CN106883912A - A kind of modified metal wire drawing powder and preparation method thereof - Google Patents
A kind of modified metal wire drawing powder and preparation method thereof Download PDFInfo
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- CN106883912A CN106883912A CN201710067316.6A CN201710067316A CN106883912A CN 106883912 A CN106883912 A CN 106883912A CN 201710067316 A CN201710067316 A CN 201710067316A CN 106883912 A CN106883912 A CN 106883912A
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/061—Carbides; Hydrides; Nitrides
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/065—Sulfides; Selenides; Tellurides
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
- C10M2201/082—Inorganic acids or salts thereof containing nitrogen
- C10M2201/083—Inorganic acids or salts thereof containing nitrogen nitrites
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/085—Phosphorus oxides, acids or salts
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/086—Chromium oxides, acids or salts
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
- C10M2201/102—Silicates
- C10M2201/103—Clays; Mica; Zeolites
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/14—Synthetic waxes, e.g. polythene waxes
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- C—CHEMISTRY; METALLURGY
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/042—Siloxanes with specific structure containing aromatic substituents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
Abstract
The present invention relates to wire-drawing technology field, specifically disclose a kind of modified metal wire drawing powder, including following mass fraction component:10~60 parts of lubricant, 10~60 parts of antifriction auxiliary agent, 1~15 part of extreme pressure agent, 0.3~10 part of antirust agent, 5~25 parts of alkali metal/alkaline earth metal hydroxide;The extreme pressure agent includes methyl phenyl silicone oil.The preparation method of the modified metal wire drawing powder is:Lubricant, antifriction auxiliary agent and antirust agent are mixed, heating adds the saturated aqueous solution of alkali metal/alkaline earth metal hydroxide, and insulation reaction for a period of time, is eventually adding extreme pressure agent, and after stirring, dries pulverizing is obtained final product.Modified metal wire drawing powder of the present invention has a good lubricity and corrosion resistance, high temperature high voltage resistant, with low cost, wear away low and be easy to preserve.
Description
Technical field
The present invention relates to wire-drawing technology field, more particularly, to a kind of metal wire-drawing powder and preparation method thereof.
Background technology
Drawing process is a kind of metal filament processing process, will larger-diameter wire acted on obtaining by external force drawing
The processing method for obtaining the satisfactory small diameter metal wires of diameter.During metal drawing, metal surface is subject to strong squeezing
Pressure is acted on, and needs to add wire drawing powder in the process, to ensure protection metal surface of being tried one's best while drawing speed is improved
Do not destroyed by high forces, while extending the service life of wire-drawing die.Additionally, wire drawing powder can also make wire with preferable
Antirust, wear-resistant property and surface smoothness higher.
In the market existing wire drawing powder main component include alkali metal/alkaline earth metal hydroxide, water, animal oil,
Paraffin, stearic acid, odium stearate, talcum powder, lime etc., such as Authorization Notice No. a kind of gold for the patent of CN1164380C is disclosed
Belong to the manufacturing process of wire drawing powder, a large amount of impurity are contained in the lime used by the patent, easily carcinogenic many cyclophanes are also contained in paraffin
Hydrocarbon and condensed-nuclei aromatics, impact in being diffused into air during high temperature drawing process to the healthy of operator.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of modified metal wire drawing powder and preparation method thereof, and modified metal draws
Silk powder has a good lubricity and corrosion resistance, high temperature high voltage resistant, with low cost, wear away low and be easy to preserve.
In order to solve the above technical problems, the technical solution used in the present invention is:A kind of modified metal wire drawing powder, including such as
The component of lower mass fraction:
10~60 parts of lubricant, 10~60 parts of antifriction auxiliary agent, 1~15 part of extreme pressure agent, 0.3~10 part of antirust agent, alkali metal/alkali
5~25 parts of earth metal hydroxide;
The extreme pressure agent includes methyl phenyl silicone oil;
The preparation method of the modified metal wire drawing powder is:Lubricant, antifriction auxiliary agent and antirust agent are mixed, heating,
The saturated aqueous solution of alkali metal/alkaline earth metal hydroxide is added, insulation reaction for a period of time, is eventually adding extreme pressure agent, stirs
After mixing uniformly, dries pulverizing is obtained final product.
The extreme pressure agent also include tungsten disulfide, phosphite ester, boron nitride, kodalk, borax anhydrous in one kind or
It is several.
Further, the methyl phenyl silicone oil is to contain dimethyl siloxane and diphenyl silica on molecular backbone simultaneously
The methyl phenyl silicone oil of alkane segment, the methyl phenyl silicone oil molecular weight is 500~5000.
The methyl phenyl silicone oil is 2%~8% in the mass fraction of the modified metal wire drawing powder.
The lubricant is one or more in gum rosin, capric acid, palmitic acid, stearic acid, laurate.
The antirust agent is one or more in natrium nitrosum, sodium phosphite, sodium molybdate, sodium chromate.
Alkali metal/the alkaline earth metal hydroxide is in NaOH, calcium hydroxide, aluminium hydroxide, potassium hydroxide
One or more.
The antifriction auxiliary agent is one or more in graphite, Tissuemat E, bentonite, barium stearate, talcum powder.
Further, the antifriction auxiliary agent also functionalization graphene oxide including sheet.
Further, present invention also offers the preferred preparation method of modified metal wire drawing powder as previously described, including:Will profit
Lubrication prescription, antifriction auxiliary agent and antirust agent are mixed, and are heated to 75~85 DEG C, add alkali metal/alkaline-earth metal hydrogen-oxygen
The saturated aqueous solution of compound, insulation reaction is eventually adding extreme pressure agent, and after stirring, dries pulverizing to 100 mesh is obtained final product.
It is using the beneficial effect produced by above-mentioned technical proposal:Modified metal wire drawing powder of the present invention can be used as at a high speed
Drawing lubricant, have the advantages that wire without pickling, use pollution-free, safe, its tack during steel wire drawing
Good, excellent lubricating properties, abrasion are low, with low cost, it is easy to preserve.Modified metal wire drawing powder of the present invention is used as steel wire drawing, most
Big drawing speed can reach 10~12 m/s, and steel wire finished surface pattern is bright and clean after high speed drawing, and with preferable tension
Performance.
Specific embodiment
Illustrate below and modified metal wire drawing powder of the present invention and preparation method thereof is described further.
Embodiment 1
A kind of modified metal wire drawing powder, it is prepared by the raw material of following mass percents:60% lubricant, 10% antifriction are helped
Agent, 10% extreme pressure agent, 2% antirust agent, 18% NaOH.
Its preparation method is:The lubricant of corresponding proportioning, antifriction auxiliary agent and antirust agent are separately added into equipped with agitator
In the container of heater, 75~85 DEG C are warming up to, add sodium hydrate aqueous solution(Weight content 20%), insulation reaction
30 minutes, extreme pressure agent is eventually adding, is poured out after stirring, dries pulverizing obtains modified metal wire drawing to 100 mesh after packaging
Powder finished product.
Embodiment 2
A kind of modified metal wire drawing powder, it is made up of the raw material of following mass percents:55% lubricant, 15% antifriction auxiliary agent,
10% extreme pressure agent, 2% antirust agent, 18% NaOH.
Its preparation method is:The lubricant of corresponding proportioning, antifriction auxiliary agent and antirust agent are separately added into equipped with agitator
In the container of heater, 75-85 DEG C is warming up to, adds sodium hydrate aqueous solution(Weight content 20%), insulation reaction
30 minutes, extreme pressure agent is eventually adding, is poured out after stirring, dries pulverizing obtains modified metal wire drawing to 100 mesh after packaging
Powder finished product.
Embodiment 3
A kind of modified metal wire drawing powder, it is made up of the raw material of following mass percents:50% lubricant, 15% antifriction auxiliary agent,
15% extreme pressure agent, 2% antirust agent, 18% calcium hydroxide.
Its preparation method is:The lubricant of corresponding proportioning, antifriction auxiliary agent and antirust agent in each embodiment are separately added into
In container equipped with agitator and heater, 75-85 DEG C is warming up to, adds calcium hydroxide and water, 30 points of insulation reaction
Clock, is eventually adding extreme pressure agent, is poured out after stirring, dries pulverizing to 100 mesh, after packaging i.e. obtain modified metal wire drawing powder into
Product.
Embodiment 4
A kind of modified metal wire drawing powder, it is made up of the raw material of following mass percents:45% lubricant, 15% antifriction auxiliary agent,
15% extreme pressure agent, 5% antirust agent, 20% calcium hydroxide.
Its preparation method is:The lubricant of corresponding proportioning, antifriction auxiliary agent and antirust agent are separately added into equipped with agitator
In the container of heater, 75-85 DEG C is warming up to, adds calcium hydroxide and water, insulation reaction 30 minutes is eventually adding
Extreme pressure agent, pours out after stirring, and dries pulverizing obtains modified metal wire drawing powder finished product to 100 mesh after packaging.
Comparative example 1
A kind of metal wire-drawing powder, it is made up of the raw material of following mass percents:60% lubricant, 10% antifriction auxiliary agent, 10% pole
Pressure agent, 2% antirust agent, 18% NaOH.
Its preparation method is:The lubricant of corresponding proportioning, antifriction auxiliary agent and antirust agent are separately added into equipped with agitator
In the container of heater, 75-85 DEG C is warming up to, adds sodium hydrate aqueous solution(Weight content 20%), insulation reaction
30 minutes, extreme pressure agent is eventually adding, is poured out after stirring, dries pulverizing obtains modified metal wire drawing to 100 mesh after packaging
Powder finished product.
Above example 1-4 and the Ju Ti Pei Fang of comparative example 1 are as shown in table 1 below:
Wherein extreme pressure agent is by tungsten disulfide and kodalk in mass ratio 1:4 mixing, antirust agent is by sodium molybdate and nitrous acid
Sodium in mass ratio 1:1 mixing.
Above-mentioned prepared product is tested for steel wire drawing, measured product performance index refers to table 2.
Modified metal wire drawing powder of the present invention compared with prior art, does not use paraffin, matter property stabilization used, in height
Volatile harmful material will not be produced in warm drawing process, using safer;Replace lime using NaOH or calcium hydroxide,
Inorganic impurity content in wire drawing powder can be effectively reduced, is worn away lower;Extreme pressure agent uses methyl phenyl silicone oil, high with high temperature resistant
Pressure performance, can play good greasy property under the high temperature and high pressure environment that quick drawing is formed, and play raising drawing speed
Effect, while protect wire reduce stress damage.
Additionally, modified metal wire drawing powder of the present invention can also further add functionalization graphene oxide being helped as antifriction
Agent component, can decline the frictional resistance of low metal silk and mould in high temperature and high pressure environment, further improve drawing speed, it is ensured that
Wire drawing quality.
Embodiment 5
A kind of nano modification metal wire-drawing powder, its raw material lubricant, antifriction auxiliary agent, extreme pressure agent, antirust agent, 18% calcium hydroxide
Proportioning it is same as Example 1, difference is that part bentonite is by sheet functionalization graphene oxide in antifriction auxiliary agent
Replace, and functionalization graphene oxide mass fraction in the feed is 0.1%, the preparation method of modified metal wire drawing powder is with real
Apply example 1.
Functionalization graphene oxide in the present embodiment, comprises the following steps:By 1 part(Mass fraction, similarly hereinafter)Natural squama
Flake graphite in powder and 1 part of sodium nitrate are added in 88 parts of concentrated sulfuric acids, and 0.5h is stirred under ice-water bath;Control temperature is delayed between 1~5 DEG C
Slowly 4 parts of potassium permanganate are added;35 DEG C are warming up to, 2 h are stirred;It is added dropwise over 40 parts of distilled water;98 DEG C of constant temperature are warming up to stir
Mix 0.5 h;100 parts of distilled water dilutings, plus 5 part 30% of hydrogen peroxide are added after natural cooling;10000 r/min eccentric cleanings
Being in neutrality to supernatant liquor, obtain lower sediment and be graphite oxide;The W of graphite oxide solution 150 is ultrasonically treated
0.5 h, 4000 r/min are centrifuged, and supernatant liquor is graphene oxide;55 DEG C of 20 h of vacuum drying obtain drying to constant weight
Functionalization graphene oxide, size is less than 500 nm.
The present embodiment is obtained nano modification metal wire-drawing powder and is tested using identical steel wire drawing with previous embodiment, is measured
Maximum drawing speed reaches 14.5m/s.
The present invention is described in detail above, application specific case is carried out to embodiments of the present invention in the present invention
Illustrate, the explanation of above example is only intended to help and understands the present invention, it is noted that for the technology people of the art
For member, under the premise without departing from the principles of the invention, can also some improvement be carried out to the present invention, these improvement also fall into this hair
In bright scope of the claims.
Claims (10)
1. a kind of modified metal wire drawing powder, it is characterised in that:Component including following mass fraction:
10~60 parts of lubricant, 10~60 parts of antifriction auxiliary agent, 1~15 part of extreme pressure agent, 0.3~10 part of antirust agent, alkali metal/alkali
5~25 parts of earth metal hydroxide;
The extreme pressure agent includes methyl phenyl silicone oil;
The preparation method of the modified metal wire drawing powder is:Lubricant, antifriction auxiliary agent and antirust agent are mixed, heating,
The saturated aqueous solution of alkali metal/alkaline earth metal hydroxide is added, insulation reaction for a period of time, is eventually adding extreme pressure agent, stirs
After mixing uniformly, dries pulverizing is obtained final product.
2. modified metal wire drawing powder according to claim 1, it is characterised in that the extreme pressure agent also includes tungsten disulfide, Asia
One or more in phosphate, boron nitride, kodalk, borax anhydrous.
3. modified metal wire drawing powder according to claim 1, it is characterised in that the methyl phenyl silicone oil is molecular backbone
On the methyl phenyl silicone oil containing dimethyl siloxane and diphenyl siloxane segment, the methyl phenyl silicone oil molecular weight simultaneously
It is 500~5000.
4. the modified metal wire drawing powder according to claim 1 or 3, it is characterised in that the methyl phenyl silicone oil changes described
Property metal wire-drawing powder mass fraction be 2%~8%.
5. modified metal wire drawing powder according to claim 1, it is characterised in that the lubricant is gum rosin, capric acid, soft
One or more in resin acid, stearic acid, laurate.
6. modified metal wire drawing powder according to claim 1, it is characterised in that the antirust agent is natrium nitrosum, phosphorous acid
One or more in sodium, sodium molybdate, sodium chromate.
7. modified metal wire drawing powder according to claim 1, it is characterised in that the alkali metal/alkaline earth metal hydroxide
It is one or more in NaOH, calcium hydroxide, aluminium hydroxide, potassium hydroxide.
8. modified metal wire drawing powder according to claim 1, it is characterised in that the antifriction auxiliary agent is graphite, polyethylene
One or more in wax, bentonite, barium stearate, talcum powder.
9. the modified metal wire drawing powder according to claim 1 or 8, it is characterised in that the antifriction auxiliary agent also includes sheet
Functionalization graphene oxide.
10. as any one of claim 1-9 modified metal wire drawing powder preparation method, it is characterised in that including:Will profit
Lubrication prescription, antifriction auxiliary agent and antirust agent are mixed, and are heated to 75~85 DEG C, add alkali metal/alkaline-earth metal hydrogen-oxygen
The saturated aqueous solution of compound, insulation reaction is eventually adding extreme pressure agent, and after stirring, dries pulverizing to 100 mesh is obtained final product.
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108130160A (en) * | 2017-12-26 | 2018-06-08 | 贵州钢绳股份有限公司 | A kind of steel wire dry drawing powder and preparation method thereof |
CN109570252A (en) * | 2018-11-29 | 2019-04-05 | 先登高科电气有限公司 | The production technology of the enameled wire modified drawing lubricant of hexagonal boron nitride |
CN109722325A (en) * | 2017-10-27 | 2019-05-07 | 南京工程学院 | A kind of steel wire drawing composite highly effective lubricant and preparation method thereof |
CN110102587A (en) * | 2019-05-16 | 2019-08-09 | 天津市弘亚润滑粉制造有限公司 | A kind of wire-drawing lubrication powder |
CN111100762A (en) * | 2018-10-29 | 2020-05-05 | 南京派诺金属表面处理技术有限公司 | Soap powder and preparation method thereof |
CN111548846A (en) * | 2020-05-22 | 2020-08-18 | 天津市弘亚润滑粉制造有限公司 | Wire drawing powder |
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CN109722325A (en) * | 2017-10-27 | 2019-05-07 | 南京工程学院 | A kind of steel wire drawing composite highly effective lubricant and preparation method thereof |
CN108130160A (en) * | 2017-12-26 | 2018-06-08 | 贵州钢绳股份有限公司 | A kind of steel wire dry drawing powder and preparation method thereof |
CN111100762A (en) * | 2018-10-29 | 2020-05-05 | 南京派诺金属表面处理技术有限公司 | Soap powder and preparation method thereof |
CN109570252A (en) * | 2018-11-29 | 2019-04-05 | 先登高科电气有限公司 | The production technology of the enameled wire modified drawing lubricant of hexagonal boron nitride |
CN109570252B (en) * | 2018-11-29 | 2020-03-06 | 先登高科电气有限公司 | Production process of hexagonal boron nitride modified wiredrawing lubricating fluid for enameled wire |
CN110102587A (en) * | 2019-05-16 | 2019-08-09 | 天津市弘亚润滑粉制造有限公司 | A kind of wire-drawing lubrication powder |
CN111548846A (en) * | 2020-05-22 | 2020-08-18 | 天津市弘亚润滑粉制造有限公司 | Wire drawing powder |
CN112300854A (en) * | 2020-09-24 | 2021-02-02 | 常州市实创润滑剂有限公司 | Metal wire drawing powder and preparation method thereof |
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