CN105731922B - The outdoor relief materials of the anti-folding of lightweight and the method that outdoor embossment is made using the material - Google Patents
The outdoor relief materials of the anti-folding of lightweight and the method that outdoor embossment is made using the material Download PDFInfo
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- CN105731922B CN105731922B CN201610036948.1A CN201610036948A CN105731922B CN 105731922 B CN105731922 B CN 105731922B CN 201610036948 A CN201610036948 A CN 201610036948A CN 105731922 B CN105731922 B CN 105731922B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The method that outdoor embossment is made the invention discloses a kind of outdoor relief materials of the anti-folding of lightweight and using the material, wherein, outdoor relief materials include main material and auxiliary material, and the formula of main material is as follows：500 900kg of modified ordinary portland cement, 200 500kg of quartz sand, cement enhancing rubber powder 26kg, hydrophober 15kg, carbon fiber 4kg, pure acrylic acid 35kg, phenylacrylic acid 150kg, 150 200kg of water；The formula of auxiliary material is as follows：High-strength polymer powders 200kg, EPS granular polystyrene 1m3, carbon fiber 5kg, hydrophober 10kg, phenylacrylic acid 30kg, water 80kg.The invention has the beneficial effects that：Main material operable time is 30 minutes, and when upper strength time 6 12 is small, upper intensity is fast, easy for construction, and after upper intensity, compactness is good, and surface is water-fast, hydrophobicity is extremely strong, and outdoor stability is good；Auxiliary material is light, after being combined with main material, with respect to 1/5 that proportion is stone material, be the 1/4 of brick and ceramics, intensity is good, it is impervious it is good, hydrophobicity is good.
Description
Technical field
Embossing method is made the present invention relates to a kind of relief materials and using the relief materials, and in particular to a kind of lightweight resists
The outdoor relief materials of folding and the method that the outdoor relief materials of the anti-folding of the lightweight is utilized to make outdoor embossment, belong to building material technique
Field.
Background technology
At present, the mainstay material of China open air engraving industry is：Stone material, ceramics, brick, sandstone, fiberglass and resin glue.Profit
With the works that form of these materials engraving, all there are it is different degrees of the defects of.
Stone carving works：Cost is high, weight, and transport is difficult to install, and impervious and anti-fouling performance is poor.
Ceramics carving works：Cost is high, it is difficult to do big.
Tile carving works and sandstone carving works：Cost is high, and antipollution and hydrophobicity are very poor, yielding.
Fiberglass works and resin glue works：Most hollow, weatherability, intensity, restricted lifetime.
In addition, there are one the shortcomings that general character for above-mentioned a few class engraving works：Replicability is poor.
The content of the invention
First outdoor relief materials for being designed to provide a kind of anti-folding of lightweight of the present invention, not only body is light for the material,
And High anti bending strength, and outdoor stability is good.
In order to realize above-mentioned target, the present invention adopts the following technical scheme that：
A kind of outdoor relief materials of the anti-folding of lightweight, which is characterized in that including main material and auxiliary material,
The formula of foregoing main material is as follows：
The formula of foregoing auxiliary material is as follows：
Wherein, foregoing high-strength polymer powders enhance the mixture of rubber powder, the mixing ratio of the two for ordinary portland cement and cement
Example is 20kg：1kg.
The outdoor relief materials of the anti-folding of foregoing lightweight, which is characterized in that in foregoing main material, aforementioned modified ordinary portland cement
For ordinary portland cement and the mixture of early strength agent and reinforcing agent, the mixed proportion of three is 40kg：1kg：2kg.
The outdoor relief materials of the anti-folding of foregoing lightweight, which is characterized in that in foregoing main material and auxiliary material, aforementioned cement increases
Strong rubber powder is modified phenylethylene.
The outdoor relief materials of the anti-folding of foregoing lightweight, which is characterized in that in foregoing main material and auxiliary material, foregoing hydrophober
For organosilicon powder.
Second object of the present invention is to provide a kind of method for making outdoor embossment using above-mentioned material, the making side
Not only production efficiency is high, at low cost for method, but also reproducible multiple similary works.
In order to realize above-mentioned target, the present invention adopts the following technical scheme that：
A kind of method for making outdoor embossment, which is characterized in that comprise the following steps：
(1) matrix is made, and ready-made matrix is suitably fixed, then add enclosing in the surrounding of matrix；
(2) main material is prepared, the main material slurry being stirred equably is poured in die surface；
(3) in 3 minutes after casting, layer of glass fiber grid cloth is spread in main material pulp surface, and it is made to be immersed in main material
Among；
(4) auxiliary material is prepared, when completing process above 20 minutes, the auxiliary material slurry being stirred is cast to main material surface
On, until reaching the height of enclosing；
(5) one layer of large mesh grid cloth or steel wire are spread in auxiliary material pulp surface, and it is made to be immersed among auxiliary material, table
Face is not exposed；
(6) when static maintenance 5-8 is small；
(7) form removal piece, finished product complete.
The method of the outdoor embossment of foregoing making, which is characterized in that the casting thickness of foregoing main material slurry is 3mm-8cm.
The invention has the beneficial effects that：
First, main material：
1st, operable time is 30 minutes, and when upper strength time 6-12 is small, upper intensity is fast, easy for construction；
2nd, after upper intensity, compactness is good, and anti-drawing strength is higher, general >=1.5MPa；
3rd, after upper intensity, surface is water-fast, hydrophobicity is extremely strong, and water absorption rate is generally≤1%；
4th, after upper intensity, outdoor stability is good, temperature, humidity, be exposed to the sun, in the environment of freeze thawing it is indeformable, do not crack；
5th, it is good with auxiliary material associativity, and deformation modulus is very close, and have certain microcosmic flexibility.
2nd, auxiliary material：
1st, it is light, after being combined with main material, with respect to 1/5 that proportion is stone material, be brick and ceramics 1/4, not only increase fortune
Defeated convenience reduces the difficulty of construction, and can suitably increase thickness, and then enhances fracture resistence force；
2nd, intensity it is good, it is impervious it is good, hydrophobicity is good.
3rd, production method：
1st, intensity, the demoulding can be gone up when whole general maintenance 5-8 is small, the product of morning production, afternoon, just energy entrucking was dispatched from the factory,
It is with short production cycle；
2nd, mould forming method is employed, multiple products can be disposably manufactured according to production requirement, production efficiency improves；
3rd, can output large screen, individual picture is up to 3m × 3m；
4th, the designed capacity of electromechanical equipment and computer software can be maximally utilised, reduce or be not required to manually to carve chisel,
Very fine and complicated figure can be so createed, remote super manual quarter chisel ability.
Description of the drawings
Fig. 1 is the schematic diagram for making outdoor embossment.
The meaning of reference numeral in figure：1- operating platforms, 2- fixed blocks, 3- matrixs, 4- enclosings.
Specific embodiment
Make specific introduce to the present invention below in conjunction with specific embodiment.
First, the main material of outdoor relief materials
Main material appearance is powdered, mainly by modified ordinary portland cement (early strength agent and reinforcing agent are added in ordinary portland cement) and one
A little important additive compositions.
The formula of main material is as follows：Modified ordinary portland cement 500-900kg, quartz sand 200-500kg, cement enhancing rubber powder
26kg, hydrophober 15kg, carbon fiber 4kg, pure acrylic acid 35kg, phenylacrylic acid 150kg, water 150-200kg.
Modified ordinary portland cement is marked as 42.5#Ordinary portland cement (Portland cement) and early strength agent and reinforcing agent
Mixture, the mixed proportion of three is 40kg：1kg：2kg.Wherein, the active ingredient of early strength agent is calcium formate, and reinforcing agent has
It is modified phenylethylene to imitate ingredient.Intensity is fast on modified ordinary portland cement, it is small to deform.
The grain size of quartz sand is 0.2mm-1.0mm.The effect of quartz sand in formula is to increase compactness and hardness.
Cement enhancing rubber powder is modified phenylethylene.The effect of cement enhancing rubber powder in formula is that the strength of materials is made substantially to increase
By force.
Hydrophober is organosilicon powder.The effect of hydrophober in formula is to improve the impervious outlet capacity of material.
The effect of carbon fiber in formula is enhancing structure intensity.
The effect of pure acrylic acid in formula is to increase compactness and hydrophobicity performance.
The effect of phenylacrylic acid in formula is to increase the toughness of cement.
In the formula of the present invention, the dosage of modified ordinary portland cement, quartz sand and water is variable, the purpose for the arrangement is that root
According to the different main materials for needing the slightly discrepant several type of output performance.Such as：When producing general performance and middle-size and small-size works,
Material utilization amount can remove the limit；When producing Large-scale Artistic product, material utilization amount wants capping.
Main material by be formulated it is deployed after, moderate-speed mixer 3 minutes in mixer, in the good slurry of mobile performance, one
As operable time be 30 minutes, when upper strength time 6-12 is small.
The performance of main material under 1 different formulations of table compares
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Modified ordinary portland cement | 500kg | 700kg | 900kg |
| Quartz sand | 500kg | 300kg | 200kg |
| Cement enhances rubber powder | 26kg | 26kg | 26kg |
| Hydrophober | 15kg | 15kg | 15kg |
| Carbon fiber | 4kg | 4kg | 4kg |
| Pure acrylic acid | 35kg | 35kg | 35kg |
| Phenylacrylic acid | 150kg | 150kg | 150kg |
| Water | 150kg | 180kg | 200kg |
| Environment temperature | -25℃ | 25℃ | 40℃ |
| Operable time | 30 minutes | 30 minutes | 30 minutes |
| Upper strength time | 7 it is small when | 7 it is small when | 7 it is small when |
| Anti-drawing strength | ≥1.5MPa | ≥1.5MPa | ≥1.5MPa |
| Water absorption rate | ≤ 1% | ≤ 1% | ≤ 1% |
| Deformation modulus | ≤ 0.05% | ≤ 0.05% | ≤ 0.06% |
| Density | It is good | It is good | It is good |
The stability of main material under the different outdoor environments of table 2
| Selection | Outdoor temperature | Outdoor humidity | Deformation | Cracking situation |
| Embodiment 2 | -25℃ | 10% | It deforms small | Without cracking |
| Embodiment 2 | -15℃ | 10% | It deforms small | Without cracking |
| Embodiment 2 | -5℃ | 20% | It deforms small | Without cracking |
| Embodiment 2 | 5℃ | 30% | It deforms small | Without cracking |
| Embodiment 2 | 15℃ | 40% | It deforms small | Without cracking |
| Embodiment 2 | 25℃ | 60% | It deforms small | Without cracking |
| Embodiment 2 | 35℃ | 80% | It deforms small | Without cracking |
| Embodiment 2 | 45℃ | 85% | It deforms small | Without cracking |
From Tables 1 and 2：
(1) intensity is fast in main material of the invention, and construction is extremely convenient；
(2) on after intensity, compactness is good, and anti-drawing strength is higher；
(3) on after intensity, surface is water-fast, hydrophobicity is extremely strong；
(4) on after intensity, temperature, humidity, be exposed to the sun, in the environment of freeze thawing it is indeformable, do not crack, outdoor stability is good；
(5) deformation modulus≤0.05% has certain microcosmic flexibility.
It can be seen that the property indices of the main material of the present invention are all preferable, it is the only selection for making outdoor embossment.
The present invention main material, why have shorter upper strength time, be because：Used modified ordinary portland cement
Intensity is fast on (early strength agent and reinforcing agent are added in ordinary portland cement), it is small to deform；Why it has preferable outdoor stability, is
Because：Portland cement normally goes up intensity and contains a certain amount of bubble.
2nd, auxiliary material
Auxiliary material is to overlay on the composite material at the main material back side, mainly by high-strength polymer powders, EPS granular polystyrenes and some weights
The additive composition wanted.
The formula of auxiliary material is as follows：High-strength polymer powders 200kg, EPS granular polystyrene 1m3, carbon fiber 5kg, hydrophober
10kg, phenylacrylic acid 30kg, water 80kg.
High-strength polymer powders enhance the mixture of rubber powder for ordinary portland cement and cement, and the mixed proportion of the two is 20kg：
1kg.The effect of high-strength polymer powders in formula is to make thermal insulator quickly upper intensity, is formed whole.
The effect of EPS granular polystyrenes in formula is to mitigate weight, improves overall stability.
The effect of carbon fiber in formula is enhancing overall construction intensity.
Hydrophober is organosilicon powder, and effect in formula is to improve whole anti-water absorbing capacity.
The effect of phenylacrylic acid in formula is to increase the toughness of cement.
Auxiliary material by be formulated it is deployed after, mixed slowly in mixer 5 minutes, form flowable light compounds,
When operable time 1 is small, when upper strength time 5-8 is small.It under normal circumstances, can be by being adhesively fixed on base surface.
The performance evaluation of 3 auxiliary material of table
As shown in Table 3：
(1) auxiliary material of the invention is light, after being combined with main material, can not only improve the convenience of transport, reduce the difficulty of construction
Degree, and can suitably increase thickness, and then enhance fracture resistence force；
(2) anti-drawing strength is big, >=1.5MPa；
(3) impervious and hydrophobicity is good.
It can be seen that the auxiliary material of the present invention is to make the only selection of core.
3rd, the method for making outdoor embossment
1st, matrix is made
According to client's needs, designed artistic manuscript is implanted into common carpenter by the design art manuscript in engraving software
Engraving machine.
Mold materials density available plate, gypsum or oak, the mould of big figure can be spliced by so first carving out one or a few
Have prototype, then large-scale suction blow moulding machine is put into this mold prototype, suction out depiction prototype matrix, matrix is taken out, for pouring
Cast engraving work.
This matrix is made, can suitable sheet thickness be selected according to the molding works size of institute and fineness.It is this
The material of material is either polyvinyl chloride (abbreviation PVC) or polystyrene (abbreviation PS), thickness is from 0.2mm to 3mm
All may be used.
The use of PVC sheet not only makes product stripping extremely convenient, but also it is bright and clean well to generate lines product surface
Degree and compactness, so as to ensure that lines product not only has the function of water-impervious, but also are inherently derived good surface accuracy, eliminate line
The process that one layer of putty is scraped on surface again.
After making mold matrix, first matrix is lain on a platform, and it is suitably fixed, then will freely it be stuck up with adhesive tape
The part risen cements, then adds the enclosing of 1-5cm high in matrix surrounding, as shown in Figure 1.
Due to using mould forming method, so multiple products can disposably be manufactured according to production requirement, production efficiency carries significantly
It is high.
2nd, casting main material
Prepare each raw material according to the main material formula that provides, main material by be formulated it is deployed after, moderate-speed mixer 3 in mixer
Minute, the good main material slurry of mobile performance is obtained, the operable time of the main material slurry is 30 minutes, the main material that will be stirred
Slurry is equably poured in die surface.
Because matrix bottom surface is the molding male and fomale(M＆F) of engraving, the casting thickness of main material slurry will make thinnest part >=3mm, thickness
Thickness is up to 8cm.
3rd, grid cloth is spread
In 3 minutes after the casting of main material slurry, layer of glass fiber grid cloth is spread on the surface of main material slurry, and makes its leaching
Enter among main material.
4th, casting auxiliary material
Prepare each raw material according to the auxiliary material formula that provides, auxiliary material by be formulated it is deployed after, 5 are mixed slowly in mixer
Minute, flowable light compounds, i.e. auxiliary material slurry are obtained, when the operable time of the auxiliary material slurry is 1 small.
When completing 20 minutes of casting main material technique, the auxiliary material slurry being stirred is cast on main material surface, until
Reach the height of enclosing.
5th, secondary paving grid cloth
After auxiliary material of having cast slurry, one layer of large mesh grid cloth (or steel wire) is spread on the surface of auxiliary material slurry, and is made
It is immersed among auxiliary material, and surface not expose grid cloth (or steel wire).
6th, conserve, demould
It is static maintenance 5-8 it is small when can go up intensity.After matrix is taken off, finished product completes.
Since the upper strength time of main material slurry and auxiliary material slurry is all shorter, so the product of general morning production, afternoon
Energy entrucking is dispatched from the factory, the production cycle greatly shortens.
From the process of the outdoor embossment of making presented hereinbefore it will be seen that the production method of the present invention have it is following excellent
Gesture：
1st, the designed capacity of electromechanical equipment and computer software can be maximally utilised, reduce or be not required to manually to carve chisel,
Very fine and complicated figure can be so createed, remote super manual quarter chisel ability.
2nd, a variety of different natural colors can be mixed, make works more lively, pleasant.
3rd, the works of big length can be made, as a result of the auxiliary material of lightweight, substantially reduce works density, can be produced single
Block is the picture of 3m × 3m (or even bigger), this be existing traditional handicraft it is incomparable, this also makes it extend using empty
Between, imagine large area exterior wall engraving and become a reality.
4th, endless small-sized artistic work can be replicated, can both beautifies the yard, enclosure wall, and can also lay out desktop.
5th, using plastic uptake molding piece, an original mould can inhale multiple matrixs, and each matrix is again reusable, therefore,
The production method of the present invention has very strong copy function, and either big part smallclothes are all repeatable to make, and so greatly reduce
Cost improves production capacity.One secondary good works can be replicated equally very much, this is that stone carving and tile carving can not be accomplished.
The product overall evaluation：
1st, intensity, plasticity are controllable, and hydrophobic and antifouling property are promoted, and work surface finish greatly improves.Certainly,
Can surface be generated by coarse matter according to art requirement, can so changed various.And stone carving, tile carving surface can only be coarse or half
It is coarse, finish can not be improved.
2nd, it is easy for installation, it is glued on basic metope with bonding mortar point, image-stone carving is not required equally to be necessarily mounted at
On metal joist frame, construction is simple is reliable, and saving of labor saves fund.
3rd, raw material is done with silicate (ordinary portland cement), at low cost, what is taken is without cease, can be regardless of region.And it stone material, bakes bricks and makes pottery
Town of porcelain to facilitate, easily not as good as silicate material.
4th, other：Any surface finish, closely knit, water-impervious, surface accuracy are good.
It should be noted that the invention is not limited in any way for above-described embodiment, it is all to use equivalent substitution or equivalent change
The technical solution that the mode changed is obtained, all falls in protection scope of the present invention.
Claims (5)
1. a kind of outdoor relief materials of the anti-folding of lightweight, which is characterized in that including main material and auxiliary material,
The formula of the main material is as follows：
Modified ordinary portland cement 500-900kg,
Quartz sand 200-500kg,
Cement enhancing rubber powder 26kg,
Hydrophober 15kg,
Carbon fiber 4kg,
Pure acrylic acid 35kg,
Phenylacrylic acid 150kg,
Water 150-200kg；
The formula of the auxiliary material is as follows：
High-strength polymer powders 200kg,
EPS granular polystyrenes 1m3、
Carbon fiber 5kg,
Hydrophober 10kg,
Phenylacrylic acid 30kg,
Water 80kg,
Wherein, the high-strength polymer powders enhance the mixture of rubber powder for ordinary portland cement and cement, and the mixed proportion of the two is
20kg：1kg；
The modified ordinary portland cement is ordinary portland cement and early strength agent and the mixture of reinforcing agent, and the mixed proportion of three is 40kg：
1kg：2kg.
2. the outdoor relief materials of the anti-folding of lightweight according to claim 1, which is characterized in that in the main material and auxiliary material
In, the cement enhancing rubber powder is modified phenylethylene.
3. the outdoor relief materials of the anti-folding of lightweight according to claim 1, which is characterized in that in the main material and auxiliary material
In, the hydrophober is organosilicon powder.
4. a kind of outdoor relief materials using the anti-folding of lightweight described in claim 1 make the method for outdoor embossment, feature
It is, comprises the following steps：
（1）Matrix is made, and ready-made matrix is suitably fixed, then add enclosing in the surrounding of matrix；
（2）Main material is prepared, the main material slurry being stirred equably is poured in die surface；
（3）In 3 minutes after casting, layer of glass fiber grid cloth is spread in main material pulp surface, and it is made to be immersed among main material；
（4）Auxiliary material is prepared, when completing process above 20 minutes, the auxiliary material slurry being stirred is cast on main material surface, directly
To the height for reaching enclosing；
（5）One layer of large mesh grid cloth or steel wire are spread in auxiliary material pulp surface, and it is made to be immersed among auxiliary material, surface is not
It is exposed；
（6）It is static maintenance 5-8 it is small when；
（7）Form removal piece, finished product complete.
5. the method according to claim 4 for making outdoor embossment, which is characterized in that the casting thickness of the main material slurry
For 3mm-8cm.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610036948.1A CN105731922B (en) | 2016-01-20 | 2016-01-20 | The outdoor relief materials of the anti-folding of lightweight and the method that outdoor embossment is made using the material |
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|---|---|---|---|
| CN201610036948.1A CN105731922B (en) | 2016-01-20 | 2016-01-20 | The outdoor relief materials of the anti-folding of lightweight and the method that outdoor embossment is made using the material |
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| CN105731922B true CN105731922B (en) | 2018-05-18 |
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| CN106278042B (en) * | 2016-08-15 | 2018-05-25 | 湖南工业大学 | A kind of one-pass molding embossment |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101229661A (en) * | 2008-02-18 | 2008-07-30 | 成都市福美来艺术装饰材料厂 | Technique of manufacturing artificial cultured stone |
| CN104529289A (en) * | 2014-12-18 | 2015-04-22 | 上海卓欧建筑装饰工程有限公司 | Modeling stone surface slurry, structure material and modeling stone |
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2016
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101229661A (en) * | 2008-02-18 | 2008-07-30 | 成都市福美来艺术装饰材料厂 | Technique of manufacturing artificial cultured stone |
| CN104529289A (en) * | 2014-12-18 | 2015-04-22 | 上海卓欧建筑装饰工程有限公司 | Modeling stone surface slurry, structure material and modeling stone |
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