CN105176325A - Acid and alkali resistant flame retardation and antibiosis coating - Google Patents
Acid and alkali resistant flame retardation and antibiosis coating Download PDFInfo
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- CN105176325A CN105176325A CN201510560295.2A CN201510560295A CN105176325A CN 105176325 A CN105176325 A CN 105176325A CN 201510560295 A CN201510560295 A CN 201510560295A CN 105176325 A CN105176325 A CN 105176325A
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Abstract
The invention relates to an acid and alkali resistant flame retardation and antibiosis coating. The coating comprises, by mass, 32-36 parts of diethofencarb, 34-38 parts of benzyl bromide, 30-34 parts of thifluzamide, 34-38 parts of benomyl, 30-34 parts of PVC resin powder, 34-38 parts of pearl powder, 30-34 parts of methyl phenyl silicone resin, 36-40 parts of floss powder, 30-34 parts of strontium chromate, 34-38 parts of nitrocotton, 30-34 parts of citronellyl formate, 34-38 parts of epoxy acrylate, 30-34 parts of trimethylolpropane triacrylate, 34-38 parts of silver-zinc-titanium dioxide, 30-34 parts of a polyurethane copolymer, 34-38 parts of alkyd resin and 1000-2000 parts of water. A preparation method of the coating is simple, and the coating prepared through the method has superior flame retardation performance, acid and alkali resistance and waterproof and antibacterial performances, is suitable for being used in various fields, has improved performances, and is convenient to process and use.
Description
Technical field
The present invention relates to a kind of acid and alkali-resistance flame-proof antibiotic coating, belong to formulation for coating material technical field.
Background technology
Coating is coated in protected or decorated body surface; and the continuous film of firm attachment can be formed with coated article, normally based on resin or oil or emulsion, add or do not add pigment, filler; add corresponding additive, with organic solvent or the formulated thick liquid of water.China's coating circle more authoritative " coating process " book is definition like this: coating is a kind of material, and this material can be coated in article surface by different construction technologies, forms adhere well, has some strength, continuous print solid film.The film common name film of such formation, also known as paint film or coating.
Summary of the invention
The object of the present invention is to provide a kind of acid and alkali-resistance flame-proof antibiotic coating, to realize the function of coating acid and alkali-resistance flame-proof antibiotic better.
To achieve these goals, technical scheme of the present invention is as follows.
A kind of acid and alkali-resistance flame-proof antibiotic coating, be made up of the component of following mass fraction: the mould prestige of second 32 ~ 36 parts, cylite 34 ~ 38 parts, thifluzamide 30 ~ 34 parts, benzene Lay spy 34 ~ 38 parts, PVC resin powder 30 ~ 34 parts, pearlescence 34 ~ 38 parts, methyl phenyl silicone resin 30 ~ 34 parts, 36 ~ 40 parts, fine hair powder, strontium yellow 30 ~ 34 parts, nitro-cotton 34 ~ 38 parts, citronellyl formate 30 ~ 34 parts, epoxy acrylate 34 ~ 38 parts, Viscoat 295 30 ~ 34 parts, silver zinc titanium dioxide 34 ~ 38 parts, polyurethane copolymer 30 ~ 34 parts, Synolac 34 ~ 38 parts, 1000 ~ 2000 parts, water.
Further, above-mentioned acid and alkali-resistance flame-proof antibiotic coating, is made up of the component of following mass fraction: special 34 parts of the mould prestige of second 32 parts, cylite 34 parts, thifluzamide 30 parts, benzene Lay, PVC resin powder 30 parts, pearlescence 34 parts, methyl phenyl silicone resin 30 parts, 36 parts, fine hair powder, strontium yellow 30 parts, nitro-cotton 34 parts, citronellyl formate 30 parts, epoxy acrylate 34 parts, Viscoat 295 30 parts, silver-colored zinc titanium dioxide 34 parts, polyurethane copolymer 30 parts, Synolac 34 parts, 1000 parts, water.
Further, above-mentioned acid and alkali-resistance flame-proof antibiotic coating, is made up of the component of following mass fraction: special 36 parts of the mould prestige of second 34 parts, cylite 36 parts, thifluzamide 32 parts, benzene Lay, PVC resin powder 32 parts, pearlescence 36 parts, methyl phenyl silicone resin 32 parts, 38 parts, fine hair powder, strontium yellow 32 parts, nitro-cotton 36 parts, citronellyl formate 32 parts, epoxy acrylate 36 parts, Viscoat 295 32 parts, silver-colored zinc titanium dioxide 36 parts, polyurethane copolymer 32 parts, Synolac 36 parts, 1500 parts, water.
Further, above-mentioned acid and alkali-resistance flame-proof antibiotic coating, is made up of the component of following mass fraction: special 38 parts of the mould prestige of second 36 parts, cylite 38 parts, thifluzamide 34 parts, benzene Lay, PVC resin powder 34 parts, pearlescence 38 parts, methyl phenyl silicone resin 34 parts, 40 parts, fine hair powder, strontium yellow 34 parts, nitro-cotton 38 parts, citronellyl formate 34 parts, epoxy acrylate 38 parts, Viscoat 295 34 parts, silver-colored zinc titanium dioxide 38 parts, polyurethane copolymer 34 parts, Synolac 38 parts, 2000 parts, water.
Further, above-mentioned acid and alkali-resistance flame-proof antibiotic preparation method for coating step is as follows:
(1) mould for the second of described mass fraction prestige, cylite, thifluzamide, benzene Lai Te, PVC resin powder, pearlescence, methyl phenyl silicone resin, fine hair powder, strontium yellow, nitro-cotton, citronellyl formate, epoxy acrylate, silver-colored zinc titanium dioxide, Synolac are added in the water of above-mentioned mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 40KHz, rate of dispersion about 5000 ~ 5400r/min, jitter time is 30 ~ 60min;
(2) add the Viscoat 295 of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 35KHz, rate of dispersion about 4800 ~ 5200r/min, and jitter time is 30 ~ 50min;
(3) add the polyurethane copolymer of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 30KHz, rate of dispersion about 4600 ~ 4800r/min, and jitter time is 20 ~ 40min; Mix rear obtained this product.
Above-mentioned each component function is as follows:
(1) the mould prestige of second: former medicine is brown solid, is insoluble in water, is soluble in methyl alcohol.A kind of sterilant having secondary cross resistance with derosal.Medicament enter after somatic cells with the tubulin binding in somatic cells, thus affect the division of cell.
(2) cylite: this product is important organic synthesis industrial raw material, is widely used in the manufacture of whipping agent, is also used as foaming agent and yeast sanitas.
(3) thifluzamide: belong to thiazole amide sterilant, has strong Uptake and translocation and long long-lasting.
(4) benzene Lai Te: this product is systemic fungicide, has protection, roots out and therapeutic action.
(5) PVC resin powder: physical appearance is white powder, nontoxic, odorless.Water insoluble, gasoline, alcohol and vinylchlorid, be dissolved in acetone, ethylene dichloride, dimethylbenzene equal solvent, and chemical stability is very high, has good plasticity-.Its product has good physicals and chemical property, is widely used in the fields such as industry, building, agricultural, daily life, packaging, electric power, public utilities.
(6) pearlescence: microcosmic is transparent, and flats divides nothing, relies on light refraction, reflection, and transmission shows color and light.Pearly pigment toxicological harmless, high temperature resistant, resistance to illumination, acid and alkali-resistance, not spontaneous combustion, not combustion-supporting, non-conductive, do not move, can coating be met, plastics, ink, leather, printing and dyeing, rubber, papermaking, the different demands of the industries such as makeup, make the product appearance of these industries more magnificent beautiful, and light is beautiful according to people.
(7) methyl phenyl silicone resin: make electronic devices and components encapsulation coating with it; Laminating material tackiness agent; Solid rocket motor; The releasing agent of food die, baking tray and rubber item; The properties-correcting agent etc. of organic resin.
(8) fine hair powder: have caoutchouc elasticity, heat-resisting, solvent resistant, antiacid alkali and scratch resistance are all good, can be widely used in the coating of all kinds of zero diopter such as leather, plastic cement, painted soft feeling.
(9) strontium yellow: yellow monoclinic crystal or lemon yellow powder.Be slightly soluble in water.Photostabilization is good.High temperature is more stable.But opacifying power and tinting strength are not high.Acid resistance and alkali resistance better.There is good rustless property.
(10) nitro-cotton: be white or micro-yellow flocculence, can acetone be dissolved in.For the production of assorted zylonite, cinefilm, the aspect such as nitrocellulose chip and explosive; Colors are sprayed paint, stencil paper, varnished cloth, bottle mouth sleeve etc.
(11) citronellyl formate: tool is fresh and sweet rose, spiceleaf sample fragrance, slightly with the blue or green fragrance breath that Citrus bergamia, cucumber etc. are fresh clearly.
(12) epoxy acrylate: there is excellent water tolerance, hot water resistance, resistance physical property, cohesiveness, toughness.Just can be cured by organic peroxide curing method or photocuring processes.
(13) Viscoat 295: the colourless or micro-yellow transparent liquid of low smell type, water-soluble hardly, dissolve in common solvent.Be mainly used in the aspects such as photo-cured coating, light-curable ink, photoresist material, flexible printing product, solder resist, resist, paint, polymer modification.
(14) silver-colored zinc titanium dioxide: the photocatalysis performance of composite granule, anti-microbial property, color and luster and stability are ideal, has good Durability of antimicrobial effect and stability and the acid and alkali-resistance flame-proof antibiotic coating of good decorating effect.
(15) polyurethane copolymer: mechanical property has very large adjustability.By the ratio between the hard section of crystallization control and non crystallized soft section, urethane can obtain different mechanical properties.Therefore its goods have the excellent properties such as wear-resisting, heatproof, sealing, sound insulation, good processability, degradable.Purposes is very wide, can replace rubber, plastics, nylon etc.The coating made has strong tackiness, and film has excellent wear resistance, water tolerance and resistance to chemical reagents etc.Be mainly used in coatings for furniture, building materials coating and industrial printing-ink etc.
(16) Synolac: by the resin of lipid acid, diprotic acid and polyol reaction.Coating has the features such as weathering resistance, sticking power is good and bright, plentiful, and easy construction.But film is softer, water-fast, alkali resistance is not good enough, the dry or drying enamel paint of multiple different performance, priming paint, finish paint and varnish can be made into other resins, be widely used in the application such as the buildingss such as bridge and machinery, vehicle, boats and ships, aircraft, instrument.
This beneficial effect of the invention is: this acid and alkali-resistance flame-proof antibiotic Paint preparation technology method is simple, prepared product has comparatively superior fire-retardant, acid and alkali-resistance, water-proof antibiotic performance, be adapted at multiple fields to use, improve product performance, process easy to use.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is described, better to understand the present invention.
embodiment 1
Acid and alkali-resistance flame-proof antibiotic coating in the present embodiment, is made up of the component of following mass fraction: special 34 parts of the mould prestige of second 32 parts, cylite 34 parts, thifluzamide 30 parts, benzene Lay, PVC resin powder 30 parts, pearlescence 34 parts, methyl phenyl silicone resin 30 parts, 36 parts, fine hair powder, strontium yellow 30 parts, nitro-cotton 34 parts, citronellyl formate 30 parts, epoxy acrylate 34 parts, Viscoat 295 30 parts, silver-colored zinc titanium dioxide 34 parts, polyurethane copolymer 30 parts, Synolac 34 parts, 1000 parts, water.
Above-mentioned acid and alkali-resistance flame-proof antibiotic preparation method for coating step is as follows:
(1) mould for the second of described mass fraction prestige, cylite, thifluzamide, benzene Lai Te, PVC resin powder, pearlescence, methyl phenyl silicone resin, fine hair powder, strontium yellow, nitro-cotton, citronellyl formate, epoxy acrylate, silver-colored zinc titanium dioxide, Synolac are added in the water of above-mentioned mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion about 5400r/min, jitter time is 60min;
(2) add the Viscoat 295 of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion about 5200r/min, and jitter time is 50min;
(3) add the polyurethane copolymer of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion about 4800r/min, and jitter time is 40min; Mix rear obtained this product.
embodiment 2
Acid and alkali-resistance flame-proof antibiotic coating in the present embodiment, is made up of the component of following mass fraction: special 36 parts of the mould prestige of second 34 parts, cylite 36 parts, thifluzamide 32 parts, benzene Lay, PVC resin powder 32 parts, pearlescence 36 parts, methyl phenyl silicone resin 32 parts, 38 parts, fine hair powder, strontium yellow 32 parts, nitro-cotton 36 parts, citronellyl formate 32 parts, epoxy acrylate 36 parts, Viscoat 295 32 parts, silver-colored zinc titanium dioxide 36 parts, polyurethane copolymer 32 parts, Synolac 36 parts, 1500 parts, water.
Above-mentioned acid and alkali-resistance flame-proof antibiotic preparation method for coating step is as follows:
(1) mould for the second of described mass fraction prestige, cylite, thifluzamide, benzene Lai Te, PVC resin powder, pearlescence, methyl phenyl silicone resin, fine hair powder, strontium yellow, nitro-cotton, citronellyl formate, epoxy acrylate, silver-colored zinc titanium dioxide, Synolac are added in the water of above-mentioned mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 30kHz, rate of dispersion about 5200r/min, jitter time is 45min;
(2) add the Viscoat 295 of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 27kHz, rate of dispersion about 5000r/min, and jitter time is 40min;
(3) add the polyurethane copolymer of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 25kHz, rate of dispersion about 4700r/min, and jitter time is 30min; Mix rear obtained this product.
embodiment 3
Acid and alkali-resistance flame-proof antibiotic coating in the present embodiment, is made up of the component of following mass fraction: special 38 parts of the mould prestige of second 36 parts, cylite 38 parts, thifluzamide 34 parts, benzene Lay, PVC resin powder 34 parts, pearlescence 38 parts, methyl phenyl silicone resin 34 parts, 40 parts, fine hair powder, strontium yellow 34 parts, nitro-cotton 38 parts, citronellyl formate 34 parts, epoxy acrylate 38 parts, Viscoat 295 34 parts, silver-colored zinc titanium dioxide 38 parts, polyurethane copolymer 34 parts, Synolac 38 parts, 2000 parts, water.
Above-mentioned acid and alkali-resistance flame-proof antibiotic preparation method for coating step is as follows:
(1) mould for the second of described mass fraction prestige, cylite, thifluzamide, benzene Lai Te, PVC resin powder, pearlescence, methyl phenyl silicone resin, fine hair powder, strontium yellow, nitro-cotton, citronellyl formate, epoxy acrylate, silver-colored zinc titanium dioxide, Synolac are added in the water of above-mentioned mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 40kHz, rate of dispersion 5000r/min, jitter time is 30min;
(2) add the Viscoat 295 of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 35kHz, rate of dispersion 4800r/min, and jitter time is 30min;
(3) add the polyurethane copolymer of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 30kHz, rate of dispersion about 4600r/min, and jitter time is 20min; Mix rear obtained this product.
Carry out performance measurement for the coating in embodiment 1, embodiment 2 and embodiment 3 and certain commercial coating, measured data are as shown in table 1.Fire protection flame retarding level estimate adopts UL94 standard.
Table 1 the performance test results
Visible, material of the present invention has corrosion-resistant, fire protection flame retarding, waterproof, anti-microbial property preferably.
The above is the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.
Claims (5)
1. an acid and alkali-resistance flame-proof antibiotic coating, it is characterized in that: be made up of the component of following mass fraction: the mould prestige of second 32 ~ 36 parts, cylite 34 ~ 38 parts, thifluzamide 30 ~ 34 parts, benzene Lay spy 34 ~ 38 parts, PVC resin powder 30 ~ 34 parts, pearlescence 34 ~ 38 parts, methyl phenyl silicone resin 30 ~ 34 parts, 36 ~ 40 parts, fine hair powder, strontium yellow 30 ~ 34 parts, nitro-cotton 34 ~ 38 parts, citronellyl formate 30 ~ 34 parts, epoxy acrylate 34 ~ 38 parts, Viscoat 295 30 ~ 34 parts, silver zinc titanium dioxide 34 ~ 38 parts, polyurethane copolymer 30 ~ 34 parts, Synolac 34 ~ 38 parts, 1000 ~ 2000 parts, water.
2. acid and alkali-resistance flame-proof antibiotic coating according to claim 1, it is characterized in that: described acid and alkali-resistance flame-proof antibiotic coating is made up of the component of following mass fraction: the mould prestige of second 32 parts, cylite 34 parts, thifluzamide 30 parts, special 34 parts of benzene Lay, PVC resin powder 30 parts, pearlescence 34 parts, methyl phenyl silicone resin 30 parts, 36 parts, fine hair powder, strontium yellow 30 parts, nitro-cotton 34 parts, citronellyl formate 30 parts, epoxy acrylate 34 parts, Viscoat 295 30 parts, silver zinc titanium dioxide 34 parts, polyurethane copolymer 30 parts, Synolac 34 parts, 1000 parts, water.
3. according to the acid and alkali-resistance flame-proof antibiotic coating described in claim 1 to 2, it is characterized in that: described acid and alkali-resistance flame-proof antibiotic coating is made up of the component of following mass fraction: the mould prestige of second 34 parts, cylite 36 parts, thifluzamide 32 parts, special 36 parts of benzene Lay, PVC resin powder 32 parts, pearlescence 36 parts, methyl phenyl silicone resin 32 parts, 38 parts, fine hair powder, strontium yellow 32 parts, nitro-cotton 36 parts, citronellyl formate 32 parts, epoxy acrylate 36 parts, Viscoat 295 32 parts, silver zinc titanium dioxide 36 parts, polyurethane copolymer 32 parts, Synolac 36 parts, 1500 parts, water.
4. the acid and alkali-resistance flame-proof antibiotic coating according to claims 1 to 3, it is characterized in that: described acid and alkali-resistance flame-proof antibiotic coating is made up of the component of following mass fraction: the mould prestige of second 36 parts, cylite 38 parts, thifluzamide 34 parts, special 38 parts of benzene Lay, PVC resin powder 34 parts, pearlescence 38 parts, methyl phenyl silicone resin 34 parts, 40 parts, fine hair powder, strontium yellow 34 parts, nitro-cotton 38 parts, citronellyl formate 34 parts, epoxy acrylate 38 parts, Viscoat 295 34 parts, silver zinc titanium dioxide 38 parts, polyurethane copolymer 34 parts, Synolac 38 parts, 2000 parts, water.
5. the acid and alkali-resistance flame-proof antibiotic coating according to claim 1 or 4, is characterized in that: described acid and alkali-resistance flame-proof antibiotic preparation method for coating step is as follows:
(1) mould for the second of described mass fraction prestige, cylite, thifluzamide, benzene Lai Te, PVC resin powder, pearlescence, methyl phenyl silicone resin, fine hair powder, strontium yellow, nitro-cotton, citronellyl formate, epoxy acrylate, silver-colored zinc titanium dioxide, Synolac are added in the water of above-mentioned mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 40KHz, rate of dispersion about 5000 ~ 5400r/min, jitter time is 30 ~ 60min;
(2) add the Viscoat 295 of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 35KHz, rate of dispersion about 4800 ~ 5200r/min, and jitter time is 30 ~ 50min;
(3) add the polyurethane copolymer of described mass fraction, ultrasonic high speed dispersion, ultrasonic frequency is 20 ~ 30KHz, rate of dispersion about 4600 ~ 4800r/min, and jitter time is 20 ~ 40min; Mix rear obtained this product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510560295.2A CN105176325A (en) | 2015-09-07 | 2015-09-07 | Acid and alkali resistant flame retardation and antibiosis coating |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510560295.2A CN105176325A (en) | 2015-09-07 | 2015-09-07 | Acid and alkali resistant flame retardation and antibiosis coating |
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| CN201510560295.2A Pending CN105176325A (en) | 2015-09-07 | 2015-09-07 | Acid and alkali resistant flame retardation and antibiosis coating |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105860795A (en) * | 2016-04-12 | 2016-08-17 | 湖州新奥克化工有限公司 | Environmentally-friendly high-hardness aqueous woodenware coating and preparation method thereof |
| CN106189413A (en) * | 2016-07-08 | 2016-12-07 | 广安奥海通讯电子科技有限公司 | A kind of dust-proof coating of electronic product antibacterial surface |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103937339A (en) * | 2014-03-25 | 2014-07-23 | 周挺 | Antiseptic fluorescent paint |
| CN104830195A (en) * | 2015-05-04 | 2015-08-12 | 君子兰化工（上海）有限公司 | Transparent flame-retardant aqueous nanometer coating for woodenware, and production method thereof |
-
2015
- 2015-09-07 CN CN201510560295.2A patent/CN105176325A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103937339A (en) * | 2014-03-25 | 2014-07-23 | 周挺 | Antiseptic fluorescent paint |
| CN104830195A (en) * | 2015-05-04 | 2015-08-12 | 君子兰化工（上海）有限公司 | Transparent flame-retardant aqueous nanometer coating for woodenware, and production method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105860795A (en) * | 2016-04-12 | 2016-08-17 | 湖州新奥克化工有限公司 | Environmentally-friendly high-hardness aqueous woodenware coating and preparation method thereof |
| CN106189413A (en) * | 2016-07-08 | 2016-12-07 | 广安奥海通讯电子科技有限公司 | A kind of dust-proof coating of electronic product antibacterial surface |
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