CN1054966A - Composite for crop root external nutrient spray fertilizer and production process thereof - Google Patents
Composite for crop root external nutrient spray fertilizer and production process thereof Download PDFInfo
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- CN1054966A CN1054966A CN 91101093 CN91101093A CN1054966A CN 1054966 A CN1054966 A CN 1054966A CN 91101093 CN91101093 CN 91101093 CN 91101093 A CN91101093 A CN 91101093A CN 1054966 A CN1054966 A CN 1054966A
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- Prior art keywords
- fertilizer
- compound
- naphthalene
- acid
- potassium
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 37
- 239000007921 spray Substances 0.000 title claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 235000015097 nutrients Nutrition 0.000 title abstract 2
- 239000002131 composite material Substances 0.000 title description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims abstract description 16
- -1 naphthalene compound Chemical class 0.000 claims abstract description 15
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 14
- 235000009566 rice Nutrition 0.000 claims abstract description 14
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 10
- 240000000111 Saccharum officinarum Species 0.000 claims abstract description 10
- 235000007201 Saccharum officinarum Nutrition 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 10
- 239000010452 phosphate Substances 0.000 claims abstract description 10
- 239000005648 plant growth regulator Substances 0.000 claims abstract description 5
- 240000007594 Oryza sativa Species 0.000 claims abstract 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 25
- 241000196324 Embryophyta Species 0.000 claims description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- 239000011591 potassium Substances 0.000 claims description 15
- 229910052700 potassium Inorganic materials 0.000 claims description 15
- PRPINYUDVPFIRX-UHFFFAOYSA-N 1-naphthaleneacetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CC=CC2=C1 PRPINYUDVPFIRX-UHFFFAOYSA-N 0.000 claims description 14
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 11
- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 238000005507 spraying Methods 0.000 claims description 9
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 8
- 239000011575 calcium Substances 0.000 claims description 8
- 229910052791 calcium Inorganic materials 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 7
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
- 229910052796 boron Inorganic materials 0.000 claims description 6
- 239000011777 magnesium Substances 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- 238000005868 electrolysis reaction Methods 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- WZLMXYBCAZZIRQ-UHFFFAOYSA-N [N].[P].[K] Chemical compound [N].[P].[K] WZLMXYBCAZZIRQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 230000003750 conditioning effect Effects 0.000 claims description 3
- 239000008151 electrolyte solution Substances 0.000 claims description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- SDGKUVSVPIIUCF-UHFFFAOYSA-N 2,6-dimethylpiperidine Chemical compound CC1CCCC(C)N1 SDGKUVSVPIIUCF-UHFFFAOYSA-N 0.000 claims description 2
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- 238000004458 analytical method Methods 0.000 claims description 2
- 238000006555 catalytic reaction Methods 0.000 claims description 2
- 238000005660 chlorination reaction Methods 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 230000018044 dehydration Effects 0.000 claims description 2
- 238000006297 dehydration reaction Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- VOLCCIIDZBNHBK-UHFFFAOYSA-N naphthalene;propanoic acid Chemical compound CCC(O)=O.C1=CC=CC2=CC=CC=C21 VOLCCIIDZBNHBK-UHFFFAOYSA-N 0.000 claims description 2
- 239000000243 solution Substances 0.000 claims description 2
- LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical class C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 claims 3
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 229910052729 chemical element Inorganic materials 0.000 claims 1
- 239000012528 membrane Substances 0.000 claims 1
- 150000003016 phosphoric acids Chemical class 0.000 claims 1
- 235000019260 propionic acid Nutrition 0.000 claims 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims 1
- 230000012010 growth Effects 0.000 abstract description 8
- 235000013399 edible fruits Nutrition 0.000 abstract description 6
- 239000011573 trace mineral Substances 0.000 abstract description 6
- 235000013619 trace mineral Nutrition 0.000 abstract description 6
- 238000002360 preparation method Methods 0.000 abstract description 3
- 239000000047 product Substances 0.000 abstract description 3
- 244000241257 Cucumis melo Species 0.000 abstract description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 abstract description 2
- 240000008042 Zea mays Species 0.000 abstract description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 abstract description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 abstract description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 abstract description 2
- 235000005822 corn Nutrition 0.000 abstract description 2
- 239000013067 intermediate product Substances 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 241000209094 Oryza Species 0.000 description 12
- 230000000694 effects Effects 0.000 description 6
- 239000002689 soil Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- RDXARWSSOJYNLI-UHFFFAOYSA-N [P].[K] Chemical compound [P].[K] RDXARWSSOJYNLI-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 238000003306 harvesting Methods 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 230000004060 metabolic process Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 230000035764 nutrition Effects 0.000 description 2
- 235000008935 nutritious Nutrition 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 230000029553 photosynthesis Effects 0.000 description 2
- 238000010672 photosynthesis Methods 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000015320 potassium carbonate Nutrition 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241001530056 Athelia rolfsii Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229930191978 Gibberellin Natural products 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 241001274216 Naso Species 0.000 description 1
- 235000019082 Osmanthus Nutrition 0.000 description 1
- 241000333181 Osmanthus Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 244000046109 Sorghum vulgare var. nervosum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003448 gibberellin Substances 0.000 description 1
- IXORZMNAPKEEDV-OBDJNFEBSA-N gibberellin A3 Chemical class C([C@@]1(O)C(=C)C[C@@]2(C1)[C@H]1C(O)=O)C[C@H]2[C@]2(C=C[C@@H]3O)[C@H]1[C@]3(C)C(=O)O2 IXORZMNAPKEEDV-OBDJNFEBSA-N 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000000618 nitrogen fertilizer Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003375 plant hormone Substances 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000002786 root growth Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 230000007226 seed germination Effects 0.000 description 1
- 230000035040 seed growth Effects 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000004162 soil erosion Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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Abstract
The present invention provides a preparation method of nutrient spray fertilizer for crops outside root and its production process, said spray fertilizer uses phosphate and plant growth regulator naphthalene compound as main raw material, and adds specific trace elements according to different crops and different growth periods to prepare series products, and the whole production process is integrated, and fully utilizes intermediate product, and can save time and energy source, and the yield of the prepared sugarcane spray fertilizer can be increased by 20%, sugar content of sugarcane can be raised by 1%, and the yield of seedling growth-promoting agent and crop spray fertilizer can be increased by 10-30% after it is applied to crops of rice, corn and melon and fruit, etc..
Description
The present invention relates to the composition and the production technique of farm crop series spray-applied root fertilizer material.
It serves as that the main cooperation of having both various trace elements is well-known with nitrogen phosphorus potassium that farm crop are applied fertilizer, but importantly should use different fertilizer according to different crops and different times, to regulate the process of growth of crop better, reach the purpose that increases output, this respect Agricultural Scientist for many years all is devoted to research.But in vast rural area, because a variety of causes peasant can't scientifically use fertilizer, it is main getting used to nitrogen fertilizer application for a long time, phosphorus potash fertilizer is seldom used, trace element let alone, owing to execute nitrogen for a long time, soda acid in the soil is out of proportion, the soil property sex change, and crop is poor year by year.For changing this situation, various places have produced various compound fertilizer in recent years, obtained certain effect, but because compound fertilizer all forms so that machinery is mixed, and all be to impose in the soil, will cause like this and absorb complete or soil erosion slatterns because of root, in order to promote plant growth, people develop each plant growth regulators and compound fertilizer for spraying on leaf surface, regulate the physiological and biochemical procedure of plant on the one hand, increase the nutritious fertilizer of Foliage Absorption on the other hand, these conditioning agents and foliage fertilizer are common Plant hormones regulators,gibberellins, benzazolyl compounds, choline dichloride, naphthalene compound, the blade face treasured, spray treasured, multielement micro-fertilizer etc., but some is simple hormone, only work to increase cell, what have is only effective to yearly plant, to suppressing growth in 1 year after the perennial plant spray, that have even can change plant quality, being added with some micro-leaf fertilizer, often to contain the crop essential element again too low, so effect of increasing production is remarkable not enough, and because chemical transformation mix to take place, yet there are no the document record and use the serial spray that plant-growth regulator and composite fertilizer are cooperated according to different plants and different growth periods.
The objective of the invention is to be the plant-growth regulator that some are suitable and nitrogen phosphorus potassium and trace element combine the serial root outer spraying fertilizer of farm crop efficiently, make crop when fully regulating physiological and biochemical procedure, also can pass through the competent basic nutrition of Foliage Absorption, promote well developed root system, increase and tiller, improve the rate of blossoming and bearing fruit.
In order to reach this purpose, the inventor has passed through screening and simultaneous test, according to the data that many reference and agricultural sector provide, potassium primary phosphate is fertile as the basis, and naphthalene compound and choline dichloride are as the auxiliary adjustment agent, add an amount of trace element according to different crops and growth period again, make series and spray nutrition fertilizer, design production technique, form the production process of integration by such proportioning, intermediates and byproduct are fully used, do not produce three-waste pollution.
Selecting potassium primary phosphate is situation according to China's soil chemistry composition as the fertile reason in basis, in 1,500,000,000 mu of arable lands, the whole nation, 1,000,000,000 mu of scarce phosphorus potassium are arranged, wherein 500,000,000 mu seriously lack the phosphorus potassium, generally all below 10PPM, so the present invention has selected to increase the raw material of rapid available phosphorus and potassium, and the plant in this part soil is used targetedly.
Naphthalene compound is easy manufacturing, stable in properties, the plant-growth of wide adaptability is adjusted, it can strengthen metabolism and the photosynthesis of plant, improve resistance, stimulating growth, promote well developed root system, promotion is bloomed, result and promotion precocity and volume increase etc., naphthalene compound generally has naphthylacetic acid, the naphthalene propionic acid, Chlorlacetic Acid etc., generally commonly used is naphthylacetic acid, but naphthylacetic acid only is dissolved in organic solvent, water insoluble, have only naphthylacetic acid salt water-soluble, domestic producer only produces naphthylacetic acid again at present, after buying back, the peasant also to purchase organic solvent dissolution in addition, use very inconvenient, so the present invention is then mainly with the potassium of naphthylacetic acid, the embodiment of sodium salt is main, can certainly be with other naphthalene compound.The ratio of potassium primary phosphate and naphthalene compound is 100: 1～10 more suitable, and too many cost can increase.
The production that existing textbook is described potassium primary phosphate in detail is to add salt of wormwood or potassium hydroxide makes by phosphoric acid, the present invention has adopted phosphoric acid hydro-oxidation potassium method, potassium hydroxide is to obtain by electrolysis KCl, and phosphoric acid is obtained by thermal phosphoric acid, and the KOH that electrolysis is come out adds H by the same-size ratio of chemical equation
3PO
4, reaction obtains KH
2PO
4,, promptly obtain containing KH through cold analysis, dehydration, drying
2PO
4Product more than 98%, the chlorine that electrolytic process produces then feeds acetic acid solution catalysis and makes Monochloro Acetic Acid, add naphthalene then and become naphthylacetic acid, the KOH that comes out with electrolysis or add the NaOH reaction in addition and make water-soluble naphthylacetic acid k-na salt again, also available similar method is produced naphthalene potassium propionate, Carpamone or naphthalene monocarboxylic acid class salt, with this compound and KH
2PO
4Be mixed together and add the chemical combination potassium that contains elements such as boron, manganese, calcium, iron respectively and can pack by class.In addition, the crop that has needs the nitrogen element more, is producing KH
2PO
4The time, with a part of H
3PO
4Add again in the KOH electrolytic solution with the ammoniacal liquor reaction, promptly obtain KH
2PO
4And NH
4H
2PO
4Mixture.
Detailed process flow of the present invention is referring to Figure of description.
Wherein electrolysis KCl adopts traditional diaphragm process, and the KOH electrolytic solution that draws is divided into two partly, and a part is directly produced pure KH
2PO
4, another part adds ammoniacal liquor and H
3PO
4Make KH
2PO
4And NH
4H
2PO
4Mixture, at last add conditioning agent and trace element and make series and spray fertilizer according to different needs.The salifiable process of naphthylacetic acid system can with KOH or NaOH neutralization reaction, also can with NaCO
3, NaSO
4React Deng sodium salt.
Below be the preparation serial nutritious fertile several embodiment that spray of the present invention:
One, the composition composition (gram) of the short long agent of rice shoot (being applicable to crops such as paddy rice, wheat, cotton):
KH
2PO
4：200
Naphthylacetic acid potassium: 1-6
Choline dichloride: 1-3
MnSO
4(or Mn(NO
3)
2): 5-10
ZnSO
4：3-5
Choline dichloride mainly contains CCC(2-chloroethyl trimethyl ammonium chloride) 2-4D, 2-Chloroallyl trimethyl ammonium chloride and chlorination lupetidin etc. are several, and their main effect is to increase plant tillering, make the cane chap, promotes root growth, prevents lodging.
The compound of manganese and zinc mainly is to promote seed germination and growth of seedling, accelerates photosynthesis and the metabolism of crop, also can prevent and treat some Plant diseasess, as leukodermia, banded sclerotial blight etc.
The short long agent of Pei Zhi rice shoot according to said method can cultivate that the thick leaf of stem is green, root is many, drought-enduring, cold-resistant rice shoot, and rice seedling is inserted down the back and turned green soon than general control group, tillers morning, and output increases more than 10%.
Two, general crop spray is applicable to melon, beans, vegetables, fruit trees etc., and its composition is (gram):
KH
2PO
4：200
NH
4H
2PO
4：180
Nafusaku: 2-10
Sodium tetraborate: 2-6
CaSO
4Or CaO:5-10
FeSO
4：3-5
Boron has very big promoter action to yielding positive results of plant, and the result who adds boron in spraying fertilizer shows, can increase bloom quantity and percentage of fertile fruit, and can make early fruit maturity, can make crop yield 10-30% with this spray.
Three, sugarcane spraying fertilizer specially (also being applicable to corn, Chinese sorghum etc.), composition following (gram):
KH
2PO
4：100
Nafusaku: 1-6
MgSO
4：1-3
CaO(or CaSO
4): 2-4
FeSO
4：2-4
The fertilizer that sprays of cane kind crop has increased magnesium, calcium and iron, and this is that sugarcane is made sugar at necessary for growth nutriment, outside the dephosphorization potassium, an amount of magnesium, calcium and iron are arranged, can make the sugarcane jointing fast, growth is high, and is resistant to lodging, the result who sprays sugarcane by this prescription proves, what the plant height average specific did not spray during the sugarcane harvest is high more than 0.2 meter, and sugar improves about 1%, and output increases the 0.5-1 ton for every mu, peasant household and sugar refinery that this grows cane for the tropical and subtropical zone area, economic benefit are very considerable.
Below be application test result of the present invention:
One, Guiping County, Guangxi Shi Long township agrotechnical station testing data:
Use the short long agent of rice shoot of embodiment 1, the time, nineteen ninety late rice.
1. rice yield questionnaire
| Kind | Area (mu) | Mu is fringe (ten thousand) effectively | Total grain number | Real grain | Setting percentage % | The thousand seed weight gram | Theoretical yield (kilogram) | Actual output (kilogram) | Contrast 11 |
| Assorted excellent rich 64 | 0.3 | 24 | 100.8 | 89.8 | 89.1 | 24.3 | 523 | 497 | +38 |
| Contrast | 0.3 | 24.7 | 105.1 | 85.4 | 81.3 | 23.9 | 504 | 459 | 0 |
| The osmanthus late rice | 0.12 | 20 | 90.4 | 79.1 | 87.5 | 21.7 | 344 | 352 | +45 |
| Contrast | 0.12 | 19.8 | 95.6 | 76.4 | 79.9 | 21.3 | 322 | 307 | 0 |
2. the short long agent of rice shoot is to late hybrid rice seedling quality questionnaire
Annotate: rice shoot sprays concentration 1: 80 at a leaf one pin
Two, the big peace in sugar refinery, Pingnan County, Guangxi sugarcane station test situation:
Sprayed sugarcane concentration 1: 100 July nineteen ninety, observed with control group in 15 days, and 2.07 meters of plant heights, only 1.86 meters of the control group plant heights that does not spray, average 0.21 meter of the height that increases, sugar increases by 1%, and per mu yield increases by 0.51 ton during the September harvest.
Advantage of the present invention:
One, presses the KH of above-mentioned explained hereafter2PO
4、NH
4H
2PO
4With Nafusaku purity height, good water solubility is easily absorbed by plant leaf surface.
Two, production process is integrated, takes full advantage of intermediate products, and it is simple to save time, economize energy technology.
Three, nontoxic, noresidue, free from environmental pollution, product is solid, but and long-term storage never degenerate.
Four, each Plants is all played increase to grow, root is dark, full of leaves, it is many to spend, fruit is big, increases the effect of output.
Five, because to different crops and different times preparation special fertilizer, so more with strong points, effective than general broad spectrum activity foliage fertilizer.
Six, have certain disease-resistant and improve the crop quality effect.
Claims (7)
1, a kind of crops foliage spraying fertilizer, including can be by the nitrogen phosphorus potassium of plant absorbing and some chemical element, it is characterized in that thisly spraying fertilely in phosphoric acid and plant-growth regulator naphthalene compound, it is fertile that the compound of preparing other conditioning agent choline dichloride, boron, magnesium, manganese, calcium, iron, zinc is again made the series of Different Crop.
2, the fertilizer that sprays according to claim 1, it is characterized in that phosphoric acid salt is potassium primary phosphate and primary ammonium phosphate, naphthalene compound comprises naphthylacetic acid, naphthalene propionic acid, Chlorlacetic Acid or other naphthalene monocarboxylic acid class k-na salt, the compound of magnesium, manganese, calcium, iron, zinc is a vitriol soluble in water, choline dichloride comprises 2-chloroethyl trimethyl ammonium chloride, 2-4D, 2-Chloroallyl trimethyl ammonium chloride and chlorination lupetidin etc.
3,, it is characterized in that potassium primary phosphate and the naphthalene compound proportioning in spraying fertilizer is 100: 1～100: 10 according to claim 1 and the 2 described fertilizer that spray.
4, the fertilizer that sprays according to claim 1 is characterized in that the composition of the short long agent of rice shoot in the serial fertilizer has potassium primary phosphate, the compound of naphthalene compound, choline dichloride, MnZn.
5, the fertilizer that sprays according to claim 1, the composition that it is characterized in that sugarcane spray in the serial fertilizer has the compound of potassium primary phosphate, naphthalene compound, magnesium, calcium, iron.
6, the fertilizer that sprays according to claim 1 is characterized in that the composition of general crop spray in the serial fertilizer has potassium primary phosphate, primary ammonium phosphate, the compound of boron, calcium, iron.
7, according to the fertile production technique of spraying of claim 1 be: at first Repone K is adopted membrane electrolysis, the potassium hydroxide that obtains adds phosphoric acid, deliver to mixing section through cold analysis, dehydration and drying, primary ammonium phosphate is fed in the phosphoric acid by ammonia and makes, the chlorine that electrolytic process produces leads to catalyzed reaction generation chlorinated carboxylic acid in the solution such as acetate or propionic acid, add naphthalene then and make the naphthalene monocarboxylic acid compounds, generate naphthalene monocarboxylic acid salt with electrolytic solution or sodium hydroxide again, deliver to mixing section at last, respectively with the compound class wrapping of choline dichloride, boron, magnesium, calcium, iron, zinc.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91101093 CN1054966A (en) | 1991-02-19 | 1991-02-19 | Composite for crop root external nutrient spray fertilizer and production process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91101093 CN1054966A (en) | 1991-02-19 | 1991-02-19 | Composite for crop root external nutrient spray fertilizer and production process thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1054966A true CN1054966A (en) | 1991-10-02 |
Family
ID=4904957
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 91101093 Pending CN1054966A (en) | 1991-02-19 | 1991-02-19 | Composite for crop root external nutrient spray fertilizer and production process thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1054966A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999052369A1 (en) * | 1998-04-10 | 1999-10-21 | Yi Shang | A plant leaf fertiliser and its application |
| CN1048709C (en) * | 1994-11-18 | 2000-01-26 | 钟福才 | Efficient fertilizer for spraying plant root and its processing method |
| CN1068863C (en) * | 1998-10-09 | 2001-07-25 | 张毅 | Spray-applied root fertilizer of plant and its application |
| CN101209938B (en) * | 2006-12-30 | 2010-05-19 | 江苏里下河地区农业科学研究所 | Special-purpose slow release fertilizer for water-retention and sprout-cultivation |
| CN103097321A (en) * | 2010-07-09 | 2013-05-08 | 普里科尔股份有限公司 | Electrochemically treated nutrient solutions |
| CN105418219A (en) * | 2015-11-26 | 2016-03-23 | 武汉盛大神农生物工程有限公司 | Multifunctional fertilizer for preventing and treating open rice glumes |
| CN111848278A (en) * | 2020-07-28 | 2020-10-30 | 湖南农业大学 | Return fertilizer composition for mechanical transplanting, return fertilizer and application method and application thereof |
-
1991
- 1991-02-19 CN CN 91101093 patent/CN1054966A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1048709C (en) * | 1994-11-18 | 2000-01-26 | 钟福才 | Efficient fertilizer for spraying plant root and its processing method |
| WO1999052369A1 (en) * | 1998-04-10 | 1999-10-21 | Yi Shang | A plant leaf fertiliser and its application |
| CN1068863C (en) * | 1998-10-09 | 2001-07-25 | 张毅 | Spray-applied root fertilizer of plant and its application |
| CN101209938B (en) * | 2006-12-30 | 2010-05-19 | 江苏里下河地区农业科学研究所 | Special-purpose slow release fertilizer for water-retention and sprout-cultivation |
| CN103097321A (en) * | 2010-07-09 | 2013-05-08 | 普里科尔股份有限公司 | Electrochemically treated nutrient solutions |
| CN103097321B (en) * | 2010-07-09 | 2015-12-16 | 普里科尔股份有限公司 | The nutritive medium of electrochemical treatment |
| CN105418219A (en) * | 2015-11-26 | 2016-03-23 | 武汉盛大神农生物工程有限公司 | Multifunctional fertilizer for preventing and treating open rice glumes |
| CN111848278A (en) * | 2020-07-28 | 2020-10-30 | 湖南农业大学 | Return fertilizer composition for mechanical transplanting, return fertilizer and application method and application thereof |
| CN111848278B (en) * | 2020-07-28 | 2022-04-08 | 湖南农业大学 | Return fertilizer composition for mechanical transplanting, return fertilizer and application method and application thereof |
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