed using the potential of negative electric field, in cation and will reduce, to obtain a phase
Anion field to purification.The negative high voltage of the technology must be in more than 8000V, and voltage is higher, electrode and air contact area
Bigger (electric discharge is extreme more), anion generation dosage is bigger, and the negative ion concentration of generation reaches 104/cm3～9 × 107/cm3,
But regrettably increasing with anion dosage, the growing amount of ozone also accordingly increases.This is to restrict artificial anion at present
Generation equipment urgent problem.
With the continuous improvement of people's living standard, the requirement to domestic environment is increasingly paid attention to, after house decoration
Effect also take much count of.For decorative material for internal wall, the environment-friendly materials with kieselguhr as main component, but institute now are mostly adopted
The kieselguhr wall material for using has that adhesion is not strong, the problem of easy dry linting, in addition containing a large amount of in the wall covering of prior art
By the base material of chemical industry synthesis, although colloid, colorant, these products have reached national standard, but have certain toxicity or
With certain radioactivity, the activity in the space that metope is scratched by industrial chemicals of people's long-time still can affect the strong of human body
Health.
The content of the invention
For the defect that prior art is present, the invention provides a kind of environmental protection, anion releasing amount are high and can shield
The magnesium imperial or royal seal prismatic crystal home room anion spray of the function of son and reflection electromagnetic wave.Present invention also offers the magnesium imperial or royal seal prismatic crystal household
The preparation method and application field of space anion spray.
The purpose of the present invention is achieved through the following technical solutions：
A kind of magnesium imperial or royal seal prismatic crystal home room anion spray, in parts by weight containing following component：Sodium hydroxide：0.05-3
Part, anion powder：3-10 parts, paraffin：3-15 parts, synthetic resin emulsion：45-85 parts, thickening agent：0.1-1.5 parts, preservative：
0.1-1 parts, silver ion：1-3.5 part, Tissuemat E：1-5 parts.
A kind of magnesium imperial or royal seal prismatic crystal home room anion spray, preferably：Contain following component in parts by weight：Hydroxide
Sodium：0.1-2.5 parts, anion powder：5-10 parts, paraffin：5-10 parts, synthetic resin emulsion：55-65 parts, thickening agent：0.5-1 parts,
Preservative：0.5-1 parts, silver ion：1-2.5 part；Tissuemat E：3-5 parts.
A kind of magnesium imperial or royal seal prismatic crystal home room anion spray, it is preferable that in parts by weight containing following component：Hydroxide
Sodium：1 part, anion powder：10 parts, paraffin：15 parts, synthetic resin emulsion：67 parts, thickening agent：0.1 part, preservative：0.3 part, silver
Ion：1.6 part；Tissuemat E：5 parts.
Preferably, wherein the anion powder is tourmaline powder that mesh number is 500-10000.
Preferably, wherein the synthetic resin emulsion is pure-acrylic emulsion, styrene-acrylic emulsion, vinyl acetate emulsion, silicone acrylic emulsion, poly- ammonia
At least one in ester emulsion, epoxy resin latex and acrylic emulsion, and the viscosity of the synthetic resin emulsion is 300-
1000cp, solid content is 20-40wt%, and pH value is 8-9, and acid number is 50-60.
Preferably, wherein the thickening agent is in hydroxyethyl cellulose, alkali soluble is swollen acrylic thickener, sodium bentonite
It is at least one.
Preferably, wherein the silver ion is liquid nano silver ion, and the effective content of its silver ion is 3-8wt%.
Preferably, wherein the preservative is hydroxy benzoic acid esters, imidazolidinyl urea, KF88, bronopol, 1- benzene
At least one in epoxide propan-2-ol etc..
A kind of preparation method of above-mentioned magnesium imperial or royal seal prismatic crystal home room anion spray, comprises the steps：
(1) by the synthetic resin emulsion of formula ratio 1/2-2/3, and the anion powder of formula ratio, Tissuemat E and paraffin
Sequentially add high pressure to rush in mill apparatus, rush mill and be dispersed into suspension oar body；
(2) synthetic resin emulsion for being uniformly added into surplus is rushed in mill apparatus to high pressure, and mixture is adjusted with sodium hydroxide
The pH value of system to 7.5-8.5, high-speed stirred dispersion after, vibration filtering；
(3) thickening agent, preservative and silver ion, after dispersed with stirring is uniform, subpackage are uniformly added into.
A kind of application of magnesium imperial or royal seal prismatic crystal home room anion spray in household spatial decoration.
Compared with prior art, the present invention at least has advantages below：
(1) magnesium imperial or royal seal prismatic crystal home room anion spray provided by the present invention, by the glue using synthetic resin emulsion
Used as filmogen, emulsion can infiltrate into the inside of metope and top surface base material with the infiltration of moisture so that anion for knot agent
Spray can be perfectly adhered on metope or top surface base material, and VOC free is discharged, safety and environmental protection；Add in system electric
The materials such as stone powder, paraffin and silver ion so that anion spray has anion releasing, shielding neutron, reflection electromagnetic wave
And the performance of sterilization, the addition of paraffin, because the density ratio water of paraffin is low and surface tension of paraffin is low, in the process for using
In, with the evaporation of moisture, the paraffin for being enclosed with anion powder is migrated to air surface so that the anion powder with air contact
Specific surface area increase, and then cause a small amount of anion powder can just discharge substantial amounts of anion；The addition of silver ion is more held
Easily cause the electric potential difference between anion powder crystal so that air is ionized, the water that the electron attachment hit is closed on and
Oxonium ion simultaneously makes it be converted into negative aeroion, improves the burst size of anion in anion powder；And using poly- second in system
Alkene wax, it has the fusion temperature and lower surface tension higher than paraffin, in magnesium imperial or royal seal prismatic crystal home room anion spray
When forming film layer, as the evaporation of moisture is easier to migrate to film surface, finally with anion spray in other component shapes
Into the top layer of " wax ", that is, substantially increase the amount of film surface anion powder；When its be used for home room metope and
During top surface, not only continuously in air anion is conveyed so that the negative ion concentration more and more higher in whole space, and
By causing anion powder that stepped distribution is formed in film layer the animal migration of paraffin and Tissuemat E, system is considerably increased
The contact area of middle anion powder and air, and then the function of anion powder anion releasing is improve, and be conducive in shielding
Son and transmitting electromagnetic wave, reduce the impact of neutron and electromagnetic wave to health.
(2) preparation method of a kind of magnesium imperial or royal seal prismatic crystal home room anion spray provided by the present invention, by using high
Pressure rushes mill apparatus so that each material in system is well dispersed, and especially paraffin and Tissuemat E can be very good to wrap up negative
Ion powder, forms stable mixed slurry.
Specific embodiment
Below in conjunction with specific implementation, the present invention is described in detail.
When stated in the form of scope, preferred scope or preferred numerical upper limits and lower limit certain amount, concentration or its
It is worth or when parameter, it should be understood that equivalent to specifically disclose by by any pair range limit or preferred value with appoint
Any scope that meaning range lower limit or preferred value combine, and do not consider whether the scope specifically discloses.Unless referred in addition
Go out, numerical range value listed herein is in the end points including scope, and all integers and fraction within the scope of being somebody's turn to do.
Unless otherwise indicated, herein all of percentage ratio, number, ratio etc. are by weight.
The material of this paper, method and embodiment are exemplary, and unless stated otherwise, be should not be construed as restricted
's.
Details are as follows for the present invention：A kind of magnesium imperial or royal seal prismatic crystal home room anion spray, in parts by weight containing following component：
Sodium hydroxide：0.05-3 parts, anion powder：3-10 parts, paraffin：3-15 parts, synthetic resin emulsion：45-85 parts, thickening agent：
0.1-1.5 parts, preservative：0.1-1 parts, silver ion：1-3.5 part, Tissuemat E：1-5 parts.
Wherein, magnesium imperial or royal seal prismatic crystal home room anion spray provided by the present invention, by weight, including 0.05-3 parts
Sodium hydroxide, preferably 0.1-2.5 parts；Sodium hydroxide in the present invention mainly as PH regulators, as people are to household
The color in space requires more and more higher, in order that system can meet the double requirements of colorful gorgeous and stable system, by system
PH control between 7.5-8.5.
Wherein, magnesium imperial or royal seal prismatic crystal home room anion spray provided by the present invention, by weight, including 3-10 parts
Anion powder, preferably 5-10 parts.The present invention adopt anion powder be human use's nature produce anion principle, people
Work synthesize or proportioning a kind of complex mineral, typically all tourmaline powder+lanthanide series or rare earth element, its it is main into
Part is as shown in the table：
| Composition | Al2O3 | SiO2 | B2O3 | MgO | Fe2O3 | Na2O |
| Content (%) | 35.10 | 34.81 | 11.02 | 4.70 | 10.18 | 0.91 |
| Composition | K2O | CaO | P2O5 | TiO2 | FeO | Other |
| Content (%) | 0.04 | It is micro | 0.22 | 0.26 | 1.35 | It is micro |
Its mesh number is 500-10000, more preferably more preferably 3000-9000,6000-8000, and anion powder
It is XY for chemical general formula3Z6[Si6018](BO3)3(OH)4, the wherein position of X mainly occupies by Na, Ca, K, the main quilt in the position of Y
Mg, Fe, A1, Li are occupied, and the position of Z is mainly occupied by A1, due to the difference of X, Y, the displacement of Z location and soil boy structure, shape
Into numerous species, the magnesium imperial or royal seal prismatic crystal powder when Y is based on Mg.Anion powder is the cured layer for being aided with the formation of anion spray
Anion releasing provides technical support.
Wherein, magnesium imperial or royal seal prismatic crystal home room anion spray provided by the present invention, by weight, including 3-15 parts
Paraffin, preferably 5-10 parts.The paraffin that the present invention is adopted is also known as crystalline wax, typically white, tasteless waxy solid, in 47-
64 DEG C of fusings, density about 0.9g/cm3, it is dissolved in gasoline, Carbon bisulfide, dimethylbenzene, ether, benzene, chloroform, carbon tetrachloride, Petroleum
Deng a class non-polar solven, water insoluble and methanol polar solvent.Paraffin refined wax is good insulator, and its resistivity is 1013-
1017Ohm meter, will be high than the most of materials in addition to some plastics (especially Teflon).Paraffin is also good heat accumulation
Material, its specific heat capacity is 2.14-2.9JgK, and heat of fusion is 200-220Jg.Paraffin is as hydrogenous material to strong γ
The neutron source (such as radium-beryllium neutron source) of background, it is further excellent with the good effect for absorbing seed and then appropriateness shielding neutron
Elect as, paraffin has the fusion temperature and lower surface energy higher than paraffin using modified Tissuemat E, Tissuemat E,
It is more beneficial for being migrated to air surface in anion spray system, transport efficiency is up to 30% than paraffin.
Wherein, magnesium imperial or royal seal prismatic crystal home room anion spray provided by the present invention, by weight, including 45-85 parts
Synthetic resin emulsion, preferably 55-65 parts, as long as the synthetic resin emulsion that the present invention is adopted can play each of cementation
Kind of synthetic resin emulsion, in order to it is preferably supported the use with home room, preferred silicone acrylic emulsion, epoxy resin latex and
At least one in acrylic emulsion, the viscosity of the synthetic resin emulsion is 300-1000cp, and solid content is 20-40wt%,
PH value is 8-9, and acid number is 40-60, and the synthetic resin emulsion acts primarily as cementation, and the other materials in anion spray are glued
Altogether, to produce firm adhesion with base material.
Wherein, magnesium imperial or royal seal prismatic crystal home room anion spray provided by the present invention, by weight, including 0.1-1.5
Part thickening agent, preferably 0.5-1 parts, the thickening agent that the present invention is adopted with the system to have good thickening, suspension, divide
The characteristics such as scattered, emulsifying, bonding, film forming, protection moisture and offer protection adhesive tape, can specifically select hydroxyethyl cellulose type thickening
At least one in agent, alkali soluble is swollen acrylic thickener, sodium bentonite.
Wherein, magnesium imperial or royal seal prismatic crystal home room anion spray provided by the present invention, by weight, including 0.1-1 parts
Preservative, preferably 0.5-1 parts, the acting as of the preservative that the present invention is adopted postpone growth of microorganism and cause anion spray
Corruption, can in hydroxybenzoate class, imidazolidinyl urea, KF88, bronopol, 1- phenoxy group propan-2-ols etc. extremely
Few one kind, as long as addition specifies content less than products standards.
Wherein, magnesium imperial or royal seal prismatic crystal home room anion spray provided by the present invention, by weight, including 1-3.5 parts
Silver ion, preferably 1-2.5 parts, the silver ion that the present invention is adopted is the silver ion for losing more than one electronics, with ion like
State is present, generally in positive charge, such as Ag1+、Ag2+、Ag3+Deng.Silver ion has Oxidation, is usually used in killing in daily life
Bacterium is sterilized.Its not only effect with antisepsis and sterilization in the anion spray system of the present invention, also causes anion spray to exist
During the cured film formed on air-conditioning, the air channel of air purifier, the loop constituted using the silver ion in cured film is produced
Induced current, produces reverse electromagnetic field and is shielded by induced current.Metal good conductor energy reflection electromagnetic wave, that is, work as metal mesh opening
When footpath is less than electromagnetic wavelength (wavelength=light velocity/speed) 1/4, then electromagnetic wave can not be passed through, so as to substantially increase product
The functions such as antistatic, X-ray-preventing and ultraviolet.
Wherein, anion spray provided by the present invention, in parts by weight, including 1-5 part Tissuemat Es, Tissuemat E,
Preferably 3-5 parts, are widely used because it has excellent tolerance to cold, thermostability, chemical resistance and wearability；Poly- second
The action principle of alkene wax is such：Tissuemat E is being cooled to often during (about 100-140 DEG C) is dissolved in solvent in high temperature
Separate out when warm, be present in coating with microcrystalline form, because its thixotropy is conducive to the storage of coating, and coating application application it
Afterwards, film top layer can be moved in solvent volatilization process, the top layer of " wax " is finally formed with coating other components.This
Invention further increases anion powder to mobility in air using Tissuemat E, that is, substantially increase anion powder and air
Contact area, so as to substantially increase anion powder to the amount of anion releasing in air.
A kind of preparation method of above-mentioned magnesium imperial or royal seal prismatic crystal home room anion spray, comprises the steps：
(1) at normal temperatures and pressures, by the synthetic resin emulsion of formula ratio 1/2-2/3, and the anion powder, poly- of formula ratio
Ethylene waxes and paraffin sequentially add high pressure and rush in mill apparatus, rush mill with the rotating speed stirring of 1000-3000r/min and are dispersed into suspension oar
Body；
(2) synthetic resin emulsion for being uniformly added into surplus is rushed in mill apparatus to high pressure, and mixture is adjusted with sodium hydroxide
The pH value of system to 8-8.5, after the rotating speed dispersed with stirring of 1000-3000r/min, vibration filtering；
(3) thickening agent, preservative and the silver ion of formula ratio are uniformly added into, are stirred with the rotating speed of 1000-3000r/min
After being uniformly dispersed, subpackage.
Wherein, high pressure rushes the patented product that mill apparatus are our company, and its Patent No. " CN203842640U ", the equipment exists
Allow mixed slurry to circulate under the drive of high-pressure pump, and mixed slurry is fully contacted with wear-resistant ball, and in stainless steel ball
High-speed rotation, so that mixed slurry is sufficiently mixed uniformly.
Unless otherwise defined, all technologies used herein and scientific terminology have and those skilled in the art of the invention
The identical meanings being generally understood that.If there is contradiction, it is defined by the definition that the application is provided, wherein：
Magnesium imperial or royal seal prismatic crystal is referred to chemical general formula as XY3Z6[Si6018](BO3)3(OH)4, wherein the position of X mainly by Na, Ca,
K is occupied, and the position of Y is mainly occupied by Mg, Fe, A1, Li, and the position of Z is mainly occupied by A1, due to X, Y, Z location displacement with
And the difference of soil boy structure, numerous species are defined, the tourmaline powder when Y is based on Mg.
Embodiment 1：
A kind of magnesium imperial or royal seal prismatic crystal home room anion spray, it contains by weight following component：Sodium hydroxide：0.8kg,
Anion powder：5kg, paraffin：3kg, synthetic resin emulsion：84kg, thickening agent：0.5kg, preservative：0.5kg, silver ion：
3.2kg, Tissuemat E：3kg；The preparation method of the magnesium imperial or royal seal prismatic crystal home room anion spray, comprises the steps：
(1) at normal temperatures and pressures, by 56kg synthetic resin emulsions, and 5kg anion powder, 3kg Tissuemat Es and 3kg stones
Wax sequentially adds high pressure and rushes in mill apparatus, rushes mill with the rotating speed stirring of 1000r/min and is dispersed into suspension oar body；
(2) synthetic resin emulsion for being uniformly added into 28kg is rushed in mill apparatus to high pressure, and adjusts mixed with 0.8kg sodium hydroxide
The pH value of zoarium system is rushed after mill is uniformly dispersed, vibration filtering to after 8 with the stirring of the rotating speed of 1300r/min；
(3) 0.5kg thickening agents, 0.5kg preservative and 3.2kg silver ions are uniformly added into, are stirred with the rotating speed of 2000r/min
Mix after being uniformly dispersed, subpackage.
Wherein anion powder is 6000 tourmaline powder for mesh number and mesh number is that 9000 tourmaline powder is according to mass ratio
2:1 mix homogeneously；It is 1 according to mass ratio with acrylic emulsion that synthetic resin emulsion is pure-acrylic emulsion：3 mix homogeneously, and mix
The viscosity of synthetic resin emulsion is 480cp, and solid content is 22wt%, and pH value is 8, and acid number is 50；Thickening agent is hydroxy ethyl fiber
Element；Silver ion is liquid nano silver ion, and the effective content of its silver ion is 3wt%；Preservative is hydroxy benzoic acid esters.
Embodiment 2：
A kind of magnesium imperial or royal seal prismatic crystal home room anion spray, it contains by weight following component：Sodium hydroxide：1.5kg,
Anion powder：6kg, paraffin：10kg, synthetic resin emulsion：77kg, thickening agent：0.8kg, preservative：0.7kg, silver ion：
2kg, Tissuemat E：2kg；The preparation method of the magnesium imperial or royal seal prismatic crystal home room anion spray, comprises the steps：
(1) at normal temperatures and pressures, by 50kg synthetic resin emulsions, and 6kg anion powder, 2kg Tissuemat Es and 10kg
Paraffin sequentially adds high pressure and rushes in mill apparatus, rushes mill with the rotating speed of 1000r/min and is dispersed into suspension oar body；
(2) synthetic resin emulsion for being uniformly added into 27kg is rushed in mill apparatus to high pressure, and adjusts mixed with 1.5kg sodium hydroxide
The pH value of zoarium system is rushed after mill is uniformly dispersed, vibration filtering to after 8.2 with the stirring of the rotating speed of 1500r/min；
(3) 0.8kg thickening agents, 0.7kg preservative and 2kg silver ions are uniformly added into, are stirred with the rotating speed of 2000r/min
After being uniformly dispersed, subpackage.
Wherein, anion powder is 1500 tourmaline powder for mesh number and mesh number is that 6000 tourmaline powder is according to mass ratio
1:2 mix homogeneously；Synthetic resin emulsion is vinyl acetate emulsion, and the viscosity of vinyl acetate emulsion is 750cp, and solid content is 30wt%, pH
It is worth for 8, acid number is 52；Thickening agent is sodium bentonite；Silver ion is liquid nano silver ion, and the effective content of its silver ion
For 5wt%；Preservative is bronopol.
Embodiment 3：
A kind of magnesium imperial or royal seal prismatic crystal home room anion spray, it contains by weight following component：Sodium hydroxide：2kg, bears
Ion powder：8kg, paraffin：12kg, synthetic resin emulsion：71kg, thickening agent：1.2kg, preservative：0.3kg, silver ion：
1.5kg, Tissuemat E：4kg；The preparation method of the magnesium imperial or royal seal prismatic crystal home room anion spray, comprises the steps：
(1) at normal temperatures and pressures, by 40kg synthetic resin emulsions, and 8kg anion powder, 4kg Tissuemat Es and 12kg
Paraffin sequentially adds high pressure and rushes in mill apparatus, rushes mill with the rotating speed stirring of 2000r/min and is dispersed into suspension oar body；
(2) synthetic resin emulsion for being uniformly added into 31kg is rushed in mill apparatus to high pressure, and mixing is adjusted with 2kg sodium hydroxide
The pH value of system is rushed after mill is uniformly dispersed, vibration filtering to after 8.5 with the stirring of the rotating speed of 1000r/min；
(3) 1.2kg thickening agents, 0.3kg preservative and 1.5kg silver ions are uniformly added into, with the rotating speed of 1800r/min
After dispersed with stirring is uniform, subpackage.
Wherein anion powder is 10000 tourmaline powder for mesh number；Silicone acrylic emulsion is with epoxy resin latex according to mass ratio
For 1：1 mix homogeneously, and the viscosity of the synthetic resin emulsion is 620cp, solid content is 28wt%, and pH value is 8, and acid number is
56；Thickening agent is the swollen acrylic thickener of alkali soluble；Silver ion is liquid nano silver ion, and the effective content of its silver ion is
5.6wt%；It is 1 according to mass ratio with KF88 that preservative is hydroxy benzoic acid esters:1 mix homogeneously.
Embodiment 4：
A kind of magnesium imperial or royal seal prismatic crystal home room anion spray, it contains by weight following component：Sodium hydroxide：1kg, bears
Ion powder：10kg, paraffin：15kg, synthetic resin emulsion：67kg, thickening agent：0.1kg, preservative：0.3kg, silver ion：
1.6kg, Tissuemat E：5kg；The preparation method of the magnesium imperial or royal seal prismatic crystal home room anion spray, comprises the steps：
(1) at normal temperatures and pressures, by 38kg synthetic resin emulsions, and 10kg anion powder, 5kg Tissuemat Es and 15kg
Paraffin sequentially adds high pressure and rushes in mill apparatus, rushes mill with the rotating speed stirring of 1500r/min and is dispersed into suspension oar body；
(2) synthetic resin emulsion for being uniformly added into 29kg is rushed in mill apparatus to high pressure, and mixing is adjusted with 1kg sodium hydroxide
The pH value of system is rushed after mill is uniformly dispersed, vibration filtering to after 8.1 with the stirring of the rotating speed of 2000r/min；
(3) 0.1kg thickening agents, 0.3kg preservative and 1.6kg silver ions are uniformly added into, are stirred with the rotating speed of 1000r/min
Mix after being uniformly dispersed, subpackage.
Wherein anion powder is 3800 tourmaline powder for mesh number and mesh number is that 8000 tourmaline powder is according to mass ratio
3:1 mix homogeneously；Synthetic resin emulsion is acrylic emulsion, and the viscosity of acrylic emulsion is 600cp, and solid content is
32wt%, pH value is 8, and acid number is 55；Thickening agent is hydroxyethyl cellulose；Silver ion be liquid nano silver ion, and its silver from
The effective content of son is 6wt%；Preservative is imidazolidinyl urea.
Performance test：
(1) to each performance indications of the magnesium imperial or royal seal prismatic crystal home room anion spray prepared by embodiment of the present invention 1-4
Detected, concrete numerical value is as shown in table 1：
Table 1：Property indices
| Project | Standard is required | Examination criteria |
| Condition in container | It is in uniform state after stirring without lump | HG/T2458-1993 |
| Application property | Spraying | ----- |
| Drying time (surface drying) h | ≤2h | GB/T1728-1989 |
| Bin stability (1 year) | Never degenerate | HG/T2458-1993 |
| Radioactive material radionuclides limitation | Meet the index request of A class finishing materials | GB6566-2010 |
Remarks：Wherein radiological safety detection method is：50cm × 50cm × 1.2cm common white glass is taken, is entered with 5g products
Row even application, room temperature 24h is pressed after being dried《GB6566-2010 radioactive material radionuclides limitations》Detected.
(2) effect of magnesium imperial or royal seal prismatic crystal home room anion spray anion releasing
In order to test the effect of the home room anion spray anion releasing that embodiment of the present invention 1-4 is provided, and
Introduce 4 groups of contrast groups, contrast groups 1 not spray anion spray, contrast groups 2 with when preparation method with embodiment 1, it is different
Part is will to be added without paraffin and Tissuemat E component；The proportioning and preparation method of contrast groups 3 with embodiment 1, difference
Place is to be added without silver ion；With embodiment 1, difference is to be added without poly- second to the proportioning and preparation method of contrast groups 4
Alkene wax, and we are surveyed using the methods of anion static state emission measure and anion dynamic two kinds of generating capacity test anion
Fixed, the method for testing of wherein anion static state emission measure is：1L products are taken, is contained with 1L measuring cups, with static anionic textiles instrument
Approach test；The method of testing of anion dynamic emission amount is：5 50cm × 50cm × 1.2cm common white glass is taken, it is common per
White glass 5g products carry out even application, and spraying is inward-facing to make bell glass, is placed on simple glass table top, by 1L glass graduates
Bell glass central authorities are inverted in, after 15 minutes, with dynamic anionic textiles instrument the anion in 15 minutes test glass graduates are continued
Burst size.The technical specification of gained is as shown in table 2：
The anion emission amount situation test of the anion spray of table 2
| Project name | Anion static state emission measure | Anion dynamic emission amount (15 minutes) |
| Contrast groups 1 | 0 | 0 |
| Contrast groups 2 | 123/cm3 | 540/cm3More than |
| Contrast groups 3 | 120/cm3 | 3800/cm3More than |
| Contrast groups 4 | 123/cm3 | 3200/cm3More than |
| Embodiment 1 | 124/cm3 | 4500/cm3More than |
| Embodiment 2 | 150/cm3 | 6000/cm3More than |
| Embodiment 3 | 200/cm3 | 7600/cm3More than |
| Embodiment 4 | 245/cm3 | 9100/cm3More than |
As shown in Table 2, by comparing contrast groups 1 and embodiment 1, magnesium imperial or royal seal prismatic crystal home room anion spray energy
Effective anion releasing；By comparing contrast groups 2 and embodiment 1, there is the anion spray for adding paraffin and Tissuemat E component
Anion dynamic emission amount will greatly improve, this is primarily due to paraffin and the density of Tissuemat E itself is relatively low, and surface
Tension force is little, easily migrates to air surface, and during anion spray use, with the evaporation of moisture, paraffin drives negative
Ion powder to air surface is migrated, and the surface tension and density of paraffin and Tissuemat E are inconsistent, in the evaporation with moisture
When migrating to air surface, define stepped, further increase the contact area of anion powder and air in system, so as to
Substantially increase the dynamic emission amount of anion powder；By comparing contrast groups 3 and embodiment 1, silver ion is added also to help
In the raising of anion dynamic emission amount, this is primarily due to pyroelectricity and the piezoelectricity having in anion powder, when component body
When adding silver ion in system, the small changes such as air flow are even similar to, it is easier to cause the potential between composition crystal
Difference, so that air is ionized, water that the electron attachment hit is closed on and oxonium ion simultaneously make it be converted into negative aeroion；
By comparing contrast groups 4 and embodiment 1, being added without Tissuemat E will affect not on the static test result of negative ion amount
Greatly, the burst size but to negative ion amount is impacted, and is unfavorable for anion part anion releasing amount；By comparing embodiment 1-4
Understand, as anion powder occupies the increase of ratio, anion static state emission measure and dynamic generating capacity are substantially improved, and this is significantly
The use range of home room anion spray is widened, to provide technical support rich in anion in large space；
(3) practical effect of magnesium imperial or royal seal prismatic crystal home room anion spray
Lee has newly purchased a set of new house because marrying, and when finishing, Lee is understanding the material of home room in depth
After material diatom ooze, emulsion paint and magnesium imperial or royal seal prismatic crystal home room anion spray, the magnesium imperial or royal seal prepared by the embodiment of the present invention 1 has been selected
Prismatic crystal home room anion spray fits up metope and top surface, and after finishing, abnormal flavour is little, and does not have any discomfort to body, and
Lee respectively live half a year, 1 year, 2 years, 3 years, 5 years, 7 years and 10 years when, same test point using dynamic bear from
The indoor anion concentration of sub- detector detection, the result of concrete test is as shown in table 3：
The magnesium imperial or royal seal prismatic crystal home room anion spray of table 3 is used for anion releasing effect during home room
| Project name | Half a year | 1 year | 2 years | 3 years | 5 years | 7 years | 10 years |
| Negative ion amount (individual/cm3) | 18012 | 17558 | 17800 | 17480 | 17210 | 16834 | 16021 |
As shown in Table 3, when magnesium imperial or royal seal prismatic crystal home room anion spray provided by the present invention is used for home room, only
Very thin one layer is sprayed, general thickness is 0.05-0.1mm, from the point of view of test data, magnesium imperial or royal seal prismatic crystal home room anion spray
For home room metope and top surface when, during using 10 years, the negative ion amount in home room uses when ratio with starting spraying
Relatively decline less than 10%, illustrate the magnesium imperial or royal seal prismatic crystal home room anion spray of the embodiment of the present invention 1 during use, bear
The burst size of ion hardly declines, but can continuously anion releasing, purify air, it is ensured that people's living environment
Safety and Health, and it can be tuned into different design and colors according to the demand of people, to meet the diverse requirements in market.
It is provided by the present invention for magnesium imperial or royal seal prismatic crystal home room anion spray, by the migration of paraffin and Tissuemat E
Characteristic, significantly increases the contact area of the anion powder in system and air, so that using a small amount of anion powder just
Substantial amounts of anion can be discharged, support is provided in the use of household spatial surface for anion spray, in addition, the system
In only with anion powder, shielding action of other extender pigments to anion powder is reduced, while be more favorable to system oozing
Thoroughly to metope or top surface base material；And the sterilizing function of anion itself combines the sterilizing function of silver ion, substantially increases house
The ability of murdering of space-to-space antibacterial is occupied, purify air, sterilization, the environment space to provide safety and Health provides condition.
More than, the only present invention preferably specific embodiment, but the protection domain invented is not limited thereto, any ripe
Know those skilled in the art the invention discloses technical scope in, the change or replacement that can be readily occurred in all should be contained
Cover within protection scope of the present invention.Therefore, protection scope of the present invention should be defined by the protection domain of claims.
Claims (10)
1. a kind of magnesium imperial or royal seal prismatic crystal home room anion spray, it is characterised in that in parts by weight containing following component：Hydroxide
Sodium：0.05-3 parts, anion powder：3-10 parts, paraffin：3-15 parts, synthetic resin emulsion：45-85 parts, thickening agent：0.1-1.5
Part, preservative：0.1-1 parts, silver ion：1-3.5 part, Tissuemat E：1-5 parts.
2. magnesium imperial or royal seal prismatic crystal home room anion spray according to claim 1, it is characterised in that contain in parts by weight
Following component：Sodium hydroxide：0.1-2.5 parts, anion powder：5-10 parts, paraffin：5-10 parts, synthetic resin emulsion：55-65 parts,
Thickening agent：0.5-1 parts, preservative：0.5-1 parts, silver ion：1-2.5 part；Tissuemat E：3-5 parts.
3. magnesium imperial or royal seal prismatic crystal home room anion spray according to claim 1, it is characterised in that contain in parts by weight
Following component：Sodium hydroxide：1 part, anion powder：10 parts, paraffin：15 parts, synthetic resin emulsion：67 parts, thickening agent：0.1 part,
Preservative：0.3 part, silver ion：1.6 part；Tissuemat E：5 parts.
4. the magnesium imperial or royal seal prismatic crystal home room anion spray according to any one of claims 1 to 3, it is characterised in that institute
The tourmaline powder stated anion powder and be 500-10000 for mesh number.
5. the magnesium imperial or royal seal prismatic crystal home room anion spray according to any one of Claims 1 to 4, it is characterised in that institute
State synthetic resin emulsion for pure-acrylic emulsion, styrene-acrylic emulsion, vinyl acetate emulsion, silicone acrylic emulsion, polyaminoester emulsion, epoxy resin latex and
At least one in acrylic emulsion, and the viscosity of the synthetic resin emulsion is 300-1000cp, solid content is 20-
40wt%, pH value is 8-9, and acid number is 50-60.
6. the magnesium imperial or royal seal prismatic crystal home room anion spray according to any one of Claims 1 to 5, it is characterised in that institute
Thickening agent is stated at least one in hydroxyethyl cellulose, alkali soluble is swollen acrylic thickener, sodium bentonite.
7. the magnesium imperial or royal seal prismatic crystal home room anion spray according to any one of claim 1～6, it is characterised in that institute
It is liquid nano silver ion to state silver ion, and the effective content of its silver ion is 3-8wt%.
8. the magnesium imperial or royal seal prismatic crystal home room anion spray according to any one of claim 1～7, it is characterised in that institute
State preservative in hydroxy benzoic acid esters, imidazolidinyl urea, KF88, bronopol, 1- phenoxy group propan-2-ols etc. at least
It is a kind of.
9. a kind of preparation method of the magnesium imperial or royal seal prismatic crystal home room anion spray according to any one of claim 1～8,
Characterized in that, comprising the steps：
(1) by the synthetic resin emulsion of formula ratio 1/2-2/3, and the anion powder of formula ratio, Tissuemat E and paraffin are successively
Add high pressure to rush in mill apparatus, rush mill and be dispersed into suspension oar body；
(2) synthetic resin emulsion for being uniformly added into surplus is rushed in mill apparatus to high pressure, and mixed system is adjusted with sodium hydroxide
PH value to 7.5-8.5, high-speed stirred dispersion after, vibration filtering；
(3) thickening agent, preservative and the silver ion of formula ratio, after dispersed with stirring is uniform, subpackage are uniformly added into.
10. a kind of magnesium imperial or royal seal prismatic crystal home room anion spray according to any one of claim 1～8 is in home room
Application in decoration.
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| CN201611169080.9A CN106590253A (en) | 2016-12-16 | 2016-12-16 | Magnesium seal prism home space negative ion spray and preparation method and application thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110227334A (en) * | 2019-06-21 | 2019-09-13 | 广州市纳能环保技术开发有限公司 | A kind of anion air purifying solution and preparation method thereof |
| CN111266028A (en) * | 2020-04-10 | 2020-06-12 | 东莞醇原纳米新材料有限公司 | Anion purification spray blending method |
| WO2021207805A1 (en) * | 2020-04-13 | 2021-10-21 | Bonilha Mariana | Water-based composition for producing an antiviral, antimicrobial coating film |
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| CN1899626A (en) * | 2005-07-21 | 2007-01-24 | 朱枫林 | Multifunction negative ion colorless spray agent |
| CN105860701A (en) * | 2016-04-18 | 2016-08-17 | 孙小力 | Anion-aqueous interior-wall paint and preparing method |
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| CN1648178A (en) * | 2004-01-19 | 2005-08-03 | 范存玉 | Long action negative ion antiseptic function paint |
| CN1899626A (en) * | 2005-07-21 | 2007-01-24 | 朱枫林 | Multifunction negative ion colorless spray agent |
| CN105860701A (en) * | 2016-04-18 | 2016-08-17 | 孙小力 | Anion-aqueous interior-wall paint and preparing method |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110227334A (en) * | 2019-06-21 | 2019-09-13 | 广州市纳能环保技术开发有限公司 | A kind of anion air purifying solution and preparation method thereof |
| CN111266028A (en) * | 2020-04-10 | 2020-06-12 | 东莞醇原纳米新材料有限公司 | Anion purification spray blending method |
| WO2021207805A1 (en) * | 2020-04-13 | 2021-10-21 | Bonilha Mariana | Water-based composition for producing an antiviral, antimicrobial coating film |
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Application publication date: 20170426 |