CN104804606A - Anaglyphic paint and preparation method thereof - Google Patents
Anaglyphic paint and preparation method thereof Download PDFInfo
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- CN104804606A CN104804606A CN201510238352.5A CN201510238352A CN104804606A CN 104804606 A CN104804606 A CN 104804606A CN 201510238352 A CN201510238352 A CN 201510238352A CN 104804606 A CN104804606 A CN 104804606A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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Abstract
The invention discloses an anaglyphic paint and a preparation method thereof and relates to the technical field of art paint. The anaglyphic paint is prepared from the following components in parts by weight: 85-95 parts of epoxy modified acrylic resin, 1.5-3.5 parts of a film forming aid, 0.5-1.5 parts of a flatting agent, 0.2-0.5 part of a dispersant, 0.4-0.7 part of a wetting agent, 0.8-1.2 parts of a defoaming agent, 15-25 parts of 1250-mesh talcum powder, 2.0-3.5 parts of a thickening agent, 3-8 parts of a bactericide, 0.5-0.8 part of a pH regulating agent and 35-65 parts of water. The anaglyphic paint disclosed by the invention has the beneficial effects that the anaglyphic paint obtained by a specific prescription and a specific preparation has the characteristics of good waterproofness, good dustproof property and good flame resistance effect of the existing anaglyphic paint, is also relatively low in free formaldehyde content, full in paint film, high in artistic feeling after being sprayed by a spraying gun, and satisfies the national relevant regulations in other performances.
Description
Technical field
The present invention relates to a kind of art coatings, particularly a kind of anaglyphy paint and preparation method thereof.
Background technology
Art coatings originates from Europe, and advanced technique is also spread by Europe and comes, after entering domestic market, with the decorated style of its novelty, and unusual decorative effect, doubly welcomed by the people and high praise.Art coatings is a kind of novel wall decoration art paint, adds the treatment process of modern high technology, makes product nontoxic, environmental protection, and also possess waterproof and dustproof and the function such as fire-retardant, high-quality art coatings can criticize brush simultaneously, and adsorptivity is strong, and color sustains its quality through age.
Textured paint is a series in art coatings, and textured paint is the colored metope coating material that a kind of match volume is true to nature.Metope after decoration exactly likes three-dimensional perception effect as embossment, so be referred to as anaglyph.Textured paint is not only a kind of brand-new decorative art
coating, the perfection performance of decorative art especially.Enhancing volatile organic compounds (Volatile Organic Compound is called for short VOC) along with people's environmental consciousness more and more receives the concern of the public and is strictly limited, although control VOC has become promote that Main Means VOC of water emulsion coating for solvent based coating of building coating Sustainable development reduces greatly, but owing to still containing the low molecule organic volatiles such as a certain amount of film coalescence aid frostproofer in water-borne coatings, they constitute the main source of latex coating VOC, how to reduce VOC further, improving environment friendly is the important developing direction of Architectural Emulsion Paints.
Summary of the invention
In view of this, an object of the present invention is to provide a kind of anaglyphy paint, and have lower free formaldehyde content, environmental protection, good waterproof performance, paint film is full, and strong through spray gun spraying artistic feeling, other performances meet relevant specification of country.
The present invention is solved the problems of the technologies described above by following technique means:
The invention provides a kind of anaglyphy paint, composed of the following components by weight: epoxy modified acrylic resin 85-95 part, film coalescence aid 1.5-3.5 part, flow agent 0.5-1.5 part, dispersion agent 0.2-0.5 part, wetting agent 0.4-0.7 part, defoamer 0.8-1.2 part, 1250 order talcum powder 15-25 parts, thickening material 2.0-3.5 part, sterilant 3-8 part, pH adjusting agent 0.5-0.8 part, water 35-65 part, described epoxy modified acrylic resin is composed of the following components by weight: E-44 epoxy resin 40-55 part, methyl methacrylate 60-77 part, vinylformic acid 5-12 part, Octyl acrylate 30-38 part, vinylbenzene 10-15 part, Propylene glycol monoacrylate 10-15 part, trimethyol propane triacrylate 2-5 part, benzoyl peroxide 2-5 part, solidifying agent 3-6 part, the preparation method of described epoxy modified acrylic resin: for subsequent use by described formula feeding, E-44 epoxy resin and solidifying agent are added in reactor successively, with 600 revs/min of blending dispersion 3 minutes, heating, in reactor, vinylformic acid is dripped when temperature is added to 70 DEG C, again heat, when temperature is added to 85 DEG C, reactor adds methyl methacrylate after reacting 1 hour, vinylformic acid, Octyl acrylate, vinylbenzene, Propylene glycol monoacrylate, the mixture of trimethyol propane triacrylate and benzoyl peroxide, reactor reaction 2-3 hour, be cooled to room temperature.
Epoxy modified acrylic resin introduces propenyl unsaturated double-bond at the two ends of epoxy molecule chain, then with other monomer copolymerizations, make the various premium propertiess of epoxy resin, adhesive power be strong, molding shrinkage is low, chemical stability is good, electrical insulating property and Heat stability is good etc.
Flow agent adopts and can impel coating in drying and forming-film process, form smooth, smooth, a uniform film.Can effectively reduce
cover with paint, lacquer, colour wash, etc.liquid
surface tension, improve it
levelling propertywith a class material of homogeneity, can improve and cover with paint, lacquer, colour wash, etc. liquid
perviousness, the possibility producing spot and spot when brushing can be reduced, increase spreadability, make film forming even, natural.
Wetting agent adopts non-ionic wetting agent, mainly containing simple function group, oleoyl alkylene oxide block multipolymer, to color stuffing dissemination, and improves color developing.
Defoamer is the one in non-ionic type defoamer, molecular antifoaming agent, has good consistency and can principal characteristic.
Further, composed of the following components by weight: epoxy modified acrylic resin part 88-92 part, film coalescence aid 2.0-3.0 part, flow agent 0.7-1.2 part, dispersion agent 0.3-0.4 part, wetting agent 0.5-0.65 part, defoamer 1.0-1.1 part, 1250 order talcum powder 18-23 parts, thickening material 2.5-3.0 part, sterilant 4-6 part, pH adjusting agent 0.6-0.7 part, water 40-55 part.
Further, composed of the following components by weight: epoxy modified acrylic resin part 90 parts, film coalescence aid 2.5 parts, flow agent 1.1 parts, dispersion agent 0.35 part, wetting agent 0.6 part, defoamer 1.0 parts, 1250 order talcum powder 22 parts, thickening material 2.8 parts, 5 parts, sterilant, pH adjusting agent 0.65 part, 50 parts, water.
Further, described film coalescence aid is one in dipropylene and dipropylene glycol methyl ether or two kinds of mixing arbitrarily.Film coalescence aid contributes to film forming matter film forming at low temperatures.
Further, flow agent is polyether polyester modified organic silicon oxygen alkane flow agent, be greatly improved by the consistency of polyethers, polyester modification siloxanes and resin, reduce surface tension, the effect of the ability that control surface flows, the slip that increases, nonshrink hole, antiblocking is also all fine.
Further, described sterilant adopts not containing the isothiazolinone disinfecting agent of VOC, has thermotolerance, plays sterilization and anticorrosion effect simultaneously.
The present invention also provides a kind of preparation method of anaglyphy paint, specifically comprises the following steps:
A. for subsequent use by above-mentioned formula feeding;
B. in mixing machine, add water, then add sterilant, wetting agent, dispersion agent and flow agent successively in water, with the speed of 600 revs/min DEG C blending dispersion 6 minutes;
C. in described dispersion liquid, epoxy modified acrylic resin, film coalescence aid, defoamer and talcum powder is added successively, with the speed of 1500 revs/min DEG C blending dispersion 10 minutes;
D. in described dispersion liquid, add thickening material and pH adjusting agent, with the speed of 800 revs/min DEG C blending dispersion 5 minutes, the pH value range of described dispersion liquid is adjusted to 8-8.5.
Beneficial effect of the present invention: the anaglyphy paint obtained by special formulation and preparation method, not only there is existing textured paint there is waterproof, dust-proof, the feature of good flame retardation effect, also there is lower free formaldehyde content, paint film is full, and strong through spray gun spraying artistic feeling, other performances meet relevant specification of country.
Embodiment
Embodiment 1
A kind of anaglyphy paint of the present invention, comprise epoxy modified acrylic resin 85Kg, film coalescence aid 3.5Kg, flow agent 0.6Kg, dispersion agent 0.2Kg, wetting agent 0.4Kg, defoamer 0.8Kg, 1250 order talcum powder 15Kg, thickening material 2.0Kg, sterilant 3Kg, pH adjusting agent 0.5Kg, water 40Kg, described epoxy modified acrylic resin is composed of the following components by weight: E-44 epoxy resin 40Kg, methyl methacrylate 60Kg, vinylformic acid 5Kg, Octyl acrylate 30Kg, vinylbenzene 10Kg, Propylene glycol monoacrylate 10Kg, trimethyol propane triacrylate 2Kg, benzoyl peroxide 2Kg, solidifying agent 3Kg, the preparation method of described epoxy modified acrylic resin: for subsequent use by described formula feeding, E-44 epoxy resin and solidifying agent are added in reactor successively, with 600 revs/min of blending dispersion 3 minutes, heating, in reactor, vinylformic acid is dripped when temperature is added to 70 DEG C, again heat, when temperature is added to 85 DEG C, reactor adds methyl methacrylate after reacting 1 hour, vinylformic acid, Octyl acrylate, vinylbenzene, Propylene glycol monoacrylate, the mixture of trimethyol propane triacrylate and benzoyl peroxide, reactor reaction 2-3 hour, be cooled to room temperature.Epoxy resin makes a general reference in the molecular structure containing two or more epoxy group(ing), and with aliphatics, the organic compound such as aromatic series are a class thermosetting resin of skeleton.Because epoxy group(ing), ehter bond, hydroxyl and the phenyl ring hungry E Gudeng feature group contained in epoxy resin makes epoxy resin have excellent sticking power and good resistance to chemical corrosion.Epoxy modified acrylic resin introduces propenyl unsaturated double-bond at the two ends of epoxy molecule chain, then with other monomer copolymerizations, make the various premium propertiess of epoxy resin, adhesive power be strong, molding shrinkage is low, chemical stability is good, electrical insulating property and Heat stability is good etc.Fully played in acrylic resin, over-all properties respectively gets the chief, its dryness, plentiful DEG C, gloss, the over-all properties such as hard DEG C be better than general acrylic resin.Sterilant adopts not containing the isothiazolinone disinfecting agent of VOC.Film coalescence aid is one in dipropylene and dipropylene glycol methyl ether or two kinds of mixing arbitrarily.Film coalescence aid contributes to film forming matter film forming at low temperatures.Film coalescence aid also can adopt Lauryl Alcohol ester.
A preparation method for anaglyphy paint, for subsequent use by above-mentioned formula feeding, first in mixing machine, adding water, then adding isothiazolinone disinfecting agent, wetting agent, dispersion agent and flow agent successively in water, with the speed of 600 revs/min DEG C blending dispersion 6 minutes; Epoxy modified acrylic resin, film coalescence aid, defoamer and 1250 order talcum powder are added successively, with the speed of 1500 revs/min DEG C blending dispersion 10 minutes in described dispersion liquid; In described dispersion liquid, add thickening material and pH adjusting agent, with the speed of 800 revs/min DEG C blending dispersion 5 minutes, the pH value range of described dispersion liquid is adjusted to 8-8.5.
Embodiment 2
A kind of anaglyphy paint of the present invention, comprise epoxy modified acrylic resin 95Kg, film coalescence aid 1.5Kg, flow agent 1.5Kg, dispersion agent 0.5Kg, wetting agent 0.7Kg, defoamer 1Kg, 1250 order talcum powder 23Kg, thickening material 3.5Kg, sterilant 8Kg, pH adjusting agent 0.8Kg, water 40Kg, above-mentioned epoxy modified acrylic resin is composed of the following components by weight: E-44 epoxy resin 50Kg, methyl methacrylate 65Kg, vinylformic acid 12Kg, Octyl acrylate 38Kg, vinylbenzene 15Kg, Propylene glycol monoacrylate 15Kg, trimethyol propane triacrylate 5Kg, benzoyl peroxide 4Kg, solidifying agent 5Kg, the preparation method of epoxy modified acrylic resin is with embodiment 1.
The preparation method of above-mentioned anaglyphy paint is with embodiment 1.
Embodiment 3
A kind of anaglyphy paint of the present invention, comprise epoxy modified acrylic resin 90Kg, film coalescence aid 2.5Kg, flow agent 1.1Kg, dispersion agent 0.35Kg, wetting agent 0.6Kg, defoamer 1.2Kg, 1250 order talcum powder 25Kg, thickening material 2.8Kg, sterilant 5Kg, pH adjusting agent 0.65Kg, water 50Kg, above-mentioned epoxy modified acrylic resin is composed of the following components by weight: E-44 epoxy resin 55Kg, methyl methacrylate 77Kg, vinylformic acid 8Kg, Octyl acrylate 35Kg, vinylbenzene 13Kg, Propylene glycol monoacrylate 12Kg, trimethyol propane triacrylate 3Kg, benzoyl peroxide 5Kg, solidifying agent 6Kg.The preparation method of epoxy modified acrylic resin is with embodiment 1.
The preparation method of above-mentioned anaglyphy paint is with embodiment 1.
In above-mentioned three embodiments, defoamer adopts Dongguan City Gauss to enter the product of Fine Chemical Co., Ltd, and product type is GSK-713 defoamer, and pH adjusting agent adopts the product of the credible Chemical Co., Ltd. of Yixing City, and product type is the pH adjusting agent of KX-pH.
By carrying out Performance Detection to above-described embodiment gained anaglyphy paint, property indices is in table 1:
| Performance index | Embodiment 1 | Embodiment 2 | Embodiment 3 | Technical requirements |
| Condition in container | Outward appearance is plentiful, good fluidity | Outward appearance is plentiful, good fluidity | Outward appearance is plentiful, good fluidity | Without lump, in uniform state after stirring |
| Time of drying/h | 1.5 | 1.5 | 1 | ≤2 |
| Appearance of film | Accessible | Accessible | Accessible | Brushing twice are accessible |
| Brushing resistance/time | ＞380 | ＞380 | ＞400 | ≥200 |
| Low-temperature stability | Never degenerate | Never degenerate | Never degenerate | Never degenerate |
| Free formaldehyde/g/Kg | 0.006 | 0.005 | 0.005 | ≤0.1 |
| Water tolerance (96h) | Without exception | Without exception | Without exception | Without exception |
Table 1
As can be seen from Table 1, specifically filled a prescription by the present invention and the anaglyphy paint that obtains of preparation method, have lower free formaldehyde content, environmental protection, good waterproof performance, paint film is full, and strong through spray gun spraying artistic feeling, other performances meet relevant specification of country.
What finally illustrate is, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted, although with reference to preferred embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that, can modify to technical scheme of the present invention or equivalent replacement, and not departing from aim and the scope of technical solution of the present invention, it all should be encompassed in the middle of right of the present invention.
Claims (7)
1. an anaglyphy paint, it is characterized in that: composed of the following components by weight: epoxy modified acrylic resin 85-95 part, film coalescence aid 1.5-3.5 part, flow agent 0.5-1.5 part, dispersion agent 0.2-0.5 part, wetting agent 0.4-0.7 part, defoamer 0.8-1.2 part, 1250 order talcum powder 15-25 parts, thickening material 2.0-3.5 part, sterilant 3-8 part, pH adjusting agent 0.5-0.8 part, water 35-65 part; Described epoxy modified acrylic resin is composed of the following components by weight: E-44 epoxy resin 40-55 part, methyl methacrylate 60-77 part, vinylformic acid 5-12 part, Octyl acrylate 30-38 part, vinylbenzene 10-15 part, Propylene glycol monoacrylate 10-15 part, trimethyol propane triacrylate 2-5 part, benzoyl peroxide 2-5 part, solidifying agent 3-6 part, the preparation method of described epoxy modified acrylic resin: for subsequent use by described formula feeding; E-44 epoxy resin and solidifying agent are added successively in reactor, with 600 revs/min of blending dispersion 3 minutes, heating, dripped vinylformic acid when temperature is added to 70 DEG C in reactor; Again heat, when temperature is added to 85 DEG C, reactor adds the mixture of methyl methacrylate, vinylformic acid, Octyl acrylate, vinylbenzene, Propylene glycol monoacrylate, trimethyol propane triacrylate and benzoyl peroxide after reacting 1 hour, reactor reaction 2-3 hour, is cooled to room temperature.
2. anaglyphy paint as claimed in claim 1, it is characterized in that: composed of the following components by weight: epoxy modified acrylic resin 88-92 part, film coalescence aid 2.0-3.0 part, flow agent 0.7-1.2 part, dispersion agent 0.3-0.4 part, wetting agent 0.5-0.65 part, defoamer 1.0-1.1 part, 1250 order talcum powder 18-23 parts, thickening material 2.5-3.0 part, sterilant 4-6 part, pH adjusting agent 0.6-0.7 part, water 40-55 part.
3. anaglyphy paint as claimed in claim 1, it is characterized in that: composed of the following components by weight: epoxy modified acrylic resin 90 parts, film coalescence aid 2.5 parts, flow agent 1.1 parts, dispersion agent 0.35 part, wetting agent 0.6 part, defoamer 1.0 parts, 1250 order talcum powder 22 parts, thickening material 2.8 parts, 5 parts, sterilant, pH adjusting agent 0.65 part, 50 parts, water.
4. anaglyphy paint as described in one of claim 1-3, is characterized in that: described film coalescence aid is one in dipropylene and dipropylene glycol methyl ether or two kinds of mixing arbitrarily.
5. the anaglyphy paint as described in one of claim 1-3, is characterized in that: described flow agent is polyether polyester modified organic silicon oxygen alkane flow agent.
6. the anaglyphy paint as described in one of claim 1-3, is characterized in that: described sterilant adopts not containing the isothiazolinone disinfecting agent of VOC.
7. a preparation method for anaglyphy paint, is characterized in that:
A. for subsequent use by described formula feeding;
B. in mixing machine, add water, then add sterilant, wetting agent, dispersion agent and flow agent successively in water, with the speed of 600 revs/min DEG C blending dispersion 6 minutes;
C. in described dispersion liquid, epoxy modified acrylic resin, film coalescence aid, defoamer and talcum powder is added successively, with the speed of 1500 revs/min DEG C blending dispersion 10 minutes;
D. in described dispersion liquid, add thickening material and pH adjusting agent, with the speed of 800 revs/min DEG C blending dispersion 5 minutes, the pH value range of described dispersion liquid is adjusted to 8-8.5.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107057512A (en) * | 2017-01-03 | 2017-08-18 | 醴陵市天鑫瓷业有限公司 | Pearl fruit glaze of over-glaze decoration and preparation method thereof |
| CN107629521A (en) * | 2017-09-21 | 2018-01-26 | 苏州振振好新型建材科技有限公司 | A kind of reflective anaglyphy paint |
| CN108359356A (en) * | 2018-03-23 | 2018-08-03 | 白山市和硅藻科技有限公司 | A kind of diatom art paint coating containing inorganic salts |
| CN108676478A (en) * | 2018-06-14 | 2018-10-19 | 薛方德 | A kind of abrasion resistance textured paint and preparation method thereof |
| CN109053116A (en) * | 2018-10-23 | 2018-12-21 | 熊敏 | A kind of wall surface spraying raw material and spraying method |
| CN110145082A (en) * | 2019-06-03 | 2019-08-20 | 安徽天地间文化产业有限公司 | A kind of wall relief easy making engineering method |
| CN113861809A (en) * | 2021-11-24 | 2021-12-31 | 泉州加士涂环保科技有限公司 | Environment-friendly artistic paint and preparation method thereof |
| CN116515396A (en) * | 2023-06-05 | 2023-08-01 | 广州励宝新材料科技有限公司 | High-fullness water-based embossment sound box paint and preparation method thereof |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107057512A (en) * | 2017-01-03 | 2017-08-18 | 醴陵市天鑫瓷业有限公司 | Pearl fruit glaze of over-glaze decoration and preparation method thereof |
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| CN107629521A (en) * | 2017-09-21 | 2018-01-26 | 苏州振振好新型建材科技有限公司 | A kind of reflective anaglyphy paint |
| CN108359356A (en) * | 2018-03-23 | 2018-08-03 | 白山市和硅藻科技有限公司 | A kind of diatom art paint coating containing inorganic salts |
| CN108676478A (en) * | 2018-06-14 | 2018-10-19 | 薛方德 | A kind of abrasion resistance textured paint and preparation method thereof |
| CN109053116A (en) * | 2018-10-23 | 2018-12-21 | 熊敏 | A kind of wall surface spraying raw material and spraying method |
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| CN116515396A (en) * | 2023-06-05 | 2023-08-01 | 广州励宝新材料科技有限公司 | High-fullness water-based embossment sound box paint and preparation method thereof |
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