Summary of the invention
Technical problem to be solved by this invention is to provide a kind of preparation method of heat storing and heat preserving worsted fabric, and the worsted fabric that obtains of preparation method is in illumination thus, especially under sunlight, can reach better accumulation of heat, heat insulation effect.
For solving the problems of the technologies described above, the invention provides a kind of preparation method of heat storing and heat preserving worsted fabric, comprising: the preparation process of bar dye heat storing and heat preserving worsted fabric or piece dyeing heat storing and heat preserving worsted fabric;
Wherein, the preparation process of bar dye heat storing and heat preserving worsted fabric comprises: raw material selection → bar dye → recombing → spin → weave → mending → dressing → dry finishing;
The preparation process of piece dyeing heat storing and heat preserving worsted fabric comprises: raw material selection → recombing → spin → weave → mending → dressing → piece dyeing → dry finishing.
(1), when described bar dye ribbon or piece dyeing piece dyeing finishing, Selective absorber sunshine, especially preferably absorbs the near infrared ray in sunshine, and the dyeing containing metal ion, to increase the heat storage capacity of fabric.
A. for animal fibers such as wool, cashmere, spun silk, tussah silk, camel's hair, the rabbit hairs, and/or polyamide fibre form ribbon or grey cloth, adopt mordant dyes and/or premetallized dye dyeing.
Described mordant dyes comprise: the Mordant Black PV of the Mordant Black WPN of Japanese Yamada Co., Ltd., DS Si Da Co., Ltd, the dark blue RRN of medium, the grey BS of Wujiang, Jiangsu Huifeng Dye Co., Ltd, float blue B, red S-80, brown RH.
Described premetallized dye comprises: the orchid of Hensel graceful weaving Ran Hua Co., Ltd receives free and easy black B, dark blue R, grey G, the red B of sauce, red 2B, red G, brown G-01, yellow 2R, Hensel graceful weaving Ran Hua Co., Ltd should and the black P of logical sequence, dark blue P, blue P, red P, orange P etc., DS Si Da Co., Ltd according to the black 2S-RLN in Soren, grey S-GL, dark blue 2S-GL01, green S-GLN, army blue S-RL, brown S-RL, red S-RL, orange S-RL01.
B. the ribbon formed for chemical fibre or grey cloth, selecting to adopt relatively can the disperse dyeing of absorption near infrared ray.
Described chemical fibre comprises: the TWINAIR doughnut of absorption ultrared sunlight heat storing and heat preserving fiber UE-10, the Thermolite of du pont company of terylene, modified dacron, sorona, PTT, T400, CM80, acetate, Japanese You Nijika company, Japanese Asahi Kasei Corporation, the hollow terylene of Shanghai Defulun Chemical Fiber Co., Ltd., the hollow far IR fibre of terylene wool top Co., Ltd of Rongchang County of Zhangjagang City.
Described DISPERSE DYES comprises: the large ENIX of DS Si Da Co., Ltd disperses black SE-R, dark blue SE-R, emerald green blue S-GL, blue E-4R, red SE-GFL, yellow SE-5R.
Adopt above mordant dyes and/or premetallized dye, and relatively can the disperse dyeing of absorption near infrared ray, when illumination, especially under sunlight, infrared ray, especially near infrared ray can be absorbed, to generate heat accumulation of heat to make fabric.
(2) further, the animal fiber such as described wool, cashmere, spun silk, tussah silk, camel's hair, the rabbit hair, and/or when the ribbon that forms of polyamide fibre or grey cloth adopt mordant dyes dyeing, the consumption of mordant arsenic is the 1.5-3.0% of ribbon or grey cloth weight.After adding red sail, except the mordant dyeing effect of mordant dyes own, fabric under light illumination, can absorb infrared ray more, and the metal chromium ions warm-up movement increase under light illumination in arsenic, thus fabric heating accumulation of heat.
(3) for animal fibers such as wool, cashmere, spun silk, tussah silk, camel's hair, the rabbit hairs, and/or polyamide fibre form ribbon or grey cloth, when adopting mordant dyes and/or premetallized dye dyeing, and/or adding the IR absorbing dye GREENPLUSA1 of Japanese hillside plot chemical industry Co., Ltd., consumption is the 0-4% of ribbon or grey cloth weight.The colouring method adding GREENPLUSA1 comprises: first ribbon or grey cloth are put into dye vat, 30-40 DEG C is warmed up to after adding water, add dyeing assistant again, operate and add GREENPLUSA1 after 10 minutes, medium and/or premetallized dye is added after rerunning 10 minutes, rerun after 10 minutes and heat up, by mordant dyes and/or the dyeing of premetallized dye dyeing.After adding IR absorbing dye, fabric can be made better to absorb infrared ray, thus fabric heating accumulation of heat.
(4), when the ribbon that forms of described chemical fibre or grey cloth adopt disperse dyeing, add the infrared absorbent KPDeeperNR of Nippon Kayaku K. K, consumption is the 0.5-4% of ribbon or grey cloth weight.The colouring method adding KPDeeperNR comprises: first ribbon or grey cloth are put into dye vat, 40-50 DEG C is warmed up to after adding water, add dyeing assistant again, operate adding assistant KPDeeperNR after 10 minutes, rerun after within 10 minutes, being warming up to 50-80 DEG C and add DISPERSE DYES, dye by disperse dyeing process.After adding infrared absorbent, fabric can be made better to absorb infrared ray, thus fabric heating accumulation of heat.
(5) described ribbon or grey cloth adopt and/or thermal storage fiber and/or former black fibre.Described former black fibre comprises: former black terylene, former black sorona, former black T400, former black
Hollow polyester, former black hollow Far Infrared Polyester Fiber etc.
Described thermal storage fiber comprises: the ultrared sunlight accumulation of heat of absorption of Japanese You Nijika company
Insulation fibre UE-10, the near-infrared absorbing fiber Thermocatch of Mitsubishi artificial silk company; Described former black fibre adopts known former black terylene, former black sorona, former black T400, former black hollow polyester, former black hollow Far Infrared Polyester Fiber etc.; The consumption of described thermal storage fiber and/or former black fibre is the 0-80% of ribbon or grey cloth weight; Thermal storage fiber and/or former black fibre are mixed into when recombing or when spinning.
Described former black fibre, and/or adopt the infrared absorbent KPDeeperNR process adding Nippon Kayaku K. K, the consumption of KPDeeperNR is the 0-4% of former black fibre weight.The method of process is: first ribbon or grey cloth are put into dye vat, be warmed up to 40-50 DEG C after adding water, then add dyeing assistant, operate adding assistant KPDeeperNR after 10 minutes, operates and be warming up to 130 DEG C in 10 minutes, discharges hot water after being then incubated 20-60min, to go forward side by side water for cooling, finally go out cylinder.
Adopt thermal storage fiber, as the absorption ultrared sunlight heat storing and heat preserving fiber UE-10 of Japanese You Nijika company, wherein containing zirconium carbide, it under light illumination can absorption near infrared ray, make fabric heat absorption and heat storage, can thermal radiation of body be reflected again simultaneously, there is good heat insulation function; As the near-infrared absorbing fiber Thermocatch fiber of Mitsubishi artificial silk company, the compound containing tin oxide and antimony oxide, it can absorption near infrared ray, is fabric heat absorption heating.Adopt former black fibre, containing carbon in its fiber manufacturing process, its heating of absorbing heat under light illumination.
(6) described ribbon or grey cloth adopt and/or thermal fiber, adopt thermal fiber that fabric can be made to be incubated.
Described thermal fiber comprises: the Thermolite of du pont company, the TWINAIR doughnut of Asahi Kasei Corporation of Japan, Shanghai Defulun Chemical Fiber Co., Ltd. is hollow terylene, the hollow far IR fibre of terylene wool top Co., Ltd of Rongchang County of Zhangjagang City, the consumption of described thermal fiber is the 0-80% of ribbon or grey cloth weight, and thermal fiber can be mixed into when recombing or when spinning.
(7) described ribbon or grey cloth adopt and/or far IR fibre and/or hollow far IR fibre.Adopt far IR fibre or hollow far IR fibre, fabric can be made emitting far-infrared.Far-infrared engergy infiltration human body, promotes microvascular expansion and blood circulation, increases body temperature.And hollow far IR fibre can also be incubated.
Described far IR fibre comprises: the hollow far IR fibre of terylene wool top Co., Ltd of Rongchang County of Zhangjagang City, the consumption of described far IR fibre, hollow far IR fibre is the 0-80% of ribbon or grey cloth weight, and far IR fibre, hollow far IR fibre can be mixed into when recombing or when spinning.
Doughnut is a kind of important profiled filament that cross section has cavity vertically, and hollow structure imparts the characteristics such as the good warmth retention property of fiber, bulkiness.Hollow far IR fibre is after the dyestuff process containing metal ion, metal biosorption quantity is relative to non-hollow fiber, increase 50-80%, be lifted at the endothermic effect (relative to the fabric adopting non-hollow fiber and same production technology of the present invention to produce, the fabric endothermic effect adopting doughnut to be worth promotes 20-30%) under illumination condition further.Due to doughnut, there is the characteristics such as better warmth retention property, bulkiness further, the warmth retention property of fabric and comfortableness are significantly improved.In this patent, after fabric heat absorption, doughnut more can serve the effect of heat storing and heat preserving.
(8) grey cloth after described dressing or after piece dyeing, and/or adopt auxiliary agent infrared ray to absorption, or hotness auxiliary agent, or moisture absorption heating auxiliary agent carries out heat absorption heat preserving finishing, and its processing method is that two leachings two are rolled.
The described auxiliary agent having an absorption to infrared ray can be the accumulation of heat processing aid SUNWARMERTOP of Japanese Daiwa Chemical Ind Co., Ltd., consumption is 0-100g/l, crosslinking aid S-200L, consumption is 0-50g/l, the bleeding agent 650 of Hensel graceful weaving Ran Hua Co., Ltd, consumption is 0-2g/l, pick-up rate 60-100%, bake out temperature 100-130 DEG C, drying time 60-120 second, baking temperature 150-170 DEG C, bakes time 60-120 second; Or adopting the infrared absorbent KPDeeperNR of Nippon Kayaku K. K, consumption is 0-80g/l, crosslinking agent NS, consumption is 0-50g/l, pick-up rate 60-100%, bake out temperature 90-120 DEG C, drying time 60-120 second, baking temperature 170-190 DEG C, bakes time 60-120 second.
Described hotness auxiliary agent can be the hotness auxiliary agent HOT2 of Tuo Na chemical company, and consumption is 0-60g/l, pick-up rate 60-100%, dries temperature 80-130 DEG C, dries time 60-180 second.
Described moisture absorption heating auxiliary agent can be the moisture absorption heating agent AH-30 of Qingdao great Yuan Chemical Co., Ltd., consumption is 0-150g/l, moisture absorption heating also uses bridging agent AQH, consumption is 0-20g/l, pick-up rate 60-100%, bake out temperature 100-130 DEG C, drying time 1-2 minute, baking temperature 150-170 DEG C, bakes time 60-120 second.
Technique effect of the present invention: the preparation method of heat storing and heat preserving worsted fabric of the present invention, compared with the production method of common worsted fabric, when its worsted fabric produced is ribbon or piece dyeing finishing, select to adopt sunshine, especially the near infrared ray in sunshine is had to the dyeing of the dye well metal ion of very large absorptivity; When adopting mordant dyes dyeing, the consumption of mordant arsenic is 1.5-3.0%; When adopting the dyeing of mordant dyes, premetallized dye, and/or add IR absorbing dye, when adopting disperse dyeing, add infrared absorbent, increase the extinction heating of fabric.Simultaneously, maybe thermal storage fiber can also be adopted, former black terylene, former black sorona, former black T400, former black hollow polyester, former black hollow Far Infrared Polyester Fiber etc. increase the extinction heating of fiber, or can also further adopt infrared absorbent process when using former black terylene, former black sorona, former black T400 etc., to increase the extinction heating of fiber, maybe thermal fiber can also be adopted, fabric is incubated, especially there is the effect of insulation after heat absorption, maybe can also adopt far IR fibre or hollow far IR fibre, promote blood circulation of human body, human body generates heat.Maybe can also pad when Final finishing grey cloth and to infrared ray, there is the auxiliary agent of absorption or hotness auxiliary agent or moisture absorption heating auxiliary agent and carry out heat absorption heat preserving finishing.Thus obtained heat storing and heat preserving worsted fabric generates heat under light illumination, especially under sunlight, temperature height 2-8 DEG C under identical illumination condition, compared with the fabric of prior art, and (heat insulation effect promotes 10-30% than compared with the fabric of prior art), reflecting far-infrared ray can be incubated, promote blood circulation of human body etc.
Embodiment 1
In the present embodiment, the preparation method of heat absorption insulation worsted fabric adopts bar dyeing technique, and the raw material of bar dye ribbon is chosen as wool, terylene, sorona;
For the selection of dyestuff, the Mordant Black WPN of Yamada Co., Ltd. of wool animal fiber strip adoption Japan, the Mordant Black PV of DS Si Da Co., Ltd, the dark blue RRN of medium, the grey BS of Wujiang, Jiangsu Huifeng Dye Co., Ltd, floats blue B, red S-80, one or more in brown RH; The large ENIX of terylene, sorona chemical fibre strip adoption DS Si Da Co., Ltd disperse in black SE-R, dark blue SE-R, emerald green blue S-GL, blue E-4R, red SE-GFL, yellow SE-5R one or more; The consumption of dyestuff uses different component according to the depth of color.
During the dyeing of wool animal fiber bar, add mordant arsenic, consumption is 3% of fibre weight to be dyed, and add the IR absorbing dye GREENPLUSA1 of Japanese hillside plot chemical industry Co., Ltd., consumption is 3% of fibre weight to be dyed.The colouring method adding GREENPLUSA1 comprises: first ribbon is put into dye vat, 30-40 DEG C is warmed up to after adding water, add dyeing assistant again, operate and add GREENPLUSA1 after 10 minutes, mordant dyes are added after rerunning 10 minutes, rerun after 10 minutes and heat up, by mordant dyes dyeing and the dyeing adding arsenic.
During the dyeing of terylene, sorona chemical fibre bar, add the infrared absorbent KPDeeperNR of Nippon Kayaku K. K, consumption is 2% of ribbon weight; The colouring method adding KPDeeperNR is: first ribbon or grey cloth are put into dye vat, be warmed up to 50 DEG C after adding water, then add dyeing assistant, operate adding assistant KPDeeperNR after 10 minutes, rerun after within 10 minutes, being warming up to 80 DEG C and add DISPERSE DYES, dye by disperse dyeing process.Above-mentioned dyeing assistant is known technology.Above-mentioned disperse dyeing process is known technology.
After dressing, adopt the auxiliary agent to infrared ray has an absorption to carry out heat absorption heat preserving finishing, processing method is that two leachings two are rolled; The described auxiliary agent having an absorption to infrared ray is the accumulation of heat processing aid SUNWARMERTOP of Japanese Daiwa Chemical Ind Co., Ltd., consumption is 100g/l, crosslinking aid S-200L, consumption is 50g/l, the bleeding agent 650 of Hensel graceful weaving Ran Hua Co., Ltd, consumption is 2g/l, pick-up rate 60%, bake out temperature 100 DEG C, drying time 80 seconds, baking temperature 160 DEG C, bakes 80 seconds time.
Embodiment 3
In the present embodiment, the preparation method of heat absorption insulation worsted fabric adopts bar dyeing technique, and its Raw is chosen as the hollow terylene of wool, spun silk, modified dacron, Shanghai Defulun Chemical Fiber Co., Ltd..
For the selection of dyestuff, the orchid of wool, silk flock strip adoption Hensel graceful weaving Ran Hua Co., Ltd receives free and easy black B, dark blue R, grey G, the red B of sauce, red 2B, red G, brown G-01, yellow 2R, Hensel graceful weaving Ran Hua Co., Ltd should and the black P of logical sequence, dark blue P, blue P, red P, orange P etc., DS Si Da Co., Ltd according to one or more in the black 2S-RLN in Soren, grey S-GL, dark blue 2S-GL01, green S-GLN, army blue S-RL, brown S-RL, red S-RL, orange S-RL01; The hollow terylene of modified dacron, Shanghai Defulun Chemical Fiber Co., Ltd. adopt the large ENIX of DS Si Da Co., Ltd to disperse in black SE-R, dark blue SE-R, emerald green blue S-GL, blue E-4R, red SE-GFL, yellow SE-5R one or more; The consumption of dyestuff uses different component according to the depth of color.
During the dyeing of wool, silk flock bar, add the IR absorbing dye GREENPLUSA1 of Japanese hillside plot chemical industry Co., Ltd., consumption is 2% of fibre weight to be dyed.The colouring method adding GREENPLUSA1 comprises: first ribbon is put into dye vat, 30-40 DEG C is warmed up to after adding water, add dyeing assistant again, operate and add GREENPLUSA1 after 10 minutes, mordant dyes are added after rerunning 10 minutes, rerun after 10 minutes and heat up, by mordant dyes dyeing and the dyeing adding arsenic.
When the hollow terylene of modified dacron, Shanghai Defulun Chemical Fiber Co., Ltd. dyes, add the infrared absorbent KPDeeperNR of Nippon Kayaku K. K, consumption is 4% of ribbon weight; The colouring method adding KPDeeperNR comprises: first ribbon or grey cloth are put into dye vat, be warmed up to 50 DEG C after adding water, then add dyeing assistant, operate adding assistant KPDeeperNR after 10 minutes, rerun after within 10 minutes, being warming up to 80 DEG C and add DISPERSE DYES, dye by disperse dyeing process.Above-mentioned dyeing assistant is known technology.Above-mentioned disperse dyeing process is known technology.
The hollow terylene consumption of Shanghai Defulun Chemical Fiber Co., Ltd. is 30% of ribbon weight, is mixed into when recombing.
After dressing, adopt moisture absorption heating auxiliary agent to carry out heat absorption heat preserving finishing, processing method is that two leachings two are rolled; Described moisture absorption heating auxiliary agent is the moisture absorption heating agent AH-30 of Qingdao great Yuan Chemical Co., Ltd., and consumption is 150g/l, and moisture absorption heating also uses bridging agent AQH, consumption is 20g/l, pick-up rate 60%, bake out temperature 130 DEG C, drying time 1 minute, baking temperature 170 DEG C, bakes 90 seconds time.