CN104928000A - Multipurpose carbon-deposition-free environmental-friendly water soluble drawing lubricant - Google Patents
Multipurpose carbon-deposition-free environmental-friendly water soluble drawing lubricant Download PDFInfo
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- CN104928000A CN104928000A CN201510383807.2A CN201510383807A CN104928000A CN 104928000 A CN104928000 A CN 104928000A CN 201510383807 A CN201510383807 A CN 201510383807A CN 104928000 A CN104928000 A CN 104928000A
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- friendly water
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- carbon distribution
- acid
- soluble drawing
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 8
- 239000000314 lubricant Substances 0.000 title abstract 3
- -1 ester compound Chemical class 0.000 claims abstract description 38
- 239000013530 defoamer Substances 0.000 claims abstract description 14
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 239000002184 metal Substances 0.000 claims abstract description 9
- 239000005069 Extreme pressure additive Substances 0.000 claims abstract description 8
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- 239000002199 base oil Substances 0.000 claims abstract description 7
- 238000005260 corrosion Methods 0.000 claims abstract description 7
- 230000007797 corrosion Effects 0.000 claims abstract description 7
- 239000003112 inhibitor Substances 0.000 claims abstract description 7
- 239000013556 antirust agent Substances 0.000 claims abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 20
- 229910052799 carbon Inorganic materials 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 18
- 239000003921 oil Substances 0.000 claims description 17
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 8
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 8
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 7
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 7
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 7
- 239000005642 Oleic acid Substances 0.000 claims description 7
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 7
- 229920002367 Polyisobutene Polymers 0.000 claims description 7
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 7
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 7
- 239000001384 succinic acid Substances 0.000 claims description 7
- 239000013543 active substance Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 claims description 6
- 229940043276 diisopropanolamine Drugs 0.000 claims description 6
- 239000003995 emulsifying agent Substances 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 claims description 6
- 239000002585 base Substances 0.000 claims description 5
- POULHZVOKOAJMA-UHFFFAOYSA-N methyl undecanoic acid Natural products CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 5
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 claims description 4
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 4
- WMDZKDKPYCNCDZ-UHFFFAOYSA-N 2-(2-butoxypropoxy)propan-1-ol Chemical compound CCCCOC(C)COC(C)CO WMDZKDKPYCNCDZ-UHFFFAOYSA-N 0.000 claims description 4
- SAUIGQBKPDQYHL-QXMHVHEDSA-N 6-methylheptyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCCCC(C)C SAUIGQBKPDQYHL-QXMHVHEDSA-N 0.000 claims description 4
- 241000722946 Acanthocybium solandri Species 0.000 claims description 4
- 239000005639 Lauric acid Substances 0.000 claims description 4
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 4
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 229940049964 oleate Drugs 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 239000001294 propane Substances 0.000 claims description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 claims description 3
- MSWZFWKMSRAUBD-UHFFFAOYSA-N 2-Amino-2-Deoxy-Hexose Chemical compound NC1C(O)OC(CO)C(O)C1O MSWZFWKMSRAUBD-UHFFFAOYSA-N 0.000 claims description 3
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 3
- 229940099451 3-iodo-2-propynylbutylcarbamate Drugs 0.000 claims description 3
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 claims description 3
- 235000016068 Berberis vulgaris Nutrition 0.000 claims description 3
- 241000335053 Beta vulgaris Species 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 3
- MBBZMMPHUWSWHV-BDVNFPICSA-N N-methylglucamine Chemical compound CNC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO MBBZMMPHUWSWHV-BDVNFPICSA-N 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 150000001413 amino acids Chemical class 0.000 claims description 3
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 3
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 claims description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 3
- 239000012964 benzotriazole Substances 0.000 claims description 3
- 125000003354 benzotriazolyl group Chemical class N1N=NC2=C1C=CC=C2* 0.000 claims description 3
- JEJCUBGTTOKYHG-UHFFFAOYSA-N boric acid;4,5-dihydro-1h-imidazole Chemical compound OB(O)O.C1CN=CN1 JEJCUBGTTOKYHG-UHFFFAOYSA-N 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 3
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 229940066675 ricinoleate Drugs 0.000 claims description 3
- 159000000000 sodium salts Chemical class 0.000 claims description 3
- 239000008117 stearic acid Substances 0.000 claims description 3
- 125000005591 trimellitate group Chemical group 0.000 claims description 3
- 229940057402 undecyl alcohol Drugs 0.000 claims description 3
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 2
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 239000007957 coemulsifier Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 208000028659 discharge Diseases 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses a multipurpose carbon-deposition-free environmental-friendly water soluble drawing lubricant which consists of base oil, a synthetic ester compound, an antirust agent, an ashless anti-wear extreme pressure additive, a metal corrosion inhibitor, a surfactant, a co-emulsifier, a bactericide, a defoamer and water. The multipurpose carbon-deposition-free environmental-friendly water soluble drawing lubricant disclosed by the invention is excellent in performance and convenient to prepare.
Description
Technical field
The present invention relates to a kind of water-soluble drawing compound.
Background technology
So-called drawing process is exactly under external broach effect, makes metal stock by nib, obtains the plastic processing method of respective shapes and gauge articles.Due to technique, the reason such as backward in technique, also there is some problems demand and solve in the domestic water-soluble drawing compound being used in drawing process at present.One is that oilness and extreme pressure anti-wear are poor, cause drawing mould and drawable material area carbon and greasy dirt in drawing process more, not only have a strong impact on luminance brightness and the cleanliness factor on drawable material surface, and exacerbate the wearing and tearing of drawing mould, shorten its work-ing life; Two is that biodegradability is poor, causes the easy smelly raw bacterium of emulsion, and the waste liquid also not easily biochemical treatment of discharge, is detrimental to health, serious environment pollution; Three is that range of application is narrow, can not meet the drawing process requirement of multiple pipe, line, bar.
Summary of the invention
The object of the present invention is to provide a kind of multi-usage of excellent performance without carbon distribution environment-friendly water-soluble drawing compound.
Technical solution of the present invention is:
A kind of multi-usage, without carbon distribution environment-friendly water-soluble drawing compound, is characterized in that: be grouped into by the one-tenth of following weight percents:
Base oil ... 5 ~ 15%
Synthetic ester compound ... 5 ~ 20%
Rust-preventive agent ... 5 ~ 20%
Ashless extreme pressure additive ... 2 ~ 10%
Metal corrosion inhibitor ... 0.1 ~ 5%
Tensio-active agent ... 2 ~ 10%
Assistant for emulsifying agent ... 0.1 ~ 5%
Sterilant ... 0.1 ~ 3%
Defoamer ... 0.1 ~ 1%
Water ... surplus.
Base oil is one or more in No. 10 white oils, No. 15 white oils, No. 26 white oils, No. 32 white oils, naphthenic base white oil.
Synthetic ester compound is one or more in tricarboxymethyl propane oleate, TriMethylolPropane(TMP) cocinin, PETO, dipentaerythritol oleic acid ester, isooctyl oleate, Witconol 2301, trimellitate, ricinoleate ester.
Rust-preventive agent is Long carbon chain monocarboxylic acid, Long carbon chain di-carboxylic acid, 2,4,6-tri-(amino caproyl)-1, the composite antirust agent of one or more in one or more and monoisopropanolamine in 3,5-triazine, tolysulfonyl hexosamine, ring carboxylic propyl group oleic acid, diisopropanolamine (DIPA), tri-isopropanolamine.
Ashless extreme pressure additive is one or more in saturated collateralization esters polymer, stearic acid Imidazoline Borate, oleic imidazolinone boric acid ester, lauric acid imidazoline boric acid ester, polyisobutylene succinic acid imines, polyisobutylene succinic acid acid amides.
Metal corrosion inhibitor is one or more in benzotriazole, methyl benzotriazazole, first Benzotriazole Derivative, 2-amino-2-methyl-1-propanol, N-β-(aminoethyl)-γ-aminopropyltrimethoxysilane.
Tensio-active agent is one or more in imidazoline type amphoterics, beet alkali ampholytic surface active agent, amino acid type amphoteric surface active agent, alcohol ether carboxylate, methyl glucamine, isomery ten polyoxyethylenated alcohol, isomery undecyl alcohol Soxylat A 25-7, isomerous tridecanol polyoxyethylene ether, sulphosuccinates.
Assistant for emulsifying agent is one or more in propylene glycol, ethylene glycol, Dipropylene glycol mono-n-butyl Ether, high-carbon monohydroxy-alcohol.
Sterilant is N, N-methylene-bis morpholine, BIT, Kathon, MIT, 2-mercaptopyridine-1-are oxidized one or more in sodium salt, 3-iodo-2-propynyl-butyl carbamate.
Defoamer is one or more in Siloxane-Oxyalkylene Copolymers defoamer, polysiloxane defoamers, polyethers defoamer.
Advantage of the present invention:
1. the ashless extreme pressure additive group 5 of high molecular polymerization ester that this product synthetic ester compound, abrasion resistant extreme-pressure performance of selecting multiple lubricity good is superpower, product has extremely strong lubricity (5% diluent tapping torque≤300Ncm) and abrasion resistant extreme-pressure performance (workpiece surface roughness Ra≤1.0 μm), and in the course of processing, drawing mould and drawable material are without carbon distribution and greasy dirt.
2. this product is selected multiple biology easily to degrade and is resisted antibacterial synthetic ester compound, high molecular polymerization ester, novel surfactant compound thing group 5, product has excellent biodegradability and anti-biocidal property, its BOD(biological oxygen demand (BOD) of 5% diluent)/COD(chemical oxygen demand) >=0.7, use annual bacterium number≤102, the waste liquid of discharge can biochemical treatment ability strong, on HUMAN HEALTH and environmental safety impact little.
3. Products Compatibility is strong, can meet the drawing process requirement of stainless steel, carbon steel, pipe such as various metals such as conjunction conjunction steel, aluminium alloy etc., line, bar, applied range.
Below in conjunction with embodiment, the invention will be further described.
Embodiment
Embodiment 1:
A kind of multi-usage, without carbon distribution environment-friendly water-soluble drawing compound, is mixed together by the composition of following weight percents:
Naphthenic base white oil 10.0%
5# paraffinic base white oil 5.0%
PETO 5.0%
Isooctyl oleate 5.0%
Tricarboxymethyl propane oleate 10.0%
2,4,6-tri-(amino caproyl)-1,3,5-triazines 3.0%
Bay diacid 2.0%
Ring carboxylic propyl group oleic acid 2.0%
Monoisopropanolamine 5.0%
Tri-isopropanolamine 10.0%
Polyisobutylene succinic acid acid amides 5.0%
Saturated collateralization esters polymer GY-25 5.0%
N-β-(aminoethyl)-γ-aminopropyltrimethoxysilane 1.0%
Methyl benzotriazazole 0.2%
Lauric acid imidazoline type amphoterics 1.0%
Isomerous tridecanol polyoxyethylene ether 2.0%
Sulphosuccinates 3.0%
Alcohol ether carboxylate 1.0%
Dipropylene glycol mono-n-butyl Ether 1.0%
MIT 3.0%
Siloxane-Oxyalkylene Copolymers defoamer 1.0%
All the other compositions are water.
Embodiment 2:
A kind of multi-usage, without carbon distribution environment-friendly water-soluble drawing compound, is mixed together by the composition of following weight percents:
Base oil ... 5 ~ 15%(example 5%, 10%, 15%)
Synthetic ester compound ... 5 ~ 20%(example 5%, 10%, 20%)
Rust-preventive agent ... 5 ~ 20%(example 5%, 15%, 20%)
Ashless extreme pressure additive ... 2 ~ 10%(example 2%, 6%, 10%)
Metal corrosion inhibitor ... 0.1 ~ 5%(example 0.1%, 2%, 5%)
Tensio-active agent ... 2 ~ 10%(example 5%, 10%, 15%)
Assistant for emulsifying agent ... 0.1 ~ 5%(example 0.1%, 2%, 5%)
Sterilant ... 0.1 ~ 3%(example 0.1%, 2%, 3%)
Defoamer ... 0.1 ~ 1%(example 0.1%, 0.5%, 1%)
Water ... surplus.
Base oil is one or more in No. 10 white oils, No. 15 white oils, No. 26 white oils, No. 32 white oils, naphthenic base white oil.
Synthetic ester compound is one or more in tricarboxymethyl propane oleate, TriMethylolPropane(TMP) cocinin, PETO, dipentaerythritol oleic acid ester, isooctyl oleate, Witconol 2301, trimellitate, ricinoleate ester.
Rust-preventive agent is Long carbon chain monocarboxylic acid, Long carbon chain di-carboxylic acid, 2,4,6-tri-(amino caproyl)-1, the composite antirust agent of one or more in one or more and monoisopropanolamine in 3,5-triazine, tolysulfonyl hexosamine, ring carboxylic propyl group oleic acid, diisopropanolamine (DIPA), tri-isopropanolamine.
Ashless extreme pressure additive is one or more in saturated collateralization esters polymer, stearic acid Imidazoline Borate, oleic imidazolinone boric acid ester, lauric acid imidazoline boric acid ester, polyisobutylene succinic acid imines, polyisobutylene succinic acid acid amides.
Metal corrosion inhibitor is one or more in benzotriazole, methyl benzotriazazole, first Benzotriazole Derivative, 2-amino-2-methyl-1-propanol, N-β-(aminoethyl)-γ-aminopropyltrimethoxysilane.
Tensio-active agent is one or more in imidazoline type amphoterics, beet alkali ampholytic surface active agent, amino acid type amphoteric surface active agent, alcohol ether carboxylate, methyl glucamine, isomery ten polyoxyethylenated alcohol, isomery undecyl alcohol Soxylat A 25-7, isomerous tridecanol polyoxyethylene ether, sulphosuccinates.
Assistant for emulsifying agent is one or more in propylene glycol, ethylene glycol, Dipropylene glycol mono-n-butyl Ether, high-carbon monohydroxy-alcohol.
Sterilant is N, N-methylene-bis morpholine, BIT, Kathon, MIT, 2-mercaptopyridine-1-are oxidized one or more in sodium salt, 3-iodo-2-propynyl-butyl carbamate.
Defoamer is one or more in Siloxane-Oxyalkylene Copolymers defoamer, polysiloxane defoamers, polyethers defoamer.
Claims (10)
1. multi-usage is without a carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: be grouped into by the one-tenth of following weight percents:
Base oil ... 5 ~ 15%
Synthetic ester compound ... 5 ~ 20%
Rust-preventive agent ... 5 ~ 20%
Ashless extreme pressure additive ... 2 ~ 10%
Metal corrosion inhibitor ... 0.1 ~ 5%
Tensio-active agent ... 2 ~ 10%
Assistant for emulsifying agent ... 0.1 ~ 5%
Sterilant ... 0.1 ~ 3%
Defoamer ... 0.1 ~ 1%
Water ... surplus.
2. multi-usage according to claim 1 is without carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: base oil is one or more in No. 10 white oils, No. 15 white oils, No. 26 white oils, No. 32 white oils, naphthenic base white oil.
3. multi-usage according to claim 1 and 2 is without carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: synthetic ester compound is one or more in tricarboxymethyl propane oleate, TriMethylolPropane(TMP) cocinin, PETO, dipentaerythritol oleic acid ester, isooctyl oleate, Witconol 2301, trimellitate, ricinoleate ester.
4. multi-usage according to claim 1 and 2 is without carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: rust-preventive agent is Long carbon chain monocarboxylic acid, Long carbon chain di-carboxylic acid, 2,4,6-tri-(amino caproyl)-1, the composite antirust agent of one or more in one or more and monoisopropanolamine in 3,5-triazine, tolysulfonyl hexosamine, ring carboxylic propyl group oleic acid, diisopropanolamine (DIPA), tri-isopropanolamine.
5. multi-usage according to claim 1 and 2 is without carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: ashless extreme pressure additive is one or more in saturated collateralization esters polymer, stearic acid Imidazoline Borate, oleic imidazolinone boric acid ester, lauric acid imidazoline boric acid ester, polyisobutylene succinic acid imines, polyisobutylene succinic acid acid amides.
6. multi-usage according to claim 1 and 2 is without carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: metal corrosion inhibitor is one or more in benzotriazole, methyl benzotriazazole, first Benzotriazole Derivative, 2-amino-2-methyl-1-propanol, N-β-(aminoethyl)-γ-aminopropyltrimethoxysilane.
7. multi-usage according to claim 1 and 2 is without carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: tensio-active agent is one or more in imidazoline type amphoterics, beet alkali ampholytic surface active agent, amino acid type amphoteric surface active agent, alcohol ether carboxylate, methyl glucamine, isomery ten polyoxyethylenated alcohol, isomery undecyl alcohol Soxylat A 25-7, isomerous tridecanol polyoxyethylene ether, sulphosuccinates.
8. multi-usage according to claim 1 and 2 is without carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: assistant for emulsifying agent is one or more in propylene glycol, ethylene glycol, Dipropylene glycol mono-n-butyl Ether, high-carbon monohydroxy-alcohol.
9. multi-usage according to claim 1 and 2 is without carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: sterilant is N, N-methylene-bis morpholine, BIT, Kathon, MIT, 2-mercaptopyridine-1-are oxidized one or more in sodium salt, 3-iodo-2-propynyl-butyl carbamate.
10. multi-usage according to claim 1 and 2 is without carbon distribution environment-friendly water-soluble drawing compound, it is characterized in that: defoamer is one or more in Siloxane-Oxyalkylene Copolymers defoamer, polysiloxane defoamers, polyethers defoamer.
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CN201510383807.2A CN104928000A (en) | 2015-07-03 | 2015-07-03 | Multipurpose carbon-deposition-free environmental-friendly water soluble drawing lubricant |
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CN201510383807.2A CN104928000A (en) | 2015-07-03 | 2015-07-03 | Multipurpose carbon-deposition-free environmental-friendly water soluble drawing lubricant |
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Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080234152A1 (en) * | 2004-02-25 | 2008-09-25 | Idemitsu Kosan Co., Ltd. | Alkyl Acetal Compound, Process for Producing the Same, and Lubricating Oil Composition |
CN101892117A (en) * | 2010-07-30 | 2010-11-24 | 湖北恒鑫化工有限公司 | Water-based lubricant for drawing processing of brass-plated steel wire and preparation method thereof |
CN102559350A (en) * | 2011-12-28 | 2012-07-11 | 上海中孚特种油品有限公司 | High-speed copper tube drawing lubricant and preparing method thereof |
CN103525529A (en) * | 2013-10-15 | 2014-01-22 | 上海尤希路化学工业有限公司 | High-performance environment-friendly water-soluble punching oil |
CN103710106A (en) * | 2013-12-14 | 2014-04-09 | 广西大学 | Lubricant for drawing of beryllium and beryllium-alloy wires, rods and tubes |
-
2015
- 2015-07-03 CN CN201510383807.2A patent/CN104928000A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080234152A1 (en) * | 2004-02-25 | 2008-09-25 | Idemitsu Kosan Co., Ltd. | Alkyl Acetal Compound, Process for Producing the Same, and Lubricating Oil Composition |
CN101892117A (en) * | 2010-07-30 | 2010-11-24 | 湖北恒鑫化工有限公司 | Water-based lubricant for drawing processing of brass-plated steel wire and preparation method thereof |
CN102559350A (en) * | 2011-12-28 | 2012-07-11 | 上海中孚特种油品有限公司 | High-speed copper tube drawing lubricant and preparing method thereof |
CN103525529A (en) * | 2013-10-15 | 2014-01-22 | 上海尤希路化学工业有限公司 | High-performance environment-friendly water-soluble punching oil |
CN103710106A (en) * | 2013-12-14 | 2014-04-09 | 广西大学 | Lubricant for drawing of beryllium and beryllium-alloy wires, rods and tubes |
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CN109504354A (en) * | 2019-01-14 | 2019-03-22 | 中海石油(中国)有限公司上海分公司 | A kind of lubricant, drilling fluid and its application |
CN112300859A (en) * | 2019-08-01 | 2021-02-02 | 东莞市绿博化工科技有限公司 | Aluminum profile extrusion separating agent and preparation method thereof |
CN111233663A (en) * | 2020-02-05 | 2020-06-05 | 新疆工程学院 | Polyricinoleic acid modified trimellitate lubricating oil base oil and preparation method thereof |
CN111233663B (en) * | 2020-02-05 | 2023-02-21 | 新疆工程学院 | Polyricinoleic acid modified trimellitate lubricating oil base oil and preparation method thereof |
CN111423925A (en) * | 2020-05-06 | 2020-07-17 | 上海尤希路化学工业有限公司 | High-speed drawing liquid for preparing MT-grade tire steel cords with low die consumption, strong corrosion resistance and high cleanness |
CN111778093A (en) * | 2020-08-05 | 2020-10-16 | 陕西高精尖新材料科技有限责任公司 | Titanium alloy wire high-temperature drawing oil-based lubricant and preparation method thereof |
CN113355172A (en) * | 2021-06-08 | 2021-09-07 | 深圳市能效能汽车服务信息有限公司 | Cleaning fluid composition for carbon deposition in fuel automobile engine and cleaning method |
CN115261108A (en) * | 2022-08-24 | 2022-11-01 | 苏州襄行新材料有限公司 | Ultra-fine filament drawing lubricating liquid and preparation method thereof |
CN115678654A (en) * | 2022-10-21 | 2023-02-03 | 清华大学 | Steel cord drawing fluid with low die consumption and low abrasion loss and preparation method thereof |
CN115678654B (en) * | 2022-10-21 | 2024-03-26 | 清华大学 | Low-die-consumption low-abrasion-loss steel cord wiredrawing liquid and preparation method thereof |
CN116478756A (en) * | 2023-03-10 | 2023-07-25 | 广州米奇化工有限公司 | Cutting fluid and preparation method thereof |
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