CN104793355A - Electronic control intelligent light dimming base material component - Google Patents
Electronic control intelligent light dimming base material component Download PDFInfo
- Publication number
- CN104793355A CN104793355A CN201510229735.6A CN201510229735A CN104793355A CN 104793355 A CN104793355 A CN 104793355A CN 201510229735 A CN201510229735 A CN 201510229735A CN 104793355 A CN104793355 A CN 104793355A
- Authority
- CN
- China
- Prior art keywords
- composite coating
- electric
- light modulation
- polymer composite
- high polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title abstract description 8
- 238000000576 coating method Methods 0.000 claims abstract description 25
- 239000011248 coating agent Substances 0.000 claims abstract description 24
- 239000002131 composite material Substances 0.000 claims abstract description 23
- 239000011521 glass Substances 0.000 claims abstract description 21
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229920000831 ionic polymer Polymers 0.000 claims abstract description 15
- 239000007788 liquid Substances 0.000 claims abstract description 15
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 9
- 239000000758 substrate Substances 0.000 claims description 45
- 229920000642 polymer Polymers 0.000 claims description 21
- 230000000712 assembly Effects 0.000 claims description 17
- 238000000429 assembly Methods 0.000 claims description 17
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 15
- 239000010410 layer Substances 0.000 claims description 8
- 239000003292 glue Substances 0.000 claims description 7
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 6
- 239000002608 ionic liquid Substances 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 6
- 229960003280 cupric chloride Drugs 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000011247 coating layer Substances 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 11
- 239000004332 silver Substances 0.000 abstract description 11
- 229910052709 silver Inorganic materials 0.000 abstract description 11
- 239000004973 liquid crystal related substance Substances 0.000 abstract description 4
- 238000002834 transmittance Methods 0.000 abstract description 3
- 229920002521 macromolecule Polymers 0.000 abstract 5
- 239000006185 dispersion Substances 0.000 abstract 2
- 235000000396 iron Nutrition 0.000 abstract 1
- 230000008859 change Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/0102—Constructional details, not otherwise provided for in this subclass
Abstract
The invention relates to an electronic control intelligent light dimming base material component. The electronic control intelligent light dimming base material component comprises two base boards and a macromolecule dispersion liquid crystal layer, wherein the two base boards are correspondingly arranged in parallel, and the macromolecule dispersion liquid crystal layer is formed between the two base boards, faces, which are in contact with a macromolecule coating, of the two base boards are conducting faces, and the macromolecule composite coating comprises polyion liquid and silver nitrate. By using the macromolecule composite coating comprising the polyion liquid and the silver nitrate, when the conducting faces are powered on, silver irons can be restored to silver, a mirror face is formed, the light transmittance of a glass component is changed, and the glass component can serve as a mirror to be used by a consumer; on the other hand, when the conducting faces do not conduct, the silver can be oxidized by reacting with the polyion liquid, and the silver is recovered to be in an original state.
Description
Technical field
The invention belongs to ambetti field, relate to a kind of substrate assemblies, be specifically related to a kind of electric-controlled intelligent minute surface light modulation substrate assemblies.
Background technology
Glass is the ornament materials that Discussion on architecture is conventional, from glass curtain wall, window, automobile and public transport, shower/glass sunlight house, showcase and show window etc.In a lot of situation, people use the mode of installing curtain to realize object that is heat insulation, attractive in appearance, that maintain secrecy usually, and curtain is installed not only increases investment, and take the interior space, also constantly clean and change, and switch curtain is very inconvenient, therefore people extremely wish a kind of glass of energy auto-changing transmittance.This glass is identical with simple glass under normal circumstances, change transmittance when certain condition (as energising), plays the effect of curtain.
The patent No. be 200420079163.5 Chinese utility model patent disclose a kind of intelligent dimming glass, this glass uses liquid crystal material layer effect light modulation layer, thus under the effect of electric current, realize the control to glass transmission rate.Although this intelligent dimming glass has all advantages, the liquid crystal material that it is selected is poisonous, and that just requires higher to its sealing, thus improves the difficulty of its manufacture craft to a certain extent.
Summary of the invention
The present invention seeks to provide a kind of electric-controlled intelligent minute surface light modulation substrate assemblies to overcome the deficiencies in the prior art.
For achieving the above object, the technical solution used in the present invention is: a kind of electric-controlled intelligent minute surface light modulation substrate assemblies, it comprise parallel and corresponding setting two pieces of substrates, be formed at high polymer composite coating between two pieces of described substrates, the face that two pieces of described substrates contact with described polymeric coating layer is conducting surface, and described high polymer composite coating comprises poly ion liquid and silver nitrate.
Optimally, it also comprise respectively with the electrode slice that described conducting surface contacts and the switch that be connected corresponding with described electrode slice.
Optimally, it also comprises the glass be bonded in by glue layer on described outer surface of substrate.
Optimally, described high polymer composite coating comprises the composition of following parts by weight:
Poly ion liquid 10 ~ 50 parts;
Silver nitrate 1 ~ 5 part.
Further, described high polymer composite coating also comprises 0.1 ~ 1 part of cupric chloride.
Further, described high polymer composite coating (3) also comprises 20 ~ 50 parts of dimethyl sulfoxide (DMSO)s.
Further, described high polymer composite coating (3) also comprises the ionic liquid monomer of 20 ~ 50 parts of described poly ion liquids of preparation.
Further, described ionic liquid monomer is
m=0 ~ 15 in formula, n=1 ~ 6, p=1 ~ 4, X is Cl, Br or I.
Because technique scheme is used, the present invention compared with prior art has following advantages: electric-controlled intelligent minute surface light modulation substrate assemblies of the present invention, by using the high polymer composite coating comprising poly ion liquid and silver nitrate, silver ion reduction can be become silver and form minute surface when conducting surface is energized, thus change the light transmission of glass assembly, and can use to consumer as mirror; On the other hand when conducting surface is non-conductive, silver can with poly ion liquid effect and silver is oxidized, restPose.
Accompanying drawing explanation
Accompanying drawing 1 is the structural representation of electric-controlled intelligent minute surface light modulation substrate assemblies of the present invention;
Wherein, 1, substrate; 2, substrate; 3, high polymer composite coating; 4, glass; 5, glass; 6, glue layer; 7, electrode slice; 8, switch; 9, electrode slice; 10, switch.
Embodiment
Below in conjunction with accompanying drawing, the preferred embodiment of the invention is described in detail:
Electric-controlled intelligent minute surface light modulation substrate assemblies as shown in Figure 1, it mainly comprises substrate 1, substrate 2 and high polymer composite coating 3.
Wherein, substrate 1 and substrate 2 are parallel to each other and corresponding arrange, and defining their one sides is in opposite directions inside surface, and the one side supported or opposed is outside surface, then the inside surface of substrate 1 and substrate 2 is conducting surface; Substrate 1 and substrate 2 can be electro-conductive glass, also can be flexible conductive film materials or other is transparent and have Traditional flexible or the non-flexible material of conducting surface.High polymer composite coating 3 is formed between substrate 1 and substrate 2, and namely it contacts with the inside surface of substrate 1, substrate 2; This high polymer composite coating 3 comprises poly ion liquid and silver nitrate, silver ion reduction can be become silver and form minute surface like this, thus change the light transmission of glass assembly, and can use to consumer as mirror when conducting surface is energized; On the other hand when conducting surface is non-conductive, silver can with poly ion liquid effect and silver is oxidized, restPose.
In the present embodiment, electric-controlled intelligent minute surface light modulation substrate assemblies also comprises the electrode slice 7 contacted with the conducting surface of substrate 1, the electrode slice 9 contacted with the conducting surface of substrate 2, and the switch 8, the switch 10 that are connected with electrode slice 7, electrode slice 9 respectively.Electrode slice 7 and electrode slice 9 are arranged on the marginal portion of substrate 1, substrate 2 conducting surface, in L-type.Switch 8, switch 10 can be regular tap, dimmer switch, light-operated switch, light-operated dimmer switch, audio-switch, teleswitch, remote-control light-modulating switch, far infrared switch, the switch based on NFC technique, the switch etc. based on wireless transmission technique, and then the controlling functions realized in the present embodiment, the long-range network control switch that can also control with telepilot, computer-controlled long-range network control switch, mobile phone development of Mobile Internet technology or be designed to all kinds of gauge tap as required.
In the present embodiment, electric-controlled intelligent minute surface light modulation substrate assemblies also comprises and is bonded in the glass 4 on substrate 1 outside surface by glue layer 6 and is bonded in the glass 5 on substrate 2 outside surface by glue layer 6, glue layer 6 is transparent, can be optic-solidified adhesive, heat-curable glue etc.
In the present embodiment, high polymer composite coating 3 comprises the composition of following parts by weight: poly ion liquid 10 ~ 50 parts; Silver nitrate 1 ~ 5 part.In order to stable silver mirror, high polymer composite coating 3 also comprises 0.1 ~ 1 part of cupric chloride.In order to improve the circulation of high polymer composite coating, thus reduce the difficulty of its coating process, high polymer composite coating 3 also comprises 20 ~ 50 parts of dimethyl sulfoxide (DMSO)s or/and the ionic liquid monomer of 20 ~ 50 parts of above-mentioned poly ion liquids of preparation, be conducive to reducing oxygen to its impact, improve serviceable life, these ionic liquid monomer are preferably
m=0 ~ 15 in formula, n=1 ~ 6, p=1 ~ 4, X is Cl, Br or I.
Above-described embodiment is only for illustrating technical conceive of the present invention and feature; its object is to person skilled in the art can be understood content of the present invention and implement according to this; can not limit the scope of the invention with this; all equivalences done according to Spirit Essence of the present invention change or modify, and all should be encompassed within protection scope of the present invention.
Claims (8)
1. an electric-controlled intelligent minute surface light modulation substrate assemblies, it comprises two pieces of substrates (1 of parallel and corresponding setting, 2) two pieces of described substrates (1, are formed at, 2) high polymer composite coating (3) between, two pieces of described substrates (1,2) face contacted with described polymeric coating layer (3) is conducting surface, it is characterized in that, described high polymer composite coating (3) comprises poly ion liquid and silver nitrate.
2. electric-controlled intelligent minute surface light modulation substrate assemblies according to claim 1, it is characterized in that: it also comprises the electrode slice (7 contacted with described conducting surface respectively, 9) and with the switch (8,10) of described electrode slice (7,9) corresponding connection.
3. intelligent dimming two-way mirror assembly according to claim 1 and 2, is characterized in that: it also comprises the glass (4,5) be bonded in by glue layer (6) on described substrate (1,2) outside surface.
4. electric-controlled intelligent minute surface light modulation substrate assemblies according to claim 1, it is characterized in that, described high polymer composite coating (3) comprises the composition of following parts by weight:
Poly ion liquid 10 ~ 50 parts;
Silver nitrate 1 ~ 5 part.
5. electric-controlled intelligent minute surface light modulation substrate assemblies according to claim 4, is characterized in that: described high polymer composite coating (3) also comprises 0.1 ~ 1 part of cupric chloride.
6. the electric-controlled intelligent minute surface light modulation substrate assemblies according to claim 4 or 5, is characterized in that: described high polymer composite coating (3) also comprises 20 ~ 50 parts of dimethyl sulfoxide (DMSO)s.
7. electric-controlled intelligent minute surface light modulation substrate assemblies according to claim 1, is characterized in that: described high polymer composite coating (3) also comprises the ionic liquid monomer of 20 ~ 50 parts of described poly ion liquids of preparation.
8. electric-controlled intelligent minute surface light modulation substrate assemblies according to claim 7, is characterized in that: described ionic liquid monomer is
,
m=0 ~ 15 in formula, n=1 ~ 6, p=1 ~ 4, X is Cl, Br or I.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510229735.6A CN104793355B (en) | 2015-05-06 | 2015-05-06 | A kind of electric-controlled intelligent minute surface dims substrate assemblies |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510229735.6A CN104793355B (en) | 2015-05-06 | 2015-05-06 | A kind of electric-controlled intelligent minute surface dims substrate assemblies |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104793355A true CN104793355A (en) | 2015-07-22 |
| CN104793355B CN104793355B (en) | 2017-09-29 |
Family
ID=53558299
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510229735.6A Expired - Fee Related CN104793355B (en) | 2015-05-06 | 2015-05-06 | A kind of electric-controlled intelligent minute surface dims substrate assemblies |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104793355B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108711366A (en) * | 2018-05-22 | 2018-10-26 | 张飞 | A kind of advertisement play back device |
| CN109031835A (en) * | 2018-08-06 | 2018-12-18 | 康曦 | A kind of electric-controlled intelligent light modulation device liquid-crystal composition and its application |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040150866A1 (en) * | 2003-01-31 | 2004-08-05 | Innovative Technology Licensing, Llc | Locally-switched reversible electrodeposition optical modulator |
| US20050248825A1 (en) * | 2004-05-04 | 2005-11-10 | Rockwell Scientific Licensing, Llc | Reversible electrodeposition optical modulation device with conducting polymer counter electrode |
| CN104317129A (en) * | 2014-10-28 | 2015-01-28 | 电子科技大学 | High-throughput screening electrochromic device for electrochromic materials and method for manufacturing high-throughput screening electrochromic device |
| CN104614913A (en) * | 2015-03-05 | 2015-05-13 | 哈尔滨工业大学 | Method for preparing flexible adhesive electrochromic device capable of being switched between mirror state and transparent state |
| CN104788022A (en) * | 2015-03-31 | 2015-07-22 | 哈尔滨工业大学 | Preparation method and application of flaky nano-silver electrochromic film |
-
2015
- 2015-05-06 CN CN201510229735.6A patent/CN104793355B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040150866A1 (en) * | 2003-01-31 | 2004-08-05 | Innovative Technology Licensing, Llc | Locally-switched reversible electrodeposition optical modulator |
| US20050248825A1 (en) * | 2004-05-04 | 2005-11-10 | Rockwell Scientific Licensing, Llc | Reversible electrodeposition optical modulation device with conducting polymer counter electrode |
| CN104317129A (en) * | 2014-10-28 | 2015-01-28 | 电子科技大学 | High-throughput screening electrochromic device for electrochromic materials and method for manufacturing high-throughput screening electrochromic device |
| CN104614913A (en) * | 2015-03-05 | 2015-05-13 | 哈尔滨工业大学 | Method for preparing flexible adhesive electrochromic device capable of being switched between mirror state and transparent state |
| CN104788022A (en) * | 2015-03-31 | 2015-07-22 | 哈尔滨工业大学 | Preparation method and application of flaky nano-silver electrochromic film |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108711366A (en) * | 2018-05-22 | 2018-10-26 | 张飞 | A kind of advertisement play back device |
| CN109031835A (en) * | 2018-08-06 | 2018-12-18 | 康曦 | A kind of electric-controlled intelligent light modulation device liquid-crystal composition and its application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104793355B (en) | 2017-09-29 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170928 Address after: 244002 No. 695, north section of Taishan Avenue, Tongling Economic Development Zone, Anhui Patentee after: Anhui Mcgee Mstar Technology Ltd. Address before: 215121 city garden, Suzhou Industrial Park, Jiangsu 34-804, China Patentee before: Yan Feng |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170929 |