CN103725378B - The lubricant of drawing best bright finish aluminium and aluminium alloy pipe - Google Patents
The lubricant of drawing best bright finish aluminium and aluminium alloy pipe Download PDFInfo
- Publication number
- CN103725378B CN103725378B CN201310701762.XA CN201310701762A CN103725378B CN 103725378 B CN103725378 B CN 103725378B CN 201310701762 A CN201310701762 A CN 201310701762A CN 103725378 B CN103725378 B CN 103725378B
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- CN
- China
- Prior art keywords
- agent
- aluminium
- lubricant
- oil
- alloy pipe
- Prior art date
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- Expired - Fee Related
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- 239000000314 lubricant Substances 0.000 title claims abstract description 14
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 9
- 239000004411 aluminium Substances 0.000 title claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- -1 friction improver Substances 0.000 claims abstract description 11
- 229910052751 metal Inorganic materials 0.000 claims abstract description 7
- 239000002184 metal Substances 0.000 claims abstract description 7
- 239000003921 oil Substances 0.000 claims abstract description 7
- 239000010729 system oil Substances 0.000 claims abstract description 7
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 5
- 238000005282 brightening Methods 0.000 claims abstract description 5
- 239000003112 inhibitor Substances 0.000 claims abstract description 5
- 230000003647 oxidation Effects 0.000 claims abstract description 5
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 5
- 239000000654 additive Substances 0.000 claims abstract description 3
- 230000000996 additive effect Effects 0.000 claims abstract description 3
- 239000002131 composite material Substances 0.000 claims abstract description 3
- QVXGKJYMVLJYCL-UHFFFAOYSA-N 2,3-di(nonyl)-N-phenylaniline Chemical compound C(CCCCCCCC)C=1C(=C(C=CC1)NC1=CC=CC=C1)CCCCCCCCC QVXGKJYMVLJYCL-UHFFFAOYSA-N 0.000 claims description 5
- 229920002367 Polyisobutene Polymers 0.000 claims description 5
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical group CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 5
- IKCOOALACZVGLI-GNOQXXQHSA-K bis[[(z)-octadec-9-enoyl]oxy]alumanyl (z)-octadec-9-enoate Chemical compound [Al+3].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O IKCOOALACZVGLI-GNOQXXQHSA-K 0.000 claims description 5
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 150000003014 phosphoric acid esters Chemical group 0.000 claims description 5
- 229920002545 silicone oil Polymers 0.000 claims description 5
- 150000003852 triazoles Chemical class 0.000 claims description 4
- 239000002199 base oil Substances 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 5
- 238000005299 abrasion Methods 0.000 abstract description 4
- 238000001816 cooling Methods 0.000 abstract description 4
- 230000008698 shear stress Effects 0.000 abstract description 4
- 238000000034 method Methods 0.000 description 5
- SJTOTXNQRUESGY-KVVVOXFISA-N (z)-octadec-9-enoic acid;oxalic acid Chemical group OC(=O)C(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O SJTOTXNQRUESGY-KVVVOXFISA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- MZWDAEVXPZRJTQ-WUXMJOGZSA-N 4-[(e)-(4-fluorophenyl)methylideneamino]-3-methyl-1h-1,2,4-triazole-5-thione Chemical compound CC1=NNC(=S)N1\N=C\C1=CC=C(F)C=C1 MZWDAEVXPZRJTQ-WUXMJOGZSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011796 hollow space material Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
A kind of lubricant of drawing best bright finish aluminium and aluminium alloy pipe, employing is oil based on No. 46 total loss system oil, coordinate multiple composite additive, comprise oiliness improver, anti-wear agent, extreme pressure agent, kilfoam, oxidation inhibitor, friction improver, metal passivator, brightening agent, auxiliary agent.The lubricant of drawing best bright finish aluminium and aluminium alloy pipe of the present invention, there is stronger adhesivity, strength of lubricant film is large, resistance to abrasion and sticky warm nature good, extreme pressure property is strong, cooling, cleaning and oilness are good, reduces the wearing and tearing of drawing device and drawing-die, has less flowing shear-stress, improve metallic surface smooth finish and specification precision, have certain chemical stability and minimizing to occur the features such as oil mark.
Description
Technical field
The invention belongs to the field of lubricant of non-ferrous metal drawing processing, especially drawing best bright finish aluminium and aluminium alloy pipe.
Background technology
Drawing is one of main production process of tubing, bar, section bar and wire rod.By article section shape, drawing can be divided into: solid material drawing and the large class of hollow material drawing two.Drawing aluminum pipe imposes pulling force to aluminum pipe blank, makes it by nib to obtain the plastic processing method with nib sectional dimension, goods that shape is identical.
In drawing process, except material, friction between drawing-die and steel core, on the contact surface because drawing speed improves, will occurrence temperature sharply rise.Heavy wear or sintering is there is, the effect thus requiring lubricant to play antifriction and prevent wearing and tearing, cool, lubricate in order to reduce in drawing process; Be improved drawing speed and section reduction rate simultaneously, to improve the seed output and quality of drawing process processing, prevent the generation of the defect such as surface tear, fold, bending, bias, crackle, broken end, metal press-in.Guarantee that the aluminium and aluminium alloy pipe after drawing has best bright finish.
And the factor affecting aluminum pipe drawing has usually: aluminum pipe character (hardness, degree of cleaning, condition of surface); The material kind of drawing and drawing-die; The adaptability of drawing compound.Due to the difference of the mode of drawing, condition and range of product, also there is difference to the requirement of lubricant.But usually require that there is stronger adhesivity, strength of lubricant film is large, resistance to abrasion and sticky warm nature good, extreme pressure property is strong, cooling, cleaning and oilness are good, reduce the wearing and tearing of drawing device and drawing-die, there is less flowing shear-stress, improve metallic surface smooth finish and specification precision, have certain chemical stability and minimizing to occur the features such as oil mark.And lubricating method usually can adopt immersion, brush, roll be stained with, traction or circulation etc.Therefore, drawing compound should meet many-sided requirements such as drawing process condition, industrial safety, economy, environmental friendliness, energy-conservation, reduction of discharging.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind ofly has stronger adhesivity, strength of lubricant film is large, resistance to abrasion and sticky warm nature good, extreme pressure property is strong, cooling, cleaning and oilness are good, reduce the wearing and tearing of drawing device and drawing-die, there is less flowing shear-stress, improve metallic surface smooth finish and specification precision, have certain chemical stability and reduce the lubricant occurring the drawing best bright finish aluminium and aluminium alloy pipe of oil mark etc.
The present invention solves the problems of the technologies described above by following technical scheme: employing is oil based on No. 46 total loss system oil, and coordinate multiple composite additive, its each component and mass percent are:
| Component | Content (mass percent) |
| Base oil | Surplus |
| Oiliness improver | 3.0～5.0 |
| Anti-wear agent | 5.0～6.0 |
| Extreme pressure agent | 3.0～5.0 |
| Metal passivator | 0.3～0.5 |
| Oxidation inhibitor | 0.5～1.2 |
| Kilfoam | 0.005～0.01 |
| Friction improver | 5.0～8.0 |
| Brightening agent | 0.5～1.0 |
| Auxiliary agent | 3.0～5.0 |
Base oil is No. 46 total loss system oil.
Oiliness improver is oleic acid oxalic acid ester.
Anti-wear agent is tritolyl phosphate.
Extreme pressure agent is boronation phosphamidon ester.
Metal passivator is 124 Triazole derivative.
Oxidation inhibitor is the dinonyldiphenylamine of mass ratio 60% ~ 50% and 2, the 6-di-t-butyl mixed ester compounds of 40% ~ 50%.
Kilfoam is dimethyl silicone oil.
Friction improver is phosphoric acid ester.
Brightening agent is tetrahydroglyoxaline aluminium oleate.
Auxiliary agent is polyisobutene.
The lubricant of drawing best bright finish aluminium and aluminium alloy pipe of the present invention, there is stronger adhesivity, strength of lubricant film is large, resistance to abrasion and sticky warm nature good, extreme pressure property is strong, cooling, cleaning and oilness are good, reduces the wearing and tearing of drawing device and drawing-die, has less flowing shear-stress, improve metallic surface smooth finish and specification precision, have certain chemical stability and minimizing to occur the features such as oil mark.
Embodiment
Embodiment 1:
Following component is in harmonious proportion by mass percentage and forms:
| Component | Content (mass percent) |
| No. 46 total loss system oil | 68.29 |
| Oleic acid oxalic acid ester | 5.0 |
| Tritolyl phosphate | 6.0 |
| Boronation phosphamidon ester | 5.0 |
| 124 Triazole derivative | 0.5 |
| The dinonyldiphenylamine of mass ratio 60% and 2, the 6-di-t-butyl mixed ester compounds of 40% | 1.2 |
| Dimethyl silicone oil | 0.01 |
| Phosphoric acid ester | 8.0 |
| Tetrahydroglyoxaline aluminium oleate | 1.0 |
| Polyisobutene | 5.0 |
Above component summation is 100%.
Embodiment 2:
Following component is in harmonious proportion by mass percentage and forms:
| Component | Content (mass percent) |
| No. 46 total loss system oil | 73.9925 |
| Oleic acid oxalic acid ester | 4.0 |
| Tritolyl phosphate | 5.5 |
| Boronation phosphamidon ester | 4.0 |
| 124 Triazole derivative | 0.4 |
| The dinonyldiphenylamine of mass ratio 55% and 2, the 6-di-t-butyl mixed ester compounds of 45% | 0.85 |
| Dimethyl silicone oil | 0.0075 |
| Phosphoric acid ester | 6.5 |
| Tetrahydroglyoxaline aluminium oleate | 0.75 |
| Polyisobutene | 4.0 |
Above component summation is 100%.
Embodiment 3:
Following component is in harmonious proportion by mass percentage and forms:
| Component | Content (mass percent) |
| No. 46 total loss system oil | 79.695 |
| Oleic acid oxalic acid ester | 3.0 |
| Tritolyl phosphate | 5.0 |
| Boronation phosphamidon ester | 3.0 |
| 124 Triazole derivative | 0.3 |
| The dinonyldiphenylamine of mass ratio 50% and 2, the 6-di-t-butyl mixed ester compounds of 50% | 0.5 |
| Dimethyl silicone oil | 0.005 |
| Phosphoric acid ester | 5.0 |
| Tetrahydroglyoxaline aluminium oleate | 0.5 |
| Polyisobutene | 3.0 |
Above component summation is 100%.
The main physical and chemical index of embodiment 2 product is:
| Project | Quality index |
| Moisture, % | Vestige |
| 40 DEG C of kinematic viscosity mm 2/s | 48.5 |
| Flash-point (opening) DEG C, | 210 |
| Mechanical impurity, % | Nothing |
| Last non seizure load (Pb), Kg | 110 |
| Pour point, DEG C, | -5 |
| Water soluble acid or alkali | Nothing |
| Corrosion test (copper sheet, 100 DEG C, 3h), level | 1 |
| Viscosity index, is not less than | 110 |
Claims (1)
1. a lubricant for drawing best bright finish aluminium and aluminium alloy pipe, it is characterized in that employing is oil based on No. 46 total loss system oil, coordinate multiple composite additive, its each component and mass percent are:
Wherein:
Anti-wear agent is tritolyl phosphate;
Extreme pressure agent is boronation phosphamidon ester;
Metal passivator is 124 Triazole derivative;
Oxidation inhibitor is the dinonyldiphenylamine of mass ratio 60% ~ 50% and 2, the 6-di-t-butyl mixed ester compounds of 40% ~ 50%;
Kilfoam is dimethyl silicone oil;
Friction improver is phosphoric acid ester;
Brightening agent is tetrahydroglyoxaline aluminium oleate;
Auxiliary agent is polyisobutene.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310701762.XA CN103725378B (en) | 2013-12-18 | 2013-12-18 | The lubricant of drawing best bright finish aluminium and aluminium alloy pipe |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310701762.XA CN103725378B (en) | 2013-12-18 | 2013-12-18 | The lubricant of drawing best bright finish aluminium and aluminium alloy pipe |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103725378A CN103725378A (en) | 2014-04-16 |
| CN103725378B true CN103725378B (en) | 2015-10-07 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310701762.XA Expired - Fee Related CN103725378B (en) | 2013-12-18 | 2013-12-18 | The lubricant of drawing best bright finish aluminium and aluminium alloy pipe |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103725378B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104946366A (en) * | 2015-07-20 | 2015-09-30 | 广西大学 | Composition of drawing lubricating agent for aluminum and alloy wire rods of aluminum |
| CN105038929A (en) * | 2015-07-20 | 2015-11-11 | 广西大学 | Monel alloy plate strip cold rolling lubricant composition |
| CN104962364A (en) * | 2015-07-20 | 2015-10-07 | 广西大学 | Niobium wire drawing lubricant composition |
| CN104974834A (en) * | 2015-07-20 | 2015-10-14 | 广西大学 | Rhenium filament drawing lubricant composition |
| CN104962368A (en) * | 2015-07-20 | 2015-10-07 | 广西大学 | Rhenium bar rotary-swaging lubricant composition |
| CN104974840A (en) * | 2015-07-20 | 2015-10-14 | 广西大学 | Hafnium wire drawing lubricant composition |
| CN104974836A (en) * | 2015-07-20 | 2015-10-14 | 广西大学 | Zirconium wire drawing lubricant composition |
| CN104974843A (en) * | 2015-07-20 | 2015-10-14 | 广西大学 | Tungsten-rhenium filament drawing lubricant composition |
| CN104962369A (en) * | 2015-07-20 | 2015-10-07 | 广西大学 | Lubricant composition for drawing tantalum filament |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103421587A (en) * | 2013-08-26 | 2013-12-04 | 广西大学 | Magnesium and magnesium alloy sheet strip cold rolling lubricating agent |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002020704A1 (en) * | 2000-09-05 | 2002-03-14 | Honda Motor Co., Ltd. | Aqueous one step type lubricating agent for efficient cold forging |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103421587A (en) * | 2013-08-26 | 2013-12-04 | 广西大学 | Magnesium and magnesium alloy sheet strip cold rolling lubricating agent |
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| Publication number | Publication date |
|---|---|
| CN103725378A (en) | 2014-04-16 |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
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Granted publication date: 20151007 |