CN104877572A - Graphene additive and application thereof in shoe cream - Google Patents
Graphene additive and application thereof in shoe cream Download PDFInfo
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- CN104877572A CN104877572A CN201510186485.2A CN201510186485A CN104877572A CN 104877572 A CN104877572 A CN 104877572A CN 201510186485 A CN201510186485 A CN 201510186485A CN 104877572 A CN104877572 A CN 104877572A
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- graphene
- shoe polish
- graphene additive
- additive
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/02—Polishing compositions containing abrasives or grinding agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/06—Other polishing compositions
- C09G1/08—Other polishing compositions based on wax
- C09G1/10—Other polishing compositions based on wax based on mixtures of wax and natural or synthetic resin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
Abstract
The invention belongs to the field of shoe cream, relates to a shoe cream additive, and in particular relates to a graphene additive and an application thereof in shoe cream. The graphene additive comprises an effective component A and an effective component B, wherein the effective component A is graphene; and the effective component B is nanometer TiO2. Compared with the prior art, the graphene additive disclosed by the invention has the advantages and active effects that by utilizing the characteristics of graphene, the nanometer TiO2 is added into graphene so as to prepare the graphene additive; therefore, the light absorption of the shoe cream is effectively increased; the electronic conduction efficiency is increased; the self-cleaning property of the shoe cream is finally increased; and simultaneously, graphene has great specific surface area and strong adsorption capability, so that the abrasive resistance of the shoe cream is increased.
Description
Technical field
The invention belongs to shoe polish field, relate to shoe polish additive, particularly relate to a kind of Graphene additive and the application in shoe polish thereof.
Background technology
Along with the raising day by day of standard of living, the requirement of people to image is more and more higher, although current shoe polish can improve the glossiness of leather shoes, but need carry out wiping frequently every day, not only increase the time of safeguarding leather shoes, also add maintenance cost, to people particularly business people bring worry.
In order to solve the above problems, there is various TiO2 nano level shoe polish in recent years on the market, such as, State Intellectual property right document describes three kinds of TiO2 nano level shoe polish, China Patent No. CN 102559067 A, Shen Qing Publication date 2012.07.11, a kind of nanometer self-cleaning shoe polish for leather shoes of title.The patented product is mixed by the composition of following weight percents and forms: the paraffin of 40%-60%, the Nano self-cleaning material of 2%-5%, the emulsifying agent of 1%-3% and the water of 35%-55%; Described paraffin is molten state; Described Nano self-cleaning material is TiO2; Described emulsifying agent is alkyl benzene sulphonate (ABS) sodium solution.
China Patent No. CN 1683462 A, application publication date 2005.10.19, title Nano shoe polish, this patent adds the nano TiO 2 particles that massfraction is 3%, under stirrer high-speed stirring, makes nano particle in a solvent dispersed.Add the dispersion agent WA that massfraction is 2%.
Although these two patents reach nanosized TiO_2, there is photochemical reaction characteristic, can photocatalysis be passed through, decompose vamp organic dirt, but these two patent TiO2 used photocatalysis effects are very not obvious in actual use, really do not realize self-cleaning action.
China Patent No. CN 103409069 A, application publication date 2013.11.27, the preparation method of a kind of nanometer emulsified shoe polish by name.This relates to a kind of preparation method of nanometer emulsified shoe polish as patent, comprises the Yelkin TTS of 20-40g, is dissolved in 100ml water, is made into saturated solution; Paraffin and Yelkin TTS proportioning are that 1:2 ~ 1:3 mixes, pH8 ~ 10, and temperature is 55 ~ 65 DEG C, 1000/min magnetic agitation, and Keep agitation 3 ~ 5h, to obtain final product.
This patent relates to nanotechnology, does not have self-cleaning function, although add Yelkin TTS to improve glossiness, but Yelkin TTS own is not easily preserved, and improves production cost.
Summary of the invention
The present invention is directed to above-mentioned shoe polish cannot have the technical problem such as self-cleaning and wear resistance concurrently simultaneously, provide a kind of reasonable in design, fill a prescription simple, with low cost and there is self-cleaning and a kind of Graphene additive of wear resistance and the application in shoe polish thereof simultaneously.
In order to achieve the above object, the technical solution used in the present invention is, the invention provides a kind of Graphene additive, this Graphene additive comprises A, B two kinds of active princlples, wherein component A is Graphene, B component is nanosized TiO_2, and in this Graphene additive, the weight ratio of active princlple A and B is 1: 10 ~ 10: 1, and the gross weight of this Bactericidal composite species active princlple A and B accounts for 3% ~ 20% of whole composition total weight.
In above-mentioned Graphene additive, also comprise dispersion agent, described dispersion agent is at least one material in tetrahydrofuran (THF), DMF, N-Methyl pyrrolidone.
As preferably, described dispersion agent is tetrahydrofuran (THF).
The present invention also provides a kind of shoe polish being added with above-mentioned Graphene additive, and this shoe polish comprises following composition according to important number:
Card such clings to 5 parts ~ 10 parts, wax;
Cover too 5 parts ~ 10 parts, wax;
Stearic acid 1 part ~ 5 parts;
Nigrosine 10 parts ~ 20 parts;
10 parts ~ 20 parts, ceresine;
50 parts ~ 80 parts, turps;
Graphene additive 2 parts ~ 20 parts.
Invention additionally provides a kind of shoe polish being added with above-mentioned Graphene additive, this shoe polish comprises following composition according to important number:
20 parts ~ 50 parts, paraffin;
Emulsifying agent 1 part ~ 10 parts;
40 parts ~ 60 parts, water;
Graphene additive 2 parts ~ 20 parts.
As preferably, mentioned emulsifier is alkyl benzene sulphonate (ABS) sodium solution or monoglyceride-sucrose fatty acid ester solution.
The present invention also provides a kind of shoe polish being added with above-mentioned Graphene additive, and this shoe polish comprises following composition according to important number:
Film forming matrix 20 parts ~ 40 parts;
Nano ceramic material 2 parts ~ 10 parts;
Emulsifying agent 0.1 part ~ 1 part;
30 parts ~ 50 parts, water;
Graphene additive 2 parts ~ 20 parts.
As preferably, described film forming matrix is the mixture of palm vinegar, crystallite vinegar, methyl-silicone oil, amido silicon oil and polysiloxane.
As preferably, described nano ceramic material is at least one material in aluminum oxide, silicon carbide and silicon nitride.
As preferably, described emulsifying agent is tween 20 or Arlacel-80.
Compared with prior art, advantage of the present invention and positively effect are,
1, the present invention utilizes the characteristic of Graphene, nano level TiO2 is added in Graphene and makes Graphene additive, thus the light absorption ratio of the effective shoe polish increased, improve the efficiency of electronic conduction, finally improve the self-cleaning of shoe polish, Graphene has great specific surface area and very strong adsorptive power simultaneously, thus improves the wear resistance of shoe polish.
2, the present invention is by providing the shoe polish of three kinds of different ingredients, by adding Graphene additive thus making the shoe polish of different ingredients also have self-cleaning and wear resistance.
Embodiment
In order to more clearly understand above-mentioned purpose of the present invention, feature and advantage, below in conjunction with embodiment, the present invention will be further described.It should be noted that, when not conflicting, the feature in the embodiment of the application and embodiment can combine mutually.
Set forth a lot of detail in the following description so that fully understand the present invention, but the present invention can also adopt and be different from other modes described here and implement, and therefore, the present invention is not limited to the restriction of the specific embodiment of prospectus below.
Embodiment 1, this enforcement provides a kind of nano TiO 2 and Graphene ratio to be the application of Graphene additive in shoe polish of 8:2:
First nano TiO 2 and Graphene are uniformly mixed according to the ratio of 8:2 in dispersion agent (tetrahydrofuran (THF)), utilize mechanochemical effect principle (by mechanical energy such as extraneous shearing force or impact forces, material fully to be disperseed in media as well.Causing physics in system, chemical property and adjoint series of chemical by applying mechanical force to dispersion system, reaching the object of dispersion), form uniform Graphene additive for subsequent use.
Then stirring heating is carried out in a kettle. according to the formula (card such clings to wax 5.0g, covers too wax 5.0g, stearic acid 2.0g, nigrosine 1.0g, ceresine 12g, turps 75g) of common shoe polish, evenly rear interpolation Graphene additive to be mixed, adding proportion is 3% of above-mentioned substance gross weight, and proceeds high-speed stirring until stir.Can filling finished product after naturally cooling.
After adding Graphene and TiO2 nano composite material, make common shoe polish possess self-cleaning effect, and improve brightness.Save maintenance cost.
Embodiment 2, this enforcement provides a kind of nano TiO 2 and Graphene ratio to be the application of Graphene additive in shoe polish of 5:5:
First nano TiO 2 and Graphene are uniformly mixed according to the ratio of 5:5 in dispersion agent (tetrahydrofuran (THF)), utilize mechanochemical effect principle (by mechanical energy such as extraneous shearing force or impact forces, material fully to be disperseed in media as well.Causing physics in system, chemical property and adjoint series of chemical by applying mechanical force to dispersion system, reaching the object of dispersion), form uniform Graphene additive for subsequent use.
Then stirring heating is carried out in a kettle. according to the formula (card such clings to wax 5.0g, covers too wax 5.0g, stearic acid 2.0g, nigrosine 1..0g, ceresine 12g, turps 75g) of common shoe polish, evenly rear interpolation Graphene additive to be mixed, adding proportion is 5% of above-mentioned substance gross weight, and proceeds high-speed stirring until stir.Can filling finished product after naturally cooling.
After adding Graphene and TiO2 nano composite material, shoe polish possesses self-cleaning effect, reduces the labour intensity that people maintain leather shoes, cost-saving.
Embodiment 3, this enforcement provides a kind of nano TiO 2 and Graphene ratio to be the application of Graphene additive in shoe polish of 2:8:
First nano TiO 2 and Graphene are uniformly mixed according to the ratio of 2:8 in dispersion agent (tetrahydrofuran (THF)), utilize mechanochemical effect principle (by mechanical energy such as extraneous shearing force or impact forces, material fully to be disperseed in media as well.Causing physics in system, chemical property and adjoint series of chemical by applying mechanical force to dispersion system, reaching the object of dispersion), form uniform Graphene additive for subsequent use.
Then stirring heating is carried out in a kettle. according to the formula (card such clings to wax 5.0g, covers too wax 5.0g, stearic acid 2.0g, nigrosine 1.0g, ceresine 12g, turps 75g) of common shoe polish, evenly rear interpolation Graphene additive to be mixed, adding proportion is 10% of above-mentioned substance gross weight, and proceeds high-speed stirring until stir.Can filling finished product after naturally cooling.
After adding Graphene and TiO2 nano composite material, by photocatalysis, make common shoe polish possess self-cleaning property, while cost-saving, extend the work-ing life of leather shoes.
Embodiment 4, this enforcement provides a kind of nano TiO 2 and Graphene ratio to be the application of Graphene additive in another kind of shoe polish of 8:2:
First nano TiO 2 and Graphene are uniformly mixed according to the ratio of 8:2 in dispersion agent (tetrahydrofuran (THF)), utilize mechanochemical effect principle (by mechanical energy such as extraneous shearing force or impact forces, material fully to be disperseed in media as well.Causing physics in system, chemical property and adjoint series of chemical by applying mechanical force to dispersion system, reaching the object of dispersion), form uniform Graphene additive for subsequent use.
Then according to the formula (water of the paraffin of 40g, the emulsifying agent of 2g and 58ml of common shoe polish; Described paraffin is molten state; Described emulsifying agent is alkyl benzene sulphonate (ABS) sodium solution.) carrying out stirring heating in a kettle., evenly rear interpolation Graphene additive to be mixed, adding proportion is 10% of above-mentioned substance gross weight, and proceeds high-speed stirring until stir.Can filling finished product after naturally cooling.
After adding Graphene and TiO2 matrix material, shoe polish possesses self-cleaning function, has obvious photocatalysis effect, realizes self-cleaning function, has saved cost, and improves shoe polish brightness.
Embodiment 5, this enforcement provides a kind of nano TiO 2 and Graphene ratio to be the application of Graphene additive in another kind of shoe polish of 8:2:
First nano TiO 2 and Graphene are uniformly mixed according to the ratio of 8:2 in dispersion agent (tetrahydrofuran (THF)), utilize mechanochemical effect principle (by mechanical energy such as extraneous shearing force or impact forces, material fully to be disperseed in media as well.Causing physics in system, chemical property and adjoint series of chemical by applying mechanical force to dispersion system, reaching the object of dispersion), form uniform Graphene additive for subsequent use.
Then according to common shoe polish formula (water 100ml, film forming matrix 30g, nano ceramic material 5g, emulsifying agent 0.1g, film forming matrix is the mixture of palm vinegar, crystallite vinegar, methyl-silicone oil, amido silicon oil and polysiloxane; Nano ceramic material is aluminum oxide; Emulsifying agent is tween 20) carry out stirring heating in a kettle., evenly rear interpolation nano TiO 2 and graphene dispersing solution to be mixed, adding proportion is 10%, and proceeds high-speed stirring until stir.Can filling finished product after naturally cooling.
After adding Graphene TiO2 nano composite material, have the bright time length long, wear resistance is good, the effect of waterproof, by photocatalysis, effectively decomposes organic dirt on vamp, dirt is come off naturally, reduce cost of upkeep, extend the leather shoes life-span.
In each above-mentioned embodiment, the temperature carried is this area temperature conventional in whipping process, therefore in various embodiments of the present invention, is not warmed to the details such as how many degree in detailed description.
The above; it is only preferred embodiment of the present invention; it is not restriction the present invention being made to other form; the Equivalent embodiments that any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changed or be modified as equivalent variations is applied to other field; but everyly do not depart from technical solution of the present invention content; according to any simple modification, equivalent variations and remodeling that technical spirit of the present invention is done above embodiment, still belong to the protection domain of technical solution of the present invention.
Claims (10)
1. a Graphene additive, it is characterized in that, this Graphene additive comprises A, B two kinds of active princlples, wherein component A is Graphene, B component is nanosized TiO_2, in this Graphene additive, the weight ratio of active princlple A and B is 1: 10 ~ 10: 1, and the gross weight of this Bactericidal composite species active princlple A and B accounts for 3% ~ 20% of whole composition total weight.
2. Graphene additive according to claim 1, is characterized in that, described Graphene additive also comprises dispersion agent, and described dispersion agent is at least one material in tetrahydrofuran (THF), DMF, N-Methyl pyrrolidone.
3. Graphene additive according to claim 2, is characterized in that, described dispersion agent is tetrahydrofuran (THF).
4. be added with the shoe polish of the Graphene additive described in the claims 1, it is characterized in that, described shoe polish comprises following composition according to important number:
Card such clings to 5 parts ~ 10 parts, wax;
Cover too 5 parts ~ 10 parts, wax;
Stearic acid 1 part ~ 5 parts;
Nigrosine 10 parts ~ 20 parts;
10 parts ~ 20 parts, ceresine;
50 parts ~ 80 parts, turps;
Graphene additive 2 parts ~ 20 parts.
5. be added with the shoe polish of the Graphene additive described in the claims 1, it is characterized in that, described shoe polish comprises following composition according to important number:
20 parts ~ 50 parts, paraffin;
Emulsifying agent 1 part ~ 10 parts;
40 parts ~ 60 parts, water;
Graphene additive 2 parts ~ 20 parts.
6. shoe polish according to claim 5, is characterized in that, described emulsifying agent is alkyl benzene sulphonate (ABS) sodium solution or monoglyceride-sucrose fatty acid ester solution.
7. be added with the shoe polish of the Graphene additive described in the claims 1, it is characterized in that, described shoe polish comprises following composition according to important number:
Film forming matrix 20 parts ~ 40 parts;
Nano ceramic material 2 parts ~ 10 parts;
Emulsifying agent 0.1 part ~ 1 part;
30 parts ~ 50 parts, water;
Graphene additive 2 parts ~ 20 parts.
8. shoe polish according to claim 7, is characterized in that, described film forming matrix is the mixture of palm vinegar, crystallite vinegar, methyl-silicone oil, amido silicon oil and polysiloxane.
9. shoe polish according to claim 7, is characterized in that, described nano ceramic material is at least one material in aluminum oxide, silicon carbide and silicon nitride.
10. shoe polish according to claim 7, is characterized in that, described emulsifying agent is tween 20 or Arlacel-80.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510186485.2A CN104877572A (en) | 2015-04-20 | 2015-04-20 | Graphene additive and application thereof in shoe cream |
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| CN201510186485.2A CN104877572A (en) | 2015-04-20 | 2015-04-20 | Graphene additive and application thereof in shoe cream |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101613575A (en) * | 2008-06-25 | 2009-12-30 | 孙文国 | A kind of preparation method of high-level bright shoe cream |
| CN101735731A (en) * | 2009-12-04 | 2010-06-16 | 金猴集团有限公司 | Nano-ceramic self-cleaning type leather shoe brightener |
| CN102559067A (en) * | 2010-12-14 | 2012-07-11 | 周志昌 | Nanometer self-cleaning shoe polish for leather shoes |
| CN102872889A (en) * | 2012-10-10 | 2013-01-16 | 江苏大学 | Graphene, silver phosphate and titanium dioxide dual-functional composite and method for preparing same |
| CN104313549A (en) * | 2014-09-16 | 2015-01-28 | 同济大学 | Making method of graphene-based film with automatic cleaning function |
-
2015
- 2015-04-20 CN CN201510186485.2A patent/CN104877572A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101613575A (en) * | 2008-06-25 | 2009-12-30 | 孙文国 | A kind of preparation method of high-level bright shoe cream |
| CN101735731A (en) * | 2009-12-04 | 2010-06-16 | 金猴集团有限公司 | Nano-ceramic self-cleaning type leather shoe brightener |
| CN102559067A (en) * | 2010-12-14 | 2012-07-11 | 周志昌 | Nanometer self-cleaning shoe polish for leather shoes |
| CN102872889A (en) * | 2012-10-10 | 2013-01-16 | 江苏大学 | Graphene, silver phosphate and titanium dioxide dual-functional composite and method for preparing same |
| CN104313549A (en) * | 2014-09-16 | 2015-01-28 | 同济大学 | Making method of graphene-based film with automatic cleaning function |
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Application publication date: 20150902 |