CN105778851A - Binding agent for power cable installation and preparation method thereof - Google Patents
Binding agent for power cable installation and preparation method thereof Download PDFInfo
- Publication number
- CN105778851A CN105778851A CN201610361164.6A CN201610361164A CN105778851A CN 105778851 A CN105778851 A CN 105778851A CN 201610361164 A CN201610361164 A CN 201610361164A CN 105778851 A CN105778851 A CN 105778851A
- Authority
- CN
- China
- Prior art keywords
- agent
- cyanacrylate
- polyacrylic acid
- modified
- binding agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/04—Polysiloxanes
- C09J183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Insulating Materials (AREA)
Abstract
The invention relates to a binding agent for power cable installation. The binding agent is prepared from modified ethyl cyanoacrylate, modified polyacrylic acid, an antioxidant, a stabilizing agent, an ultraviolet light absorber, an anti-settling agent, a thickening agent, a polymerization inhibitor and N,N-dimethyl formamide. The modified ethyl cyanoacrylate is prepared from hydroxyl silicone oil and ethyl cyanoacrylate through a reaction. The modified polyacrylic acid is prepared from a coupling agent and polyacrylic acid through a reaction. The invention further discloses a preparation method of the binding agent for power cable installation. The preparation method comprises the steps that the coupling agent and the polyacrylic acid react to form the modified polyacrylic acid, the hydroxyl silicone oil and the ethyl cyanoacrylate react to form the modified modified ethyl cyanoacrylate, and the modified ethyl cyanoacrylate, the modified polyacrylic acid, the antioxidant, the stabilizing agent, the ultraviolet light absorber, the anti-settling agent, the thickening agent, the polymerization inhibitor and the N,N-dimethyl formamide react to form the binding agent. The binding agent has the excellent fire resistance, binding force, water resistance, compatibility and the like.
Description
Technical field
The present invention relates to a kind of power cable installation binding agent and preparation method thereof, belong to power cable technical field.
Background technology
Alpha-cyanoacrylate binding agent has one-pack type, low viscosity, quick solidifying, high intensity, transparent good, the advantage such as toxicity is little,
Be widely used in artware, noble metal, the splicing of precision instrument, medically can be used for skin, blood vessel, osseous tissue bonding.
At present, alpha-cyanoacrylate binding agent needs to improve in the performances such as anti-flammability, resistance to water and cohesive force.The present invention is first
First pass through and the raw material such as alpha-cyanoacrylate and polyacrylic acid is carried out chemical modification, then by hydroxyl polydimethylsiloxane and ketoxime
Type silane coupler introduces in alpha-cyanoacrylate binding agent, can impart the excellent water proofing property of alpha-cyanoacrylate binding agent, glue
Knot property, anti-flammability.
Summary of the invention
The problem that the invention aims to overcome prior art to exist, it is provided that a kind of power cable installation binding agent
Preparation method, the method is by changing reactant feed and solvent species, and the binding agent of preparation has the compatibility of excellence, resistance
Fuel efficiency fruit, caking property is good, water proofing property, fast curing properties.
It is an object of the invention to be achieved through the following technical solutions:
A kind of power cable installations binding agent, is made up of following material: modification cyanacrylate, modified polyacrylic acid,
Antioxidant, stabilizer, UV absorbent, anti-settling agent, thickening agent, polymerization inhibitor, DMF, described modified cyanogen
Base ethyl acrylate, modified polyacrylic acid, antioxidant, stabilizer, UV absorbent, anti-settling agent, thickening agent, polymerization inhibitor,
The mass ratio of N,N-dimethylformamide be 0.1～85:0.01～5:0.001～3:0.001～3:0.001～3:0.001～
3:0.0001～3:0.0001～1:0.001～3；Wherein, described modified cyanacrylate is by hydroxyl polydimethylsiloxanes
Alkane and cyanacrylate reaction prepare, and the mass ratio of described hydroxyl polydimethylsiloxane and cyanacrylate is
0.01～10:0.1～90；Described modified polyacrylic acid is reacted by ketoxime type silane coupler and polyacrylic acid and prepares, described ketone
Oxime type silane coupler and polyacrylic mass ratio are 0.1～10:0.001～30.
Further, described ketoxime type silane coupler is vinyl tributyl ketoximyl silane coupling agent, methyl three butanone
One in oximino silane coupling agent, four diacetylmonoxime base silane coupling agents；
Further, described antioxidant be tricresyl phosphite monooctyl ester, triphenyl phosphite, phosphorous acid, 2,6-di-t-butyl-4-first
One in base phenol, tert-butylhydroquinone；
Further, described thickening agent is the middle one of white carbon, cellulose ether, sodium alginate, polyvinyl alcohol；
Further, the one during described stabilizer is methyl phosphite, phosphorous acid ethyl ester, epoxy soybean oil；
Further, described UV absorbent be 2-(2-hydroxy-5-methyl base phenyl) BTA, 2,4-dihydroxy hexichol
Ketone, ESCALOL 567, Octabenzone, 2-(2'-hydroxyl-3', 5'-bis-uncle
Butyl phenyl)-5-chlorination benzotriazole, single benzoic acid resorcinol, 2,2-thiobis (4-t-octyl phenol epoxide) nickel, three
One in (1,2,2,6,6-pempidine base) methyl phosphite, phosphorous acid ethyl ester；
Further, described anti-settling agent is organobentonite, Oleum Ricini, polyolefin-wax, the N-Methyl pyrrolidone of polyureas, polyamides
One in amine wax；
Further, the one during described polymerization inhibitor is methanol, ortho-methyl phenol, phenol, formaldehyde.
Further, described power cable installation binding agent is prepared by following preparation method:
(1) it is, 0.1～10:0.001～30 to join reactor by ketoxime type silane coupler and polyacrylic acid according to mass ratio
In, mixing speed is 100-400r/min, maintenance system temperature 60～170 DEG C, and vacuum-0.01～-0.1MPa subtracts in heating
React 3～15h under the conditions of pushing back stream, obtain modified polyacrylic acid；
(2), hydroxyl polydimethylsiloxane and cyanacrylate are added another according to mass ratio 0.01～10:0.1～90
One reactor, temperature 80～180 DEG C, mixing speed be 90-300r/min, vacuum-0.01～-0.1MPa, heating decompression
React 2～10h under counterflow condition, i.e. obtain modified cyanacrylate；
(3), by modification cyanacrylate, modified polyacrylic acid, antioxidant, stabilizer, UV absorbent, anti-settling
Agent, thickening agent, polymerization inhibitor, N,N-dimethylformamide are according to mass ratio 0.1～85:0.01～5:0.001～3:0.001～3:
0.001～3:0.001～3:0.0001～3:0.0001～1:0.001～3, at temperature 20～100 DEG C, stirred under nitrogen atmosphere
Speed is reaction 1～9h under the conditions of 20-200r/min, i.e. obtains cable installation binding agent.
Further, described ketoxime type silane coupler and polyacrylic mass ratio are 1～10:0.1～30；Described hydroxyl
The mass ratio of base polydimethylsiloxane and cyanacrylate is 1～10:1～90；Described modified cyanacrylate,
Modified polyacrylic acid, antioxidant, stabilizer, UV absorbent, anti-settling agent, thickening agent, polymerization inhibitor, N, N-dimethyl formyl
The mass ratio of amine is 1～85:1～5:1～3:0.1～3:0.1～3:0.1～3:0.1～3:0.01～1:1～3.
Further, described ketoxime type silane coupler and polyacrylic mass ratio are 1:0.5～3；Described hydroxyl gathers
The mass ratio of dimethyl siloxane and cyanacrylate is 1:1～10；Described modified cyanacrylate, modification poly-third
Olefin(e) acid, antioxidant, stabilizer, UV absorbent, anti-settling agent, thickening agent, polymerization inhibitor, the quality of N,N-dimethylformamide
Than for 1:0.01～0.05:0.01～0.03:0.005～0.01:0.001～0.005:0.001～0.007:0.003～
0.008:0.001～0.01:0.01～0.03.
Power cable installation binding agent in the present invention, including following raw material components: modified cyanacrylate, change
Property polyacrylic acid, antioxidant, stabilizer, UV absorbent, anti-settling agent, thickening agent, polymerization inhibitor, N, N-dimethyl formyl
Amine, modified cyanacrylate is reacted by hydroxy silicon oil and cyanacrylate and prepares, and modified polyacrylic acid is by coupling agent
Prepare with polyacrylic acid reaction.The invention also discloses the preparation method of power cable installation binding agent, including: coupling agent and
Polyacrylic acid reaction forms modified polyacrylic acid, hydroxy silicon oil and cyanacrylate reaction and forms modified alpha-cyanoacrylate second
Ester, modified cyanacrylate, modified polyacrylic acid, antioxidant, stabilizer, UV absorbent, anti-settling agent, thickening
Agent, polymerization inhibitor, N,N-dimethylformamide reaction form binding agent.Binding agent of the present invention has fire-retardant, the cohesive force of excellence, anti-
The performance such as water, the compatibility.
Power cable installation binding agent of the present invention can be applied electric apparatus, power cable, plastic lined piping, rubber
Hose line, plastic, rubber are in fields such as water proofing property, caking property, anti-flammability and compatible stabilities.
In power cable installation binding agent preparation process of the present invention, reaction temperature is low, and raw material waste discharge is few, price
Low and have excellence water proofing property, caking property, anti-flammability and compatible stability.Compared with existing synthetic technology, the present invention has
Following advantage:
1, cyanacrylate is in the curing process, can discharge a certain amount of ammonia, and ammonia combines with phosphorous antioxidant
Forming phosphorus compound-ammino-complex, in pyroprocess, complex can progressively decompose at material surface, be polymerized, at material surface
Form one layer of flame retardant layer, on the one hand, can completely cut off heat or burning things which may cause a fire disaster and oxygen, on the other hand, complex decomposes polymerization and can absorb
Big calorimetric, finally realizes material fire-retardant；
2, ketoxime type silane coupler and the modification to raw material of the hydroxyl polydimethylsiloxane, mainly in binder molecule structure
Middle introducing also rabbets low-surface-energy, hydrophobic structure, on the one hand, this processing method can improve ketoxime type silane coupler and hydroxyl
Base polydimethylsiloxane dispersibility in a binder and itself low-surface-energy and hydrophobic performance, on the other hand, it is also possible to
Improve ketoxime type silane coupler and hydroxyl polydimethylsiloxane chemical stability in a binder；
3, ketoxime type silane coupler and hydroxyl polydimethylsiloxane introduce in binding agent macromolecular structure, and ketoxime type silane is even
Connection agent and the chemical characteristic that has of hydroxyl polydimethylsiloxane molecule itself and active function groups, can play cross-linking agent and make
With, improve the crosslink density of cyanoacrylates, improve the adhesion strength of binding agent；
4, DMF is possible not only to clean material surface to be bonded, and may also reach up microcorrosion material surface
Effect, improve the surface roughness of material to be bonded, to improve binding agent adhesive property have the biggest room for promotion.
Detailed description of the invention
Below by detailed description of the invention, technical scheme is described further.
Embodiment 1
A kind of power cable installation binding agent, its preparation method comprises the following steps:
(1), weigh 1000g vinyl tributyl ketoximyl silane coupling agent and 583g polyacrylic acid joins in reactor, stirring
Speed is 260r/min, maintenance system temperature 95 DEG C, vacuum-0.07MPa, reacts 5.5h under the conditions of heating reduced-pressure backflow,
Obtain modified polyacrylic acid；
(2), 1000g hydroxyl polydimethylsiloxane and 6300g cyanacrylate are weighed, in temperature 127 DEG C, mixing speed
For 190r/min, vacuum-0.06MPa, under the conditions of heating reduced-pressure backflow, react 3.5h, i.e. obtain modified alpha-cyanoacrylate second
Ester；
(3) 1000g modification cyanacrylate, 25g modified polyacrylic acid, 18g tricresyl phosphite monooctyl ester, 5.1g phosphorous, are weighed
Acid methyl ester, 2.3g2,4-dihydroxy benaophenonel, polyamide wax 1.3g, polyvinyl alcohol 3.6g, 1.3g phenol, 14gN, N-diformazan
Base Methanamide, temperature 46 DEG C, stirred under nitrogen atmosphere speed is reaction 2.8h under the conditions of 95r/min, i.e. obtains cable and installs
Use binding agent.
Embodiment 2
A kind of power cable installation binding agent, its preparation method comprises the following steps:
(1), weighing 1000g tetra-diacetylmonoxime base silane coupling agent and 50g polyacrylic acid joins in reactor, mixing speed is
140r/min, maintenance system temperature 80 DEG C, vacuum-0.04MPa, reacts 3h under the conditions of heating reduced-pressure backflow, obtains modification
Polyacrylic acid；
(2), 1000g hydroxyl polydimethylsiloxane and 1000g cyanacrylate are weighed, in temperature 80 DEG C, mixing speed
For 120r/min, vacuum-0.03MPa, under the conditions of heating reduced-pressure backflow, react 2h, i.e. obtain modified cyanacrylate；
(3) 1000g modification cyanacrylate, 10g modified polyacrylic acid, 10g triphenyl phosphite, 5g phosphorous acid, are weighed
Methyl ester, 1g2,4-dihydroxy benaophenonel, polyamide wax 1g, polyvinyl alcohol 3g, 1g methanol, 10gN, dinethylformamide,
Temperature 20 DEG C, stirred under nitrogen atmosphere speed is reaction 1h under the conditions of 40r/min, i.e. obtains cable installation binding agent.
Embodiment 3
A kind of power cable installation binding agent, its preparation method comprises the following steps:
(1), weighing 1000g tetra-diacetylmonoxime base silane coupling agent and 3000g polyacrylic acid joins in reactor, mixing speed is
300r/min, maintenance system temperature 160 DEG C, vacuum-0.09MPa, reacts 9h under the conditions of heating reduced-pressure backflow, obtains modification
Polyacrylic acid；
(2), 1000g hydroxyl polydimethylsiloxane and 10000g cyanacrylate are weighed, in temperature 160 DEG C, stirring speed
Degree is 230r/min, vacuum-0.07MPa, reacts 6h under the conditions of heating reduced-pressure backflow, i.e. obtains modified alpha-cyanoacrylate second
Ester；
(3) 1000g modification cyanacrylate, 50g modified polyacrylic acid, 30g tert-butylhydroquinone, 10g phosphorous, are weighed
Acid methyl ester, 5g2-(2-hydroxy-5-methyl base phenyl) BTA, machine bentonite 7g, polyvinyl alcohol 8g, 10g formaldehyde, 30gN,
Dinethylformamide, temperature 80 DEG C, stirred under nitrogen atmosphere speed is reaction 5h under the conditions of 160r/min, i.e. obtains cable
Installation binding agent.
Embodiment 4
A kind of power cable installation binding agent, its preparation method comprises the following steps:
(1), weigh 1000g vinyl tributyl ketoximyl silane coupling agent and 703g polyacrylic acid joins in reactor, stirring
Speed is 180r/min, maintenance system temperature 95 DEG C, vacuum-0.06MPa, reacts 4.9h under the conditions of heating reduced-pressure backflow,
Obtain modified polyacrylic acid；
(2), 1000g hydroxyl polydimethylsiloxane and 2387g cyanacrylate are weighed, in temperature 109 DEG C, mixing speed
For 137r/min, vacuum-0.05MPa, under the conditions of heating reduced-pressure backflow, react 4.3h, i.e. obtain modified alpha-cyanoacrylate second
Ester；
(3) 1000g modification cyanacrylate, 23g modified polyacrylic acid, 23g triphenyl phosphite, 8g phosphorous acid, are weighed
Ethyl ester, 3.4g2,4-dihydroxy benaophenonel, polyamide wax 1.7g, cellulose ether 3.8g, 4.7g ortho-methyl phenol, 21.9gN,
Dinethylformamide, temperature 48 DEG C, stirred under nitrogen atmosphere speed is reaction 3.7h under the conditions of 90r/min, i.e. obtains electricity
Cable installation binding agent.
Embodiment 5
A kind of power cable installation binding agent, its preparation method comprises the following steps:
(1), weighing 1000g tetra-diacetylmonoxime base silane coupling agent and 2740g polyacrylic acid joins in reactor, mixing speed is
215r/min, maintenance system temperature 150 DEG C, vacuum-0.08MPa, reacts 4.7h under the conditions of heating reduced-pressure backflow, is changed
Property polyacrylic acid；
(2), 1000g hydroxyl polydimethylsiloxane and 9423g cyanacrylate are weighed, in temperature 137 DEG C, mixing speed
For 194r/min, vacuum-0.04MPa, under the conditions of heating reduced-pressure backflow, react 3.1h, i.e. obtain modified alpha-cyanoacrylate second
Ester；
(3), weigh 1000g modification cyanacrylate, 34.2g modified polyacrylic acid, 19.8g tert-butylhydroquinone,
6.7g methyl phosphite, 5g phosphorous acid ethyl ester, the N-Methyl pyrrolidone 6.2g of polyureas, polyvinyl alcohol 5.3g, 9.4g neighbour's methyl
Phenol, 21.7gN, dinethylformamide, temperature 57.8 DEG C, stirred under nitrogen atmosphere speed is anti-under the conditions of 139r/min
Answer 3.5h, i.e. obtain cable installation binding agent.
Embodiment 6
A kind of power cable installation binding agent, its preparation method comprises the following steps:
(1), weigh 1000g methyl tributanoximo silane coupling agent and 2756g polyacrylic acid joins in reactor, stirring speed
Degree is 183r/min, maintenance system temperature 134 DEG C, vacuum-0.05MPa, reacts 6h, obtain under the conditions of heating reduced-pressure backflow
Modified polyacrylic acid；
(2), 1000g hydroxyl polydimethylsiloxane and 6427g cyanacrylate are weighed, in temperature 116 DEG C, mixing speed
For 179r/min, vacuum-0.04MPa, under the conditions of heating reduced-pressure backflow, react 3.7h, i.e. obtain modified alpha-cyanoacrylate second
Ester；
(3), weigh 1000g modification cyanacrylate, 34.5g modified polyacrylic acid, 16.4g tert-butylhydroquinone,
7.3g methyl phosphite, 2.8g tri-(1,2,2,6,6-pempidine base) methyl phosphite, machine bentonite 4.6g, cellulose ether
5.6g, 7.6g phenol, 21.3gN, dinethylformamide, temperature 63.6 DEG C, stirred under nitrogen atmosphere speed is 132r/min
Under the conditions of react 3.6h, i.e. obtain cable installation binding agent.
Embodiment 7
A kind of power cable installation binding agent, its preparation method comprises the following steps:
(1), weigh 1000g vinyl tributyl ketoximyl silane coupling agent and 1593g polyacrylic acid joins in reactor, stirring
Speed is 239r/min, maintenance system temperature 136 DEG C, vacuum-0.06MPa, reacts 5.8h under the conditions of heating reduced-pressure backflow,
Obtain modified polyacrylic acid；
(2), 1000g hydroxyl polydimethylsiloxane and 6729g cyanacrylate are weighed, in temperature 129 DEG C, mixing speed
For 165r/min, vacuum-0.04MPa, under the conditions of heating reduced-pressure backflow, react 2.7h, i.e. obtain modified alpha-cyanoacrylate second
Ester；
(3) 1000g modification cyanacrylate, 20.7g modified polyacrylic acid, 17.9g triphenyl phosphite, 8.9g, are weighed
Methyl phosphite, 3.8g2,2-thiobis (4-t-octyl phenol epoxide) nickel, polyolefin-wax 4.1g, polyvinyl alcohol 5.7g, 8.3g benzene
Phenol, 21.6gN, dinethylformamide, temperature 66 DEG C, stirred under nitrogen atmosphere speed is reaction under the conditions of 136r/min
2.7h, i.e. obtains cable installation binding agent.
Embodiment 8
A kind of power cable installation binding agent, its preparation method comprises the following steps:
(1), weighing 1000g tetra-diacetylmonoxime base silane coupling agent and 1249g polyacrylic acid joins in reactor, mixing speed is
225r/min, maintenance system temperature 117 DEG C, vacuum-0.06MPa, reacts 6.3h under the conditions of heating reduced-pressure backflow, is changed
Property polyacrylic acid；
(2), 1000g hydroxyl polydimethylsiloxane and 3690g cyanacrylate are weighed, in temperature 138 DEG C, mixing speed
For 169r/min, vacuum-0.04MPa, under the conditions of heating reduced-pressure backflow, react 4.9h, i.e. obtain modified alpha-cyanoacrylate second
Ester；
(3) 1000g modification cyanacrylate, 38.5g modified polyacrylic acid, 23.1g tricresyl phosphite monooctyl ester, 7.4g, are weighed
Methyl phosphite, 3.1g2,4-dihydroxy benaophenonel, polyamide wax 3.7g, sodium alginate 6.2g, 9.3g ortho-methyl phenol,
19.3gN, dinethylformamide, temperature 73 DEG C, stirred under nitrogen atmosphere speed is reaction 1.9h under the conditions of 139r/min,
I.e. obtain cable installation binding agent.
Embodiment 9
A kind of power cable installation binding agent, its preparation method comprises the following steps:
(1), weighing 1000g tetra-diacetylmonoxime base silane coupling agent and 2390g polyacrylic acid joins in reactor, mixing speed is
267r/min, maintenance system temperature 94 DEG C, vacuum-0.07MPa, reacts 5.2h under the conditions of heating reduced-pressure backflow, is changed
Property polyacrylic acid；
(2), 1000g hydroxyl polydimethylsiloxane and 4931g cyanacrylate are weighed, in temperature 92 DEG C, mixing speed
For 140r/min, vacuum-0.04MPa, under the conditions of heating reduced-pressure backflow, react 3.4h, i.e. obtain modified alpha-cyanoacrylate second
Ester；
(3) 1000g modification cyanacrylate, 19g modified polyacrylic acid, 18g2,6-di-t-butyl-4-methylbenzene, are weighed
Phenol, 5.1g phosphorous acid ethyl ester, 2.3g2-(2-hydroxy-5-methyl base phenyl) BTA, machine bentonite 6.2g, cellulose ether
3.6g, 1.8g phenol, 22.3gN, dinethylformamide, temperature 36 DEG C, stirred under nitrogen atmosphere speed is 56r/min bar
React 2.7h under part, i.e. obtain cable installation binding agent.
Embodiment 10
A kind of power cable installation binding agent, its preparation method comprises the following steps:
(1), weigh 1000g vinyl tributyl ketoximyl silane coupling agent and 1670g polyacrylic acid joins in reactor, stirring
Speed is 194r/min, maintenance system temperature 109 DEG C, vacuum-0.06MPa, reacts 5.7h under the conditions of heating reduced-pressure backflow,
Obtain modified polyacrylic acid；
(2), 1000g hydroxyl polydimethylsiloxane and 2380g cyanacrylate are weighed, in temperature 112 DEG C, mixing speed
For 139r/min, vacuum-0.04MPa, under the conditions of heating reduced-pressure backflow, react 4.1h, i.e. obtain modified alpha-cyanoacrylate second
Ester；
(3) 1000g modification cyanacrylate, 26.5g modified polyacrylic acid, 21.7g triphenyl phosphite, 6.9g, are weighed
Methyl phosphite, 3.2g mono-benzoic acid resorcinol, Oleum Ricini 3.1g, polyvinyl alcohol 5.7g, 2.6g ortho-methyl phenol,
17.2gN, dinethylformamide, temperature 41 DEG C, stirred under nitrogen atmosphere speed is reaction 3.1h under the conditions of 89r/min, i.e.
Obtain cable installation binding agent.
Embodiment 11
A kind of power cable installation binding agent, its preparation method comprises the following steps:
(1), weighing 1000g tetra-diacetylmonoxime base silane coupling agent and 1470g polyacrylic acid joins in reactor, mixing speed is
239r/min, maintenance system temperature 128 DEG C, vacuum-0.05MPa, reacts 6h under the conditions of heating reduced-pressure backflow, obtains modification
Polyacrylic acid；
(2), 1000g hydroxyl polydimethylsiloxane and 5612g cyanacrylate are weighed, in temperature 121 DEG C, mixing speed
For 187r/min, vacuum-0.04MPa, under the conditions of heating reduced-pressure backflow, react 5.1h, i.e. obtain modified alpha-cyanoacrylate second
Ester；
(3) 1000g modification cyanacrylate, 41g modified polyacrylic acid, 15.7g tricresyl phosphite monooctyl ester, 7.3g Asia, are weighed
Methyl orthophosphoric acid, 3.9g2,4-dihydroxy benaophenonel, polyolefin-wax 3.6g, polyvinyl alcohol 6.4g, 8.6g methanol, 23.1gN, N-
Dimethylformamide, temperature 57 DEG C, stirred under nitrogen atmosphere speed is reaction 4.5h under the conditions of 97r/min, i.e. obtains cable
Installation binding agent.
Embodiment 12
A kind of power cable installation binding agent, its preparation method comprises the following steps:
(1), weigh 1000g methyl tributanoximo silane coupling agent and 1670g polyacrylic acid joins in reactor, stirring speed
Degree is 279r/min, maintenance system temperature 156 DEG C, vacuum-0.06MPa, reacts 5.6h under the conditions of heating reduced-pressure backflow,
To modified polyacrylic acid；
(2), 1000g hydroxyl polydimethylsiloxane and 6239g cyanacrylate are weighed, in temperature 137 DEG C, mixing speed
For 176r/min, vacuum-0.06MPa, under the conditions of heating reduced-pressure backflow, react 4.7h, i.e. obtain modified alpha-cyanoacrylate second
Ester；
(3) 1000g modification cyanacrylate, 35.9g modified polyacrylic acid, 14.7g phosphorous acid, 7.6g phosphorous acid, are weighed
Methyl ester, 3.2g2-hydroxyl-4-methoxy benzophenone, polyamide wax 7g, sodium alginate 7.2g, 7.6g ortho-methyl phenol,
25.2gN, dinethylformamide, temperature 72 DEG C, stirred under nitrogen atmosphere speed is reaction 3.2h under the conditions of 150r/min,
I.e. obtain cable installation binding agent.
Embodiment 13
A kind of power cable installation binding agent, its preparation method comprises the following steps:
(1), weigh 1000g vinyl tributyl ketoximyl silane coupling agent and 2156g polyacrylic acid joins in reactor, stirring
Speed is 167r/min, maintenance system temperature 136 DEG C, vacuum-0.07MPa, reacts 5.7h under the conditions of heating reduced-pressure backflow,
Obtain modified polyacrylic acid；
(2), 1000g hydroxyl polydimethylsiloxane and 6721g cyanacrylate are weighed, in temperature 96 DEG C, mixing speed
For 140r/min, vacuum-0.05MPa, under the conditions of heating reduced-pressure backflow, react 4h, i.e. obtain modified cyanacrylate；
(3) 1000g modification cyanacrylate, 43g modified polyacrylic acid, 27g2,6-di-t-butyl-4-methylbenzene, are weighed
Phenol, 6g methyl phosphite, 1g2,4-dihydroxy benaophenonel, machine bentonite 2g, white carbon 5g, 7g methanol, 26gN, N-dimethyl
Methanamide, temperature 37 DEG C, stirred under nitrogen atmosphere speed is reaction 4h under the conditions of 67r/min, i.e. obtains cable and installs with viscous
Knot agent.
Embodiment 14
A kind of power cable installation binding agent, its preparation method comprises the following steps:
(1), weigh 1000g methyl tributanoximo silane coupling agent and 2471g polyacrylic acid joins in reactor, stirring speed
Degree is 180r/min, maintenance system temperature 130 DEG C, vacuum-0.07MPa, reacts 6h, obtain under the conditions of heating reduced-pressure backflow
Modified polyacrylic acid；
(2), 1000g hydroxyl polydimethylsiloxane and 8721g cyanacrylate are weighed, in temperature 112 DEG C, mixing speed
For 186r/min, vacuum-0.06MPa, under the conditions of heating reduced-pressure backflow, react 6h, i.e. obtain modified cyanacrylate；
(3) 1000g modification cyanacrylate, 35g modified polyacrylic acid, 19g phosphorous acid, 6g phosphorous acid ethyl ester, 3g, are weighed
Single benzoic acid resorcinol, Oleum Ricini 5g, polyvinyl alcohol 4g, 8g methanol, 19gN, dinethylformamide, temperature 57 DEG C,
Stirred under nitrogen atmosphere speed is reaction 4h under the conditions of 52r/min, i.e. obtains cable installation binding agent.
Embodiment 15
A kind of power cable installation binding agent, its preparation method comprises the following steps:
(1), weigh 1000g vinyl tributyl ketoximyl silane coupling agent and 2392g polyacrylic acid joins in reactor, stirring
Speed is 222r/min, maintenance system temperature 150 DEG C, vacuum-0.08MPa, reacts 4h under the conditions of heating reduced-pressure backflow,
To modified polyacrylic acid；
(2), 1000g hydroxyl polydimethylsiloxane and 6731g cyanacrylate are weighed, in temperature 140 DEG C, mixing speed
For 187r/min, vacuum-0.05MPa, under the conditions of heating reduced-pressure backflow, react 5h, i.e. obtain modified cyanacrylate；
(3) 1000g modification cyanacrylate, 32g modified polyacrylic acid, 21.4g tricresyl phosphite monooctyl ester, 7.2g ring, are weighed
Oxygen soybean oil 2.3g2-hydroxyl-4-methoxy benzophenone, polyamide wax 6g, polyvinyl alcohol 3.4g, 2.6g formaldehyde, 13gN, N-
Dimethylformamide, temperature 54 DEG C, stirred under nitrogen atmosphere speed is reaction 5h under the conditions of 130r/min, i.e. obtains cable peace
Dress binding agent.
Embodiment 16
A kind of power cable installation binding agent, its preparation method comprises the following steps:
(1), weigh 1000g methyl tributanoximo silane coupling agent and 1582g polyacrylic acid joins in reactor, stirring speed
Degree is 170r/min, maintenance system temperature 136 DEG C, vacuum-0.07MPa, reacts 7h, obtain under the conditions of heating reduced-pressure backflow
Modified polyacrylic acid；
(2), 1000g hydroxyl polydimethylsiloxane and 7520g cyanacrylate are weighed, in temperature 126 DEG C, mixing speed
For 167r/min, vacuum-0.06MPa, under the conditions of heating reduced-pressure backflow, react 3h, i.e. obtain modified cyanacrylate；
(3), weigh 1000g modification cyanacrylate, 36g modified polyacrylic acid, 25g phosphorous acid, 7g methyl phosphite,
3g2-(2'-hydroxyl-3', 5'-di-tert-butyl-phenyl)-5-chlorination benzotriazole, polyamide wax 4g, sodium alginate 4g, 7g methanol,
23gN, dinethylformamide, at temperature 50 C, stirred under nitrogen atmosphere speed is reaction 3h under the conditions of 137r/min, to obtain final product
To cable installation binding agent.
Embodiment 17
A kind of power cable installation binding agent, its preparation method comprises the following steps:
(1), weigh 1000g methyl tributanoximo silane coupling agent and 1582g polyacrylic acid joins in reactor, stirring speed
Degree is 190r/min, maintenance system temperature 160 DEG C, vacuum-0.09MPa, reacts 9h, obtain under the conditions of heating reduced-pressure backflow
Modified polyacrylic acid；
(2), 1000g hydroxyl polydimethylsiloxane and 9630g cyanacrylate are weighed, in temperature 90 DEG C, mixing speed
For 128r/min, vacuum-0.05MPa, under the conditions of heating reduced-pressure backflow, react 5h, i.e. obtain modified cyanacrylate；
(3) 1000g modification cyanacrylate, 17g modified polyacrylic acid, 16g tricresyl phosphite monooctyl ester, 9g epoxy, are weighed big
Oleum Glycines 5g2-hydroxyl-4-oxy-octyl benzophenone, Oleum Ricini 4g, white carbon 5g, 7g formaldehyde, 30gN, dinethylformamide,
At temperature 60 C, stirred under nitrogen atmosphere speed is reaction 5h under the conditions of 160r/min, i.e. obtains cable installation binding agent.
The binding agent being obtained embodiment 1 to 17 carries out performance measurement, and with certain commercially available binding agent as a comparison, is surveyed
Obtain performance as shown in table 1, it is seen then that the binding agent properties in the embodiment of the present invention is preferable.
Table 1
Claims (5)
1. a power cable installation binding agent, it is characterised in that: it is made up of following material: modified cyanacrylate,
Modified polyacrylic acid, antioxidant, stabilizer, UV absorbent, anti-settling agent, thickening agent, polymerization inhibitor, N, N-dimethyl formyl
Amine, described modified cyanacrylate, modified polyacrylic acid, antioxidant, stabilizer, UV absorbent, anti-settling agent, increasing
Thick dose, polymerization inhibitor, the mass ratio of N,N-dimethylformamide be 0.1～85:0.01～5:0.001～3:0.001～3:0.001
～3:0.001～3:0.0001～3:0.0001～1:0.001～3；Wherein, described modified cyanacrylate is gathered by hydroxyl
Dimethyl siloxane and cyanacrylate reaction prepare, described hydroxyl polydimethylsiloxane and cyanacrylate
Mass ratio is 0.01～10:0.1～90；Described modified polyacrylic acid is reacted system by ketoxime type silane coupler and polyacrylic acid
, described ketoxime type silane coupler and polyacrylic mass ratio are 0.1～10:0.001～30.
Power cable installation binding agent the most according to claim 1, it is characterised in that:
Described ketoxime type silane coupler is vinyl tributyl ketoximyl silane coupling agent, methyl tributanoximo silane coupling
One in agent, four diacetylmonoxime base silane coupling agents；
Described antioxidant is tricresyl phosphite monooctyl ester, triphenyl phosphite, phosphorous acid, 2,6 di tert butyl 4 methyl phenol, spy
One in butylhydroquinone；
Described thickening agent is the middle one of white carbon, cellulose ether, sodium alginate, polyvinyl alcohol；
Described stabilizer is the one in methyl phosphite, phosphorous acid ethyl ester, epoxy soybean oil；
Described UV absorbent is 2-(2-hydroxy-5-methyl base phenyl) BTA, 2,4 dihydroxyl benzophenone, 2-hydroxyl
Base-4-methoxy benzophenone, Octabenzone, 2-(2'-hydroxyl-3', 5'-di-tert-butyl-phenyl)-
5-chlorination benzotriazole, single benzoic acid resorcinol, 2,2-thiobis (4-t-octyl phenol epoxide) nickel, three (1,2,2,6,6-
Pempidine base) methyl phosphite, one in phosphorous acid ethyl ester；
Described anti-settling agent is in organobentonite, Oleum Ricini, polyolefin-wax, the N-Methyl pyrrolidone of polyureas, polyamide wax
A kind of；
Described polymerization inhibitor is the one in methanol, ortho-methyl phenol, phenol, formaldehyde.
Power cable installation binding agent the most according to claim 1, it is characterised in that: described power cable installation bonds
Agent is prepared by following preparation method:
(1) it is, 0.1～10:0.001～30 to join reactor by ketoxime type silane coupler and polyacrylic acid according to mass ratio
In, mixing speed is 100-400r/min, maintenance system temperature 60～170 DEG C, and vacuum-0.01～-0.1MPa subtracts in heating
React 3～15h under the conditions of pushing back stream, obtain modified polyacrylic acid；
(2), hydroxyl polydimethylsiloxane and cyanacrylate are added another according to mass ratio 0.01～10:0.1～90
One reactor, temperature 80～180 DEG C, mixing speed be 90-300r/min, vacuum-0.01～-0.1MPa, heating decompression
React 2～10h under counterflow condition, i.e. obtain modified cyanacrylate；
(3), by modification cyanacrylate, modified polyacrylic acid, antioxidant, stabilizer, UV absorbent, anti-settling
Agent, thickening agent, polymerization inhibitor, N,N-dimethylformamide are according to mass ratio 0.1～85:0.01～5:0.001～3:0.001～3:
0.001～3:0.001～3:0.0001～3:0.0001～1:0.001～3, at temperature 20～100 DEG C, stirred under nitrogen atmosphere
Speed is reaction 1～9h under the conditions of 20-200r/min, i.e. obtains cable installation binding agent.
Power cable installation binding agent the most according to claim 1, it is characterised in that: described ketoxime type silane coupler and
Polyacrylic mass ratio is 1～10:0.1～30；Described hydroxyl polydimethylsiloxane and the quality of cyanacrylate
Ratio is 1～10:1～90；Described modified cyanacrylate, modified polyacrylic acid, antioxidant, stabilizer, ultraviolet are inhaled
Receipts agent, anti-settling agent, thickening agent, polymerization inhibitor, the mass ratio of N,N-dimethylformamide are 1～85:1～5:1～3:0.1～3:
0.1～3:0.1～3:0.1～3:0.01～1:1～3.
Power cable installation binding agent the most according to claim 1, it is characterised in that: described ketoxime type silane coupler and
Polyacrylic mass ratio is 1:0.5～3；The mass ratio of described hydroxyl polydimethylsiloxane and cyanacrylate is 1:
1～10；Described modified cyanacrylate, modified polyacrylic acid, antioxidant, stabilizer, UV absorbent, anti-settling
Agent, thickening agent, polymerization inhibitor, the mass ratio of N,N-dimethylformamide be 1:0.01～0.05:0.01～0.03:0.005～
0.01:0.001～0.005:0.001～0.007:0.003～0.008:0.001～0.01:0.01～0.03.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610361164.6A CN105778851A (en) | 2016-05-29 | 2016-05-29 | Binding agent for power cable installation and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610361164.6A CN105778851A (en) | 2016-05-29 | 2016-05-29 | Binding agent for power cable installation and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105778851A true CN105778851A (en) | 2016-07-20 |
Family
ID=56379500
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610361164.6A Pending CN105778851A (en) | 2016-05-29 | 2016-05-29 | Binding agent for power cable installation and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105778851A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106396496A (en) * | 2016-08-26 | 2017-02-15 | 佛山市高明区明城镇新能源新材料产业技术创新中心 | Method for preparing environment-friendly quartz stone composite board |
| CN108078624A (en) * | 2017-11-16 | 2018-05-29 | 席婷 | A kind of special stripping off device of digestive endoscopy |
| CN108987753A (en) * | 2018-07-23 | 2018-12-11 | 芜湖彰鸿工程技术有限公司 | A kind of new energy bonder for lithium ion batteries and its application |
| CN116731666A (en) * | 2023-08-15 | 2023-09-12 | 山东凯恩新材料科技有限公司 | Waterproof quick-drying adhesive and preparation method thereof |
-
2016
- 2016-05-29 CN CN201610361164.6A patent/CN105778851A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106396496A (en) * | 2016-08-26 | 2017-02-15 | 佛山市高明区明城镇新能源新材料产业技术创新中心 | Method for preparing environment-friendly quartz stone composite board |
| CN106396496B (en) * | 2016-08-26 | 2018-09-18 | 佛山市高明区明城镇新能源新材料产业技术创新中心 | A kind of preparation method of environmental-proteccomposite composite quartz stone board |
| CN108078624A (en) * | 2017-11-16 | 2018-05-29 | 席婷 | A kind of special stripping off device of digestive endoscopy |
| CN108987753A (en) * | 2018-07-23 | 2018-12-11 | 芜湖彰鸿工程技术有限公司 | A kind of new energy bonder for lithium ion batteries and its application |
| CN116731666A (en) * | 2023-08-15 | 2023-09-12 | 山东凯恩新材料科技有限公司 | Waterproof quick-drying adhesive and preparation method thereof |
| CN116731666B (en) * | 2023-08-15 | 2023-10-20 | 山东凯恩新材料科技有限公司 | Waterproof quick-drying adhesive and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105778851A (en) | Binding agent for power cable installation and preparation method thereof | |
| CN101466807B (en) | Bonding method with flowable adhesive composition | |
| CN101654607B (en) | High purity photo-thermal curing adhesive and preparation method thereof | |
| CN109535657A (en) | A kind of phosphorus silicon systems shock resistance Halogenless fire retarded epoxy resin material and preparation method thereof | |
| CN108276538A (en) | A kind of preparation process of phosphorus containing phenolic resin and its application | |
| CN103320075A (en) | One-component ultraviolet-light-anaerobic dual-curing adhesive | |
| CN108912169A (en) | A kind of new compound two-（4- aminocarbonyl phenyl）Phenyl phosphonic acid esters and its synthetic method | |
| CN104263309A (en) | Polyurethane adhesive and preparation method thereof | |
| CN109111771A (en) | A kind of moisture cured high reliability UV conformal coating and preparation method thereof | |
| CN110698988A (en) | Handheld quick-bonding adhesive | |
| CN108084937A (en) | A kind of epoxy acrylic adhesive and preparation method thereof | |
| CN106566195A (en) | Aging-resistant rapid-curing epoxy resin system | |
| CN103881304B (en) | There is the volatile composition epoxy resin of low organism | |
| CN115322735A (en) | High-temperature-resistant ultraviolet-curing three-proofing adhesive, and preparation method and application thereof | |
| CN110591376B (en) | Bifunctional epoxy resin-silicon rubber block interpenetrating network material and preparation method thereof | |
| CN106893078A (en) | A kind of dimer acid modified epoxy resin and preparation method thereof | |
| JP2002038028A (en) | Photocurable resin composition | |
| CN106432654B (en) | A kind of polyethers acetoacetic ester copolymerization phenol formaldehyde (PF) Foamex and preparation method thereof | |
| US20190002685A1 (en) | Flame-retardant, high temperature resistant thermosets on the basis of naphthalene-based epoxy resins and cyanate esters | |
| CN108342160A (en) | A kind of Environment-friendlyadhesive adhesive and preparation method thereof | |
| GB2231575A (en) | Command-curable composition | |
| CN107151309B (en) | A kind of preparation method of carborane phenoxy resin | |
| JPS5792017A (en) | Preparation of flame retardant epoxy resin | |
| JPH0623235B2 (en) | Epoxy resin composition curable at room temperature | |
| JPS54123200A (en) | Curable mixture |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160720 |
|
| WD01 | Invention patent application deemed withdrawn after publication |