CN104928000A - Multipurpose carbon-deposition-free environmental-friendly water soluble drawing lubricant - Google Patents

Multipurpose carbon-deposition-free environmental-friendly water soluble drawing lubricant Download PDF

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Publication number
CN104928000A
CN104928000A CN201510383807.2A CN201510383807A CN104928000A CN 104928000 A CN104928000 A CN 104928000A CN 201510383807 A CN201510383807 A CN 201510383807A CN 104928000 A CN104928000 A CN 104928000A
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China
Prior art keywords
friendly water
distribution environment
carbon distribution
acid
soluble drawing
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Pending
Application number
CN201510383807.2A
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Chinese (zh)
Inventor
林丽静
常建忠
阿部聪
俞威
陈华东
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Shanghai Yushiro Chemical Industry Co Ltd
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Shanghai Yushiro Chemical Industry Co Ltd
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Priority to CN201510383807.2A priority Critical patent/CN104928000A/en
Publication of CN104928000A publication Critical patent/CN104928000A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a multipurpose carbon-deposition-free environmental-friendly water soluble drawing lubricant which consists of base oil, a synthetic ester compound, an antirust agent, an ashless anti-wear extreme pressure additive, a metal corrosion inhibitor, a surfactant, a co-emulsifier, a bactericide, a defoamer and water. The multipurpose carbon-deposition-free environmental-friendly water soluble drawing lubricant disclosed by the invention is excellent in performance and convenient to prepare.

Description

Multi-usage is without carbon distribution environment-friendly water-soluble drawing compound
Technical field
The present invention relates to a kind of water-soluble drawing compound.
Background technology
So-called drawing process is exactly under external broach effect, makes metal stock by nib, obtains the plastic processing method of respective shapes and gauge articles.Due to technique, the reason such as backward in technique, also there is some problems demand and solve in the domestic water-soluble drawing compound being used in drawing process at present.One is that oilness and extreme pressure anti-wear are poor, cause drawing mould and drawable material area carbon and greasy dirt in drawing process more, not only have a strong impact on luminance brightness and the cleanliness factor on drawable material surface, and exacerbate the wearing and tearing of drawing mould, shorten its work-ing life; Two is that biodegradability is poor, causes the easy smelly raw bacterium of emulsion, and the waste liquid also not easily biochemical treatment of discharge, is detrimental to health, serious environment pollution; Three is that range of application is narrow, can not meet the drawing process requirement of multiple pipe, line, bar.
Summary of the invention
The object of the present invention is to provide a kind of multi-usage of excellent performance without carbon distribution environment-friendly water-soluble drawing compound.
Technical solution of the present invention is:
A kind of multi-usage, without carbon distribution environment-friendly water-soluble drawing compound, is characterized in that: be grouped into by the one-tenth of following weight percents:
Base oil ... 5 ~ 15%
Synthetic ester compound ... 5 ~ 20%
Rust-preventive agent ... 5 ~ 20%
Ashless extreme pressure additive ... 2 ~ 10%
Metal corrosion inhibitor ... 0.1 ~ 5%
Tensio-active agent ... 2 ~ 10%
Assistant for emulsifying agent ... 0.1 ~ 5%
Sterilant ... 0.1 ~ 3%
Defoamer ... 0.1 ~ 1%
Water ... surplus.
Base oil is one or more in No. 10 white oils, No. 15 white oils, No. 26 white oils, No. 32 white oils, naphthenic base white oil.
Synthetic ester compound is one or more in tricarboxymethyl propane oleate, TriMethylolPropane(TMP) cocinin, PETO, dipentaerythritol oleic acid ester, isooctyl oleate, Witconol 2301, trimellitate, ricinoleate ester.
Rust-preventive agent is Long carbon chain monocarboxylic acid, Long carbon chain di-carboxylic acid, 2,4,6-tri-(amino caproyl)-1, the composite antirust agent of one or more in one or more and monoisopropanolamine in 3,5-triazine, tolysulfonyl hexosamine, ring carboxylic propyl group oleic acid, diisopropanolamine (DIPA), tri-isopropanolamine.
Ashless extreme pressure additive is one or more in saturated collateralization esters polymer, stearic acid Imidazoline Borate, oleic imidazolinone boric acid ester, lauric acid imidazoline boric acid ester, polyisobutylene succinic acid imines, polyisobutylene succinic acid acid amides.
Metal corrosion inhibitor is one or more in benzotriazole, methyl benzotriazazole, first Benzotriazole Derivative, 2-amino-2-methyl-1-propanol, N-β-(aminoethyl)-γ-aminopropyltrimethoxysilane.
Tensio-active agent is one or more in imidazoline type amphoterics, beet alkali ampholytic surface active agent, amino acid type amphoteric surface active agent, alcohol ether carboxylate, methyl glucamine, isomery ten polyoxyethylenated alcohol, isomery undecyl alcohol Soxylat A 25-7, isomerous tridecanol polyoxyethylene ether, sulphosuccinates.
Assistant for emulsifying agent is one or more in propylene glycol, ethylene glycol, Dipropylene glycol mono-n-butyl Ether, high-carbon monohydroxy-alcohol.
Sterilant is N, N-methylene-bis morpholine, BIT, Kathon, MIT, 2-mercaptopyridine-1-are oxidized one or more in sodium salt, 3-iodo-2-propynyl-butyl carbamate.
Defoamer is one or more in Siloxane-Oxyalkylene Copolymers defoamer, polysiloxane defoamers, polyethers defoamer.
Advantage of the present invention:
1. the ashless extreme pressure additive group 5 of high molecular polymerization ester that this product synthetic ester compound, abrasion resistant extreme-pressure performance of selecting multiple lubricity good is superpower, product has extremely strong lubricity (5% diluent tapping torque≤300Ncm) and abrasion resistant extreme-pressure performance (workpiece surface roughness Ra≤1.0 μm), and in the course of processing, drawing mould and drawable material are without carbon distribution and greasy dirt.
2. this product is selected multiple biology easily to degrade and is resisted antibacterial synthetic ester compound, high molecular polymerization ester, novel surfactant compound thing group 5, product has excellent biodegradability and anti-biocidal property, its BOD(biological oxygen demand (BOD) of 5% diluent)/COD(chemical oxygen demand) >=0.7, use annual bacterium number≤102, the waste liquid of discharge can biochemical treatment ability strong, on HUMAN HEALTH and environmental safety impact little.
3. Products Compatibility is strong, can meet the drawing process requirement of stainless steel, carbon steel, pipe such as various metals such as conjunction conjunction steel, aluminium alloy etc., line, bar, applied range.
Below in conjunction with embodiment, the invention will be further described.
Embodiment
Embodiment 1:
A kind of multi-usage, without carbon distribution environment-friendly water-soluble drawing compound, is mixed together by the composition of following weight percents:
Naphthenic base white oil 10.0%
5# paraffinic base white oil 5.0%
PETO 5.0%
Isooctyl oleate 5.0%
Tricarboxymethyl propane oleate 10.0%
2,4,6-tri-(amino caproyl)-1,3,5-triazines 3.0%
Bay diacid 2.0%
Ring carboxylic propyl group oleic acid 2.0%
Monoisopropanolamine 5.0%
Tri-isopropanolamine 10.0%
Polyisobutylene succinic acid acid amides 5.0%
Saturated collateralization esters polymer GY-25 5.0%
N-β-(aminoethyl)-γ-aminopropyltrimethoxysilane 1.0%
Methyl benzotriazazole 0.2%
Lauric acid imidazoline type amphoterics 1.0%
Isomerous tridecanol polyoxyethylene ether 2.0%
Sulphosuccinates 3.0%
Alcohol ether carboxylate 1.0%
Dipropylene glycol mono-n-butyl Ether 1.0%
MIT 3.0%
Siloxane-Oxyalkylene Copolymers defoamer 1.0%
All the other compositions are water.
Embodiment 2:
A kind of multi-usage, without carbon distribution environment-friendly water-soluble drawing compound, is mixed together by the composition of following weight percents:
Base oil ... 5 ~ 15%(example 5%, 10%, 15%)
Synthetic ester compound ... 5 ~ 20%(example 5%, 10%, 20%)
Rust-preventive agent ... 5 ~ 20%(example 5%, 15%, 20%)
Ashless extreme pressure additive ... 2 ~ 10%(example 2%, 6%, 10%)
Metal corrosion inhibitor ... 0.1 ~ 5%(example 0.1%, 2%, 5%)
Tensio-active agent ... 2 ~ 10%(example 5%, 10%, 15%)
Assistant for emulsifying agent ... 0.1 ~ 5%(example 0.1%, 2%, 5%)
Sterilant ... 0.1 ~ 3%(example 0.1%, 2%, 3%)
Defoamer ... 0.1 ~ 1%(example 0.1%, 0.5%, 1%)
Water ... surplus.
Base oil is one or more in No. 10 white oils, No. 15 white oils, No. 26 white oils, No. 32 white oils, naphthenic base white oil.
Synthetic ester compound is one or more in tricarboxymethyl propane oleate, TriMethylolPropane(TMP) cocinin, PETO, dipentaerythritol oleic acid ester, isooctyl oleate, Witconol 2301, trimellitate, ricinoleate ester.
Rust-preventive agent is Long carbon chain monocarboxylic acid, Long carbon chain di-carboxylic acid, 2,4,6-tri-(amino caproyl)-1, the composite antirust agent of one or more in one or more and monoisopropanolamine in 3,5-triazine, tolysulfonyl hexosamine, ring carboxylic propyl group oleic acid, diisopropanolamine (DIPA), tri-isopropanolamine.
Ashless extreme pressure additive is one or more in saturated collateralization esters polymer, stearic acid Imidazoline Borate, oleic imidazolinone boric acid ester, lauric acid imidazoline boric acid ester, polyisobutylene succinic acid imines, polyisobutylene succinic acid acid amides.
Metal corrosion inhibitor is one or more in benzotriazole, methyl benzotriazazole, first Benzotriazole Derivative, 2-amino-2-methyl-1-propanol, N-β-(aminoethyl)-γ-aminopropyltrimethoxysilane.
Tensio-active agent is one or more in imidazoline type amphoterics, beet alkali ampholytic surface active agent, amino acid type amphoteric surface active agent, alcohol ether carboxylate, methyl glucamine, isomery ten polyoxyethylenated alcohol, isomery undecyl alcohol Soxylat A 25-7, isomerous tridecanol polyoxyethylene ether, sulphosuccinates.
Assistant for emulsifying agent is one or more in propylene glycol, ethylene glycol, Dipropylene glycol mono-n-butyl Ether, high-carbon monohydroxy-alcohol.
Sterilant is N, N-methylene-bis morpholine, BIT, Kathon, MIT, 2-mercaptopyridine-1-are oxidized one or more in sodium salt, 3-iodo-2-propynyl-butyl carbamate.
Defoamer is one or more in Siloxane-Oxyalkylene Copolymers defoamer, polysiloxane defoamers, polyethers defoamer.

Claims (10)

1. multi-usage is without a carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: be grouped into by the one-tenth of following weight percents:
Base oil ... 5 ~ 15%
Synthetic ester compound ... 5 ~ 20%
Rust-preventive agent ... 5 ~ 20%
Ashless extreme pressure additive ... 2 ~ 10%
Metal corrosion inhibitor ... 0.1 ~ 5%
Tensio-active agent ... 2 ~ 10%
Assistant for emulsifying agent ... 0.1 ~ 5%
Sterilant ... 0.1 ~ 3%
Defoamer ... 0.1 ~ 1%
Water ... surplus.
2. multi-usage according to claim 1 is without carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: base oil is one or more in No. 10 white oils, No. 15 white oils, No. 26 white oils, No. 32 white oils, naphthenic base white oil.
3. multi-usage according to claim 1 and 2 is without carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: synthetic ester compound is one or more in tricarboxymethyl propane oleate, TriMethylolPropane(TMP) cocinin, PETO, dipentaerythritol oleic acid ester, isooctyl oleate, Witconol 2301, trimellitate, ricinoleate ester.
4. multi-usage according to claim 1 and 2 is without carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: rust-preventive agent is Long carbon chain monocarboxylic acid, Long carbon chain di-carboxylic acid, 2,4,6-tri-(amino caproyl)-1, the composite antirust agent of one or more in one or more and monoisopropanolamine in 3,5-triazine, tolysulfonyl hexosamine, ring carboxylic propyl group oleic acid, diisopropanolamine (DIPA), tri-isopropanolamine.
5. multi-usage according to claim 1 and 2 is without carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: ashless extreme pressure additive is one or more in saturated collateralization esters polymer, stearic acid Imidazoline Borate, oleic imidazolinone boric acid ester, lauric acid imidazoline boric acid ester, polyisobutylene succinic acid imines, polyisobutylene succinic acid acid amides.
6. multi-usage according to claim 1 and 2 is without carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: metal corrosion inhibitor is one or more in benzotriazole, methyl benzotriazazole, first Benzotriazole Derivative, 2-amino-2-methyl-1-propanol, N-β-(aminoethyl)-γ-aminopropyltrimethoxysilane.
7. multi-usage according to claim 1 and 2 is without carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: tensio-active agent is one or more in imidazoline type amphoterics, beet alkali ampholytic surface active agent, amino acid type amphoteric surface active agent, alcohol ether carboxylate, methyl glucamine, isomery ten polyoxyethylenated alcohol, isomery undecyl alcohol Soxylat A 25-7, isomerous tridecanol polyoxyethylene ether, sulphosuccinates.
8. multi-usage according to claim 1 and 2 is without carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: assistant for emulsifying agent is one or more in propylene glycol, ethylene glycol, Dipropylene glycol mono-n-butyl Ether, high-carbon monohydroxy-alcohol.
9. multi-usage according to claim 1 and 2 is without carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: sterilant is N, N-methylene-bis morpholine, BIT, Kathon, MIT, 2-mercaptopyridine-1-are oxidized one or more in sodium salt, 3-iodo-2-propynyl-butyl carbamate.
10. multi-usage according to claim 1 and 2 is without carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: defoamer is one or more in Siloxane-Oxyalkylene Copolymers defoamer, polysiloxane defoamers, polyethers defoamer.
CN201510383807.2A 2015-07-03 2015-07-03 Multipurpose carbon-deposition-free environmental-friendly water soluble drawing lubricant Pending CN104928000A (en)

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106867645A (en) * 2017-02-04 2017-06-20 北京康普锡威科技有限公司 A kind of wire drawing liquid of graphene-containing and preparation method thereof
CN106929859A (en) * 2017-01-23 2017-07-07 中国第汽车股份有限公司 A kind of water-based antirust of residual less and preparation method thereof
CN108441293A (en) * 2018-03-15 2018-08-24 清华大学天津高端装备研究院 Hard water resistance semi-synthetic metal working fluid of one kind and preparation method thereof
CN108467770A (en) * 2018-05-09 2018-08-31 安徽润藤电缆材料科技有限公司 A kind of quick drawing wire drawing liquid of copper wire
CN108531274A (en) * 2018-05-09 2018-09-14 安徽润藤电缆材料科技有限公司 A kind of long-acting semi-emulsifying copper drawing fluid
CN109233986A (en) * 2018-11-02 2019-01-18 浙江师范大学 A kind of intelligent mobile terminal glass cover-plate all-synthetic grinding fluid and preparation method thereof
CN109504354A (en) * 2019-01-14 2019-03-22 中海石油(中国)有限公司上海分公司 A kind of lubricant, drilling fluid and its application
CN111233663A (en) * 2020-02-05 2020-06-05 新疆工程学院 Polyricinoleic acid modified trimellitate lubricating oil base oil and preparation method thereof
CN111423925A (en) * 2020-05-06 2020-07-17 上海尤希路化学工业有限公司 High-speed drawing liquid for preparing MT-grade tire steel cords with low die consumption, strong corrosion resistance and high cleanness
CN111778093A (en) * 2020-08-05 2020-10-16 陕西高精尖新材料科技有限责任公司 Titanium alloy wire high-temperature drawing oil-based lubricant and preparation method thereof
CN112300859A (en) * 2019-08-01 2021-02-02 东莞市绿博化工科技有限公司 Aluminum profile extrusion separating agent and preparation method thereof
CN113355172A (en) * 2021-06-08 2021-09-07 深圳市能效能汽车服务信息有限公司 Cleaning fluid composition for carbon deposition in fuel automobile engine and cleaning method
CN115261108A (en) * 2022-08-24 2022-11-01 苏州襄行新材料有限公司 Ultra-fine filament drawing lubricating liquid and preparation method thereof
CN115678654A (en) * 2022-10-21 2023-02-03 清华大学 Steel cord drawing fluid with low die consumption and low abrasion loss and preparation method thereof
CN116478756A (en) * 2023-03-10 2023-07-25 广州米奇化工有限公司 Cutting fluid and preparation method thereof

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CN103525529A (en) * 2013-10-15 2014-01-22 上海尤希路化学工业有限公司 High-performance environment-friendly water-soluble punching oil
CN103710106A (en) * 2013-12-14 2014-04-09 广西大学 Lubricant for drawing of beryllium and beryllium-alloy wires, rods and tubes

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US20080234152A1 (en) * 2004-02-25 2008-09-25 Idemitsu Kosan Co., Ltd. Alkyl Acetal Compound, Process for Producing the Same, and Lubricating Oil Composition
CN101892117A (en) * 2010-07-30 2010-11-24 湖北恒鑫化工有限公司 Water-based lubricant for drawing processing of brass-plated steel wire and preparation method thereof
CN102559350A (en) * 2011-12-28 2012-07-11 上海中孚特种油品有限公司 High-speed copper tube drawing lubricant and preparing method thereof
CN103525529A (en) * 2013-10-15 2014-01-22 上海尤希路化学工业有限公司 High-performance environment-friendly water-soluble punching oil
CN103710106A (en) * 2013-12-14 2014-04-09 广西大学 Lubricant for drawing of beryllium and beryllium-alloy wires, rods and tubes

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106929859A (en) * 2017-01-23 2017-07-07 中国第汽车股份有限公司 A kind of water-based antirust of residual less and preparation method thereof
CN106867645B (en) * 2017-02-04 2020-01-31 北京康普锡威科技有限公司 graphene-containing drawing fluid and preparation method thereof
CN106867645A (en) * 2017-02-04 2017-06-20 北京康普锡威科技有限公司 A kind of wire drawing liquid of graphene-containing and preparation method thereof
CN108441293A (en) * 2018-03-15 2018-08-24 清华大学天津高端装备研究院 Hard water resistance semi-synthetic metal working fluid of one kind and preparation method thereof
CN108467770A (en) * 2018-05-09 2018-08-31 安徽润藤电缆材料科技有限公司 A kind of quick drawing wire drawing liquid of copper wire
CN108531274A (en) * 2018-05-09 2018-09-14 安徽润藤电缆材料科技有限公司 A kind of long-acting semi-emulsifying copper drawing fluid
CN109233986A (en) * 2018-11-02 2019-01-18 浙江师范大学 A kind of intelligent mobile terminal glass cover-plate all-synthetic grinding fluid and preparation method thereof
CN109504354A (en) * 2019-01-14 2019-03-22 中海石油(中国)有限公司上海分公司 A kind of lubricant, drilling fluid and its application
CN112300859A (en) * 2019-08-01 2021-02-02 东莞市绿博化工科技有限公司 Aluminum profile extrusion separating agent and preparation method thereof
CN111233663A (en) * 2020-02-05 2020-06-05 新疆工程学院 Polyricinoleic acid modified trimellitate lubricating oil base oil and preparation method thereof
CN111233663B (en) * 2020-02-05 2023-02-21 新疆工程学院 Polyricinoleic acid modified trimellitate lubricating oil base oil and preparation method thereof
CN111423925A (en) * 2020-05-06 2020-07-17 上海尤希路化学工业有限公司 High-speed drawing liquid for preparing MT-grade tire steel cords with low die consumption, strong corrosion resistance and high cleanness
CN111778093A (en) * 2020-08-05 2020-10-16 陕西高精尖新材料科技有限责任公司 Titanium alloy wire high-temperature drawing oil-based lubricant and preparation method thereof
CN113355172A (en) * 2021-06-08 2021-09-07 深圳市能效能汽车服务信息有限公司 Cleaning fluid composition for carbon deposition in fuel automobile engine and cleaning method
CN115261108A (en) * 2022-08-24 2022-11-01 苏州襄行新材料有限公司 Ultra-fine filament drawing lubricating liquid and preparation method thereof
CN115678654A (en) * 2022-10-21 2023-02-03 清华大学 Steel cord drawing fluid with low die consumption and low abrasion loss and preparation method thereof
CN115678654B (en) * 2022-10-21 2024-03-26 清华大学 Low-die-consumption low-abrasion-loss steel cord wiredrawing liquid and preparation method thereof
CN116478756A (en) * 2023-03-10 2023-07-25 广州米奇化工有限公司 Cutting fluid and preparation method thereof

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Application publication date: 20150923