CN101811173A - Graphite-free high-performance environment-friendly hot forging processing liquid - Google Patents

Graphite-free high-performance environment-friendly hot forging processing liquid Download PDF

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Publication number
CN101811173A
CN101811173A CN 201010163678 CN201010163678A CN101811173A CN 101811173 A CN101811173 A CN 101811173A CN 201010163678 CN201010163678 CN 201010163678 CN 201010163678 A CN201010163678 A CN 201010163678A CN 101811173 A CN101811173 A CN 101811173A
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CN
China
Prior art keywords
graphite
processing liquid
hot forging
forging processing
friendly hot
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 201010163678
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Chinese (zh)
Inventor
林丽静
丸三英二
常建忠
王勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd
Shanghai Yushiro Chemical Industry Co Ltd
Original Assignee
QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd
Shanghai Yushiro Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd, Shanghai Yushiro Chemical Industry Co Ltd filed Critical QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd
Priority to CN 201010163678 priority Critical patent/CN101811173A/en
Publication of CN101811173A publication Critical patent/CN101811173A/en
Pending legal-status Critical Current

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Abstract

The invention discloses graphite-free high-performance environment-friendly hot forging processing liquid, which consists of high molecular compounds, high-temperature resistance lubricating agents, inorganic substances, auxiliary materials and water. The invention adopts the high molecular compounds and the high-temperature resistance lubricating agents as composite film forming agents and lubricating agents to be matched and compounded with various inorganic substances, anticorrosive agents, defoaming agents and surface active agents. Products do not contain graphite, the operation environment is good, and the products have excellent lubricating performance which reaches or exceeds the same level of the graphite type products, the impurity oil resistance performance is excellent, and the service life is long. At the same time, the products have green and environment protection effect, and belong to the high-performance environment-friendly hot forging processing liquid.

Description

Graphite-free high-performance environment-friendly hot forging processing liquid
Technical field:
The present invention relates to the lubricant that uses in the forge hot manufacturing procedure of steel.
Background technology:
Along with mechanical industry, developing of automobile industry particularly, the forging part demand constantly increases, and impels hot precision die forging process to develop more rapidly.Good die lubricant is the important supplementary material that guarantees the net-size forging quality.Forge to add between heat and generally all use the graphite mould lubricant in order to reach purpose lubricated, the demoulding man-hour, comprise oil base graphite and water-based graphite, but there are problems such as severe operational environment, corrosion machine, also exist simultaneously because there is graphite to be dispersed in water or the mineral oil, use stability poor, so must carry out more liquid by some months, cause the big problem of waste liquid amount.
For reaching the purpose of improving operating environment, though the not lubricant of graphitiferous is arranged in the market, greasy property is poor, can only limit to be used for light manufacture field.
Summary of the invention:
The object of the present invention is to provide a kind ofly do not have graphite, to human and environment close friend's graphite-free high-performance environment-friendly hot forging processing liquid.
Technical solution of the present invention is:
A kind of graphite-free high-performance environment-friendly hot forging processing liquid is characterized in that: the component by following percentage by weight is formed:
Macromolecular compound 5~30%
Fire-resistant lubricants 5~30%
Inorganic matter 5~30%
Auxiliary material 1~10%
Water 35~84%.
Macromolecular compound is that polyacrylate, polyacrylate, polyethers, polyester, polyamine are resin, polyethylene polyoxyethylene phosphoric acid, acrylic acid maleic copolymer-maleic anhydride, ethylene-vinyl acetate copolymer, Tissuemat E or polyimides.
Fire-resistant lubricants is benzoate, p-tert-butyl benzoic acid salt, phthalate, phenylacetate, cinnamate, stearate, molybdenum bisuphide, curing aluminium or silane.
Inorganic matter is the hydroxide of carbonate, sulfate, phosphate, borate, silicate or metal.
Auxiliary material is one or more in anticorrisive agent, defoamer, the surfactant.
Anticorrisive agent is 5-chloro-2-methyl-4-isothiazoline-3-ketone, 2-methyl-4-isothiazoline-3-ketone, 1,2-benzisothiazole-3-ketone, methyl-N-benzimidazole-2-carbamate or s-triazine; Defoamer is silicone emulsion, modified silicon oil, polyethers or higher alcohols; Surfactant is aliphatic alcohol polyethenoxy (5~12) ether, alkylphenol-polyethenoxy (5~12) ether, aliphatic alcohol polyethenoxy polyethenoxy ether, alkylolamides, aliphatic alcohol polyethenoxy (5~12) ester or sulfonate, quaternary amine.
The present invention adopts macromolecular compound, fire-resistant lubricants as compound film former and lubricant, and composite multiple inorganic matter, anticorrisive agent, defoamer, surfactant, product is graphitiferous not, operating environment is excellent, has excellent lubricating property, greasy property meets or exceeds graphite mould product peer-level, and anti-assorted oiliness can be excellent, long service life.The Product Green environmental protection is a kind of high-performance environment-friendly hot forging processing liquid simultaneously.
1, to add man-hour be to reach purpose lubricated, the demoulding generally all to use the graphite mould lubricant in forge hot, but severe operational environment is seriously polluted.This product is graphitiferous not, and operating environment is good, does not pollute.
2, this product has excellent lubricating property and demolding performace, and this product is compared with the graphite mould product, and the life-span of metal die can meet or exceed peer-level.Geared parts adds to be compared with the graphite mould product man-hour, and the life-span of metal die improves more than 20%.
3, this product has excellent assorted oily separation property, has significantly promoted the liquid life-span, reaches service life more than 1 year, improves more than 1 times than the graphite mould product.
The invention will be further described below in conjunction with embodiment.
The specific embodiment:
Embodiment 1:
The component of following percentage by weight is mixed stirring, gets graphite-free high-performance environment-friendly hot forging processing liquid:
Polyester 6%
Sodium Polyacrylate 8%
Benzoic acid 15%
P-tert-butyl benzoic acid 10%
NaOH 15%
5-chloro-2-methyl-4-isothiazoline-3-ketone 0.5%
Dimethicone 0.3%
Water 45.2%.
Embodiment 2:
A kind of graphite-free high-performance environment-friendly hot forging processing liquid, form by the component of following percentage by weight:
Macromolecular compound 5~30% (example 5%, 20%, 30%)
Fire-resistant lubricants 5~30% (example 5%, 20%, 30%)
Inorganic matter 5~30% (example 5%, 20%, 30%)
Auxiliary material 1~10% (example 1%, 5%, 10%)
Water 35~84% (example 35%, 55%, 84%).
Macromolecular compound is that polyacrylate, polyacrylate, polyethers, polyester, polyamine are resin, polyethylene polyoxyethylene phosphoric acid, acrylic acid maleic copolymer-maleic anhydride, ethylene-vinyl acetate copolymer, Tissuemat E or polyimides.
Fire-resistant lubricants is benzoate, p-tert-butyl benzoic acid salt, phthalate, phenylacetate, cinnamate, stearate, molybdenum bisuphide, curing aluminium or silane.
Inorganic matter is the hydroxide of carbonate, sulfate, phosphate, borate, silicate or metal.
Auxiliary material is one or more in anticorrisive agent, defoamer, the surfactant.
Anticorrisive agent is 5-chloro-2-methyl-4-isothiazoline-3-ketone, 2-methyl-4-isothiazoline-3-ketone, 1,2-benzisothiazole-3-ketone, methyl-N-benzimidazole-2-carbamate or s-triazine; Defoamer is silicone emulsion, modified silicon oil, polyethers or higher alcohols; Surfactant is aliphatic alcohol polyethenoxy (5~12) ether, alkylphenol-polyethenoxy (5~12) ether, aliphatic alcohol polyethenoxy polyethenoxy ether, alkylolamides, aliphatic alcohol polyethenoxy (5~12) ester or sulfonate, quaternary amine.

Claims (6)

1. graphite-free high-performance environment-friendly hot forging processing liquid, it is characterized in that: the component by following percentage by weight is formed:
Macromolecular compound 5~30%
Fire-resistant lubricants 5~30%
Inorganic matter 5~30%
Auxiliary material 1~10%
Water 35~84%.
2. graphite-free high-performance environment-friendly hot forging processing liquid according to claim 1 is characterized in that: macromolecular compound is that polyacrylate, polyacrylate, polyethers, polyester, polyamine are resin, polyethylene polyoxyethylene phosphoric acid, acrylic acid maleic copolymer-maleic anhydride, ethylene-vinyl acetate copolymer, Tissuemat E or polyimides.
3. graphite-free high-performance environment-friendly hot forging processing liquid according to claim 1 and 2 is characterized in that: fire-resistant lubricants is benzoate, p-tert-butyl benzoic acid salt, phthalate, phenylacetate, cinnamate, stearate, molybdenum bisuphide, curing aluminium or silane.
4. graphite-free high-performance environment-friendly hot forging processing liquid according to claim 1 and 2 is characterized in that: inorganic matter is the hydroxide of carbonate, sulfate, phosphate, borate, silicate or metal.
5. graphite-free high-performance environment-friendly hot forging processing liquid according to claim 1 and 2 is characterized in that: auxiliary material is one or more in anticorrisive agent, defoamer, the surfactant.
6. graphite-free high-performance environment-friendly hot forging processing liquid according to claim 5, it is characterized in that: anticorrisive agent is 5-chloro-2-methyl-4-isothiazoline-3-ketone, 2-methyl-4-isothiazoline-3-ketone, 1,2-benzisothiazole-3-ketone, methyl-N-benzimidazole-2-carbamate or s-triazine; Defoamer is silicone emulsion, modified silicon oil, polyethers or higher alcohols; Surfactant is aliphatic alcohol polyethenoxy (5~12) ether, alkylphenol-polyethenoxy (5~12) ether, aliphatic alcohol polyethenoxy polyethenoxy ether, alkylolamides, aliphatic alcohol polyethenoxy (5~12) ester or sulfonate, quaternary amine.
CN 201010163678 2010-04-28 2010-04-28 Graphite-free high-performance environment-friendly hot forging processing liquid Pending CN101811173A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 201010163678 CN101811173A (en) 2010-04-28 2010-04-28 Graphite-free high-performance environment-friendly hot forging processing liquid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 201010163678 CN101811173A (en) 2010-04-28 2010-04-28 Graphite-free high-performance environment-friendly hot forging processing liquid

Publications (1)

Publication Number Publication Date
CN101811173A true CN101811173A (en) 2010-08-25

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102533423A (en) * 2011-12-02 2012-07-04 华中科技大学 Non-graphite type lubricant for hot die forging of metal and preparation method of non-graphite type lubricant
CN106085579A (en) * 2016-06-22 2016-11-09 上海尤希路化学工业有限公司 High release property low-residual can be recycled wheel hub and forges with lubricator
CN108751980A (en) * 2018-07-10 2018-11-06 芜湖市元奎新材料科技有限公司 Zinc oxide piezoresistor ceramic and preparation method thereof
CN109135879A (en) * 2018-09-19 2019-01-04 广东赛米克新材料有限公司 One kind being hot-forged pressure environmental protection release agent for ferrous metal
CN115975710A (en) * 2022-11-30 2023-04-18 上海尤希路化学工业有限公司 Water-based hot forging processing oil for high-demolding-property titanium alloy forging and preparation method and application thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85103499A (en) * 1984-05-30 1986-10-29 隆察股份公司 The high temperature lubricant of used in chipless-hot working of metals
CN1243150A (en) * 1998-06-09 2000-02-02 日本巴可莱新株式会社 Lubricant for plastic working of metal material
CN1272529A (en) * 2000-05-30 2000-11-08 宝山钢铁股份有限公司 Lubricating agent for hot-working treatment of metal
US20050075253A1 (en) * 2003-10-02 2005-04-07 Yushiro Chemical Industry Co., Ltd. Water-soluble lubricant for warm or hot metal forming
JP2007176962A (en) * 2005-12-26 2007-07-12 Yushiro Chem Ind Co Ltd Water-soluble lubricant composition for warm or hot plastic working and warm or hot plastic working method using the same

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85103499A (en) * 1984-05-30 1986-10-29 隆察股份公司 The high temperature lubricant of used in chipless-hot working of metals
CN1243150A (en) * 1998-06-09 2000-02-02 日本巴可莱新株式会社 Lubricant for plastic working of metal material
CN1272529A (en) * 2000-05-30 2000-11-08 宝山钢铁股份有限公司 Lubricating agent for hot-working treatment of metal
US20050075253A1 (en) * 2003-10-02 2005-04-07 Yushiro Chemical Industry Co., Ltd. Water-soluble lubricant for warm or hot metal forming
JP2007176962A (en) * 2005-12-26 2007-07-12 Yushiro Chem Ind Co Ltd Water-soluble lubricant composition for warm or hot plastic working and warm or hot plastic working method using the same

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102533423A (en) * 2011-12-02 2012-07-04 华中科技大学 Non-graphite type lubricant for hot die forging of metal and preparation method of non-graphite type lubricant
CN102533423B (en) * 2011-12-02 2013-10-30 华中科技大学 Non-graphite type lubricant for hot die forging of metal and preparation method of non-graphite type lubricant
CN106085579A (en) * 2016-06-22 2016-11-09 上海尤希路化学工业有限公司 High release property low-residual can be recycled wheel hub and forges with lubricator
CN108751980A (en) * 2018-07-10 2018-11-06 芜湖市元奎新材料科技有限公司 Zinc oxide piezoresistor ceramic and preparation method thereof
CN109135879A (en) * 2018-09-19 2019-01-04 广东赛米克新材料有限公司 One kind being hot-forged pressure environmental protection release agent for ferrous metal
CN115975710A (en) * 2022-11-30 2023-04-18 上海尤希路化学工业有限公司 Water-based hot forging processing oil for high-demolding-property titanium alloy forging and preparation method and application thereof

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Open date: 20100825