CN104911675A - 一种镁基抗菌耐蚀纳米涂层的制备方法 - Google Patents
一种镁基抗菌耐蚀纳米涂层的制备方法 Download PDFInfo
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- CN104911675A CN104911675A CN201510404559.5A CN201510404559A CN104911675A CN 104911675 A CN104911675 A CN 104911675A CN 201510404559 A CN201510404559 A CN 201510404559A CN 104911675 A CN104911675 A CN 104911675A
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- 239000011777 magnesium Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 40
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 229910052749 magnesium Inorganic materials 0.000 title claims abstract description 34
- 230000000845 anti-microbial effect Effects 0.000 title claims abstract description 24
- 238000005260 corrosion Methods 0.000 title abstract description 6
- 239000004599 antimicrobial Substances 0.000 title abstract 6
- 239000011247 coating layer Substances 0.000 title abstract 6
- 229920005604 random copolymer Polymers 0.000 claims abstract description 34
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 150000001875 compounds Chemical class 0.000 claims abstract description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 230000001476 alcoholic effect Effects 0.000 claims abstract description 9
- 238000001652 electrophoretic deposition Methods 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 8
- 230000000694 effects Effects 0.000 claims abstract description 5
- 239000002245 particle Substances 0.000 claims abstract description 4
- 241000191967 Staphylococcus aureus Species 0.000 claims abstract description 3
- 239000000243 solution Substances 0.000 claims description 36
- 230000000844 anti-bacterial effect Effects 0.000 claims description 33
- 239000002103 nanocoating Substances 0.000 claims description 30
- 239000002131 composite material Substances 0.000 claims description 23
- 239000002105 nanoparticle Substances 0.000 claims description 23
- 238000000576 coating method Methods 0.000 claims description 16
- 239000011248 coating agent Substances 0.000 claims description 15
- 239000000178 monomer Substances 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- 239000003999 initiator Substances 0.000 claims description 12
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 9
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims description 8
- 239000008151 electrolyte solution Substances 0.000 claims description 8
- 238000001338 self-assembly Methods 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 239000012295 chemical reaction liquid Substances 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 230000003628 erosive effect Effects 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 6
- 229910052697 platinum Inorganic materials 0.000 claims description 6
- 238000003860 storage Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 claims description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 5
- 230000005611 electricity Effects 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- VMSBGXAJJLPWKV-UHFFFAOYSA-N 2-ethenylbenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1C=C VMSBGXAJJLPWKV-UHFFFAOYSA-N 0.000 claims description 3
- NZQQFMVULBBDSP-FPLPWBNLSA-N bis(4-methylpentan-2-yl) (z)-but-2-enedioate Chemical compound CC(C)CC(C)OC(=O)\C=C/C(=O)OC(C)CC(C)C NZQQFMVULBBDSP-FPLPWBNLSA-N 0.000 claims description 3
- DCUFMVPCXCSVNP-UHFFFAOYSA-N methacrylic anhydride Chemical compound CC(=C)C(=O)OC(=O)C(C)=C DCUFMVPCXCSVNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 241000894006 Bacteria Species 0.000 claims description 2
- 240000002853 Nelumbo nucifera Species 0.000 claims description 2
- 235000006508 Nelumbo nucifera Nutrition 0.000 claims description 2
- 235000006510 Nelumbo pentapetala Nutrition 0.000 claims description 2
- 238000000151 deposition Methods 0.000 claims description 2
- 230000000968 intestinal effect Effects 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- 230000000452 restraining effect Effects 0.000 claims description 2
- 229910000861 Mg alloy Inorganic materials 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 6
- 230000005764 inhibitory process Effects 0.000 abstract description 2
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Chinese gallotannin Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 abstract 4
- 229920002258 tannic acid Polymers 0.000 abstract 2
- 241000588724 Escherichia coli Species 0.000 abstract 1
- 239000003792 electrolyte Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 239000007943 implant Substances 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000000721 bacterilogical effect Effects 0.000 description 1
- 239000012620 biological material Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000001124 body fluid Anatomy 0.000 description 1
- 239000010839 body fluid Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000001408 fungistatic effect Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 229940119545 isobornyl methacrylate Drugs 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
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Cited By (1)
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CN108904895A (zh) * | 2018-06-20 | 2018-11-30 | 江南大学 | 一种抗细菌粘附纳米涂层的制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1036393A (zh) * | 1987-10-14 | 1989-10-18 | 罗姆和哈斯公司 | 含低分子量聚合物添加剂的粘合剂组合物 |
JP2006509736A (ja) * | 2002-10-21 | 2006-03-23 | ロレアル | 両親媒性ブロックコポリマーを用いた水溶液に脂質親和性化合物を溶解させる方法、及び化粧品用組成物 |
CN101351490A (zh) * | 2006-01-19 | 2009-01-21 | 首尔产业大学校算学协力团 | 基于壳聚糖或透明质酸-聚(环氧乙烷)和壳聚糖-透明质酸-聚(环氧乙烷)的水凝胶及其制备方法 |
US20100160487A1 (en) * | 2002-05-17 | 2010-06-24 | The Clorox Company | Polymeric Surface Treatment Compositions |
US20140228466A1 (en) * | 2013-02-13 | 2014-08-14 | Becton, Dickinson And Company | Uv curable solventless antimicrobial compositions |
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2015
- 2015-07-10 CN CN201510404559.5A patent/CN104911675B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1036393A (zh) * | 1987-10-14 | 1989-10-18 | 罗姆和哈斯公司 | 含低分子量聚合物添加剂的粘合剂组合物 |
US20100160487A1 (en) * | 2002-05-17 | 2010-06-24 | The Clorox Company | Polymeric Surface Treatment Compositions |
JP2006509736A (ja) * | 2002-10-21 | 2006-03-23 | ロレアル | 両親媒性ブロックコポリマーを用いた水溶液に脂質親和性化合物を溶解させる方法、及び化粧品用組成物 |
CN101351490A (zh) * | 2006-01-19 | 2009-01-21 | 首尔产业大学校算学协力团 | 基于壳聚糖或透明质酸-聚(环氧乙烷)和壳聚糖-透明质酸-聚(环氧乙烷)的水凝胶及其制备方法 |
US20140228466A1 (en) * | 2013-02-13 | 2014-08-14 | Becton, Dickinson And Company | Uv curable solventless antimicrobial compositions |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108904895A (zh) * | 2018-06-20 | 2018-11-30 | 江南大学 | 一种抗细菌粘附纳米涂层的制备方法 |
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Effective date of registration: 20240320 Address after: 100000 Room 205-211526, No. 40, Fuqian West Street, Pinggu Town, Pinggu District, Beijing (cluster registration) Patentee after: BEIJING YONGBO TECHNOLOGY CO.,LTD. Country or region after: China Address before: No. 1800 road 214122 Jiangsu Lihu Binhu District City of Wuxi Province Patentee before: Jiangnan University Country or region before: China |
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Effective date of registration: 20240517 Address after: Shop 07, No. 277 Taoyuan East Road, Tianhe District, Guangzhou City, Guangdong Province, 510000 Patentee after: Guangdong Lidao Home Furnishings Co.,Ltd. Country or region after: China Address before: 100000 Room 205-211526, No. 40, Fuqian West Street, Pinggu Town, Pinggu District, Beijing (cluster registration) Patentee before: BEIJING YONGBO TECHNOLOGY CO.,LTD. Country or region before: China |