CN105063995B - 一种增强天然蛋白纤维拉伸力学性能的方法 - Google Patents
一种增强天然蛋白纤维拉伸力学性能的方法 Download PDFInfo
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- CN105063995B CN105063995B CN201510476570.2A CN201510476570A CN105063995B CN 105063995 B CN105063995 B CN 105063995B CN 201510476570 A CN201510476570 A CN 201510476570A CN 105063995 B CN105063995 B CN 105063995B
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- natural protein
- protein fiber
- fiber
- ammonium
- ammonium salt
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- 239000000835 fiber Substances 0.000 title claims abstract description 254
- 102000004169 proteins and genes Human genes 0.000 title claims abstract description 160
- 108090000623 proteins and genes Proteins 0.000 title claims abstract description 160
- 238000000034 method Methods 0.000 title claims abstract description 36
- 150000003863 ammonium salts Chemical class 0.000 claims abstract description 103
- 238000004140 cleaning Methods 0.000 claims abstract description 55
- 238000003780 insertion Methods 0.000 claims abstract description 33
- 230000037431 insertion Effects 0.000 claims abstract description 33
- 230000002708 enhancing effect Effects 0.000 claims abstract description 18
- 238000002360 preparation method Methods 0.000 claims abstract description 16
- 239000000243 solution Substances 0.000 claims description 55
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 54
- 210000002268 wool Anatomy 0.000 claims description 45
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 28
- 241000283973 Oryctolagus cuniculus Species 0.000 claims description 25
- 239000011259 mixed solution Substances 0.000 claims description 25
- 238000001035 drying Methods 0.000 claims description 21
- 239000004094 surface-active agent Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000008367 deionised water Substances 0.000 claims description 18
- 229910021641 deionized water Inorganic materials 0.000 claims description 18
- 238000007654 immersion Methods 0.000 claims description 15
- 206010042674 Swelling Diseases 0.000 claims description 14
- 230000008961 swelling Effects 0.000 claims description 14
- 238000013019 agitation Methods 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 11
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 9
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 9
- 239000001099 ammonium carbonate Substances 0.000 claims description 8
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 7
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 7
- -1 esters salt Chemical class 0.000 claims description 7
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims description 6
- 125000000129 anionic group Chemical group 0.000 claims description 6
- 239000002798 polar solvent Substances 0.000 claims description 6
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 4
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 4
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 4
- 235000019270 ammonium chloride Nutrition 0.000 claims description 4
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 4
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 4
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 4
- 235000019838 diammonium phosphate Nutrition 0.000 claims description 4
- WWILHZQYNPQALT-UHFFFAOYSA-N 2-methyl-2-morpholin-4-ylpropanal Chemical compound O=CC(C)(C)N1CCOCC1 WWILHZQYNPQALT-UHFFFAOYSA-N 0.000 claims description 3
- 239000004254 Ammonium phosphate Substances 0.000 claims description 3
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 3
- MHABMANUFPZXEB-UHFFFAOYSA-N O-demethyl-aloesaponarin I Natural products O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C MHABMANUFPZXEB-UHFFFAOYSA-N 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 3
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims description 3
- 229940113088 dimethylacetamide Drugs 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 3
- 238000002242 deionisation method Methods 0.000 claims 1
- SEGLCEQVOFDUPX-UHFFFAOYSA-N di-(2-ethylhexyl)phosphoric acid Chemical compound CCCCC(CC)COP(O)(=O)OCC(CC)CCCC SEGLCEQVOFDUPX-UHFFFAOYSA-N 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 239000004753 textile Substances 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 3
- 238000009434 installation Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000002105 nanoparticle Substances 0.000 description 11
- 239000003643 water by type Substances 0.000 description 10
- 210000004209 hair Anatomy 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 3
- 229920001872 Spider silk Polymers 0.000 description 3
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 3
- 150000003948 formamides Chemical class 0.000 description 3
- 235000019837 monoammonium phosphate Nutrition 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- 241000255789 Bombyx mori Species 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 241001494479 Pecora Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 150000003460 sulfonic acids Chemical class 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- BIGPRXCJEDHCLP-UHFFFAOYSA-N ammonium bisulfate Chemical class [NH4+].OS([O-])(=O)=O BIGPRXCJEDHCLP-UHFFFAOYSA-N 0.000 description 1
- PRKQVKDSMLBJBJ-UHFFFAOYSA-N ammonium carbonate Chemical class N.N.OC(O)=O PRKQVKDSMLBJBJ-UHFFFAOYSA-N 0.000 description 1
- 235000011162 ammonium carbonates Nutrition 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000005837 radical ions Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
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- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
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CN106380701A (zh) * | 2016-08-28 | 2017-02-08 | 安徽省华晟塑胶股份有限公司 | 一种高机械强度汽车抓手 |
CN106380656A (zh) * | 2016-08-28 | 2017-02-08 | 安徽省华晟塑胶股份有限公司 | 一种汽车车顶支架 |
CN108178589A (zh) * | 2017-12-30 | 2018-06-19 | 安徽城洁环境科技有限公司 | 一种耐冲击透水砖 |
CN108660748B (zh) * | 2018-04-26 | 2020-05-26 | 海斯摩尔生物科技有限公司 | 一种溶胀状态下拉伸增强壳聚糖纤维的方法 |
CN108642873B (zh) * | 2018-04-26 | 2020-05-26 | 海斯摩尔生物科技有限公司 | 一种在溶胀状态下交联拉伸增强壳聚糖纤维的方法 |
CN108893997A (zh) * | 2018-06-01 | 2018-11-27 | 苏州先蚕丝绸有限公司 | 一种溶胀天然蚕丝纤维材料的制备方法 |
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JPH086250B2 (ja) * | 1988-05-02 | 1996-01-24 | 宇部興産株式会社 | ハイブリッド繊維の製造方法 |
FR2691171B1 (fr) * | 1992-05-15 | 1994-12-23 | Vetrotex France Sa | Procédé de fabrication d'un fil continu par étirage mécanique et produits en résultant. |
CN1176263C (zh) * | 2001-05-11 | 2004-11-17 | 东华大学 | 一种用于羊毛拉细定型的化学工艺 |
CN1164826C (zh) * | 2001-05-11 | 2004-09-01 | 东华大学 | 用于羊毛拉伸的化学处理剂 |
CN100396831C (zh) * | 2003-01-06 | 2008-06-25 | 仓敷纺绩株式会社 | 细长化兽毛纤维的制造方法 |
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Inventor after: Liu Xin Inventor after: Zhang Ke Inventor after: Tang Yunrong Inventor after: Xu Weilin Inventor after: Song Baoxiang Inventor after: Wu Longtao Inventor after: Cao Genyang Inventor after: Li Wenbin Inventor after: Zhang Bowen Inventor after: Yang Jie Inventor before: Liu Xin Inventor before: Tang Yunrong Inventor before: Xu Weilin Inventor before: Cao Genyang Inventor before: Li Wenbin Inventor before: Zhang Bowen Inventor before: Yang Jie Inventor before: Zhang Ke |
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Address after: On the north side of Suqian province Jiangsu City Road 223800 Fudan Sucheng Economic Development Zone Applicant after: JIANGSU YIMAO FILTER CO., LTD. Address before: 223800 Jiangsu province moved north road, Xu Fudan Sucheng Economic Development Zone Applicant before: JIANGSU YIMAO FILTER CO., LTD. |
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Address after: 223800 north side of Fudan Road, Sucheng Economic Development Zone, Suqian City, Jiangsu Province Patentee after: Yimao Environmental Technology Co.,Ltd. Address before: 223800 north side of Fudan Road, Sucheng Economic Development Zone, Suqian City, Jiangsu Province Patentee before: JIANGSU YIMAO FILTER MATERIALS Co.,Ltd. |