CN105734955B - 一种纺织品喷墨印花涂层 - Google Patents

一种纺织品喷墨印花涂层 Download PDF

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CN105734955B
CN105734955B CN201610281620.6A CN201610281620A CN105734955B CN 105734955 B CN105734955 B CN 105734955B CN 201610281620 A CN201610281620 A CN 201610281620A CN 105734955 B CN105734955 B CN 105734955B
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隋晓迪
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Zhuhai Huacai New Materials Technology Co., Ltd.
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Abstract

本发明公开了一种纺织品喷墨印花涂层，该印花涂层包括以下按质量百份数计的组分：水性二氧化硅1‑10份、柔软剂1‑5份、杀菌剂0.1‑5份、抑制剂0.1‑5份、润湿剂1‑5份、水70‑90份、水性聚氨酯5‑15份、交联剂1‑10份、溶剂1‑10份。将除了水性聚氨酯和交联剂之外的上述组分按顺序投入物料机在500r/min下搅拌20min使其混合均匀后，加入水性聚氨酯和交联剂在500r/min下搅拌20min，最后使用5μm的滤膜过滤即得纺织品喷墨印花涂层。该涂层与基布有很好的结合牢度、提高染料墨水在基布的色牢度和颜色亮度，使用该涂层印花的纺织品手感柔软、透气性强，环保、对人体无害。

Description

一种纺织品喷墨印花涂层
技术领域
本发明涉及纺织品印染助剂技术领域，具体涉及一种纺织品喷墨印花涂层。
背景技术
近年来，数字印刷技术的应用越来越广泛，纺织品印花也面临机遇和挑战，纺织品数字喷墨印花就是一种创新的染整工艺，它具有精度高、快捷、灵活多变、富有个性化等特点，而且不退浆、环保。这种工艺的实现离不开纺织品涂层为之提供良好的印花介质。随着环保法规的完善和人们的环保意识不断增强，高性能、无公害、省能源的水性颜料墨水越来越受到人们的重视，水性颜料墨水在棉、麻、丝、毛和合成中得到了广泛的应用。同样地，随着水性颜料墨水的广泛应用，人们对纺织品涂层的要求也越来越高。但目前现有的纺织品涂层所制得纺织品的环保性差、手感差、透气性差。
发明内容
为了克服现有技术的不足，本发明的目的在于提供一种纺织品喷墨印花涂层，该涂层与基布有很好的结合牢度、提高染料墨水在基布的色牢度和颜色亮度，使用该涂层印花的纺织品手感柔软、透气性强，环保、对人体无害。
为解决上述问题，本发明所采用的技术方案如下：
一种纺织品喷墨印花涂层，包括以下按质量份数计的组分：
作为本发明的优选实施方式，所述纺织品喷墨印花涂层包括以下按质量份数计的组分：
作为本发明进一步的优选实施方式，所述纺织品喷墨印花涂层包括以下按质量份数计的组分：
优选地，所述涂层的表面张力为26-34dyn/cm、粘度为6-20厘泊。
优选地，所述柔软剂为含有机硅的非离子型柔软剂，优选巴斯夫路平莫印花柔软剂BASF Luprintol Solf VSN。
优选地，所述杀菌剂为异噻唑啉酮类杀菌剂。
优选地，所述抑制剂选自醋酸、碳酸、柠檬酸中的一种或任意两种以上的混合。
优选地，所述润湿剂为弱阳离子型润湿剂或者非离子型润湿剂，优选自直链聚氧乙烯醚、脂肪醇聚氧乙烯醚、异构醇聚氧乙烯醚中的一种或任意两种以上的混合。
优选地，所述交联剂为开环温度为90-130℃的脂肪族封闭异氰酸酯固化剂。
优选地，所述水性聚氨酯为水性脂肪族聚氨酯分散乳液，其分子量小于20000。
优选地，所述溶剂为二乙二醇、尿素、甘油、peg400-20000中的一种。
在本发明的配方中，其中：
水性二氧化硅的表面存在大量的微孔结构，由于这些微孔结构的存在使得二氧化硅微利的表面积大大增加。二氧化硅微粒的表面积越大，对墨水的吸附能力越强。当水性二氧化硅的浓度足以使微粒之间的距离缩小到构成网络，形成一系列微孔，则由于毛细管作用，进一步增加了吸墨容量，因此水性二氧化硅能够提高墨水或涂料在基布上的固色效果。
柔软剂的加入使得织物涂层的弹性明显提高，使得涂层与纤维的结合非常牢固，具有很好的耐洗效果，使其具有柔软、滑爽丰满、富有弹性的手感。
杀菌剂能够提高涂层的保质期，防止涂层霉变。本发明优选的异噻唑啉酮类杀菌剂对微生物杀生效率高、降解性好，具有不产生残留、操作安全、配伍性好、稳定性强、使用成本低等优点。
抑制剂优选为醋酸、碳酸、柠檬酸等弱酸，其与弱碱性的墨水发生反应，利于提高墨水边界的清晰程度，控制涂层pH值在5-7之间。
润湿剂的水溶性好，有助于提高涂层的渗透速度，提高涂层在基布上的渗透性。
在本发明中，水作为溶剂和助剂的载体，优选为去离子水。
水性聚氨酯能使涂层在基布上形成坚韧柔软且透湿透气的薄膜，能够提高墨水在基布上的附着力。
交联剂配合脂肪族水性聚氨酯分散乳液使用，使水性聚氨酯分子链形成支链结构，显著提高耐水压及耐水性性能，并能够提高墨水在基布上的附着力。
溶剂用于调节涂层的粘度。
相比现有技术，本发明的有益效果在于：
本发明所述的纺织品喷墨印花涂层与基布有很好的结合牢度，能够适用于多种不同的基布上，尤其是纯棉；提高染料墨水在基布的色牢度和颜色亮度，使用该涂层印花的纺织品手感柔软、透气性强，环保、对人体无害。
具体实施方式
下面具体实施方式对本发明作进一步详细说明。
一种纺织品喷墨印花涂层，其包括以下按质量份数计的组分：水性二氧化硅1-10份、柔软剂1-5份、杀菌剂0.1-5份、抑制剂0.1-5份、润湿剂1-5份、水70-90份、水性聚氨酯5-15份、交联剂1-10份、溶剂1-10份。其中，所述柔软剂为含有机硅的非离子型柔软剂，优选巴斯夫路平莫印花柔软剂BASF Luprintol Solf VSN。所述杀菌剂为异噻唑啉酮类杀菌剂。所述抑制剂选自醋酸、碳酸、柠檬酸中的一种或任意两种以上的混合。所述润湿剂选自为弱阳离子型润湿剂或者非离子型润湿剂，优选直链聚氧乙烯醚、脂肪醇聚氧乙烯醚、异构醇聚氧乙烯醚中的一种或任意两种以上的混合。优选地，所述交联剂选自为开环温度为90-130℃的脂肪族封闭异氰酸酯固化剂。所述水性聚氨酯为水性脂肪族聚氨酯分散乳液，其分子量小于20000。所述溶剂为二乙二醇、尿素、甘油、peg400-20000中的一种。所述涂层的表面张力为26-34dyn/cm、粘度为6-20厘泊。
实施例1：
一种纺织品喷墨印花涂层，包括以下按质量份数计的组分：
将除了水性聚氨酯和交联剂之外的上述组分按顺序投入物料机在500r/min下搅拌20min使其混合均匀后，加入水性聚氨酯和交联剂在500r/min下搅拌20min，最后使用5μm的滤膜过滤即得纺织品喷墨印花涂层。
实施例2：
一种纺织品喷墨印花涂层，包括以下按质量份数计的组分：
将除了水性聚氨酯和交联剂之外的上述组分按顺序投入物料机在500r/min下搅拌20min使其混合均匀后，加入水性聚氨酯和交联剂在500r/min下搅拌20min，最后使用5μm的滤膜过滤即得纺织品喷墨印花涂层。
实施例3：
一种纺织品喷墨印花涂层，包括以下按质量份数计的组分：
将除了水性聚氨酯和交联剂之外的上述组分按顺序投入物料机在500r/min下搅拌20min使其混合均匀后，加入水性聚氨酯和交联剂在500r/min下搅拌20min，最后使用5μm的滤膜过滤即得纺织品喷墨印花涂层。
实施例4：
一种纺织品喷墨印花涂层，包括以下按质量份数计的组分：
将除了水性聚氨酯和交联剂之外的上述组分按顺序投入物料机在500r/min下搅拌20min使其混合均匀后，加入水性聚氨酯和交联剂在500r/min下搅拌20min，最后使用5μm的滤膜过滤即得纺织品喷墨印花涂层。
实施例5：
一种纺织品喷墨印花涂层，包括以下按质量份数计的组分：
将除了水性聚氨酯和交联剂之外的上述组分按顺序投入物料机在500r/min下搅拌20min使其混合均匀后，加入水性聚氨酯和交联剂在500r/min下搅拌20min，最后使用5μm的滤膜过滤即得纺织品喷墨印花涂层。
产品性能检测：
将上述实施例1～5所制得的涂层与国内某涂层采用爱普生DX5打印头在规格为1440*720的纯棉块上打印后，对纯棉块进行以下性能测试：
1、耐干擦度测试：按照GB/T3921.1-1997进行纺织品色牢度试验测试耐干擦度，标准定为≥3.0级为合格；
2、耐湿擦度测试：按照GB/T3921.1-1997进行耐湿擦度试验测试耐湿擦度，标准定为≥3.0级为合格；
3、颜色鲜艳程度：在D65光源下，图档和光源成45度角，颜色从十分鲜艳、一般鲜艳、颜色普通、颜色略暗、到颜色暗沉无光泽分别为5-1级；
4、边界清晰度测试：涂层喷涂量30ml/平方米，喷涂后30秒打印复合黑色颜色50mm*50mm色块，待干燥后在涂层上边缘向外的渗透情况，标准定为≤1.0mm级为合格；
检测结果如表1所示。
表1产品性能检测结果表
实施例1 实施例2 实施例3 实施例4 实施例5 国内某涂层
颜色鲜艳程度 5 4 5 5 4 4
干擦牢度 4 5 3 4 4 3
湿擦牢度 4 3 4 4 5 4
柔软度 无手感 无手感 无手感 无手感 无手感 略有手感
涂层颜色 无 无 无 无 无 无
边界清晰度 0.6mm 0.7mm 0.6mm 0.8mm 0.8mm 1.1mm
由表1可知，本发明所述的纺织品喷墨印花涂层与国内某涂层相比，对基布具有很好的结合牢度，耐干擦、湿擦牢度优异，能够适用于多种不同的基布上，尤其是纯棉；提高染料墨水在基布的色牢度和颜色亮度，而且打印边界清晰度高，使用该涂层印花的纺织品手感柔软、透气性强，环保、对人体无害。
上述实施方式仅为本发明的优选实施方式，不能以此来限定本发明保护的范围，本领域的技术人员在本发的基础上所做的任何非实质性的变化及替换均属于本发明所要求保护的范围。

Claims (7)

1.一种纺织品喷墨印花涂层，其特征在于：包括以下按质量份数计的组分：
所述涂层的表面张力为26-34dyn/cm、粘度为6-20厘泊；所述抑制剂选自醋酸、碳酸、柠檬酸中的一种或任意两种以上的混合；所述交联剂为开环温度为90-130℃的脂肪族封闭异氰酸酯固化剂。
2.根据权利要求1所述的纺织品喷墨印花涂层，其特征在于：包括以下按质量份数计的组分：
3.根据权利要求1所述的纺织品喷墨印花涂层，其特征在于：包括以下按质量份数计的组分：
4.根据权利要求1～3中任一项所述的纺织品喷墨印花涂层，其特征在于：所述杀菌剂为异噻唑啉酮类杀菌剂。
5.根据权利要求1～3中任一项所述的纺织品喷墨印花涂层，其特征在于：所述润湿剂为脂肪醇聚氧乙烯醚。
6.根据权利要求1～3中任一项所述的纺织品喷墨印花涂层，其特征在于：所述水性聚氨酯为水性脂肪族聚氨酯分散乳液，其分子量小于20000。
7.根据权利要求1～3中任一项所述的纺织品喷墨印花涂层，其特征在于：所述溶剂为二乙二醇、甘油、peg400中的一种。
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