CN105419223A - Improved glass-bead-packed phenolic aldehyde composite material - Google Patents
Improved glass-bead-packed phenolic aldehyde composite material Download PDFInfo
- Publication number
- CN105419223A CN105419223A CN201511006577.4A CN201511006577A CN105419223A CN 105419223 A CN105419223 A CN 105419223A CN 201511006577 A CN201511006577 A CN 201511006577A CN 105419223 A CN105419223 A CN 105419223A
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- CN
- China
- Prior art keywords
- parts
- composite material
- glass microballon
- phenolic aldehyde
- bead
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Provided is an improved glass-bead-packed phenolic aldehyde composite material. The composite material is prepared from the following raw materials, by weight, 8-14 parts of rosin, 3-6 parts of plant ash, 5-10 parts of zinc oxide, 0.5-1.6 parts of promoter, 16-24 parts of phenolic resins, 0.5-2.2 parts of metal oxide, 2-5 parts of silicon nitride, 0.5-1 part of surface compatilizer, 1.2-2 parts of release agent, 7-11 parts of wood fiber, 3-5 parts of seaweed mud, 2-4 parts of guar gum, 3-7 parts of meerschaum powder, 3-5 parts of corn starch, 4-7 parts of sodium methyl cellulose, 3-6 parts of surfactant, 7-11 parts of sodium sulfate, 4-5 parts of kaolin and 25-30 parts of glass beads. The beneficial effects are that the heat resistance of the phenolic aldehyde composite material is raised, the insulating property is raised well, and lightweighting is achieved.
Description
Technical field
The present invention relates to a kind of glass microballon filled phenolic matrix material of improvement.
Background technology
Resol realizes industrialized synthetic resins the earliest in the world, so far the history of existing more than 90 year.Because its raw material sources is wide, production technique and equipment simple, and, product have unique heat-resisting, resistance to so, the premium properties such as electric insulation, mechanical property and dimensional stabilizing, therefore, it has become the indispensable material of industrial sector, and tool has been widely used.And glass microballon is a kind of great thermotolerance, the filler of light specific gravity, can improve the resistance toheat of material.Light specific gravity volume is large.The density of hollow glass micropearl is about ten parts of traditional stopping composition density of particle, greatly can alleviate the basic weight of product after filling, and it has sound insulation, every thermal property, is the splendid weighting agent as various insulation, acoustical insulation products.The performance of phenolic composite is can be good at improving by adding glass microballon.
Summary of the invention
For the deficiencies in the prior art, the problem to be solved in the present invention is, provides a kind of glass microballon filled phenolic matrix material of improvement, improves the resistance toheat of phenolic composite, and insulativity is well improved simultaneously, and lightweight more.
For solving prior art problem, technical scheme provided by the invention is, a kind of glass microballon filled phenolic matrix material of improvement, and it is made up of the raw material of following parts by weight:
Rosin 8-14 part, plant ash 3-6 part, zinc oxide 5-10 part, promotor 0.5-1.6 part, resol 16-24 part, metal oxide 0.5-2.2 part, silicon nitride 2-5 part, surface compatilizer 0.5-1 part, releasing agent 1.2-2 part, wood fibre 7-11 part, algae clay 3-5 part, guar gum 2-4 part, sepiolite powder 3-7 part, W-Gum 3-5 part, sodium carboxymethylcellulose pyce 4-7 part, tensio-active agent 3-6 part, sodium sulfate 7-11 part, kaolin 4-5 part, glass microballon 25-30 part.
Further, a kind of glass microballon filled phenolic matrix material of improvement, it is made up of the raw material of following parts by weight:
Rosin 11 parts, 4.5 parts, plant ash, 7.5 parts, zinc oxide, promotor 1.1 parts, 20 parts, resol, metal oxide 1.6 parts, silicon nitride 3.5 parts, surface compatilizer 0.7 part, releasing agent 1.6 parts, wood fibre 9 parts, algae clay 4 parts, guar gum 3 parts, sepiolite powder 5 parts, W-Gum 4 parts, sodium carboxymethylcellulose pyce 5.5 parts, 4.5 parts, tensio-active agent, 9 parts, sodium sulfate, kaolin 4.5 parts, glass microballon 28 parts.
The invention has the beneficial effects as follows: glass microballon filled phenolic matrix material of the present invention, improve the resistance toheat of phenolic composite, insulativity is well improved simultaneously, and lightweight more.
Embodiment
embodiment 1
A glass microballon filled phenolic matrix material for improvement, it is made up of the raw material of following parts by weight:
Rosin 8 parts, 3 parts, plant ash, 5 parts, zinc oxide, promotor 0.5 part, 16 parts, resol, metal oxide 0.5 part, silicon nitride 2 parts, surface compatilizer 0.5 part, releasing agent 1.2 parts, wood fibre 7 parts, algae clay 3 parts, guar gum 2 parts, sepiolite powder 3 parts, W-Gum 3 parts, sodium carboxymethylcellulose pyce 4 parts, 3 parts, tensio-active agent, 7 parts, sodium sulfate, kaolin 4 parts, glass microballon 25 parts.
embodiment 2
A glass microballon filled phenolic matrix material for improvement, it is made up of the raw material of following parts by weight:
Rosin 14 parts, 6 parts, plant ash, 10 parts, zinc oxide, promotor 1.6 parts, 24 parts, resol, metal oxide 2.2 parts, silicon nitride 5 parts, surface compatilizer 1 part, releasing agent 2 parts, wood fibre 11 parts, algae clay 5 parts, guar gum 4 parts, sepiolite powder 7 parts, W-Gum 5 parts, sodium carboxymethylcellulose pyce 7 parts, 6 parts, tensio-active agent, 11 parts, sodium sulfate, kaolin 5 parts, glass microballon 30 parts.
embodiment 3
A glass microballon filled phenolic matrix material for improvement, it is made up of the raw material of following parts by weight:
Rosin 11 parts, 4.5 parts, plant ash, 7.5 parts, zinc oxide, promotor 1.1 parts, 20 parts, resol, metal oxide 1.6 parts, silicon nitride 3.5 parts, surface compatilizer 0.7 part, releasing agent 1.6 parts, wood fibre 9 parts, algae clay 4 parts, guar gum 3 parts, sepiolite powder 5 parts, W-Gum 4 parts, sodium carboxymethylcellulose pyce 5.5 parts, 4.5 parts, tensio-active agent, 9 parts, sodium sulfate, kaolin 4.5 parts, glass microballon 28 parts.
Claims (2)
1. a glass microballon filled phenolic matrix material for improvement, is characterized in that: it is made up of the raw material of following parts by weight:
Rosin 8-14 part, plant ash 3-6 part, zinc oxide 5-10 part, promotor 0.5-1.6 part, resol 16-24 part, metal oxide 0.5-2.2 part, silicon nitride 2-5 part, surface compatilizer 0.5-1 part, releasing agent 1.2-2 part, wood fibre 7-11 part, algae clay 3-5 part, guar gum 2-4 part, sepiolite powder 3-7 part, W-Gum 3-5 part, sodium carboxymethylcellulose pyce 4-7 part, tensio-active agent 3-6 part, sodium sulfate 7-11 part, kaolin 4-5 part, glass microballon 25-30 part.
2. the glass microballon filled phenolic matrix material of improvement according to claim 1, is characterized in that: it is made up of the raw material of following parts by weight:
Rosin 11 parts, 4.5 parts, plant ash, 7.5 parts, zinc oxide, promotor 1.1 parts, 20 parts, resol, metal oxide 1.6 parts, silicon nitride 3.5 parts, surface compatilizer 0.7 part, releasing agent 1.6 parts, wood fibre 9 parts, algae clay 4 parts, guar gum 3 parts, sepiolite powder 5 parts, W-Gum 4 parts, sodium carboxymethylcellulose pyce 5.5 parts, 4.5 parts, tensio-active agent, 9 parts, sodium sulfate, kaolin 4.5 parts, glass microballon 28 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511006577.4A CN105419223A (en) | 2015-12-29 | 2015-12-29 | Improved glass-bead-packed phenolic aldehyde composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511006577.4A CN105419223A (en) | 2015-12-29 | 2015-12-29 | Improved glass-bead-packed phenolic aldehyde composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105419223A true CN105419223A (en) | 2016-03-23 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511006577.4A Pending CN105419223A (en) | 2015-12-29 | 2015-12-29 | Improved glass-bead-packed phenolic aldehyde composite material |
Country Status (1)
| Country | Link |
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| CN (1) | CN105419223A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108456396A (en) * | 2018-01-24 | 2018-08-28 | 合肥铭佑高温技术有限公司 | A kind of high-temperature service mating switch and preparation method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102875960A (en) * | 2012-09-20 | 2013-01-16 | 常熟市永祥机电有限公司 | Macromolecular composite phenolic aldehyde material filled with glass beads |
| CN103183918A (en) * | 2011-12-27 | 2013-07-03 | 常熟市亚美模特儿衣架有限公司 | Thermosetting moulding compound filled with glass beads |
| CN103183917A (en) * | 2011-12-27 | 2013-07-03 | 常熟市亚美模特儿衣架有限公司 | Halogen-free flame-retardant thermosetting moulding compound filled with glass beads |
-
2015
- 2015-12-29 CN CN201511006577.4A patent/CN105419223A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103183918A (en) * | 2011-12-27 | 2013-07-03 | 常熟市亚美模特儿衣架有限公司 | Thermosetting moulding compound filled with glass beads |
| CN103183917A (en) * | 2011-12-27 | 2013-07-03 | 常熟市亚美模特儿衣架有限公司 | Halogen-free flame-retardant thermosetting moulding compound filled with glass beads |
| CN102875960A (en) * | 2012-09-20 | 2013-01-16 | 常熟市永祥机电有限公司 | Macromolecular composite phenolic aldehyde material filled with glass beads |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108456396A (en) * | 2018-01-24 | 2018-08-28 | 合肥铭佑高温技术有限公司 | A kind of high-temperature service mating switch and preparation method |
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| PB01 | Publication | ||
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| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160323 |