TWM474629U - Reset device for pinball game table - Google Patents

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Publication number
TWM474629U
TWM474629U TW102221343U TW102221343U TWM474629U TW M474629 U TWM474629 U TW M474629U TW 102221343 U TW102221343 U TW 102221343U TW 102221343 U TW102221343 U TW 102221343U TW M474629 U TWM474629 U TW M474629U
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Taiwan
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layer
laser
metal substrate
embossing
decorative film
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TW102221343U
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Chinese (zh)
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Guo-Long Cai
Jia-You Lin
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Univacco Technology Inc
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Description

表面具裝飾膜層之金屬基材Metal substrate with decorative film on the surface

本創作係有關於一種表面具裝飾膜層之金屬基材,尤其是指一種具備表面平整度佳、耐刮性佳、製作容易、節省成本之效果之表面具有裝飾膜層的金屬基材者。The present invention relates to a metal substrate having a decorative film layer on the surface, and particularly to a metal substrate having a decorative film layer on the surface having a good surface smoothness, good scratch resistance, easy fabrication, and cost saving effect.

按,馬口鐵因具有不透光性及良好的密封性,而且其表面之錫既不被空氣氧化又不與水反應,所以有相當強的抗腐蝕能力,不易生鏽,使得馬口鐵罐具有食品貯存之高穩定性與較佳營養素保存性之優勢,因此,馬口鐵被大量用來作為食品包裝之容器,甚至用來作為油脂罐、化學品罐、噴霧罐等。According to the tinplate, because of the opacity and good sealing property, and the tin on the surface is neither oxidized by air nor reacted with water, it has a strong anti-corrosion ability and is not easy to rust, so that the tinplate can have food storage. The high stability and the superiority of nutrient preservation, therefore, tinplate is used in large quantities as a container for food packaging, and even as a grease can, chemical can, spray can, and the like.

一般以馬口鐵作為包裝材料時,為標示內容物及品牌,因此必須在馬口鐵的表面設置標示內容物及品牌之相關圖案或文字(即印鐵),而其設置之方式是先在馬口鐵表面完成印刷圖案或文字之後,再將馬口鐵製成各種規格容器。Generally, when tinplate is used as the packaging material, it is used to mark the contents and brand. Therefore, it is necessary to set the relevant content or brand related pattern or text (ie, printed iron) on the surface of the tinplate, and the setting method is to finish the printing pattern on the surface of the tinplate. Or after the text, the tinplate is made into containers of various specifications.

而印鐵通常採用膠印方式,主要利用水、墨相斥的物理性質,藉印刷壓力,經由橡皮布把印刷模版上的圖文轉印到馬口鐵上,屬於平版膠印原理。而因馬口鐵表面光潔,不吸收油墨,且具有一定的硬度和厚度,所以印刷油墨對馬口鐵需有較好的附著力,否則印刷油墨將無法附著或是容易脫落,影響印刷品質。同時,馬口鐵表層油墨是利用熱固化形式乾燥,因此,控制對馬口鐵表層油墨的烘烤溫度,是馬口鐵產品品質的關鍵所在,它將直接影響整個油墨膜層的附著力。當烘烤溫度偏低,樹脂中的化學分子鍵未充分交聯固化成膜,非但無附著力可言,還會造成馬口鐵背面沾黏,出現反印的現象,以致下道工序因油墨沾黏,使馬口鐵分張困難,影響套色。當烘烤溫度過高,化學分子鍵斷裂,油墨膜層脆化乾裂,將會因為無法承受機械加工及高溫殺菌而脫落。因此,此一技術在實施時,必須嚴格控制烘烤溫度,且機台的運轉速度也應控制在一定範圍內,以保證油墨膜層有合適的烘烤時間,然此卻導致業者在生產製造上的困擾與不便,同時所需之成本也較高,無法提升較佳之產品利潤。The printing iron usually adopts the offset printing method, mainly uses the physical properties of water and ink repelling, and transfers the graphic on the printing stencil to the tinplate via the blanket by the printing pressure, which belongs to the principle of lithographic offset printing. Because the surface of the tinplate is smooth, does not absorb ink, and has a certain hardness and thickness, the printing ink needs good adhesion to the tinplate, otherwise the printing ink will not adhere or fall off easily, which affects the printing quality. At the same time, the tinplate surface ink is dried by means of heat curing. Therefore, controlling the baking temperature of the tinplate surface ink is the key to the quality of the tinplate product, and it will directly affect the adhesion of the entire ink film layer. When the baking temperature is low, the chemical molecular bonds in the resin are not sufficiently cross-linked to form a film, and there is no adhesion, and the back surface of the tinplate is sticky, and the reverse printing phenomenon occurs, so that the next process is stuck due to the ink. It makes it difficult to separate the tinplate and affect the color registration. When the baking temperature is too high, the chemical molecular bonds are broken, and the ink film layer is brittle and dry, which will fall off because it cannot withstand mechanical processing and high temperature sterilization. Therefore, when this technology is implemented, the baking temperature must be strictly controlled, and the operating speed of the machine should be controlled within a certain range to ensure proper baking time of the ink film layer, which leads to the manufacturer's manufacturing. The troubles and inconveniences are high, and the cost required is also high, which cannot improve the profit of the better products.

今,本創作人即是鑒於上述之情形,而開發出本案之結構,以改善現有結構在使用上的缺失。Today, the creator developed the structure of the case in view of the above situation to improve the use of the existing structure.

本創作之主要目的,係提供一種表面具裝飾膜層之金屬基材,主要是透過冷轉印或冷燙金的方式於金屬基材表面形成裝飾膜層,且使該裝飾膜層具有電鍍或/及雷射效果,可提升產品獨特性及附加價值,以增加產品利潤。尤其此雷射效果是一般油墨或金屬油墨印刷無法達到的效果,且雷射樣式種類多,可提供多種不同選擇。The main purpose of the present invention is to provide a metal substrate having a decorative film layer on the surface thereof, which is mainly formed by forming a decorative film layer on the surface of the metal substrate by cold transfer or cold stamping, and the decorative film layer is plated or/ And the laser effect can enhance product uniqueness and added value to increase product profit. In particular, this laser effect is an effect that cannot be achieved by general ink or metal ink printing, and there are many types of laser styles, and various options are available.

本創作之另一主要目的,係解決過去馬口鐵的印刷過程,其表層油墨是利用熱固化形式乾燥,需要較高的烘烤溫度,且溫度控制不易,導致在生產上的困擾與不便;本創作所採用之技術,不需要進行烘烤溫度的控管,因此能減少生產過程中的困擾與不便,進而提升產品製造過程的良率,降低生產製造成本,提升利潤。Another main purpose of this creation is to solve the printing process of tinplate in the past. The surface ink is dried by heat curing, which requires high baking temperature, and temperature control is not easy, which causes trouble and inconvenience in production; The technology used does not require the control of the baking temperature, so it can reduce the troubles and inconveniences in the production process, thereby improving the yield of the product manufacturing process, reducing the manufacturing cost and increasing the profit.

上述本創作之主要目的與功效,是由以下之具體技術手段所達成:The main purpose and effect of the above creations are achieved by the following specific technical means:

一種表面具裝飾膜層之金屬基材,係在一金屬基材表面由下而上依序包括有一底油層、一油墨層、一印刷層、一膠合層、一接著層、一電鍍層、一著色層及一上光層;據此,即能在金屬基材表面形成電鍍壓印膜層,且具備表面平整度佳、耐刮性佳、製作容易、節省成本之效果。A metal substrate having a decorative film layer on a surface of a metal substrate, which comprises a bottom oil layer, an ink layer, a printing layer, a glue layer, an adhesive layer, a plating layer, and a layer from bottom to top. The colored layer and a glazing layer can form an electroplated embossed film layer on the surface of the metal substrate, and have the advantages of good surface flatness, good scratch resistance, easy production, and cost saving.

如上所述之表面具裝飾膜層之金屬基材,其中,該著色層與該上光層之間設有一離形層。The metal substrate having a decorative film layer on the surface as described above, wherein a separation layer is disposed between the colored layer and the glazing layer.

如上所述之表面具裝飾膜層之金屬基材,其中,在該接著層與該電鍍層之間設有一雷射壓印層。A metal substrate having a decorative film layer as described above, wherein a laser embossing layer is disposed between the bonding layer and the plating layer.

如上所述之表面具裝飾膜層之金屬基材,其中,在該電鍍層與該著色層之間設有一雷射壓印層。A metal substrate having a decorative film layer as described above, wherein a laser embossing layer is disposed between the plating layer and the colored layer.

如上所述之表面具裝飾膜層之金屬基材,其中,在該著色層與該上光層之間設有一雷射壓紋層。The metal substrate having a decorative film layer on the surface as described above, wherein a laser embossed layer is disposed between the colored layer and the glazing layer.

如上所述之表面具裝飾膜層之金屬基材,其中,在該離形層與該上光層之間設有一雷射壓紋層。A metal substrate having a decorative film layer as described above, wherein a laser embossed layer is disposed between the release layer and the glazing layer.

如上所述之表面具裝飾膜層之金屬基材,其中,在該著色層與該上光層之間由下而上依序設有一雷射壓紋層、一塗佈層。The metal substrate having a decorative film layer as described above, wherein a laser embossed layer and a coating layer are sequentially disposed between the colored layer and the glazing layer from bottom to top.

如上所述之表面具裝飾膜層之金屬基材,其中,在該離形層與該上光層之間由下而上依序設有一雷射壓紋層、一塗佈層。The metal substrate having a decorative film layer as described above, wherein a laser embossed layer and a coating layer are sequentially disposed between the release layer and the glazing layer from bottom to top.

如上所述之表面具裝飾膜層之金屬基材,其中,該雷射壓印層係直接於一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於該接著層或該電鍍層上,使該接著層或該電鍍層上具有凸凹對應的雷射壓紋。a metal substrate having a decorative film layer as described above, wherein the laser embossing layer is formed by laser embossing on a metal stencil by laser engraving, and then the metal stencil is heat-embossed. On the adhesive layer or the plating layer, the adhesive layer or the plating layer has a convex and concave corresponding laser embossing.

如上所述之表面具裝飾膜層之金屬基材,其中,該雷射壓紋層係先在一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於一塑膠基材表面,使該塑膠基材表面具有凸凹對應的雷射壓紋,再將該塑膠基材以具有雷射壓紋的表面與該著色層或該離形層結合,待彼此之間的結合狀態固化後,再撕除一部份厚度的該塑膠基材,該撕除的一部份厚度上包含有雷射壓紋,使該著色層或該離形層表面留有一部分未被撕除包含有雷射壓紋的該塑膠基材,令該雷射壓紋得以轉貼於該著色層或該離形層表面,並因此形成該雷射壓紋層。a metal substrate having a decorative film layer as described above, wherein the laser embossed layer is first formed by laser engraving on a metal stencil by a laser engraving technique, and then the metal stencil is heat-embossed. The surface of the plastic substrate is provided with a convex and concave laser embossing on the surface of the plastic substrate, and the plastic substrate is combined with the colored layer or the release layer with a laser embossed surface to be mutually After the bonding state is cured, a portion of the thickness of the plastic substrate is removed, and a portion of the tearing portion is covered with a laser embossing to leave a portion of the colored layer or the surface of the release layer. The plastic substrate comprising the laser embossing is torn off to allow the laser embossing to be applied to the colored layer or the surface of the release layer and thereby form the laser embossed layer.

如上所述之表面具裝飾膜層之金屬基材,其中,該塑膠基材係選自雙軸拉伸聚丙烯薄膜(BOPP)。The metal substrate having a decorative film layer as described above, wherein the plastic substrate is selected from a biaxially oriented polypropylene film (BOPP).

如上所述之表面具裝飾膜層之金屬基材,其中,該雷射壓紋層係先在一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,並於一塑膠基材表面設一塗佈層,將該金屬模版加熱壓印於該塗佈層表面,使該塗佈層表面具有凸凹對應的雷射壓紋,再將該塗佈層以具有雷射壓紋的表面與該著色層或該離形層結合,待彼此之間的結合狀態固化後,再撕除該塑膠基材與該塗佈層的一部份厚度,且該撕除的一部份厚度上包含有雷射壓紋,使該著色層或該離形層表面留有另一部分未被撕除且包含有雷射壓紋的塗佈層,令該雷射壓紋成型於該著色層或該離形層表面,並因此形成該雷射壓紋層。The metal substrate having a decorative film layer as described above, wherein the laser embossed layer is formed by laser embossing on a metal stencil by laser engraving technology, and is disposed on a plastic substrate surface. a coating layer, the metal stencil is heat-embossed on the surface of the coating layer, the surface of the coating layer has a convex and concave corresponding laser embossing, and the coating layer is further provided with a surface having a laser embossing The colored layer or the release layer is combined, and after the bonding state between the two layers is cured, a part of the thickness of the plastic substrate and the coating layer is peeled off, and a part of the thickness of the tearing portion includes a thunder The embossing pattern is such that the colored layer or the surface of the release layer leaves another coating layer which is not torn off and contains laser embossing, and the laser embossing is formed on the colored layer or the release layer. The surface, and thus the laser embossed layer.

如上所述之表面具裝飾膜層之金屬基材,其中,該塑膠基材係選自聚乙烯基對苯二甲酯薄膜(PET)或雙軸拉伸聚丙烯薄膜(BOPP)。The metal substrate having a decorative film layer as described above, wherein the plastic substrate is selected from the group consisting of polyvinyl terephthalate film (PET) or biaxially oriented polypropylene film (BOPP).

如上所述之表面具裝飾膜層之金屬基材,其中,該底油層係選自乙烯基類、改性乙烯基類、環氧胺基類或改性醇基類樹脂其中之一。The metal substrate having a decorative film layer as described above, wherein the primer layer is one selected from the group consisting of vinyl, modified vinyl, epoxy amine based or modified alcohol based resin.

如上所述之表面具裝飾膜層之金屬基材,其中,該油墨層係選自丙烯酸類、聚酯類、醇酸基類或改性醇酸基類樹脂其中之一,並加入一定量之白色顏料。a metal substrate having a decorative film layer as described above, wherein the ink layer is one selected from the group consisting of acrylic, polyester, alkyd or modified alkyd based resins, and is added in a certain amount. White pigment.

如上所述之表面具裝飾膜層之金屬基材,其中,該白色顏料選自鈦白粉、二氧化鈦其中之一。The metal substrate having a decorative film layer as described above, wherein the white pigment is selected from one of titanium dioxide and titanium dioxide.

如上所述之表面具裝飾膜層之金屬基材,其中,該膠合層係採用UV膠、UV光油或UV樹脂其中之一。The metal substrate having a decorative film layer as described above, wherein the glue layer is one of UV glue, UV varnish or UV resin.

如上所述之表面具裝飾膜層之金屬基材,其中,該上光層係選自丙烯酸類、丙烯酸氨基類、環氧類、醇酸類或聚醇類樹脂其中之一。The metal substrate having a decorative film layer as described above, wherein the glazing layer is one selected from the group consisting of acrylic, acrylic acid, epoxy, alkyd or polyalcohol.

如上所述之表面具裝飾膜層之金屬基材,其中,離型層包括有水性聚胺基甲酸乙脂(PU)或聚胺基甲酸乙脂(PU)其中之一與乙酸纖維素(CA)、乙酸丁酸纖維素(CAB)、乙酸丙酸纖維素(CAP)或硝化纖維素(NC)其中之一及臘(WAX)、三聚氰胺甲醛樹脂(MF)、消泡劑、滑劑。a metal substrate having a decorative film layer as described above, wherein the release layer comprises one of aqueous polyurethane (PU) or polyurethane (PU) and cellulose acetate (CA) ), cellulose acetate butyrate (CAB), cellulose acetate propionate (CAP) or nitrocellulose (NC) and wax (WAX), melamine formaldehyde resin (MF), defoamer, slip agent.

如上所述之表面具裝飾膜層之金屬基材,其中,著色層包括環氧樹脂(EP)、熱可塑性丙烯酸樹脂(AC)、三聚氰胺甲醛樹脂(MF)、熱固型丙烯酸樹脂、聚胺基甲酸乙脂(PU)、丙烯酸多元醇樹脂、松香樹脂其中之一與硝化纖維素(NC)、乙酸丙酸纖維素(CAP)其中之一、邻苯二甲酸二烯丙酯(DAP)及異氰酸脂基(-NCO)架橋劑、羧酸基(-COOH)架橋劑其中一和染料。a metal substrate having a decorative film layer as described above, wherein the colored layer comprises an epoxy resin (EP), a thermoplastic acrylic resin (AC), a melamine formaldehyde resin (MF), a thermosetting acrylic resin, and a polyamine group. One of ethyl formate (PU), acrylic polyol resin, and rosin resin, and one of nitrocellulose (NC), cellulose acetate propionate (CAP), diallyl phthalate (DAP), and One of a cyanate-based (-NCO) bridging agent, a carboxylic acid group (-COOH) bridging agent and a dye.

如上所述之表面具裝飾膜層之金屬基材,其中,電鍍層之電鍍材質選自鋁或硫化鋅其中之一。The metal substrate having a decorative film layer as described above, wherein the plating material of the plating layer is selected from one of aluminum or zinc sulfide.

如上所述之表面具裝飾膜層之金屬基材,其中,接著層之成分選自熱可塑性丙烯酸樹脂(AC)、聚胺基甲酸乙脂(PU)、氯化聚丙烯(CPP)、氯化丁二烯橡膠(CR)、聚酮樹脂、環氧樹脂(EP)、聚甲基丙烯酸樹脂(PMMA)、氯乙烯樹脂(Vinyl)、松香樹脂、二氧化矽其中之一。a metal substrate having a decorative film layer as described above, wherein the composition of the adhesive layer is selected from the group consisting of thermoplastic acrylic resin (AC), polyurethane (PU), chlorinated polypropylene (CPP), and chlorination. Butadiene rubber (CR), polyketone resin, epoxy resin (EP), polymethacrylic resin (PMMA), vinyl chloride resin (Vinyl), rosin resin, cerium oxide.

上述本創作之主要目的與功效,又可由以下之具體技術手段所達成:The main purpose and effect of the above creation can be achieved by the following specific technical means:

一種表面具裝飾膜層之金屬基材,係在一金屬基材表面由下而上依序包括有一底油層、一油墨層、一膠合層、一接著層、一電鍍層、一著色層、一印刷層及一上光層;據此,即能在金屬基材表面形成電鍍壓印膜層,且具備表面平整度佳、耐刮性佳、製作容易、節省成本之效果。A metal substrate having a decorative film layer on a surface of a metal substrate, which comprises a bottom oil layer, an ink layer, a glue layer, an adhesive layer, a plating layer, a colored layer, and a layer on the surface of the metal substrate. The printed layer and a glazing layer can form an electroplated embossed film layer on the surface of the metal substrate, and have the advantages of good surface flatness, good scratch resistance, easy fabrication, and cost saving.

如上所述之表面具裝飾膜層之金屬基材,其中,該著色層與該印刷層之間設有一離形層。The metal substrate having a decorative film layer on the surface as described above, wherein a separation layer is disposed between the colored layer and the printing layer.

如上所述之表面具裝飾膜層之金屬基材,其中,在該接著層與該電鍍層之間設有一雷射壓印層。A metal substrate having a decorative film layer as described above, wherein a laser embossing layer is disposed between the bonding layer and the plating layer.

如上所述之表面具裝飾膜層之金屬基材,其中,在該電鍍層與該著色層之間設有一雷射壓印層。A metal substrate having a decorative film layer as described above, wherein a laser embossing layer is disposed between the plating layer and the colored layer.

如上所述之表面具裝飾膜層之金屬基材,其中,該雷射壓印層係直接於一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於該接著層或該電鍍層上,使該該接著層或該電鍍層上具有凸凹對應的雷射壓紋。a metal substrate having a decorative film layer as described above, wherein the laser embossing layer is formed by laser embossing on a metal stencil by laser engraving, and then the metal stencil is heat-embossed. On the adhesive layer or the plating layer, the adhesive layer or the plating layer has a convex and concave corresponding laser embossing.

如上所述之表面具裝飾膜層之金屬基材,其中,該底油層係選自乙烯基類、改性乙烯基類、環氧胺基類或改性醇基類樹脂其中之一。The metal substrate having a decorative film layer as described above, wherein the primer layer is one selected from the group consisting of vinyl, modified vinyl, epoxy amine based or modified alcohol based resin.

如上所述之表面具裝飾膜層之金屬基材,其中,該油墨層係選自丙烯酸類、聚酯類、醇酸基類或改性醇酸基類樹脂其中之一,並加入一定量之白色顏料其中之一。a metal substrate having a decorative film layer as described above, wherein the ink layer is one selected from the group consisting of acrylic, polyester, alkyd or modified alkyd based resins, and is added in a certain amount. One of the white pigments.

如上所述之表面具裝飾膜層之金屬基材,其中,該白色顏料選自鈦白粉、二氧化鈦其中之一。The metal substrate having a decorative film layer as described above, wherein the white pigment is selected from one of titanium dioxide and titanium dioxide.

如上所述之表面具裝飾膜層之金屬基材,其中,該膠合層係採用UV膠、UV光油或UV樹脂其中之一。The metal substrate having a decorative film layer as described above, wherein the glue layer is one of UV glue, UV varnish or UV resin.

如上所述之表面具裝飾膜層之金屬基材,其中,該上光層係選自丙烯酸類、丙烯酸氨基類、環氧類、醇酸類或聚醇類樹脂其中之一。The metal substrate having a decorative film layer as described above, wherein the glazing layer is one selected from the group consisting of acrylic, acrylic acid, epoxy, alkyd or polyalcohol.

如上所述之表面具裝飾膜層之金屬基材,其中,離型層包括有水性聚胺基甲酸乙脂(PU)或聚胺基甲酸乙脂(PU)其中之一與乙酸纖維素(CA)、乙酸丁酸纖維素(CAB)、乙酸丙酸纖維素(CAP)或硝化纖維素(NC)其中之一及臘(WAX)、三聚氰胺甲醛樹脂(MF)、消泡劑、滑劑。a metal substrate having a decorative film layer as described above, wherein the release layer comprises one of aqueous polyurethane (PU) or polyurethane (PU) and cellulose acetate (CA) ), cellulose acetate butyrate (CAB), cellulose acetate propionate (CAP) or nitrocellulose (NC) and wax (WAX), melamine formaldehyde resin (MF), defoamer, slip agent.

如上所述之表面具裝飾膜層之金屬基材,其中,著色層包括環氧樹脂(EP)、熱可塑性丙烯酸樹脂(AC)、三聚氰胺甲醛樹脂(MF)、熱固型丙烯酸樹脂、聚胺基甲酸乙脂(PU)、丙烯酸多元醇樹脂、松香樹脂其中之一與硝化纖維素(NC)、乙酸丙酸纖維素(CAP)其中之一、邻苯二甲酸二烯丙酯(DAP)及異氰酸脂基(-NCO)架橋劑、羧酸基(-COOH)架橋劑其中一和染料。a metal substrate having a decorative film layer as described above, wherein the colored layer comprises an epoxy resin (EP), a thermoplastic acrylic resin (AC), a melamine formaldehyde resin (MF), a thermosetting acrylic resin, and a polyamine group. One of ethyl formate (PU), acrylic polyol resin, and rosin resin, and one of nitrocellulose (NC), cellulose acetate propionate (CAP), diallyl phthalate (DAP), and One of a cyanate-based (-NCO) bridging agent, a carboxylic acid group (-COOH) bridging agent and a dye.

如上所述之表面具裝飾膜層之金屬基材,其中,電鍍層之電鍍材質選自鋁或硫化鋅其中之一。The metal substrate having a decorative film layer as described above, wherein the plating material of the plating layer is selected from one of aluminum or zinc sulfide.

如上所述之表面具裝飾膜層之金屬基材,其中,接著層之成分選自熱可塑性丙烯酸樹脂(AC)、聚胺基甲酸乙脂(PU)、氯化聚丙烯(CPP)、氯化丁二烯橡膠(CR)、聚酮樹脂、環氧樹脂(EP)、聚甲基丙烯酸樹脂(PMMA)、氯乙烯樹脂(Vinyl)、松香樹脂、二氧化矽其中之一。a metal substrate having a decorative film layer as described above, wherein the composition of the adhesive layer is selected from the group consisting of thermoplastic acrylic resin (AC), polyurethane (PU), chlorinated polypropylene (CPP), and chlorination. Butadiene rubber (CR), polyketone resin, epoxy resin (EP), polymethacrylic resin (PMMA), vinyl chloride resin (Vinyl), rosin resin, cerium oxide.

為令本創作所運用之技術內容、創作目的及其達成之功效有更完整且清楚的揭露,茲於下詳細說明之,並請一併參閱所揭之圖式及圖號:In order to make the technical content, creative purpose and the effect achieved by this creation more complete and clear, please elaborate below, and please refer to the drawings and drawings:

請參看第一圖所示,其係本創作之表面具裝飾膜層之金屬基材的其一較佳實施例結構斷面示意圖。Referring to the first figure, it is a structural cross-sectional view of a preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention.

本實施例係在一金屬基材(11)表面由下而上依序包括有一底油層(12)、一油墨層(13)、一印刷層(14)、一膠合層(15)、一接著層(25)、一電鍍層(24)、一著色層(23)及一上光層(31)。In this embodiment, a bottom layer (12), an ink layer (13), a printed layer (14), a glue layer (15), and a layer are sequentially arranged from bottom to top on the surface of a metal substrate (11). A layer (25), a plating layer (24), a colored layer (23) and a glazing layer (31).

請參看第二圖,其中該著色層(23)、該電鍍層(24)、該接著層(25)係由下而上先成型於一塑膠薄膜(21)表面的離形層(22)上,以形成一裝飾膜(2)結構,接著,令該金屬基材(11)表面由下而上依序成型該底油層(12)、該油墨層(13)、該印刷層(14)及該膠合層(15)後,再將該裝飾膜(2)以其接著層(25)貼合於該膠合層(15)上,最後將該塑膠薄膜(21)連同該離形層(22)一併撕除後,再於該著色層(23)上設置該上光層(31),如此即得如第一圖所示之其一較佳實施例結構。Referring to the second figure, the colored layer (23), the plating layer (24), and the bonding layer (25) are formed on the release layer (22) of the surface of a plastic film (21) from bottom to top. Forming a decorative film (2) structure, and then sequentially molding the bottom surface layer (12), the ink layer (13), the printing layer (14), and the surface of the metal substrate (11) from bottom to top. After the glue layer (15), the decorative film (2) is attached to the glue layer (15) with its adhesive layer (25), and finally the plastic film (21) is combined with the release layer (22). After the tearing off, the glazing layer (31) is further disposed on the colored layer (23), so that the structure of a preferred embodiment as shown in the first figure is obtained.

其中,在本實施例中,該底油層(12)係選自乙烯基類、改性乙烯基類、環氧胺基類或改性醇基類樹脂其中之一。該油墨層(13)係選自丙烯酸類、聚酯類、醇酸基類或改性醇酸基類樹脂其中之一,並加入一定量之白色顏料;該白色顏料選自鈦白粉、二氧化鈦其中之一。該膠合層(15)係採用UV膠、UV光油或UV樹脂其中之一。該上光層係選自丙烯酸類、丙烯酸氨基類、環氧類、醇酸類或聚醇類樹脂其中之一。In the present embodiment, the primer layer (12) is one selected from the group consisting of vinyl, modified vinyl, epoxy amine based or modified alcohol based resins. The ink layer (13) is selected from one of an acrylic, a polyester, an alkyd or a modified alkyd based resin, and a certain amount of a white pigment is added; the white pigment is selected from the group consisting of titanium dioxide and titanium dioxide. one. The glue layer (15) is one of UV glue, UV varnish or UV resin. The glazing layer is selected from one of an acrylic, an acryl amide, an epoxy, an alkyd or a polyalcohol.

該塑膠薄膜(21)係選自聚乙烯基對苯二甲酯薄膜(PET)。該離型層(22)包括有水性聚胺基甲酸乙脂(PU)或聚胺基甲酸乙脂(PU)其中之一與乙酸纖維素(CA)、乙酸丁酸纖維素(CAB)、乙酸丙酸纖維素(CAP)或硝化纖維素(NC)其中之一及臘(WAX)、三聚氰胺甲醛樹脂(MF)、消泡劑、滑劑。The plastic film (21) is selected from the group consisting of polyvinyl terephthalate film (PET). The release layer (22) comprises one of aqueous polyurethane (PU) or polyurethane (PU) and cellulose acetate (CA), cellulose acetate butyrate (CAB), acetic acid One of cellulose propionate (CAP) or nitrocellulose (NC) and wax (WAX), melamine formaldehyde resin (MF), antifoaming agent, and slip agent.

而該著色層(23)包括環氧樹脂(EP)、熱可塑性丙烯酸樹脂(AC)、三聚氰胺甲醛樹脂(MF)、熱固型丙烯酸樹脂、聚胺基甲酸乙脂(PU)、丙烯酸多元醇樹脂、松香樹脂其中之一與硝化纖維素(NC)、乙酸丙酸纖維素(CAP)其中之一、邻苯二甲酸二烯丙酯(DAP)及異氰酸脂基(-NCO)架橋劑、羧酸基(-COOH)架橋劑其中一和染料。The colored layer (23) comprises an epoxy resin (EP), a thermoplastic acrylic resin (AC), a melamine formaldehyde resin (MF), a thermosetting acrylic resin, a polyurethane (PU), an acrylic polyol resin. One of rosin resins and one of nitrocellulose (NC), cellulose acetate propionate (CAP), diallyl phthalate (DAP) and isocyanate-based (-NCO) bridging agent, One of the carboxylic acid group (-COOH) bridging agents and the dye.

至於該電鍍層(24)之電鍍材質選自鋁或硫化鋅其中之一。該接著層(25)之成分選自熱可塑性丙烯酸樹脂(AC)、聚胺基甲酸乙脂(PU)、氯化聚丙烯(CPP)、氯化丁二烯橡膠(CR)、聚酮樹脂、環氧樹脂(EP)、聚甲基丙烯酸樹脂(PMMA)、氯乙烯樹脂(Vinyl)、松香樹脂、二氧化矽其中之一。The plating material of the plating layer (24) is selected from one of aluminum or zinc sulfide. The component of the adhesive layer (25) is selected from the group consisting of thermoplastic acrylic resin (AC), polyurethane (PU), chlorinated polypropylene (CPP), chlorinated butadiene rubber (CR), polyketone resin, Epoxy resin (EP), polymethacrylic resin (PMMA), vinyl chloride resin (Vinyl), rosin resin, cerium oxide.

請參看第三圖所示,其係本創作之表面具裝飾膜層之金屬基材的其二較佳實施例結構斷面示意圖。Please refer to the third figure, which is a schematic cross-sectional view of a second preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention.

本實施例與其一較佳實施例的差異之處,係在該著色層(23)與該上光層(31)之間設有一離形層(22)。即本實施例係在一金屬基材(11)表面由下而上依序包括有一底油層(12)、一油墨層(13)、一印刷層(14)、一膠合層(15)、一接著層(25)、一電鍍層(24)、一著色層(23)、及一離形層(22)一上光層(31)。The difference between this embodiment and its preferred embodiment is that a release layer (22) is disposed between the colored layer (23) and the glazing layer (31). That is, the present embodiment includes a bottom oil layer (12), an ink layer (13), a printing layer (14), a glue layer (15), and a bottom portion of a metal substrate (11). Next, a layer (25), a plating layer (24), a colored layer (23), and a release layer (22) a glazing layer (31).

其中,請參看第四圖,本實施例主要是在將該裝飾膜(2)以其接著層(25)貼合於該膠合層(15)上後,最後僅將該塑膠薄膜(21)撕除,使該離形層(22)留存於該著色層(23)上,再於該離形層(22)上設置該上光層(31),如此即得如第三圖所示之其二較佳實施例結構。Please refer to the fourth figure. In this embodiment, after the decorative film (2) is attached to the bonding layer (15) with the adhesive layer (25), only the plastic film (21) is finally torn. In addition, the release layer (22) is retained on the colored layer (23), and the glazing layer (31) is disposed on the release layer (22), so that it is as shown in the third figure. The structure of the second preferred embodiment.

請參看第五圖所示,其係本創作之表面具裝飾膜層之金屬基材的其三較佳實施例結構斷面示意圖。本實施例係延續其一較佳實施例之結構,其與其一較佳實施例的差異之處係在:該接著層(25)與該電鍍層(24)之間設有一雷射壓印層(26)。Referring to FIG. 5, it is a structural cross-sectional view of a third preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention. This embodiment is a continuation of the structure of a preferred embodiment thereof, which differs from a preferred embodiment in that a laser embossing layer is disposed between the bonding layer (25) and the plating layer (24). (26).

請參看第六圖所示,其係本創作之表面具裝飾膜層之金屬基材的其四較佳實施例結構斷面示意圖。本實施例係延續其二較佳實施例之結構,其與其二較佳實施例的差異之處係在:該接著層(25)與該電鍍層(24)之間設有一雷射壓印層(26)。Please refer to the sixth figure, which is a schematic cross-sectional view of a fourth preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention. This embodiment is a continuation of the structure of the second preferred embodiment, which differs from the two preferred embodiments in that a laser embossing layer is disposed between the bonding layer (25) and the plating layer (24). (26).

請參看第七圖所示,其係本創作之表面具裝飾膜層之金屬基材的其五較佳實施例結構斷面示意圖。本實施例係延續其一較佳實施例之結構,其與其一較佳實施例的差異之處係在:該電鍍層(24)與該著色層(23)之間設有一雷射壓印層(26)。Referring to the seventh figure, it is a structural sectional view of a fifth preferred embodiment of the metal substrate having a decorative film layer on the surface of the present invention. This embodiment is a continuation of the structure of a preferred embodiment thereof, which differs from a preferred embodiment in that a laser embossing layer is disposed between the plating layer (24) and the colored layer (23). (26).

請參看第八圖所示,其係本創作之表面具裝飾膜層之金屬基材的其六較佳實施例結構斷面示意圖。本實施例係延續其二較佳實施例之結構,其與其二較佳實施例的差異之處係在:該電鍍層(24)與該著色層(23)之間設有一雷射壓印層(26)。Referring to FIG. 8 , it is a structural cross-sectional view of a sixth preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention. This embodiment is a continuation of the structure of the second preferred embodiment, which differs from the two preferred embodiments in that a laser embossing layer is disposed between the plating layer (24) and the colored layer (23). (26).

其中,如上所述本創作之表面具裝飾膜層之金屬基材的其三、其四、其五與其六較佳實施例,該雷射壓印層(26)係直接於一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於該接著層(25)或該電鍍層(24)上,使該接著層(25)或該電鍍層(24)上具有凸凹對應的雷射壓紋,而形成該雷射壓印層(26)。Wherein, as described above, the third surface of the metal substrate having the decorative film layer, the fourth, the fifth, and the sixth preferred embodiment thereof, the laser embossing layer (26) is directly on a metal stencil The laser engraving technique forms a laser embossing of the bump, and then the metal stencil is heat-embossed on the adhesive layer (25) or the plating layer (24) to make the adhesive layer (25) or the plating layer (24) The laser embossing layer (26) is formed by having a laser embossing corresponding to the convex and concave.

請參看第九圖所示,其係本創作之表面具裝飾膜層之金屬基材的其七較佳實施例結構斷面示意圖。本實施例仍係延續其一較佳實施例之結構,其與其一較佳實施例的差異之處係在:該著色層(23)與該上光層(31)之間設有一雷射壓紋層(41)。Please refer to the ninth figure, which is a structural sectional view of a seventh preferred embodiment of the metal substrate with a decorative film layer on the surface of the present invention. This embodiment is still a structure of a preferred embodiment thereof, which differs from a preferred embodiment in that a laser pressure is provided between the colored layer (23) and the glazing layer (31). Texture layer (41).

其中,請參看第十圖,該雷射壓紋層(41)的其一成型方式為:係先在一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於一塑膠基材(42)表面,使該塑膠基材(42)表面具有凸凹對應的雷射壓紋,再將該塑膠基材(42)以具有雷射壓紋的表面與該著色層(23)結合,待該塑膠基材(42)與該著色層(23)之間的結合狀態固化後,再撕除一部份厚度的塑膠基材(42),該撕除的一部份厚度上包含有雷射壓紋,使該著色層(23)表面留有一部分未被撕除且包含有雷射壓紋的塑膠基材(42),令該塑膠基材(42)的雷射壓紋轉貼於該著色層(23)表面,並因此形成該雷射壓紋層(41)。其中,該塑膠基材(42)係選自雙軸拉伸聚丙烯薄膜(BOPP)。Referring to the tenth figure, the laser embossed layer (41) is formed by first forming a laser embossing of a concave and convex surface by laser engraving on a metal stencil, and then heating the metal stencil. Imprinting on the surface of a plastic substrate (42), the surface of the plastic substrate (42) has a convex and concave corresponding embossing, and then the plastic substrate (42) is surfaced with a laser embossed surface and the coloring The layer (23) is bonded, and after the bonding state between the plastic substrate (42) and the colored layer (23) is cured, a part of the thickness of the plastic substrate (42) is removed, and the torn part is removed. The thickness of the portion of the colored layer (23) is left with a part of the plastic substrate (42) which is not torn off and contains laser embossing, so that the plastic substrate (42) is made of thunder The embossing pattern is applied to the surface of the colored layer (23), and thus the laser embossed layer (41) is formed. Wherein, the plastic substrate (42) is selected from the group consisting of biaxially oriented polypropylene film (BOPP).

其中,請參看第十二圖,該雷射壓紋層(41)的其二成型方式為:係先在一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,並於一塑膠基材(42)表面設一塗佈層(43),將該金屬模版加熱壓印於該塗佈層(43)表面,使該塗佈層(43)表面具有凸凹對應的雷射壓紋,再將該塗佈層(43)以具有雷射壓紋的表面與該著色層(23)結合,待該塗佈層(43)與該著色層(23)彼此之間的結合狀態固化後,再撕除該塑膠基材(42)與該塗佈層(43)的一部份厚度,且該撕除的一部份厚度上包含有雷射壓紋,使該著色層(23)表面留有另一部分未被撕除且包含有雷射壓紋的塗佈層(43),令該雷射壓紋成型於該著色層(23)表面,並因此形成該雷射壓紋層(41);如此一來,使該著色層(23)之上依序為該雷射壓紋層(41)、該塗佈層(43)、上光層(31)[參第十一圖]。其中,該塑膠基材(42)係選自聚乙烯基對苯二甲酯薄膜(PET)或雙軸拉伸聚丙烯薄膜(BOPP)。Referring to the twelfth figure, the laser embossing layer (41) is formed by the following method: firstly, laser embossing is formed on a metal stencil by laser engraving technology, and is formed on a plastic base. a coating layer (43) is disposed on the surface of the material (42), and the metal stencil is heat-embossed on the surface of the coating layer (43), so that the surface of the coating layer (43) has a convex and concave corresponding embossing, and then The coating layer (43) is bonded to the colored layer (23) with a laser embossed surface, and after the bonding state of the coating layer (43) and the colored layer (23) is solidified, And peeling off a portion of the thickness of the plastic substrate (42) and the coating layer (43), and the portion of the tearing portion comprises laser embossing, leaving the surface of the colored layer (23) Another portion of the coating layer (43) that has not been torn off and contains laser embossing, so that the laser embossing is formed on the surface of the colored layer (23), and thus the laser embossed layer (41) is formed; In this way, the colored layer (23) is sequentially arranged as the laser embossed layer. 41), the coating layer (43), the glaze layer (31) [reference to FIG Eleventh]. Wherein, the plastic substrate (42) is selected from a polyethylene terephthalate film (PET) or a biaxially oriented polypropylene film (BOPP).

請參看第十三圖所示,其係本創作之表面具裝飾膜層之金屬基材的其九較佳實施例結構斷面示意圖。本實施例係延續其二較佳實施例之結構,其與其二較佳實施例的差異之處係在:該離形層(22)與該上光層(31)之間設有一雷射壓紋層(41)。Referring to Fig. 13, there is shown a schematic sectional view of a nine preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention. This embodiment is a continuation of the structure of the second preferred embodiment, which differs from the two preferred embodiments in that a laser pressure is provided between the release layer (22) and the glazing layer (31). Texture layer (41).

其中,請參看第十四圖,該雷射壓紋層(41)的其一成型方式為:係先在一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於一塑膠基材(42)表面,使該塑膠基材(42)表面具有凸凹對應的雷射壓紋,再將該塑膠基材(42)以具有雷射壓紋的表面與該離形層(22)結合,待該塑膠基材(42)與該離形層(22)彼此之間的結合狀態固化後,再撕除一部份厚度的塑膠基材(42),該撕除的一部份厚度上包含有雷射壓紋,使該著色層(22)表面留有一部分未被撕除包含有雷射壓紋的塑膠基材(42),令該離形層(22)表面留有所需之部分雷射壓紋,並因此形成該雷射壓紋層(41)。其中,該塑膠基材(42)係選自雙軸拉伸聚丙烯薄膜(BOPP)。Referring to FIG. 14 , the laser embossed layer ( 41 ) is formed by first forming a laser embossing of a concave and convex laser on a metal stencil by a laser engraving technique, and then the metal stencil. Heating and imprinting on the surface of a plastic substrate (42), so that the surface of the plastic substrate (42) has a convex and concave corresponding embossing, and then the plastic substrate (42) has a surface with a laser embossing The release layer (22) is combined, and after the bonding state of the plastic substrate (42) and the release layer (22) is solidified, a part of the thickness of the plastic substrate (42) is peeled off. A portion of the thickness includes a laser embossing such that a portion of the surface of the colored layer (22) is left without tearing off the plastic substrate (42) containing the laser embossing, so that the release layer (22) The surface is left with the desired portion of the laser embossing and thus forms the laser embossed layer (41). Wherein, the plastic substrate (42) is selected from the group consisting of biaxially oriented polypropylene film (BOPP).

其中,請參看第十六圖,該雷射壓紋層(41)的其二成型方式為:係先在一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,並於一塑膠基材(42)表面設一塗佈層(43),將該金屬模版加熱壓印於該塗佈層(43)表面,使該塗佈層(43)表面具有凸凹對應的雷射壓紋,再將該塗佈層(43)以具有雷射壓紋的表面與該離形層(22)結合,待該塗佈層(43)與該離形層(22)彼此之間的結合狀態固化後,再撕除該塑膠基材(42)與該塗佈層(43)的一部份厚度,且該撕除的一部份厚度上包含有雷射壓紋,使該離形層(22)表面留有另一部分未被撕除且包含有雷射壓紋的塗佈層(43),令該離形層(22)表面上因此形成該雷射壓紋層(41);如此一來,使該離形層(22)之上依序為該雷射壓紋層(41)、該塗佈層(43)、上光層(31)[參第十五圖]。Referring to the sixteenth figure, the laser embossing layer (41) is formed by the following method: firstly, laser embossing is performed on a metal stencil by laser engraving technology, and is formed on a plastic base. a coating layer (43) is disposed on the surface of the material (42), and the metal stencil is heat-embossed on the surface of the coating layer (43), so that the surface of the coating layer (43) has a convex and concave corresponding embossing, and then The coating layer (43) is bonded to the release layer (22) with a laser embossed surface, and after the bonding layer (43) and the release layer (22) are bonded to each other, the bonding state is cured. And then peeling off a portion of the thickness of the plastic substrate (42) and the coating layer (43), and the portion of the tearing portion includes laser embossing to make the release layer (22) The surface leaves another coating layer (43) which is not torn off and contains laser embossing, so that the surface of the release layer (22) thus forms the laser embossed layer (41); thus, The laser embossed layer (41) and the coating layer are sequentially arranged on the release layer (22). 43), the glaze layer (31) [reference to FIG XV].

請參看第十七圖所示,其係本創作之表面具裝飾膜層之金屬基材的其十一較佳實施例結構斷面示意圖。Please refer to FIG. 17, which is a structural sectional view of an eleventh preferred embodiment of the metal substrate having a decorative film layer on the surface of the present invention.

在本實施例中,主要係在一金屬基材(51)表面由下而上依序包括設置有一底油層(52)、一油墨層(53)、一膠合層(54)、一接著層(65)、一電鍍層(64)、一著色層(63)、一印刷層(71)及一上光層(72);據此,即能在金屬基材(51)表面形成電鍍壓印膜層(6),且具備表面平整度佳、耐刮性佳、製作容易、節省成本之效果。In this embodiment, the bottom surface of the metal substrate (51) is mainly provided with a bottom oil layer (52), an ink layer (53), a glue layer (54), and an adhesive layer. 65), an electroplated layer (64), a colored layer (63), a printed layer (71) and a glazing layer (72); accordingly, an electroplated embossing film can be formed on the surface of the metal substrate (51) The layer (6) has the advantages of good surface flatness, good scratch resistance, easy production, and cost saving.

請參看第十八圖,其中該著色層(63)、該電鍍層(64)、該接著層(65)係由下而上先成型於一塑膠薄膜(61)表面的離形層(62)上,以形成一電鍍壓印膜層(6)結構,接著,令該金屬基材(51)表面由下而上依序成型該底油層(52)、該油墨層(53)、該膠合層(54)後,再將該電鍍壓印膜層(6)以其接著層(65)貼合於該膠合層(54)上,最後將該塑膠薄膜(61)連同該離形層(62)一併撕除後,再於該著色層(63)上由下而上依序設置該印刷層(71)與該上光層(72),如此即得如第十七圖所示之其十一較佳實施例結構。Referring to FIG. 18, the colored layer (63), the plating layer (64), and the adhesive layer (65) are a release layer (62) formed on the surface of a plastic film (61) from bottom to top. Forming a structure of the electroplated embossed film layer (6), and then sequentially molding the surface of the metal substrate (51) from the bottom to the bottom layer (52), the ink layer (53), the glue layer After (54), the electroplated imprinting film layer (6) is attached to the bonding layer (54) with its adhesive layer (65), and finally the plastic film (61) is combined with the release layer (62). After being removed together, the printed layer (71) and the glazing layer (72) are sequentially disposed from the bottom to the top on the colored layer (63), so that the ten layers as shown in FIG. A preferred embodiment structure.

請參看第十九圖所示,其係本創作之表面具裝飾膜層之金屬基材的其十二較佳實施例結構斷面示意圖。本實施例與其十一較佳實施例的差異之處,係在該著色層(63)與該印刷層(72)之間設有一離形層(62)。即本實施例係在一金屬基材(51)表面由下而上依序包括有一底油層(52)、一油墨層(53)、一膠合層(54)、一接著層(65)、一電鍍層(64)、一著色層(63)、一離形層(62)、一印刷層(71)及一上光層(72)。Referring to Fig. 19, it is a schematic sectional view showing the structure of a twelve-preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention. The difference between this embodiment and its eleventh preferred embodiment is that a release layer (62) is disposed between the colored layer (63) and the printed layer (72). That is, the embodiment comprises a bottom oil layer (52), an ink layer (53), a glue layer (54), an adhesive layer (65), and a bottom layer on the surface of a metal substrate (51). A plating layer (64), a colored layer (63), a release layer (62), a printed layer (71), and a glazing layer (72).

其中,請參看第二十圖,本實施例主要是在將該電鍍壓印膜層(6)以其接著層(65)貼合於該膠合層(54)上後,最後僅將該塑膠薄膜(61)撕除,使該離形層(62)留存於該著色層(63)上,再於該離形層(62)上由下而上依序設置該印刷層(71)與該上光層(72),如此即得如第十九圖所示之其十二較佳實施例結構。For example, please refer to the twentieth figure. In this embodiment, after the electroplating embossing film layer (6) is attached to the bonding layer (54) with the adhesive layer (65), only the plastic film is finally applied. (61) tearing off, leaving the release layer (62) on the colored layer (63), and then sequentially placing the printed layer (71) and the upper layer on the release layer (62) from bottom to top. The optical layer (72) thus has the structure of its twelve preferred embodiments as shown in Fig. 19.

請參看第二十一圖所示,其係本創作之表面具裝飾膜層之金屬基材的其十三較佳實施例結構斷面示意圖。本實施例係延續其十一較佳實施例之結構,其與其十一較佳實施例的差異之處係在:該接著層(65)與該電鍍層(64)之間設有一雷射壓印層(66)。Referring to the twenty-first embodiment, it is a structural sectional view of a thirteenth preferred embodiment of the metal substrate having a decorative film layer on the surface of the present invention. This embodiment is a continuation of the structure of the eleventh preferred embodiment, which differs from the eleventh preferred embodiment in that a laser pressure is provided between the adhesive layer (65) and the plating layer (64). Printed layer (66).

請參看第二十二圖所示,其係本創作之表面具裝飾膜層之金屬基材的其十四較佳實施例結構斷面示意圖。本實施例係延續其十二較佳實施例之結構,其與其十二較佳實施例的差異之處係在:該接著層(65)與該電鍍層(64)之間設有一雷射壓印層(66)。Please refer to the twenty-second figure, which is a structural sectional view of a fourteenth preferred embodiment of the metal substrate with a decorative film layer on the surface of the present invention. This embodiment is a continuation of the structure of the twelve preferred embodiments, which differs from the twelve preferred embodiments in that a laser pressure is provided between the adhesive layer (65) and the plating layer (64). Printed layer (66).

請參看第二十三圖所示,其係本創作之表面具裝飾膜層之金屬基材的其十五較佳實施例結構斷面示意圖。本實施例係延續其十一較佳實施例之結構,其與其十一較佳實施例的差異之處係在:該電鍍層(64)與該著色層(63)之間設有一雷射壓印層(66)。【00100】   請參看第二十四圖所示,其係本創作之表面具裝飾膜層之金屬基材的其十六較佳實施例結構斷面示意圖。本實施例係延續其十二較佳實施例之結構,其與其十二較佳實施例的差異之處係在:該電鍍層(64)與該著色層(63)之間設有一電鍍壓印膜層(6)。【00101】   其中,如上所述本創作之表面具裝飾膜層之金屬基材的其十三~其十六較佳實施例,該雷射壓印層(66)係直接於一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於該接著層(65)或該電鍍層(64)上,使該接著層(65)或該電鍍層(64)上具有凸凹對應的雷射壓紋,而形成該雷射壓印層(66)。【00102】   其中,如上所述本創作之表面具裝飾膜層之金屬基材的其十三~其十六較佳實施例,該雷射壓印層(66)係直接於一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於該接著層(65)或該電鍍層(64)上,使該接著層(65)或該電鍍層(64)上具有凸凹對應的雷射壓紋,而形成該雷射壓印層(66)。【00103】   其中,如上所述本創作之表面具裝飾膜層之金屬基材的其十三~其十六較佳實施例,該雷射壓印層(66)係直接於一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於該接著層(65)或該電鍍層(64)上,使該接著層(65)或該電鍍層(64)上具有凸凹對應的雷射壓紋,而形成該雷射壓印層(66)。【00104】   其中,在本實施例中,該底油層(52)係選自乙烯基類、改性乙烯基類、環氧胺基類或改性醇基類樹脂其中之一。該油墨層(53)係選自丙烯酸類、聚酯類、醇酸基類或改性醇酸基類樹脂其中之一,並加入一定量之白色顏料;該白色顏料選自鈦白粉、二氧化鈦其中之一。該膠合層(54)係採用UV膠、UV光油或UV樹脂其中之一。【00105】   該塑膠薄膜(61)係選自聚乙烯基對苯二甲酯薄膜(PET)。該離形層(62)包括有水性聚胺基甲酸乙脂(PU)或聚胺基甲酸乙脂(PU)其中之一與乙酸纖維素(CA)、乙酸丁酸纖維素(CAB)、乙酸丙酸纖維素(CAP)或硝化纖維素(NC)其中之一及臘(WAX)、三聚氰胺甲醛樹脂(MF)、消泡劑、滑劑。【00106】   而該著色層(63)包括環氧樹脂(EP)、熱可塑性丙烯酸樹脂(AC)、三聚氰胺甲醛樹脂(MF)、熱固型丙烯酸樹脂、聚胺基甲酸乙脂(PU)、丙烯酸多元醇樹脂、松香樹脂其中之一與硝化纖維素(NC)、乙酸丙酸纖維素(CAP)其中之一、邻苯二甲酸二烯丙酯(DAP)及異氰酸脂基(-NCO)架橋劑、羧酸基(-COOH)架橋劑其中一和染料。【00107】   至於該電鍍層(64)之電鍍材質選自鋁或硫化鋅其中之一。該接著層(65)之成分選自熱可塑性丙烯酸樹脂(AC)、聚胺基甲酸乙脂(PU)、氯化聚丙烯(CPP)、氯化丁二烯橡膠(CR)、聚酮樹脂、環氧樹脂(EP)、聚甲基丙烯酸樹脂(PMMA)、氯乙烯樹脂(Vinyl)、松香樹脂、二氧化矽其中之一。【00108】 以上所舉者僅係本創作之部份實施例,並非用以限制本創作,致依本創作之創意精神及特徵,稍加變化修飾而成者,亦應包括在本專利範圍之內。【00109】 綜上所述,本創作實施例確能達到所預期之使用功效,又其所揭露之具體構造,不僅未曾見諸於同類產品中,亦未曾公開於申請前,誠已完全符合專利法之規定與要求,爰依法提出新型專利之申請,懇請惠予審查,並賜准專利,則實感德便。Please refer to the twenty-third figure, which is a structural sectional view of a fifteenth preferred embodiment of the metal substrate with a decorative film on the surface of the present invention. This embodiment is a continuation of the structure of the eleventh preferred embodiment, which differs from the eleventh preferred embodiment in that a laser pressure is applied between the plating layer (64) and the colored layer (63). Printed layer (66). [00100] Please refer to the twenty-fourth figure, which is a structural sectional view of a sixteen preferred embodiment of the metal substrate with a decorative film layer on the surface of the present invention. This embodiment is a continuation of the structure of the twelve preferred embodiments, which differs from the twelve preferred embodiments in that an electroplated embossing is provided between the plating layer (64) and the colored layer (63). Film layer (6). [00101] wherein, as described above, in the thirteenth to sixteenth preferred embodiments of the metal substrate having a decorative film layer as described above, the laser embossing layer (66) is directly on a metal stencil The laser engraving technique forms a laser embossing of the bump, and then the metal stencil is heat-embossed on the adhesive layer (65) or the plating layer (64) to make the adhesive layer (65) or the plating layer (64) The laser embossing layer (66) is formed by a laser embossing corresponding to the convex and concave. [00102] Wherein, as described above, in the thirteenth to sixteenth preferred embodiments of the metal substrate having the decorative film layer as described above, the laser embossing layer (66) is directly on a metal stencil The laser engraving technique forms a laser embossing of the bump, and then the metal stencil is heat-embossed on the adhesive layer (65) or the plating layer (64) to make the adhesive layer (65) or the plating layer (64) The laser embossing layer (66) is formed by a laser embossing corresponding to the convex and concave. [00103] Wherein, as described above, in the thirteenth to sixteenth preferred embodiments of the metal substrate having the decorative film layer as described above, the laser embossing layer (66) is directly on a metal stencil The laser engraving technique forms a laser embossing of the bump, and then the metal stencil is heat-embossed on the adhesive layer (65) or the plating layer (64) to make the adhesive layer (65) or the plating layer (64) The laser embossing layer (66) is formed by a laser embossing corresponding to the convex and concave. [00104] wherein, in the present embodiment, the bottom oil layer (52) is selected from one of a vinyl type, a modified vinyl type, an epoxy amine type or a modified alcohol based type resin. The ink layer (53) is one selected from the group consisting of acrylic, polyester, alkyd or modified alkyd based resins, and a certain amount of white pigment is added; the white pigment is selected from the group consisting of titanium dioxide and titanium dioxide. one. The glue layer (54) is one of UV glue, UV varnish or UV resin. [00105] The plastic film (61) is selected from the group consisting of polyvinyl terephthalate film (PET). The release layer (62) comprises one of aqueous polyurethane (PU) or polyurethane (PU) and cellulose acetate (CA), cellulose acetate butyrate (CAB), acetic acid One of cellulose propionate (CAP) or nitrocellulose (NC) and wax (WAX), melamine formaldehyde resin (MF), antifoaming agent, and slip agent. [00106] The colored layer (63) comprises epoxy resin (EP), thermoplastic acrylic resin (AC), melamine formaldehyde resin (MF), thermosetting acrylic resin, polyurethane (PU), acrylic acid. One of polyol resin and rosin resin and one of nitrocellulose (NC), cellulose acetate propionate (CAP), diallyl phthalate (DAP) and isocyanate (-NCO) One of a bridging agent, a carboxylic acid group (-COOH) bridging agent and a dye. [00107] The plating material of the plating layer (64) is selected from one of aluminum or zinc sulfide. The component of the adhesive layer (65) is selected from the group consisting of thermoplastic acrylic resin (AC), polyurethane (PU), chlorinated polypropylene (CPP), chlorinated butadiene rubber (CR), polyketone resin, Epoxy resin (EP), polymethacrylic resin (PMMA), vinyl chloride resin (Vinyl), rosin resin, cerium oxide. [00108] The above are only some of the examples of this creation, and are not intended to limit the creation of this creation. The modifications and variations of the creative spirit and characteristics of this creation should also be included in the scope of this patent. Inside. [00109] In summary, the present embodiment can achieve the expected use efficiency, and the specific structure disclosed therein has not been seen in the same product, nor has it been disclosed before the application, and has completely complied with the patent. The provisions and requirements of the law, the application for a new type of patent in accordance with the law, the application for review, and the grant of a patent, the real sense of virtue.

【00110】
(11)‧‧‧金屬基材
(12)‧‧‧底油層
【00111】
(13)‧‧‧油墨層
(14)‧‧‧印刷層
【00112】
(15)‧‧‧膠合層
(2)‧‧‧裝飾膜
【00113】
(21)‧‧‧塑膠薄膜
(22)‧‧‧離形層
【00114】
(24)‧‧‧電鍍層
(25)‧‧‧接著層
【00115】
(26)‧‧‧雷射壓印層
(31)‧‧‧上光層
【00116】
(41)‧‧‧雷射壓紋層
(42)‧‧‧塑膠基材
【00117】
(43)‧‧‧塗佈層
(51)‧‧‧金屬基材
【00118】
(52)‧‧‧底油層
(53)‧‧‧油墨層
【00119】
(54)‧‧‧膠合層
(71)‧‧‧印刷層
【00120】
(72)‧‧‧上光層
(6)‧‧‧電鍍壓印膜層
【00121】
(61)‧‧‧塑膠薄膜
(62)‧‧‧離形層
【00122】
(63)‧‧‧著色層
(64)‧‧‧電鍍層
【00123】
(65)‧‧‧接著層
(66)‧‧‧雷射壓印層
[00110]
(11)‧‧‧Metal substrate (12)‧‧‧ bottom oil layer [00111]
(13) ‧ ‧ ink layer (14) ‧ ‧ printed layer [00112]
(15) ‧ ‧ glue layer (2) ‧ ‧ decorative film [00113]
(21)‧‧‧Plastic film (22)‧‧‧Fractal layer [00114]
(24) ‧‧‧Electroplating layer (25)‧‧‧Next layer [00115]
(26) ‧‧‧Laser embossing layer (31)‧‧‧ glazing layer [00116]
(41)‧‧‧Laser embossed layer (42)‧‧‧Plastic substrate [00117]
(43) ‧ ‧ coating layer (51) ‧ ‧ metal substrate [00118]
(52) ‧ ‧ bottom oil layer (53) ‧ ‧ ink layer [00119]
(54) ‧ ‧ glue layer (71) ‧ ‧ print layer [00120]
(72) ‧ ‧ glazing layer (6) ‧ ‧ electroplating embossing film layer [00121]
(61)‧‧‧Plastic film (62)‧‧‧Fractal layer [00122]
(63)‧‧‧Colored layer (64)‧‧‧ plating layer [00123]
(65) ‧‧‧Layer (66)‧‧‧Laser embossing

第一圖:本創作之表面具裝飾膜層之金屬基材的其一較佳實施例結構斷面示意圖First: a schematic cross-sectional view of a preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention

第二圖:本創作之表面具裝飾膜層之金屬基材的其一較佳實施例成型步驟示意圖Fig. 2 is a schematic view showing a molding step of a preferred embodiment of the metal substrate having a decorative film layer on the surface of the present invention

第三圖:本創作之表面具裝飾膜層之金屬基材的其二較佳實施例結構斷面示意圖Third: a schematic cross-sectional view of a second preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention

第四圖:本創作之表面具裝飾膜層之金屬基材的其二較佳實施例的成型步驟示意圖Fig. 4 is a schematic view showing the molding steps of the second preferred embodiment of the metal substrate having the decorative film layer on the surface of the creation

第五圖:本創作之表面具裝飾膜層之金屬基材的其三較佳實施例結構斷面示意圖Fig. 5 is a schematic sectional view showing the structure of a metal substrate having a decorative film layer on the surface of the present invention

第六圖:本創作之表面具裝飾膜層之金屬基材的其四較佳實施例結構斷面示意圖Fig. 6 is a cross-sectional view showing the structure of a fourth preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention

第七圖:本創作之表面具裝飾膜層之金屬基材的其五較佳實施例結構斷面示意圖Figure 7 is a cross-sectional view showing the structure of a five-preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention.

第八圖:係本創作之表面具裝飾膜層之金屬基材的其六較佳實施例結構斷面示意圖Figure 8 is a cross-sectional view showing the structure of a six-preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention.

第九圖:係本創作之表面具裝飾膜層之金屬基材的其七較佳實施例結構斷面示意圖Ninth view: a schematic sectional view of a seventh preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention

第十圖:係本創作之表面具裝飾膜層之金屬基材的其七較佳實施例之雷射壓紋成型層的成型示意圖Fig. 10 is a schematic view showing the formation of a laser embossed layer of a seventh preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention.

第十一圖:係本創作之表面具裝飾膜層之金屬基材的其八較佳實施例結構斷面示意圖Figure 11 is a cross-sectional view showing the structure of a preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention.

第十二圖:係本創作之表面具裝飾膜層之金屬基材的其八較佳實施例之雷射壓紋成型層的成型示意圖Twelfth Figure: Schematic diagram of the laser embossed forming layer of the eight preferred embodiments of the metal substrate having the decorative film layer on the surface of the present invention

第十三圖:係本創作之表面具裝飾膜層之金屬基材的其九較佳實施例結構斷面示意圖Thirteenth Figure: A schematic cross-sectional view of a nine preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention

第十四圖:係本創作之表面具裝飾膜層之金屬基材的其九較佳實施例之雷射壓紋成型層的成型示意圖Figure 14 is a schematic view showing the formation of a laser embossed layer of the nine preferred embodiments of the metal substrate having a decorative film layer on the surface of the present invention.

第十五圖:本創作之表面具裝飾膜層之金屬基材的其十較佳實施例結構斷面示意圖Fifteenth Figure: Schematic cross-sectional view of a ten preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention

第十六圖:係本創作之表面具裝飾膜層之金屬基材的其十較佳實施例之雷射壓紋成型層的成型示意圖Figure 16 is a schematic view showing the formation of a laser embossed layer of a tenth preferred embodiment of the metal substrate having a decorative film layer on the surface of the present invention.

第十七圖:係本創作之表面具裝飾膜層之金屬基材的其十一較佳實施例結構斷面示意圖Figure 17 is a cross-sectional view showing the structure of the eleventh preferred embodiment of the metal substrate having the decorative film layer on the surface of the present invention.

第十八圖:係本創作之表面具裝飾膜層之金屬基材的其十一較佳實施例之雷射壓紋成型層的成型示意圖Figure 18: Schematic diagram of the laser embossed forming layer of the eleventh preferred embodiment of the metal substrate having the decorative film layer on the surface of the present invention

第十九圖:係本創作之表面具裝飾膜層之金屬基材的其十二較佳實施例結構斷面示意圖Figure 19 is a cross-sectional view showing the structure of a twelve-preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention.

第二十圖:係本創作之表面具裝飾膜層之金屬基材的其十二較佳實施例之雷射壓紋成型層的成型示意圖Figure 20: Schematic diagram of the laser embossed forming layer of the twelve preferred embodiment of the metal substrate having the decorative film layer on the surface of the present invention

第二十一圖:係本創作之表面具裝飾膜層之金屬基材的其十三較佳實施例結構斷面示意圖21: A schematic cross-sectional view of a thirteenth preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention

第二十二圖:係本創作之表面具裝飾膜層之金屬基材的其十四較佳實施例結構斷面示意圖Twenty-second diagram: a schematic sectional view of a fourteenth preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention

第二十三圖:係本創作之表面具裝飾膜層之金屬基材的其十五較佳實施例結構斷面示意圖Twenty-third drawing: a schematic sectional view of a fifteenth preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention

第二十四圖:係本創作之表面具裝飾膜層之金屬基材的其十六較佳實施例結構斷面示意圖Figure 24 is a cross-sectional view showing the structure of a sixteen preferred embodiment of a metal substrate having a decorative film layer on the surface of the present invention.

(11)‧‧‧金屬基材(11)‧‧‧Metal substrate

(12)‧‧‧底油層(12) ‧‧‧ bottom oil layer

(13)‧‧‧油墨層(13) ‧ ‧ ink layer

(14)‧‧‧印刷層(14) ‧‧‧Printing layer

(15)‧‧‧膠合層(15)‧‧‧Glued layers

(23)‧‧‧著色層(23) ‧‧‧Colored layer

(24)‧‧‧電鍍層(24)‧‧‧Electroplating

(25)‧‧‧接著層(25) ‧‧‧Next layer

(31)‧‧‧上光層(31) ‧ ‧ glazing

Claims (39)

一種表面具裝飾膜層之金屬基材,係在一金屬基材表面由下而上依序包括有一底油層、一油墨層、一印刷層、一膠合層、一接著層、一電鍍層、一著色層及一上光層;據此,即能在金屬基材表面形成電鍍壓印膜層,且具備表面平整度佳、耐刮性佳、製作容易、節省成本之效果。A metal substrate having a decorative film layer on a surface of a metal substrate, which comprises a bottom oil layer, an ink layer, a printing layer, a glue layer, an adhesive layer, a plating layer, and a layer from bottom to top. The colored layer and a glazing layer can form an electroplated embossed film layer on the surface of the metal substrate, and have the advantages of good surface flatness, good scratch resistance, easy production, and cost saving. 如申請專利範圍第1項所述之表面具裝飾膜層之金屬基材,其中,該著色層與該上光層之間設有一離形層。The metal substrate having a decorative film layer on the surface according to claim 1, wherein a release layer is disposed between the colored layer and the glazing layer. 如申請專利範圍第2項所述之表面具裝飾膜層之金屬基材,其中,在該接著層與該電鍍層之間設有一雷射壓印層。A metal substrate having a decorative film layer as described in claim 2, wherein a laser embossing layer is disposed between the bonding layer and the plating layer. 如申請專利範圍第3項所述之表面具裝飾膜層之金屬基材,其中,該雷射壓印層係直接於一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於該接著層或該電鍍層上,使該該接著層或該電鍍層上具有凸凹對應的雷射壓紋。The metal substrate with a decorative film layer as described in claim 3, wherein the laser embossing layer is directly embossed by a laser engraving technique on a metal stencil, and then The metal stencil is heat-embossed on the adhesive layer or the plating layer such that the adhesive layer or the plating layer has a convex and concave corresponding laser embossing. 如申請專利範圍第2項所述之表面具裝飾膜層之金屬基材,其中,該電鍍層與該著色層之間設有一雷射壓印層。A metal substrate having a decorative film layer as described in claim 2, wherein a laser embossing layer is disposed between the plating layer and the colored layer. 如申請專利範圍第5項所述之表面具裝飾膜層之金屬基材,其中,該雷射壓印層係直接於一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於該接著層或該電鍍層上,使該該接著層或該電鍍層上具有凸凹對應的雷射壓紋。The metal substrate with a decorative film layer as described in claim 5, wherein the laser embossing layer is directly formed on a metal stencil by laser engraving technology to form a convex laser embossing, and then The metal stencil is heat-embossed on the adhesive layer or the plating layer such that the adhesive layer or the plating layer has a convex and concave corresponding laser embossing. 如申請專利範圍第2項所述之表面具裝飾膜層之金屬基材,其中,該離形層與該上光層之間設有一雷射壓紋層。A metal substrate having a decorative film layer as described in claim 2, wherein a laser embossed layer is disposed between the release layer and the glazing layer. 如申請專利範圍第7項所述之表面具裝飾膜層之金屬基材,其中,該雷射壓紋層係先在一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於一塑膠基材表面,使該塑膠基材表面具有凸凹對應的雷射壓紋,再將該塑膠基材以具有雷射壓紋的表面與該離形層結合,待彼此之間的結合狀態固化後,再撕除一部份厚度的該塑膠基材,該撕除的一部份厚度上包含有雷射壓紋,使該離形層表面留有一部分未被撕除包含有雷射壓紋的該塑膠基材,並因此形成該雷射壓紋層。The metal substrate with a decorative film layer as described in claim 7 , wherein the laser embossed layer is first formed on a metal stencil by laser engraving technology to form a convex laser embossing, and then The metal stencil is heat-embossed on the surface of a plastic substrate, so that the surface of the plastic substrate has convex and concave corresponding embossing, and the plastic substrate is combined with the embossed surface and the release layer. After curing the bonding state of each other, a part of the thickness of the plastic substrate is removed, and a portion of the tearing portion is covered with a laser embossing, so that a part of the surface of the release layer is not torn. In addition to the plastic substrate comprising the laser embossing, the laser embossed layer is thus formed. 如申請專利範圍第2項所述之表面具裝飾膜層之金屬基材,其中,該離形層與該上光層之間由下而上依序設有一雷射壓紋層、一塗佈層。The metal substrate having a decorative film layer on the surface according to claim 2, wherein a laser embossed layer and a coating are sequentially disposed between the release layer and the glazing layer from bottom to top. Floor. 如申請專利範圍第9項所述之表面具裝飾膜層之金屬基材,其中,該雷射壓紋層係先在一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,並於一塑膠基材表面設該塗佈層,將該金屬模版加熱壓印於該塗佈層表面,使該塗佈層表面具有凸凹對應的雷射壓紋,再將該塗佈層以具有雷射壓紋的表面與該離形層結合,待彼此之間的結合狀態固化後,再撕除該塑膠基材與該塗佈層的一部份厚度,且該撕除的一部份厚度上包含有雷射壓紋,使該該離形層表面留有另一部分未被撕除且包含有雷射壓紋的塗佈層,令該雷射壓紋成型於該離形層表面,並因此形成該雷射壓紋層。The metal substrate with a decorative film layer as described in claim 9 , wherein the laser embossed layer is first formed on a metal stencil by laser engraving technology to form a convex embossing of the concave and convex, and a coating layer is disposed on a surface of a plastic substrate, and the metal stencil is heat-embossed on the surface of the coating layer, so that the surface of the coating layer has a convex embossing corresponding to the convex and concave, and then the coating layer has a laser The embossed surface is combined with the release layer, and after the bonding state between the two is cured, a part of the thickness of the plastic substrate and the coating layer is peeled off, and a part of the thickness of the tearing layer is included Laser embossing, leaving the surface of the release layer with another portion of the coating layer that has not been torn off and contains laser embossing, so that the laser embossing is formed on the surface of the release layer, and thus formed The laser embossed layer. 如申請專利範圍第1項所述之表面具裝飾膜層之金屬基材,其中,在該接著層與該電鍍層之間設有一雷射壓印層。A metal substrate having a decorative film layer as described in claim 1, wherein a laser embossing layer is disposed between the bonding layer and the plating layer. 如申請專利範圍第11項所述之表面具裝飾膜層之金屬基材,其中,該雷射壓印層係直接於一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於該接著層或該電鍍層上,使該該接著層或該電鍍層上具有凸凹對應的雷射壓紋。The metal substrate having a decorative film layer as described in claim 11 , wherein the laser embossing layer is directly formed on a metal stencil by laser engraving technology to form a convex embossing of the concave and convex, and then The metal stencil is heat-embossed on the adhesive layer or the plating layer such that the adhesive layer or the plating layer has a convex and concave corresponding laser embossing. 如申請專利範圍第1項所述之表面具裝飾膜層之金屬基材,其中,該電鍍層與該著色層之間設有一雷射壓印層。The metal substrate having a decorative film layer on the surface of the first aspect of the invention, wherein a laser embossing layer is disposed between the plating layer and the colored layer. 如申請專利範圍第13項所述之表面具裝飾膜層之金屬基材,其中,該雷射壓印層係直接於一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於該接著層或該電鍍層上,使該該接著層或該電鍍層上具有凸凹對應的雷射壓紋。The metal substrate with a decorative film layer as described in claim 13 , wherein the laser embossing layer is directly formed on a metal stencil by laser engraving technology to form a convex laser embossing, and then The metal stencil is heat-embossed on the adhesive layer or the plating layer such that the adhesive layer or the plating layer has a convex and concave corresponding laser embossing. 如申請專利範圍第1項所述之表面具裝飾膜層之金屬基材,其中,該著色層與該上光層之間設有一雷射壓紋層。The metal substrate having a decorative film layer on the surface according to claim 1, wherein a laser embossed layer is disposed between the colored layer and the glazing layer. 如申請專利範圍第15項所述之表面具裝飾膜層之金屬基材,其中,該雷射壓紋層係先在一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於一塑膠基材表面,使該塑膠基材表面具有凸凹對應的雷射壓紋,再將該塑膠基材以具有雷射壓紋的表面與該著色層結合,待彼此之間的結合狀態固化後,再撕除一部份厚度的該塑膠基材,該撕除的一部份厚度上包含有雷射壓紋,使該著色層表面留有一部分未被撕除包含有雷射壓紋的該塑膠基材,令該著色層表面留有所需之部分雷射壓紋,並因此形成該雷射壓紋層。The metal substrate with a decorative film layer as described in claim 15 , wherein the laser embossed layer is first formed on a metal stencil by laser engraving technology to form a convex embossing of the concave and convex, and then The metal stencil is heat-embossed on the surface of a plastic substrate, so that the surface of the plastic substrate has a convex and concave corresponding embossing, and the plastic substrate is combined with the colored layer by a laser embossed surface to be mutually After the bonding state is cured, a part of the thickness of the plastic substrate is peeled off, and a portion of the tearing portion is covered with a laser embossing, so that a part of the surface of the colored layer is left unpeeled. The plastic substrate having laser embossing leaves the surface of the colored layer with a desired portion of the laser embossing and thus forms the laser embossed layer. 如申請專利範圍第1項所述之表面具裝飾膜層之金屬基材,其中,該著色層與該上光層之間由下而上依序設有一雷射壓紋層、一塗佈層。 The metal substrate having a decorative film layer on the surface of the first aspect of the invention, wherein the colored layer and the glazing layer are sequentially provided with a laser embossed layer and a coating layer from bottom to top. . 如申請專利範圍第17項所述之表面具裝飾膜層之金屬基材,其中,該雷射壓紋層係先在一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,並於一塑膠基材表面設該塗佈層,將該金屬模版加熱壓印於該塗佈層表面,使該塗佈層表面具有凸凹對應的雷射壓紋,再將該塗佈層以具有雷射壓紋的表面與該著色層貼合,結合,待彼此之間的結合狀態固化後,再撕除該塑膠基材與該塗佈層的一部份厚度,且該撕除的一部份厚度上包含有雷射壓紋,使該著色層表面留有另一部分未被撕除且包含有雷射壓紋的塗佈層,令該雷射壓紋成型於該著色層表面,並因此形成該雷射壓紋層。 The metal substrate having a decorative film layer as described in claim 17, wherein the laser embossed layer is formed by laser engraving on a metal stencil by a laser engraving technique, and a coating layer is disposed on a surface of a plastic substrate, and the metal stencil is heat-embossed on the surface of the coating layer, so that the surface of the coating layer has a convex embossing corresponding to the convex and concave, and then the coating layer has a laser The embossed surface is adhered to the colored layer, and after being bonded to each other, the part of the plastic substrate and the coating layer is peeled off, and a part of the thickness of the peeling layer is removed. Having a laser embossing thereon, leaving a surface of the colored layer with another portion of the coating layer that is not torn off and containing the laser embossing, so that the laser embossing is formed on the surface of the colored layer, and thus the Laser embossed layer. 如申請專利範圍第8或16項所述之表面具裝飾膜層之金屬基材,其中,該塑膠基材係選自雙軸拉伸聚丙烯薄膜(BOPP)。 The metal substrate having a decorative film layer as described in claim 8 or 16, wherein the plastic substrate is selected from the group consisting of biaxially oriented polypropylene film (BOPP). 如申請專利範圍第10或18項所述之表面具裝飾膜層之金屬基材,其中,該塑膠基材係選自聚乙烯基對苯二甲酯薄膜(PET)或雙軸拉伸聚丙烯薄膜(BOPP)。 The metal substrate having a decorative film layer as described in claim 10 or 18, wherein the plastic substrate is selected from the group consisting of polyvinyl terephthalate film (PET) or biaxially oriented polypropylene. Film (BOPP). 一種表面具裝飾膜層之金屬基材,係在一金屬基材表面由下而上依序包括有一底油層、一油墨層、一膠合層、一接著層、一電鍍層、一著色層、一印刷層及一上光層;據此,即能在金屬基材表面形成電鍍壓印膜層,且具備表面平整度佳、耐刮性佳、製作容易、節省成本之效果。 A metal substrate having a decorative film layer on a surface of a metal substrate, which comprises a bottom oil layer, an ink layer, a glue layer, an adhesive layer, a plating layer, a colored layer, and a layer on the surface of the metal substrate. The printed layer and a glazing layer can form an electroplated embossed film layer on the surface of the metal substrate, and have the advantages of good surface flatness, good scratch resistance, easy fabrication, and cost saving. 如申請專利範圍第21項所述之表面具裝飾膜層之金屬基材,其中,該著色層與該印刷層之間設有一離形層。The metal substrate having a decorative film layer on the surface according to claim 21, wherein a release layer is disposed between the colored layer and the printed layer. 如申請專利範圍第22項所述之表面具裝飾膜層之金屬基材,其中,在該接著層與該電鍍層之間設有一雷射壓印層。A metal substrate having a decorative film layer as described in claim 22, wherein a laser embossing layer is disposed between the bonding layer and the plating layer. 如申請專利範圍第23項所述之表面具裝飾膜層之金屬基材,其中,該雷射壓印層係直接於一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於該接著層上,使該接著層上具有凸凹對應的雷射壓紋。The metal substrate having a decorative film layer as described in claim 23, wherein the laser embossing layer is directly formed on a metal stencil by laser engraving technology to form a convex laser embossing, and then The metal stencil is heat-embossed on the adhesive layer such that the adhesive layer has a convex and concave corresponding laser embossing. 如申請專利範圍第22項所述之表面具裝飾膜層之金屬基材,其中,該電鍍層與該著色層之間設有一雷射壓印層。The metal substrate having a decorative film layer on the surface according to claim 22, wherein a laser embossing layer is disposed between the plating layer and the colored layer. 如申請專利範圍第25項所述之表面具裝飾膜層之金屬基材,其中,該雷射壓印層係直接於一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於該電鍍層上,使該電鍍層上具有凸凹對應的雷射壓紋。The metal substrate with a decorative film layer as described in claim 25, wherein the laser embossing layer is directly formed on a metal stencil by laser engraving technology to form a convex embossing of the concave and convex, and then The metal stencil is heat-embossed on the plating layer such that the plating layer has a convex and concave corresponding laser embossing. 如申請專利範圍第21項所述之表面具裝飾膜層之金屬基材,其中,在該接著層與該電鍍層之間設有一雷射壓印層。A metal substrate having a decorative film layer as described in claim 21, wherein a laser embossing layer is disposed between the bonding layer and the plating layer. 如申請專利範圍第27項所述之表面具裝飾膜層之金屬基材,其中,該雷射壓印層係直接於一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於該接著層上,使該接著層上具有凸凹對應的雷射壓紋。The metal substrate with a decorative film layer as described in claim 27, wherein the laser embossing layer is directly formed on a metal stencil by laser engraving technology to form a convex embossing of the concave and convex, and then The metal stencil is heat-embossed on the adhesive layer such that the adhesive layer has a convex and concave corresponding laser embossing. 如申請專利範圍第21項所述之表面具裝飾膜層之金屬基材,其中,該電鍍層與該著色層之間設有一雷射壓印層。The metal substrate having a decorative film layer on the surface according to claim 21, wherein a laser embossing layer is disposed between the plating layer and the colored layer. 如申請專利範圍第29項所述之表面具裝飾膜層之金屬基材,其中,該雷射壓印層係直接於一金屬模版上以雷射雕刻技術成型凹凸之雷射壓紋,再將該金屬模版加熱壓印於該電鍍層上,使該電鍍層上具有凸凹對應的雷射壓紋。The metal substrate with a decorative film layer as described in claim 29, wherein the laser embossing layer is directly formed on a metal stencil by laser engraving technology to form a convex laser embossing, and then The metal stencil is heat-embossed on the plating layer such that the plating layer has a convex and concave corresponding laser embossing. 如申請專利範圍第2至10、22至26項中任意一項所述之表面具裝飾膜層之金屬基材,其中,該離型層包括有水性聚胺基甲酸乙脂(PU)或聚胺基甲酸乙脂(PU)其中之一與乙酸纖維素(CA)、乙酸丁酸纖維素(CAB)、乙酸丙酸纖維素(CAP)或硝化纖維素(NC)其中之一及臘(WAX)、三聚氰胺甲醛樹脂(MF)、消泡劑、滑劑。The metal substrate having a decorative film layer on the surface according to any one of claims 2 to 10, 22 to 26, wherein the release layer comprises aqueous polyurethane (PU) or poly One of urethane (PU) and one of cellulose acetate (CA), cellulose acetate butyrate (CAB), cellulose acetate propionate (CAP) or nitrocellulose (NC) and wax (WAX) ), melamine formaldehyde resin (MF), defoamer, slip agent. 如申請專利範圍第1至18、21至30項中任意一項所述之表面具裝飾膜層之金屬基材,其中,該底油層係選自乙烯基類、改性乙烯基類、環氧胺基類或改性醇基類樹脂其中之一。The metal substrate having a decorative film layer on the surface according to any one of claims 1 to 18, wherein the bottom oil layer is selected from the group consisting of vinyl, modified vinyl, and epoxy. One of an amine-based or modified alcohol-based resin. 如申請專利範圍第1至18、21至30項中任意一項所述之表面具裝飾膜層之金屬基材,其中,該油墨層係選自丙烯酸類、聚酯類、醇酸基類或改性醇酸基類樹脂其中之一,並加入一定量之白色顏料。The metal substrate having a decorative film layer on the surface according to any one of claims 1 to 18, wherein the ink layer is selected from the group consisting of acrylic, polyester, alkyd or One of the modified alkyd-based resins, and a certain amount of white pigment is added. 如申請專利範圍第33項所述之表面具裝飾膜層之金屬基材,其中,該白色顏料選自鈦白粉、二氧化鈦其中之一。The metal substrate having a decorative film layer as described in claim 33, wherein the white pigment is selected from one of titanium dioxide and titanium dioxide. 如申請專利範圍第1至18、21至30項中任意一項所述之表面具裝飾膜層之金屬基材,其中,該膠合層係採用UV膠、UV光油或UV樹脂其中之一。The metal substrate having a decorative film layer on the surface according to any one of claims 1 to 18, wherein the bonding layer is one of UV glue, UV varnish or UV resin. 如申請專利範圍第1至18、21至30項中任意一項所述之表面具裝飾膜層之金屬基材,其中,該上光層係選自丙烯酸類、丙烯酸氨基類、環氧類、醇酸類或聚醇類樹脂其中之一。The metal substrate having a decorative film layer on the surface according to any one of claims 1 to 18, wherein the glazing layer is selected from the group consisting of acrylics, acrylics, and epoxys. One of alkyd or polyalcohol resins. 如申請專利範圍第1至18、21至30項中任意一項所述之表面具裝飾膜層之金屬基材,其中,該著色層包括環氧樹脂(EP)、熱可塑性丙烯酸樹脂(AC)、三聚氰胺甲醛樹脂(MF)、熱固型丙烯酸樹脂、聚胺基甲酸乙脂(PU)、丙烯酸多元醇樹脂、松香樹脂其中之一與硝化纖維素(NC)、乙酸丙酸纖維素(CAP)其中之一、邻苯二甲酸二烯丙酯(DAP)及異氰酸脂基(-NCO)架橋劑、羧酸基(-COOH)架橋劑其中一和染料。The metal substrate having a decorative film layer on the surface according to any one of claims 1 to 18, wherein the colored layer comprises an epoxy resin (EP) or a thermoplastic acrylic resin (AC). , melamine formaldehyde resin (MF), thermosetting acrylic resin, polyurethane (PU), acrylic polyol resin, rosin resin and nitrocellulose (NC), cellulose acetate propionate (CAP) One of them, diallyl phthalate (DAP) and isocyanate-based (-NCO) bridging agent, carboxylic acid group (-COOH) bridging agent and dye. 如申請專利範圍第1至18、21至30項中任意一項所述之表面具裝飾膜層之金屬基材,其中,該電鍍層之電鍍材質選自鋁或硫化鋅其中之一。The metal substrate having a decorative film layer on the surface according to any one of claims 1 to 18, wherein the plating material is selected from one of aluminum or zinc sulfide. 如申請專利範圍第1至18、21至30項中任意一項所述之表面具裝飾膜層之金屬基材,其中,該接著層之成分選自熱可塑性丙烯酸樹脂(AC)、聚胺基甲酸乙脂(PU)、氯化聚丙烯(CPP)、氯化丁二烯橡膠(CR)、聚酮樹脂、環氧樹脂(EP)、聚甲基丙烯酸樹脂(PMMA)、氯乙烯樹脂(Vinyl)、松香樹脂、二氧化矽其中之一。The metal substrate having a decorative film layer on the surface according to any one of claims 1 to 18, wherein the adhesive layer is selected from the group consisting of thermoplastic acrylic resin (AC) and polyamine. Ethyl formate (PU), chlorinated polypropylene (CPP), chlorinated butadiene rubber (CR), polyketone resin, epoxy resin (EP), polymethacrylic resin (PMMA), vinyl chloride resin (Vinyl) ), one of rosin resin and cerium oxide.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109527723A (en) * 2018-11-29 2019-03-29 深圳市联星服装辅料有限公司 A kind of production method of double-colored metal zip fastener

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109527723A (en) * 2018-11-29 2019-03-29 深圳市联星服装辅料有限公司 A kind of production method of double-colored metal zip fastener

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