CN104962408A - Marine fish oil washing product and preparation method thereof - Google Patents
Marine fish oil washing product and preparation method thereof Download PDFInfo
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- CN104962408A CN104962408A CN201510377901.7A CN201510377901A CN104962408A CN 104962408 A CN104962408 A CN 104962408A CN 201510377901 A CN201510377901 A CN 201510377901A CN 104962408 A CN104962408 A CN 104962408A
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Abstract
The invention discloses a marine fish oil washing product and a preparation method thereof. The washing product is prepared in the steps of taking marine fish oil as a basic component and taking strong base, washing additive, essential oil, preservative, antibacterial agent, deionized water and the like as auxiliary components and mixing the marine fish oil and the strong base to have saponification in a given ratio under appropriate condition, and the natural environment-friendly and healthy washing product based on the marine fish oil is formed by adopting an optimized process. Raw materials in the marine fish oil washing product are environment-friendly substances, non-toxic, harmless and healthy, and the harm of synthetic washing agent to washed articles and residue of the synthetic washing agent in water can be avoided; in addition, the washing product is high in decontamination capacity, convenient to use, pollution-free, high in degradation capacity, free from producing secondary pollution and favorable for the environment-friendly rapid development.
Description
Technical field
The present invention relates to a kind of cosmetics of everyday use field, particularly relate to deep sea fish oil Cleaning preparations and preparation method thereof.
Background technology
The major ingredient of fish oil is triglyceride, phosphorus glyceryl ether, lipoid, liposoluble vitamin, and protein degradation thing etc.Mercury, arsenic, plumbous toxic substance is not all measured in the fish body of marine fishes, and potassium, copper, aluminium, cadmium etc. are all lower than health permissible value, pesticide residue is also no better than zero, thus obtaining fish oil with fish and waste machining thereof, to be used as the quality of grease be reliable, the same with other greases, fish oil also can be used for carrying out saponification reaction, is applied in daily use chemicals production.Now commercially there is the Cleaning preparations of abundant species, and in existing production technology, major part Cleaning preparations is all synthetic, the use of this type of washing composition not only can cause certain injury to health, the discharge of washes also can cause environmental pollution, and therefore this area still needs the Cleaning preparations of more healthy natural green.The present inventor, by concentrated research, finds that fish oil soap compound has stronger washing effect, and has the surfactant of natural health in ocean, can degradation of contaminant, and does not hinder hand and be beneficial to environment sustainable development.
Up to the present, there is many relevant reports that many health environment-friendlies wash clean goods in prior art, such as:
CN1434109A application discloses Nano colloidal silver skin-protective liquid soap, first be that silver is made electrode, by electrical spark bombardment colloidal silver ion, directly mix in liquid soap, adopt sodium oleate, AEO-7, sodium xylene sulfonate, monoethanolamine, deionized water, sodium laurate, AEO-5, ethylene glycol, carboxymethyl glass amber hydrochlorate, sanitas, colloidal silver particle etc. as raw material.Have that decontamination is strong, sterilizing and nourishing function.
CN102517177A application discloses a kind of biological environmental production multifunction special effect washing liquid, it forms by the various ingredients of alkyl glycoside 30-50 part, Oleum Cocois 15-20 part, Sumizyme MP 5-10 part, Seed of Chinese Soapberry soap breast 5-15 part, matrine 1-5 part, natural soap powder 5-10 part, Oleum Cocois LAO 5-10 part, disodium ethylene diamine tetraacetate 0.1-0.5 part, auxiliary agent 5-10 part, sanitas 0.1-0.5 part, essence 0.5-1 part, appropriate citric acid is composite, has the effect that environmentally friendly, comprehensive scourability is outstanding, can remove multiple stain simultaneously.
CN102051284A application discloses a kind of transparent liquid soap, is made up of sweet oil or oleum gossypii seminis 50 ~ 70 weight part, potassium hydroxide 10 ~ 20 weight part, alcohol 2 ~ 10 weight parts water, 400 ~ 700 weight parts.Making method: be first dissolved in a small amount of hot water by potassium hydroxide for subsequent use, separately puts into the heating of soap pot water proof, then adds in pot by potassium hydroxide solution for subsequent use by sweet oil or oleum gossypii seminis, ceaselessly stir, to the soap lye in pot alkalizes completely, now add suitable alcohols, continue to be heated to transparency, first instill in cold water with this soap lye, see that it condenses, is furnished with color again subsequently, dissolve, this soap lye conformance with standard, places one or two, filter, add spices.Produce the liquid soap of transparence, and be contained in bottle and use, seem graceful health.
CN103540464A application discloses a kind of clean liquid soap, by lauryl alcohol sodium sulfovinate 40 ~ 60 parts, 6 ~ 10 parts, lanolin, 50 ~ 70 parts, sweet oil, 10 ~ 20 parts, potassium hydroxide, 400 ~ 700 parts, water waits raw material composition, the clean liquid soap of preparation has good antibacterial effect, and transparent liquid soap, is contained in join in coloured bottle and uses, and seem graceful health.
CN103627548A application discloses a kind of liquid soap, is calculated as follows according to mass fraction: be made up of raw materials such as dihydromyrcenol 2-2.5 part, coptis elite 5-8 part, tripoly phosphate sodium STPP 0.5-0.8 part, sodium hydroxide 1.5-1.8 parts.By adding dihydromyrcenol, coptis elite, tripoly phosphate sodium STPP, sodium hydroxide, this liquid soap is made to have good cleaning effect.
Above-mentioned washing composition of the prior art or cleaning article also exist the problem that complicated components is various, detersive efficiency is low, complex process, part material derive from synthetics, then cause certain pollution and injury to washes, environment and human body.
Summary of the invention
The object of the invention is to provide that a kind of washing effect is excellent, composition simple for prior art and health environment-friendly, have superpower soil removability, sterilizing ability, by fish oil deep sea fish oil Cleaning preparations carrying out higher value application and preparation method thereof.
The present invention solves the problems of the technologies described above adopted technical scheme: deep sea fish oil Cleaning preparations and preparation method thereof, take fish oil as main raw material, and wherein: with 100 parts by weight, its concrete component concentration is as follows:
Deep sea fish oil 15-30;
Highly basic 3-6;
Washing auxiliary detergent 1-8;
Essential oil 0.2-2;
Natural antiseptic agent 0.2-1;
Antiseptic-germicide 0.5-2;
Deionized water surplus.
Deep sea fish oil and highly basic are carried out saponification reaction according to a certain percentage, prepares by the technique optimized, form a kind of Cleaning preparations of the natural environmental-protective green health based on deep sea fish oil.The raw material adopted in the present invention is all green matters, nontoxic, health environment-friendly, avoids synthetic washing composition to washes infringement and remaining in water; In addition, Cleaning preparations soil removability of the present invention is strong, easy to use, pollution-free, and degradation capability is strong, can not produce secondary pollution.
For optimizing technique scheme, the measure taked also comprises: deep sea fish oil is adopted and prepared with the following method:
1) crude fish oil preparation: the mixing internal organ of fresh fish are removed impurity, and drain after cleaning, then homogenate is smashed to pieces and stirred evenly; Distilled water is added in the ratio of solid-liquid ratio 1 ︰ 1 to 1:1.2, pour in the flask cleaned up in advance after regulating pH=8 with KOH and HCl, then 1.8% neutral protease and tryptic mixture is added, place it in enzymolysis 3.5h in the thermostat water bath of 45 DEG C, by solution after enzymolysis in centrifuges with the centrifugal 15min of 6000r/min, isolate upper strata grease, add the extraction of appropriate petroleum ether solvent, remove unnecessary sherwood oil with Rotary Evaporators, obtain crude fish oil;
2) ferment treatment of crude fish oil: get crude fish oil prepared by step 1) and add 0.3g/kg antioxidant, proteolytic enzyme and tryptic mass ratio are 1:1;
3) phosphoric acid degumming: the crude fish oil of precise certain mass is in beaker, be placed on heated and stirred to 80 DEG C in water-bath, slowly adding crude fish oil amount 1% concentration is the phosphoric acid of 75%, continuous stirring is until evenly, 6min is heated under condition at 80 DEG C, then with the centrifugal 15min of 3500rpm, isolate upper strata oil sample, be the crude fish oil that comes unstuck; This step is carried out under being in inflated with nitrogen state always;
4) sodium hydroxide depickling: add the NaOH solution uniform stirring of 12 ° of Be of 0.2% in the fish oil that comes unstuck after, be heated to 65 DEG C, insulation 30min, is then cooled to room temperature, static layering, with the centrifugal 15min of 4000rpm, removing precipitation.And then remove the soap that remains with the washing of certain volume, until clean up; Upper strata depickling crude fish oil is got after separatory; This step is carried out under being in inflated with nitrogen state always;
5) crude fish oil decolouring: the depickling fish oil of above-mentioned gained is heated to 65 DEG C in a water bath, adds 12% atlapulgite, constantly stirs and makes to mix, and after maintaining 20min, with the centrifugal 15min of 4000rpm, is separated and obtains the fish oil that decolours;
6) fish oil takes off raw meat: step 5) gained decolouring fish oil is put into round-bottomed flask, utilizes Rotary Evaporators to be heated to 70 ~ 80 DEG C of deodorization 30 ~ 40min; Except smelling removal stink substance, obtain deep sea fish oil;
Step 3) to step 6) is carried out under being in inflated with nitrogen state.Oxygenant is selected from any one or multiple mixture of natural VE, S-WAT, Sodium Pyrosulfite, 2,6 di tert butyl 4 methyl phenol.Fish oil is selected from one in common fish oil or fish oil or mixture.Highly basic is selected from potassium hydroxide or sodium hydroxide.Washing auxiliary detergent be selected from EDTA-2Na, Trisodium Citrate, sodium bicarbonate, sodium carbonate, Sumizyme MP, amylase, cellulase any one or its mixing.Natural antiseptic agent selects vitamin-E.Nanometer silver selected by antiseptic-germicide.9, preparation is as the method for claim 1 deep sea fish oil Cleaning preparations, it is characterized in that: have following steps:
A) by fish oil heating in water bath to 60 DEG C-80 DEG C;
B) highly basic is dissolved in distilled water, cools to 60 DEG C-80 DEG C;
C) by step B) the aqueous solution slowly pour steps A into) basic grease solution in, and constantly stir about 90min, until become pasty state dope;
D) by step C) gains be stored in Baolilong insulation can inside holding 24h, afterwards take out be placed in ventilation slaking fortnight;
E) in the soap base after slaking, add the deionized water of certain adding proportion heat, be dissolved into soap lye, in solution, add appropriate washing auxiliary detergent, natural antiseptic agent, antiseptic-germicide etc. successively again, uniform stirring forms the strong uniform liquid of mobility, obtains deep sea fish oil Cleaning preparations.Adding proportion is, with 100 parts by weight, component concentration is as follows:
Deep sea fish oil 15-30;
Highly basic 3-6;
Washing auxiliary detergent 1-8;
Essential oil 0.2-2;
Natural antiseptic agent 0.2-1;
Antiseptic-germicide 0.5-2;
Deionized water surplus.
Owing to present invention employs, deep sea fish oil and highly basic are carried out saponification reaction according to a certain percentage, prepare by the technique optimized, form a kind of mode of Cleaning preparations of the natural environmental-protective green health based on deep sea fish oil.The raw material adopted in the present invention is all green matters, nontoxic, health environment-friendly, avoids synthetic washing composition to washes infringement and remaining in water; In addition, Cleaning preparations soil removability of the present invention is strong, easy to use, pollution-free, and degradation capability is strong, can not produce secondary pollution.Thus the present invention's advantage of there is the simple and health environment-friendly of washing effect excellence, composition, having superpower soil removability, sterilizing ability, fish oil carried out higher value application.
Embodiment
Below in conjunction with attached embodiment, the present invention is described in further detail.
embodiment 1:be 100 parts by total weight parts, a kind of Cleaning preparations based on deep sea fish oil is prepared as follows:
(1) by 15 weight part fish oil heating in water bath to 60 DEG C;
(2) 3 weight part potassium hydroxide are dissolved in distilled water, cool to 60 DEG C;
(3) aqueous solution of step (2) is slowly poured in the basic grease solution of step (1), and constantly stir about 90min, until become pasty state dope.
(4) gains of step (3) are stored in Baolilong insulation can inside holding 24h, take out afterwards and be placed in ventilation slaking fortnight.
(5) in the soap base after slaking, a certain proportion of hot distilled water is added, be dissolved into soap lye, the washing auxiliary detergent sodium bicarbonate of 2 weight parts and Trisodium Citrate (adjusting pH=7-10), the natural antiseptic agent vitamin-E of 0.4 weight part, the antiseptic-germicide nanometer silver etc. of 0.6 weight part is added again successively in solution, uniform stirring forms the strong uniform liquid of mobility, obtain the Cleaning preparations based on deep sea fish oil, called after 1 group.
embodiment 2:be 100 parts by total weight parts, a kind of Cleaning preparations based on deep sea fish oil is prepared as follows:
(1) by 19 weight part fish oil heating in water bath to 65 DEG C;
(2) 3.8 weight part potassium hydroxide are dissolved in distilled water, cool to 65 DEG C;
(3) aqueous solution of step (2) is slowly poured in the basic grease solution of step (1), and constantly stir about 90min, until become pasty state dope.
(4) gains of step (3) are stored in Baolilong insulation can inside holding 24h, take out afterwards and be placed in ventilation slaking fortnight.
(5) in the soap base after slaking, a certain proportion of hot distilled water is added, be dissolved into soap lye, the washing auxiliary detergent Sumizyme MP of 4 weight parts and Trisodium Citrate (adjusting pH=7-10), the natural antiseptic agent vitamin-E of 0.5 weight part, the antiseptic-germicide nanometer silver etc. of 0.8 weight part is added again successively in solution, uniform stirring forms the strong uniform liquid of mobility, obtain the Cleaning preparations of the natural environmental-protective green health based on deep sea fish oil, called after 2 groups.
embodiment 3:be 100 parts by total weight parts, a kind of Cleaning preparations based on deep sea fish oil is prepared as follows:
(1) by 23 weight part fish oil heating in water bath to 70 DEG C;
(2) 4.6 weight part potassium hydroxide are dissolved in distilled water, cool to 70 DEG C;
(3) aqueous solution of step (2) is slowly poured in the basic grease solution of step (1), and constantly stir about 90min, until become pasty state dope.
(4) gains of step (3) are stored in Baolilong insulation can inside holding 24h, take out afterwards and be placed in ventilation slaking fortnight.
(5) in the soap base after slaking, a certain proportion of hot distilled water is added, be dissolved into soap lye, in solution, add the washing auxiliary detergent Trisodium Citrate of 6 weight parts more successively and EDTA-2Na(adjusts pH=7-10), the natural antiseptic agent vitamin-E of 0.6 weight part, the antiseptic-germicide nanometer silver etc. of 1.0 weight parts, uniform stirring forms the strong uniform liquid of mobility, obtain the Cleaning preparations based on deep sea fish oil, called after 3 groups.
embodiment 4:be 100 parts by total weight parts, a kind of Cleaning preparations based on deep sea fish oil is prepared as follows:
(1) by 30 weight part fish oil heating in water bath to 75 DEG C;
(2) 6 weight part potassium hydroxide are dissolved in distilled water, cool to 75 DEG C;
(3) aqueous solution of step (2) is slowly poured in the basic grease solution of step (1), and constantly stir about 90min, until become pasty state dope.
(4) gains of step (3) are stored in Baolilong insulation can inside holding 24h, take out afterwards and be placed in ventilation slaking fortnight.
(5) in the soap base after slaking, a certain proportion of hot distilled water is added, be dissolved into soap lye, the washing auxiliary detergent EDTA-2Na of 8 weight parts, Sumizyme MP and sodium bicarbonate (adjusting pH=7-10), the natural antiseptic agent vitamin-E of 0.8 weight part, the antiseptic-germicide nanometer silver etc. of 1.8 weight parts is added again successively in solution, uniform stirring forms the strong uniform liquid of mobility, obtain the Cleaning preparations based on deep sea fish oil, called after 4 groups.
embodiment 5:be 100 parts by total weight parts, a kind of Cleaning preparations based on deep sea fish oil is prepared as follows:
(1) by 27 weight part fish oil heating in water bath to 80 DEG C;
(2) 5.4 weight part potassium hydroxide are dissolved in distilled water, cool to 80 DEG C;
(3) aqueous solution of step (2) is slowly poured in the basic grease solution of step (1), and constantly stir about 90min, until become pasty state dope.
(4) gains of step (3) are stored in Baolilong insulation can inside holding 24h, take out afterwards and be placed in ventilation slaking fortnight.
(5) in the soap base after slaking, add a certain proportion of hot distilled water, be dissolved into soap lye,
The washing auxiliary detergent Trisodium Citrate of 6 weight parts, lipase, sodium bicarbonate (adjusting pH=7-10), the natural antiseptic agent vitamin-E of 1.0 weight parts, the antiseptic-germicide nanometer silver etc. of 1.6 weight parts is added again successively in solution, uniform stirring forms the strong uniform liquid of mobility, obtain the Cleaning preparations based on deep sea fish oil, called after 5 groups.
performance test is tested
1, a kind of test of the clean effect based on deep sea fish oil Cleaning preparations of the present invention.
Use that the Cleaning preparations of the deep sea fish oil prepared by the present invention speckles with even spot of the same race, measure-alike rectangle band, washing methods is as follows: be put in washing machine by that stained by even spot of the same race, measure-alike rectangle band, then the present invention of equivalent weight is added, after its dispersion, start washing machine, wash the identical time, then use whiteness instrument (blancometer) to measure its fair and clear degree.
experimental procedure:
(1) test the fair and clear degree of clean band as standard reference, measure and average for three times;
(2) get 5 soiled cotton bars as experimental group, test the fair and clear degree of soiled cotton bar before 5 groups of cleanings respectively, measure and average for three times;
(3) with above-mentioned washing methods, 5 groups of soiled cotton bars are cleaned, then dry, measure the fair and clear degree of soiled cotton bar after cleaning, measure and average for three times;
(4) calculate soil removal efficiency, adopt following formula:
Soil removal efficiency (%)=[(the fair and clear degree of soiled cotton bar before the fair and clear degree-cleaning of the soiled cotton bar after cleaning)/(the fair and clear degree of soiled cotton bar before the fair and clear degree-cleaning of clean band)] × 100%.Experimental result is in table 1.
2, the present invention is based on the sterilization effect test of the Cleaning preparations of deep sea fish oil.
Use streptococcus aureus, intestinal bacteria as the bacterial classification of bactericidal assay; The Cleaning preparations based on deep sea fish oil of use prepared by the present invention is as bactericidal agent.
experimental procedure
(1) solution that 0.5 mL streptococcus aureus and colibacillary bacteria suspension be the present invention is based on respectively the Cleaning preparations of deep sea fish oil with 4.5 mL mixes, and leaves standstill effect 10 min, obtains two kinds of bacterium medicine suspensions respectively;
(2) neutralizing agent that 0.5 mL bacterium medicine suspension adds 4.5 mL is respectively got, after mixing, comprehensive action 8 min, get 0.5 mL mixing liquid inoculation plate respectively, pour into plain agar and mix, cultivating 36 hours at 37 DEG C, counting colony number, calculate sterilizing rate, experimental result is in table 2.
interpretation of result
Table 1. each group of clean effect based on the Cleaning preparations of deep sea fish oil compares
From table 1 result: the soil removal efficiency after adopting the Cleaning preparations of deep sea fish oil of the present invention to wash all reaches more than 80%, the visible suitable selection by component and particular combination, make to wash clean article exhibits and go out excellent clean effect.
Table 2. each group of Comparison of effect on sterilization based on the Cleaning preparations of deep sea fish oil
From table 2 result: adopt the Cleaning preparations based on deep sea fish oil of the present invention to carry out bacteriostatic experiment and all obtain the excellent effect that sterilizing rate reaches more than 90%, the visible suitable selection by component and particular combination, make this Cleaning preparations be attended by good sterilizing power.
Comprehensively above-mentioned, the Cleaning preparations of deep sea fish oil of the present invention has the advantages such as component is simple, preparation is convenient, its suitable selection by component and particular combination and show excellent clean effect, and be attended by good sterilizing power simultaneously, achieve beat all effect, there is industrial production prospect and marketable value widely.
embodiment 6:deep sea fish oil Cleaning preparations and preparation method thereof take fish oil as main raw material, and wherein: with 100 parts by weight, its concrete component concentration is as follows:
Deep sea fish oil 15-30; Highly basic 3-6; Washing auxiliary detergent 1-8; Essential oil 0.2-2; Natural antiseptic agent 0.2-1; Antiseptic-germicide 0.5-2; Deionized water surplus.
Deep sea fish oil and highly basic are carried out saponification reaction according to a certain percentage, prepares by the technique optimized, form a kind of Cleaning preparations of the natural environmental-protective green health based on deep sea fish oil.The raw material adopted in the present invention is all green matters, nontoxic, health environment-friendly, avoids synthetic washing composition to washes infringement and remaining in water; In addition, Cleaning preparations soil removability of the present invention is strong, easy to use, pollution-free, and degradation capability is strong, can not produce secondary pollution.Deep sea fish oil is adopted and is prepared with the following method:
1) crude fish oil preparation: the mixing internal organ of fresh fish are removed impurity, and drain after cleaning, then homogenate is smashed to pieces and stirred evenly; Distilled water is added in the ratio of solid-liquid ratio 1 ︰ 1 to 1:1.2, pour in the flask cleaned up in advance after regulating pH=8 with KOH and HCl, then 1.8% neutral protease and tryptic mixture is added, place it in enzymolysis 3.5h in the thermostat water bath of 45 DEG C, by solution after enzymolysis in centrifuges with the centrifugal 15min of 6000r/min, isolate upper strata grease, add the extraction of appropriate petroleum ether solvent, remove unnecessary sherwood oil with Rotary Evaporators, obtain crude fish oil;
2) ferment treatment of crude fish oil: get crude fish oil prepared by step 1) and add 0.3g/kg antioxidant, proteolytic enzyme and tryptic mass ratio are 1:1;
3) phosphoric acid degumming: the crude fish oil of precise certain mass is in beaker, be placed on heated and stirred to 80 DEG C in water-bath, slowly adding crude fish oil amount 1% concentration is the phosphoric acid of 75%, continuous stirring is until evenly, 6min is heated under condition at 80 DEG C, then with the centrifugal 15min of 3500rpm, isolate upper strata oil sample, be the crude fish oil that comes unstuck; This step is carried out under being in inflated with nitrogen state always;
4) sodium hydroxide depickling: add the NaOH solution uniform stirring of 12 ° of Be of 0.2% in the fish oil that comes unstuck after, be heated to 65 DEG C, insulation 30min, is then cooled to room temperature, static layering, with the centrifugal 15min of 4000rpm, removing precipitation.And then remove the soap that remains with the washing of certain volume, until clean up; Upper strata depickling crude fish oil is got after separatory; This step is carried out under being in inflated with nitrogen state always;
5) crude fish oil decolouring: the depickling fish oil of above-mentioned gained is heated to 65 DEG C in a water bath, adds 12% atlapulgite, constantly stirs and makes to mix, and after maintaining 20min, with the centrifugal 15min of 4000rpm, is separated and obtains the fish oil that decolours;
6) fish oil takes off raw meat: step 5) gained decolouring fish oil is put into round-bottomed flask, utilizes Rotary Evaporators to be heated to 70 ~ 80 DEG C of deodorization 30 ~ 40min; Except smelling removal stink substance, obtain deep sea fish oil;
Step 3) to step 6) is carried out under being in inflated with nitrogen state.Oxygenant is selected from any one or multiple mixture of natural VE, S-WAT, Sodium Pyrosulfite, 2,6 di tert butyl 4 methyl phenol.Fish oil is selected from one in common fish oil or fish oil or mixture.Highly basic is selected from potassium hydroxide or sodium hydroxide.Washing auxiliary detergent be selected from EDTA-2Na, Trisodium Citrate, sodium bicarbonate, sodium carbonate, Sumizyme MP, amylase, cellulase any one or its mixing.Natural antiseptic agent selects vitamin-E.Nanometer silver selected by antiseptic-germicide.9, preparation is as the method for claim 1 deep sea fish oil Cleaning preparations, it is characterized in that: have following steps:
A) by fish oil heating in water bath to 60 DEG C-80 DEG C;
B) highly basic is dissolved in distilled water, cools to 60 DEG C-80 DEG C;
C) by step B) the aqueous solution slowly pour steps A into) basic grease solution in, and constantly stir about 90min, until become pasty state dope;
D) by step C) gains be stored in Baolilong insulation can inside holding 24h, afterwards take out be placed in ventilation slaking fortnight;
E) in the soap base after slaking, add the deionized water of certain adding proportion heat, be dissolved into soap lye, in solution, add appropriate washing auxiliary detergent, natural antiseptic agent, antiseptic-germicide etc. successively again, uniform stirring forms the strong uniform liquid of mobility, obtains deep sea fish oil Cleaning preparations.Adding proportion is, with 100 parts by weight, component concentration is as follows:
Deep sea fish oil 15-30; Highly basic 3-6; Washing auxiliary detergent 1-8; Essential oil 0.2-2; Natural antiseptic agent 0.2-1; Antiseptic-germicide 0.5-2; Deionized water surplus.
In the Cleaning preparations of deep sea fish oil of the present invention, its deep sea fish oil is common fish or dark
Ocean fish oil, its parts by weight are 15-30 part, and this scope includes any sub-range scope wherein,
As being 15-20 part, 21-25 part, 26-30 part.
In the Cleaning preparations of deep sea fish oil of the present invention, highly basic is sodium hydroxide or potassium hydroxide, and its parts by weight are 3-6 part, as being 3-4 part, 4-5 part, 5-6 part.
In the Cleaning preparations of deep sea fish oil of the present invention, washing auxiliary detergent elects any one or multiple mixture in EDTA-2Na, Trisodium Citrate, sodium bicarbonate, sodium carbonate, Sumizyme MP, amylase, cellulase as, and adjust pH=7-10, its parts by weight are 1-8 part, as being 1-4 part, 3-6 part, 5-8 part.
In the Cleaning preparations of deep sea fish oil of the present invention, natural antiseptic agent is vitamin-E, and its parts by weight are 0.2-1 part, as being 0.2-0.5 part, 0.4-0.7 part, 0.7-1.0 part.
In the Cleaning preparations of deep sea fish oil of the present invention, antiseptic-germicide is nanometer silver, and its parts by weight are 0.5-2 part, as being 0.5-0.9 part, 1.0-1.5 part, 1.6-2.0 part.
Although describe the present invention in conjunction with preferred embodiment; so itself and be not used to limit the present invention; any those skilled in the art; without departing from the spirit and scope of the present invention; can implement various change, the displacement of coordinator and amendment here to the theme listed, therefore protection scope of the present invention be as the criterion when the scope limited depending on proposed claim.
Claims (11)
1. deep sea fish oil Cleaning preparations and preparation method thereof, comprising with fish oil is main raw material, it is characterized in that: with 100 parts by weight, and its concrete component concentration is as follows:
Deep sea fish oil 15-30;
Highly basic 3-6;
Washing auxiliary detergent 1-8;
Essential oil 0.2-2;
Natural antiseptic agent 0.2-1;
Antiseptic-germicide 0.5-2;
Deionized water surplus.
2. deep sea fish oil Cleaning preparations according to claim 1 and preparation method thereof, is characterized in that: described deep sea fish oil is adopted and prepared with the following method:
1) crude fish oil preparation: the mixing internal organ of fresh fish are removed impurity, and drain after cleaning, then homogenate is smashed to pieces and stirred evenly; Distilled water is added in the ratio of solid-liquid ratio 1 ︰ 1 to 1:1.2, pour in the flask cleaned up in advance after regulating pH=8 with KOH and HCl, then 1.8% neutral protease and tryptic mixture is added, place it in enzymolysis 3.5h in the thermostat water bath of 45 DEG C, by solution after enzymolysis in centrifuges with centrifugal 15 min of 6000 r/min, isolate upper strata grease, add the extraction of appropriate petroleum ether solvent, remove unnecessary sherwood oil with Rotary Evaporators, obtain crude fish oil;
2) ferment treatment of crude fish oil: get crude fish oil prepared by step 1) and add 0.3g/kg antioxidant, described proteolytic enzyme and tryptic mass ratio are 1:1;
3) phosphoric acid degumming: the crude fish oil of precise certain mass is in beaker, be placed on heated and stirred to 80 DEG C in water-bath, slowly adding crude fish oil amount 1% concentration is the phosphoric acid of 75%, continuous stirring is until evenly, 6 min are heated under condition at 80 DEG C, then with the centrifugal 15min of 3500rpm, isolate upper strata oil sample, be the crude fish oil that comes unstuck; This step is carried out under being in inflated with nitrogen state always;
4) sodium hydroxide depickling: add the NaOH dissolution homogeneity stirring of 12 ° of Be of 0.2% in the fish oil that comes unstuck after, be heated to 65 DEG C, insulation 30min, is then cooled to room temperature, static layering, with the centrifugal 15min of 4000rpm, removing precipitation.
3. and then remove the soap that remains with the washing of certain volume, until clean up; Upper strata depickling crude fish oil is got after separatory; This step is carried out under being in inflated with nitrogen state always;
5) crude fish oil decolouring: the depickling fish oil of above-mentioned gained is heated to 65 DEG C in a water bath, adds 12% atlapulgite, constantly stirs and makes to mix, and after maintaining 20min, with the centrifugal 15min of 4000rpm, is separated and obtains the fish oil that decolours;
6) fish oil takes off raw meat: step 5) gained decolouring fish oil is put into round-bottomed flask, utilizes Rotary Evaporators to be heated to 70 ~ 80 DEG C of deodorization 30 ~ 40min; Except smelling removal stink substance, obtain deep sea fish oil;
Described step 3) to step 6) is carried out under being in inflated with nitrogen state.
4. deep sea fish oil Cleaning preparations according to claim 2 and preparation method thereof, it is characterized in that: described oxygenant is selected from any one or multiple mixture of natural VE, S-WAT, Sodium Pyrosulfite, 2,6 di tert butyl 4 methyl phenol.
5. deep sea fish oil Cleaning preparations according to claim 2 and preparation method thereof, is characterized in that: described fish oil is selected from one in common fish oil or fish oil or mixture.
6. deep sea fish oil Cleaning preparations according to claim 2 and preparation method thereof, is characterized in that: described highly basic is selected from potassium hydroxide or sodium hydroxide.
7. deep sea fish oil Cleaning preparations according to claim 2 and preparation method thereof, is characterized in that: described washing auxiliary detergent be selected from EDTA-2Na, Trisodium Citrate, sodium bicarbonate, sodium carbonate, Sumizyme MP, amylase, cellulase any one or its mixing.
8. deep sea fish oil Cleaning preparations according to claim 2 and preparation method thereof, is characterized in that: described natural antiseptic agent selects vitamin-E.
9. deep sea fish oil Cleaning preparations according to claim 2 and preparation method thereof, is characterized in that: nanometer silver selected by described antiseptic-germicide.
10. prepare the method for deep sea fish oil Cleaning preparations as claimed in claim 1, it is characterized in that: there are following steps:
A) by fish oil heating in water bath to 60 DEG C-80 DEG C;
B) highly basic is dissolved in distilled water, cools to 60 DEG C-80 DEG C;
C) by step B) the aqueous solution slowly pour steps A into) basic grease solution in, and constantly stir about 90min, until become pasty state dope;
D) by step C) gains be stored in Baolilong insulation can inside holding 24h, afterwards take out be placed in ventilation slaking fortnight;
E) in the soap base after slaking, add the deionized water of certain adding proportion heat, be dissolved into soap lye, in solution, add appropriate washing auxiliary detergent, natural antiseptic agent, antiseptic-germicide etc. successively again, uniform stirring forms the strong uniform liquid of mobility, obtains deep sea fish oil Cleaning preparations.
11. deep sea fish oil Cleaning preparations according to claim 9 and preparation method thereof, is characterized in that: described adding proportion is, with 100 parts by weight, component concentration is as follows:
Deep sea fish oil 15-30;
Highly basic 3-6;
Washing auxiliary detergent 1-8;
Essential oil 0.2-2;
Natural antiseptic agent 0.2-1;
Antiseptic-germicide 0.5-2;
Deionized water surplus.
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| CN201510377901.7A CN104962408A (en) | 2015-07-01 | 2015-07-01 | Marine fish oil washing product and preparation method thereof |
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| CN108004066A (en) * | 2017-12-01 | 2018-05-08 | 浙江海洋大学 | It is a kind of suitable for soap of sensitiveness skin and preparation method thereof |
| CN108913401A (en) * | 2018-06-28 | 2018-11-30 | 西北师范大学 | A kind of skin-wetting soap prepared using fish oil and donkey oil as animal fat |
| CN108969461A (en) * | 2018-09-29 | 2018-12-11 | 韶关市小豆子电子科技有限公司 | A kind of collagen beautifying liquid and preparation method thereof based on marine organism extract |
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Application publication date: 20151007 |