CN105136889A - 一种石墨烯葡萄糖传感器 - Google Patents
一种石墨烯葡萄糖传感器 Download PDFInfo
- Publication number
- CN105136889A CN105136889A CN201510660526.7A CN201510660526A CN105136889A CN 105136889 A CN105136889 A CN 105136889A CN 201510660526 A CN201510660526 A CN 201510660526A CN 105136889 A CN105136889 A CN 105136889A
- Authority
- CN
- China
- Prior art keywords
- electrode
- graphene
- glucose sensor
- polyaniline
- substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 31
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 title claims abstract description 28
- 239000008103 glucose Substances 0.000 title claims abstract description 28
- 239000000758 substrate Substances 0.000 claims abstract description 23
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 17
- 229920000767 polyaniline Polymers 0.000 claims abstract description 12
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 9
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 9
- 108010015776 Glucose oxidase Proteins 0.000 claims abstract description 8
- 239000004366 Glucose oxidase Substances 0.000 claims abstract description 8
- 229940116332 glucose oxidase Drugs 0.000 claims abstract description 8
- 235000019420 glucose oxidase Nutrition 0.000 claims abstract description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 24
- 238000003756 stirring Methods 0.000 claims description 18
- 229910052697 platinum Inorganic materials 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- -1 acryl Chemical group 0.000 claims description 7
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical group Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 239000004642 Polyimide Substances 0.000 claims description 3
- 229920001721 polyimide Polymers 0.000 claims description 3
- 229920000193 polymethacrylate Polymers 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 230000004044 response Effects 0.000 abstract description 4
- 238000001514 detection method Methods 0.000 abstract description 3
- 230000021523 carboxylation Effects 0.000 abstract 1
- 238000006473 carboxylation reaction Methods 0.000 abstract 1
- 230000035945 sensitivity Effects 0.000 abstract 1
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 206010012601 diabetes mellitus Diseases 0.000 description 2
- 208000024172 Cardiovascular disease Diseases 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000003745 diagnosis Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
Landscapes
- Carbon And Carbon Compounds (AREA)
- Measurement Of The Respiration, Hearing Ability, Form, And Blood Characteristics Of Living Organisms (AREA)
- Investigating Or Analysing Biological Materials (AREA)
- Measuring Or Testing Involving Enzymes Or Micro-Organisms (AREA)
Abstract
本发明公开了一种石墨烯葡萄糖传感器，包括基板、配置在基板上的电极***和配置在电极***上的试剂层；所述电极***包括工作电极、对电极和参比电极；所述试剂层包括聚苯胺改性石墨烯、羧基化碳纳米管和葡萄糖氧化酶。本发明提出的一种石墨烯葡萄糖传感器的，其稳定好，用于葡萄糖的检测选择性好，响应时间短，灵敏度高。
Description
技术领域
本发明涉及传感器技术领域，尤其涉及一种石墨烯葡萄糖传感器。
背景技术
糖尿病是仅次于癌症、心血管病的第三大危险疾病，是世界性的多发病和常见病。因此对人体血液中葡萄糖含量的准确快速的测定，对于糖尿病的前期诊断和治疗有着十分重要的意义。葡萄糖生物传感器是一种能够简单快捷的检测人体血液中葡萄糖浓度的方法，越来越受到科研工作者的广泛关注。但是，现有的葡萄糖传感器存在响应时间长，重现性差，选择性及稳定性不是很好的缺陷，不能满足现在社会发展的需要。
发明内容
本发明的目的是为了解决现有技术中存在的缺点，而提出的一种石墨烯葡萄糖传感器，其稳定好，用于葡萄糖的检测选择性好，响应时间短，灵敏度高。
为了实现上述目的，本发明采用了如下技术方案：
一种石墨烯葡萄糖传感器，包括基板、配置在基板上的电极***和配置在电极***上的试剂层；所述电极***包括工作电极、对电极和参比电极；所述试剂层包括聚苯胺改性石墨烯、羧基化碳纳米管和葡萄糖氧化酶。
优选地，所述工作电极为玻碳电极、铂电极、金电极、银电极、镍电极、钯电极中的一种。
优选地，所述参比电极为饱和甘汞电极。
优选地，所述对电极为铂电极。
优选地，所述基板的材料为聚甲基丙烯酸酯、丙烯酸树脂、聚苯乙烯、聚丙烯、聚乙烯、聚酰亚胺中的一种。
优选地，所述聚苯胺改性石墨烯按照以下工艺进行制备：按重量份将10-20份聚苯胺加入50-100份浓度为0.5-1mg/mL的氧化石墨烯水溶液中搅拌均匀，然后加入2-10份氢氧化钠，在70-80℃下搅拌10-20h，离心后得到所述聚苯胺改性石墨烯。
优选地，所述聚苯胺改性石墨烯按照以下工艺进行制备：按重量份将15份聚苯胺加入80份浓度为0.7mg/mL的氧化石墨烯水溶液中搅拌均匀，然后加入8份氢氧化钠，在76℃下搅拌15h，离心后得到所述聚苯胺改性石墨烯。
本发明中，利用了聚苯胺对氧化石墨烯进行改性得到了聚苯胺改性石墨烯，从而将聚苯胺引入传感器中，与氧化石墨烯和羧基化碳纳米管联用，促进了电子传输，得到的葡萄糖传感器稳定性好，用于葡萄糖的检测选择性好，响应时间短，灵敏度高，并且可多次使用。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白，以下结合具体实施例，对本发明进行进一步详细说明。应当理解，此处所描述的具体实施例仅仅用以解释本发明，并不用于限定本发明。
实施例1
一种石墨烯葡萄糖传感器，包括基板、配置在基板上的电极***和配置在电极***上的试剂层；所述电极***包括工作电极、对电极和参比电极；所述试剂层包括聚苯胺改性石墨烯、羧基化碳纳米管和葡萄糖氧化酶；
其中，所述工作电极为铂电极；所述参比电极为饱和甘汞电极，所述对电极为铂电极；所述基板的材料为聚丙烯；所述聚苯胺改性石墨烯按照以下工艺进行制备：按重量份将20份聚苯胺加入50份浓度为1mg/mL的氧化石墨烯水溶液中搅拌均匀，然后加入2份氢氧化钠，在70℃下搅拌20h，离心后得到所述聚苯胺改性石墨烯。
实施例2
一种石墨烯葡萄糖传感器，包括基板、配置在基板上的电极***和配置在电极***上的试剂层；所述电极***包括工作电极、对电极和参比电极；所述试剂层包括聚苯胺改性石墨烯、羧基化碳纳米管和葡萄糖氧化酶；
其中，所述工作电极为铂电极；所述参比电极为饱和甘汞电极，所述对电极为铂电极；所述基板的材料为聚丙烯；所述聚苯胺改性石墨烯按照以下工艺进行制备：按重量份将10份聚苯胺加入100份浓度为0.5mg/mL的氧化石墨烯水溶液中搅拌均匀，然后加入10份氢氧化钠，在80℃下搅拌10h，离心后得到所述聚苯胺改性石墨烯。
实施例3
一种石墨烯葡萄糖传感器，包括基板、配置在基板上的电极***和配置在电极***上的试剂层；所述电极***包括工作电极、对电极和参比电极；所述试剂层包括聚苯胺改性石墨烯、羧基化碳纳米管和葡萄糖氧化酶；
其中，所述工作电极为铂电极；所述参比电极为饱和甘汞电极，所述对电极为铂电极；所述基板的材料为聚酰亚胺；所述聚苯胺改性石墨烯按照以下工艺进行制备：按重量份将18份聚苯胺加入65份浓度为0.9mg/mL的氧化石墨烯水溶液中搅拌均匀，然后加入3份氢氧化钠，在73℃下搅拌13h，离心后得到所述聚苯胺改性石墨烯。
实施例4
一种石墨烯葡萄糖传感器，包括基板、配置在基板上的电极***和配置在电极***上的试剂层；所述电极***包括工作电极、对电极和参比电极；所述试剂层包括聚苯胺改性石墨烯、羧基化碳纳米管和葡萄糖氧化酶；
其中，所述工作电极为玻碳电极；所述参比电极为饱和甘汞电极，所述对电极为铂电极；所述基板的材料为丙烯酸树脂；所述聚苯胺改性石墨烯按照以下工艺进行制备：按重量份将12份聚苯胺加入80份浓度为0.6mg/mL的氧化石墨烯水溶液中搅拌均匀，然后加入8份氢氧化钠，在73℃下搅拌17h，离心后得到所述聚苯胺改性石墨烯。
实施例5
一种石墨烯葡萄糖传感器，包括基板、配置在基板上的电极***和配置在电极***上的试剂层；所述电极***包括工作电极、对电极和参比电极；所述试剂层包括聚苯胺改性石墨烯、羧基化碳纳米管和葡萄糖氧化酶；
其中，所述工作电极为玻碳电极；所述参比电极为饱和甘汞电极，所述对电极为铂电极；所述基板的材料为聚甲基丙烯酸酯；所述聚苯胺改性石墨烯按照以下工艺进行制备：按重量份将15份聚苯胺加入80份浓度为0.7mg/mL的氧化石墨烯水溶液中搅拌均匀，然后加入8份氢氧化钠，在76℃下搅拌15h，离心后得到所述聚苯胺改性石墨烯。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。
Claims (7)
1.一种石墨烯葡萄糖传感器，其特征在于，包括基板、配置在基板上的电极***和配置在电极***上的试剂层；所述电极***包括工作电极、对电极和参比电极；所述试剂层包括聚苯胺改性石墨烯、羧基化碳纳米管和葡萄糖氧化酶。
2.根据权利要求1所述石墨烯葡萄糖传感器，其特征在于，所述工作电极为玻碳电极、铂电极、金电极、银电极、镍电极、钯电极中的一种。
3.根据权利要求1所述石墨烯葡萄糖传感器，其特征在于，所述参比电极为饱和甘汞电极。
4.根据权利要求1所述石墨烯葡萄糖传感器，其特征在于，所述对电极为铂电极。
5.根据权利要求1所述石墨烯葡萄糖传感器，其特征在于，所述基板的材料为聚甲基丙烯酸酯、丙烯酸树脂、聚苯乙烯、聚丙烯、聚乙烯、聚酰亚胺中的一种。
6.根据权利要求1所述石墨烯葡萄糖传感器，其特征在于，所述聚苯胺改性石墨烯按照以下工艺进行制备：按重量份将10-20份聚苯胺加入50-100份浓度为0.5-1mg/mL的氧化石墨烯水溶液中搅拌均匀，然后加入2-10份氢氧化钠，在70-80℃下搅拌10-20h，离心后得到所述聚苯胺改性石墨烯。
7.根据权利要求1-6中任一项所述石墨烯葡萄糖传感器，其特征在于，所述聚苯胺改性石墨烯按照以下工艺进行制备：按重量份将15份聚苯胺加入80份浓度为0.7mg/mL的氧化石墨烯水溶液中搅拌均匀，然后加入8份氢氧化钠，在76℃下搅拌15h，离心后得到所述聚苯胺改性石墨烯。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510660526.7A CN105136889B (zh) | 2015-10-15 | 2015-10-15 | 一种石墨烯葡萄糖传感器 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510660526.7A CN105136889B (zh) | 2015-10-15 | 2015-10-15 | 一种石墨烯葡萄糖传感器 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105136889A true CN105136889A (zh) | 2015-12-09 |
| CN105136889B CN105136889B (zh) | 2018-10-23 |
Family
ID=54722314
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510660526.7A Active CN105136889B (zh) | 2015-10-15 | 2015-10-15 | 一种石墨烯葡萄糖传感器 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105136889B (zh) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106923842A (zh) * | 2017-03-23 | 2017-07-07 | 刘慧� | 一种血糖监测*** |
| CN108490055A (zh) * | 2018-03-22 | 2018-09-04 | 浙江工贸职业技术学院 | 一种基于氧化石墨烯的高生物相容性葡萄糖生物传感器及其制备方法 |
| CN110231336A (zh) * | 2019-06-18 | 2019-09-13 | 济南大学 | 一种石墨烯/聚苯胺纳米线阵列免疫传感器的制备方法及应用 |
| RU2811305C1 (ru) * | 2023-04-11 | 2024-01-11 | Федеральное государственное бюджетное учреждение науки Институт физики полупроводников им. А.В. Ржанова Сибирского отделения Российской академии наук (ИФП СО РАН) | Носимый на теле сенсорный узел для определения содержания глюкозы в крови |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101781459A (zh) * | 2010-02-04 | 2010-07-21 | 南京理工大学 | 一种石墨烯/聚苯胺导电复合材料及其制备方法 |
| US20140066736A1 (en) * | 2006-03-31 | 2014-03-06 | Abbott Diabetes Care Inc. | Analyte Sensor Calibration Management |
| WO2014110492A2 (en) * | 2013-01-11 | 2014-07-17 | Northeastern University | Saliva glucose monitoring system |
| CN103995033A (zh) * | 2014-05-29 | 2014-08-20 | 天津大学 | 基于石墨烯和纳米颗粒修饰的电化学葡萄糖传感器及应用 |
-
2015
- 2015-10-15 CN CN201510660526.7A patent/CN105136889B/zh active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140066736A1 (en) * | 2006-03-31 | 2014-03-06 | Abbott Diabetes Care Inc. | Analyte Sensor Calibration Management |
| CN101781459A (zh) * | 2010-02-04 | 2010-07-21 | 南京理工大学 | 一种石墨烯/聚苯胺导电复合材料及其制备方法 |
| WO2014110492A2 (en) * | 2013-01-11 | 2014-07-17 | Northeastern University | Saliva glucose monitoring system |
| CN103995033A (zh) * | 2014-05-29 | 2014-08-20 | 天津大学 | 基于石墨烯和纳米颗粒修饰的电化学葡萄糖传感器及应用 |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106923842A (zh) * | 2017-03-23 | 2017-07-07 | 刘慧� | 一种血糖监测*** |
| CN106923842B (zh) * | 2017-03-23 | 2020-07-07 | 湖南众连康医疗科技有限公司 | 一种血糖监测*** |
| CN108490055A (zh) * | 2018-03-22 | 2018-09-04 | 浙江工贸职业技术学院 | 一种基于氧化石墨烯的高生物相容性葡萄糖生物传感器及其制备方法 |
| CN110231336A (zh) * | 2019-06-18 | 2019-09-13 | 济南大学 | 一种石墨烯/聚苯胺纳米线阵列免疫传感器的制备方法及应用 |
| CN110231336B (zh) * | 2019-06-18 | 2021-09-28 | 济南大学 | 一种石墨烯/聚苯胺纳米线阵列免疫传感器的制备方法 |
| RU2811305C1 (ru) * | 2023-04-11 | 2024-01-11 | Федеральное государственное бюджетное учреждение науки Институт физики полупроводников им. А.В. Ржанова Сибирского отделения Российской академии наук (ИФП СО РАН) | Носимый на теле сенсорный узел для определения содержания глюкозы в крови |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105136889B (zh) | 2018-10-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Elfadil et al. | Molecularly imprinted polymers combined with electrochemical sensors for food contaminants analysis | |
| Kim et al. | Disposable amperometric glycated hemoglobin sensor for the finger prick blood test | |
| Hasseb et al. | Application of molecularly imprinted polymers for electrochemical detection of some important biomedical markers and pathogens | |
| Pei et al. | Disposable copper-based electrochemical sensor for anodic stripping voltammetry | |
| Lusi et al. | Innovative electrochemical approach for an early detection of microRNAs | |
| CN104459124B (zh) | 一种基于HS-β-CD-Ag-GOD共轭物的电化学免疫传感器的制备方法及应用 | |
| Tamboli et al. | Hybrid synthetic receptors on MOSFET devices for detection of prostate specific antigen in human plasma | |
| Yan et al. | A selective strategy for determination of ascorbic acid based on molecular imprinted copolymer of o-phenylenediamine and pyrrole | |
| Saleem et al. | Antibody functionalized graphene biosensor for label-free electrochemical immunosensing of fibrinogen, an indicator of trauma induced coagulopathy | |
| CN105067690B (zh) | 一种基于二硫化钼复合材料构建的***电化学免疫传感器的制备方法 | |
| Mazlan et al. | A new laccase based biosensor for tartrazine | |
| CN103713026A (zh) | 一种检测孔雀石绿的核酸适配体电化学生物传感器的制备方法及应用 | |
| Patra et al. | Imprinted ZnO nanostructure-based electrochemical sensing of calcitonin: a clinical marker for medullary thyroid carcinoma. | |
| Pandey et al. | A novel dual imprinted conducting nanocubes based flexible sensor for simultaneous detection of hemoglobin and glycated haemoglobin in gestational diabetes mellitus patients | |
| Kubiak et al. | Application of molecularly imprinted polymers for bisphenols extraction from food samples–A review | |
| CN104330448A (zh) | 一种高灵敏度电极式尿酸试纸及其制作方法 | |
| CN105136889A (zh) | 一种石墨烯葡萄糖传感器 | |
| CN104502432A (zh) | 一种敏感膜及含有该敏感膜的丝网印刷电极及其应用 | |
| Mukasa et al. | A Computationally Assisted Approach for Designing Wearable Biosensors toward Non‐Invasive Personalized Molecular Analysis | |
| Hammond et al. | Cysteine-cystine redox cycling in a gold–gold dual-plate generator-collector microtrench sensor | |
| Adane et al. | Highly sensitive and selective electrochemical sensor for the simultaneous determination of tinidazole and chloramphenicol in food samples (egg, honey and milk) | |
| Kim et al. | Reusable urine glucose sensor based on functionalized graphene oxide conjugated Au electrode with protective layers | |
| Mugo et al. | A molecularly imprinted electrochemical microneedle sensor for multiplexed metabolites detection in human sweat | |
| Deng et al. | Lab on smartphone with interfaced electrochemical chips for on-site gender verification | |
| Jaffrezic-Renault et al. | New trends in the electrochemical detection of endocrine disruptors in complex media |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180913 Address after: 318050 Licun, Luqiao, Taizhou, Zhejiang Province, 38 Applicant after: Li Youhong Address before: 075000 air force complex, 1 Lin Yuan Road, Qiaodong District, Zhangjiakou, Hebei Applicant before: Tian Ye |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191113 Address after: Room 301-15, building 1, No.111, Guigu Er Road, Luoxing street, Jiashan County, Jiaxing City, Zhejiang Province Patentee after: Jiashan chuangyue Intellectual Property Service Co.,Ltd. Address before: 318050 Licun, Luqiao, Taizhou, Zhejiang Province, 38 Patentee before: Li Youhong |
|
| TR01 | Transfer of patent right | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20151209 Assignee: Jiashan Jiuze Intellectual Property Service Co., Ltd. Assignor: Jiashan chuangyue Intellectual Property Service Co.,Ltd. Contract record no.: X2022330000346 Denomination of invention: A graphene glucose sensor Granted publication date: 20181023 License type: Common License Record date: 20220728 |
|
| EE01 | Entry into force of recordation of patent licensing contract | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20231010 Address after: Room 401-89, Building 1, No. 111 Guigu Second Road, Luoxing Street, Jiashan County, Jiaxing City, Zhejiang Province, 314100 (Residence application) Patentee after: Jiashan Luoxing Venture Capital Co.,Ltd. Address before: Room 301-15, building 1, No. 111, Guigu 2nd Road, Luoxing street, Jiashan County, Jiaxing City, Zhejiang Province Patentee before: Jiashan chuangyue Intellectual Property Service Co.,Ltd. |
|
| TR01 | Transfer of patent right |