CN101811173A - Graphite-free high-performance environment-friendly hot forging processing liquid - Google Patents
Graphite-free high-performance environment-friendly hot forging processing liquid Download PDFInfo
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- CN101811173A CN101811173A CN 201010163678 CN201010163678A CN101811173A CN 101811173 A CN101811173 A CN 101811173A CN 201010163678 CN201010163678 CN 201010163678 CN 201010163678 A CN201010163678 A CN 201010163678A CN 101811173 A CN101811173 A CN 101811173A
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- CN
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- Prior art keywords
- graphite
- processing liquid
- hot forging
- forging processing
- friendly hot
- Prior art date
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- Pending
Links
- 238000005242 forging Methods 0.000 title claims abstract description 18
- 239000007788 liquid Substances 0.000 title claims abstract description 18
- 239000000314 lubricant Substances 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 18
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical group C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 9
- -1 polyethylene Polymers 0.000 claims description 9
- 239000013530 defoamer Substances 0.000 claims description 7
- 230000009970 fire resistant effect Effects 0.000 claims description 7
- 229920002521 macromolecule Polymers 0.000 claims description 7
- 229920000058 polyacrylate Polymers 0.000 claims description 6
- 229920000570 polyether Polymers 0.000 claims description 6
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical class CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000004642 Polyimide Substances 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- IPBVNPXQWQGGJP-UHFFFAOYSA-N acetic acid phenyl ester Natural products CC(=O)OC1=CC=CC=C1 IPBVNPXQWQGGJP-UHFFFAOYSA-N 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 150000001412 amines Chemical group 0.000 claims description 3
- 229940114081 cinnamate Drugs 0.000 claims description 3
- 229940125898 compound 5 Drugs 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 3
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- 229940049953 phenylacetate Drugs 0.000 claims description 3
- WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical compound OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 3
- 229920000768 polyamine Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920001721 polyimide Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 229940114926 stearate Drugs 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- WBYWAXJHAXSJNI-VOTSOKGWSA-M trans-cinnamate Chemical compound [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 12
- 239000010439 graphite Substances 0.000 abstract description 12
- 229910002804 graphite Inorganic materials 0.000 abstract description 12
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 230000001050 lubricating effect Effects 0.000 abstract description 3
- 239000002131 composite material Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses graphite-free high-performance environment-friendly hot forging processing liquid, which consists of high molecular compounds, high-temperature resistance lubricating agents, inorganic substances, auxiliary materials and water. The invention adopts the high molecular compounds and the high-temperature resistance lubricating agents as composite film forming agents and lubricating agents to be matched and compounded with various inorganic substances, anticorrosive agents, defoaming agents and surface active agents. Products do not contain graphite, the operation environment is good, and the products have excellent lubricating performance which reaches or exceeds the same level of the graphite type products, the impurity oil resistance performance is excellent, and the service life is long. At the same time, the products have green and environment protection effect, and belong to the high-performance environment-friendly hot forging processing liquid.
Description
Technical field:
The present invention relates to the lubricant that uses in the forge hot manufacturing procedure of steel.
Background technology:
Along with mechanical industry, developing of automobile industry particularly, the forging part demand constantly increases, and impels hot precision die forging process to develop more rapidly.Good die lubricant is the important supplementary material that guarantees the net-size forging quality.Forge to add between heat and generally all use the graphite mould lubricant in order to reach purpose lubricated, the demoulding man-hour, comprise oil base graphite and water-based graphite, but there are problems such as severe operational environment, corrosion machine, also exist simultaneously because there is graphite to be dispersed in water or the mineral oil, use stability poor, so must carry out more liquid by some months, cause the big problem of waste liquid amount.
For reaching the purpose of improving operating environment, though the not lubricant of graphitiferous is arranged in the market, greasy property is poor, can only limit to be used for light manufacture field.
Summary of the invention:
The object of the present invention is to provide a kind ofly do not have graphite, to human and environment close friend's graphite-free high-performance environment-friendly hot forging processing liquid.
Technical solution of the present invention is:
A kind of graphite-free high-performance environment-friendly hot forging processing liquid is characterized in that: the component by following percentage by weight is formed:
Macromolecular compound 5~30%
Fire-resistant lubricants 5~30%
Inorganic matter 5~30%
Auxiliary material 1~10%
Water 35~84%.
Macromolecular compound is that polyacrylate, polyacrylate, polyethers, polyester, polyamine are resin, polyethylene polyoxyethylene phosphoric acid, acrylic acid maleic copolymer-maleic anhydride, ethylene-vinyl acetate copolymer, Tissuemat E or polyimides.
Fire-resistant lubricants is benzoate, p-tert-butyl benzoic acid salt, phthalate, phenylacetate, cinnamate, stearate, molybdenum bisuphide, curing aluminium or silane.
Inorganic matter is the hydroxide of carbonate, sulfate, phosphate, borate, silicate or metal.
Auxiliary material is one or more in anticorrisive agent, defoamer, the surfactant.
Anticorrisive agent is 5-chloro-2-methyl-4-isothiazoline-3-ketone, 2-methyl-4-isothiazoline-3-ketone, 1,2-benzisothiazole-3-ketone, methyl-N-benzimidazole-2-carbamate or s-triazine; Defoamer is silicone emulsion, modified silicon oil, polyethers or higher alcohols; Surfactant is aliphatic alcohol polyethenoxy (5~12) ether, alkylphenol-polyethenoxy (5~12) ether, aliphatic alcohol polyethenoxy polyethenoxy ether, alkylolamides, aliphatic alcohol polyethenoxy (5~12) ester or sulfonate, quaternary amine.
The present invention adopts macromolecular compound, fire-resistant lubricants as compound film former and lubricant, and composite multiple inorganic matter, anticorrisive agent, defoamer, surfactant, product is graphitiferous not, operating environment is excellent, has excellent lubricating property, greasy property meets or exceeds graphite mould product peer-level, and anti-assorted oiliness can be excellent, long service life.The Product Green environmental protection is a kind of high-performance environment-friendly hot forging processing liquid simultaneously.
1, to add man-hour be to reach purpose lubricated, the demoulding generally all to use the graphite mould lubricant in forge hot, but severe operational environment is seriously polluted.This product is graphitiferous not, and operating environment is good, does not pollute.
2, this product has excellent lubricating property and demolding performace, and this product is compared with the graphite mould product, and the life-span of metal die can meet or exceed peer-level.Geared parts adds to be compared with the graphite mould product man-hour, and the life-span of metal die improves more than 20%.
3, this product has excellent assorted oily separation property, has significantly promoted the liquid life-span, reaches service life more than 1 year, improves more than 1 times than the graphite mould product.
The invention will be further described below in conjunction with embodiment.
The specific embodiment:
Embodiment 1:
The component of following percentage by weight is mixed stirring, gets graphite-free high-performance environment-friendly hot forging processing liquid:
Polyester 6%
Sodium Polyacrylate 8%
Benzoic acid 15%
P-tert-butyl benzoic acid 10%
NaOH 15%
5-chloro-2-methyl-4-isothiazoline-3-ketone 0.5%
Dimethicone 0.3%
Water 45.2%.
Embodiment 2:
A kind of graphite-free high-performance environment-friendly hot forging processing liquid, form by the component of following percentage by weight:
Macromolecular compound 5~30% (example 5%, 20%, 30%)
Fire-resistant lubricants 5~30% (example 5%, 20%, 30%)
Inorganic matter 5~30% (example 5%, 20%, 30%)
Auxiliary material 1~10% (example 1%, 5%, 10%)
Water 35~84% (example 35%, 55%, 84%).
Macromolecular compound is that polyacrylate, polyacrylate, polyethers, polyester, polyamine are resin, polyethylene polyoxyethylene phosphoric acid, acrylic acid maleic copolymer-maleic anhydride, ethylene-vinyl acetate copolymer, Tissuemat E or polyimides.
Fire-resistant lubricants is benzoate, p-tert-butyl benzoic acid salt, phthalate, phenylacetate, cinnamate, stearate, molybdenum bisuphide, curing aluminium or silane.
Inorganic matter is the hydroxide of carbonate, sulfate, phosphate, borate, silicate or metal.
Auxiliary material is one or more in anticorrisive agent, defoamer, the surfactant.
Anticorrisive agent is 5-chloro-2-methyl-4-isothiazoline-3-ketone, 2-methyl-4-isothiazoline-3-ketone, 1,2-benzisothiazole-3-ketone, methyl-N-benzimidazole-2-carbamate or s-triazine; Defoamer is silicone emulsion, modified silicon oil, polyethers or higher alcohols; Surfactant is aliphatic alcohol polyethenoxy (5~12) ether, alkylphenol-polyethenoxy (5~12) ether, aliphatic alcohol polyethenoxy polyethenoxy ether, alkylolamides, aliphatic alcohol polyethenoxy (5~12) ester or sulfonate, quaternary amine.
Claims (6)
1. graphite-free high-performance environment-friendly hot forging processing liquid, it is characterized in that: the component by following percentage by weight is formed:
Macromolecular compound 5~30%
Fire-resistant lubricants 5~30%
Inorganic matter 5~30%
Auxiliary material 1~10%
Water 35~84%.
2. graphite-free high-performance environment-friendly hot forging processing liquid according to claim 1 is characterized in that: macromolecular compound is that polyacrylate, polyacrylate, polyethers, polyester, polyamine are resin, polyethylene polyoxyethylene phosphoric acid, acrylic acid maleic copolymer-maleic anhydride, ethylene-vinyl acetate copolymer, Tissuemat E or polyimides.
3. graphite-free high-performance environment-friendly hot forging processing liquid according to claim 1 and 2 is characterized in that: fire-resistant lubricants is benzoate, p-tert-butyl benzoic acid salt, phthalate, phenylacetate, cinnamate, stearate, molybdenum bisuphide, curing aluminium or silane.
4. graphite-free high-performance environment-friendly hot forging processing liquid according to claim 1 and 2 is characterized in that: inorganic matter is the hydroxide of carbonate, sulfate, phosphate, borate, silicate or metal.
5. graphite-free high-performance environment-friendly hot forging processing liquid according to claim 1 and 2 is characterized in that: auxiliary material is one or more in anticorrisive agent, defoamer, the surfactant.
6. graphite-free high-performance environment-friendly hot forging processing liquid according to claim 5, it is characterized in that: anticorrisive agent is 5-chloro-2-methyl-4-isothiazoline-3-ketone, 2-methyl-4-isothiazoline-3-ketone, 1,2-benzisothiazole-3-ketone, methyl-N-benzimidazole-2-carbamate or s-triazine; Defoamer is silicone emulsion, modified silicon oil, polyethers or higher alcohols; Surfactant is aliphatic alcohol polyethenoxy (5~12) ether, alkylphenol-polyethenoxy (5~12) ether, aliphatic alcohol polyethenoxy polyethenoxy ether, alkylolamides, aliphatic alcohol polyethenoxy (5~12) ester or sulfonate, quaternary amine.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN 201010163678 CN101811173A (en) | 2010-04-28 | 2010-04-28 | Graphite-free high-performance environment-friendly hot forging processing liquid |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201010163678 CN101811173A (en) | 2010-04-28 | 2010-04-28 | Graphite-free high-performance environment-friendly hot forging processing liquid |
Publications (1)
Publication Number | Publication Date |
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CN101811173A true CN101811173A (en) | 2010-08-25 |
Family
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Family Applications (1)
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CN 201010163678 Pending CN101811173A (en) | 2010-04-28 | 2010-04-28 | Graphite-free high-performance environment-friendly hot forging processing liquid |
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CN (1) | CN101811173A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102533423A (en) * | 2011-12-02 | 2012-07-04 | 华中科技大学 | Non-graphite type lubricant for hot die forging of metal and preparation method of non-graphite type lubricant |
CN106085579A (en) * | 2016-06-22 | 2016-11-09 | 上海尤希路化学工业有限公司 | High release property low-residual can be recycled wheel hub and forges with lubricator |
CN108751980A (en) * | 2018-07-10 | 2018-11-06 | 芜湖市元奎新材料科技有限公司 | Zinc oxide piezoresistor ceramic and preparation method thereof |
CN109135879A (en) * | 2018-09-19 | 2019-01-04 | 广东赛米克新材料有限公司 | One kind being hot-forged pressure environmental protection release agent for ferrous metal |
CN115975710A (en) * | 2022-11-30 | 2023-04-18 | 上海尤希路化学工业有限公司 | Water-based hot forging processing oil for high-demolding-property titanium alloy forging and preparation method and application thereof |
Citations (5)
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CN85103499A (en) * | 1984-05-30 | 1986-10-29 | 隆察股份公司 | The high temperature lubricant of used in chipless-hot working of metals |
CN1243150A (en) * | 1998-06-09 | 2000-02-02 | 日本巴可莱新株式会社 | Lubricant for plastic working of metal material |
CN1272529A (en) * | 2000-05-30 | 2000-11-08 | 宝山钢铁股份有限公司 | Lubricating agent for hot-working treatment of metal |
US20050075253A1 (en) * | 2003-10-02 | 2005-04-07 | Yushiro Chemical Industry Co., Ltd. | Water-soluble lubricant for warm or hot metal forming |
JP2007176962A (en) * | 2005-12-26 | 2007-07-12 | Yushiro Chem Ind Co Ltd | Water-soluble lubricant composition for warm or hot plastic working and warm or hot plastic working method using the same |
-
2010
- 2010-04-28 CN CN 201010163678 patent/CN101811173A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN85103499A (en) * | 1984-05-30 | 1986-10-29 | 隆察股份公司 | The high temperature lubricant of used in chipless-hot working of metals |
CN1243150A (en) * | 1998-06-09 | 2000-02-02 | 日本巴可莱新株式会社 | Lubricant for plastic working of metal material |
CN1272529A (en) * | 2000-05-30 | 2000-11-08 | 宝山钢铁股份有限公司 | Lubricating agent for hot-working treatment of metal |
US20050075253A1 (en) * | 2003-10-02 | 2005-04-07 | Yushiro Chemical Industry Co., Ltd. | Water-soluble lubricant for warm or hot metal forming |
JP2007176962A (en) * | 2005-12-26 | 2007-07-12 | Yushiro Chem Ind Co Ltd | Water-soluble lubricant composition for warm or hot plastic working and warm or hot plastic working method using the same |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102533423A (en) * | 2011-12-02 | 2012-07-04 | 华中科技大学 | Non-graphite type lubricant for hot die forging of metal and preparation method of non-graphite type lubricant |
CN102533423B (en) * | 2011-12-02 | 2013-10-30 | 华中科技大学 | Non-graphite type lubricant for hot die forging of metal and preparation method of non-graphite type lubricant |
CN106085579A (en) * | 2016-06-22 | 2016-11-09 | 上海尤希路化学工业有限公司 | High release property low-residual can be recycled wheel hub and forges with lubricator |
CN108751980A (en) * | 2018-07-10 | 2018-11-06 | 芜湖市元奎新材料科技有限公司 | Zinc oxide piezoresistor ceramic and preparation method thereof |
CN109135879A (en) * | 2018-09-19 | 2019-01-04 | 广东赛米克新材料有限公司 | One kind being hot-forged pressure environmental protection release agent for ferrous metal |
CN115975710A (en) * | 2022-11-30 | 2023-04-18 | 上海尤希路化学工业有限公司 | Water-based hot forging processing oil for high-demolding-property titanium alloy forging and preparation method and application thereof |
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Open date: 20100825 |