CN105419625A - 自清洁水性紫外光固化涂料及其制备方法 - Google Patents
自清洁水性紫外光固化涂料及其制备方法 Download PDFInfo
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- CN105419625A CN105419625A CN201511018732.4A CN201511018732A CN105419625A CN 105419625 A CN105419625 A CN 105419625A CN 201511018732 A CN201511018732 A CN 201511018732A CN 105419625 A CN105419625 A CN 105419625A
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- automatically cleaning
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- 238000004140 cleaning Methods 0.000 title claims abstract description 55
- 238000002360 preparation method Methods 0.000 title claims abstract description 50
- 239000003973 paint Substances 0.000 title abstract description 5
- 238000006243 chemical reaction Methods 0.000 claims abstract description 115
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims abstract description 51
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 45
- 239000006185 dispersion Substances 0.000 claims abstract description 43
- 238000003756 stirring Methods 0.000 claims abstract description 42
- MMCOUVMKNAHQOY-UHFFFAOYSA-N carbonoperoxoic acid Chemical compound OOC(O)=O MMCOUVMKNAHQOY-UHFFFAOYSA-N 0.000 claims abstract description 38
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000004970 Chain extender Substances 0.000 claims abstract description 29
- 150000001336 alkenes Chemical class 0.000 claims abstract description 29
- 239000008367 deionised water Substances 0.000 claims abstract description 25
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 23
- 239000004814 polyurethane Substances 0.000 claims abstract description 23
- 229920002635 polyurethane Polymers 0.000 claims abstract description 23
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 239000000243 solution Substances 0.000 claims description 60
- 238000000576 coating method Methods 0.000 claims description 51
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 36
- 239000003153 chemical reaction reagent Substances 0.000 claims description 28
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 25
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 25
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 24
- 239000000080 wetting agent Substances 0.000 claims description 24
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 23
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 22
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 21
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical group CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 19
- 239000000945 filler Substances 0.000 claims description 19
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 16
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 16
- 238000013019 agitation Methods 0.000 claims description 15
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 14
- -1 isocyano ion Chemical class 0.000 claims description 14
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical compound COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 claims description 12
- 239000012752 auxiliary agent Substances 0.000 claims description 11
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical group COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 11
- 238000010792 warming Methods 0.000 claims description 11
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 claims description 10
- 230000001804 emulsifying effect Effects 0.000 claims description 8
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000011259 mixed solution Substances 0.000 claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- 150000002334 glycols Chemical class 0.000 claims description 5
- 229920001610 polycaprolactone Polymers 0.000 claims description 5
- 239000004632 polycaprolactone Substances 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 4
- KXBFLNPZHXDQLV-UHFFFAOYSA-N [cyclohexyl(diisocyanato)methyl]cyclohexane Chemical compound C1CCCCC1C(N=C=O)(N=C=O)C1CCCCC1 KXBFLNPZHXDQLV-UHFFFAOYSA-N 0.000 claims description 4
- 150000002009 diols Chemical class 0.000 claims description 4
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims description 4
- 230000001681 protective effect Effects 0.000 claims description 4
- 239000008096 xylene Substances 0.000 claims description 4
- ZMARGGQEAJXRFP-UHFFFAOYSA-N 1-hydroxypropan-2-yl 2-methylprop-2-enoate Chemical compound OCC(C)OC(=O)C(C)=C ZMARGGQEAJXRFP-UHFFFAOYSA-N 0.000 claims description 3
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 claims description 3
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 3
- TUOBEAZXHLTYLF-UHFFFAOYSA-N [2-(hydroxymethyl)-2-(prop-2-enoyloxymethyl)butyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(CC)COC(=O)C=C TUOBEAZXHLTYLF-UHFFFAOYSA-N 0.000 claims description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 3
- 239000012295 chemical reaction liquid Substances 0.000 abstract 8
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000005442 diisocyanate group Chemical group 0.000 abstract 1
- 238000004945 emulsification Methods 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000013530 defoamer Substances 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 229910010413 TiO 2 Inorganic materials 0.000 description 4
- 238000006555 catalytic reaction Methods 0.000 description 4
- 238000007599 discharging Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 230000004044 response Effects 0.000 description 4
- 230000003068 static effect Effects 0.000 description 4
- 239000003643 water by type Substances 0.000 description 4
- 239000011538 cleaning material Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000003848 UV Light-Curing Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- OBVDANUWTSVXRO-UHFFFAOYSA-N 2,3,3-trihydroxyprop-2-enoic acid Chemical compound OC(O)=C(O)C(O)=O OBVDANUWTSVXRO-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- CQHKDHVZYZUZMJ-UHFFFAOYSA-N [2,2-bis(hydroxymethyl)-3-prop-2-enoyloxypropyl] prop-2-enoate Chemical group C=CC(=O)OCC(CO)(CO)COC(=O)C=C CQHKDHVZYZUZMJ-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002103 nanocoating Substances 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 238000001782 photodegradation Methods 0.000 description 1
- AZIQALWHRUQPHV-UHFFFAOYSA-N prop-2-eneperoxoic acid Chemical compound OOC(=O)C=C AZIQALWHRUQPHV-UHFFFAOYSA-N 0.000 description 1
- 239000005348 self-cleaning glass Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
- C08G18/348—Hydroxycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
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CN201511018732.4A CN105419625B (zh) | 2015-12-30 | 2015-12-30 | 自清洁水性紫外光固化涂料及其制备方法 |
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CN201511018732.4A CN105419625B (zh) | 2015-12-30 | 2015-12-30 | 自清洁水性紫外光固化涂料及其制备方法 |
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CN105419625A true CN105419625A (zh) | 2016-03-23 |
CN105419625B CN105419625B (zh) | 2018-01-05 |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106675383A (zh) * | 2016-12-30 | 2017-05-17 | 江南大学 | 一种自修复型紫外光固化防涂鸦树脂及其制备方法 |
CN106928763A (zh) * | 2017-04-24 | 2017-07-07 | 四川嘉宝莉涂料有限公司 | 一种抗菌水性聚氨酯涂料的制备方法 |
CN108484867A (zh) * | 2018-04-28 | 2018-09-04 | 广州顺力聚氨酯科技有限公司 | 热塑性聚氨酯弹性体及其制备方法和应用 |
CN109294422A (zh) * | 2018-06-04 | 2019-02-01 | 惠州市远安新材料有限公司 | 一种自清洁水性uv紫外光固化清漆及其制备方法 |
CN111978506A (zh) * | 2019-05-23 | 2020-11-24 | 珠海瑞杰包装制品有限公司 | 一种水性超支化聚氨酯丙烯酸酯乳液的制备方法、uv固化涂料及其制备方法和应用 |
CN112239622A (zh) * | 2020-10-29 | 2021-01-19 | 长春工业大学 | 一种用于玻璃基体的水性聚氨酯复合涂料的制备方法 |
CN113861833A (zh) * | 2021-10-22 | 2021-12-31 | 浙江奋飞科技有限公司 | 适用于橡胶传输带表面处理的紫外光固化涂料及其应用 |
CN114605593A (zh) * | 2022-02-18 | 2022-06-10 | 海洋化工研究院有限公司 | 一种水性自清洁聚氨酯分散体、杀菌组合物及制法和应用 |
CN114872388A (zh) * | 2022-04-30 | 2022-08-09 | 维尔特新材料科技(无锡)有限公司 | 一种低VOCs释放的玻镁板复合地板及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1844182A (zh) * | 2006-03-22 | 2006-10-11 | 中国科学技术大学 | 一种可紫外光固化水性聚氨酯树脂的制备方法 |
CN101423677A (zh) * | 2008-12-18 | 2009-05-06 | 江南大学 | 一种透明隔热的水性紫外光固化涂料的制备方法 |
-
2015
- 2015-12-30 CN CN201511018732.4A patent/CN105419625B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1844182A (zh) * | 2006-03-22 | 2006-10-11 | 中国科学技术大学 | 一种可紫外光固化水性聚氨酯树脂的制备方法 |
CN101423677A (zh) * | 2008-12-18 | 2009-05-06 | 江南大学 | 一种透明隔热的水性紫外光固化涂料的制备方法 |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106675383A (zh) * | 2016-12-30 | 2017-05-17 | 江南大学 | 一种自修复型紫外光固化防涂鸦树脂及其制备方法 |
CN106675383B (zh) * | 2016-12-30 | 2018-12-28 | 江南大学 | 一种自修复型紫外光固化防涂鸦树脂及其制备方法 |
CN106928763A (zh) * | 2017-04-24 | 2017-07-07 | 四川嘉宝莉涂料有限公司 | 一种抗菌水性聚氨酯涂料的制备方法 |
CN108484867A (zh) * | 2018-04-28 | 2018-09-04 | 广州顺力聚氨酯科技有限公司 | 热塑性聚氨酯弹性体及其制备方法和应用 |
CN109294422A (zh) * | 2018-06-04 | 2019-02-01 | 惠州市远安新材料有限公司 | 一种自清洁水性uv紫外光固化清漆及其制备方法 |
CN111978506A (zh) * | 2019-05-23 | 2020-11-24 | 珠海瑞杰包装制品有限公司 | 一种水性超支化聚氨酯丙烯酸酯乳液的制备方法、uv固化涂料及其制备方法和应用 |
CN112239622A (zh) * | 2020-10-29 | 2021-01-19 | 长春工业大学 | 一种用于玻璃基体的水性聚氨酯复合涂料的制备方法 |
CN113861833A (zh) * | 2021-10-22 | 2021-12-31 | 浙江奋飞科技有限公司 | 适用于橡胶传输带表面处理的紫外光固化涂料及其应用 |
CN113861833B (zh) * | 2021-10-22 | 2022-06-10 | 浙江奋飞科技有限公司 | 适用于橡胶传输带表面处理的紫外光固化涂料及其应用 |
CN114605593A (zh) * | 2022-02-18 | 2022-06-10 | 海洋化工研究院有限公司 | 一种水性自清洁聚氨酯分散体、杀菌组合物及制法和应用 |
CN114605593B (zh) * | 2022-02-18 | 2023-11-10 | 海洋化工研究院有限公司 | 一种水性自清洁聚氨酯分散体、杀菌组合物及制法和应用 |
CN114872388A (zh) * | 2022-04-30 | 2022-08-09 | 维尔特新材料科技(无锡)有限公司 | 一种低VOCs释放的玻镁板复合地板及其制备方法 |
CN114872388B (zh) * | 2022-04-30 | 2023-09-22 | 维尔特新材料科技(无锡)有限公司 | 一种低VOCs释放的玻镁板复合地板及其制备方法 |
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