CN105859354A - Humic acid-containing water-soluble fertilizer for increasing selenium content of strawberries and preparation method and application thereof - Google Patents

Humic acid-containing water-soluble fertilizer for increasing selenium content of strawberries and preparation method and application thereof Download PDF

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Publication number
CN105859354A
CN105859354A CN201610206177.6A CN201610206177A CN105859354A CN 105859354 A CN105859354 A CN 105859354A CN 201610206177 A CN201610206177 A CN 201610206177A CN 105859354 A CN105859354 A CN 105859354A
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humic acid
edta
soluble fertilizer
potassium
map
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CN201610206177.6A
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CN105859354B (en
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孙茂旭
孙磊
苏群
刘勇
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Shandong Baoyuan Biological Technology Co Ltd
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Shandong Baoyuan Biological Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C21/00Methods of fertilising, sowing or planting

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  • Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Fertilizers (AREA)

Abstract

The invention relates to a humic acid-containing water-soluble fertilizer for increasing the selenium content of strawberries and a preparation method and application thereof. The humic acid-containing water-soluble fertilizer comprises the following components in parts by weight: 300-350 parts of urea, 85-115 parts of monoammonium phosphate, 300-360 parts of potassium sulfate, 5-15 parts of EDTA chelated Ca, 2-8 parts of EDTA chelated Mg, 0.5-1.5 parts of sodium selenite, 80-120 parts of potassium fulvate and 110-138 parts of brown sugar. The humic acid-containing water-soluble fertilizer for increasing the selenium content of strawberries, provided by the invention, has important functions of improving soil, increasing the selenium content of strawberries, improving the sugar degree and color, increasing the yield and quality and the like.

Description

Improve Fructus Fragariae Ananssae Se content containing humic acid water-soluble fertilizer and preparation method and application
Technical field
The present invention relates to fertilizer field, be specifically related to a kind of improve Fructus Fragariae Ananssae Se content containing humic acid water-soluble fertilizer And preparation method and application, it is especially useful in Fructus Fragariae Ananssae trophophase absorbs selenium element, improves yield and pol.
Background technology
Selenium is one of trace element of needed by human, and it has antioxidation, anti-inflammatory, alleviates heavy metal in human body Accumulation, the biological function of raising body immunity, contribute to anti-cancer, the liver protecting and protection vision etc., It is described as " life kindling material ".
China soil is vast, and geology, landforms, natural environment and climate are complicated, under the Chinese Academy of Agricultural Sciences with all strength tissue, China had once carried out the national researching determining about selenium distribution.According to survey result, there is the ground of 72% in China District lacks selenium or lean selenium, has the population selenium Deficiency of Intake of 2/3, and about 700,000,000 people are in low selenium band.Southeastern coast is for I State's district rich in selenium, the most only 0.1ppm, be the minimum that specifies of the United Nations's health organization.
And in strawberry fruit containing abundant aminoacid, fructose, sucrose, glucose, citric acid, malic acid, Pectin, carotene, vitamin B1、B2, nicotinic acid and mineral calcium, magnesium, phosphorus, potassium, ferrum etc., these Nutrient has good facilitation to growth promoter.Fructus Fragariae Ananssae selenium-rich has two kinds of approach: Soil accumulation and fertilizer Supplement.But China's most area lacks selenium or lean selenium, therefore, just becomes for Fructus Fragariae Ananssae Selenium Supplement from fertilizer Inevitable approach.Utilize the feature that Fructus Fragariae Ananssae is the strongest to the absorbability of selenium when leaf stretching period and full-bloom stage, for it Selenium Supplement element.Meanwhile, selenium element is distributed at most in seed, and the seed of Fructus Fragariae Ananssae is distributed in fruit surface, Can be absorbed by the body and utilize part more.
Summary of the invention
An object of the present invention is to provide one can promote that Fructus Fragariae Ananssae grows, and improves yield, can improve again grass Certain kind of berries fruit pol and Se content special containing humic acid water-soluble fertilizer.
It is a further object of the present invention to provide a kind of preparation containing humic acid water-soluble fertilizer improving Fructus Fragariae Ananssae Se content Method.
To achieve these goals, the present invention adopts the following technical scheme that
A kind of improve Fructus Fragariae Ananssae Se content containing humic acid water-soluble fertilizer, including the component of following weight portion: carbamide 300-350 part, MAP 85-115 part, potassium sulfate 300-360 part, EDTA chelates Ca 5-15 part, EDTA chelates Mg 2-8 part, sodium selenite 0.5-1.5 part, potassium fulvate 80-120 part, brown sugar 110-148 Part.
Preferably, the described water-soluble fertilizer containing humic acid includes the component of following weight portion: carbamide 310-340 part, MAP 90-110 part, potassium sulfate 310-350 part, EDTA chelates Ca 7-13 part, and EDTA chelates Mg 3-7 part, sodium selenite 0.7-1.3 part, potassium fulvate 85-115 part, brown sugar 115-143 part.
It is further preferred that the described water-soluble fertilizer containing humic acid includes the component of following weight portion: carbamide 320-330 part, MAP 95-105 part, potassium sulfate 320-340 part, EDTA chelates Ca 9-11 part, EDTA chelates Mg 4-6 part, sodium selenite 0.9-1.1 part, potassium fulvate 95-105 part, brown sugar 120-138 Part.
Preferably, the particle diameter of carbamide of the present invention is 0.85mm-2.80mm;Described MAP, sulphuric acid Potassium, potassium fulvate, EDTA chelating Ca, EDTA chelating Mg, sodium selenite, brown sugar are powder.
Research finds, described in when each component is in above-mentioned particle size range containing humic acid water-soluble fertilizer action effect Good.
Carbamide of the present invention, MAP, potassium sulfate, sodium selenite are known commercially available prod, as can Throw Xinjiang spread out purchased from chemical inc of alliance, Shandong, the peaceful Chemical Co., Ltd. in Hubei three, state respectively Pool potassium salt Co., Ltd, De Rui bio tech ltd, Zhengzhou.Wherein, described MAP contains Nitrogen 12%, phosphorous 61%;Containing selenium 50% in described sodium selenite.(being mass fraction)
Potassium fulvate of the present invention, brown sugar, the most understood by one of ordinary skill in the art, it is possible to commercially available The known raw material obtained, wherein, described potassium fulvate is nitrogenous for 3%-4%, is 10%-11% containing potassium, contains Organic 60%-70%, (being mass fraction).Above-mentioned raw materials is purchased from Huifeng, the Yichang limited public affairs of fertilizer industry Department, Hong Yuan, east, Tengzhou City, Shandong Province Food Co., Ltd etc., this is not specially limited by the present invention.
Additionally, EDTA of the present invention chelating Ca (EDTA-Ca), EDTA chelating Mg (EDTA-Mg), For understood by one of ordinary skill in the art, it is possible to the known secondary and micro-element fertilizers being commercially available, it is purchased from stone Village Jack Chemical Co., Ltd. of family, Shijiazhuang Jack Chemical Co., Ltd. etc., this is not done limit especially by the present invention Fixed.The 14.5-15.5% Han Ca in described EDTA-Ca, the 14.5-15.5% Han Mg in EDTA-Mg.(it is Mass fraction).
Weight portion of the present invention can be the unit of weights well known in the art such as μ g, mg, g, kg, it is possible to To be its multiple, such as 1/10,1/100,10 times, 100 times etc..
The present invention also provides for the above-mentioned preparation method containing humic acid water-soluble fertilizer, comprises the steps:
1) carbamide, MAP are pulverized, in proportion with potassium sulfate, potassium fulvate mixing, obtain mixed material;
2) brown sugar is levigate, in proportion with step 1) mixing of gained mixed material;
3) EDTA-Ca, EDTA-Mg, sodium selenite are weighed in proportion, mixing, it is then added to step 2) In gained mixed material, mixing;Obtain.
Wherein, step 1) carbamide, MAP preferred powder are broken to 100 mesh;
Step 2) can use colloid mill that brown sugar is levigate, the colloid mill of available levigate viscous food, levigate is red The available double conic rotary vacuum dryer of sugar is dried.
The present invention also provides for the application on strawberry cultivating of the above-mentioned water-soluble fertilizer containing humic acid.Different according to Fructus Fragariae Ananssae Kind and resident time, it is proposed that mu amount of application 40-50kg, full-bloom stage is used once, and fruit picking early stage is used once, Fruit picking is used once mid-term;Foliage-spray is better.
Containing substantial amounts of aminoacid, vitamin and trace element in brown sugar, for improvement soil, improve Fructus Fragariae Ananssae Sugar content in fruit, increase yield and have an effect of highly significant, and containing Partial Antioxidation material and Electrolyte, can promote the growth of Fructus Fragariae Ananssae to a certain extent.Brown sugar is come by the present invention as aminoacid and saccharide Source, potassium fulvate originates as humic acid, both provided the nutrition that Fructus Fragariae Ananssae needs, promotion Fructus Fragariae Ananssae to nitrogen, phosphorus, Absorbing of potassium element, improves pol and the yield of strawberry fruit, again can appropriateness improvement soil;Add Sodium selenite and chelating Ca, chelating Mg, middle trace element is reasonably combined, can increase the middle trace in fruit The content of element, improves quality and yield.
Of the present invention containing humic acid water-soluble fertilizer, can promote that Fructus Fragariae Ananssae grows, improve yield, can carry again High-quality, uses conveniently, and fertilizer efficiency is high, is conducive to promoting the use of.In addition to being particularly suitable for Fructus Fragariae Ananssae, the present invention The described water-soluble fertilizer containing humic acid may be equally applicable to other fruit, also can play a certain degree of carrying Se content in high fruit, the purpose improved the yield and quality.
Accompanying drawing explanation
Fig. 1 is the technological process of production schematic diagram that the present invention contains humic acid water-soluble fertilizer.
Detailed description of the invention
Following example are used for illustrating the present invention, but are not limited to the scope of the present invention.Embodiment is not noted Bright concrete technology or condition person, according to the technology described by the document in this area or condition, or according to product Product description is carried out.Agents useful for same or instrument unreceipted production firm person, be and can be purchased by regular channel Available conventional products.
Embodiment 1-7
Embodiment 1-7 each provide a kind of improve Fructus Fragariae Ananssae Se content containing humic acid water-soluble fertilizer, its formula have Body is shown in Table 1.
Table 1 (units/kg)
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Embodiment 7
Carbamide 310 340 325 300 350 310 340
MAP 110 90 100 85 115 90 110
Potassium sulfate 340 315 330 300 360 310 350
EDTA-Ca 12 5.2 10 5 15 7 13
EDTA-Mg 5 7 5 2 8 3 7
Sodium selenite 1 0.8 1 0.5 1.5 0.7 1.3
Potassium fulvate 85 100 100 80 120 85 115
Brown sugar 137 142 129 110 148 115 143
Embodiment 8
Present embodiments provide embodiment 1-7 any one improve Fructus Fragariae Ananssae Se content containing humic acid water-soluble fertilizer Preparation method, sees Fig. 1, specifically includes following steps:
1) carbamide, MAP are weighed the most in proportion, be crushed to 100 mesh, with potassium sulfate, fulvic acid Potassium mixes, and obtains mixed material;
2) levigate for brown sugar colloid mill, levigate brown sugar double conic rotary vacuum dryer is dried, then with Step 1) mixing of gained mixed material;
3) EDTA-Ca, EDTA-Mg, sodium selenite are weighed the most in proportion, mixing, added Auxiliary agent;Gained is added auxiliary agent and joins step 2) in the mixed material that obtains, stir;Quantitative package, Be improved Fructus Fragariae Ananssae Se content containing humic acid water-soluble fertilizer.
Experimental example 1
Fructus Fragariae Ananssae is applied fertilizer containing humic acid water-soluble fertilizer (preparing by embodiment 8 method) described in embodiment 1-3 Investigate.
1) it is measured growing area soil analyzing, investigation strawberry cultivating district, Fushan District, Yantai soil nutrient status, Soil sampling measures and analyzes respectively, and on the whole, soil organic matter content is on the low side, and potassium content is on the low side, and soil is slightly Acidifying.
2) fertilising field test, strawberry cultivars Syria, use fertilizer described in embodiment 1-3 for each every mu 30-40kg。
Application test one:
Within 2014, in 2 peasant household fields such as bar town, Fushan District, Yantai Li De photographs, use described in embodiment 1-3 Fertilizer more than 20 mu, each mu is executed 40kg, is compareed plot and use reference examples 1 fertilizer (sea, Qingdao champion 16-6-32 Sargassum punching fertilising) 50kg.Concrete yield increase effect is shown in Table 2.
Table 2 yield increase effect contrast table
Process Per mu yield (kg) Yield increases (%)
Product described in embodiment 1 3101.8 7.5
Product described in embodiment 2 3052.8 5.8
Product described in embodiment 3 3179.7 10.2
Reference examples 1 2885.4 ---
Knowable to synopsis, compared with reference examples 1 fertilizer, use the average every mu of increasing of Fructus Fragariae Ananssae of embodiment 1-3 fertilizer Producing more than 7.8%, wherein product effect described in embodiment 3 is best, reaches 10.2%.
Application test two:
Within 2014, carry out manure trial in strawberry cultivating base, Chu Tang village, bar town, Fushan District, Yantai, be divided into 4 Process, process one: mu executes fertilizer 30kg described in embodiment 1;Process two: mu executes fertilizer described in embodiment 2 30kg;Process three: mu executes fertilizer 30kg described in embodiment 3;Process four: use fertilizer described in reference examples 1 (the punching fertilising of sea, Qingdao champion 16-6-32 Sargassum), according to using explanation, 30kg/ mu.Trophophase uses three altogether Secondary.Concrete yield increase effect is shown in Table 3.
Table 3 yield increase effect contrast table
Process Per mu yield (kg) Yield increases (%)
Product described in embodiment 1 2689.1 7.2
Product described in embodiment 2 2661.5 6.1
Product described in embodiment 3 2744.3 9.4
Reference examples 1 2508.5 ---
Compared with reference examples 1, the Fructus Fragariae Ananssae growing way using embodiment 1-3 fertilizer is good, and fruit is beautiful full, mouthfeel Good, fruit aromatic flavor, wherein product effect described in embodiment 3 is best, and yield increases by 9.4%.
After fruit harvesting, atomic fluorescence spectrometry is used to detect on the selenium in fruit.Wherein, embodiment 1 Product records 35.8 micro-g kg, and embodiment 2 product records 19.4 micro-g kg, and embodiment 3 product is surveyed Obtaining 36.9 micro-g kg, reference product records 6.5 micro-g kg.Prove to use containing selenium fertilizer improving Fructus Fragariae Ananssae Se content in fruit greatly facilitates effect really, and, the Water soluble fertilizer Han humic acid described in embodiment 3 Expect that the effect played for improving the Se content in fruit is the most significant.
Press the most same experimental technique, containing humic acid water-soluble fertilizer (by embodiment 8 method described in embodiment 4-7 Preparation) also there is similar action effect, but to contain the effect effect of humic acid water-soluble fertilizer described in embodiment 1-3 Fruit is more preferably.
Although, the present invention is described in detail the most with a general description of the specific embodiments, But on the basis of the present invention, can make some modifications or improvements it, this is to those skilled in the art Obviously.Therefore, these modifications or improvements without departing from theon the basis of the spirit of the present invention, all Belong to the scope of protection of present invention.

Claims (9)

1. one kind improve Fructus Fragariae Ananssae Se content containing humic acid water-soluble fertilizer, it is characterised in that include following weight The component of part: carbamide 300-350 part, MAP 85-115 part, potassium sulfate 300-360 part, EDTA Chelating Ca 5-15 part, EDTA chelates Mg 2-8 part, sodium selenite 0.5-1.5 part, potassium fulvate 80-120 Part, brown sugar 110-148 part.
The most according to claim 1 containing humic acid water-soluble fertilizer, it is characterised in that to include following weight The component of part: carbamide 310-340 part, MAP 90-110 part, potassium sulfate 310-350 part, EDTA Chelating Ca 7-13 part, EDTA chelates Mg 3-7 part, sodium selenite 0.7-1.3 part, potassium fulvate 85-115 Part, brown sugar 115-143 part.
The most according to claim 1 containing humic acid water-soluble fertilizer, it is characterised in that to include following weight The component of part: carbamide 320-330 part, MAP 95-105 part, potassium sulfate 320-340 part, EDTA Chelating Ca 9-11 part, EDTA chelates Mg 4-6 part, sodium selenite 0.9-1.1 part, potassium fulvate 95-105 Part, brown sugar 120-138 part.
4. according to described in any one of claim 1-3 containing humic acid water-soluble fertilizer, it is characterised in that described In MAP nitrogenous 12%, phosphorous 61%;Containing selenium 50% in described sodium selenite;In described potassium fulvate Nitrogenous 3%-4%, containing potassium 10%-11%, containing organic 60%-70%;Containing Ca in described EDTA-Ca 14.5-15.5%;The 14.5-15.5% Han Mg in described EDTA-Mg.
5. according to described in any one of claim 1-3 containing humic acid water-soluble fertilizer, it is characterised in that described The particle diameter of carbamide is 0.85mm-2.80mm;Described MAP, potassium sulfate, potassium fulvate, EDTA chela Conjunction Ca, EDTA chelating Mg, sodium selenite, brown sugar are powder.
6. described in any one of claim 1-5, contain the preparation method of humic acid water-soluble fertilizer, it is characterised in that Comprise the steps:
1) carbamide, MAP are pulverized, in proportion with potassium sulfate, potassium fulvate mixing, obtain mixed material;
2) brown sugar is levigate, in proportion with step 1) mixing of gained mixed material;
3) EDTA-Ca, EDTA-Mg, sodium selenite are weighed in proportion, mixing, it is then added to step 2) In gained mixed material, mixing;Obtain.
7. the application on strawberry cultivating of the water-soluble fertilizer containing humic acid described in any one of claim 1-5.
Application the most according to claim 7, wherein said containing humic acid water-soluble fertilizer mu amount of application 40-50kg。
Application the most according to claim 7, the wherein said water-soluble fertilizer containing humic acid is used in full-bloom stage Once, fruit picking early stage is used once, and fruit picking is used once mid-term;Preferably foliage-spray.
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Cited By (1)

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Publication number Priority date Publication date Assignee Title
CN110092688A (en) * 2019-04-30 2019-08-06 新疆农业科学院科技成果转化中心 A kind of fulvic acid chelated selenium bio-fertilizer and its application in walnut plantation

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CN104904471A (en) * 2015-06-01 2015-09-16 张亚南 Strawberry planting method
CN104945168A (en) * 2015-07-14 2015-09-30 甘肃省昕农福农业科技有限责任公司 Activity compound leaf fertilizer special for potatoes
CN105272532A (en) * 2015-09-25 2016-01-27 全椒县大地种植专业合作社 Selenium-rich foliar fertilizer for walnut

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102173927A (en) * 2011-01-10 2011-09-07 金盈 Nanometer selenium probiotics composite leaf surface nutrient solution and application thereof in production of selenium-enriched pears
CN102863280A (en) * 2011-12-06 2013-01-09 新疆新纪元农牧业发展有限责任公司 Growth nutrient solution special for grapes and production process thereof
CN103380693A (en) * 2013-07-23 2013-11-06 安徽向荣农林生态产业有限公司 Strawberry culture method
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Publication number Priority date Publication date Assignee Title
CN110092688A (en) * 2019-04-30 2019-08-06 新疆农业科学院科技成果转化中心 A kind of fulvic acid chelated selenium bio-fertilizer and its application in walnut plantation
CN110092688B (en) * 2019-04-30 2021-12-21 新疆农业科学院科技成果转化中心 Fulvic acid chelated selenium biological fertilizer and application thereof in walnut planting

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