CN105670127B - 一种制备高性能pp/pet共混物的新方法 - Google Patents
一种制备高性能pp/pet共混物的新方法 Download PDFInfo
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- CN105670127B CN105670127B CN201610097741.5A CN201610097741A CN105670127B CN 105670127 B CN105670127 B CN 105670127B CN 201610097741 A CN201610097741 A CN 201610097741A CN 105670127 B CN105670127 B CN 105670127B
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- Prior art keywords
- pet
- dap
- masterbatch
- grafted
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- 239000000203 mixture Substances 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims abstract description 16
- 239000004641 Diallyl-phthalate Substances 0.000 claims abstract description 49
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 41
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 claims abstract description 40
- 238000002156 mixing Methods 0.000 claims abstract description 14
- 239000000178 monomer Substances 0.000 claims abstract description 11
- 239000003999 initiator Substances 0.000 claims abstract description 10
- 238000002360 preparation method Methods 0.000 claims abstract description 7
- 238000006243 chemical reaction Methods 0.000 claims abstract description 6
- 150000002148 esters Chemical group 0.000 claims abstract description 3
- 230000001988 toxicity Effects 0.000 claims abstract 2
- 231100000419 toxicity Toxicity 0.000 claims abstract 2
- 239000004743 Polypropylene Substances 0.000 claims description 60
- 229920001155 polypropylene Polymers 0.000 claims description 60
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 21
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 21
- -1 polypropylene Polymers 0.000 claims description 16
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 6
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical group C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 2
- 230000035484 reaction time Effects 0.000 description 13
- 238000001035 drying Methods 0.000 description 12
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- IEBJZLRZRKTGFN-UHFFFAOYSA-N N=NC=NN.N=NC=NN.C1=CC=CC=C1 Chemical group N=NC=NN.N=NC=NN.C1=CC=CC=C1 IEBJZLRZRKTGFN-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000004067 bulking agent Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 229920002338 polyhydroxyethylmethacrylate Polymers 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 229920013730 reactive polymer Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
DAP接枝率(%) | 拉伸强度(MPa) | 断裂伸长率(%) | |
实例一 | 5.85 | 20±0.2 | 50±5 |
实例二 | 6.58 | 21±0.7 | 46±7 |
实例三 | 8.84 | 23±0.3 | 40±4 |
实例四 | 9.25 | 23±0.5 | 39±2 |
实例五 | 8.56 | 23±0.6 | 44±5 |
实例六 | 6.15 | 20±0.4 | 39±3 |
实例七 | 5.06 | 20±0.8 | 47±8 |
实例八 | 8.78 | 23±0.2 | 42±7 |
实例九 | 7.45 | 22±0.8 | 47±4 |
实例十 | 9.56 | 29±0.4 | 45±2 |
实例十一 | 6.58 | 22±0.6 | 46±6 |
实例十二 | 6.58 | 21±0.3 | 35±6 |
PPJ340纯样 | 0 | 21±0.8 | 361±2 |
PPGM1600E纯样 | 0 | 30±0.2 | 870±4 |
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610097741.5A CN105670127B (zh) | 2016-02-23 | 2016-02-23 | 一种制备高性能pp/pet共混物的新方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610097741.5A CN105670127B (zh) | 2016-02-23 | 2016-02-23 | 一种制备高性能pp/pet共混物的新方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105670127A CN105670127A (zh) | 2016-06-15 |
CN105670127B true CN105670127B (zh) | 2018-01-02 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610097741.5A Active CN105670127B (zh) | 2016-02-23 | 2016-02-23 | 一种制备高性能pp/pet共混物的新方法 |
Country Status (1)
Country | Link |
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CN (1) | CN105670127B (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108641198A (zh) * | 2018-05-25 | 2018-10-12 | 宁波星陆汽车部件有限公司 | 改性高熔融流动轮罩的制备工艺 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1226576A (zh) * | 1998-12-25 | 1999-08-25 | 清华大学 | 添加多官能单体对聚丙烯共混物反应增容的方法 |
-
2016
- 2016-02-23 CN CN201610097741.5A patent/CN105670127B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1226576A (zh) * | 1998-12-25 | 1999-08-25 | 清华大学 | 添加多官能单体对聚丙烯共混物反应增容的方法 |
Non-Patent Citations (2)
Title |
---|
"Compatibilization of polypropylene/recycled polyethylene";Ye ling Zhu,Changsheng Liang,Yang Bo,Shiai Xu;《Journal of Polymer Research》;20150211;摘要及结论部分 * |
"多单体接枝聚丙烯对PBT/PP共混体系的形态结构";高宁,叶苗,张景春,谢续明;《高分子学报》;20011231(第6期);第1-4段 * |
Also Published As
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CN105670127A (zh) | 2016-06-15 |
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Effective date of registration: 20231219 Address after: 321000, 1st floor, No. 1213 Hulian East Street, Liushi Street, Dongyang City, Jinhua City, Zhejiang Province (self declaration) Patentee after: Dongyang Fukang Environmental Protection Technology Co.,Ltd. Address before: 101200 room 205-211526, No. 40, Fuqian West Street, Pinggu town, Pinggu District, Beijing (cluster registration) Patentee before: BEIJING YONGBO TECHNOLOGY CO.,LTD. Effective date of registration: 20231219 Address after: 101200 room 205-211526, No. 40, Fuqian West Street, Pinggu town, Pinggu District, Beijing (cluster registration) Patentee after: BEIJING YONGBO TECHNOLOGY CO.,LTD. Address before: Gehu Lake Road Wujin District 213164 Jiangsu city of Changzhou province No. 1 Patentee before: CHANGZHOU University |
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