The content of the invention
The technical problems to be solved by the invention are to provide a kind of preparation method of heat storing and heat preserving worsted fabric, thus prepare
Worsted fabric made from method especially under sunshine irradiation, can reach more preferable accumulation of heat, heat insulation effect in illumination.
In order to solve the above technical problems, the invention provides a kind of preparation method of heat storing and heat preserving worsted fabric, including:Bar
Contaminate the preparation process of heat storing and heat preserving worsted fabric or piece dyeing heat storing and heat preserving worsted fabric;
Wherein, the preparation process of bar dye heat storing and heat preserving worsted fabric includes:Raw material selection → bar dye → recombing → spinning
→ weaving → mending → dressing → dry finishing;
The preparation process of piece dyeing heat storing and heat preserving worsted fabric includes:Raw material selection → recombing → spinning → weaving → mending
→ dressing → piece dyeing → dry finishing.
(1)When the bar dye ribbon or piece dyeing piece dyeing finishing, selection absorbs sunshine, especially preferred to absorb sunshine
In near infrared ray, and the dyeing containing metal ion, to increase the heat storage capacity of fabric.
A. for the animal origins such as wool, cashmere, spun silk, tussah silk, camel's hair, the rabbit hair, and/or the ribbon that polyamide fibre is formed
Or fabric, dyed using mordant dyes, and/or premetallized dye.
The mordant dyes include:The Mordant Black of Mordant Black WPN, the DS Si Da Co., Ltds of Japanese Yamada Co., Ltd.
PV, the dark blue RRN of medium, grey BS, the blue B of drift, the red S-80, brown RH of Jiangsu Wujiang Huifeng Dye Co., Ltd.
The premetallized dye includes:The orchid of the graceful weaving Ran Hua Co., Ltds of Hensel receives free and easy black B, dark blue R, grey G, sauce
Red B, red 2B, red G, brown G-01, yellow 2R, P preferably black with logical sequence, dark blue P, blue P, red P, the orange P of the graceful weaving Ran Hua Co., Ltds of Hensel
Deng, DS Si Da Co., Ltds according to the black 2S-RLN in Soren, grey S-GL, dark blue 2S-GL01, green S-GLN, army orchid S-RL, brown S-RL,
Red S-RL, orange S-RL01.
B. for chemical fibre form ribbon or fabric, selection using relatively can absorption near infrared ray scattered dye
Material dyeing.
The chemical fibre includes:Terylene, modified dacron, sorona, PTT, T400, CM80, polyacetates, the outstanding Buddhist nun of Japan
Sunlight heat storing and heat preserving fiber UE-10, the Thermolite of du pont company, the Japanese rising sun of the absorption infrared ray of Ji Ka companies
It is flourish into the TWINAIR doughnuts of Co., Ltd., the hollow terylene of Shanghai Defulun Chemical Fiber Co., Ltd., Zhangjagang City
The hollow far IR fibre of prosperous terylene wool top Co., Ltd.
The disperse dyes include:The big ENIX of DS Si Da Co., Ltds disperses black SE-R, dark blue SE-R, emerald green blue S-
GL, blue E-4R, red SE-GFL, yellow SE-5R.
Using above mordant dyes, and/or premetallized dye, and relatively can absorption near infrared ray disperse dyes dye
Color, especially under sunshine irradiation, infrared ray, especially near infrared ray can be absorbed, the accumulation of heat so that fabric generates heat in illumination.
(2)Further, the animal origin such as the wool, cashmere, spun silk, tussah silk, camel's hair, rabbit hair, and/or polyamide fibre are formed
Ribbon or fabric when being dyed using mordant dyes, the dosage of mordant arsenic is ribbon or the 1.5- of fabric weight
3.0%.After adding red sail, in addition to the mordant dyeing effect of mordant dyes itself, fabric under light illumination, can more absorb infrared ray, and
And the warm-up movement increase under light illumination of the metal chromium ions in arsenic, so as to fabric heating accumulation of heat.
(3)For the animal origins such as wool, cashmere, spun silk, tussah silk, camel's hair, the rabbit hair, and/or the fiber that polyamide fibre is formed
Bar or fabric, when being dyed using mordant dyes, and/or premetallized dye, and/or add Japanese hillside plot chemical industry strain formula meeting
The IR absorbing dye GREENPLUS A1 of society, dosage are ribbon or the 0-4% of fabric weight.Add GREENPLUS A1
Colouring method include:Ribbon or fabric are first put into dye vat, 30-40 DEG C is warming up to after adding water, adds dyeing assistant, is transported
Add GREENPLUS A1 after turning 10 minutes, medium, and/or premetallized dye are added after rerunning 10 minutes, is rerunned 10 minutes
After heat up, dyed by mordant dyes, and/or premetallized dye dyeing., can be preferably after adding IR absorbing dye
Fabric is set to absorb infrared ray, so as to fabric heating accumulation of heat.
(4)When the ribbon or fabric that the chemical fibre is formed use disperse dyeing, Japanese chemical drug strain formula is added
The infrared absorbent KP Deeper NR of commercial firm, dosage are ribbon or the 0.5-4% of fabric weight.Add KP Deeper
NR colouring method includes:Ribbon or fabric are first put into dye vat, 40-50 DEG C is warming up to after adding water, adds dyeing assistant,
Adding assistant KP Deeper NR after operating 10 minutes, rerun 10 minutes and add disperse dyes after being warming up to 50-80 DEG C, by scattered
Dyeing dyeing.After adding infrared absorbent, fabric can be preferably set to absorb infrared ray, so as to which fabric heating stores
Heat.
(5)The ribbon or fabric use and/or thermal storage fiber, and/or former black fibre.The former black fibre includes:
Former black terylene, former black sorona, former black T400, original are black
Hollow polyester, former black hollow Far Infrared Polyester Fiber etc..
The thermal storage fiber includes:The sunlight accumulation of heat of the absorption infrared ray of Japanese You Nijika companies
Insulation fibre UE-10, the near-infrared absorbing fiber Ther mocatch of Mitsubishi artificial silk company;The original
Former black terylene, former black sorona, former black T400, former black hollow polyester, the black hollow Far Infrared Polyester Fiber of original known to black fibre use
Deng;The thermal storage fiber, and/or the dosage of former black fibre are ribbon or the 0-80% of fabric weight;Thermal storage fiber, and/or original
Black fibre is mixed into recombing or when spinning.
The former black fibre, and/or using at the infrared absorbent KP Deeper NR for adding Nippon Kayaku K. K
Reason, KP Deeper NR dosage are the 0-4% of former black fibre weight.The method of processing is:Ribbon or fabric are first put into dye
Cylinder, 40-50 DEG C is warming up to after adding water, adds dyeing assistant, adding assistant KP Deeper NR after operating 10 minutes, operate 10 points
Clock is warming up to 130 DEG C, is then incubated 20-60min heel row and puts hot water, and cooling of intaking, and finally goes out cylinder.
Using thermal storage fiber, the sunlight heat storing and heat preserving fiber UE-10 of the absorption infrared ray of such as Japanese You Nijika companies, its
In contain zirconium carbide, its under light illumination can absorption near infrared ray, make fabric heat absorption and heat storage, while and can reflection Studies of Human Body Heat spoke
Penetrate, there is good heat insulation function;Such as the near-infrared absorbing fiber Thermocatch fibers of Mitsubishi artificial silk company,
Compound containing tin oxide and antimony oxide, its energy absorption near infrared ray, it is fabric heat absorption heating.Using former black fibre, it is fine
Contain carbon in dimension preparation process, its heating of absorbing heat under light illumination.
(6)The ribbon or fabric use and/or thermal fiber, can be incubated fabric using thermal fiber.
The thermal fiber includes:The Thermolite of du pont company, the TWINAIR of Japanese Asahi Kasei Corporation
Doughnut, Shanghai Defulun Chemical Fiber Co., Ltd. are hollow terylenes, terylene wool top Co., Ltd of Rongchang County of Zhangjagang City
Hollow far IR fibre, the dosage of the thermal fiber is ribbon or the 0-80% of fabric weight, and thermal fiber can be multiple
It is mixed into during combing or when spinning.
(7)The ribbon or fabric use and/or far IR fibre, and/or hollow far IR fibre.Using far infrared
Fiber or hollow far IR fibre, fabric can be made emitting far-infrared.Far-infrared engergy permeates human body, promotes the expansion of capilary
And blood circulation, increase body temperature.And hollow far IR fibre can also be incubated.
The far IR fibre includes:The hollow far IR fibre of terylene wool top Co., Ltd of Rongchang County of Zhangjagang City, it is described
Far IR fibre, hollow far IR fibre dosage for ribbon or fabric weight 0-80%, it is far IR fibre, hollow remote red
Outer fiber can be mixed into recombing or when spinning.
Doughnut is a kind of important profiled filament that cross section has cavity vertically, and hollow structure imparts fiber
The characteristics such as good warmth retention property, bulkiness.Hollow far IR fibre through containing metal ion dyestuff processing after, metal ion
Quantity is adsorbed relative to non-hollow fiber, increases 50-80%, the endothermic effect being further lifted under illumination condition(Relative to adopting
The fabric produced with the same production technology of non-hollow fiber and the present invention, the fabric being worth using doughnut, which is absorbed heat, imitates
Fruit lifts 20-30%).There is the characteristics such as more preferable warmth retention property, bulkiness further as doughnut so that fabric it is warming
Property and comfortableness greatly improve.In this patent, after fabric heat absorption, doughnut can more serve the effect of heat storing and heat preserving.
(8)Fabric after the dressing or after piece dyeing, and/or using the auxiliary agent to infrared ray with absorption, or
Thermal sensation auxiliary agent, or moisture absorption heating auxiliary agent carry out heat absorption heat preserving finishing, and its processing method is that two leachings two are rolled.
The auxiliary agent to infrared ray with absorption can add for the accumulation of heat of Japanese Daiwa Chemical Ind Co., Ltd.
Work auxiliary agent SUNWARMER TOP, dosage 0-100g/l, crosslinking aid S -200L, dosage 0-50g/l, the graceful weaving dyeization of Hensel
The bleeding agent 650 of Co., Ltd, dosage 0-2g/l, pick-up rate 60-100%, 100-130 DEG C of drying temperature, drying time 60-
120 seconds, 150-170 DEG C of baking temperature, bake second time 60-120;Or the infrared absorbent using Nippon Kayaku K. K
KP Deeper NR, dosage 0-80g/l, crosslinking agent NS, dosage 0-50g/l, pick-up rate 60-100%, drying temperature 90-
120 DEG C, the drying time 60-120 seconds, 170-190 DEG C of baking temperature, bake second time 60-120.
The thermal sensation auxiliary agent can be thermal sensation the auxiliary agent HOT2, dosage 0-60g/l, pick-up rate 60- of Tuo Na chemical companies
100%, 80-130 DEG C of temperature is dried, dries second time 60-180.
The moisture absorption heating auxiliary agent can be moisture absorption heating the agent AH-30, dosage 0- of Qingdao great Yuan Chemical Co., Ltd.s
150g/l, moisture absorption heating and with bridging agent AQH, dosage 0-20g/l, pick-up rate 60-100%, drying temperature 100-130
DEG C, drying time 1-2 minutes, 150-170 DEG C of baking temperature, bake second time 60-120.
The technique effect of the present invention:The preparation method of the heat storing and heat preserving worsted fabric of the present invention, with common worsted fabric
Production method compare, worsted fabric that it is produced is when being to ribbon or piece dyeing finishing, and selection is using to sunshine, especially
It is the dyeing for the dyestuff and metal ion that there is very big absorptivity to the near infrared ray in sunshine;Using medium
During dyeing, the dosage of mordant arsenic is 1.5-3.0%;During using mordant dyes, premetallized dye dyeing, and/or add
IR absorbing dye, during using disperse dyeing, add infrared absorbent, increase the extinction heating of fabric.Meanwhile or also
Thermal storage fiber, former black terylene, former black sorona, former black T400, former black hollow polyester, former black hollow Far Infrared Polyester Fiber can be used
Deng the extinction heating of increase fiber, or can also further be adopted when using former black terylene, former black sorona, former black T400 etc.
Handled with infrared absorbent, to increase the heating of the extinction of fiber, or thermal fiber can also be used, be incubated fabric, especially
There is the effect of insulation after heat absorption, or far IR fibre or hollow far IR fibre can also be used, promote blood of human body to follow
Ring, human body heating.Or the auxiliary agent or thermal sensation to infrared ray with absorption can also be padded in final finishing to fabric
Auxiliary agent or moisture absorption heating auxiliary agent carry out heat absorption heat preserving finishing.So as to which obtained heat storing and heat preserving worsted fabric generates heat under light illumination,
Especially under sunshine irradiation, under the conditions of same light photograph, temperature is high 2-8 DEG C compared with the fabric of prior art, and can be incubated
(Heat insulation effect compared with the fabric of prior art than lifting 10-30%), reflecting far-infrared ray, promote blood circulation of human body etc..
Embodiment 1
In the present embodiment, the preparation method of heat absorption insulation worsted fabric uses bar dyeing technique, and bar contaminates the raw material of ribbon
Select as wool, terylene, sorona;
Selection for dyestuff, Mordant Black WPN, the DS departments of Yamada Co., Ltd. of wool animal origin strip adoption Japan, which reach, to be had
The Mordant Black PV of limit company, the dark blue RRN of medium, grey BS, the blue B of drift, the red S-80, brown RH of Jiangsu Wujiang Huifeng Dye Co., Ltd
In one or more;Terylene, the big ENIX of sorona chemical fibre strip adoption DS Si Da Co., Ltds disperse black SE-R,
One or more in dark blue SE-R, emerald green blue S-GL, blue E-4R, red SE-GFL, yellow SE-5R;The dosage of dyestuff is according to color
The depth uses different components.
When wool animal origin bar dyes, mordant arsenic is added, dosage is the 3% of fibre weight to be dyed, adds Japan
The IR absorbing dye GREENPLUS A1 of hillside plot chemical industry Co., Ltd., dosage are the 3% of fibre weight to be dyed.Add
Add GREENPLUS A1 colouring method to include:Ribbon is first put into dye vat, 30-40 DEG C is warming up to after adding water, adds dye
Color auxiliary agent, operating add GREENPLUS A1 after 10 minutes, mordant dyes are added after rerunning 10 minutes, are risen after rerunning 10 minutes
Temperature, by mordant dyes dyeing and add arsenic dyeing.
When terylene, the dyeing of sorona chemical fibres bar, the infrared absorbent KP of Nippon Kayaku K. K is added
Deeper NR, dosage are the 2% of ribbon weight;Addition KP Deeper NR colouring method is:First by ribbon or fabric
Dye vat is put into, 50 DEG C are warming up to after adding water, adds dyeing assistant, adding assistant KP Deeper NR after operating 10 minutes, then transport
Turn 10 minutes to add disperse dyes after being warming up to 80 DEG C, dyed by disperse dyeing process.Above-mentioned dyeing assistant is known
Technology.Above-mentioned disperse dyeing process is known technology.
After dressing, heat absorption heat preserving finishing, processing method two are carried out using the auxiliary agent to infrared ray with absorption
Leaching two is rolled;It is described there is absorption to infrared ray auxiliary agent be Japanese Daiwa Chemical Ind Co., Ltd. accumulation of heat processing aid
SUNWARMER TOP, dosage 100g/l, crosslinking aid S -200L, dosage 50g/l, the graceful weaving Ran Hua Co., Ltds of Hensel
Bleeding agent 650, dosage 2g/l, pick-up rate 60%, 100 DEG C of drying temperature, drying time 80 seconds, 160 DEG C of baking temperature, bake
80 seconds time.
Embodiment 3
In the present embodiment, the preparation method of heat absorption insulation worsted fabric use bar dyeing technique, wherein raw material selection be wool,
Spun silk, modified dacron, the hollow terylene of Shanghai Defulun Chemical Fiber Co., Ltd..
Selection for dyestuff, the orchids of the graceful weaving Ran Hua Co., Ltds of wool, silk flock strip adoption Hensel receive free and easy black
B, dark blue R, grey G, sauce red B, red 2B, red G, brown G-01, yellow 2R, it is the P preferably black with logical sequence of the graceful weaving Ran Hua Co., Ltds of Hensel, dark blue
P, blue P, red P, orange P etc., DS Si Da Co., Ltds according to the black 2S-RLN in Soren, grey S-GL, dark blue 2S-GL01, green S-GLN, army
One or more in blue S-RL, brown S-RL, red S-RL, orange S-RL01;Modified dacron, Shanghai Defulun Chemical Fiber Co., Ltd.
Hollow terylene disperses black SE-R, dark blue SE-R, emerald green blue S-GL, blue E- using the big ENIX of DS Si Da Co., Ltds
One or more in 4R, red SE-GFL, yellow SE-5R;The dosage of dyestuff uses different components according to the depth of color.
When wool, the dyeing of silk flock bar, the IR absorbing dye of Japanese hillside plot chemical industry Co., Ltd. is added
GREENPLUS A1, dosage are the 2% of fibre weight to be dyed.Addition GREENPLUS A1 colouring method includes:First by fiber
Bar is put into dye vat, and 30-40 DEG C is warming up to after adding water, adds dyeing assistant, operating adds GREENPLUS A1 after 10 minutes, then transports
Turn 10 minutes after plus mordant dyes, heated up after rerunning 10 minutes, by mordant dyes dyeing and add arsenic dyeing.
When modified dacron, the hollow terylene of Shanghai Defulun Chemical Fiber Co., Ltd. dye, Japanese chemical drug strain formula is added
The infrared absorbent KP Deeper NR of commercial firm, dosage are the 4% of ribbon weight;Add KP Deeper NR dyeing side
Method includes:Ribbon or fabric are first put into dye vat, 50 DEG C are warming up to after adding water, adds dyeing assistant, after operating 10 minutes
Adding assistant KP Deeper NR, rerun 10 minutes and add disperse dyes after being warming up to 80 DEG C, contaminated by disperse dyeing process
Color.Above-mentioned dyeing assistant is known technology.Above-mentioned disperse dyeing process is known technology.
The hollow terylene dosage of Shanghai Defulun Chemical Fiber Co., Ltd. is the 30% of ribbon weight, in recombing
It is mixed into.
After dressing, heat absorption heat preserving finishing is carried out using moisture absorption heating auxiliary agent, processing method is that two leachings two are rolled;The moisture absorption
Generate heat moisture absorption heating agent AH-30 of the auxiliary agent for Qingdao great Yuan Chemical Co., Ltd.s, dosage 150g/l, and moisture absorption heating simultaneously uses frame
Bridge agent AQH, dosage 20g/l, pick-up rate 60%, 130 DEG C of drying temperature, drying time 1 minute, 170 DEG C of baking temperature, is roasted
Dry 90 seconds time.