CN105385356B - A kind of polishing fluid, preparation method and application - Google Patents
A kind of polishing fluid, preparation method and application Download PDFInfo
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- CN105385356B CN105385356B CN201510663022.0A CN201510663022A CN105385356B CN 105385356 B CN105385356 B CN 105385356B CN 201510663022 A CN201510663022 A CN 201510663022A CN 105385356 B CN105385356 B CN 105385356B
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- fluosilicate
- marble
- polishing
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- 238000005498 polishing Methods 0.000 title claims abstract description 75
- 239000012530 fluid Substances 0.000 title claims abstract description 64
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000000839 emulsion Substances 0.000 claims abstract description 57
- 239000004203 carnauba wax Substances 0.000 claims abstract description 39
- 239000012188 paraffin wax Substances 0.000 claims abstract description 25
- 239000007822 coupling agent Substances 0.000 claims abstract description 22
- 239000004579 marble Substances 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 20
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002023 wood Substances 0.000 claims abstract description 13
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 10
- 150000003891 oxalate salts Chemical class 0.000 claims abstract description 8
- 239000000314 lubricant Substances 0.000 claims abstract description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 57
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 38
- 239000007788 liquid Substances 0.000 claims description 22
- 239000007864 aqueous solution Substances 0.000 claims description 19
- 235000011187 glycerol Nutrition 0.000 claims description 19
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical group OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 17
- 239000007787 solid Substances 0.000 claims description 17
- 239000004593 Epoxy Substances 0.000 claims description 16
- 239000001301 oxygen Substances 0.000 claims description 16
- 229910052760 oxygen Inorganic materials 0.000 claims description 16
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 16
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 13
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 claims description 13
- 229940039790 sodium oxalate Drugs 0.000 claims description 13
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 12
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 10
- 239000011777 magnesium Substances 0.000 claims description 10
- 229910052749 magnesium Inorganic materials 0.000 claims description 10
- 239000011701 zinc Substances 0.000 claims description 10
- 229910052725 zinc Inorganic materials 0.000 claims description 10
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 claims description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
- 239000003995 emulsifying agent Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical group [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000002969 artificial stone Substances 0.000 claims 1
- ZHPNWZCWUUJAJC-UHFFFAOYSA-N fluorosilicon Chemical compound [Si]F ZHPNWZCWUUJAJC-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 7
- 229910000831 Steel Inorganic materials 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000010959 steel Substances 0.000 abstract description 5
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- 229920000647 polyepoxide Polymers 0.000 description 14
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 230000006872 improvement Effects 0.000 description 6
- 235000006408 oxalic acid Nutrition 0.000 description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 2
- QXDMQSPYEZFLGF-UHFFFAOYSA-L calcium oxalate Chemical compound [Ca+2].[O-]C(=O)C([O-])=O QXDMQSPYEZFLGF-UHFFFAOYSA-L 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- -1 sorbitan fatty acid ester Chemical class 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 238000004018 waxing Methods 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Abstract
Add lustre to the invention belongs to marble or artificial plate surface, the technical field of protective treatment, more particularly to a kind of polishing fluid, preparation method and application.The polishing fluid includes pH adjusting agent, Soluble oxalate salt, lubricant, fluosilicate, nano titanium oxide, nano silicon, coupling agent, palm wax emulsion and/or paraffin wax emulsions and water.Polishing fluid of the present invention is applied to marble or artificial plate surface, can be in a thick layer of fine and close glassy bright material of Surface Creation under a series of materialization effect, this glassy bright material is hard, wear-resisting weather-proof is good, floor surface is formed the bright mirror surface effect of " Wang Shui ", easily repaired after surface tear.Polishing fluid is when handling marble or artificial plate surface, it is only necessary to polishing fluid is poured on marble or wood-based plate, cast aside with polishing pad.Without using polished steel silk flosssilk wadding, production efficiency is improved, saves cost, improves polishing brightness.
Description
Technical field
Add lustre to the invention belongs to marble or artificial plate surface, the technical field of protective treatment, more particularly to a kind of polishing
Liquid, preparation method and application.
Background technology
At present, the material surface such as marble or wood-based plate bright treatment method is generally waxed or using throwing in material surface
Light liquid is surface-treated.But after material surface waxing, layer not rub resistance of waxing, easily come off, and material surface is imitated
Fruit is also not bright enough.And the problem of existing when using polishing fluid to handle the material surfaces such as marble or wood-based plate for：(1)
Need mat and steel wool while use, just polishing fluid can be made to spread over material surface, and in use, polishing cotton needs
Often change, not only waste of materials, and speed of production is slow.(2) steel wire is not although needed for indivedual import resinae products
Cotton, but the dry solidification time of more than 24 hours is needed, it could polish, this greatly wastes production time, and resin
Material cost is very high, and the time has grown the easy xanthochromia of formed film, difficult after scratch to repair.
The content of the invention
The present invention is in order to overcome the shortcomings of the prior art, there is provided a kind of time saving and energy saving and do not need polished steel silk flosssilk wadding just
The polishing fluid that the material surfaces such as marble or wood-based plate can be polished well.
Specially：A kind of polishing fluid, calculating this polishing fluid by mass percentage includes following components：
PH adjusting agent：0.02-1.27%；
Soluble oxalate salt：0.2%-2%；
Lubricant：2.3%-3.8%；
Fluosilicate：10%-15%；
Nano titanium oxide：2%-5%；
Nano silicon：1%-5%；
Coupling agent：0.1%-0.5%；
Palm wax emulsion and/or paraffin wax emulsions：3.9%-11.8%；
Surplus is water.
Wherein, palm wax emulsion can use the palm wax emulsion of in the market purchase, for example, brand is the palm wax of holy nation
Emulsion, palm wax emulsion of Laiyang Sheng Bang organosilicons Science and Technology Ltd. etc., naturally it is also possible to disclosed in prior art
Method prepared by palm wax emulsion.For example with sorbitan fatty acid ester (sapn) and polyoxyethylene sorbitan
Palm wax emulsion prepared by the materials such as fatty acid ester (tween) series of surfactants.
Paraffin wax emulsions can also use the paraffin wax emulsions of in the market purchase, such as：Australia produces paraffin up to Chemical Co., Ltd.
Emulsion etc..Equally, paraffin wax emulsions can also use the paraffin wax emulsions prepared by disclosed method in the prior art.
As a further improvement, the solid content of the palm wax emulsion and/or paraffin wax emulsions is 15-30%.Palm wax
The mass ratio of palm wax and emulsifying agent is 85 in emulsion:15；The mass ratio of paraffin and emulsifying agent is 90 in paraffin wax emulsions:10.
As a further improvement, the lubricant is the mixture of ethylene glycol and glycerine, and ethylene glycol in polishing fluid
Mass fraction is 0.3%-0.8%, and the mass fraction of glycerine is 2%-3%；The Soluble oxalate salt is potassium oxalate and/or grass
Sour sodium.
As a further improvement, the pH adjusting agent is HOOCCOOH, H3PO4、H2SO4, it is a kind of or several in HCl
Kind.Wherein, oxalic acid, phosphoric acid can not only adjust pH, can also be generated with marble or the calcium carbonate reaction of artificial plate surface
Calcium oxalate, calcium phosphate, improve the brightness on surface.In addition, adding phosphoric acid also has lubrication so that polishing fluid is coated onto marble
Or wood-based plate surface when more lubricate, be more prone to cast aside.It should be noted that various sour quality percentages in pH adjusting agent
Than the pure sour mass percent for referring to not containing water.
As a further improvement, the fluosilicate be magnesium fluosilicate, zinc fluosilicate, one kind in ammonium fluosilicate or
It is several.Magnesium fluosilicate, zinc fluosilicate and ammonium fluosilicate can be combined together with other materials applied to marble or artificial
Plate surface, improve surface brightness.In terms of brightness is improved, zinc fluosilicate is than magnesium fluosilicate or ammonium fluosilicate effect more
It is good.Separately exist, the polishing fluid prepared using oxalic acid as pH adjusting agent, when placing more than 1 year, fraction of precipitation is had, although not
Influence to use, but can influence attractive in appearance, add ammonium fluosilicate when placing for a long time, it is possible to reduce or avoid the production of such case
It is raw.
As a further improvement, the coupling agent is γ-(2,3- the third oxygen of epoxy) propyl trimethoxy silicane.
Present invention also offers the preparation method of above-mentioned polishing fluid, the following steps are specifically included：
A) pH adjusting agent is added to the water to form the aqueous solution；
B) Soluble oxalate salt, lubricant are added in step a) liquid, stirred；
C) fluosilicate, nano titanium oxide, nano silicon, coupling agent are added in the liquid obtained by step b),
Stir；
D) palm wax emulsion and/or paraffin wax emulsions are added in step c) liquid and stirred, such as stir one
Hour.
Wherein, the step a), b), c) and d) carry out at normal temperatures.
As a further improvement, the pH of the aqueous solution is 0.5-2 in the step a)；Palm wax emulsion in the step d)
Or paraffin wax emulsions solid content is 15-30%, and the diluter stirring of emulsion concentration is easier.Palm wax and emulsification in palm wax emulsion
The mass ratio of agent is 85:15, the mass ratio of paraffin and emulsifying agent is 90 in paraffin wax emulsions:10.
Present invention also offers the application process of above-mentioned polishing fluid, its concrete application method is：Polishing fluid is poured on Dali
Stone or on wood-based plate, casts aside polishing fluid with polishing pad.
Compared with prior art, the beneficial effects of the invention are as follows：
(1) polishing fluid of the present invention is applied to marble or artificial plate surface, can be in table under a series of materialization effect
Face generates a thick layer of fine and close glassy bright material, and this glassy bright material is hard, wear-resisting weather-proof is good, makes ground
Plate surface forms the bright mirror surface effect of " Wang Shui ", is easily repaired after surface tear.Significantly better than like product in the world.Through
The marble for testing polishing fluid processing of the present invention or wood-based plate surface brightness are crossed up to 110 degree or so, brightness effect is very good.
(2) polishing fluid of the present invention is when handling marble or artificial plate surface, it is only necessary to which polishing fluid is poured on into marble or people
Make on plate, cast aside polishing fluid with polishing pad.Without using polished steel silk flosssilk wadding, production efficiency is improved, saves cost,
Improve polishing brightness.
(3) present invention polishing liquid and preparation method thereof is simple, and raw material sources are extensive, and cost is cheap.
Embodiment
In the polishing fluid of the present invention：
1) pH adjusting agent in polishing fluid can clean out the impurity of floor surface；
2) the Soluble oxalate salt in polishing fluid or oxalic acid can be with marble or the calcium carbonate reactions of wood-based plate upper surface
Generate calcium oxalate crystals so that floor surface is brighter, more resistant, harder.
3) fluorine ion in fluosilicate and marble or the calcium carbonate reaction of wood-based plate upper surface generation calcirm-fluoride so that
Floor surface is harder.
4) hydrophilic group of coupling agent contacts with silicate, nano silicon, nano titanium oxide, lipophilic group and palm wax
And/or paraffin contact, smooth film is combined under heat effect in casting aside for mat so that floor surface is extremely brilliant.Wherein, silicon
Hydrochlorate is by fluosilicate with being obtained after calcium carbonate reaction.
5) glycerine and ethylene glycol cause the surface of marble or wood-based plate more to lubricate, and are more prone to cast aside.
Its embodiment is as follows：
Embodiment 1
A kind of polishing fluid, by mass percentage the polishing fluid include following component：
H2SO4：0.8%；
Sodium oxalate：0.2%；
Ethylene glycol：0.3%；
Glycerine：2%；
Zinc fluosilicate：10%；
Nano titanium oxide：2%；
Nano silicon：1%；
Coupling agent γ-(oxygen of 2,3- epoxies third) propyl trimethoxy silicane：0.1%；
Solid content is 30% palm wax emulsion：3.9%；
Surplus is water.
The specific preparation method of the polishing fluid is：
A) sulfuric acid is added to the water to form the aqueous solution；
B) sodium oxalate, ethylene glycol and glycerine are added in the step a) aqueous solution, stirred；
C) by zinc fluosilicate, nano titanium oxide, nano silicon, coupling agent γ-(oxygen of 2,3- epoxies third) propyl group three
Methoxy silane is added in the liquid obtained by step b), is stirred；
D) the palm wax emulsion that solid content is 30% is added in step c) liquid and stirred.
Wherein, the step a), b), c) and d) carry out at normal temperatures.
Embodiment 2
A kind of polishing fluid, by mass percentage the polishing fluid include following component：
H3PO4：0.5%；
Sodium oxalate：2%；
Ethylene glycol：0.8%；
Glycerine：3%；
Magnesium fluosilicate：15%；
Nano titanium oxide：5%；
Nano silicon：5%；
Coupling agent γ-(oxygen of 2,3- epoxies third) propyl trimethoxy silicane：0.5%；
Solid content is 30% palm wax emulsion：11.8%；
Surplus is water.
The specific preparation method of the polishing fluid is：
A) phosphoric acid is added to the water to form the aqueous solution；
B) sodium oxalate, ethylene glycol and glycerine are added in the step a) aqueous solution, stirred；
C) by magnesium fluosilicate, nano titanium oxide, nano silicon, coupling agent γ-(oxygen of 2,3- epoxies third) propyl group three
Methoxy silane is added in the liquid obtained by step b), is stirred；
D) the palm wax emulsion that solid content is 30% is added in step c) liquid and stirred.
Wherein, the step a), b), c) and d) carry out at normal temperatures.
Embodiment 3
A kind of polishing fluid, by mass percentage the polishing fluid include following component：
Oxalic acid：0.5%；
Sodium oxalate：0.2%；
Ethylene glycol：0.3%；
Glycerine：2%；
Ammonium fluosilicate：10%；
Nano titanium oxide：2%；
Nano silicon：1%；
Coupling agent γ-(oxygen of 2,3- epoxies third) propyl trimethoxy silicane：0.1%；
Solid content is 30% palm wax emulsion：3.9%；
Surplus is water.
The specific preparation method of the polishing fluid is：
A) oxalic acid is added to the water to form the aqueous solution；
B) sodium oxalate, ethylene glycol and glycerine are added in the step a) aqueous solution, stirred；
C) by ammonium fluosilicate, nano titanium oxide, nano silicon, coupling agent γ-(oxygen of 2,3- epoxies third) propyl group three
Methoxy silane is added in the liquid obtained by step b), is stirred；
D) stirred in the liquid for step c) being added with the palm wax emulsion that the solid content after emulsifier is 30% equal
It is even.
Wherein, the step a), b), c) and d) carry out at normal temperatures.
Embodiment 4
A kind of polishing fluid, by mass percentage the polishing fluid include following component：
H2SO4：0.3%；
Sodium oxalate：1%；
Ethylene glycol：0.5%；
Glycerine：2.5%；
Zinc fluosilicate：12%；
Nano titanium oxide：3%；
Nano silicon：3%；
Coupling agent γ-(oxygen of 2,3- epoxies third) propyl trimethoxy silicane：0.4%；
Solid content is 30% palm wax emulsion：7.8%；
Surplus is water.
The specific preparation method of the polishing fluid is：
A) sulfuric acid is added to the water to form the aqueous solution；
B) sodium oxalate, ethylene glycol and glycerine are added in the step a) aqueous solution, stirred；
C) by zinc fluosilicate, nano titanium oxide, nano silicon, coupling agent γ-(oxygen of 2,3- epoxies third) propyl group three
Methoxy silane is added in the liquid obtained by step b), is stirred；
D) the palm wax emulsion that solid content is 30% is added in step c) liquid and stirred.
Wherein, the step a), b), c) and d) carry out at normal temperatures.
Embodiment 5
Except H2SO4Mass fraction is that remaining is same as Example 4 beyond 0.1%.
Embodiment 6
A kind of polishing fluid, by mass percentage the polishing fluid include following component：
H3PO4：0.6%；
Sodium oxalate：0.8%；
Ethylene glycol：0.4%；
Glycerine：2.2%；
Magnesium fluosilicate：11%；
Nano titanium oxide：4%；
Nano silicon：2%；
Coupling agent γ-(oxygen of 2,3- epoxies third) propyl trimethoxy silicane：0.2%；
Solid content is 30% palm wax emulsion：5.9%；
Surplus is water.
The specific preparation method of the polishing fluid is：
A) phosphoric acid is added into water and forms the aqueous solution；
B) sodium oxalate, ethylene glycol and glycerine are added in the step a) aqueous solution, stirred；
C) by magnesium fluosilicate, nano titanium oxide, nano silicon, coupling agent γ-(oxygen of 2,3- epoxies third) propyl group three
Methoxy silane is added in the liquid obtained by step b), is stirred；
D) the palm wax emulsion that solid content is 30% is added in step c) liquid and stirred.
Wherein, the step a), b), c) and d) carry out at normal temperatures.
Embodiment 7
A kind of polishing fluid, by mass percentage the polishing fluid include following component：
H2SO4：1.27%；
Sodium oxalate：0.2%；
Ethylene glycol：0.3%；
Glycerine：2%；
Zinc fluosilicate：10%；
Nano titanium oxide：2%；
Nano silicon：1%；
Coupling agent γ-(oxygen of 2,3- epoxies third) propyl trimethoxy silicane：0.1%；
Solid content is 30% palm wax emulsion：3.9%；
Surplus is water.
The specific preparation method of the polishing fluid is：
A) sulfuric acid is added to the water to form the aqueous solution；
B) sodium oxalate, ethylene glycol and glycerine are added in the step a) aqueous solution, stirred；
C) by zinc fluosilicate, nano titanium oxide, nano silicon, coupling agent γ-(oxygen of 2,3- epoxies third) propyl group three
Methoxy silane is added in the liquid obtained by step b), is stirred；
D) the palm wax emulsion that solid content is 30% is added in step c) liquid and stirred one hour.
Wherein, the step a), b), c) and d) carry out at normal temperatures.
Embodiment 8
A kind of polishing fluid, by mass percentage the polishing fluid include following component：
HCl：0.02%；
Potassium oxalate：2%；
Ethylene glycol：0.8%；
Glycerine：3%；
Magnesium fluosilicate：15%；
Nano titanium oxide：5%；
Nano silicon：5%；
Coupling agent γ-(oxygen of 2,3- epoxies third) propyl trimethoxy silicane：0.5%；
Solid content is 30% paraffin wax emulsions：11.7%；
Surplus is water.
The specific preparation method of the polishing fluid is：
A) hydrochloric acid is added to the water to form the aqueous solution；
B) potassium oxalate, ethylene glycol and glycerine are added in the step a) aqueous solution, stirred；
C) by magnesium fluosilicate, nano titanium oxide, nano silicon, coupling agent γ-(oxygen of 2,3- epoxies third) propyl group three
Methoxy silane is added in the liquid obtained by step b), is stirred；
D) paraffin wax emulsions that solid content is 30% are added in step c) liquid and stirred one hour.
Wherein, the step a), b), c) and d) carry out at normal temperatures.
Embodiment 9
In addition to 30% palm wax emulsion is changed into 30% paraffin wax emulsions, remaining is same as Example 4.
Embodiment 10
Except 30% palm wax emulsion is changed to 30% paraffin wax emulsions and 30% palm wax emulsion using mass ratio as
1：Beyond 1, remaining is same as Example 3.
Embodiment 11
In addition to 30% palm wax emulsion is changed into 15% paraffin wax emulsions, remaining is same as Example 4.
Embodiment 12
In addition to 30% palm wax emulsion is changed into 15% palm wax emulsion, remaining is same as Example 4.
It should be noted that the total various sour mass fractions of embodiment, refer to not containing the sour mass fraction of water, and
In preparation method, the acid such as sulfuric acid or hydrochloric acid of addition, addition is the solution containing water.
Applications of the embodiment 1-12 in marble and wood-based plate
1st, polishing fluid is poured on marble, cast aside with polishing pad.With vancometer measure embodiment 1,2,3,4,
5th, 6,7,8,9,10,11,12 brightness is 105,110,105,106,102,105,95,97,95,99,95,99.
2nd, polishing fluid is poured on wood-based plate, cast aside with polishing pad.With vancometer measure embodiment 1,2,3,4,
5th, 6,7,8,9,10,11,12 brightness is 106,109,108,106,102,106,96,95,97,100,95,100.
Only as described above, only the preferred embodiments of the invention, when the model that implementation of the invention can not be limited with this
Enclose, i.e., generally according to simple equivalent changes and modifications made by the content described in the claims in the present invention and description of the invention,
All it is still covered by the claims of the invention.In addition, summary part and title are intended merely to aid in patent document to search
Seek and being used, be not used for limiting the interest field of the present invention.
Claims (10)
1. a kind of polishing fluid, it is characterised in that calculating this polishing fluid by mass percentage includes following components：
PH adjusting agent：0.02-1.27%；
Soluble oxalate salt：0.2%-2%；
Lubricant：2.3%-3.8%；
Fluosilicate：10%-15%；
Nano titanium oxide：2%-5%；
Nano silicon：1%-5%；
Coupling agent：0.1%-0.5%；
Palm wax emulsion and/or paraffin wax emulsions：3.9%-11.8%；
Surplus is water；
Wherein, the lubricant is the mixture of ethylene glycol and glycerine, and the mass fraction of ethylene glycol is 0.3%- in polishing fluid
0.8%, the mass fraction of glycerine is 2%-3%.
2. polishing fluid as claimed in claim 1, it is characterised in that the solid content of the palm wax emulsion and/or paraffin wax emulsions
For 15-30%.
3. polishing fluid as claimed in claim 1, it is characterised in that the quality of palm wax and emulsifying agent in the palm wax emulsion
Than for 85:15；The mass ratio of paraffin and emulsifying agent is 90 in paraffin wax emulsions:10.
4. polishing fluid as claimed in claim 1, it is characterised in that the Soluble oxalate salt is potassium oxalate and/or sodium oxalate.
5. polishing fluid as claimed in claim 1, it is characterised in that the pH adjusting agent is HOOCCOOH, H3PO4、H2SO4、HCl
In one or several kinds.
6. polishing fluid as claimed in claim 1, it is characterised in that the fluosilicate is magnesium fluosilicate, zinc fluosilicate, fluorine silicon
One or several kinds in sour ammonium.
7. polishing fluid as claimed in claim 1, it is characterised in that the coupling agent is γ-(2,3- the third oxygen of epoxy) propyl group three
Methoxy silane.
8. the preparation method of the polishing fluid as described in claim any one of 1-7, it is characterised in that comprise the following steps：
A) pH adjusting agent is added to the water to form the aqueous solution；
B) Soluble oxalate salt, lubricant are added in the step a) aqueous solution, stirred；
C) fluosilicate, nano titanium oxide, nano silicon, coupling agent are added in the liquid obtained by step b), stirring
Uniformly；
D) palm wax emulsion and/or paraffin wax emulsions are added in step c) liquid and stirred；
Wherein, the step a), b), c) and d) carry out at normal temperatures.
9. the preparation method of polishing fluid as claimed in claim 8, it is characterised in that the pH of the aqueous solution is in the step a)
0.5-2。
10. application of the polishing fluid as described in claim any one of 1-7 in marble or artificial stone, its concrete application side
Method is：Polishing fluid is poured on marble or wood-based plate, polishing fluid cast aside with polishing pad.
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| CN105385356B true CN105385356B (en) | 2017-12-19 |
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Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107964371A (en) * | 2016-10-20 | 2018-04-27 | 佛山中科腾达科技有限公司 | A kind of marble crystal face agent and preparation method thereof |
| CN107964372A (en) * | 2016-10-20 | 2018-04-27 | 佛山市高明区(中国科学院)新材料专业中心 | A kind of stone material crystal face agent and preparation method thereof |
| CN106905857A (en) * | 2017-02-24 | 2017-06-30 | 青岛海之星生物科技有限公司 | A kind of high-durability floor wax and preparation method thereof |
| CN106905847A (en) * | 2017-04-14 | 2017-06-30 | 青岛瑞利特新材料科技有限公司 | A kind of Graphene aldehyde removal floor wax |
| CN107382378B (en) * | 2017-07-28 | 2021-05-04 | 河北畅步地面防滑工程技术有限公司 | Preparation method of anti-skid ceramic tile with sucker effect when meeting water |
| CN107325790B (en) * | 2017-07-28 | 2019-05-10 | 河北畅步地面防滑工程技术有限公司 | A kind of preparation method of floor tile antilubricant |
| CN108373881A (en) * | 2018-02-08 | 2018-08-07 | 广东车路士能源科技有限公司 | A kind of compound stone material crystal face agent composition and preparation method thereof |
| CN110157338A (en) * | 2019-07-03 | 2019-08-23 | 郑州石宝宝科技有限公司 | A kind of surface coating formula antiscuffing paste for lithotome |
| CN110511678B (en) * | 2019-08-23 | 2021-05-28 | 广州正一品生物环境科技有限公司 | Weak-acid stone crystal face cream and preparation method and application thereof |
| CN114591685A (en) * | 2022-03-03 | 2022-06-07 | 深圳市润尔鑫智能环境科技有限公司 | Stone polishing paste and preparation method thereof |
| CN115926628A (en) * | 2022-04-07 | 2023-04-07 | 东莞市立信环保科技有限公司 | Polishing agent with high glossiness |
| CN115466530B (en) * | 2022-09-30 | 2023-10-27 | 武汉工程大学 | Modified silicon dioxide crystal face agent and preparation method and application thereof |
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| CN103374715A (en) * | 2012-04-27 | 2013-10-30 | 中国钢铁股份有限公司 | Aqueous metal surface treatment agent and metal surface treatment method using same |
| CN104497731A (en) * | 2014-12-31 | 2015-04-08 | 苏州禾川化学技术服务有限公司 | Multifunctional marble crystal face finishing agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103374715A (en) * | 2012-04-27 | 2013-10-30 | 中国钢铁股份有限公司 | Aqueous metal surface treatment agent and metal surface treatment method using same |
| CN104497731A (en) * | 2014-12-31 | 2015-04-08 | 苏州禾川化学技术服务有限公司 | Multifunctional marble crystal face finishing agent |
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