CN105694227A - 一种高填充烷锑复合型阻燃母粒及其制备方法与应用 - Google Patents

一种高填充烷锑复合型阻燃母粒及其制备方法与应用 Download PDF

Info

Publication number
CN105694227A
CN105694227A CN201610231093.8A CN201610231093A CN105694227A CN 105694227 A CN105694227 A CN 105694227A CN 201610231093 A CN201610231093 A CN 201610231093A CN 105694227 A CN105694227 A CN 105694227A
Authority
CN
China
Prior art keywords
parts
antimony
alkane
retardant master
master granule
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610231093.8A
Other languages
English (en)
Inventor
杨春彬
孙彤江
刘善书
孙桂林
林春辉
刘淑洪
邢福成
陈长建
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANDONG HAIWANG CHEMICAL CO Ltd
Original Assignee
SHANDONG HAIWANG CHEMICAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANDONG HAIWANG CHEMICAL CO Ltd filed Critical SHANDONG HAIWANG CHEMICAL CO Ltd
Priority to CN201610231093.8A priority Critical patent/CN105694227A/zh
Publication of CN105694227A publication Critical patent/CN105694227A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0853—Vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C08J2323/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/10—Homopolymers or copolymers of propene
    • C08J2423/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/066—LDPE (radical process)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种高填充烷锑复合型阻燃母粒，以重量份为单位，所述的阻燃母粒包括以下原料：十溴二苯乙烷50-70份，三氧化二锑10-20份，滑石粉8-20份，氢氧化镁3-8份，载体树脂4-12份，助剂1-3份，抗氧剂0.4-0.6份和白油0.5-1.5份。本发明具有更好的互容性，更易于分散和添加，更卫生，并减少挥发浪费；阻燃效果更好，机械性能提高，提高氧指数，降低熔滴性；使用时可使制品件表面光滑，提高产品附加值；并且随着滑石粉和氢氧化镁的加入与添加量的改变，大大降低了生产成本。

Description

一种高填充烷锑复合型阻燃母粒及其制备方法与应用
技术领域
本发明涉及化工材料领域，尤其涉及一种高填充烷锑复合型阻燃母粒及其制备方法与应用。
背景技术
近年来，随着多种阻燃剂并重使用的呼声日益提高，人们也把无机阻燃剂和有机阻燃剂相互添加。无机阻燃剂最大优点是低毒、低烟或抑烟、低腐蚀、且价格低廉，因而，国内外市场上陆续推出了一些新型环保复配阻燃母粒，使复配母粒得到了广泛应用。阻燃母粒亦称阻燃母料，防火母粒。是为了达到塑料、橡胶制品实现防火要求而产生的一类产品。阻燃母料(母粒)是在阻燃剂的基础上经过多种阻燃成份的有机结合、改性处理与协效作用，而制得的一种颗粒状产品。粉末状阻燃剂在运输过程中易产生粉尘，易受潮，不易分散，与树脂的相容性差，填充性低，添加量大，阻燃效果差、生产成本高等。十溴二苯乙烷母粒单独添加在ABS制品里，添加量大，添加量能达到20-25份，才能达到阻燃级别V0级。在生产中十溴二苯乙烷母粒含量达到90％时，挤出母粒困难，挤出电流高，压力大，产量低，颗粒不均匀，无光泽。
发明内容
本发明所要解决的技术问题是：针对现有技术存在的相容性差，填充性低，添加量大，阻燃效果差、生产成本高等不足，提供一种高填充烷锑复合型阻燃母粒及其制备方法与应用。
为解决上述技术问题，本发明的技术方案是：
一种高填充烷锑复合型阻燃母粒，以重量份为单位，所述的阻燃母粒包括以下原料：十溴二苯乙烷50-70份，三氧化二锑10-20份，滑石粉8-20份，氢氧化镁3-8份，载体树脂4-12份，助剂1-3份，抗氧剂0.4-0.6份和白油0.5-1.5份。
优选的，所述的阻燃母粒为以重量份为单位的以下原料：十溴二苯乙烷60份，三氧化二锑12份，滑石粉11.5份，氢氧化镁5份，载体树脂8份，助剂2份，抗氧剂0.5份和白油1份。
优选的，所述的载体树脂为均聚聚丙烯、低密度聚乙烯、乙烯-醋酸乙烯中至少一种。
优选的，所述的助剂为聚乙烯蜡。
一种高填充烷锑复合型阻燃母粒的制备方法，包括以下步骤：
a.以重量份为单位，按照比例准确称取十溴二苯乙烷、三氧化二锑、滑石粉、氢氧化镁、树脂、助剂、抗氧剂和白油；
b.将称取的物料投入高混机中，盖好盖子，先常温低速启动混合3分钟，然后在温度80-100℃下高速混合5-7分钟；混料完毕后，以低速旋转将物料送入密炼机；
c.设定好树脂的熔化温度，在密炼机内密炼成团后，倒出物料，投入到挤出机；
d.设定比步骤c温度高10-20℃的温度，将物料挤出；
e.将挤出后的物料进行切粒；
f.准确称量重量，检测并进行包装。
优选的，上述步骤d中温度使用水循环***调节。
优选的，上述步骤e中切粒的速度是根据步骤d中的物料的挤出速度进行调整。
一种高填充烷锑复合型阻燃母粒的应用，所述高填充烷锑复合型阻燃母粒在聚乙烯、聚丙烯、乙烯-醋酸乙烯等塑料制品中的应用。
由于采用了上述技术方案，本发明的有益效果是：本发明的阻燃母粒与一般塑料颗粒大小相当，提高了他们之间的互容性，更易于分散和添加，更卫生，并减少挥发浪费。同时克服了生产时产生的分层，起霜，花纹等问题，制品件表面光滑，提高了产品附加值。同样在ABS制品中，单独母粒添加量20-25％，才能达到V0级，复合母粒只需添加18％。溴锑混合阻燃效果比单纯的溴、锑阻燃要好，机械性能提高，提高氧指数，降低熔滴性。相比于普通的三氧化二锑、十溴二苯乙烷粉体单独使用来说，本发明制备的复合阻燃母粒在阻燃性与力学性能有所提高，并且滑石粉氢氧化镁的加入与添加量的改变，大大降低了生产成本。
具体实施方式
下面结合实施例，进一步阐述本发明。
实施例一：以重量份为单位，准确称取十溴二苯乙烷50份，三氧化二锑20份，滑石粉12.6份，氢氧化镁3份，以均聚聚丙烯为载体12份，聚乙烯蜡1份，抗氧剂0.4份(1010和168并用)，白油1.0份投入高速混合机，盖好盖子，先常温低速启动混合3分钟，然后高速混料7.0分钟，混料温度为120℃，混料结束后，打开放料阀，用低速旋转将物料送入密炼机密炼，密炼成团后，经单螺杆切粒机挤出，切粒、筛分，得到阻燃母粒产品。再添加到聚丙烯制品中，添加量为3％-5％,就能达到该产品的防火要求，阻燃级别V2级。
添加3％复合阻燃母粒到聚丙烯中，在水平垂直燃烧测定仪下测得数据如下(见表1)：
表1.1.6mm样条阻燃性能检测结果v2
实施例二：以重量为单位，准确称取十溴二苯乙烷60份，三氧化二锑12份，滑石粉12份，氢氧化镁8份，以低密度聚乙烯为载体4份，聚乙烯蜡2份，抗氧剂0.5份(1010和168并用)，白油1.5份投入高速混合机，盖好盖子，先常温低速启动混合3分钟，然后高速混料7.0分钟，混料温度为100℃，混料结束后，打开放料阀，用低速旋转将物料送入密炼机密炼，密炼成团后，经单螺杆切粒机挤出，切粒、筛分，得到阻燃母粒产品。再添加到其它塑料制品中(聚乙烯除外)，添加量为20％左右，就能达到国家规定的防火要求，阻燃级别V0级。添加到聚乙烯制品中，添加量在8％左右，会减缓火焰的燃烧速度，同样制品火焰燃烧速度比未添加的小20s，添加量过大，会严重影响聚乙烯制品的力学性能和机械性能。
添加16％复合阻燃母粒到PBT中，在水平垂直燃烧测定仪下测得数据如下(见表2)：
表2.1.6mm样条阻燃性能检测结果v0
实施例三：以重量为单位，称取十溴二苯乙烷70份，三氧化二锑10.9份，滑石粉8份，氢氧化镁3份，以EVA(乙烯-醋酸乙烯)为载体4份，聚乙烯蜡3份，抗氧剂0.6份(1010和168并用)，白油0.5份投入高速混合机，盖好盖子，先常温低速启动混合3分钟，然后高速混料7.0分钟，混料温度为75℃，混料结束后，打开放料阀，用低速旋转将物料送入密炼机密炼，密炼成团后，经单螺杆切粒机挤出，切粒、筛分，得到阻燃母粒产品。添加到塑料制品中，添加量为20％左右，就能达到V0级国家规定的防火要求。
添加19％复合阻燃母粒到ABS中，在水平垂直燃烧测定仪下测得数据如下(见表3)：
表3.1.6mm样条阻燃性能检测结果v0
塑料阻燃等级由HB，V-2，V-1向V-0逐级递增：
1、HB：UL94标准中最低的阻燃等级。要求对于3到13毫米厚的样品，燃烧速度小于40毫米每分钟；小于3毫米厚的样品，燃烧速度小于70毫米每分钟；或者在100毫米的标志前熄灭。
2、V-2：对样品进行两次10秒的燃烧测试后，火焰在60秒内熄灭。可以有燃烧物掉下。
3、V-1：对样品进行两次10秒的燃烧测试后，火焰在60秒内熄灭。不能有燃烧物掉下。
4、V-0：对样品进行两次10秒的燃烧测试后，火焰在30秒内熄灭。不能有燃烧物掉下。
应理解，这些实施例仅用于说明本发明而不用于限制本发明的范围。此外应理解，在阅读了本发明讲授的内容之后，本领域技术人员可以对本发明作各种改动或修改，这些等价形式同样落于本申请所附权利要求书所限定的范围。

Claims (8)

1.一种高填充烷锑复合型阻燃母粒，其特征在于：以重量份为单位，所述阻燃母粒包括以下原料：十溴二苯乙烷50-70份，三氧化二锑10-20份，滑石粉8-20份，氢氧化镁3-8份，载体树脂4-12份，助剂1-3份，抗氧剂0.4-0.6份和白油0.5-1.5份。
2.如权利要求1所述的高填充烷锑复合型阻燃母粒，其特征在于：所述阻燃母粒包括以重量份为单位的以下原料：十溴二苯乙烷60份，三氧化二锑12份，滑石粉11.5份，氢氧化镁5份，载体树脂8份，助剂2份，抗氧剂0.5份和白油1份。
3.如权利要求2所述的高填充烷锑复合型阻燃母粒，其特征在于：所述载体树脂为均聚聚丙烯、低密度聚乙烯、乙烯-醋酸乙烯中至少一种。
4.如权利要求2所述的高填充烷锑复合型阻燃母粒，其特征在于：所述助剂为聚乙烯蜡。
5.一种高填充烷锑复合型阻燃母粒的制备方法，其特征在于：所述制备方法包括以下步骤：
a.以重量份为单位，按比例称取十溴二苯乙烷、三氧化二锑、滑石粉、氢氧化镁、树脂、助剂、抗氧剂和白油；
b.将称取的物料投入高混机中，盖好盖子，先常温低速启动混合3分钟，然后在温度80-100℃下高速混合5-7分钟；混料完毕后，以低速旋转将物料送入密炼机；
c.设定好树脂的熔化温度，在密炼机内密炼成团后，倒出物料，投入到挤出机；
d.设定比步骤c温度高10-20℃的温度，将物料挤出；
e.将挤出后的物料进行切粒；
f.称重，检测并进行包装。
6.如权利要求5所述的高填充烷锑复合型阻燃母粒的制备方法，其特征在于：所述步骤d中温度使用水循环***调节。
7.如权利要求5所述的高填充烷锑复合型阻燃母粒的制备方法，其特征在于：所述步骤e中切粒的速度是根据步骤d中的物料的挤出速度进行调整。
8.一种高填充烷锑复合型阻燃母粒的应用，其特征在于；所述高填充烷锑复合型阻燃母粒在聚乙烯、聚丙烯、乙烯-醋酸乙烯等塑料制品中的应用。
CN201610231093.8A 2016-04-14 2016-04-14 一种高填充烷锑复合型阻燃母粒及其制备方法与应用 Pending CN105694227A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610231093.8A CN105694227A (zh) 2016-04-14 2016-04-14 一种高填充烷锑复合型阻燃母粒及其制备方法与应用

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610231093.8A CN105694227A (zh) 2016-04-14 2016-04-14 一种高填充烷锑复合型阻燃母粒及其制备方法与应用

Publications (1)

Publication Number Publication Date
CN105694227A true CN105694227A (zh) 2016-06-22

Family

ID=56216306

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610231093.8A Pending CN105694227A (zh) 2016-04-14 2016-04-14 一种高填充烷锑复合型阻燃母粒及其制备方法与应用

Country Status (1)

Country Link
CN (1) CN105694227A (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111057302A (zh) * 2019-12-30 2020-04-24 广东国珑新材料科技有限公司 一种复合无机阻燃母粒及其制备方法
CN113698737A (zh) * 2021-10-15 2021-11-26 湖南美莱珀科技发展有限公司 一种阻燃材料、含该阻燃材料的母粒及母粒的制备方法
CN114015164A (zh) * 2021-11-25 2022-02-08 安庆会通新材料有限公司 一种阻燃聚丙烯材料及其制备方法
CN114230932A (zh) * 2021-11-23 2022-03-25 金发科技股份有限公司 一种阻燃填充聚丙烯材料及其制备方法与应用

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1865335A (zh) * 2006-06-26 2006-11-22 李彦波 一种高浓度塑料纳米阻燃母粒的生产方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1865335A (zh) * 2006-06-26 2006-11-22 李彦波 一种高浓度塑料纳米阻燃母粒的生产方法

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111057302A (zh) * 2019-12-30 2020-04-24 广东国珑新材料科技有限公司 一种复合无机阻燃母粒及其制备方法
CN113698737A (zh) * 2021-10-15 2021-11-26 湖南美莱珀科技发展有限公司 一种阻燃材料、含该阻燃材料的母粒及母粒的制备方法
CN114230932A (zh) * 2021-11-23 2022-03-25 金发科技股份有限公司 一种阻燃填充聚丙烯材料及其制备方法与应用
CN114015164A (zh) * 2021-11-25 2022-02-08 安庆会通新材料有限公司 一种阻燃聚丙烯材料及其制备方法

Similar Documents

Publication Publication Date Title
CN102391608B (zh) 一种超高耐热阻燃abs组合物及其制备方法
CN105694227A (zh) 一种高填充烷锑复合型阻燃母粒及其制备方法与应用
CN102002203B (zh) 一种阻燃asa改性树脂及其制备方法
CN101659779B (zh) 一种无卤阻燃abs树脂及其制备方法
CN105385028A (zh) 一种高阻燃聚丙烯材料及其制备方法
CN103627168B (zh) 一种尼龙专用无卤阻燃母粒及其制备方法
CN102675776A (zh) 一种高流动性高阻燃性聚氯乙烯复合材料及其制备方法
CN104119556A (zh) 一种含有热稳定剂的阻燃母粒及其制备方法
CN104086943A (zh) 一种具有优异表面的高光泽高黑度阻燃abs树脂及其制备方法
CN109705462A (zh) 一种挤出吸塑专用v0级无卤阻燃聚丙烯材料及其制备方法
CN102746607A (zh) 一种绝缘导热环保阻燃abs树脂及其制备方法
CN107501834A (zh) 一种电器外壳用低气味、高光泽和高流动性的阻燃hips材料及其制备方法
CN104334622A (zh) 无锑的阻燃苯乙烯类热塑性聚合物组合物,含有它的制品以及制造它的方法
CN101891952B (zh) 一种无析出阻燃母料
WO2013085791A1 (en) Low antimony flame-retarded styrenic thermoplastic polymer composition
CN110305440B (zh) 一种环保阻燃abs复合材料及其制备方法
CN103044848A (zh) Abs/pmma复合材料及其制备方法
CN102181141B (zh) 一种无卤阻燃高韧的改性聚碳酸酯的制备方法
CN104194302B (zh) 一种abs缓燃级色母粒
CN109593281A (zh) 一种eps阻燃母粒及其制备方法
CN105273298A (zh) 一种高光泽耐析出阻燃聚丙烯材料及其制备方法
CN101429313A (zh) 一种无卤阻燃高抗冲聚苯乙烯及其制备方法
JP2003512493A (ja) 安定化された難燃性添加剤及びそれらの使用
EP2617769B1 (en) Thermoplastic resin composition having excellent flame retardancy, coloring properties, and scratch resistance
CN105086077A (zh) 一种抗静电效果优异的阻燃电缆料及其制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20160622