CN105647358A - Powder paint for aluminum section and preparation method thereof - Google Patents
Powder paint for aluminum section and preparation method thereof Download PDFInfo
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- CN105647358A CN105647358A CN201610120118.7A CN201610120118A CN105647358A CN 105647358 A CN105647358 A CN 105647358A CN 201610120118 A CN201610120118 A CN 201610120118A CN 105647358 A CN105647358 A CN 105647358A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The invention relates to powder paint, provides powder paint for the aluminum section and solves the problem that powder paint in the prior art is poor in adhesive force and prone to powder shedding and orange peel. The powder paint comprises, by weight, 66-70 parts of end carboxy polyester resin, 10-15 parts of titanium dioxide, 5-10 parts of ultrafine sericite, 12-18 parts of precipitated barium sulfate, 10-18 parts of alcohol, 4-5 parts of triglycidyl isocyanurate, 10-15 parts of silane coupling agent and 2-8 parts of expanded perlite.
Description
Technical field
The present invention relates to a kind of powdery paints, particularly relate to a kind of powdery paint for aluminum profile and preparation method thereof.
Background technology
The surface treatment mode of aluminium alloy extrusions substantially also exists anodic oxidation, electrophoretic painting, and fluorocarbon-sprayed and four kinds of processing modes of powder spray, each mode all respectively has superiority, and occupies the suitable market share. 1, in anodic oxidation, in the production process of electrophoretic painting, water, electric consumption are sizable. Particularly at oxidation operation, the output electric current of motor-generator set can reach between 8000��11000A, voltage is between 15��17.5V, add the heat consumption of machine itself, need ceaselessly to lower the temperature with recirculated water, ton power consumption is often at about 1000 degree, and auxiliary equipment also can increase some electric energy losses simultaneously; Secondly the pollution level of water, air is big, water and air are produced to pollute by sheet alkali, sulphuric acid and other liguid organic solvent, also can workmen's health be had undesirable effect; 2, the color of electrophoretic painting is more single, only several colors (silvery white, champagne, golden yellow, black, artificial stainless steel colour); Secondly, electrophoresis color tolerance is easily generated aberration and cannot increase coating layer thickness, and safety equipment requirement is higher, has certain danger; 3, fluorocarbon-sprayed, human body using solvent as dilution, to be produced harmful effect during operation during spraying by this series products, and secondly cost price is high, if processing bad during spraying, it is easy to produce Pericarpium Citri tangerinae; 4, comparing chromatic colour in powder spray easily to fade, the bad Surface of profile of surface treatment easily produces Pericarpium Citri tangerinae, even shedding, and powder thickness is uneven, it addition, existing powdery paints does not have effect of heat insulation.
Summary of the invention
Therefore, for above content, the present invention provides a kind of powdery paint for aluminum profile, solves powdery paints adhesive force of the prior art shedding not strong, easy, the problem easily producing Pericarpium Citri tangerinae.
For reaching above-mentioned purpose, the present invention is achieved by the following technical solutions: a kind of powdery paint for aluminum profile, including each raw material of following weight portion: terminal carboxyl polyester resin 66��70 weight portion, titanium dioxide 10��15 weight portion, ultra-fine sericite 5��10 weight portion, blanc fixe 12��18 weight portion, ethanol 10��18 weight portion, isocyanuric acid three-glycidyl ester 4��5 weight portion, silane coupler 10��15 weight portion, expanded perlite 2��8 weight portion.
Further, including each raw material of following weight portion: terminal carboxyl polyester resin 68��70 weight portion, titanium dioxide 13��15 weight portion, ultra-fine sericite 7��10 weight portion, blanc fixe 15��18 weight portion, ethanol 14��18 weight portion, isocyanuric acid three-glycidyl ester 4��5 weight portion, silane coupler 12��15 weight portion, expanded perlite 5��8 weight portion.
Further, including each raw material of following weight portion: terminal carboxyl polyester resin 69 weight portion, titanium dioxide 14 weight portion, ultra-fine sericite 8 weight portion, blanc fixe 16 weight portion, ethanol 17 weight portion, isocyanuric acid three-glycidyl ester 4 weight portion, silane coupler 14 weight portion, expanded perlite 6 weight portion.
Further, the potassium carbonate of 10��15 weight portions is also included.
Further, the ammonium dihydrogen phosphate of 15��20 weight portions is also included.
A kind of preparation method of powdery paint for aluminum profile, including following process step: terminal carboxyl polyester resin 66��70 weight portion, titanium dioxide 10��15 weight portion, blanc fixe 12��18 weight portion, ethanol 10��18 weight portion, isocyanuric acid three-glycidyl ester 4��5 weight portion, expanded perlite 2��8 weight portion are put into stirrer for mixing stirring 10��15min by (1), are heated to 16��25 DEG C; (2) it is subsequently added into ultra-fine sericite 5��10 weight portion, silane coupler 10��15 weight portion, continues stirring 5��10min, then melt extrude; (3) pulverization process: step (2) melt extrudate is pulverized; (4) screening, process of sieving, namely obtain powdery paint for aluminum profile.
Further, in step (2), it is also added with the potassium carbonate of 10��15 weight portions.
Further, in step (2), it is also added with the ammonium dihydrogen phosphate of 15��20 weight portions.
By adopting preceding solution, the invention has the beneficial effects as follows: the powdery paint for aluminum profile of the present invention, each raw material including following weight portion: terminal carboxyl polyester resin 66��70 weight portion, titanium dioxide 10��15 weight portion, ultra-fine sericite 5��10 weight portion, blanc fixe 12��18 weight portion, ethanol 10��18 weight portion, isocyanuric acid three-glycidyl ester 4��5 weight portion, silane coupler 10��15 weight portion, expanded perlite 2��8 weight portion, each material composition in raw material is collocated with each other, the coating being worth is made to have heat-blocking action, and be not likely to produce Pericarpium Citri tangerinae and be not easy shedding, the equal environment-protecting asepsis of each raw material, expanded perlite has loose structure, the light that can hinder different wave length involves the propagation of Thermal Infra-Red, play heat-blocking action, the collocation of ultra-fine sericite and silane coupler and other materials uses, the coating prepared can be made to have good performance, it is not easy shedding. the preparation method of the present invention is simple, adopts the powdery paints that the method prepares, adhesive force shedding higher, more difficult.
Detailed description of the invention
Describing embodiments of the present invention in detail below with reference to specific embodiment, to the present invention, how application technology means solve technical problem whereby, and the process that realizes reaching technique effect can fully understand and implement according to this.
If not specializing, the conventional means that the technological means adopted in embodiment is well known to those skilled in the art, the reagent adopted and product are also available commercial. The source of agents useful for same, trade name and be necessary to list its constituent person, all indicate when occurring first.
Embodiment one
A kind of powdery paint for aluminum profile, including each raw material of following weight portion: terminal carboxyl polyester resin 66 weight portion, titanium dioxide 10 weight portion, ultra-fine sericite 5 weight portion, blanc fixe 12 weight portion, ethanol 10 weight portion, isocyanuric acid three-glycidyl ester 4 weight portion, silane coupler 10 weight portion, expanded perlite 2 weight portion, the potassium carbonate of 10 weight portions, 15 weight portions ammonium dihydrogen phosphate.
Its preparation method, including following process step: terminal carboxyl polyester resin 66 weight portion, titanium dioxide 10 weight portion, blanc fixe 12 weight portion, ethanol 10 weight portion, isocyanuric acid three-glycidyl ester 4 weight portion, expanded perlite 2 weight portion are put into stirrer for mixing stirring 10min by (1), are heated to 16 DEG C; (2) it is subsequently added into ultra-fine sericite 5 weight portion, silane coupler 10 weight portion, continues stirring 5min, then melt extrude; (3) pulverization process: step (2) melt extrudate is pulverized; (4) screening, process of sieving, namely obtain powdery paint for aluminum profile.
Embodiment two
A kind of powdery paint for aluminum profile, including each raw material of following weight portion: terminal carboxyl polyester resin 66��70 weight portion, titanium dioxide 15 weight portion, ultra-fine sericite 10 weight portion, blanc fixe 18 weight portion, ethanol 18 weight portion, isocyanuric acid three-glycidyl ester 5 weight portion, silane coupler 15 weight portion, expanded perlite 8 weight portion, the potassium carbonate of 15 weight portions, 20 weight portions ammonium dihydrogen phosphate.
Its preparation method, including following process step: terminal carboxyl polyester resin 70 weight portion, titanium dioxide 15 weight portion, blanc fixe 18 weight portion, ethanol 18 weight portion, isocyanuric acid three-glycidyl ester 5 weight portion, expanded perlite 8 weight portion are put into stirrer for mixing stirring 15min by (1), are heated to 25 DEG C; (2) it is subsequently added into the ammonium dihydrogen phosphate of ultra-fine sericite 10 weight portion, silane coupler 15 weight portion, the potassium carbonate of 15 weight portions, 20 weight portions, continues stirring 10min, then melt extrude; (3) pulverization process: step (2) melt extrudate is pulverized; (4) screening, process of sieving, namely obtain powdery paint for aluminum profile.
Embodiment three
A kind of powdery paint for aluminum profile, including each raw material of following weight portion: terminal carboxyl polyester resin 69 weight portion, titanium dioxide 14 weight portion, ultra-fine sericite 8 weight portion, blanc fixe 16 weight portion, ethanol 17 weight portion, isocyanuric acid three-glycidyl ester 4 weight portion, silane coupler 14 weight portion, expanded perlite 6 weight portion, the potassium carbonate of 12 weight portions, 17 weight portions ammonium dihydrogen phosphate.
Its preparation method, including following process step: (1) terminal carboxyl polyester resin 69 weight portion, titanium dioxide 14 weight portion, blanc fixe 16 weight portion, ethanol 17 weight portion, isocyanuric acid three-glycidyl ester 4 weight portion, expanded perlite 6 weight portion put into stirrer for mixing stirring 12min, are heated to 16��25 DEG C; (2) be subsequently added into, the ammonium dihydrogen phosphate of ultra-fine sericite 8 weight portion, silane coupler 14 weight portion, the potassium carbonate of 12 weight portions, 17 weight portions, continue stirring 7min, then melt extrude; (3) pulverization process: step (2) melt extrudate is pulverized; (4) screening, process of sieving, namely obtain powdery paint for aluminum profile.
Raw material used by the powdery paint for aluminum profile of the present invention all can realize the purpose of the present invention in following scope: terminal carboxyl polyester resin 66��70 weight portion, titanium dioxide 10��15 weight portion, ultra-fine sericite 5��10 weight portion, blanc fixe 12��18 weight portion, ethanol 10��18 weight portion, isocyanuric acid three-glycidyl ester 4��5 weight portion, silane coupler 10��15 weight portion, expanded perlite 2��8 weight portion, the potassium carbonate of 10��15 weight portions, the ammonium dihydrogen phosphate of 15��20 weight portions.
Described in above, being only the embodiment utilizing this origination techniques content, any those skilled in the art use modification, the change that this creation does, and all belong to the scope of the claims that this creation is advocated, and are not limited to those disclosed embodiments.
Claims (8)
1. a powdery paint for aluminum profile, it is characterized in that, including each raw material of following weight portion: terminal carboxyl polyester resin 66��70 weight portion, titanium dioxide 10��15 weight portion, ultra-fine sericite 5��10 weight portion, blanc fixe 12��18 weight portion, ethanol 10��18 weight portion, isocyanuric acid three-glycidyl ester 4��5 weight portion, silane coupler 10��15 weight portion, expanded perlite 2��8 weight portion.
2. powdery paint for aluminum profile according to claim 1, it is characterized in that, including each raw material of following weight portion: terminal carboxyl polyester resin 68��70 weight portion, titanium dioxide 13��15 weight portion, ultra-fine sericite 7��10 weight portion, blanc fixe 15��18 weight portion, ethanol 14��18 weight portion, isocyanuric acid three-glycidyl ester 4��5 weight portion, silane coupler 12��15 weight portion, expanded perlite 5��8 weight portion.
3. powdery paint for aluminum profile according to claim 1, it is characterized in that, including each raw material of following weight portion: terminal carboxyl polyester resin 69 weight portion, titanium dioxide 14 weight portion, ultra-fine sericite 8 weight portion, blanc fixe 16 weight portion, ethanol 17 weight portion, isocyanuric acid three-glycidyl ester 4 weight portion, silane coupler 14 weight portion, expanded perlite 6 weight portion.
4. the powdery paint for aluminum profile according to claim 1 or 2 or 3, it is characterised in that: also include the potassium carbonate of 10��15 weight portions.
5. powdery paint for aluminum profile according to claim 4, it is characterised in that: also include the ammonium dihydrogen phosphate of 15��20 weight portions.
6. the preparation method of a powdery paint for aluminum profile, it is characterized in that, including following process step: terminal carboxyl polyester resin 66��70 weight portion, titanium dioxide 10��15 weight portion, blanc fixe 12��18 weight portion, ethanol 10��18 weight portion, isocyanuric acid three-glycidyl ester 4��5 weight portion, expanded perlite 2��8 weight portion are put into stirrer for mixing stirring 10��15min by (1), are heated to 16��25 DEG C; (2) it is subsequently added into ultra-fine sericite 5��10 weight portion, silane coupler 10��15 weight portion, continues stirring 5��10min, then melt extrude; (3) pulverization process: step (2) melt extrudate is pulverized; (4) screening, process of sieving, namely obtain powdery paint for aluminum profile.
7. the preparation method of powdery paint for aluminum profile according to claim 6, it is characterised in that: in step (2), it is also added with the potassium carbonate of 10��15 weight portions.
8. the preparation method of powdery paint for aluminum profile according to claim 7, it is characterised in that: in step (2), it is also added with the ammonium dihydrogen phosphate of 15��20 weight portions.
Priority Applications (1)
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CN201610120118.7A CN105647358A (en) | 2016-03-03 | 2016-03-03 | Powder paint for aluminum section and preparation method thereof |
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CN201610120118.7A CN105647358A (en) | 2016-03-03 | 2016-03-03 | Powder paint for aluminum section and preparation method thereof |
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CN201610120118.7A Pending CN105647358A (en) | 2016-03-03 | 2016-03-03 | Powder paint for aluminum section and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110317526A (en) * | 2019-06-28 | 2019-10-11 | 广东华江粉末科技有限公司 | A kind of high resistance to infiltration powdery paints and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102382010A (en) * | 2010-09-03 | 2012-03-21 | 袁雪冲 | Preparation process for 4- bromo phenyl hydrazine |
CN104263211A (en) * | 2014-10-17 | 2015-01-07 | 西北永新涂料有限公司 | Special anticorrosive powder coating for high-decorativeness pure polyester aluminum section and preparation method of powder coating |
-
2016
- 2016-03-03 CN CN201610120118.7A patent/CN105647358A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102382010A (en) * | 2010-09-03 | 2012-03-21 | 袁雪冲 | Preparation process for 4- bromo phenyl hydrazine |
CN104263211A (en) * | 2014-10-17 | 2015-01-07 | 西北永新涂料有限公司 | Special anticorrosive powder coating for high-decorativeness pure polyester aluminum section and preparation method of powder coating |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110317526A (en) * | 2019-06-28 | 2019-10-11 | 广东华江粉末科技有限公司 | A kind of high resistance to infiltration powdery paints and preparation method thereof |
CN110317526B (en) * | 2019-06-28 | 2021-08-03 | 广东华江粉末科技有限公司 | High-water-seepage-resistance powder coating and preparation method thereof |
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