CN105219192A - Steel rust prevention coating and preparation method thereof - Google Patents

Steel rust prevention coating and preparation method thereof Download PDF

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Publication number
CN105219192A
CN105219192A CN201510729213.2A CN201510729213A CN105219192A CN 105219192 A CN105219192 A CN 105219192A CN 201510729213 A CN201510729213 A CN 201510729213A CN 105219192 A CN105219192 A CN 105219192A
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CN
China
Prior art keywords
rust prevention
prevention coating
component
steel rust
sulfonate
Prior art date
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Pending
Application number
CN201510729213.2A
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Chinese (zh)
Inventor
徐德生
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Jiabang Electric Power Pipeline Factory
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Wuxi Jiabang Electric Power Pipeline Factory
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Publication date
Application filed by Wuxi Jiabang Electric Power Pipeline Factory filed Critical Wuxi Jiabang Electric Power Pipeline Factory
Priority to CN201510729213.2A priority Critical patent/CN105219192A/en
Publication of CN105219192A publication Critical patent/CN105219192A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a kind of steel rust prevention coating, it comprises the component of following massfraction: acrylic resin 20 ~ 35%; Phenylformic acid 25 ~ 40%; Polyamide wax 10 ~ 20%; Modification aluminium triphosphate 15 ~ 20%; Petroleum-sulfonate composite antirust agent 5 ~ 10%.This steel rust prevention coating has low viscosity, high flash point, flame retardant properties and antistatic property.After tested, under the condition that thickness is 45 ± 5 μm, salt spray resistance reaches non-foaming, not corrosion in 650 ~ 690 hours.

Description

Steel rust prevention coating and preparation method thereof
Technical field
The present invention relates to rust proof paint, particularly relate to the rust proof paint of steel anti-corrosive, the invention still further relates to the preparation method of this rust proof paint.
Background technology
Most of rust proof paint of the prior art is all water-borne coatings or water-based paint, such as, disclosed in Chinese patent CN1083834, CN1456602A.As its name suggests, water-borne coatings take water as the coating that solvent or dispersion medium are made, and water-borne coatings mainly comprises water soluble paint and water latex paint two class.Its maximum feature is that whole or most of water instead of organic solvent, and filmogen is dispersed or dissolved in water by different way equably, and the rear paint film of dry or solidification has the water-fast of similar solvent based coating and physicals.But the composition of water-borne coatings is much more complicated than coatings volatile organic compounds, and the water volatile ratio solvent evaporates in water-borne coatings needs to absorb more heat, so energy consumption is higher.Therefore, be necessary to prepare a kind of environmentally safe, solvent based coating that energy consumption is low.
And from antirust aspect, the water capacity in water-borne coatings easily causes hardware corrosion, and organic solvent is not easy to form corrosion to hardware on the one hand, also can dissolve some water-fast materials on the other hand.Such as Chinese patent CN1085926A discloses a kind of antirust coatings, and the component that this coating comprises has epoxy system resin and polyvinyl acetal, phosphoric acid, Weibull, phosphoric acid salt, lead salt, ferriferous oxide, talcum powder and organic solvent.Although this coating strengthens toughness and the stability of paint film, the resistance to neutral salt spray performance of coating and corresponding anti-corrosion time are not disclosed.
Summary of the invention
First technical problem to be solved by this invention is the steel rust prevention coating providing a kind of salt spray resistance excellent for the state of the art.
Second technical problem to be solved by this invention is to provide a kind of preparation method of steel rust prevention coating.
The present invention solves the technical scheme that above-mentioned first technical problem adopt: a kind of steel rust prevention coating, comprises the component of following massfraction:
Wherein, steel rust prevention coating also comprises the calcium phosphate that massfraction is 5 ~ 10%.
Wherein, steel rust prevention coating also comprises the zinc sulfide white that massfraction is 5 ~ 10%.
Wherein, steel rust prevention coating is made up of the component of following massfraction:
Wherein, steel rust prevention coating is made up of the component of following massfraction:
Wherein, described petroleum-sulfonate rust-preventive agent comprises petroleum sodium sulfonate, barium mahogany sulfonate and dinonyl naphthalene barium mahogany sulfonate.
The present invention solves the technical scheme that above-mentioned first technical problem adopt: a kind of preparation method of steel rust prevention coating, is characterized in that, comprise the steps:
(1) according to the weight percent of component each in described rust proof paint, the weighing of each component is carried out;
(2) in reaction vessel, first phenylformic acid is loaded, lead to and be steam heated to 80 ~ 85 DEG C, add acrylic resin again, be incubated 1 ~ 2 hour, continue to be warming up to 100 ~ 105 DEG C, be incubated 1.5 ~ 2.5 hours, be cooled to 40 ~ 48 DEG C again, add the agent of petroleum-sulfonate composite antirust and modification aluminium triphosphate and urethane wax, insulation, cooling, obtained rust proof paint.
The present invention solves another technical scheme that above-mentioned first technical problem adopt: a kind of preparation method of steel rust prevention coating, is characterized in that, comprise the steps:
(1) according to the weight percent of component each in described rust proof paint, the weighing of each component is carried out;
(2) in reaction vessel, first phenylformic acid is loaded, lead to and be steam heated to 80 ~ 85 DEG C, add acrylic resin again, be incubated 1 ~ 2 hour, continue to be warming up to 100 ~ 105 DEG C, be incubated 1.5 ~ 2.5 hours, be cooled to 40 ~ 48 DEG C again, add the agent of petroleum-sulfonate composite antirust and modification aluminium triphosphate, urethane wax, calcium phosphate and zinc sulfide white, insulation, cooling, obtained rust proof paint.
Compared with prior art, the invention has the advantages that: this steel rust prevention coating has low viscosity, high flash point, flame retardant properties and antistatic property.After tested, under the condition that thickness is 45 ± 5 μm, salt spray resistance reaches non-foaming, not corrosion in 650 ~ 690 hours.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment 1
The steel rust prevention coating of the present embodiment is made up of the component of following massfraction:
Wherein, petroleum-sulfonate rust-preventive agent comprises petroleum sodium sulfonate, barium mahogany sulfonate and dinonyl naphthalene barium mahogany sulfonate.
The preparation method of the steel rust prevention coating of the present embodiment comprises the steps:
(1) according to the weight percent of component each in described rust proof paint, the weighing of each component is carried out;
(2) in reaction vessel, first phenylformic acid is loaded, lead to and be steam heated to 80 DEG C, add acrylic resin again, be incubated 1 hour, continue to be warming up to 100 DEG C, be incubated 1.5 hours, be cooled to 40 DEG C again, add the agent of petroleum-sulfonate composite antirust and modification aluminium triphosphate, urethane wax, calcium phosphate and zinc sulfide white, insulation, cooling, obtained rust proof paint.
Embodiment 2
The steel rust prevention coating of the present embodiment is made up of the component of following massfraction:
Wherein, petroleum-sulfonate rust-preventive agent comprises petroleum sodium sulfonate, barium mahogany sulfonate and dinonyl naphthalene barium mahogany sulfonate.
Preparation method's reference example 1 of the steel rust prevention coating of the present embodiment.
Embodiment 3
The steel rust prevention coating of the present embodiment is made up of the component of following massfraction:
Wherein, petroleum-sulfonate rust-preventive agent comprises petroleum sodium sulfonate, barium mahogany sulfonate and dinonyl naphthalene barium mahogany sulfonate.
Preparation method's reference example 1 of the steel rust prevention coating of the present embodiment.
Above content is only preferred embodiment of the present invention, and for those of ordinary skill in the art, according to thought of the present invention, all will change in specific embodiments and applications, this description should not be construed as limitation of the present invention.

Claims (8)

1. a steel rust prevention coating, is characterized in that, comprises the component of following massfraction:
2. steel rust prevention coating according to claim 1, is characterized in that, also comprises the calcium phosphate that massfraction is 5 ~ 10%.
3. steel rust prevention coating according to claim 1, is characterized in that, also comprises the zinc sulfide white that massfraction is 5 ~ 10%.
4. steel rust prevention coating according to claim 1, is characterized in that, is made up of the component of following massfraction:
5. steel rust prevention coating according to claim 1, is characterized in that, is made up of the component of following massfraction:
6. the steel rust prevention coating according to any one of claim 1 to 5, is characterized in that: described petroleum-sulfonate rust-preventive agent comprises petroleum sodium sulfonate, barium mahogany sulfonate and dinonyl naphthalene barium mahogany sulfonate.
7. a preparation method for steel rust prevention coating as claimed in claim 1, is characterized in that, comprise the steps:
(1) according to the weight percent of component each in described rust proof paint, the weighing of each component is carried out;
(2) in reaction vessel, first phenylformic acid is loaded, lead to and be steam heated to 80 ~ 85 DEG C, add acrylic resin again, be incubated 1 ~ 2 hour, continue to be warming up to 100 ~ 105 DEG C, be incubated 1.5 ~ 2.5 hours, be cooled to 40 ~ 48 DEG C again, add the agent of petroleum-sulfonate composite antirust and modification aluminium triphosphate and urethane wax, insulation, cooling, obtained rust proof paint.
8. a preparation method for the steel rust prevention coating as described in claim 4 or 5, is characterized in that, comprise the steps:
(1) according to the weight percent of component each in described rust proof paint, the weighing of each component is carried out;
(2) in reaction vessel, first phenylformic acid is loaded, lead to and be steam heated to 80 ~ 85 DEG C, add acrylic resin again, be incubated 1 ~ 2 hour, continue to be warming up to 100 ~ 105 DEG C, be incubated 1.5 ~ 2.5 hours, be cooled to 40 ~ 48 DEG C again, add the agent of petroleum-sulfonate composite antirust and modification aluminium triphosphate, urethane wax, calcium phosphate and zinc sulfide white, insulation, cooling, obtained rust proof paint.
CN201510729213.2A 2015-10-30 2015-10-30 Steel rust prevention coating and preparation method thereof Pending CN105219192A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510729213.2A CN105219192A (en) 2015-10-30 2015-10-30 Steel rust prevention coating and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510729213.2A CN105219192A (en) 2015-10-30 2015-10-30 Steel rust prevention coating and preparation method thereof

Publications (1)

Publication Number Publication Date
CN105219192A true CN105219192A (en) 2016-01-06

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105632722A (en) * 2016-02-24 2016-06-01 李聪 Tuning electric reactor
CN105884237A (en) * 2016-05-12 2016-08-24 陆静 Concrete rust inhibitor
CN110760208A (en) * 2019-10-23 2020-02-07 国网山东省电力公司莒南县供电公司 Antistatic antirust paint for communication machine room and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1944556A (en) * 2006-11-13 2007-04-11 三河市来金涂料工程有限公司 Anti-rust paint and anti-rust coating and their preparing method
CN102079933A (en) * 2009-11-30 2011-06-01 程雷 Aqueous acrylate emulsion antirust paint
CN102079891A (en) * 2009-11-30 2011-06-01 王苏彪 Petroleum-sulfonate antirust paint
CN102079931A (en) * 2009-11-30 2011-06-01 王佳宇 Industrial antirust coating
CN104059511A (en) * 2013-03-18 2014-09-24 福建省腾龙工业公司 Quick-drying primer-topcoat two-in-one steel member paint and preparation method thereof
CN104152020A (en) * 2014-07-30 2014-11-19 苏州聚康新材料科技有限公司 Antirust coating for steel member and preparation method of antirust coating

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1944556A (en) * 2006-11-13 2007-04-11 三河市来金涂料工程有限公司 Anti-rust paint and anti-rust coating and their preparing method
CN102079933A (en) * 2009-11-30 2011-06-01 程雷 Aqueous acrylate emulsion antirust paint
CN102079891A (en) * 2009-11-30 2011-06-01 王苏彪 Petroleum-sulfonate antirust paint
CN102079931A (en) * 2009-11-30 2011-06-01 王佳宇 Industrial antirust coating
CN104059511A (en) * 2013-03-18 2014-09-24 福建省腾龙工业公司 Quick-drying primer-topcoat two-in-one steel member paint and preparation method thereof
CN104152020A (en) * 2014-07-30 2014-11-19 苏州聚康新材料科技有限公司 Antirust coating for steel member and preparation method of antirust coating

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105632722A (en) * 2016-02-24 2016-06-01 李聪 Tuning electric reactor
CN105884237A (en) * 2016-05-12 2016-08-24 陆静 Concrete rust inhibitor
CN110760208A (en) * 2019-10-23 2020-02-07 国网山东省电力公司莒南县供电公司 Antistatic antirust paint for communication machine room and preparation method thereof

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Application publication date: 20160106