CN104802484A - Metal base material with surface decorative films - Google Patents
Metal base material with surface decorative films Download PDFInfo
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- CN104802484A CN104802484A CN201410043722.5A CN201410043722A CN104802484A CN 104802484 A CN104802484 A CN 104802484A CN 201410043722 A CN201410043722 A CN 201410043722A CN 104802484 A CN104802484 A CN 104802484A
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Abstract
The invention discloses a metal base material with surface decorative films. A base oil layer, an ink layer, a printing layer, a gluing layer, a bonding layer, an electroplated layer, a coloring layer and a glazing layer are orderly arranged on the surface of the metal base material from bottom to top so that the metal base material with the surface decorative films is obtained. Through a cold transferring or cold gold stamping method, the decorative films are arranged on the surface of the metal base material so that base material surface flatness is good, scratch resistance is good, preparation processes are easy and a cost is reduced.
Description
Technical field
The invention relates to a kind of metal base of surperficial tool decoration coating, refer in particular to and a kind ofly possess the metal base that surface smoothness is good, scratch resistance is good, make easy, cost-effective effect surface has decoration coating.
Background technology
Tinplate is because having opaqueness and good sealing, and the tin on its surface neither oxidation by air do not react with water again, so there is great resistance to corrosion, not easily get rusty, can is made to have the high stability of food storage and the conservatory advantage of better nutrient, therefore, tinplate is used as the container of packaging for foodstuff in a large number, is even used as oil tank, chemicals tank, aerosol can etc.
Time generally using tinplate as packaging material, for indicating content and brand, the relational pattern or word (i.e. tin graphed sheet) that indicate content and brand therefore must be set on the surface of tinplate, and its mode arranged is first after tinplate surface completes printed patterns or word, then tinplate is made all size container.
And tin graphed sheet adopts offset mode usually, mainly utilize water, physical property that ink repels each other, mat squeegee pressure, is transferred to the picture and text on printing stencil on tinplate via blanket, belongs to offset lithography principle.And because of tinplate any surface finish, do not absorb ink, and there is certain hardness and thickness, so printing-ink need have good adhesive force to tinplate, otherwise printing-ink cannot adhere to or easily come off, and affect press quality.Meanwhile, tinplate top layer ink utilizes heat cure form dry, and therefore, controlling the baking temperature to tinplate top layer ink, is the key point of tinplate product quality, and it will directly affect the adhesive force of whole ink rete.When baking temperature is on the low side, the not full cross-linked film-forming of the chemical molecular key in resin, not only can say without adhesive force, also the tinplate back side can be caused to be stained with glutinous, occur the phenomenon of reverse-printed, so that next procedure is stained with glutinous because of ink, tinplate is said good-bye difficulty, affects chromatography.When baking temperature is too high, chemical molecular bond fission, the embrittlement of ink rete is dry and cracked, will because of cannot bearing machining and high temperature sterilization and coming off.Therefore, this technology is when implementing, strictly must control baking temperature, and the running speed of board also should control within the specific limits, to ensure that ink rete has suitable baking time, so this but causes the puzzlement of dealer on manufacturing and inconvenience, and the cost is simultaneously also higher, cannot promote preferably product profit.
Summary of the invention
Main purpose of the present invention, be to provide a kind of metal base of surperficial tool decoration coating, mainly form decoration coating by the mode of cold transfer printing or cold wave gold in metallic substrate surface, and make this decoration coating have plating and/or laser effect, can the unique and surcharge of improving product, to increase product profit.Especially this laser effect is that general ink or metal ink printing are beyond one's reach effect, and laser pattern kind is many, can provide multiple different choice.
Another main purpose of the present invention is the printing process solving tinplate in the past, and its top layer ink utilizes heat cure form dry, need higher baking temperature, and temperature controls not easily, causes the puzzlement on producing and inconvenience; The technology used in the present invention, does not need the keyholed back plate carrying out baking temperature, therefore can reduce the puzzlement in production process and inconvenience, and then the yield of improving product manufacture process, reduces manufacturing cost, promotes profit.
The main purpose of the invention described above and effect reached by following concrete technological means:
A metal base for surperficial tool decoration coating, it from bottom to top sequentially includes an end oil reservoir, an ink layer, a printed layers, a cementing layer, a following layer, an electrodeposited coating, a dyed layer and a glazing layer in a metallic substrate surface; Accordingly, plating impression rete can be formed in metallic substrate surface, and possess that surface smoothness is good, scratch resistance is good, make easy, cost-effective effect.
The metal base of surperficial tool decoration coating as above, wherein, is provided with one from shape layer between this dyed layer and this glazing layer.
The metal base of surperficial tool decoration coating as above, wherein, is provided with a laser imprinted layer between this following layer and this electrodeposited coating.
The metal base of surperficial tool decoration coating as above, wherein, is provided with a laser imprinted layer between this electrodeposited coating and this dyed layer.
The metal base of surperficial tool decoration coating as above, wherein, is provided with a laser embossed layer between this dyed layer and this glazing layer.
The metal base of surperficial tool decoration coating as above, wherein, at this from being provided with a laser embossed layer between shape layer and this glazing layer.
The metal base of surperficial tool decoration coating as above, wherein, is from bottom to top sequentially provided with a laser embossed layer, a coating layer between this dyed layer and this glazing layer.
The metal base of surperficial tool decoration coating as above, wherein, is from bottom to top sequentially provided with a laser embossed layer, a coating layer at this between shape layer and this glazing layer.
The metal base of surperficial tool decoration coating as above, wherein, this laser imprinted layer be directly on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again this metal matrix is added hot padding on this following layer or this electrodeposited coating, make this following layer or this electrodeposited coating to have laser embossing corresponding to convex-concave.
The metal base of surperficial tool decoration coating as above, wherein, this laser embossed layer be first on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again this metal matrix is added hot padding in a plastic rubber substrate surface, this plastic rubber substrate surface is made to have laser embossing corresponding to convex-concave, again this plastic rubber substrate was combined from shape layer with this dyed layer or this with the surface with laser embossing, after bonding state solidification each other, remove this plastic rubber substrate of a part of thickness again, this a part of thickness removed includes laser embossing, make this dyed layer or a part should be left from shape layer surface not removed this plastic rubber substrate including laser embossing, this laser embossing is made to be posted in this dyed layer or to be somebody's turn to do from shape layer surface, and therefore form this laser embossed layer.
The metal base of surperficial tool decoration coating as above, wherein, this plastic rubber substrate is selected from biaxial stretch-formed polypropylene film (BOPP).
The metal base of surperficial tool decoration coating as above, wherein, this laser embossed layer be first on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, and establish a coating layer in a plastic rubber substrate surface, this metal matrix is added hot padding in this painting layer surface, this painting layer surface is made to have laser embossing corresponding to convex-concave, again this coating layer was combined from shape layer with this dyed layer or this with the surface with laser embossing, after bonding state solidification each other, remove a part of thickness of this plastic rubber substrate and this coating layer again, and this part of thickness removed includes laser embossing, make this dyed layer or another part should be left from shape layer surface not removed and the coating layer including laser embossing, make this laser embossing take shape in this dyed layer or be somebody's turn to do from shape layer surface, and therefore form this laser embossed layer.
The metal base of surperficial tool decoration coating as above, wherein, this plastic rubber substrate is selected from polyvinyl terephthaldehyde ester film (PET) or biaxial stretch-formed polypropylene film (BOPP).
The metal base of surperficial tool decoration coating as above, wherein, this end oil reservoir be selected from vinyl-based, ethene improved base class, epoxy amine base class or modification alcohol radical resinoid one of them.
The metal base of surperficial tool decoration coating as above, wherein, this ink layer be selected from acrylic compounds, polyesters, alkyd base class or acid modified alcoholic base class resin one of them, and add a certain amount of Chinese white.
The metal base of surperficial tool decoration coating as above, wherein, this Chinese white be selected from titanium dioxide, titanium dioxide one of them.
The metal base of surperficial tool decoration coating as above, wherein, this cementing layer be adopt UV glue, UV gloss oil or UV resin one of them.
The metal base of surperficial tool decoration coating as above, wherein, this glazing layer be selected from acrylic compounds, acrylic-amino class, epoxies, alcohol acids or polyalcohols resin one of them.
The metal base of surperficial tool decoration coating as above, wherein, release layer includes water-based polyamine group formic acid second fat (PU) or polyamine group formic acid second fat (PU) one of them and cellulose acetate (CA), cellulose acetate-butyrate (CAB), cellulose-acetate propionate (CAP) or nitrocellulose (NC) one of them and wax (WAX), melamine resin (MF), defoamer, lubrication prescription.
The metal base of surperficial tool decoration coating as above, wherein, dyed layer comprises epoxy resin (EP), thermoplasticity acrylic resin (AC), melamine resin (MF), thermosetting acrylic resin, polyamine group formic acid second fat (PU), acrylic polyol resin, abietic resin one of them and nitrocellulose (NC), cellulose-acetate propionate (CAP) one of them, diallyl phthalate (DAP) and carbimide base (-NCO) bridging agent, carboxylic acid group (-COOH) bridging agent one of them and dyestuff.
The metal base of surperficial tool decoration coating as above, wherein, the plating material of electrodeposited coating be selected from aluminium or zinc sulphide one of them.
The metal base of surperficial tool decoration coating as above, wherein, the composition of following layer be selected from thermoplasticity acrylic resin (AC), polyamine group formic acid second fat (PU), chlorinated polypropylene (CPP), chlorination butadiene rubber (CR), polyketone resin, epoxy resin (EP), polymethacrylate resin (PMMA), vinyl chloride resin (Vinyl), abietic resin, silica one of them.
The main purpose of the invention described above and effect, can be reached by following concrete technological means again:
A metal base for surperficial tool decoration coating, it from bottom to top sequentially includes an end oil reservoir, an ink layer, a cementing layer, a following layer, an electrodeposited coating, a dyed layer, a printed layers and a glazing layer in a metallic substrate surface; Accordingly, plating impression rete can be formed in metallic substrate surface, and possess that surface smoothness is good, scratch resistance is good, make easy, cost-effective effect.
The metal base of surperficial tool decoration coating as above, wherein, is provided with one from shape layer between this dyed layer and this printed layers.
The metal base of surperficial tool decoration coating as above, wherein, is provided with a laser imprinted layer between this following layer and this electrodeposited coating.
The metal base of surperficial tool decoration coating as above, wherein, is provided with a laser imprinted layer between this electrodeposited coating and this dyed layer.
The metal base of surperficial tool decoration coating as above, wherein, this laser imprinted layer be directly on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again this metal matrix is added hot padding on this following layer or this electrodeposited coating, make this this following layer or this electrodeposited coating to have laser embossing corresponding to convex-concave.
The metal base of surperficial tool decoration coating as above, wherein, this end oil reservoir be selected from vinyl-based, ethene improved base class, epoxy amine base class or modification alcohol radical resinoid one of them.
The metal base of surperficial tool decoration coating as above, wherein, this ink layer be selected from acrylic compounds, polyesters, alkyd base class or acid modified alcoholic base class resin one of them, and add a certain amount of Chinese white one of them.
The metal base of surperficial tool decoration coating as above, wherein, this Chinese white be selected from titanium dioxide, titanium dioxide one of them.
The metal base of surperficial tool decoration coating as above, wherein, this cementing layer be adopt UV glue, UV gloss oil or UV resin one of them.
The metal base of surperficial tool decoration coating as above, wherein, this glazing layer be selected from acrylic compounds, acrylic-amino class, epoxies, alcohol acids or polyalcohols resin one of them.
The metal base of surperficial tool decoration coating as above, wherein, release layer includes water-based polyamine group formic acid second fat (PU) or polyamine group formic acid second fat (PU) one of them and cellulose acetate (CA), cellulose acetate-butyrate (CAB), cellulose-acetate propionate (CAP) or nitrocellulose (NC) one of them and wax (WAX), melamine resin (MF), defoamer, lubrication prescription.
The metal base of surperficial tool decoration coating as above, wherein, dyed layer comprises epoxy resin (EP), thermoplasticity acrylic resin (AC), melamine resin (MF), thermosetting acrylic resin, polyamine group formic acid second fat (PU), acrylic polyol resin, abietic resin one of them and nitrocellulose (NC), cellulose-acetate propionate (CAP) one of them, diallyl phthalate (DAP) and carbimide base (-NCO) bridging agent, carboxylic acid group (-COOH) bridging agent one of them and dyestuff.
The metal base of surperficial tool decoration coating as above, wherein, the plating material of electrodeposited coating be selected from aluminium or zinc sulphide one of them.
The metal base of surperficial tool decoration coating as above, wherein, the composition of following layer be selected from thermoplasticity acrylic resin (AC), polyamine group formic acid second fat (PU), chlorinated polypropylene (CPP), chlorination butadiene rubber (CR), polyketone resin, epoxy resin (EP), polymethacrylate resin (PMMA), vinyl chloride resin (Vinyl), abietic resin, silica one of them.
Accompanying drawing explanation
Fig. 1 is the structure section schematic diagram of the preferred embodiment 1 of the metal base of surperficial tool decoration coating of the present invention;
Fig. 2 is the forming step schematic diagram of the preferred embodiment 1 of the metal base of surperficial tool decoration coating of the present invention;
Fig. 3 is the structure section schematic diagram of the preferred embodiment 2 of the metal base of surperficial tool decoration coating of the present invention;
Fig. 4 is the forming step schematic diagram of the preferred embodiment 2 of the metal base of surperficial tool decoration coating of the present invention;
Fig. 5 is the structure section schematic diagram of the preferred embodiment 3 of the metal base of surperficial tool decoration coating of the present invention;
Fig. 6 is the structure section schematic diagram of the preferred embodiment 4 of the metal base of surperficial tool decoration coating of the present invention;
Fig. 7 is the structure section schematic diagram of the preferred embodiment 5 of the metal base of surperficial tool decoration coating of the present invention;
Fig. 8 is the structure section schematic diagram of the preferred embodiment 6 of the metal base of surperficial tool decoration coating of the present invention;
Fig. 9 is the structure section schematic diagram of the preferred embodiment 7 of the metal base of surperficial tool decoration coating of the present invention;
Figure 10 is the shaping schematic view of the laser embossing shape layer of the preferred embodiment 7 of the metal base of surperficial tool decoration coating of the present invention;
Figure 11 is the structure section schematic diagram of the preferred embodiment 8 of the metal base of surperficial tool decoration coating of the present invention;
Figure 12 is the shaping schematic view of the laser embossing shape layer of the preferred embodiment 8 of the metal base of surperficial tool decoration coating of the present invention;
Figure 13 is the structure section schematic diagram of the preferred embodiment 9 of the metal base of surperficial tool decoration coating of the present invention;
Figure 14 is the shaping schematic view of the laser embossing shape layer of the preferred embodiment 9 of the metal base of surperficial tool decoration coating of the present invention;
Figure 15 is the structure section schematic diagram of the preferred embodiment 10 of the metal base of surperficial tool decoration coating of the present invention;
Figure 16 is the shaping schematic view of the laser embossing shape layer of the preferred embodiment 10 of the metal base of surperficial tool decoration coating of the present invention;
Figure 17 is the structure section schematic diagram of the preferred embodiment 11 of the metal base of surperficial tool decoration coating of the present invention;
Figure 18 is the shaping schematic view of the laser embossing shape layer of the preferred embodiment 11 of the metal base of surperficial tool decoration coating of the present invention;
Figure 19 is the structure section schematic diagram of the preferred embodiment 12 of the metal base of surperficial tool decoration coating of the present invention;
Figure 20 is the shaping schematic view of the laser embossing shape layer of the preferred embodiment 12 of the metal base of surperficial tool decoration coating of the present invention;
Figure 21 is the structure section schematic diagram of the preferred embodiment 13 of the metal base of surperficial tool decoration coating of the present invention;
Figure 22 is the structure section schematic diagram of the preferred embodiment 14 of the metal base of surperficial tool decoration coating of the present invention;
Figure 23 is the structure section schematic diagram of the preferred embodiment 15 of the metal base of surperficial tool decoration coating of the present invention;
Figure 24 is the structure section schematic diagram of the preferred embodiment 16 of the metal base of surperficial tool decoration coating of the present invention.
Main Reference label declaration:
11 metal base 12 end oil reservoirs
13 ink layer 14 printed layers
15 cementing layer 2 decorating films
21 plastic films 22 are from shape layer
24 electrodeposited coating 25 following layers
26 laser imprinted layer 31 glazing layers
41 laser embossed layer 42 plastic rubber substrates
43 coating layer 51 metal bases
52 end oil reservoir 53 ink layeies
54 cementing layer 71 printed layers
72 glazing layers 6 electroplate impression rete
61 plastic films 62 are from shape layer
63 dyed layer 64 electrodeposited coatings
65 following layer 66 laser imprinted layers
23 dyed layers
Detailed description of the invention
In order to there be understanding clearly to technical characteristic of the present invention, object and beneficial effect, existing following detailed description is carried out to technical scheme of the present invention, but can not be interpreted as to of the present invention can the restriction of practical range.
Embodiment 1
Please refer to shown in Fig. 1, the present embodiment from bottom to top sequentially includes end oil reservoir 12, ink layer 13, printed layers 14, cementing layer 15, following layer 25, electrodeposited coating 24, dyed layer 23 and a glazing layer 31.
Please refer to Fig. 2, wherein this dyed layer 23, this electrodeposited coating 24, this following layer 25 be from bottom to top first take shape in plastic film 21 surface from shape layer 22, to form decorating film 2 structure, then, make this metal base 11 surface from bottom to top sequentially this end oil reservoir 12 shaping, this ink layer 13, after this printed layers 14 and this cementing layer 15, again this decorating film 2 is fitted on this cementing layer 15 with its following layer 25, after finally this plastic film 21 being removed from shape layer 22 in the lump together with this, again this glazing layer 31 is set on this dyed layer 23, so namely obtain one preferred embodiment structure as shown in Figure 1.
Wherein, in the present embodiment, this end oil reservoir 12 be selected from vinyl-based, ethene improved base class, epoxy amine base class or modification alcohol radical resinoid one of them.This ink layer 13 be selected from acrylic compounds, polyesters, alkyd base class or acid modified alcoholic base class resin one of them, and add a certain amount of Chinese white; This Chinese white be selected from titanium dioxide, titanium dioxide one of them.This cementing layer 15 be adopt UV glue, UV gloss oil or UV resin one of them.This glazing layer be selected from acrylic compounds, acrylic-amino class, epoxies, alcohol acids or polyalcohols resin one of them.
This plastic film 21 is selected from polyvinyl terephthaldehyde ester film (PET).This release layer 22 includes water-based polyamine group formic acid second fat (PU) or polyamine group formic acid second fat (PU) one of them and cellulose acetate (CA), cellulose acetate-butyrate (CAB), cellulose-acetate propionate (CAP) or nitrocellulose (NC) one of them and wax (WAX), melamine resin (MF), defoamer, lubrication prescription.
And this dyed layer 23 comprises epoxy resin (EP), thermoplasticity acrylic resin (AC), melamine resin (MF), thermosetting acrylic resin, polyamine group formic acid second fat (PU), acrylic polyol resin, abietic resin one of them and nitrocellulose (NC), cellulose-acetate propionate (CAP) one of them, diallyl phthalate (DAP) and carbimide base (-NCO) bridging agent, carboxylic acid group (-COOH) bridging agent one of them and dyestuff.
Plating material as this electrodeposited coating 24 be selected from aluminium or zinc sulphide one of them.The composition of this following layer 25 be selected from thermoplasticity acrylic resin (AC), polyamine group formic acid second fat (PU), chlorinated polypropylene (CPP), chlorination butadiene rubber (CR), polyketone resin, epoxy resin (EP), polymethacrylate resin (PMMA), vinyl chloride resin (Vinyl), abietic resin, silica one of them.
Embodiment 2
Please refer to shown in Fig. 3, it is the structure section schematic diagram of the preferred embodiment 2 of the metal base of surperficial tool decoration coating of the present invention.
The difference part of the present embodiment and preferred embodiment 1 is provided with one from shape layer 22 between this dyed layer 23 and this glazing layer 31.Namely the present embodiment from bottom to top sequentially includes end oil reservoir 12, ink layer 13, printed layers 14, cementing layer 15, following layer 25, electrodeposited coating 24, dyed layer 23 and on metal base 11 surface from shape layer 22 1 glazing layer 31.
Wherein, please refer to Fig. 4, this decorating film 2 is mainly fitting in after on this cementing layer 15 with its following layer 25 by the present embodiment, finally only this plastic film 21 is removed, this is made to reside on this dyed layer 23 from shape layer 22, in this, this glazing layer 31 is set on shape layer 22 again, so namely obtains its two preferred embodiments structure as shown in Figure 3.
Embodiment 3
Please refer to shown in Fig. 5, it is the structure section schematic diagram of the preferred embodiment 3 of the metal base of surperficial tool decoration coating of the present invention.The present embodiment is the structure of continuity preferred embodiment 1, the difference part of itself and preferred embodiment 1 be: be provided with a laser imprinted layer 26 between this following layer 25 and this electrodeposited coating 24.
Embodiment 4
Please refer to shown in Fig. 6, it is the structure section schematic diagram of the preferred embodiment 4 of the metal base of surperficial tool decoration coating of the present invention.The present embodiment is the structure of continuity preferred embodiment 2, the difference part of itself and preferred embodiment 2 be: be provided with a laser imprinted layer 26 between this following layer 25 and this electrodeposited coating 24.
Embodiment 5
Please refer to shown in Fig. 7, it is the structure section schematic diagram of the preferred embodiment 5 of the metal base of surperficial tool decoration coating of the present invention.The present embodiment is the structure of continuity preferred embodiment 1, the difference part of itself and preferred embodiment 1 be: be provided with a laser imprinted layer 26 between this electrodeposited coating 24 and this dyed layer 23.
Embodiment 6
Please refer to shown in Fig. 8, it is the structure section schematic diagram of the preferred embodiment 6 of the metal base of surperficial tool decoration coating of the present invention.The present embodiment is the structure of continuity preferred embodiment 2, the difference part of itself and preferred embodiment 2 be: be provided with a laser imprinted layer 26 between this electrodeposited coating 24 and this dyed layer 23.
Wherein, the preferred embodiment 3,4,5 and 6 of the metal base of surperficial tool decoration coating of the present invention described above, this laser imprinted layer 26 be directly on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again this metal matrix is added hot padding on this following layer 25 or this electrodeposited coating 24, make this following layer 25 or this electrodeposited coating 24 to have laser embossing corresponding to convex-concave, and form this laser imprinted layer 26.
Embodiment 7
Please refer to shown in Fig. 9, it is the structure section schematic diagram of the preferred embodiment 7 of the metal base of surperficial tool decoration coating of the present invention.The present embodiment is still the structure of continuity preferred embodiment 1, the difference part of itself and preferred embodiment 1 be: be provided with a laser embossed layer 41 between this dyed layer 23 and this glazing layer 31.
Wherein, please refer to Figure 10, first molding mode of this laser embossed layer 41 is: first on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again this metal matrix is added hot padding in plastic rubber substrate 42 surface, this plastic rubber substrate 42 surface is made to have laser embossing corresponding to convex-concave, again this plastic rubber substrate 42 is combined with this dyed layer 23 with the surface with laser embossing, after the bonding state between this plastic rubber substrate 42 and this dyed layer 23 solidifies, remove the plastic rubber substrate 42 of a part of thickness again, this a part of thickness removed includes laser embossing, make this dyed layer 23 surface leave a part not removed and the plastic rubber substrate 42 including laser embossing, the laser embossing of this plastic rubber substrate 42 is made to be posted in this dyed layer 23 surface, and therefore form this laser embossed layer 41.Wherein, this plastic rubber substrate 42 is selected from biaxial stretch-formed polypropylene film (BOPP).
Embodiment 8
Please refer to Figure 12, second molding mode of this laser embossed layer 41 in Fig. 9 is: first on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, and establish a coating layer 43 in plastic rubber substrate 42 surface, this metal matrix is added hot padding in this coating layer 43 surface, this coating layer 43 surface is made to have laser embossing corresponding to convex-concave, again this coating layer 43 is combined with this dyed layer 23 with the surface with laser embossing, after this coating layer 43 solidifies with this dyed layer 23 bonding state each other, remove a part of thickness of this plastic rubber substrate 42 and this coating layer 43 again, and this part of thickness removed includes laser embossing, make this dyed layer 23 surface leave another part not removed and the coating layer 43 including laser embossing, this laser embossing is made to take shape in this dyed layer 23 surface, and therefore form this laser embossed layer 41, thus, make to be sequentially on this dyed layer 23 this laser embossed layer 41, this coating layer 43, glazing layer 31(join Figure 11).Wherein, this plastic rubber substrate 42 is selected from polyvinyl terephthaldehyde ester film (PET) or biaxial stretch-formed polypropylene film (BOPP).
Embodiment 9
Please refer to shown in Figure 13, it is the structure section schematic diagram of the preferred embodiment 9 of the metal base of surperficial tool decoration coating of the present invention.The present embodiment is the structure of continuity preferred embodiment 2, its difference part with preferred embodiment 2 be: this is from being provided with a laser embossed layer 41 between shape layer 22 and this glazing layer 31.
Wherein, please refer to Figure 14, first molding mode of this laser embossed layer 41 is: first on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again this metal matrix is added hot padding in plastic rubber substrate 42 surface, this plastic rubber substrate 42 surface is made to have laser embossing corresponding to convex-concave, again this plastic rubber substrate 42 was combined from shape layer 22 with this with the surface with laser embossing, until this plastic rubber substrate 42 and after should solidifying from shape layer 22 bonding state each other, remove the plastic rubber substrate 42 of a part of thickness again, this a part of thickness removed includes laser embossing, make this dyed layer 22 surface leave a part and do not removed the plastic rubber substrate 42 including laser embossing, this is made to leave required fraction of laser light embossing from shape layer 22 surface, and therefore form this laser embossed layer 41.Wherein, this plastic rubber substrate 42 is selected from biaxial stretch-formed polypropylene film (BOPP).
Embodiment 10
Please refer to Figure 16, it is its two molding mode of this laser embossed layer 41 in Figure 13: first on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, and establish a coating layer 43 in plastic rubber substrate 42 surface, this metal matrix is added hot padding in this coating layer 43 surface, this coating layer 43 surface is made to have laser embossing corresponding to convex-concave, again this coating layer 43 was combined from shape layer 22 with this with the surface with laser embossing, until this coating layer 43 and after should solidifying from shape layer 22 bonding state each other, remove a part of thickness of this plastic rubber substrate 42 and this coating layer 43 again, and this part of thickness removed includes laser embossing, make this leave another part from shape layer 22 surface not removed and the coating layer 43 including laser embossing, therefore order should form this laser embossed layer 41 on the surface from shape layer 22, thus, make that this is sequentially this laser embossed layer 41 on shape layer 22, this coating layer 43, glazing layer 31(join Figure 15).
Embodiment 11
Please refer to shown in Figure 17, it is the structure section schematic diagram of the preferred embodiment 11 of the metal base of surperficial tool decoration coating of the present invention.
In the present embodiment, mainly from bottom to top sequentially comprise on metal base 51 surface and be provided with end oil reservoir 52, ink layer 53, cementing layer 54, following layer 65, electrodeposited coating 64, dyed layer 63, printed layers 71 and a glazing layer 72; Accordingly, plating impression rete 6 can be formed on metal base 51 surface, and possess that surface smoothness is good, scratch resistance is good, make easy, cost-effective effect.
Please refer to Figure 18, wherein this dyed layer 63, this electrodeposited coating 64, this following layer 65 be from bottom to top first take shape in plastic film 61 surface from shape layer 62, to form plating impression rete 6 structure, then, make this metal base 51 surface from bottom to top sequentially this end oil reservoir 52 shaping, this ink layer 53, after this cementing layer 54, again this plating impression rete 6 is fitted on this cementing layer 54 with its following layer 65, after finally this plastic film 61 being removed from shape layer 62 in the lump together with this, this printed layers 71 and this glazing layer 72 are from bottom to top sequentially set on this dyed layer 63 again, so namely obtain the structure of preferred embodiment 11 as shown in figure 17.
Embodiment 12
Please refer to shown in Figure 19, it is the structure section schematic diagram of the preferred embodiment 12 of the metal base of surperficial tool decoration coating of the present invention.The difference part of the present embodiment and preferred embodiment 11 is provided with one from shape layer 62 between this dyed layer 63 and this printed layers 72.Namely the present embodiment from bottom to top sequentially includes end oil reservoir 52, ink layer 53, cementing layer 54, following layer 65, electrodeposited coating 64, dyed layer 63, on metal base 51 surface from shape layer 62, printed layers 71 and a glazing layer 72.
Wherein, please refer to Figure 20, this plating impression rete 6 is mainly fitting in after on this cementing layer 54 with its following layer 65 by the present embodiment, finally only this plastic film 61 is removed, this is made to reside on this dyed layer 63 from shape layer 62, again this printed layers 71 and this glazing layer 72 are from bottom to top sequentially set on shape layer 62 in this, so namely obtain its 12 preferred embodiment structure as shown in figure 19.
Embodiment 13
Please refer to shown in Figure 21, it is the structure section schematic diagram of the preferred embodiment 13 of the metal base of surperficial tool decoration coating of the present invention.The present embodiment is the structure of continuity preferred embodiment 11, the difference part of itself and preferred embodiment 11 be: be provided with a laser imprinted layer 66 between this following layer 65 and this electrodeposited coating 64.
Embodiment 14
Please refer to shown in Figure 22, it is the structure section schematic diagram of the preferred embodiment 14 of the metal base of surperficial tool decoration coating of the present invention.The present embodiment is the structure of continuity preferred embodiment 12, the difference part of itself and preferred embodiment 12 be: be provided with a laser imprinted layer 66 between this following layer 65 and this electrodeposited coating 64.
Embodiment 15
Please refer to shown in Figure 23, it is the structure section schematic diagram of the preferred embodiment 15 of the metal base of surperficial tool decoration coating of the present invention.The present embodiment is the structure of continuity preferred embodiment 11, the difference part of itself and preferred embodiment 11 be: be provided with a laser imprinted layer 66 between this electrodeposited coating 64 and this dyed layer 63.
Embodiment 16
Please refer to shown in Figure 24, it is the structure section schematic diagram of the preferred embodiment 16 of the metal base of surperficial tool decoration coating of the present invention.The present embodiment is the structure of continuity preferred embodiment 12, the difference part of itself and preferred embodiment 12 be: be provided with a plating between this electrodeposited coating 64 and this dyed layer 63 and impress rete 6.
Wherein, the preferred embodiment 13-16 of the metal base of surperficial tool decoration coating of the present invention described above, this laser imprinted layer 66 be directly on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again this metal matrix is added hot padding on this following layer 65 or this electrodeposited coating 64, make this following layer 65 or this electrodeposited coating 64 to have laser embossing corresponding to convex-concave, and form this laser imprinted layer 66.
Wherein, the preferred embodiment 13-16 of the metal base of surperficial tool decoration coating of the present invention described above, this laser imprinted layer 6 be directly on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again this metal matrix is added hot padding on this following layer 65 or this electrodeposited coating 64, make this following layer 65 or this electrodeposited coating 64 to have laser embossing corresponding to convex-concave, and form this laser imprinted layer 66.
Wherein, the preferred embodiment 13-16 of the metal base of surperficial tool decoration coating of the present invention described above, this laser imprinted layer 66 be directly on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again this metal matrix is added hot padding on this following layer 65 or this electrodeposited coating 64, make this following layer 65 or this electrodeposited coating 64 to have laser embossing corresponding to convex-concave, and form this laser imprinted layer 66.
Wherein, in the present embodiment, this end oil reservoir 52 be selected from vinyl-based, ethene improved base class, epoxy amine base class or modification alcohol radical resinoid one of them.This ink layer 53 be selected from acrylic compounds, polyesters, alkyd base class or acid modified alcoholic base class resin one of them, and add a certain amount of Chinese white; This Chinese white be selected from titanium dioxide, titanium dioxide one of them.This cementing layer 54 be adopt UV glue, UV gloss oil or UV resin one of them.
This plastic film 61 is selected from polyvinyl terephthaldehyde ester film (PET).Water-based polyamine group formic acid second fat (PU) or polyamine group formic acid second fat (PU) one of them and cellulose acetate (CA), cellulose acetate-butyrate (CAB), cellulose-acetate propionate (CAP) or nitrocellulose (NC) one of them and wax (WAX), melamine resin (MF), defoamer, lubrication prescription should be included from shape layer 62.
And this dyed layer 63 comprises epoxy resin (EP), thermoplasticity acrylic resin (AC), melamine resin (MF), thermosetting acrylic resin, polyamine group formic acid second fat (PU), acrylic polyol resin, abietic resin one of them and nitrocellulose (NC), cellulose-acetate propionate (CAP) one of them, diallyl phthalate (DAP) and carbimide base (-NCO) bridging agent, carboxylic acid group (-COOH) bridging agent one of them and dyestuff.
Plating material as this electrodeposited coating 64 be selected from aluminium or zinc sulphide one of them.The composition of this following layer 65 be selected from thermoplasticity acrylic resin (AC), polyamine group formic acid second fat (PU), chlorinated polypropylene (CPP), chlorination butadiene rubber (CR), polyketone resin, epoxy resin (EP), polymethacrylate resin (PMMA), vinyl chloride resin (Vinyl), abietic resin, silica one of them.
Claims (50)
1. a metal base for surperficial tool decoration coating, it from bottom to top sequentially includes an end oil reservoir, an ink layer, a printed layers, a cementing layer, a following layer, an electrodeposited coating, a dyed layer and a glazing layer in a metallic substrate surface.
2. the metal base of surperficial tool decoration coating as claimed in claim 1, wherein, is provided with one from shape layer between described dyed layer and described glazing layer.
3. the metal base of surperficial tool decoration coating as claimed in claim 2, wherein, is provided with a laser imprinted layer between described following layer and described electrodeposited coating.
4. the metal base of surperficial tool decoration coating as claimed in claim 3, wherein, described laser imprinted layer be directly on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again described metal matrix is added hot padding on described following layer or described electrodeposited coating, make described following layer or described electrodeposited coating to have laser embossing corresponding to convex-concave.
5. the metal base of surperficial tool decoration coating as claimed in claim 2, wherein, is provided with a laser imprinted layer between described electrodeposited coating and described dyed layer.
6. the metal base of surperficial tool decoration coating as claimed in claim 5, wherein, described laser imprinted layer be directly on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again described metal matrix is added hot padding on described following layer or described electrodeposited coating, make described following layer or described electrodeposited coating to have laser embossing corresponding to convex-concave.
7. the metal base of surperficial tool decoration coating as claimed in claim 2, wherein, described from being provided with a laser embossed layer between shape layer and described glazing layer.
8. the metal base of surperficial tool decoration coating as claimed in claim 7, wherein, described laser embossed layer be first on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again described metal matrix is added hot padding in a plastic rubber substrate surface, described plastic rubber substrate surface is made to have laser embossing corresponding to convex-concave, again described plastic rubber substrate is combined from shape layer with described with the surface with laser embossing, after bonding state solidification each other, remove the described plastic rubber substrate of a part of thickness again, the described a part of thickness removed includes laser embossing, make described from shape layer surface leave a part do not removed the described plastic rubber substrate including laser embossing, and therefore form described laser embossed layer.
9. the metal base of surperficial tool decoration coating as claimed in claim 8, wherein, described plastic rubber substrate is selected from biaxial stretch-formed polypropylene film.
10. the metal base of surperficial tool decoration coating as claimed in claim 2, wherein, is describedly from bottom to top sequentially provided with a laser embossed layer, a coating layer between shape layer and described glazing layer.
The metal base of 11. surperficial tool decoration coatings as claimed in claim 10, wherein, described laser embossed layer be first on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, and establish described coating layer in a plastic rubber substrate surface, described metal matrix is added hot padding in described painting layer surface, described painting layer surface is made to have laser embossing corresponding to convex-concave, again described coating layer is combined from shape layer with described with the surface with laser embossing, after bonding state solidification each other, remove a part of thickness of described plastic rubber substrate and described coating layer again, and described in a part of thickness of removing includes laser embossing, make describedly to leave another part do not removed and the coating layer including laser embossing from shape layer surface, described laser embossing is made to take shape in described from shape layer surface, and therefore form described laser embossed layer.
The metal base of 12. surperficial tool decoration coatings as claimed in claim 11, wherein, described plastic rubber substrate is selected from polyvinyl terephthaldehyde ester film or biaxial stretch-formed polypropylene film.
The metal base of 13. surperficial tool decoration coatings as claimed in claim 1, wherein, is provided with a laser imprinted layer between described following layer and described electrodeposited coating.
The metal base of 14. surperficial tool decoration coatings as claimed in claim 13, wherein, described laser imprinted layer be directly on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again described metal matrix is added hot padding on described following layer or described electrodeposited coating, make described following layer or described electrodeposited coating to have laser embossing corresponding to convex-concave.
The metal base of 15. surperficial tool decoration coatings as claimed in claim 1, wherein, is provided with a laser imprinted layer between described electrodeposited coating and described dyed layer.
The metal base of 16. surperficial tool decoration coatings as claimed in claim 15, wherein, described laser imprinted layer be directly on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again described metal matrix is added hot padding on described following layer or described electrodeposited coating, make described following layer or described electrodeposited coating to have laser embossing corresponding to convex-concave.
The metal base of 17. surperficial tool decoration coatings as claimed in claim 1, wherein, is provided with a laser embossed layer between described dyed layer and described glazing layer.
The metal base of 18. surperficial tool decoration coatings as claimed in claim 17, wherein, described laser embossed layer be first on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again described metal matrix is added hot padding in a plastic rubber substrate surface, described plastic rubber substrate surface is made to have laser embossing corresponding to convex-concave, again described plastic rubber substrate is combined with described dyed layer with the surface with laser embossing, after bonding state solidification each other, remove the described plastic rubber substrate of a part of thickness again, the described a part of thickness removed includes laser embossing, make described dyed layer surface leave a part and do not removed the described plastic rubber substrate including laser embossing, described dyed layer surface is made to leave required fraction of laser light embossing, and therefore form described laser embossed layer.
The metal base of 19. surperficial tool decoration coatings as claimed in claim 18, wherein, described plastic rubber substrate is selected from biaxial stretch-formed polypropylene film.
The metal base of 20. surperficial tool decoration coatings as claimed in claim 1, wherein, is from bottom to top sequentially provided with a laser embossed layer, a coating layer between described dyed layer and described glazing layer.
The metal base of 21. surperficial tool decoration coatings as claimed in claim 20, wherein, described laser embossed layer be first on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, and establish described coating layer in a plastic rubber substrate surface, described metal matrix is added hot padding in described painting layer surface, described painting layer surface is made to have laser embossing corresponding to convex-concave, again described coating layer is fitted with the surface and described dyed layer with laser embossing, in conjunction with, after bonding state solidification each other, remove a part of thickness of described plastic rubber substrate and described coating layer again, and described in a part of thickness of removing includes laser embossing, make described dyed layer surface leave another part not removed and the coating layer including laser embossing, described laser embossing is made to take shape in described dyed layer surface, and therefore form described laser embossed layer.
The metal base of 22. surperficial tool decoration coatings as claimed in claim 21, wherein, described plastic rubber substrate is selected from polyvinyl terephthaldehyde ester film or biaxial stretch-formed polypropylene film.
The metal base of 23. surperficial tool decoration coatings as claimed in claim 2, wherein, described release layer includes water-based polyamine group formic acid second fat or polyamine group formic acid second fat one of them and cellulose acetate, cellulose acetate-butyrate, cellulose-acetate propionate or nitrocellulose one of them and wax, melamine resin, defoamer, lubrication prescription.
The metal base of 24. surperficial tool decoration coatings as claimed in claim 1, wherein, oil reservoir of the described end be selected from vinyl-based, ethene improved base class, epoxy amine base class or modification alcohol radical resinoid one of them.
The metal base of 25. surperficial tool decoration coatings as claimed in claim 1, wherein, described ink layer be selected from acrylic compounds, polyesters, alkyd base class or acid modified alcoholic base class resin one of them, and add a certain amount of Chinese white.
The metal base of 26. surperficial tool decoration coatings as claimed in claim 25, wherein, described Chinese white be selected from titanium dioxide, titanium dioxide one of them.
The metal base of 27. surperficial tool decoration coatings as claimed in claim 1, wherein, described cementing layer be adopt UV glue, UV gloss oil or UV resin one of them.
The metal base of 28. surperficial tool decoration coatings as claimed in claim 1, wherein, described glazing layer be selected from acrylic compounds, acrylic-amino class, epoxies, alcohol acids or polyalcohols resin one of them.
The metal base of 29. surperficial tool decoration coatings as claimed in claim 1, wherein, described dyed layer comprise epoxy resin, thermoplasticity acrylic resin, melamine resin, thermosetting acrylic resin, polyamine group formic acid second fat, acrylic polyol resin, abietic resin one of them and nitrocellulose, cellulose-acetate propionate one of them, diallyl phthalate and carbimide base bridging agent, carboxylic acid group's bridging agent one of them and dyestuff.
The metal base of 30. surperficial tool decoration coatings as claimed in claim 1, wherein, the plating material of described electrodeposited coating be selected from aluminium or zinc sulphide one of them.
The metal base of 31. surperficial tool decoration coatings as claimed in claim 1, wherein, the composition of described following layer be selected from thermoplasticity acrylic resin, polyamine group formic acid second fat, chlorinated polypropylene, chlorination butadiene rubber, polyketone resin, epoxy resin, polymethacrylate resin, vinyl chloride resin, abietic resin, silica one of them.
The metal base of 32. 1 kinds of surperficial tool decoration coatings, it from bottom to top sequentially includes an end oil reservoir, an ink layer, a cementing layer, a following layer, an electrodeposited coating, a dyed layer, a printed layers and a glazing layer in a metallic substrate surface.
The metal base of 33. surperficial tool decoration coatings as claimed in claim 32, wherein, is provided with one from shape layer between described dyed layer and described printed layers.
The metal base of 34. surperficial tool decoration coatings as claimed in claim 33, wherein, is provided with a laser imprinted layer between described following layer and described electrodeposited coating.
The metal base of 35. surperficial tool decoration coatings as claimed in claim 34, wherein, described laser imprinted layer be directly on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again described metal matrix is added hot padding on described following layer, make described following layer to have laser embossing corresponding to convex-concave.
The metal base of 36. surperficial tool decoration coatings as claimed in claim 33, wherein, is provided with a laser imprinted layer between described electrodeposited coating and described dyed layer.
The metal base of 37. surperficial tool decoration coatings as claimed in claim 36, wherein, described laser imprinted layer be directly on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again described metal matrix is added hot padding on described electrodeposited coating, make described electrodeposited coating to have laser embossing corresponding to convex-concave.
The metal base of 38. surperficial tool decoration coatings as claimed in claim 32, wherein, is provided with a laser imprinted layer between described following layer and described electrodeposited coating.
The metal base of 39. surperficial tool decoration coatings as claimed in claim 38, wherein, described laser imprinted layer be directly on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again described metal matrix is added hot padding on described following layer, make described following layer to have laser embossing corresponding to convex-concave.
The metal base of 40. surperficial tool decoration coatings as claimed in claim 32, wherein, is provided with a laser imprinted layer between described electrodeposited coating and described dyed layer.
The metal base of 41. surperficial tool decoration coatings as claimed in claim 40, wherein, described laser imprinted layer be directly on a metal matrix with the shaping concavo-convex laser embossing of laser-engraving technique, again described metal matrix is added hot padding on described electrodeposited coating, make described electrodeposited coating to have laser embossing corresponding to convex-concave.
The metal base of 42. surperficial tool decoration coatings as claimed in claim 33, wherein, described release layer includes water-based polyamine group formic acid second fat or polyamine group formic acid second fat one of them and cellulose acetate, cellulose acetate-butyrate, cellulose-acetate propionate or nitrocellulose one of them and wax, melamine resin, defoamer, lubrication prescription.
The metal base of 43. surperficial tool decoration coatings as claimed in claim 32, wherein, oil reservoir of the described end be selected from vinyl-based, ethene improved base class, epoxy amine base class or modification alcohol radical resinoid one of them.
The metal base of 44. surperficial tool decoration coatings as claimed in claim 32, wherein, described ink layer be selected from acrylic compounds, polyesters, alkyd base class or acid modified alcoholic base class resin one of them, and add a certain amount of Chinese white.
The metal base of 45. surperficial tool decoration coatings as claimed in claim 44, wherein, described Chinese white be selected from titanium dioxide, titanium dioxide one of them.
The metal base of 46. surperficial tool decoration coatings as claimed in claim 32, wherein, described cementing layer be adopt UV glue, UV gloss oil or UV resin one of them.
The metal base of 47. surperficial tool decoration coatings as claimed in claim 32, wherein, described glazing layer be selected from acrylic compounds, acrylic-amino class, epoxies, alcohol acids or polyalcohols resin one of them.
The metal base of 48. surperficial tool decoration coatings as claimed in claim 32, wherein, described dyed layer comprise epoxy resin, thermoplasticity acrylic resin, melamine resin, thermosetting acrylic resin, polyamine group formic acid second fat, acrylic polyol resin, abietic resin one of them and nitrocellulose, cellulose-acetate propionate one of them, diallyl phthalate and carbimide base bridging agent, carboxylic acid group's bridging agent wherein one and dyestuff.
The metal base of 49. surperficial tool decoration coatings as claimed in claim 32, wherein, the plating material of described electrodeposited coating be selected from aluminium or zinc sulphide one of them.
The metal base of 50. surperficial tool decoration coatings as claimed in claim 32, wherein, the composition of described following layer be selected from thermoplasticity acrylic resin, polyamine group formic acid second fat, chlorinated polypropylene, chlorination butadiene rubber, polyketone resin, epoxy resin, polymethacrylate resin, vinyl chloride resin, abietic resin, silica one of them.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410043722.5A CN104802484A (en) | 2014-01-29 | 2014-01-29 | Metal base material with surface decorative films |
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| CN201410043722.5A CN104802484A (en) | 2014-01-29 | 2014-01-29 | Metal base material with surface decorative films |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107718831A (en) * | 2017-11-08 | 2018-02-23 | 佛山市顺德区宝丽马彩膜板业科技有限公司 | A kind of decorating film easy to use |
-
2014
- 2014-01-29 CN CN201410043722.5A patent/CN104802484A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107718831A (en) * | 2017-11-08 | 2018-02-23 | 佛山市顺德区宝丽马彩膜板业科技有限公司 | A kind of decorating film easy to use |
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