CN105032474A - 一种裂解碳四馏分生产1-丁烯用负载型纳米金属催化剂 - Google Patents
一种裂解碳四馏分生产1-丁烯用负载型纳米金属催化剂 Download PDFInfo
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- CN105032474A CN105032474A CN201510270390.9A CN201510270390A CN105032474A CN 105032474 A CN105032474 A CN 105032474A CN 201510270390 A CN201510270390 A CN 201510270390A CN 105032474 A CN105032474 A CN 105032474A
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- 239000003054 catalyst Substances 0.000 title claims abstract description 34
- 238000005336 cracking Methods 0.000 title claims abstract description 20
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 15
- 239000002184 metal Substances 0.000 title claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 title abstract description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 title abstract 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000004927 clay Substances 0.000 claims abstract description 8
- 239000002808 molecular sieve Substances 0.000 claims abstract description 8
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 7
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000010941 cobalt Substances 0.000 claims abstract description 3
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 3
- 230000002860 competitive effect Effects 0.000 claims abstract description 3
- 239000000306 component Substances 0.000 claims abstract description 3
- 229910052742 iron Inorganic materials 0.000 claims abstract description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 3
- 239000011733 molybdenum Substances 0.000 claims abstract description 3
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 3
- 239000010937 tungsten Substances 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 13
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims description 13
- 238000002803 maceration Methods 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 238000005984 hydrogenation reaction Methods 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000001291 vacuum drying Methods 0.000 claims description 3
- -1 wash 3 times Substances 0.000 claims description 3
- 239000002156 adsorbate Substances 0.000 claims description 2
- 239000011230 binding agent Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 238000000926 separation method Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 238000006555 catalytic reaction Methods 0.000 abstract 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000003463 adsorbent Substances 0.000 abstract 1
- 238000011284 combination treatment Methods 0.000 abstract 1
- 238000007598 dipping method Methods 0.000 abstract 1
- 238000002604 ultrasonography Methods 0.000 abstract 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 5
- 239000006227 byproduct Substances 0.000 description 3
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 3
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000001994 activation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
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Abstract
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CN201510270390.9A CN105032474B (zh) | 2015-05-25 | 2015-05-25 | 一种裂解碳四馏分生产1‑丁烯用负载型纳米金属催化剂 |
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CN201510270390.9A CN105032474B (zh) | 2015-05-25 | 2015-05-25 | 一种裂解碳四馏分生产1‑丁烯用负载型纳米金属催化剂 |
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CN105032474A true CN105032474A (zh) | 2015-11-11 |
CN105032474B CN105032474B (zh) | 2018-01-12 |
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1352231A (zh) * | 2000-11-08 | 2002-06-05 | 中国石油化工股份有限公司 | 临氢降凝催化剂及其制备方法 |
CN1470614A (zh) * | 2003-07-01 | 2004-01-28 | 中国石油天然气集团公司 | 一种用于含烯烃石脑油加氢处理的催化剂及其制备方法 |
CN1590353A (zh) * | 2003-08-26 | 2005-03-09 | 中国石化集团齐鲁石油化工公司 | 丁二烯抽提装置残余物的利用方法 |
CN1872961A (zh) * | 2005-05-31 | 2006-12-06 | 中国石油化工股份有限公司 | 一种烃油加氢处理方法 |
CN101440305A (zh) * | 2007-11-22 | 2009-05-27 | 中国石油大学(北京) | 催化裂化汽油的加氢改质方法 |
CN101591567A (zh) * | 2008-05-29 | 2009-12-02 | 中国石油化工股份有限公司 | 一种降低二次加工汽油中烯烃含量的方法 |
CN102285859A (zh) * | 2010-06-18 | 2011-12-21 | 中国石油化工股份有限公司 | 一种高丁二烯含量c4物流的选择加氢工艺 |
CN103100400A (zh) * | 2011-11-09 | 2013-05-15 | 中国石油化工股份有限公司 | 一种加氢裂化催化剂的制备方法 |
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2015
- 2015-05-25 CN CN201510270390.9A patent/CN105032474B/zh active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1352231A (zh) * | 2000-11-08 | 2002-06-05 | 中国石油化工股份有限公司 | 临氢降凝催化剂及其制备方法 |
CN1470614A (zh) * | 2003-07-01 | 2004-01-28 | 中国石油天然气集团公司 | 一种用于含烯烃石脑油加氢处理的催化剂及其制备方法 |
CN1590353A (zh) * | 2003-08-26 | 2005-03-09 | 中国石化集团齐鲁石油化工公司 | 丁二烯抽提装置残余物的利用方法 |
CN1872961A (zh) * | 2005-05-31 | 2006-12-06 | 中国石油化工股份有限公司 | 一种烃油加氢处理方法 |
CN101440305A (zh) * | 2007-11-22 | 2009-05-27 | 中国石油大学(北京) | 催化裂化汽油的加氢改质方法 |
CN101591567A (zh) * | 2008-05-29 | 2009-12-02 | 中国石油化工股份有限公司 | 一种降低二次加工汽油中烯烃含量的方法 |
CN102285859A (zh) * | 2010-06-18 | 2011-12-21 | 中国石油化工股份有限公司 | 一种高丁二烯含量c4物流的选择加氢工艺 |
CN103100400A (zh) * | 2011-11-09 | 2013-05-15 | 中国石油化工股份有限公司 | 一种加氢裂化催化剂的制备方法 |
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Address after: 238251 Ma'anshan province and Anhui City, Wujiang province fine chemical base Patentee after: ANHUI HAIDE CHEMICAL TECHNOLOGY Co.,Ltd. Address before: 238251 Ma'anshan province and Anhui City, Wujiang province fine chemical base Patentee before: ANHUI HAIDE PETROCHEMICAL Co.,Ltd. |
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Effective date of registration: 20240204 Address after: 243000 No.1 Chaosan Road, Provincial Fine Chemical Base, Hexian Economic Development Zone, Ma'anshan City, Anhui Province Patentee after: Anhui Jubaoshi Technology Co.,Ltd. Country or region after: China Address before: 238251 fine chemical base of Wujiang Town, Wujiang, Anhui Province Patentee before: ANHUI HAIDE CHEMICAL TECHNOLOGY Co.,Ltd. Country or region before: China |
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